#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/62/4086293.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4086293
loop_
_publ_author_name
'Gu, Xiaoxia'
'Zhang, Lijun'
'Zhu, Xiancui'
'Wang, Shaowu'
'Zhou, Shuangliu'
'Wei, Yun'
'Zhang, Guangchao'
'Mu, Xiaolong'
'Huang, Zeming'
'Hong, Dongjing'
'Zhang, Feng'
_publ_section_title
;
 Synthesis of Bis(NHC)-Based CNC-Pincer Rare-Earth-Metal Amido Complexes
 and Their Application for the Hydrophosphination of Heterocumulenes
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              4553
_journal_paper_doi               10.1021/acs.organomet.5b00628
_journal_volume                  34
_journal_year                    2015
_chemical_formula_sum            'C34 H58 Eu N7 Si4'
_chemical_formula_weight         829.19
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.2560(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.9169(8)
_cell_length_b                   29.663(2)
_cell_length_c                   12.2490(8)
_cell_measurement_reflns_used    8970
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.18
_cell_measurement_theta_min      2.20
_cell_volume                     4177.3(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0604
_diffrn_reflns_av_sigmaI/netI    0.0620
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       38
_diffrn_reflns_limit_k_min       -38
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            35540
_diffrn_reflns_theta_full        27.42
_diffrn_reflns_theta_max         27.42
_diffrn_reflns_theta_min         1.37
_exptl_absorpt_coefficient_mu    1.647
_exptl_absorpt_correction_T_max  0.8268
_exptl_absorpt_correction_T_min  0.7670
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.318
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1720
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.983
_refine_diff_density_min         -0.863
_refine_diff_density_rms         0.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     431
_refine_ls_number_reflns         9471
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.0798
_refine_ls_R_factor_gt           0.0424
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0308P)²+2.1033P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0750
_refine_ls_wR_factor_ref         0.0853
_reflns_number_gt                6469
_reflns_number_total             9471
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om5b00628_si_003.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 
;
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               4086293
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.7106(4) 0.04381(14) 0.1392(3) 0.0439(10) Uani 1 1 d .
C2 C 0.6471(4) -0.02375(16) 0.0610(4) 0.0610(13) Uani 1 1 d .
H2 H 0.6142 -0.0524 0.0525 0.073 Uiso 1 1 calc R
C3 C 0.6902(4) -0.00175(15) -0.0134(4) 0.0558(12) Uani 1 1 d .
H3 H 0.6939 -0.0121 -0.0840 0.067 Uiso 1 1 calc R
C22 C 0.6308(5) -0.00906(17) 0.2565(4) 0.0711(15) Uani 1 1 d .
H22A H 0.6769 -0.0346 0.2893 0.107 Uiso 1 1 calc R
H22B H 0.5499 -0.0169 0.2391 0.107 Uiso 1 1 calc R
H22C H 0.6460 0.0156 0.3091 0.107 Uiso 1 1 calc R
C4 C 0.7921(4) 0.07158(14) -0.0133(3) 0.0407(10) Uani 1 1 d .
C5 C 0.8785(4) 0.05537(16) -0.0602(3) 0.0487(11) Uani 1 1 d .
H5 H 0.8921 0.0245 -0.0601 0.058 Uiso 1 1 calc R
C6 C 0.9443(4) 0.08389(17) -0.1070(4) 0.0530(12) Uani 1 1 d .
C7 C 0.9202(4) 0.12908(17) -0.1079(4) 0.0567(12) Uani 1 1 d .
H7 H 0.9622 0.1491 -0.1403 0.068 Uiso 1 1 calc R
C8 C 0.8341(4) 0.14544(15) -0.0612(4) 0.0559(12) Uani 1 1 d .
H8 H 0.8203 0.1763 -0.0631 0.067 Uiso 1 1 calc R
C9 C 0.7678(4) 0.11773(14) -0.0119(3) 0.0411(10) Uani 1 1 d .
C10 C 1.0403(4) 0.06595(19) -0.1537(4) 0.0777(16) Uani 1 1 d .
H10A H 1.0220 0.0717 -0.2336 0.117 Uiso 1 1 calc R
H10B H 1.0482 0.0341 -0.1404 0.117 Uiso 1 1 calc R
H10C H 1.1121 0.0807 -0.1170 0.117 Uiso 1 1 calc R
C11 C 0.5811(4) 0.14706(12) -0.0262(3) 0.0359(9) Uani 1 1 d .
