#------------------------------------------------------------------------------
#$Date: 2019-11-24 06:13:25 +0200 (Sun, 24 Nov 2019) $
#$Revision: 236917 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/08/76/4087676.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4087676
loop_
_publ_author_name
'Ibad, Muhammad Farooq'
'Schulz, Axel'
'Villinger, Alexander'
_publ_section_title
;
 Pentafluorophenyl Silver: Structure and Bonding of Arene Solvates
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3893
_journal_paper_doi               10.1021/acs.organomet.5b00492
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C24 Ag4 F20, 4(C8 H10)'
_chemical_formula_sum            'C56 H40 Ag4 F20'
_chemical_formula_weight         1524.36
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 122.3270(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   24.5615(7)
_cell_length_b                   11.7306(4)
_cell_length_c                   21.5206(10)
_cell_measurement_reflns_used    9852
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      65.027
_cell_measurement_theta_min      5.063
_cell_volume                     5239.5(3)
_computing_cell_refinement       'Bruker Apex V7.51A'
_computing_data_collection       'Bruker Apex V7.51A'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP-3v2.01 (Farrugia, 1997)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker Apex Kappa II-CCD-diffractometer'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0495
_diffrn_reflns_av_sigmaI/netI    0.0395
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_h_min       -37
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            47856
_diffrn_reflns_theta_full        32.55
_diffrn_reflns_theta_max         32.55
_diffrn_reflns_theta_min         1.96
_exptl_absorpt_coefficient_mu    1.583
_exptl_absorpt_correction_T_max  0.8088
_exptl_absorpt_correction_T_min  0.7425
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2004)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.932
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2976
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_refine_diff_density_max         0.813
_refine_diff_density_min         -0.881
_refine_diff_density_rms         0.087
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     399
_refine_ls_number_reflns         9509
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0487
_refine_ls_R_factor_gt           0.0305
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0229P)²+4.3535P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0611
_refine_ls_wR_factor_ref         0.0685
_reflns_number_gt                7336
_reflns_number_total             9509
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            om5b00492_si_002.cif
_cod_data_source_block           av_fi128_AgC6F5_12MeC6H4
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4087676
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.424864(8) 0.474621(15) 0.188119(8) 0.03272(5) Uani 1 1 d . . .
Ag2 Ag 0.519292(7) 0.392751(13) 0.168477(8) 0.02808(4) Uani 1 1 d . . .
C1 C 0.41921(9) 0.33852(17) 0.10451(10) 0.0265(4) Uani 1 1 d . . .
C2 C 0.39814(9) 0.24020(18) 0.12081(10) 0.0284(4) Uani 1 1 d . . .
C3 C 0.34597(10) 0.17708(18) 0.06987(12) 0.0329(4) Uani 1 1 d . . .
C4 C 0.31254(10) 0.2116(2) -0.00234(12) 0.0354(5) Uani 1 1 d . . .
C5 C 0.33060(10) 0.3082(2) -0.02255(10) 0.0327(5) Uani 1 1 d . . .
C6 C 0.38306(10) 0.36901(18) 0.03100(11) 0.0290(4) Uani 1 1 d . . .
C7 C 0.60815(9) 0.49190(17) 0.23188(10) 0.0261(4) Uani 1 1 d . . .
C8 C 0.66859(10) 0.44206(19) 0.26512(11) 0.0312(4) Uani 1 1 d . . .
C9 C 0.72157(10) 0.4960(2) 0.27265(12) 0.0365(5) Uani 1 1 d . . .
C10 C 0.71514(10) 0.6036(2) 0.24541(12) 0.0374(5) Uani 1 1 d . . .
C11 C 0.65643(11) 0.6582(2) 0.21197(11) 0.0346(5) Uani 1 1 d . . .
C12 C 0.60490(9) 0.60157(18) 0.20658(10) 0.0281(4) Uani 1 1 d . . .
C13 C 0.39019(11) 0.6628(2) 0.10612(12) 0.0364(5) Uani 1 1 d . . .
C14 C 0.32725(11) 0.62699(18) 0.07735(11) 0.0338(5) Uani 1 1 d . . .
H14 H 0.3127 0.5593 0.0488 0.041 Uiso 1 1 calc R . .
