#------------------------------------------------------------------------------
#$Date: 2016-03-22 11:04:00 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178883 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/12/4111216.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4111216
loop_
_publ_author_name
'Christopher G. Oliveri'
'Nathan C. Gianneschi'
'SonBinh T. Nguyen'
'Chad A. Mirkin'
'Charlotte L. Stern'
'Zdzislaw Wawrzak'
'Maren Pink'
_publ_contact_author_address
;Northwestern University
Department of Chemistry and the 
International Institute for Nanotechnology
2145 Sheridan Road 
Evanston, IL  60208-3113
;
_publ_contact_author_email       coliveri@chem.northwestern.edu
_publ_contact_author_fax         '847-467-4998 '
_publ_contact_author_name        'Christopher Oliveri'
_publ_contact_author_phone       '847-467-4998 '
_publ_section_title
;
 Supramolecular Allosteric Cofacial Porphyrin Complexes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              16286
_journal_page_last               16296
_journal_paper_doi               10.1021/ja0661010
_journal_volume                  128
_journal_year                    2006
_chemical_formula_sum            'C87 H68 Cl2 Cu N7 O2 P2 Zn'
_chemical_formula_weight         1505.23
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.501(6)
_cell_angle_beta                 96.354(14)
_cell_angle_gamma                100.273(10)
_cell_formula_units_Z            2
_cell_length_a                   13.127(9)
_cell_length_b                   16.349(8)
_cell_length_c                   22.544(12)
_cell_measurement_temperature    293(2)
_cell_volume                     4675(5)
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.943
_diffrn_measured_fraction_theta_max 0.943
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71000
_diffrn_reflns_av_R_equivalents  0.0523
_diffrn_reflns_av_sigmaI/netI    0.4770
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            21424
_diffrn_reflns_theta_full        21.93
_diffrn_reflns_theta_max         21.93
_diffrn_reflns_theta_min         2.06
_exptl_absorpt_coefficient_mu    0.619
_exptl_crystal_density_diffrn    1.069
_exptl_crystal_F_000             1556
_refine_diff_density_max         0.666
_refine_diff_density_min         -0.488
_refine_diff_density_rms         0.084
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.974
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     909
_refine_ls_number_reflns         10756
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.974
_refine_ls_R_factor_all          0.1563
_refine_ls_R_factor_gt           0.1089
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1098P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2624
_refine_ls_wR_factor_ref         0.2787
_reflns_number_gt                3878
_reflns_number_total             10756
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja0661010si20060822_031521.cif
_cod_data_source_block           cuznet1
_cod_original_sg_symbol_H-M      'P -1 '
_cod_database_code               4111216
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.75349(9) 0.46689(5) -0.08613(5) 0.0610(4) Uani 1 1 d .
Cu1 Cu 0.70955(11) 0.80604(9) 0.41264(7) 0.0905(5) Uani 1 1 d .
Cl1 Cl 0.8052(3) 0.9211(2) 0.48044(17) 0.1239(13) Uani 1 1 d .
Cl2 Cl 0.8045(2) 0.79976(17) 0.32795(13) 0.0878(8) Uani 1 1 d .
P1 P 0.5437(3) 0.82206(18) 0.38548(14) 0.0869(9) Uani 1 1 d .
P2 P 0.7282(3) 0.68847(19) 0.45113(15) 0.0900(9) Uani 1 1 d .
O1 O 0.9610(7) 0.3140(5) -0.4521(3) 0.097(2) Uani 1 1 d .
O2 O 0.4774(6) 0.6331(4) 0.2503(4) 0.092(2) Uani 1 1 d .
N1 N 0.6710(6) 0.4020(4) -0.0297(3) 0.062(2) Uani 1 1 d .
N2 N 0.7157(6) 0.5746(4) -0.0446(4) 0.066(2) Uani 1 1 d .
N3 N 0.7917(6) 0.5276(4) -0.1583(4) 0.065(2) Uani 1 1 d .
N4 N 0.7470(5) 0.3555(4) -0.1416(3) 0.0555(18) Uani 1 1 d .
N5 N 0.9077(5) 0.4870(4) -0.0321(3) 0.0580(19) Uani 1 1 d .
N6 N 0.9858(13) 0.9753(9) 0.6291(8) 0.168(3) Uani 1 1 d .
N7 N 0.8647(15) 1.0505(9) 0.6878(8) 0.168(3) Uani 1 1 d .
C1 C 0.6552(7) 0.3164(5) -0.0311(4) 0.063(2) Uani 1 1 d .
C2 C 0.6196(8) 0.2963(5) 0.0253(5) 0.071(3) Uani 1 1 d .
H2 H 0.6002 0.2426 0.0349 0.086 Uiso 1 1 calc R
C3 C 0.6196(9) 0.3692(6) 0.0609(5) 0.082(3) Uani 1 1 d .
H3 H 0.6040 0.3760 0.1003 0.098 Uiso 1 1 calc R
C4 C 0.6489(7) 0.4346(4) 0.0251(5) 0.062(3) Uani 1 1 d .
C5 C 0.6458(6) 0.5210(5) 0.0431(5) 0.062(2) Uani 1 1 d .
C6 C 0.6682(8) 0.5828(6) 0.0063(5) 0.076(3) Uani 1 1 d .
C7 C 0.6461(8) 0.6663(6) 0.0179(5) 0.073(3) Uani 1 1 d .
H7 H 0.6162 0.6877 0.0506 0.087 Uiso 1 1 calc R
C8 C 0.6769(8) 0.7082(6) -0.0276(5) 0.079(3) Uani 1 1 d .
H8 H 0.6700 0.7627 -0.0325 0.095 Uiso 1 1 calc R
C9 C 0.7231(8) 0.6503(5) -0.0674(5) 0.068(3) Uani 1 1 d .
C10 C 0.7676(8) 0.6689(5) -0.1169(5) 0.076(3) Uani 1 1 d .
C11 C 0.8061(7) 0.6154(5) -0.1594(5) 0.067(3) Uani 1 1 d .
C12 C 0.8527(8) 0.6348(6) -0.2100(5) 0.077(3) Uani 1 1 d .
H12 H 0.8676 0.6878 -0.2215 0.092 Uiso 1 1 calc R
C13 C 0.8718(8) 0.5637(6) -0.2387(5) 0.076(3) Uani 1 1 d .
H13 H 0.9056 0.5590 -0.2728 0.092 Uiso 1 1 calc R
C14 C 0.8314(7) 0.4961(6) -0.2082(5) 0.062(2) Uani 1 1 d .
C15 C 0.8258(8) 0.4093(5) -0.2262(4) 0.064(3) Uani 1 1 d .
C16 C 0.7857(8) 0.3463(5) -0.1973(4) 0.067(3) Uani 1 1 d .
C17 C 0.7676(8) 0.2553(5) -0.2208(4) 0.065(2) Uani 1 1 d .
H17 H 0.7856 0.2314 -0.2569 0.078 Uiso 1 1 calc R
C18 C 0.7222(9) 0.2146(5) -0.1822(4) 0.072(3) Uani 1 1 d .
H18 H 0.7009 0.1566 -0.1859 0.087 Uiso 1 1 calc R
C19 C 0.7103(7) 0.2782(5) -0.1306(4) 0.057(2) Uani 1 1 d .
C20 C 0.6644(7) 0.2568(4) -0.0799(4) 0.056(2) Uani 1 1 d .
C21 C 0.7736(9) 0.7599(6) -0.1338(5) 0.080(3) Uani 1 1 d .
C22 C 0.8579(11) 0.8189(6) -0.1045(7) 0.112(5) Uani 1 1 d .
C23 C 0.8582(11) 0.9038(6) -0.1152(8) 0.113(5) Uani 1 1 d .
H23 H 0.9101 0.9480 -0.0949 0.136 Uiso 1 1 calc R
C24 C 0.7794(11) 0.9180(6) -0.1564(6) 0.088(4) Uani 1 1 d .
C25 C 0.6990(10) 0.8600(6) -0.1815(6) 0.086(3) Uani 1 1 d .
H25 H 0.6466 0.8731 -0.2077 0.103 Uiso 1 1 calc R
C26 C 0.6924(8) 0.7791(6) -0.1688(5) 0.074(3) Uani 1 1 d .
C27 C 0.9447(13) 0.7956(11) -0.0619(11) 0.205(11) Uani 1 1 d .
H27A H 0.9174 0.7452 -0.0467 0.307 Uiso 1 1 calc R
H27B H 0.9692 0.8406 -0.0288 0.307 Uiso 1 1 calc R
H27C H 1.0016 0.7866 -0.0837 0.307 Uiso 1 1 calc R
C28 C 0.7883(12) 1.0129(6) -0.1627(7) 0.123(5) Uani 1 1 d .