C16 C 0.5044(4) 0.17826(13) 0.0047(3) 0.0397(10) Uani 1 1 d .
C15 C 0.3923(4) 0.18511(15) -0.0636(4) 0.0534(12) Uani 1 1 d .
H15 H 0.3432 0.2044 -0.0380 0.064 Uiso 1 1 calc R
C14 C 0.3506(4) 0.16466(16) -0.1673(4) 0.0554(12) Uani 1 1 d .
C13 C 0.4254(4) 0.13562(15) -0.2006(4) 0.0495(11) Uani 1 1 d .
H13 H 0.4007 0.1214 -0.2706 0.059 Uiso 1 1 calc R
C12 C 0.5348(4) 0.12695(13) -0.1343(3) 0.0416(10) Uani 1 1 d .
H12 H 0.5813 0.1069 -0.1611 0.050 Uiso 1 1 calc R
C17 C 0.2296(4) 0.1741(2) -0.2406(5) 0.094(2) Uani 1 1 d .
H17A H 0.1819 0.1852 -0.1944 0.140 Uiso 1 1 calc R
H17B H 0.1965 0.1468 -0.2775 0.140 Uiso 1 1 calc R
H17C H 0.2334 0.1962 -0.2966 0.140 Uiso 1 1 calc R
C18 C 0.6186(4) 0.19162(13) 0.2041(3) 0.0384(9) Uani 1 1 d .
C19 C 0.4971(4) 0.24712(15) 0.1168(4) 0.0614(14) Uani 1 1 d .
H19 H 0.4433 0.2629 0.0611 0.074 Uiso 1 1 calc R
C20 C 0.5459(5) 0.26102(15) 0.2209(4) 0.0633(14) Uani 1 1 d .
H20 H 0.5329 0.2884 0.2526 0.076 Uiso 1 1 calc R
C21 C 0.6897(4) 0.22955(16) 0.3905(4) 0.0640(14) Uani 1 1 d .
H21A H 0.6882 0.2008 0.4260 0.096 Uiso 1 1 calc R
H21B H 0.6587 0.2522 0.4305 0.096 Uiso 1 1 calc R
H21C H 0.7684 0.2371 0.3919 0.096 Uiso 1 1 calc R
C23 C 0.4535(4) 0.05766(17) 0.4185(4) 0.0694(15) Uani 1 1 d .
H23A H 0.4877 0.0297 0.4045 0.104 Uiso 1 1 calc R
H23B H 0.3707 0.0562 0.3882 0.104 Uiso 1 1 calc R
H23C H 0.4715 0.0630 0.4986 0.104 Uiso 1 1 calc R
C24 C 0.4372(4) 0.15709(17) 0.3779(4) 0.0670(14) Uani 1 1 d .
H24A H 0.4631 0.1643 0.4569 0.100 Uiso 1 1 calc R
H24B H 0.3548 0.1520 0.3574 0.100 Uiso 1 1 calc R
H24C H 0.4548 0.1817 0.3342 0.100 Uiso 1 1 calc R
C25 C 0.4569(4) 0.09425(16) 0.1931(4) 0.0581(13) Uani 1 1 d .
H25A H 0.4777 0.1190 0.1518 0.087 Uiso 1 1 calc R
H25B H 0.3737 0.0914 0.1741 0.087 Uiso 1 1 calc R
H25C H 0.4902 0.0669 0.1736 0.087 Uiso 1 1 calc R
C26 C 0.6587(5) 0.1322(2) 0.6240(4) 0.090(2) Uani 1 1 d .
H26A H 0.6509 0.1638 0.6070 0.135 Uiso 1 1 calc R
H26B H 0.7028 0.1281 0.7010 0.135 Uiso 1 1 calc R
H26C H 0.5829 0.1191 0.6134 0.135 Uiso 1 1 calc R
C27 C 0.7607(5) 0.04519(18) 0.5794(4) 0.0798(17) Uani 1 1 d .
H27A H 0.6873 0.0303 0.5707 0.120 Uiso 1 1 calc R
H27B H 0.8027 0.0453 0.6579 0.120 Uiso 1 1 calc R
H27C H 0.8051 0.0295 0.5364 0.120 Uiso 1 1 calc R
C28 C 0.8794(4) 0.13322(17) 0.5572(4) 0.0633(14) Uani 1 1 d .