C15 C 0.28467(10) 0.68778(18) 0.08925(11) 0.0298(4) Uani 1 1 d . . .
C16 C 0.30667(11) 0.78795(19) 0.13048(11) 0.0337(4) Uani 1 1 d . . .
C17 C 0.37021(12) 0.8211(2) 0.16075(12) 0.0398(5) Uani 1 1 d . . .
H17 H 0.3854 0.8880 0.1901 0.048 Uiso 1 1 calc R . .
C18 C 0.41205(11) 0.7593(2) 0.14932(12) 0.0389(5) Uani 1 1 d . . .
H18 H 0.4555 0.7831 0.1711 0.047 Uiso 1 1 calc R . .
C19 C 0.21683(11) 0.6461(2) 0.05621(13) 0.0413(5) Uani 1 1 d . . .
H19A H 0.2124 0.5705 0.0346 0.062 Uiso 1 1 calc R . .
H19B H 0.1870 0.6993 0.0179 0.062 Uiso 1 1 calc R . .
H19C H 0.2069 0.6414 0.0946 0.062 Uiso 1 1 calc R . .
C20 C 0.26202(13) 0.8622(2) 0.14117(15) 0.0492(6) Uani 1 1 d . . .
H20A H 0.2448 0.8181 0.1656 0.074 Uiso 1 1 calc R . .
H20B H 0.2264 0.8885 0.0932 0.074 Uiso 1 1 calc R . .
H20C H 0.2859 0.9281 0.1716 0.074 Uiso 1 1 calc R . .
C21A C 0.5654(4) 0.2897(7) 0.0862(5) 0.0617(16) Uani 0.70(2) 1 d PD A 1
C22A C 0.5710(4) 0.2039(8) 0.1328(4) 0.0559(14) Uani 0.70(2) 1 d PD A 1
H22A H 0.6066 0.2046 0.1823 0.067 Uiso 0.70(2) 1 calc PR A 1
C23A C 0.5261(4) 0.1158(7) 0.1100(4) 0.0424(10) Uani 0.70(2) 1 d PD A 1
C24A C 0.4736(3) 0.1175(7) 0.0372(4) 0.0377(12) Uani 0.70(2) 1 d PD A 1
C25A C 0.4698(4) 0.2055(9) -0.0077(3) 0.0446(18) Uani 0.70(2) 1 d PD A 1
H25A H 0.4342 0.2068 -0.0572 0.053 Uiso 0.70(2) 1 calc PR A 1
C26A C 0.5141(5) 0.2901(7) 0.0153(4) 0.0569(18) Uani 0.70(2) 1 d PD A 1
H26A H 0.5095 0.3489 -0.0176 0.068 Uiso 0.70(2) 1 calc PR A 1
C27A C 0.5337(7) 0.0236(8) 0.1618(6) 0.093(3) Uani 0.70(2) 1 d PD A 1
H27A H 0.5336 -0.0507 0.1409 0.139 Uiso 0.70(2) 1 calc PR A 1
H27B H 0.4980 0.0270 0.1697 0.139 Uiso 0.70(2) 1 calc PR A 1
H27C H 0.5746 0.0339 0.2088 0.139 Uiso 0.70(2) 1 calc PR A 1
C28A C 0.4243(4) 0.0250(8) 0.0081(7) 0.070(3) Uani 0.70(2) 1 d PD A 1
H28A H 0.4099 0.0124 0.0421 0.105 Uiso 0.70(2) 1 calc PR A 1
H28B H 0.4432 -0.0454 0.0032 0.105 Uiso 0.70(2) 1 calc PR A 1
H28C H 0.3874 0.0473 -0.0401 0.105 Uiso 0.70(2) 1 calc PR A 1
C21B C 0.5539(10) 0.2882(17) 0.0665(13) 0.0617(16) Uani 0.30(2) 1 d PGD A 2
H21B H 0.5786 0.3533 0.0705 0.074 Uiso 0.30(2) 1 calc PR A 2
C22B C 0.5762(8) 0.214(2) 0.1257(10) 0.0559(14) Uani 0.30(2) 1 d PGD A 2
H22B H 0.6162 0.2285 0.1701 0.067 Uiso 0.30(2) 1 calc PR A 2