H28A H 0.8035 1.0212 -0.2024 0.184 Uiso 1 1 calc R
H28B H 0.8434 1.0461 -0.1331 0.184 Uiso 1 1 calc R
H28C H 0.7234 1.0297 -0.1564 0.184 Uiso 1 1 calc R
C29 C 0.6010(10) 0.7104(8) -0.1950(6) 0.106(4) Uani 1 1 d .
H29A H 0.6256 0.6607 -0.2097 0.159 Uiso 1 1 calc R
H29B H 0.5611 0.7279 -0.2276 0.159 Uiso 1 1 calc R
H29C H 0.5577 0.6985 -0.1643 0.159 Uiso 1 1 calc R
C30 C 0.8691(8) 0.3864(6) -0.2865(5) 0.069(3) Uani 1 1 d .
C31 C 0.8167(9) 0.4016(6) -0.3410(5) 0.082(3) Uani 1 1 d .
H31 H 0.7576 0.4255 -0.3408 0.099 Uiso 1 1 calc R
C32 C 0.8537(10) 0.3810(7) -0.3939(5) 0.091(4) Uani 1 1 d .
H32 H 0.8251 0.3972 -0.4291 0.109 Uiso 1 1 calc R
C33 C 0.9296(10) 0.3382(7) -0.3956(5) 0.085(3) Uani 1 1 d .
C34 C 0.9817(9) 0.3193(6) -0.3436(6) 0.082(3) Uani 1 1 d .
H34 H 1.0366 0.2905 -0.3459 0.099 Uiso 1 1 calc R
C35 C 0.9498(7) 0.3445(5) -0.2864(5) 0.061(2) Uani 1 1 d .
H35 H 0.9829 0.3328 -0.2507 0.074 Uiso 1 1 calc R
C36 C 1.0554(11) 0.2840(8) -0.4597(7) 0.112(4) Uani 1 1 d .
H36A H 1.0543 0.2625 -0.5020 0.134 Uiso 1 1 calc R
H36B H 1.0591 0.2380 -0.4369 0.134 Uiso 1 1 calc R
C37 C 0.6305(8) 0.1612(5) -0.0742(5) 0.065(3) Uani 1 1 d .
C38 C 0.5358(8) 0.1218(5) -0.1032(5) 0.069(3) Uani 1 1 d .
C39 C 0.5022(9) 0.0370(6) -0.0990(5) 0.074(3) Uani 1 1 d .
H39 H 0.4364 0.0091 -0.1181 0.089 Uiso 1 1 calc R
C40 C 0.5632(9) -0.0045(6) -0.0680(5) 0.073(3) Uani 1 1 d .
C41 C 0.6561(10) 0.0365(6) -0.0404(6) 0.088(3) Uani 1 1 d .
H41 H 0.6972 0.0073 -0.0181 0.106 Uiso 1 1 calc R
C42 C 0.6962(8) 0.1214(6) -0.0426(5) 0.068(3) Uani 1 1 d .
C43 C 0.4607(8) 0.1639(5) -0.1409(5) 0.084(3) Uani 1 1 d .
H43A H 0.3936 0.1550 -0.1271 0.126 Uiso 1 1 calc R
H43B H 0.4535 0.1397 -0.1827 0.126 Uiso 1 1 calc R
H43C H 0.4883 0.2231 -0.1364 0.126 Uiso 1 1 calc R
C44 C 0.5269(10) -0.0979(5) -0.0670(6) 0.097(4) Uani 1 1 d .
H44A H 0.5458 -0.1297 -0.1016 0.145 Uiso 1 1 calc R
H44B H 0.4524 -0.1103 -0.0680 0.145 Uiso 1 1 calc R
H44C H 0.5597 -0.1128 -0.0309 0.145 Uiso 1 1 calc R
C45 C 0.8001(11) 0.1632(6) -0.0088(7) 0.108(4) Uani 1 1 d .
H45A H 0.8356 0.2013 -0.0323 0.162 Uiso 1 1 calc R
H45B H 0.8409 0.1215 -0.0012 0.162 Uiso 1 1 calc R
H45C H 0.7910 0.1939 0.0289 0.162 Uiso 1 1 calc R
C46 C 0.9310(15) 0.5706(9) 0.0225(10) 0.074(7) Uani 0.50 1 d P
C47 C 0.9708(13) 0.561(2) -0.0431(10) 0.087(8) Uani 0.50 1 d P
C48 C 0.9904(15) 0.5056(16) -0.0692(10) 0.079(8) Uani 0.50 1 d P
C49 C 0.9720(18) 0.4219(10) -0.0544(10) 0.071(6) Uani 0.50 1 d P
C50 C 0.913(2) 0.4133(12) 0.0000(12) 0.098(8) Uani 0.50 1 d P
C51 C 0.884(2) 0.461(3) 0.0320(11) 0.157(15) Uani 0.50 1 d P
C52 C 0.6115(6) 0.5455(5) 0.1021(4) 0.058(2) Uani 1 1 d .
C53 C 0.5135(9) 0.5044(6) 0.1137(5) 0.082(3) Uani 1 1 d .
H53 H 0.4766 0.4573 0.0874 0.099 Uiso 1 1 calc R
C54 C 0.4712(9) 0.5348(7) 0.1653(5) 0.085(3) Uani 1 1 d .
H54 H 0.4064 0.5088 0.1735 0.102 Uiso 1 1 calc R
C55 C 0.5299(10) 0.6047(7) 0.2030(5) 0.082(3) Uani 1 1 d .
C56 C 0.6240(9) 0.6437(6) 0.1923(5) 0.084(3) Uani 1 1 d .
H56 H 0.6620 0.6903 0.2188 0.101 Uiso 1 1 calc R
C57 C 0.6639(11) 0.6129(7) 0.1402(6) 0.100(4) Uani 1 1 d .
H57 H 0.7283 0.6401 0.1323 0.120 Uiso 1 1 calc R
C58 C 0.5328(10) 0.7071(7) 0.2842(5) 0.094(4) Uani 1 1 d .
H58A H 0.5422 0.7512 0.2593 0.113 Uiso 1 1 calc R
H58B H 0.6012 0.6995 0.3010 0.113 Uiso 1 1 calc R
C59 C 0.4668(9) 0.7322(8) 0.3377(5) 0.097(4) Uani 1 1 d .
H59A H 0.4518 0.6860 0.3604 0.116 Uiso 1 1 calc R
H59B H 0.4010 0.7449 0.3211 0.116 Uiso 1 1 calc R
C60 C 0.5330(10) 0.9044(7) 0.3393(5) 0.084(3) Uani 1 1 d .
C61 C 0.6146(12) 0.9496(8) 0.3238(7) 0.121(5) Uani 1 1 d .
H61 H 0.6784 0.9367 0.3377 0.145 Uiso 1 1 calc R
C62 C 0.6207(15) 1.0187(11) 0.2872(9) 0.140(6) Uani 1 1 d .
H62 H 0.6824 1.0467 0.2765 0.168 Uiso 1 1 calc R
C63 C 0.529(2) 1.0354(12) 0.2717(7) 0.137(6) Uani 1 1 d .
H63 H 0.5239 1.0803 0.2510 0.165 Uiso 1 1 calc R
C64 C 0.4422(15) 0.9889(10) 0.2853(8) 0.119(5) Uani 1 1 d .
H64 H 0.3790 1.0007 0.2692 0.143 Uiso 1 1 calc R
C65 C 0.4359(11) 0.9260(9) 0.3201(7) 0.113(5) Uani 1 1 d .
H65 H 0.3730 0.8996 0.3304 0.135 Uiso 1 1 calc R
C66 C 0.4704(10) 0.8425(8) 0.4452(6) 0.106(4) Uani 1 1 d .
C67 C 0.5128(9) 0.8961(9) 0.4975(6) 0.106(4) Uani 1 1 d .
H67 H 0.5827 0.9224 0.5018 0.128 Uiso 1 1 calc R
C68 C 0.4532(13) 0.9129(8) 0.5456(6) 0.110(4) Uani 1 1 d .
H68 H 0.4852 0.9481 0.5810 0.132 Uiso 1 1 calc R
C69 C 0.3536(13) 0.8787(8) 0.5398(8) 0.122(5) Uani 1 1 d .
H69 H 0.3149 0.8904 0.5709 0.147 Uiso 1 1 calc R
C70 C 0.3051(14) 0.8242(12) 0.4864(8) 0.173(9) Uani 1 1 d .
H70 H 0.2346 0.7999 0.4825 0.207 Uiso 1 1 calc R
C71 C 0.3638(11) 0.8063(9) 0.4387(7) 0.126(5) Uani 1 1 d .