H28A H 0.9245 0.1205 0.5105 0.095 Uiso 1 1 calc R
H28B H 0.9199 0.1293 0.6355 0.095 Uiso 1 1 calc R
H28C H 0.8677 0.1648 0.5410 0.095 Uiso 1 1 calc R
C29 C 0.9487(4) 0.04364(17) 0.3604(4) 0.0683(14) Uani 1 1 d .
H29A H 0.9028 0.0538 0.4093 0.102 Uiso 1 1 calc R
H29B H 1.0007 0.0203 0.3975 0.102 Uiso 1 1 calc R
H29C H 0.8985 0.0320 0.2916 0.102 Uiso 1 1 calc R
C30 C 1.1533(4) 0.1018(2) 0.4584(4) 0.0773(16) Uani 1 1 d .
H30A H 1.2033 0.1254 0.4451 0.116 Uiso 1 1 calc R
H30B H 1.1976 0.0747 0.4791 0.116 Uiso 1 1 calc R
H30C H 1.1200 0.1106 0.5186 0.116 Uiso 1 1 calc R
C31 C 1.1061(5) 0.0693(2) 0.2186(4) 0.0799(17) Uani 1 1 d .
H31A H 1.0477 0.0625 0.1500 0.120 Uiso 1 1 calc R
H31B H 1.1485 0.0424 0.2469 0.120 Uiso 1 1 calc R
H31C H 1.1585 0.0915 0.2034 0.120 Uiso 1 1 calc R
C32 C 1.0681(6) 0.2181(2) 0.4022(5) 0.112(2) Uani 1 1 d .
H32A H 1.0191 0.2144 0.4524 0.169 Uiso 1 1 calc R
H32B H 1.0772 0.2496 0.3890 0.169 Uiso 1 1 calc R
H32C H 1.1429 0.2050 0.4357 0.169 Uiso 1 1 calc R
C33 C 1.1109(5) 0.1884(2) 0.1815(5) 0.093(2) Uani 1 1 d .
H33A H 1.1806 0.1742 0.2254 0.139 Uiso 1 1 calc R
H33B H 1.1281 0.2187 0.1637 0.139 Uiso 1 1 calc R
H33C H 1.0811 0.1718 0.1127 0.139 Uiso 1 1 calc R
C34 C 0.8851(5) 0.22857(17) 0.1853(5) 0.0795(17) Uani 1 1 d .
H34A H 0.8345 0.2129 0.1228 0.119 Uiso 1 1 calc R
H34B H 0.9207 0.2535 0.1574 0.119 Uiso 1 1 calc R
H34C H 0.8408 0.2395 0.2349 0.119 Uiso 1 1 calc R
Eu1 Eu 0.748475(18) 0.121865(6) 0.239757(15) 0.03397(7) Uani 1 1 d .
N1 N 0.6607(3) 0.00423(12) 0.1527(3) 0.0499(9) Uani 1 1 d .
N2 N 0.7286(3) 0.03945(11) 0.0346(3) 0.0442(8) Uani 1 1 d .
N3 N 0.6873(3) 0.13623(11) 0.0432(3) 0.0394(8) Uani 1 1 d .
N4 N 0.5412(3) 0.20456(11) 0.1061(3) 0.0417(8) Uani 1 1 d .
N5 N 0.6193(3) 0.22743(12) 0.2733(3) 0.0479(9) Uani 1 1 d .
N6 N 0.6623(3) 0.10772(11) 0.3875(3) 0.0389(8) Uani 1 1 d .
N7 N 0.9447(3) 0.13717(12) 0.2826(3) 0.0463(9) Uani 1 1 d .
Si1 Si 0.51349(11) 0.10488(4) 0.34867(10) 0.0452(3) Uani 1 1 d .
Si2 Si 0.73523(11) 0.10418(5) 0.52748(10) 0.0491(3) Uani 1 1 d .
Si3 Si 1.03451(11) 0.09176(5) 0.32685(11) 0.0536(3) Uani 1 1 d .