C23B C 0.5400(9) 0.1190(18) 0.1199(8) 0.0424(10) Uani 0.30(2) 1 d PGD A 2
C24B C 0.4815(7) 0.0980(12) 0.0549(10) 0.0377(12) Uani 0.30(2) 1 d PGD A 2
C25B C 0.4592(6) 0.1721(15) -0.0043(7) 0.0446(18) Uani 0.30(2) 1 d PGD A 2
H25B H 0.4192 0.1578 -0.0487 0.053 Uiso 0.30(2) 1 calc PR A 2
C26B C 0.4954(10) 0.2672(14) 0.0015(10) 0.0569(18) Uani 0.30(2) 1 d PGD A 2
H26B H 0.4801 0.3179 -0.0390 0.068 Uiso 0.30(2) 1 calc PR A 2
C27B C 0.5632(12) 0.036(2) 0.1816(11) 0.080(7) Uani 0.30(2) 1 d PD A 2
H27D H 0.5675 -0.0395 0.1653 0.120 Uiso 0.30(2) 1 calc PR A 2
H27E H 0.5322 0.0324 0.1970 0.120 Uiso 0.30(2) 1 calc PR A 2
H27F H 0.6051 0.0610 0.2232 0.120 Uiso 0.30(2) 1 calc PR A 2
C28B C 0.4411(12) -0.0043(14) 0.0445(17) 0.076(7) Uani 0.30(2) 1 d PD A 2
H28D H 0.4371 -0.0128 0.0873 0.115 Uiso 0.30(2) 1 calc PR A 2
H28E H 0.4615 -0.0725 0.0395 0.115 Uiso 0.30(2) 1 calc PR A 2
H28F H 0.3982 0.0054 0.0001 0.115 Uiso 0.30(2) 1 calc PR A 2
F1 F 0.76640(7) 0.65748(16) 0.25263(8) 0.0595(4) Uani 1 1 d . . .
F2 F 0.65039(7) 0.76409(13) 0.18665(8) 0.0546(4) Uani 1 1 d . . .
F3 F 0.54856(6) 0.65933(11) 0.17409(7) 0.0392(3) Uani 1 1 d . . .
F4 F 0.43028(6) 0.20046(12) 0.19071(7) 0.0405(3) Uani 1 1 d . . .
F5 F 0.32737(7) 0.08258(12) 0.08864(9) 0.0495(4) Uani 1 1 d . . .
F6 F 0.26241(6) 0.14906(14) -0.05321(8) 0.0517(4) Uani 1 1 d . . .
F7 F 0.29818(7) 0.34191(14) -0.09296(7) 0.0513(4) Uani 1 1 d . . .
F8 F 0.39941(7) 0.46302(11) 0.00794(7) 0.0420(3) Uani 1 1 d . . .
F9 F 0.67680(7) 0.33467(12) 0.29210(8) 0.0460(3) Uani 1 1 d . . .
F10 F 0.77963(6) 0.44521(15) 0.30753(8) 0.0557(4) Uani 1 1 d . . .
H21A H 0.594(2) 0.336(4) 0.098(3) 0.067 Uiso 0.70(2) 1 d P A 1
H13 H 0.4186(12) 0.626(2) 0.0928(14) 0.049(7) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C7 Ag1 C1 137.84(7) 2_655 .
C7 Ag1 C13 108.11(7) 2_655 .
C1 Ag1 C13 100.86(7) . .
C7 Ag1 Ag2 145.29(5) 2_655 .
C1 Ag1 Ag2 49.75(5) . .
C13 Ag1 Ag2 100.66(5) . .
C7 Ag1 Ag2 49.94(5) 2_655 2_655
C1 Ag1 Ag2 113.88(5) . 2_655
C13 Ag1 Ag2 144.15(5) . 2_655
Ag2 Ag1 Ag2 95.380(7) . 2_655
C7 Ag1 Ag1 95.15(5) 2_655 2_655
C1 Ag1 Ag1 101.95(5) . 2_655
C13 Ag1 Ag1 111.70(5) . 2_655
Ag2 Ag1 Ag1 55.490(6) . 2_655
Ag2 Ag1 Ag1 54.050(5) 2_655 2_655
C1 Ag2 C7 164.41(7) . .
C1 Ag2 Ag1 55.74(5) . .
C7 Ag2 Ag1 111.17(5) . .