H71 H 0.3317 0.7709 0.4034 0.151 Uiso 1 1 calc R
C72 C 0.7310(10) 0.6989(8) 0.5339(6) 0.095(4) Uani 1 1 d .
C73 C 0.7948(13) 0.6603(8) 0.5707(7) 0.126(6) Uani 1 1 d .
H73 H 0.8317 0.6224 0.5529 0.151 Uiso 1 1 calc R
C74 C 0.8043(19) 0.6778(10) 0.6350(8) 0.182(10) Uani 1 1 d .
H74 H 0.8551 0.6596 0.6592 0.219 Uiso 1 1 calc R
C75 C 0.7369(15) 0.7221(11) 0.6597(7) 0.141(7) Uani 1 1 d .
H75 H 0.7356 0.7281 0.7012 0.169 Uiso 1 1 calc R
C76 C 0.6754(13) 0.7557(7) 0.6269(8) 0.130(7) Uani 1 1 d .
H76 H 0.6319 0.7869 0.6456 0.156 Uiso 1 1 calc R
C77 C 0.6703(10) 0.7467(7) 0.5586(6) 0.101(4) Uani 1 1 d .
H77A H 0.5986 0.7237 0.5407 0.122 Uiso 1 1 calc R
H77B H 0.6887 0.8024 0.5478 0.122 Uiso 1 1 calc R
C78 C 0.6166(11) 0.6007(9) 0.4185(7) 0.110(4) Uani 1 1 d .
C79 C 0.5398(10) 0.5799(11) 0.4499(7) 0.132(6) Uani 1 1 d .
H79 H 0.5443 0.6068 0.4894 0.158 Uiso 1 1 calc R
C80 C 0.4544(16) 0.5202(11) 0.4262(10) 0.173(8) Uani 1 1 d .
H80 H 0.3997 0.5046 0.4480 0.208 Uiso 1 1 calc R
C81 C 0.4548(15) 0.4800(10) 0.3602(10) 0.157(7) Uani 1 1 d .
H81A H 0.4375 0.4194 0.3584 0.188 Uiso 1 1 calc R
H81B H 0.3986 0.4959 0.3354 0.188 Uiso 1 1 calc R
C82 C 0.5420(16) 0.4979(11) 0.3345(11) 0.174(9) Uani 1 1 d .
H82 H 0.5502 0.4667 0.2984 0.208 Uiso 1 1 calc R
C83 C 0.6140(13) 0.5599(9) 0.3618(7) 0.122(5) Uani 1 1 d .
H83 H 0.6687 0.5782 0.3407 0.147 Uiso 1 1 calc R
C84 C 0.8468(11) 0.6465(7) 0.4385(7) 0.120(5) Uani 1 1 d .
H84A H 0.8503 0.5999 0.4607 0.145 Uiso 1 1 calc R
H84B H 0.8440 0.6258 0.3959 0.145 Uiso 1 1 calc R
C85 C 0.9528(17) 1.0541(11) 0.6003(9) 0.168(3) Uani 1 1 d .
C86 C 0.8615(17) 1.0873(12) 0.6397(10) 0.168(3) Uani 1 1 d .
C87 C 1.0481(17) 1.0091(12) 0.6869(10) 0.168(3) Uani 1 1 d .
C88 C 0.9613(18) 1.0514(11) 0.7255(10) 0.168(3) Uani 1 1 d .
C89 C 0.8804(17) 0.9057(11) 0.6289(9) 0.168(3) Uani 1 1 d .
C90 C 0.8181(17) 0.9420(11) 0.6742(9) 0.168(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Zn1 N2 88.3(3) . .
N1 Zn1 N4 89.2(3) . .
N2 Zn1 N4 162.7(3) . .
N1 Zn1 N3 162.3(3) . .
N2 Zn1 N3 89.8(3) . .
N4 Zn1 N3 87.4(3) . .
N1 Zn1 N5 97.3(3) . .
N2 Zn1 N5 94.5(3) . .
N4 Zn1 N5 102.8(3) . .
N3 Zn1 N5 100.3(3) . .
P2 Cu1 P1 116.59(13) . .
P2 Cu1 Cl1 108.06(16) . .
P1 Cu1 Cl1 111.71(14) . .
P2 Cu1 Cl2 103.51(12) . .
P1 Cu1 Cl2 111.51(13) . .
Cl1 Cu1 Cl2 104.51(12) . .
C66 P1 C59 105.1(5) . .
C66 P1 C60 105.4(6) . .
C59 P1 C60 101.7(6) . .
C66 P1 Cu1 116.3(5) . .
C59 P1 Cu1 112.5(4) . .
C60 P1 Cu1 114.5(4) . .
C84 P2 C72 103.2(7) . .
C84 P2 C78 105.2(6) . .
C72 P2 C78 106.0(6) . .
C84 P2 Cu1 116.9(4) . .
C72 P2 Cu1 114.1(4) . .
C78 P2 Cu1 110.4(4) . .
C33 O1 C36 124.3(10) . .
C58 O2 C55 111.9(9) . .
C4 N1 C1 106.2(7) . .
C4 N1 Zn1 126.1(5) . .
C1 N1 Zn1 125.2(6) . .
C6 N2 C9 107.5(7) . .
C6 N2 Zn1 126.7(6) . .
C9 N2 Zn1 125.4(6) . .
C14 N3 C11 104.8(7) . .
C14 N3 Zn1 127.4(5) . .
C11 N3 Zn1 126.3(6) . .
C19 N4 C16 106.9(6) . .
C19 N4 Zn1 126.9(6) . .
C16 N4 Zn1 126.1(5) . .
C47 N5 C48 45.4(13) . .
C47 N5 C50 141.2(15) . .
C48 N5 C50 114.6(17) . .
C47 N5 C49 100.2(14) . .
C48 N5 C49 57.2(13) . .
C50 N5 C49 60.5(14) . .
C47 N5 C51 128.0(19) . .
C48 N5 C51 143.7(15) . .
C50 N5 C51 42.7(16) . .
C49 N5 C51 101.8(18) . .
C47 N5 C46 62.6(12) . .
C48 N5 C46 103.8(10) . .
C50 N5 C46 105.2(13) . .
C49 N5 C46 134.3(11) . .
C51 N5 C46 68.3(18) . .
C47 N5 Zn1 109.8(9) . .
C48 N5 Zn1 110.8(10) . .
C50 N5 Zn1 108.7(11) . .
C49 N5 Zn1 112.1(8) . .
C51 N5 Zn1 104.4(11) . .
C46 N5 Zn1 113.6(9) . .
C87 N6 C85 107.0(14) . .
C87 N6 C89 117.2(16) . .
C85 N6 C89 108.3(15) . .
C86 N7 C88 122.4(19) . .
C86 N7 C90 114.8(16) . .
C88 N7 C90 98.2(16) . .
N1 C1 C20 126.2(8) . .
N1 C1 C2 108.9(7) . .
C20 C1 C2 124.8(7) . .
C3 C2 C1 108.0(8) . .
C3 C2 H2 126.0 . .
C1 C2 H2 126.0 . .
C2 C3 C4 105.5(9) . .
C2 C3 H3 127.2 . .
C4 C3 H3 127.2 . .
N1 C4 C5 124.6(8) . .
N1 C4 C3 111.3(7) . .
C5 C4 C3 123.9(8) . .
C6 C5 C4 123.3(9) . .
C6 C5 C52 118.4(8) . .
C4 C5 C52 118.2(8) . .
N2 C6 C5 125.9(8) . .
N2 C6 C7 109.8(9) . .
C5 C6 C7 124.2(9) . .
C8 C7 C6 107.8(9) . .
C8 C7 H7 126.1 . .
C6 C7 H7 126.1 . .
C7 C8 C9 106.5(9) . .
C7 C8 H8 126.7 . .
C9 C8 H8 126.7 . .
C10 C9 N2 126.2(8) . .
C10 C9 C8 125.5(9) . .
N2 C9 C8 108.2(8) . .
C9 C10 C11 128.6(8) . .
C9 C10 C21 118.8(8) . .
C11 C10 C21 112.4(9) . .
C12 C11 C10 128.5(8) . .
C12 C11 N3 109.8(8) . .
C10 C11 N3 121.4(8) . .
C13 C12 C11 107.6(8) . .
C13 C12 H12 126.2 . .
C11 C12 H12 126.2 . .
C12 C13 C14 108.4(9) . .
C12 C13 H13 125.8 . .
C14 C13 H13 125.8 . .
N3 C14 C15 122.9(8) . .
N3 C14 C13 109.2(8) . .
C15 C14 C13 127.7(9) . .
C16 C15 C14 126.8(8) . .
C16 C15 C30 118.4(7) . .
C14 C15 C30 114.8(7) . .