Si4 Si 1.00018(13) 0.18930(5) 0.26431(12) 0.0621(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N1 C1 N2 102.5(3)
N1 C1 Eu1 138.1(3)
N2 C1 Eu1 118.6(3)
C3 C2 N1 106.3(4)
C3 C2 H2 126.9
N1 C2 H2 126.9
C2 C3 N2 106.7(4)
C2 C3 H3 126.6
N2 C3 H3 126.6
N1 C22 H22A 109.5
N1 C22 H22B 109.5
H22A C22 H22B 109.5
N1 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C5 C4 C9 121.4(4)
C5 C4 N2 117.8(4)
C9 C4 N2 120.8(4)
C6 C5 C4 121.6(4)
C6 C5 H5 119.2
C4 C5 H5 119.2
C7 C6 C5 117.6(4)
C7 C6 C10 121.4(5)
C5 C6 C10 121.0(5)
C6 C7 C8 121.0(4)
C6 C7 H7 119.5
C8 C7 H7 119.5
C9 C8 C7 122.8(4)
C9 C8 H8 118.6
C7 C8 H8 118.6
C8 C9 C4 115.6(4)
C8 C9 N3 120.8(4)
C4 C9 N3 123.4(4)
C6 C10 H10A 109.5
C6 C10 H10B 109.5
H10A C10 H10B 109.5
C6 C10 H10C 109.5
H10A C10 H10C 109.5
H10B C10 H10C 109.5
N3 C11 C16 122.9(3)
N3 C11 C12 123.3(4)
C16 C11 C12 113.7(4)
C15 C16 C11 121.2(4)
C15 C16 N4 117.9(4)
C11 C16 N4 120.9(4)
C14 C15 C16 123.1(4)
C14 C15 H15 118.4
C16 C15 H15 118.4
C15 C14 C13 116.4(4)
C15 C14 C17 121.5(5)
C13 C14 C17 122.0(5)
C12 C13 C14 122.1(4)
C12 C13 H13 118.9
C14 C13 H13 118.9
C13 C12 C11 123.3(4)
C13 C12 H12 118.3
C11 C12 H12 118.3
C14 C17 H17A 109.5
C14 C17 H17B 109.5
H17A C17 H17B 109.5
C14 C17 H17C 109.5
H17A C17 H17C 109.5
H17B C17 H17C 109.5
N5 C18 N4 102.7(3)
N5 C18 Eu1 128.6(3)
N4 C18 Eu1 128.2(3)
C20 C19 N4 107.0(4)
C20 C19 H19 126.5
N4 C19 H19 126.5
C19 C20 N5 106.8(4)
C19 C20 H20 126.6
N5 C20 H20 126.6
N5 C21 H21A 109.5
N5 C21 H21B 109.5
H21A C21 H21B 109.5
N5 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
Si1 C23 H23A 109.5
Si1 C23 H23B 109.5
H23A C23 H23B 109.5
Si1 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
Si1 C24 H24A 109.5
Si1 C24 H24B 109.5
H24A C24 H24B 109.5
Si1 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
Si1 C25 H25A 109.5
Si1 C25 H25B 109.5
H25A C25 H25B 109.5
Si1 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
Si2 C26 H26A 109.5
Si2 C26 H26B 109.5
H26A C26 H26B 109.5
Si2 C26 H26C 109.5
H26A C26 H26C 109.5
H26B C26 H26C 109.5
Si2 C27 H27A 109.5
Si2 C27 H27B 109.5
H27A C27 H27B 109.5
Si2 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
Si2 C28 H28A 109.5
Si2 C28 H28B 109.5
H28A C28 H28B 109.5
Si2 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