C1 Ag2 Ag1 121.42(4) . 2_655
C7 Ag2 Ag1 52.54(5) . 2_655
Ag1 Ag2 Ag1 70.459(7) . 2_655
C2 C1 C6 114.00(18) . .
C2 C1 Ag2 122.21(14) . .
C6 C1 Ag2 117.72(14) . .
C2 C1 Ag1 104.41(12) . .
C6 C1 Ag1 115.97(14) . .
Ag2 C1 Ag1 74.50(6) . .
F4 C2 C3 116.19(19) . .
F4 C2 C1 119.59(18) . .
C3 C2 C1 124.22(19) . .
F5 C3 C4 119.4(2) . .
F5 C3 C2 121.8(2) . .
C4 C3 C2 118.8(2) . .
F6 C4 C5 120.2(2) . .
F6 C4 C3 119.6(2) . .
C5 C4 C3 120.2(2) . .
F7 C5 C4 120.3(2) . .
F7 C5 C6 121.1(2) . .
C4 C5 C6 118.55(19) . .
F8 C6 C5 116.17(18) . .
F8 C6 C1 119.61(18) . .
C5 C6 C1 124.2(2) . .
C12 C7 C8 114.59(18) . .
C12 C7 Ag2 114.87(14) . .
C8 C7 Ag2 122.21(15) . .
C12 C7 Ag1 114.39(13) . 2_655
C8 C7 Ag1 106.81(13) . 2_655
Ag2 C7 Ag1 77.52(6) . 2_655
F9 C8 C9 117.48(19) . .
F9 C8 C7 119.06(19) . .
C9 C8 C7 123.5(2) . .
F10 C9 C10 119.6(2) . .
F10 C9 C8 121.1(2) . .
C10 C9 C8 119.3(2) . .
F1 C10 C9 120.0(2) . .
F1 C10 C11 119.8(2) . .
C9 C10 C11 120.20(19) . .
F2 C11 C10 120.26(19) . .
F2 C11 C12 121.2(2) . .
C10 C11 C12 118.5(2) . .
F3 C12 C11 116.21(19) . .
F3 C12 C7 119.83(17) . .
C11 C12 C7 123.96(19) . .
C18 C13 C14 119.3(2) . .
C18 C13 Ag1 111.24(15) . .
C14 C13 Ag1 85.99(13) . .
C18 C13 H13 118.3(16) . .
C14 C13 H13 122.1(16) . .
Ag1 C13 H13 78.8(15) . .
C13 C14 C15 121.9(2) . .
C13 C14 H14 119.1 . .
C15 C14 H14 119.1 . .
C16 C15 C14 118.22(19) . .
C16 C15 C19 122.0(2) . .
C14 C15 C19 119.8(2) . .
C17 C16 C15 119.4(2) . .
C17 C16 C20 119.5(2) . .
C15 C16 C20 121.1(2) . .
C18 C17 C16 121.7(2) . .
C18 C17 H17 119.1 . .
C16 C17 H17 119.1 . .
C13 C18 C17 119.5(2) . .
C13 C18 H18 120.3 . .
C17 C18 H18 120.3 . .
C15 C19 H19A 109.5 . .
C15 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C15 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C16 C20 H20A 109.5 . .
C16 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C16 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C26A C21A C22A 119.4(4) . .
C26A C21A H21A 119(3) . .
C22A C21A H21A 122(3) . .
C21A C22A C23A 122.2(4) . .
C21A C22A H22A 118.9 . .
C23A C22A H22A 118.9 . .
C22A C23A C24A 117.8(3) . .
C22A C23A C27A 120.9(5) . .
C24A C23A C27A 121.4(5) . .
C25A C24A C23A 118.2(3) . .
C25A C24A C28A 120.8(5) . .
C23A C24A C28A 121.0(5) . .
C26A C25A C24A 123.3(3) . .
C26A C25A H25A 118.3 . .
C24A C25A H25A 118.3 . .
C25A C26A C21A 119.1(4) . .
C25A C26A H26A 120.4 . .
C21A C26A H26A 120.4 . .
C22B C21B C26B 120.0 . .
C22B C21B H21B 120.0 . .
C26B C21B H21B 120.0 . .
C22B C21B H21A 88(3) . .
C26B C21B H21A 152(3) . .
H21B C21B H21A 32.1 . .
