#------------------------------------------------------------------------------
#$Date: 2016-03-22 11:51:51 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178920 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/49/4114944.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4114944
loop_
_publ_author_name
'Ok-Sang Jung'
'Yun Ju Kim'
'Kwan Mook Kim'
'Young-A Lee'
_publ_section_title
;
 A 20-Å-Thick Interwoven Sheet Consisting of Nanotubes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7906
_journal_page_last               7907
_journal_paper_doi               10.1021/ja026774s
_journal_volume                  124
_journal_year                    2002
_chemical_formula_sum            'C48 H58 Ag3 N11 O10 Si4'
_chemical_formula_weight         1385.02
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00(2)
_cell_angle_beta                 114.05(2)
_cell_angle_gamma                90.00(2)
_cell_formula_units_Z            4
_cell_length_a                   19.216(4)
_cell_length_b                   16.339(3)
_cell_length_c                   20.751(5)
_cell_measurement_temperature    293(2)
_cell_volume                     5950(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.609
_diffrn_measured_fraction_theta_max 0.609
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0232
_diffrn_reflns_av_sigmaI/netI    0.0400
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            6798
_diffrn_reflns_theta_full        24.97
_diffrn_reflns_theta_max         24.97
_diffrn_reflns_theta_min         1.65
_exptl_absorpt_coefficient_mu    1.119
_exptl_absorpt_correction_T_max  0.99
_exptl_absorpt_correction_T_min  0.65
_exptl_absorpt_correction_type   'empirical psi scan'
_exptl_crystal_density_diffrn    1.546
_exptl_crystal_F_000             2800
_refine_diff_density_max         0.878
_refine_diff_density_min         -0.374
_refine_diff_density_rms         0.092
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.02(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.996
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1369
_refine_ls_number_reflns         6602
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.996
_refine_ls_R_factor_all          0.0520
_refine_ls_R_factor_gt           0.0492
_refine_ls_shift/su_max          2.936
_refine_ls_shift/su_mean         0.142
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0982P)²+4.2209P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1258
_refine_ls_wR_factor_ref         0.1289
_reflns_number_gt                6278
_reflns_number_total             6602
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja026774s_s1.cif
_cod_data_source_block           ag
_cod_database_code               4114944
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.02516(8) 0.23093(8) 0.16803(8) 0.0861(4) Uani 1 1 d .
Ag2 Ag 0.35736(7) 0.02133(8) -0.12300(7) 0.0795(4) Uani 1 1 d .
Ag3 Ag -0.16350(8) -0.35735(12) -0.42032(8) 0.1059(6) Uani 1 1 d .
Ag4 Ag 0.56583(8) 0.25702(9) -0.13368(7) 0.0845(4) Uani 1 1 d .
Ag5 Ag 0.19052(6) -0.00270(8) 0.14219(8) 0.0826(4) Uani 1 1 d .
Ag6 Ag 0.68288(8) -0.35271(15) 0.41290(9) 0.1190(6) Uani 1 1 d .
Si1 Si 0.0233(3) 0.5418(3) 0.4071(3) 0.0842(15) Uani 1 1 d .
Si2 Si -0.3095(3) -0.0336(3) 0.1776(3) 0.0748(12) Uani 1 1 d .
Si3 Si 0.0109(3) 0.1875(4) -0.1488(3) 0.0874(15) Uani 1 1 d .
Si4 Si 0.1828(2) -0.2411(3) -0.4100(2) 0.0565(9) Uani 1 1 d .
Si5 Si 0.50149(19) 0.5257(3) -0.40747(19) 0.0543(9) Uani 1 1 d .
Si6 Si 0.8096(2) -0.0798(3) -0.0736(3) 0.0825(14) Uani 1 1 d .
Si7 Si 0.4795(2) 0.2614(3) 0.1597(2) 0.0569(9) Uani 1 1 d .
Si8 Si 0.3091(2) -0.3461(3) 0.3617(2) 0.0629(10) Uani 1 1 d .
N1 N -0.0064(7) 0.3411(8) 0.2350(6) 0.067(3) Uani 1 1 d .
N2 N -0.2136(7) 0.6072(10) 0.4056(7) 0.075(4) Uani 1 1 d .