Si3 C29 H29A 109.5
Si3 C29 H29B 109.5
H29A C29 H29B 109.5
Si3 C29 H29C 109.5
H29A C29 H29C 109.5
H29B C29 H29C 109.5
Si3 C30 H30A 109.5
Si3 C30 H30B 109.5
H30A C30 H30B 109.5
Si3 C30 H30C 109.5
H30A C30 H30C 109.5
H30B C30 H30C 109.5
Si3 C31 H31A 109.5
Si3 C31 H31B 109.5
H31A C31 H31B 109.5
Si3 C31 H31C 109.5
H31A C31 H31C 109.5
H31B C31 H31C 109.5
Si4 C32 H32A 109.5
Si4 C32 H32B 109.5
H32A C32 H32B 109.5
Si4 C32 H32C 109.5
H32A C32 H32C 109.5
H32B C32 H32C 109.5
Si4 C33 H33A 109.5
Si4 C33 H33B 109.5
H33A C33 H33B 109.5
Si4 C33 H33C 109.5
H33A C33 H33C 109.5
H33B C33 H33C 109.5
Si4 C34 H34A 109.5
Si4 C34 H34B 109.5
H34A C34 H34B 109.5
Si4 C34 H34C 109.5
H34A C34 H34C 109.5
H34B C34 H34C 109.5
N7 Eu1 N6 119.01(11)
N7 Eu1 N3 102.64(11)
N6 Eu1 N3 137.65(11)
N7 Eu1 C18 114.38(12)
N6 Eu1 C18 84.71(12)
N3 Eu1 C18 70.67(11)
N7 Eu1 C1 108.77(13)
N6 Eu1 C1 98.60(12)
N3 Eu1 C1 73.15(12)
C18 Eu1 C1 128.17(13)
C1 N1 C2 112.9(4)
C1 N1 C22 123.9(4)
C2 N1 C22 123.1(4)
C1 N2 C3 111.6(4)
C1 N2 C4 123.6(3)
C3 N2 C4 124.4(4)
C11 N3 C9 115.3(3)
C11 N3 Eu1 131.6(2)
C9 N3 Eu1 110.4(2)
C18 N4 C19 111.1(3)
C18 N4 C16 126.3(3)
C19 N4 C16 122.6(4)
C18 N5 C20 112.3(4)
C18 N5 C21 123.7(4)
C20 N5 C21 124.0(4)
Si2 N6 Si1 119.44(19)
Si2 N6 Eu1 125.12(17)
Si1 N6 Eu1 115.28(15)
Si3 N7 Si4 121.2(2)
Si3 N7 Eu1 115.35(18)
Si4 N7 Eu1 123.34(19)
N6 Si1 C25 111.10(19)
N6 Si1 C24 115.1(2)
C25 Si1 C24 105.7(2)
N6 Si1 C23 113.6(2)
C25 Si1 C23 105.0(2)
C24 Si1 C23 105.5(2)
N6 Si2 C27 113.3(2)
N6 Si2 C26 113.8(2)
C27 Si2 C26 105.4(3)
N6 Si2 C28 111.46(19)
C27 Si2 C28 107.9(2)
C26 Si2 C28 104.4(3)
N7 Si3 C29 109.8(2)
N7 Si3 C30 114.5(2)
C29 Si3 C30 105.5(2)
N7 Si3 C31 114.6(2)
C29 Si3 C31 105.2(3)
C30 Si3 C31 106.5(2)
N7 Si4 C34 112.0(2)
N7 Si4 C33 114.1(2)
C34 Si4 C33 104.8(3)
N7 Si4 C32 112.4(2)
C34 Si4 C32 105.5(3)
C33 Si4 C32 107.3(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 N1 1.346(5)
C1 N2 1.360(5)
C1 Eu1 2.606(4)
C2 C3 1.329(6)
C2 N1 1.372(5)
C2 H2 0.9300
C3 N2 1.381(5)
C3 H3 0.9300
C22 N1 1.462(5)
C22 H22A 0.9600
C22 H22B 0.9600
C22 H22C 0.9600
C4 C5 1.390(5)
C4 C9 1.400(5)
C4 N2 1.435(5)
C5 C6 1.377(6)
C5 H5 0.9300
C6 C7 1.370(6)
C6 C10 1.505(6)
C7 C8 1.387(6)
C7 H7 0.9300
C8 C9 1.384(6)
C8 H8 0.9300