C15 C16 N4 126.0(8) . .
C15 C16 C17 126.0(9) . .
N4 C16 C17 107.8(7) . .
C18 C17 C16 108.1(8) . .
C18 C17 H17 126.0 . .
C16 C17 H17 126.0 . .
C17 C18 C19 107.5(7) . .
C17 C18 H18 126.3 . .
C19 C18 H18 126.3 . .
N4 C19 C20 126.9(7) . .
N4 C19 C18 109.6(7) . .
C20 C19 C18 123.4(7) . .
C1 C20 C19 123.3(7) . .
C1 C20 C37 117.5(7) . .
C19 C20 C37 119.0(7) . .
C26 C21 C22 123.4(9) . .
C26 C21 C10 120.6(10) . .
C22 C21 C10 115.4(11) . .
C21 C22 C23 115.5(13) . .
C21 C22 C27 121.9(10) . .
C23 C22 C27 122.6(12) . .
C24 C23 C22 118.4(12) . .
C24 C23 H23 120.8 . .
C22 C23 H23 120.8 . .
C25 C24 C23 123.4(11) . .
C25 C24 C28 123.2(13) . .
C23 C24 C28 112.9(12) . .
C24 C25 C26 119.5(13) . .
C24 C25 H25 120.2 . .
C26 C25 H25 120.2 . .
C21 C26 C25 119.2(10) . .
C21 C26 C29 118.7(9) . .
C25 C26 C29 122.0(11) . .
C22 C27 H27A 109.5 . .
C22 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C22 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C24 C28 H28A 109.5 . .
C24 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C24 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C26 C29 H29A 109.5 . .
C26 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C26 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C35 C30 C31 121.3(9) . .
C35 C30 C15 119.2(10) . .
C31 C30 C15 119.2(9) . .
C32 C31 C30 119.4(10) . .
C32 C31 H31 120.3 . .
C30 C31 H31 120.3 . .
C33 C32 C31 120.5(11) . .
C33 C32 H32 119.8 . .
C31 C32 H32 119.8 . .
C32 C33 C34 122.1(10) . .
C32 C33 O1 118.3(12) . .
C34 C33 O1 119.5(11) . .
C33 C34 C35 119.2(10) . .
C33 C34 H34 120.4 . .
C35 C34 H34 120.4 . .
C30 C35 C34 117.1(10) . .
C30 C35 H35 121.4 . .
C34 C35 H35 121.4 . .
O1 C36 C84 112.1(10) . 2_765
O1 C36 H36A 109.2 . .
C84 C36 H36A 109.2 2_765 .
O1 C36 H36B 109.2 . .
C84 C36 H36B 109.2 2_765 .
H36A C36 H36B 107.9 . .
C38 C37 C42 123.0(8) . .
C38 C37 C20 116.4(9) . .
C42 C37 C20 120.6(8) . .
C37 C38 C39 118.3(10) . .
C37 C38 C43 124.5(8) . .
C39 C38 C43 117.1(10) . .
C40 C39 C38 120.9(10) . .
C40 C39 H39 119.5 . .
C38 C39 H39 119.5 . .
C41 C40 C39 118.8(10) . .
C41 C40 C44 121.4(12) . .
C39 C40 C44 119.7(11) . .
C40 C41 C42 124.0(12) . .
C40 C41 H41 118.0 . .
C42 C41 H41 118.0 . .
C37 C42 C41 114.9(10) . .
C37 C42 C45 124.5(8) . .
C41 C42 C45 120.5(10) . .
C38 C43 H43A 109.5 . .
C38 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
C38 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
C40 C44 H44A 109.5 . .
C40 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C40 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C42 C45 H45A 109.5 . .
C42 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
C42 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
C49 C46 C47 95.0(14) 2_765 .
C49 C46 N5 109.9(14) 2_765 .
C47 C46 N5 50.7(12) . .
C49 C46 C51 95.7(18) 2_765 .
C47 C46 C51 103.2(17) . .
N5 C46 C51 54.2(10) . .
C48 C47 N5 69(2) . .
C48 C47 C46 129(3) . .
N5 C47 C46 66.7(9) . .
C48 C47 C50 93.3(19) . 2_765
N5 C47 C50 113.6(16) . 2_765
C46 C47 C50 81.3(16) . 2_765
C48 C47 C51 59.6(18) . 2_765
N5 C47 C51 104(2) . 2_765
C46 C47 C51 108.0(15) . 2_765
C50 C47 C51 34.6(12) 2_765 2_765
C47 C48 C49 126(2) . .
C47 C48 N5 65.2(14) . .
C49 C48 N5 64.4(14) . .
C47 C48 C51 87(2) . 2_765
C49 C48 C51 98(2) . 2_765
N5 C48 C51 117.1(17) . 2_765
C46 C49 C48 95.2(17) 2_765 .
C46 C49 C50 95.1(18) 2_765 .
C48 C49 C50 113.6(15) . .
C46 C49 N5 115.8(13) 2_765 .
C48 C49 N5 58.4(9) . .
C50 C49 N5 58.2(11) . .
C51 C50 N5 74(2) . .
C51 C50 C49 133(3) . .
N5 C50 C49 61.3(13) . .
C51 C50 C47 89(2) . 2_765
N5 C50 C47 104.5(17) . 2_765
C49 C50 C47 87.3(18) . 2_765
C50 C51 N5 63.1(17) . .
C50 C51 C48 89(2) . 2_765
N5 C51 C48 96(2) . 2_765
C50 C51 C46 113(3) . .
N5 C51 C46 57.5(15) . .
C48 C51 C46 71(2) 2_765 .
C50 C51 C47 56(2) . 2_765
N5 C51 C47 86.8(15) . 2_765
C48 C51 C47 33.5(11) 2_765 2_765
C46 C51 C47 91.9(19) . 2_765
C57 C52 C53 119.4(9) . .
C57 C52 C5 121.1(8) . .
C53 C52 C5 118.7(8) . .
C52 C53 C54 120.1(10) . .
C52 C53 H53 119.9 . .
C54 C53 H53 119.9 . .
C55 C54 C53 117.4(10) . .
C55 C54 H54 121.3 . .
C53 C54 H54 121.3 . .
C56 C55 C54 122.7(9) . .
C56 C55 O2 124.5(11) . .
C54 C55 O2 112.6(10) . .
C55 C56 C57 118.9(10) . .
C55 C56 H56 120.6 . .
C57 C56 H56 120.6 . .
C52 C57 C56 121.5(11) . .
C52 C57 H57 119.2 . .
C56 C57 H57 119.2 . .
O2 C58 C59 107.5(9) . .
O2 C58 H58A 110.2 . .
C59 C58 H58A 110.2 . .
O2 C58 H58B 110.2 . .
C59 C58 H58B 110.2 . .
H58A C58 H58B 108.5 . .
C58 C59 P1 107.4(8) . .
C58 C59 H59A 110.2 . .
P1 C59 H59A 110.2 . .
C58 C59 H59B 110.2 . .
P1 C59 H59B 110.2 . .
H59A C59 H59B 108.5 . .
C61 C60 C65 115.4(13) . .
C61 C60 P1 121.9(11) . .
C65 C60 P1 122.6(11) . .
C60 C61 C62 129.3(16) . .
C60 C61 H61 115.4 . .
C62 C61 H61 115.4 . .
C63 C62 C61 111.7(16) . .
C63 C62 H62 124.1 . .
C61 C62 H62 124.1 . .
C62 C63 C64 121.2(18) . .
C62 C63 H63 119.4 . .
C64 C63 H63 119.4 . .
C63 C64 C65 127.3(17) . .
C63 C64 H64 116.3 . .
C65 C64 H64 116.3 . .
C64 C65 C60 114.8(15) . .
C64 C65 H65 122.6 . .
C60 C65 H65 122.6 . .
C67 C66 C71 117.7(11) . .
C67 C66 P1 122.3(9) . .
C71 C66 P1 120.0(9) . .
C66 C67 C68 122.2(11) . .
C66 C67 H67 118.9 . .
C68 C67 H67 118.9 . .
C69 C68 C67 120.1(13) . .
C69 C68 H68 119.9 . .
C67 C68 H68 119.9 . .
C68 C69 C70 120.1(14) . .
C68 C69 H69 119.9 . .
C70 C69 H69 119.9 . .
C69 C70 C71 120.2(15) . .
C69 C70 H70 119.9 . .
C71 C70 H70 119.9 . .
C66 C71 C70 119.6(14) . .
C66 C71 H71 120.2 . .
C70 C71 H71 120.2 . .
C77 C72 C73 119.8(13) . .
C77 C72 P2 117.2(11) . .
C73 C72 P2 123.0(10) . .
C72 C73 C74 121.4(12) . .