C23B C22B C21B 120.0 . .
C23B C22B H22B 120.0 . .
C21B C22B H22B 120.0 . .
C24B C23B C22B 120.0 . .
C24B C23B C27B 118.6(9) . .
C22B C23B C27B 121.4(9) . .
C23B C24B C25B 120.0 . .
C23B C24B C28B 122.6(8) . .
C25B C24B C28B 117.4(8) . .
C24B C25B C26B 120.0 . .
C24B C25B H25B 120.0 . .
C26B C25B H25B 120.0 . .
C25B C26B C21B 120.0 . .
C25B C26B H26B 120.0 . .
C21B C26B H26B 120.0 . .
C23B C27B H27D 109.5 . .
C23B C27B H27E 109.5 . .
H27D C27B H27E 109.5 . .
C23B C27B H27F 109.5 . .
H27D C27B H27F 109.5 . .
H27E C27B H27F 109.5 . .
C24B C28B H28D 109.5 . .
C24B C28B H28E 109.5 . .
H28D C28B H28E 109.5 . .
C24B C28B H28F 109.5 . .
H28D C28B H28F 109.5 . .
H28E C28B H28F 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C7 2.2707(17) 2_655
Ag1 C1 2.3534(18) .
Ag1 C13 2.665(2) .
Ag1 Ag2 2.7439(2) .
Ag1 Ag2 2.7930(2) 2_655
Ag1 Ag1 3.1942(3) 2_655
Ag2 C1 2.1733(19) .
Ag2 C7 2.189(2) .
Ag2 Ag1 2.7930(2) 2_655
C1 C2 1.384(3) .
C1 C6 1.384(3) .
C2 F4 1.354(2) .
C2 C3 1.375(3) .
C3 F5 1.341(3) .
C3 C4 1.374(3) .
C4 F6 1.346(2) .
C4 C5 1.371(3) .
C5 F7 1.340(2) .
C5 C6 1.382(3) .
C6 F8 1.355(2) .
C7 C12 1.382(3) .
C7 C8 1.386(3) .
C7 Ag1 2.2707(17) 2_655
C8 F9 1.356(3) .
C8 C9 1.376(3) .
C9 F10 1.344(2) .
C9 C10 1.365(3) .
C10 F1 1.341(2) .
C10 C11 1.378(3) .
C11 F2 1.332(3) .
C11 C12 1.378(3) .
C12 F3 1.352(2) .
C13 C18 1.378(3) .
C13 C14 1.388(3) .
C13 H13 0.98(3) .
C14 C15 1.398(3) .
C14 H14 0.9500 .
C15 C16 1.395(3) .
C15 C19 1.501(3) .
C16 C17 1.387(3) .
C16 C20 1.511(3) .
C17 C18 1.383(3) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21A C26A 1.363(6) .
C21A C22A 1.376(6) .
C21A H21A 0.81(5) .
C22A C23A 1.395(5) .
C22A H22A 0.9500 .
C23A C24A 1.398(5) .
C23A C27A 1.491(6) .
C24A C25A 1.382(5) .
C24A C28A 1.492(5) .
C25A C26A 1.357(5) .
C25A H25A 0.9500 .
C26A H26A 0.9500 .
C27A H27A 0.9800 .
C27A H27B 0.9800 .
C27A H27C 0.9800 .
C28A H28A 0.9800 .
C28A H28B 0.9800 .
C28A H28C 0.9800 .
C21B C22B 1.3900 .
C21B C26B 1.3900 .
C21B H21B 0.9500 .
C21B H21A 1.01(5) .
C22B C23B 1.3900 .
C22B H22B 0.9500 .
C23B C24B 1.3900 .
C23B C27B 1.492(8) .
C24B C25B 1.3900 .
C24B C28B 1.496(8) .
C25B C26B 1.3900 .
C25B H25B 0.9500 .
C26B H26B 0.9500 .
C27B H27D 0.9800 .
C27B H27E 0.9800 .
C27B H27F 0.9800 .
C28B H28D 0.9800 .
C28B H28E 0.9800 .
C28B H28F 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C7 Ag1 Ag2 C1 118.92(11) 2_655 .
C13 Ag1 Ag2 C1 -95.26(8) . .
Ag2 Ag1 Ag2 C1 116.94(6) 2_655 .