C9 N3 1.420(5)
C10 H10A 0.9600
C10 H10B 0.9600
C10 H10C 0.9600
C11 N3 1.365(5)
C11 C16 1.420(5)
C11 C12 1.424(5)
C16 C15 1.392(6)
C16 N4 1.435(5)
C15 C14 1.376(6)
C15 H15 0.9300
C14 C13 1.377(6)
C14 C17 1.511(6)
C13 C12 1.366(6)
C13 H13 0.9300
C12 H12 0.9300
C17 H17A 0.9600
C17 H17B 0.9600
C17 H17C 0.9600
C18 N5 1.357(5)
C18 N4 1.362(5)
C18 Eu1 2.552(4)
C19 C20 1.321(6)
C19 N4 1.387(5)
C19 H19 0.9300
C20 N5 1.368(6)
C20 H20 0.9300
C21 N5 1.461(5)
C21 H21A 0.9600
C21 H21B 0.9600
C21 H21C 0.9600
C23 Si1 1.878(5)
C23 H23A 0.9600
C23 H23B 0.9600
C23 H23C 0.9600
C24 Si1 1.877(5)
C24 H24A 0.9600
C24 H24B 0.9600
C24 H24C 0.9600
C25 Si1 1.874(4)
C25 H25A 0.9600
C25 H25B 0.9600
C25 H25C 0.9600
C26 Si2 1.867(5)
C26 H26A 0.9600
C26 H26B 0.9600
C26 H26C 0.9600
C27 Si2 1.859(5)
C27 H27A 0.9600
C27 H27B 0.9600
C27 H27C 0.9600
C28 Si2 1.870(5)
C28 H28A 0.9600
C28 H28B 0.9600
C28 H28C 0.9600
C29 Si3 1.863(5)
C29 H29A 0.9600
C29 H29B 0.9600
C29 H29C 0.9600
C30 Si3 1.868(5)
C30 H30A 0.9600
C30 H30B 0.9600
C30 H30C 0.9600
C31 Si3 1.878(5)
C31 H31A 0.9600
C31 H31B 0.9600
C31 H31C 0.9600
C32 Si4 1.875(6)
C32 H32A 0.9600
C32 H32B 0.9600
C32 H32C 0.9600
C33 Si4 1.864(5)
C33 H33A 0.9600
C33 H33B 0.9600
C33 H33C 0.9600
C34 Si4 1.864(5)
C34 H34A 0.9600
C34 H34B 0.9600
C34 H34C 0.9600
Eu1 N7 2.303(3)
Eu1 N6 2.342(3)
Eu1 N3 2.364(3)
N6 Si2 1.710(3)
N6 Si1 1.712(3)
N7 Si3 1.717(4)
N7 Si4 1.719(4)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N1 C2 C3 N2 -0.4(5)
C9 C4 C5 C6 0.3(6)
N2 C4 C5 C6 -179.4(4)
C4 C5 C6 C7 -1.3(6)
C4 C5 C6 C10 177.8(4)
C5 C6 C7 C8 1.3(7)
C10 C6 C7 C8 -177.8(4)
C6 C7 C8 C9 -0.2(7)
C7 C8 C9 C4 -0.8(6)
C7 C8 C9 N3 174.7(4)
C5 C4 C9 C8 0.8(6)
N2 C4 C9 C8 -179.6(4)
C5 C4 C9 N3 -174.6(4)
N2 C4 C9 N3 5.0(6)
N3 C11 C16 C15 -173.6(4)
C12 C11 C16 C15 4.1(5)
N3 C11 C16 N4 7.9(6)
C12 C11 C16 N4 -174.3(3)
C11 C16 C15 C14 -4.0(7)
N4 C16 C15 C14 174.5(4)
C16 C15 C14 C13 1.3(7)
C16 C15 C14 C17 -178.1(5)
C15 C14 C13 C12 0.8(7)
C17 C14 C13 C12 -179.8(5)
C14 C13 C12 C11 -0.3(7)
N3 C11 C12 C13 175.6(4)
C16 C11 C12 C13 -2.1(6)
N4 C19 C20 N5 0.2(6)
N5 C18 Eu1 N7 -56.5(4)
N4 C18 Eu1 N7 114.9(3)
N5 C18 Eu1 N6 63.0(4)
N4 C18 Eu1 N6 -125.6(4)
N5 C18 Eu1 N3 -152.0(4)
N4 C18 Eu1 N3 19.4(3)
N5 C18 Eu1 C1 159.8(3)