C72 C73 H73 119.3 . .
C74 C73 H73 119.3 . .
C75 C74 C73 118.0(18) . .
C75 C74 H74 121.0 . .
C73 C74 H74 121.0 . .
C76 C75 C74 121.1(17) . .
C76 C75 H75 119.4 . .
C74 C75 H75 119.4 . .
C75 C76 C77 122.7(14) . .
C75 C76 H76 118.6 . .
C77 C76 H76 118.6 . .
C72 C77 C76 116.3(13) . .
C72 C77 H77A 108.2 . .
C76 C77 H77A 108.2 . .
C72 C77 H77B 108.2 . .
C76 C77 H77B 108.2 . .
H77A C77 H77B 107.4 . .
C79 C78 C83 120.3(15) . .
C79 C78 P2 120.0(13) . .
C83 C78 P2 119.7(11) . .
C78 C79 C80 121.7(17) . .
C78 C79 H79 119.2 . .
C80 C79 H79 119.2 . .
C79 C80 C81 114.8(15) . .
C79 C80 H80 122.6 . .
C81 C80 H80 122.6 . .
C82 C81 C80 119.0(16) . .
C82 C81 H81A 107.6 . .
C80 C81 H81A 107.6 . .
C82 C81 H81B 107.6 . .
C80 C81 H81B 107.6 . .
H81A C81 H81B 107.0 . .
C83 C82 C81 117.6(19) . .
C83 C82 H82 121.2 . .
C81 C82 H82 121.2 . .
C82 C83 C78 125.5(16) . .
C82 C83 H83 117.3 . .
C78 C83 H83 117.3 . .
C36 C84 P2 109.9(8) 2_765 .
C36 C84 H84A 109.7 2_765 .
P2 C84 H84A 109.7 . .
C36 C84 H84B 109.7 2_765 .
P2 C84 H84B 109.7 . .
H84A C84 H84B 108.2 . .
N6 C85 C86 107.1(15) . .
N7 C86 C85 105(2) . .
N6 C87 C88 101.8(17) . .
N7 C88 C87 112.7(17) . .
C90 C89 N6 107.6(15) . .
C89 C90 N7 106.7(15) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 N1 2.041(7) .
Zn1 N2 2.052(7) .
Zn1 N4 2.052(6) .
Zn1 N3 2.076(7) .
Zn1 N5 2.191(8) .
Cu1 P2 2.250(4) .
Cu1 P1 2.265(4) .
Cu1 Cl1 2.331(4) .
Cu1 Cl2 2.394(3) .
P1 C66 1.770(11) .
P1 C59 1.776(13) .
P1 C60 1.821(12) .
P2 C84 1.845(13) .
P2 C72 1.847(13) .
P2 C78 1.865(15) .
O1 C33 1.411(12) .
O1 C36 1.431(15) .
O2 C58 1.378(13) .
O2 C55 1.404(11) .
N1 C4 1.362(11) .
N1 C1 1.372(10) .
N2 C6 1.368(12) .
N2 C9 1.393(12) .
N3 C14 1.371(12) .
N3 C11 1.417(10) .
N4 C19 1.336(10) .
N4 C16 1.407(11) .
N5 C47 1.41(2) .
N5 C48 1.46(2) .
N5 C50 1.49(2) .
N5 C49 1.541(19) .
N5 C51 1.61(3) .
N5 C46 1.675(17) .
N6 C87 1.44(2) .
N6 C85 1.62(2) .
N6 C89 1.63(2) .
N7 C86 1.31(2) .
N7 C88 1.44(3) .
N7 C90 1.75(2) .
C1 C20 1.403(12) .
C1 C2 1.458(13) .
C2 C3 1.347(13) .
C2 H2 0.9300 .
C3 C4 1.446(13) .
C3 H3 0.9300 .
C4 C5 1.427(11) .
C5 C6 1.401(14) .
C5 C52 1.480(12) .
C6 C7 1.442(13) .
C7 C8 1.364(14) .
C7 H7 0.9300 .
C8 C9 1.475(13) .
C8 H8 0.9300 .
C9 C10 1.359(13) .
C10 C11 1.409(13) .
C10 C21 1.573(13) .
C11 C12 1.399(13) .
C12 C13 1.333(13) .
C12 H12 0.9300 .
C13 C14 1.431(12) .
C13 H13 0.9300 .
C14 C15 1.409(12) .
C15 C16 1.348(12) .
C15 C30 1.558(12) .
C16 C17 1.481(12) .
C17 C18 1.295(12) .
C17 H17 0.9300 .
C18 C19 1.497(12) .
C18 H18 0.9300 .
C19 C20 1.404(11) .
C20 C37 1.573(11) .
C21 C26 1.363(15) .
C21 C22 1.372(16) .
C22 C23 1.439(16) .
C22 C27 1.54(2) .
C23 C24 1.385(18) .
C23 H23 0.9300 .
C24 C25 1.305(16) .
C24 C28 1.561(13) .
C25 C26 1.379(14) .
C25 H25 0.9300 .
C26 C29 1.496(15) .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
C30 C35 1.359(13) .
C30 C31 1.415(15) .
C31 C32 1.360(14) .
C31 H31 0.9300 .
C32 C33 1.317(16) .
C32 H32 0.9300 .
C33 C34 1.389(17) .
C34 C35 1.432(15) .
C34 H34 0.9300 .
C35 H35 0.9300 .
C36 C84 1.539(18) 2_765
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C37 C38 1.346(13) .
C37 C42 1.364(14) .
C38 C39 1.396(13) .
C38 C43 1.542(14) .
C39 C40 1.336(15) .
C39 H39 0.9300 .
C40 C41 1.325(15) .
C40 C44 1.521(12) .
C41 C42 1.403(13) .
C41 H41 0.9300 .
C42 C45 1.487(16) .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C45 H45A 0.9600 .
C45 H45B 0.9600 .
C45 H45C 0.9600 .
C46 C49 1.37(3) 2_765
C46 C47 1.62(3) .
C46 C51 1.84(5) .
C47 C48 1.11(3) .
C47 C50 1.67(3) 2_765
C47 C51 2.00(4) 2_765
C48 C49 1.44(3) .
C48 C51 1.73(4) 2_765
C49 C46 1.37(3) 2_765
C49 C50 1.53(4) .
C50 C51 1.14(4) .
C50 C47 1.67(3) 2_765
C51 C48 1.73(4) 2_765
C51 C47 2.00(4) 2_765
C52 C57 1.333(14) .
C52 C53 1.410(13) .
C53 C54 1.413(14) .
C53 H53 0.9300 .
C54 C55 1.381(15) .
C54 H54 0.9300 .
C55 C56 1.349(14) .
C56 C57 1.407(15) .
C56 H56 0.9300 .
C57 H57 0.9300 .
C58 C59 1.614(14) .
C58 H58A 0.9700 .
C58 H58B 0.9700 .
C59 H59A 0.9700 .
C59 H59B 0.9700 .
C60 C61 1.297(16) .
C60 C65 1.420(17) .
C61 C62 1.481(19) .
C61 H61 0.9300 .
C62 C63 1.30(2) .
C62 H62 0.9300 .
C63 C64 1.34(2) .
C63 H63 0.9300 .
C64 C65 1.37(2) .
C64 H64 0.9300 .
C65 H65 0.9300 .
C66 C67 1.371(16) .
C66 C71 1.402(17) .
C67 C68 1.433(16) .
C67 H67 0.9300 .
C68 C69 1.311(17) .
C68 H68 0.9300 .
C69 C70 1.41(2) .
C69 H69 0.9300 .
C70 C71 1.419(19) .
C70 H70 0.9300 .
C71 H71 0.9300 .
C72 C77 1.327(15) .
C72 C73 1.401(18) .
C73 C74 1.43(2) .
C73 H73 0.9300 .
C74 C75 1.36(2) .
C74 H74 0.9300 .
C75 C76 1.28(2) .
C75 H75 0.9300 .
C76 C77 1.52(2) .
C76 H76 0.9300 .
C77 H77A 0.9700 .
C77 H77B 0.9700 .
C78 C79 1.317(17) .
C78 C83 1.36(2) .
C79 C80 1.35(2) .
C79 H79 0.9300 .
C80 C81 1.55(3) .
C80 H80 0.9300 .
C81 C82 1.34(2) .
C81 H81A 0.9700 .
C81 H81B 0.9700 .
C82 C83 1.29(2) .
C82 H82 0.9300 .
C83 H83 0.9300 .
C84 C36 1.539(18) 2_765
C84 H84A 0.9700 .
C84 H84B 0.9700 .
C85 C86 1.69(3) .
C87 C88 1.70(3) .
C89 C90 1.50(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
P2 Cu1 P1 C66 70.0(5) . .