Ag1 Ag1 Ag2 C1 155.65(6) 2_655 .
C7 Ag1 Ag2 C7 -70.68(6) 2_655 .
C1 Ag1 Ag2 C7 170.40(8) . .
C13 Ag1 Ag2 C7 75.14(8) . .
Ag2 Ag1 Ag2 C7 -72.66(6) 2_655 .
Ag1 Ag1 Ag2 C7 -33.95(5) 2_655 .
C7 Ag1 Ag2 Ag1 -36.73(9) 2_655 2_655
C1 Ag1 Ag2 Ag1 -155.65(6) . 2_655
C13 Ag1 Ag2 Ag1 109.09(5) . 2_655
Ag2 Ag1 Ag2 Ag1 -38.708(8) 2_655 2_655
C7 Ag2 C1 C2 -132.9(2) . .
Ag1 Ag2 C1 C2 -97.50(15) . .
Ag1 Ag2 C1 C2 -70.41(16) 2_655 .
C7 Ag2 C1 C6 76.2(3) . .
Ag1 Ag2 C1 C6 111.57(16) . .
Ag1 Ag2 C1 C6 138.66(13) 2_655 .
C7 Ag2 C1 Ag1 -35.4(3) . .
Ag1 Ag2 C1 Ag1 27.09(7) 2_655 .
C7 Ag1 C1 C2 -12.07(19) 2_655 .
C13 Ag1 C1 C2 -145.16(13) . .
Ag2 Ag1 C1 C2 119.99(15) . .
Ag2 Ag1 C1 C2 43.90(14) 2_655 .
Ag1 Ag1 C1 C2 99.66(13) 2_655 .
C7 Ag1 C1 C6 114.25(16) 2_655 .
C13 Ag1 C1 C6 -18.85(16) . .
Ag2 Ag1 C1 C6 -113.70(16) . .
Ag2 Ag1 C1 C6 170.21(13) 2_655 .
Ag1 Ag1 C1 C6 -134.02(14) 2_655 .
C7 Ag1 C1 Ag2 -132.05(9) 2_655 .
C13 Ag1 C1 Ag2 94.85(7) . .
Ag2 Ag1 C1 Ag2 -76.09(5) 2_655 .
Ag1 Ag1 C1 Ag2 -20.32(5) 2_655 .
C6 C1 C2 F4 178.85(16) . .
Ag2 C1 C2 F4 26.9(2) . .
Ag1 C1 C2 F4 -53.61(19) . .
C6 C1 C2 C3 -0.4(3) . .
Ag2 C1 C2 C3 -152.28(15) . .
Ag1 C1 C2 C3 127.17(17) . .
F4 C2 C3 F5 1.1(3) . .
C1 C2 C3 F5 -179.69(18) . .
F4 C2 C3 C4 -178.26(17) . .
C1 C2 C3 C4 1.0(3) . .
F5 C3 C4 F6 -1.1(3) . .
C2 C3 C4 F6 178.24(17) . .
F5 C3 C4 C5 179.66(18) . .
C2 C3 C4 C5 -1.0(3) . .
F6 C4 C5 F7 0.6(3) . .
C3 C4 C5 F7 179.84(18) . .
F6 C4 C5 C6 -178.79(17) . .
C3 C4 C5 C6 0.4(3) . .
F7 C5 C6 F8 -0.2(3) . .
C4 C5 C6 F8 179.14(17) . .
F7 C5 C6 C1 -179.19(18) . .
C4 C5 C6 C1 0.2(3) . .
C2 C1 C6 F8 -179.15(16) . .
Ag2 C1 C6 F8 -25.9(2) . .
Ag1 C1 C6 F8 59.5(2) . .
C2 C1 C6 C5 -0.2(3) . .
Ag2 C1 C6 C5 153.02(15) . .
Ag1 C1 C6 C5 -121.55(18) . .
C1 Ag2 C7 C12 -38.9(3) . .
Ag1 Ag2 C7 C12 -69.78(14) . .
Ag1 Ag2 C7 C12 -111.32(15) 2_655 .
C1 Ag2 C7 C8 174.6(2) . .
Ag1 Ag2 C7 C8 143.70(14) . .
Ag1 Ag2 C7 C8 102.16(16) 2_655 .