N4 C18 Eu1 C1 -28.8(4)
N1 C1 Eu1 N7 124.7(4)
N2 C1 Eu1 N7 -67.1(3)
N1 C1 Eu1 N6 -0.1(5)
N2 C1 Eu1 N6 168.2(3)
N1 C1 Eu1 N3 -137.4(5)
N2 C1 Eu1 N3 30.8(3)
N1 C1 Eu1 C18 -90.1(5)
N2 C1 Eu1 C18 78.1(3)
N2 C1 N1 C2 -0.3(5)
Eu1 C1 N1 C2 169.1(3)
N2 C1 N1 C22 175.9(4)
Eu1 C1 N1 C22 -14.7(7)
C3 C2 N1 C1 0.5(6)
C3 C2 N1 C22 -175.8(4)
N1 C1 N2 C3 0.0(5)
Eu1 C1 N2 C3 -171.9(3)
N1 C1 N2 C4 -173.0(4)
Eu1 C1 N2 C4 15.0(5)
C2 C3 N2 C1 0.2(5)
C2 C3 N2 C4 173.2(4)
C5 C4 N2 C1 130.8(4)
C9 C4 N2 C1 -48.8(6)
C5 C4 N2 C3 -41.3(6)
C9 C4 N2 C3 139.0(4)
C16 C11 N3 C9 -159.0(4)
C12 C11 N3 C9 23.5(5)
C16 C11 N3 Eu1 41.9(5)
C12 C11 N3 Eu1 -135.6(3)
C8 C9 N3 C11 83.5(5)
C4 C9 N3 C11 -101.3(4)
C8 C9 N3 Eu1 -113.0(4)
C4 C9 N3 Eu1 62.2(4)
N7 Eu1 N3 C11 -156.7(3)
N6 Eu1 N3 C11 13.0(4)
C18 Eu1 N3 C11 -45.0(3)
C1 Eu1 N3 C11 97.2(3)
N7 Eu1 N3 C9 43.4(3)
N6 Eu1 N3 C9 -146.9(3)
C18 Eu1 N3 C9 155.1(3)
C1 Eu1 N3 C9 -62.6(3)
N5 C18 N4 C19 0.1(5)
Eu1 C18 N4 C19 -173.0(3)
N5 C18 N4 C16 -177.8(4)
Eu1 C18 N4 C16 9.1(6)
C20 C19 N4 C18 -0.2(6)
C20 C19 N4 C16 177.8(4)
C15 C16 N4 C18 149.5(4)
C11 C16 N4 C18 -32.0(6)
C15 C16 N4 C19 -28.2(6)
C11 C16 N4 C19 150.3(4)
N4 C18 N5 C20 0.0(5)
Eu1 C18 N5 C20 173.1(3)
N4 C18 N5 C21 179.5(4)
Eu1 C18 N5 C21 -7.4(6)
C19 C20 N5 C18 -0.1(6)
C19 C20 N5 C21 -179.6(4)
N7 Eu1 N6 Si2 -4.4(3)
N3 Eu1 N6 Si2 -172.89(16)
C18 Eu1 N6 Si2 -119.4(2)
C1 Eu1 N6 Si2 112.7(2)
N7 Eu1 N6 Si1 170.88(16)
N3 Eu1 N6 Si1 2.4(3)
C18 Eu1 N6 Si1 55.88(18)
C1 Eu1 N6 Si1 -71.98(19)
N6 Eu1 N7 Si3 73.2(2)
N3 Eu1 N7 Si3 -114.74(17)
C18 Eu1 N7 Si3 170.97(16)
C1 Eu1 N7 Si3 -38.5(2)
N6 Eu1 N7 Si4 -110.6(2)
N3 Eu1 N7 Si4 61.5(2)
C18 Eu1 N7 Si4 -12.8(2)
C1 Eu1 N7 Si4 137.8(2)
Si2 N6 Si1 C25 -165.1(2)
Eu1 N6 Si1 C25 19.4(2)
Si2 N6 Si1 C24 74.9(3)
Eu1 N6 Si1 C24 -100.6(2)
Si2 N6 Si1 C23 -46.9(3)
Eu1 N6 Si1 C23 137.6(2)
Si1 N6 Si2 C27 84.1(3)
Eu1 N6 Si2 C27 -100.8(3)
Si1 N6 Si2 C26 -36.2(3)
Eu1 N6 Si2 C26 138.9(3)
Si1 N6 Si2 C28 -153.9(2)
Eu1 N6 Si2 C28 21.2(3)
Si4 N7 Si3 C29 170.7(2)
Eu1 N7 Si3 C29 -13.0(3)
Si4 N7 Si3 C30 52.3(3)
Eu1 N7 Si3 C30 -131.4(2)
Si4 N7 Si3 C31 -71.2(3)
Eu1 N7 Si3 C31 105.1(2)
Si3 N7 Si4 C34 166.8(3)
Eu1 N7 Si4 C34 -9.2(3)
Si3 N7 Si4 C33 47.9(3)
Eu1 N7 Si4 C33 -128.1(3)
Si3 N7 Si4 C32 -74.5(3)
Eu1 N7 Si4 C32 109.4(3)