Cl1 Cu1 P1 C66 -54.9(5) . .
Cl2 Cu1 P1 C66 -171.4(5) . .
P2 Cu1 P1 C59 -51.2(5) . .
Cl1 Cu1 P1 C59 -176.1(4) . .
Cl2 Cu1 P1 C59 67.4(5) . .
P2 Cu1 P1 C60 -166.6(4) . .
Cl1 Cu1 P1 C60 68.5(4) . .
Cl2 Cu1 P1 C60 -48.1(4) . .
P1 Cu1 P2 C84 150.3(6) . .
Cl1 Cu1 P2 C84 -82.9(6) . .
Cl2 Cu1 P2 C84 27.5(6) . .
P1 Cu1 P2 C72 -89.1(5) . .
Cl1 Cu1 P2 C72 37.6(5) . .
Cl2 Cu1 P2 C72 148.1(5) . .
P1 Cu1 P2 C78 30.1(5) . .
Cl1 Cu1 P2 C78 156.8(5) . .
Cl2 Cu1 P2 C78 -92.7(5) . .
N2 Zn1 N1 C4 -23.0(8) . .
N4 Zn1 N1 C4 174.1(8) . .
N3 Zn1 N1 C4 -106.9(11) . .
N5 Zn1 N1 C4 71.3(8) . .
N2 Zn1 N1 C1 177.5(8) . .
N4 Zn1 N1 C1 14.7(8) . .
N3 Zn1 N1 C1 93.7(11) . .
N5 Zn1 N1 C1 -88.2(8) . .
N1 Zn1 N2 C6 8.7(8) . .
N4 Zn1 N2 C6 90.5(13) . .
N3 Zn1 N2 C6 171.1(8) . .
N5 Zn1 N2 C6 -88.5(8) . .
N1 Zn1 N2 C9 -163.3(8) . .
N4 Zn1 N2 C9 -81.5(12) . .
N3 Zn1 N2 C9 -0.9(8) . .
N5 Zn1 N2 C9 99.5(8) . .
N1 Zn1 N3 C14 -99.4(10) . .
N2 Zn1 N3 C14 176.9(8) . .
N4 Zn1 N3 C14 -20.2(8) . .
N5 Zn1 N3 C14 82.4(8) . .
N1 Zn1 N3 C11 97.0(11) . .
N2 Zn1 N3 C11 13.4(8) . .
N4 Zn1 N3 C11 176.3(8) . .
N5 Zn1 N3 C11 -81.1(8) . .
N1 Zn1 N4 C19 -6.9(8) . .
N2 Zn1 N4 C19 -88.6(12) . .
N3 Zn1 N4 C19 -169.5(8) . .
N5 Zn1 N4 C19 90.4(7) . .
N1 Zn1 N4 C16 176.6(7) . .
N2 Zn1 N4 C16 94.9(11) . .
N3 Zn1 N4 C16 14.0(7) . .
N5 Zn1 N4 C16 -86.0(7) . .
N1 Zn1 N5 C47 -151.8(12) . .
N2 Zn1 N5 C47 -63.0(12) . .
N4 Zn1 N5 C47 117.3(12) . .
N3 Zn1 N5 C47 27.6(13) . .
N1 Zn1 N5 C48 159.6(11) . .
N2 Zn1 N5 C48 -111.6(11) . .
N4 Zn1 N5 C48 68.7(11) . .
N3 Zn1 N5 C48 -21.0(11) . .
N1 Zn1 N5 C50 32.8(12) . .
N2 Zn1 N5 C50 121.7(12) . .
N4 Zn1 N5 C50 -58.1(12) . .
N3 Zn1 N5 C50 -147.8(12) . .
N1 Zn1 N5 C49 97.7(10) . .
N2 Zn1 N5 C49 -173.4(10) . .
N4 Zn1 N5 C49 6.9(10) . .
N3 Zn1 N5 C49 -82.8(10) . .
N1 Zn1 N5 C51 -11.7(17) . .
N2 Zn1 N5 C51 77.2(17) . .
N4 Zn1 N5 C51 -102.5(17) . .
N3 Zn1 N5 C51 167.8(17) . .
N1 Zn1 N5 C46 -83.9(7) . .
N2 Zn1 N5 C46 4.9(7) . .
N4 Zn1 N5 C46 -174.8(7) . .
N3 Zn1 N5 C46 95.5(7) . .
C4 N1 C1 C20 177.2(9) . .
Zn1 N1 C1 C20 -20.0(14) . .
C4 N1 C1 C2 1.3(11) . .
Zn1 N1 C1 C2 164.2(6) . .
N1 C1 C2 C3 -3.2(12) . .
C20 C1 C2 C3 -179.2(10) . .
C1 C2 C3 C4 3.6(12) . .
C1 N1 C4 C5 -173.8(9) . .
Zn1 N1 C4 C5 23.5(13) . .
C1 N1 C4 C3 1.0(11) . .
Zn1 N1 C4 C3 -161.7(7) . .
C2 C3 C4 N1 -3.0(12) . .
C2 C3 C4 C5 171.8(10) . .
N1 C4 C5 C6 -1.8(15) . .
C3 C4 C5 C6 -175.9(10) . .
N1 C4 C5 C52 174.7(9) . .
C3 C4 C5 C52 0.5(14) . .
C9 N2 C6 C5 -180.0(10) . .
Zn1 N2 C6 C5 6.9(15) . .
C9 N2 C6 C7 -1.4(11) . .
Zn1 N2 C6 C7 -174.5(7) . .
C4 C5 C6 N2 -14.4(16) . .
C52 C5 C6 N2 169.2(9) . .
C4 C5 C6 C7 167.3(9) . .
C52 C5 C6 C7 -9.2(15) . .
N2 C6 C7 C8 2.3(12) . .
C5 C6 C7 C8 -179.1(10) . .
C6 C7 C8 C9 -2.2(12) . .
C6 N2 C9 C10 178.5(11) . .
Zn1 N2 C9 C10 -8.3(15) . .
C6 N2 C9 C8 0.0(11) . .
Zn1 N2 C9 C8 173.3(7) . .
C7 C8 C9 C10 -177.1(10) . .
C7 C8 C9 N2 1.4(12) . .
N2 C9 C10 C11 7.0(19) . .
C8 C9 C10 C11 -174.8(11) . .
N2 C9 C10 C21 -176.9(10) . .
C8 C9 C10 C21 1.3(17) . .
C9 C10 C11 C12 -179.4(11) . .
C21 C10 C11 C12 4.3(17) . .
C9 C10 C11 N3 7.1(18) . .
C21 C10 C11 N3 -169.2(9) . .
C14 N3 C11 C12 0.8(11) . .
Zn1 N3 C11 C12 167.3(7) . .
C14 N3 C11 C10 175.3(10) . .
Zn1 N3 C11 C10 -18.1(14) . .
C10 C11 C12 C13 -176.8(11) . .
N3 C11 C12 C13 -2.7(12) . .
C11 C12 C13 C14 3.4(12) . .
C11 N3 C14 C15 -175.6(9) . .
Zn1 N3 C14 C15 18.1(13) . .
C11 N3 C14 C13 1.3(10) . .
Zn1 N3 C14 C13 -165.0(7) . .
C12 C13 C14 N3 -3.0(12) . .
C12 C13 C14 C15 173.7(10) . .
N3 C14 C15 C16 -2.5(16) . .
C13 C14 C15 C16 -178.8(10) . .
N3 C14 C15 C30 176.2(9) . .
C13 C14 C15 C30 -0.1(15) . .
C14 C15 C16 N4 -3.9(17) . .
C30 C15 C16 N4 177.5(9) . .
C14 C15 C16 C17 171.3(10) . .
C30 C15 C16 C17 -7.4(16) . .
C19 N4 C16 C15 177.0(10) . .
Zn1 N4 C16 C15 -5.9(14) . .
C19 N4 C16 C17 1.1(10) . .
Zn1 N4 C16 C17 178.2(6) . .
C15 C16 C17 C18 -175.9(10) . .
N4 C16 C17 C18 0.0(12) . .
C16 C17 C18 C19 -1.0(12) . .
C16 N4 C19 C20 179.8(9) . .
Zn1 N4 C19 C20 2.8(13) . .
C16 N4 C19 C18 -1.7(10) . .
Zn1 N4 C19 C18 -178.7(6) . .
C17 C18 C19 N4 1.8(12) . .
C17 C18 C19 C20 -179.7(9) . .
N1 C1 C20 C19 12.4(16) . .
C2 C1 C20 C19 -172.4(9) . .
N1 C1 C20 C37 -173.3(9) . .
C2 C1 C20 C37 1.9(14) . .
N4 C19 C20 C1 -3.0(15) . .