C1 Ag2 C7 Ag1 72.4(3) . 2_655
Ag1 Ag2 C7 Ag1 41.54(6) . 2_655
C12 C7 C8 F9 179.67(17) . .
Ag2 C7 C8 F9 -33.7(2) . .
Ag1 C7 C8 F9 51.9(2) 2_655 .
C12 C7 C8 C9 -0.2(3) . .
Ag2 C7 C8 C9 146.45(17) . .
Ag1 C7 C8 C9 -127.93(18) 2_655 .
F9 C8 C9 F10 -2.1(3) . .
C7 C8 C9 F10 177.76(18) . .
F9 C8 C9 C10 179.20(18) . .
C7 C8 C9 C10 -1.0(3) . .
F10 C9 C10 F1 0.9(3) . .
C8 C9 C10 F1 179.68(18) . .
F10 C9 C10 C11 -177.57(18) . .
C8 C9 C10 C11 1.2(3) . .
F1 C10 C11 F2 0.2(3) . .
C9 C10 C11 F2 178.69(19) . .
F1 C10 C11 C12 -178.78(18) . .
C9 C10 C11 C12 -0.3(3) . .
F2 C11 C12 F3 0.3(3) . .
C10 C11 C12 F3 179.25(18) . .
F2 C11 C12 C7 -179.89(18) . .
C10 C11 C12 C7 -0.9(3) . .
C8 C7 C12 F3 -179.07(17) . .
Ag2 C7 C12 F3 31.8(2) . .
Ag1 C7 C12 F3 -55.2(2) 2_655 .
C8 C7 C12 C11 1.1(3) . .
Ag2 C7 C12 C11 -148.00(17) . .
Ag1 C7 C12 C11 124.94(18) 2_655 .
C7 Ag1 C13 C18 53.33(18) 2_655 .
C1 Ag1 C13 C18 -157.71(16) . .
Ag2 Ag1 C13 C18 -107.00(16) . .
Ag2 Ag1 C13 C18 8.1(2) 2_655 .
Ag1 Ag1 C13 C18 -50.06(17) 2_655 .
C7 Ag1 C13 C14 -66.56(14) 2_655 .
C1 Ag1 C13 C14 82.40(14) . .
Ag2 Ag1 C13 C14 133.11(12) . .
Ag2 Ag1 C13 C14 -111.83(13) 2_655 .
Ag1 Ag1 C13 C14 -169.95(11) 2_655 .
C18 C13 C14 C15 1.8(3) . .
Ag1 C13 C14 C15 113.92(18) . .
C13 C14 C15 C16 0.9(3) . .
C13 C14 C15 C19 179.33(19) . .
C14 C15 C16 C17 -2.8(3) . .
C19 C15 C16 C17 178.9(2) . .
C14 C15 C16 C20 175.8(2) . .
C19 C15 C16 C20 -2.6(3) . .
C15 C16 C17 C18 2.0(3) . .
C20 C16 C17 C18 -176.6(2) . .
C14 C13 C18 C17 -2.6(3) . .
Ag1 C13 C18 C17 -100.1(2) . .
C16 C17 C18 C13 0.7(3) . .
C26A C21A C22A C23A 0.6(5) . .
C21A C22A C23A C24A -0.8(5) . .
C21A C22A C23A C27A 179.6(8) . .
C22A C23A C24A C25A 0.5(4) . .
C27A C23A C24A C25A -179.9(8) . .
C22A C23A C24A C28A 178.7(7) . .
C27A C23A C24A C28A -1.7(9) . .
C23A C24A C25A C26A -0.1(5) . .
C28A C24A C25A C26A -178.3(7) . .
C24A C25A C26A C21A -0.1(5) . .
C22A C21A C26A C25A -0.2(6) . .
C26B C21B C22B C23B 0.0 . .
C21B C22B C23B C24B 0.0 . .
C21B C22B C23B C27B 179(2) . .
C22B C23B C24B C25B 0.0 . .
C27B C23B C24B C25B -179(2) . .
C22B C23B C24B C28B 178.5(19) . .
C27B C23B C24B C28B 0(2) . .
C23B C24B C25B C26B 0.0 . .
C28B C24B C25B C26B -178.6(18) . .
C24B C25B C26B C21B 0.0 . .
C22B C21B C26B C25B 0.0 . .