C18 C19 C20 C1 178.7(10) . .
N4 C19 C20 C37 -177.3(9) . .
C18 C19 C20 C37 4.4(14) . .
C9 C10 C21 C26 -86.7(14) . .
C11 C10 C21 C26 90.1(13) . .
C9 C10 C21 C22 84.7(14) . .
C11 C10 C21 C22 -98.5(13) . .
C26 C21 C22 C23 -2.9(19) . .
C10 C21 C22 C23 -174.0(11) . .
C26 C21 C22 C27 175.8(16) . .
C10 C21 C22 C27 5(2) . .
C21 C22 C23 C24 -4(2) . .
C27 C22 C23 C24 177.0(16) . .
C22 C23 C24 C25 7(2) . .
C22 C23 C24 C28 179.0(12) . .
C23 C24 C25 C26 -2.6(18) . .
C28 C24 C25 C26 -173.4(11) . .
C22 C21 C26 C25 7.6(18) . .
C10 C21 C26 C25 178.3(9) . .
C22 C21 C26 C29 -175.6(12) . .
C10 C21 C26 C29 -5.0(16) . .
C24 C25 C26 C21 -4.8(16) . .
C24 C25 C26 C29 178.6(10) . .
C16 C15 C30 C35 -60.8(13) . .
C14 C15 C30 C35 120.4(10) . .
C16 C15 C30 C31 112.7(11) . .
C14 C15 C30 C31 -66.1(12) . .
C35 C30 C31 C32 -6.1(15) . .
C15 C30 C31 C32 -179.4(9) . .
C30 C31 C32 C33 8.1(17) . .
C31 C32 C33 C34 -6.2(18) . .
C31 C32 C33 O1 176.3(10) . .
C36 O1 C33 C32 165.9(11) . .
C36 O1 C33 C34 -11.7(16) . .
C32 C33 C34 C35 2.1(16) . .
O1 C33 C34 C35 179.6(9) . .
C31 C30 C35 C34 2.1(13) . .
C15 C30 C35 C34 175.4(8) . .
C33 C34 C35 C30 -0.1(14) . .
C33 O1 C36 C84 -68.5(15) . 2_765
C1 C20 C37 C38 101.1(11) . .
C19 C20 C37 C38 -84.3(11) . .
C1 C20 C37 C42 -80.6(12) . .
C19 C20 C37 C42 94.0(11) . .
C42 C37 C38 C39 2.2(14) . .
C20 C37 C38 C39 -179.6(8) . .
C42 C37 C38 C43 -178.0(9) . .
C20 C37 C38 C43 0.3(13) . .
C37 C38 C39 C40 -1.2(14) . .
C43 C38 C39 C40 178.9(9) . .
C38 C39 C40 C41 0.9(14) . .
C38 C39 C40 C44 -176.7(8) . .
C39 C40 C41 C42 -1.5(16) . .
C44 C40 C41 C42 176.1(10) . .
C38 C37 C42 C41 -2.6(15) . .
C20 C37 C42 C41 179.3(8) . .
C38 C37 C42 C45 -178.4(10) . .
C20 C37 C42 C45 3.4(15) . .
C40 C41 C42 C37 2.2(15) . .
C40 C41 C42 C45 178.3(10) . .
C47 N5 C46 C49 -79.8(17) . 2_765
C48 N5 C46 C49 -60.2(19) . 2_765
C50 N5 C46 C49 60(2) . 2_765
C49 N5 C46 C49 -3(3) . 2_765
C51 N5 C46 C49 82(2) . 2_765
Zn1 N5 C46 C49 179.2(13) . 2_765
C48 N5 C46 C47 19.5(15) . .
C50 N5 C46 C47 140.3(17) . .
C49 N5 C46 C47 76.9(19) . .
C51 N5 C46 C47 162.3(17) . .
Zn1 N5 C46 C47 -101.0(11) . .
C47 N5 C46 C51 -162.3(17) . .
C48 N5 C46 C51 -142.7(16) . .
C50 N5 C46 C51 -22.0(17) . .
C49 N5 C46 C51 -85.4(18) . .
Zn1 N5 C46 C51 96.8(13) . .
C50 N5 C47 C48 73(3) . .
C49 N5 C47 C48 18.0(18) . .
C51 N5 C47 C48 132(2) . .
C46 N5 C47 C48 153(2) . .
Zn1 N5 C47 C48 -100.1(16) . .
C48 N5 C47 C46 -153(2) . .
C50 N5 C47 C46 -80(3) . .
C49 N5 C47 C46 -134.9(13) . .
C51 N5 C47 C46 -21(2) . .
Zn1 N5 C47 C46 107.0(11) . .
C48 N5 C47 C50 -84(2) . 2_765
C50 N5 C47 C50 -12(4) . 2_765
C49 N5 C47 C50 -66(2) . 2_765
C51 N5 C47 C50 47(3) . 2_765
C46 N5 C47 C50 68(2) . 2_765
Zn1 N5 C47 C50 175.4(16) . 2_765
C48 N5 C47 C51 -49.2(18) . 2_765
C50 N5 C47 C51 24(3) . 2_765
C49 N5 C47 C51 -31.2(16) . 2_765
C51 N5 C47 C51 83(3) . 2_765
C46 N5 C47 C51 103.7(17) . 2_765
Zn1 N5 C47 C51 -149.3(11) . 2_765
C49 C46 C47 C48 79(3) 2_765 .
N5 C46 C47 C48 -33(2) . .
C51 C46 C47 C48 -19(3) . .
C49 C46 C47 N5 111.8(15) 2_765 .
C51 C46 C47 N5 14.7(14) . .
C49 C46 C47 C50 -8.7(15) 2_765 2_765
N5 C46 C47 C50 -120.5(17) . 2_765
C51 C46 C47 C50 -105.8(18) . 2_765
C49 C46 C47 C51 13(2) 2_765 2_765
N5 C46 C47 C51 -98(2) . 2_765
C51 C46 C47 C51 -84(2) . 2_765
N5 C47 C48 C49 -24(2) . .
C46 C47 C48 C49 9(4) . .
C50 C47 C48 C49 90(2) 2_765 .
C51 C47 C48 C49 98(3) 2_765 .
C46 C47 C48 N5 33(2) . .
C50 C47 C48 N5 114.0(14) 2_765 .
C51 C47 C48 N5 121.8(17) 2_765 .
N5 C47 C48 C51 -121.8(17) . 2_765
C46 C47 C48 C51 -89(2) . 2_765
C50 C47 C48 C51 -7.8(19) 2_765 2_765
C50 N5 C48 C47 -138.8(17) . .
C49 N5 C48 C47 -159(2) . .
C51 N5 C48 C47 -97(4) . .
C46 N5 C48 C47 -24.6(18) . .
Zn1 N5 C48 C47 97.7(15) . .
C47 N5 C48 C49 159(2) . .
C50 N5 C48 C49 20.0(16) . .
C51 N5 C48 C49 62(4) . .
C46 N5 C48 C49 134.1(13) . .
Zn1 N5 C48 C49 -103.5(11) . .
C47 N5 C48 C51 72(2) . 2_765
C50 N5 C48 C51 -66(3) . 2_765
C49 N5 C48 C51 -86(3) . 2_765
C51 N5 C48 C51 -24(5) . 2_765
C46 N5 C48 C51 48(3) . 2_765
Zn1 N5 C48 C51 170(2) . 2_765
C47 C48 C49 C46 -93(3) . 2_765
N5 C48 C49 C46 -117.2(14) . 2_765
C51 C48 C49 C46 -1.1(19) 2_765 2_765
C47 C48 C49 C50 4(3) . .
N5 C48 C49 C50 -19.3(17) . .
C51 C48 C49 C50 97(2) 2_765 .
C47 C48 C49 N5 24(2) . .
C51 C48 C49 N5 116.1(16) 2_765 .
C47 N5 C49 C46 64(2) . 2_765
C48 N5 C49 C46 80(2) . 2_765
C50 N5 C49 C46 -79(2) . 2_765
C51 N5 C49 C46 -68(2) . 2_765
C46 N5 C49 C46 3(3) . 2_765
Zn1 N5 C49 C46 -179.1(15) . 2_765
C47 N5 C49 C48 -15.2(15) . .
C50 N5 C49 C48 -159.1(18) . .
C51 N5 C49 C48 -147.7(18) . .
C46 N5 C49 C48 -76.6(18) . .
Zn1 N5 C49 C48 101.2(12) . .
C47 N5 C49 C50 143.9(15) . .
C48 N5 C49 C50 159.1(18) . .
C51 N5 C49 C50 11.4(19) . .
C46 N5 C49 C50 82.5(19) . .
Zn1 N5 C49 C50 -99.7(13) . .
C47 N5 C50 C51 96(3) . .
C48 N5 C50 C51 144(2) . .
C49 N5 C50 C51 163(3) . .
C46 N5 C50 C51 31(2) . .
Zn1 N5 C50 C51 -91(2) . .
C47 N5 C50 C49 -68(3) . .
C48 N5 C50 C49 -19.2(16) . .
C51 N5 C50 C49 -163(3) . .
C46 N5 C50 C49 -132.6(11) . .
Zn1 N5 C50 C49 105.4(11) . .
C47 N5 C50 C47 11(4) . 2_765
C48 N5 C50 C47 59(2) . 2_765
C49 N5 C50 C47 78.6(19) . 2_765
C51 N5 C50 C47 -85(2) . 2_765
C46 N5 C50 C47 -54.0(19) . 2_765
Zn1 N5 C50 C47 -176.0(13) . 2_765
C46 C49 C50 C51 95(4) 2_765 .
C48 C49 C50 C51 -2(4) . .
N5 C49 C50 C51 -22(3) . .
C46 C49 C50 N5 117.3(13) 2_765 .
C48 C49 C50 N5 19.4(16) . .
C46 C49 C50 C47 9.2(16) 2_765 2_765
C48 C49 C50 C47 -89(2) . 2_765
N5 C49 C50 C47 -108.1(15) . 2_765
C49 C50 C51 N5 20(3) . .
C47 C50 C51 N5 105.3(15) 2_765 .
N5 C50 C51 C48 -97.8(19) . 2_765
C49 C50 C51 C48 -78(4) . 2_765
C47 C50 C51 C48 8(2) 2_765 2_765
N5 C50 C51 C46 -29(2) . .
C49 C50 C51 C46 -9(5) . .
C47 C50 C51 C46 76(2) 2_765 .
N5 C50 C51 C47 -105.3(15) . 2_765
C49 C50 C51 C47 -85(3) . 2_765
C47 N5 C51 C50 -128(3) . .
C48 N5 C51 C50 -64(4) . .
C49 N5 C51 C50 -15(2) . .
C46 N5 C51 C50 -148(3) . .
Zn1 N5 C51 C50 102(2) . .
C47 N5 C51 C48 -42(3) . 2_765
C48 N5 C51 C48 22(5) . 2_765
C50 N5 C51 C48 86(2) . 2_765
C49 N5 C51 C48 71(2) . 2_765
C46 N5 C51 C48 -62(2) . 2_765
Zn1 N5 C51 C48 -172.2(16) . 2_765
C47 N5 C51 C46 20(2) . .
C48 N5 C51 C46 84(3) . .
C50 N5 C51 C46 148(3) . .
C49 N5 C51 C46 133.2(12) . .
Zn1 N5 C51 C46 -110.1(10) . .
C47 N5 C51 C47 -74(3) . 2_765
C48 N5 C51 C47 -10(4) . 2_765
C50 N5 C51 C47 54(2) . 2_765
C49 N5 C51 C47 38.9(19) . 2_765
C46 N5 C51 C47 -94.3(18) . 2_765
Zn1 N5 C51 C47 155.6(13) . 2_765
C49 C46 C51 C50 -79(3) 2_765 .
C47 C46 C51 C50 17(3) . .
N5 C46 C51 C50 31(2) . .
C49 C46 C51 N5 -110.5(14) 2_765 .
C47 C46 C51 N5 -14.0(13) . .
C49 C46 C51 C48 0.9(16) 2_765 2_765
C47 C46 C51 C48 97.4(15) . 2_765
N5 C46 C51 C48 111.4(15) . 2_765
C49 C46 C51 C47 -25.5(17) 2_765 2_765
C47 C46 C51 C47 71.0(17) . 2_765
N5 C46 C51 C47 85.0(14) . 2_765
C6 C5 C52 C57 -49.1(14) . .
C4 C5 C52 C57 134.3(11) . .
C6 C5 C52 C53 121.2(10) . .
C4 C5 C52 C53 -55.4(12) . .
C57 C52 C53 C54 0.3(16) . .
C5 C52 C53 C54 -170.2(9) . .
C52 C53 C54 C55 -0.6(16) . .
C53 C54 C55 C56 0.1(17) . .
C53 C54 C55 O2 175.6(9) . .
C58 O2 C55 C56 1.0(15) . .
C58 O2 C55 C54 -174.5(9) . .
C54 C55 C56 C57 0.7(18) . .
O2 C55 C56 C57 -174.3(10) . .
C53 C52 C57 C56 0.5(18) . .
C5 C52 C57 C56 170.8(10) . .
C55 C56 C57 C52 -1.0(19) . .
C55 O2 C58 C59 -178.6(9) . .
O2 C58 C59 P1 174.7(8) . .
C66 P1 C59 C58 -176.8(9) . .
C60 P1 C59 C58 73.6(9) . .
Cu1 P1 C59 C58 -49.4(9) . .
C66 P1 C60 C61 128.9(12) . .
C59 P1 C60 C61 -121.7(12) . .
Cu1 P1 C60 C61 -0.1(13) . .
C66 P1 C60 C65 -48.3(11) . .
C59 P1 C60 C65 61.1(10) . .
Cu1 P1 C60 C65 -177.3(8) . .
C65 C60 C61 C62 -2(2) . .
P1 C60 C61 C62 -179.7(13) . .
C60 C61 C62 C63 3(3) . .
C61 C62 C63 C64 -4(2) . .
C62 C63 C64 C65 7(3) . .
C63 C64 C65 C60 -6(2) . .
C61 C60 C65 C64 3.1(17) . .
P1 C60 C65 C64 -179.5(9) . .
C59 P1 C66 C67 166.2(13) . .
C60 P1 C66 C67 -86.8(14) . .
Cu1 P1 C66 C67 41.1(15) . .
C59 P1 C66 C71 -16.8(15) . .
C60 P1 C66 C71 90.1(13) . .
Cu1 P1 C66 C71 -141.9(11) . .
C71 C66 C67 C68 3(2) . .
P1 C66 C67 C68 179.7(11) . .
C66 C67 C68 C69 -2(2) . .
C67 C68 C69 C70 1(2) . .
C68 C69 C70 C71 0(3) . .
C67 C66 C71 C70 -2(2) . .
P1 C66 C71 C70 -178.9(15) . .
C69 C70 C71 C66 1(3) . .
C84 P2 C72 C77 163.7(10) . .
C78 P2 C72 C77 -85.9(11) . .
Cu1 P2 C72 C77 35.8(11) . .
C84 P2 C72 C73 -15.1(12) . .
C78 P2 C72 C73 95.2(12) . .
Cu1 P2 C72 C73 -143.1(11) . .
C77 C72 C73 C74 -6(2) . .
P2 C72 C73 C74 172.4(14) . .
C72 C73 C74 C75 11(3) . .
C73 C74 C75 C76 -8(3) . .
C74 C75 C76 C77 2(3) . .
C73 C72 C77 C76 0.0(18) . .
P2 C72 C77 C76 -178.9(9) . .
C75 C76 C77 C72 2(2) . .
C84 P2 C78 C79 131.7(13) . .
C72 P2 C78 C79 22.7(14) . .
Cu1 P2 C78 C79 -101.3(12) . .
C84 P2 C78 C83 -49.8(14) . .
C72 P2 C78 C83 -158.8(12) . .
Cu1 P2 C78 C83 77.2(13) . .
C83 C78 C79 C80 -3(3) . .
P2 C78 C79 C80 175.7(15) . .
C78 C79 C80 C81 0(3) . .
C79 C80 C81 C82 8(3) . .
C80 C81 C82 C83 -13(3) . .
C81 C82 C83 C78 11(3) . .
C79 C78 C83 C82 -2(3) . .
P2 C78 C83 C82 179.2(15) . .
C72 P2 C84 C36 -73.2(11) . 2_765
C78 P2 C84 C36 175.9(9) . 2_765
Cu1 P2 C84 C36 53.0(12) . 2_765
C87 N6 C85 C86 -72.8(18) . .
C89 N6 C85 C86 54.4(18) . .
C88 N7 C86 C85 49(2) . .
C90 N7 C86 C85 -70(2) . .
N6 C85 C86 N7 13(2) . .
C85 N6 C87 C88 63.0(17) . .
C89 N6 C87 C88 -59(2) . .
C86 N7 C88 C87 -58(2) . .
C90 N7 C88 C87 68.4(17) . .
N6 C87 C88 N7 -8(2) . .
C87 N6 C89 C90 52(2) . .
C85 N6 C89 C90 -69(2) . .
N6 C89 C90 N7 18(2) . .
C86 N7 C90 C89 56(3) . .
C88 N7 C90 C89 -75(2) . .