N3 N -0.1208(7) 0.1434(9) 0.1697(6) 0.070(3) Uani 1 1 d .
N4 N -0.5355(6) 0.0034(8) -0.0258(7) 0.065(3) Uani 1 1 d .
N5 N -0.0071(8) 0.2199(8) 0.0676(7) 0.069(3) Uani 1 1 d .
N6 N 0.2481(8) 0.0853(8) -0.1270(7) 0.075(4) Uani 1 1 d .
N7 N 0.3038(7) -0.0706(9) -0.2124(7) 0.071(4) Uani 1 1 d .
N8 N -0.0551(7) -0.3203(9) -0.4176(7) 0.072(4) Uani 1 1 d .
N9 N 0.5438(7) 0.3462(8) -0.2209(6) 0.064(3) Uani 1 1 d .
N10 N 0.7305(7) 0.6003(10) -0.4183(8) 0.082(4) Uani 1 1 d .
N11 N 0.6530(6) 0.1512(8) -0.1134(6) 0.064(3) Uani 1 1 d .
N12 N 1.0654(7) -0.0250(8) 0.0692(8) 0.076(4) Uani 1 1 d .
N13 N 0.5336(7) 0.2531(8) -0.0398(7) 0.065(3) Uani 1 1 d .
N14 N 0.2756(7) 0.0896(8) 0.1403(7) 0.065(3) Uani 1 1 d .
N15 N 0.2238(7) -0.1184(8) 0.2124(7) 0.069(3) Uani 1 1 d .
N16 N 0.5690(7) -0.3550(10) 0.4066(8) 0.078(4) Uani 1 1 d .
C1 C -0.0586(9) 0.3974(11) 0.2265(9) 0.082(5) Uani 1 1 d .
H1 H -0.1022 0.3976 0.1847 0.098 Uiso 1 1 calc R
C2 C -0.0517(8) 0.4564(11) 0.2770(9) 0.088(6) Uani 1 1 d .
H2 H -0.0911 0.4937 0.2684 0.105 Uiso 1 1 calc R
C3 C 0.0125(8) 0.4609(10) 0.3397(8) 0.065(4) Uani 1 1 d .
C4 C 0.0674(9) 0.4045(11) 0.3455(10) 0.081(5) Uani 1 1 d .
H4 H 0.1128 0.4044 0.3857 0.097 Uiso 1 1 calc R
C5 C 0.0566(11) 0.3473(11) 0.2927(10) 0.087(5) Uani 1 1 d .
H5 H 0.0962 0.3114 0.2985 0.105 Uiso 1 1 calc R
C6 C 0.0866(10) 0.5053(18) 0.4948(11) 0.137(10) Uani 1 1 d .
H6A H 0.1355 0.4920 0.4952 0.205 Uiso 1 1 calc R
H6B H 0.0650 0.4574 0.5063 0.205 Uiso 1 1 calc R
H6C H 0.0926 0.5473 0.5290 0.205 Uiso 1 1 calc R
C7 C 0.0637(13) 0.6324(16) 0.3831(14) 0.152(12) Uani 1 1 d .
H7A H 0.1128 0.6191 0.3839 0.227 Uiso 1 1 calc R
H7B H 0.0692 0.6755 0.4162 0.227 Uiso 1 1 calc R
H7C H 0.0305 0.6500 0.3365 0.227 Uiso 1 1 calc R
C8 C -0.0728(9) 0.5695(10) 0.4043(9) 0.070(5) Uani 1 1 d .
C9 C -0.1024(11) 0.5229(12) 0.4418(12) 0.104(7) Uani 1 1 d .
H9 H -0.0758 0.4779 0.4675 0.125 Uiso 1 1 calc R
C10 C -0.1763(11) 0.5447(13) 0.4407(11) 0.095(6) Uani 1 1 d .
H10 H -0.1969 0.5131 0.4659 0.113 Uiso 1 1 calc R
C11 C -0.1825(10) 0.6494(15) 0.3707(9) 0.096(6) Uani 1 1 d .
H11 H -0.2096 0.6938 0.3443 0.115 Uiso 1 1 calc R
C12 C -0.1150(10) 0.6333(13) 0.3702(10) 0.089(5) Uani 1 1 d .
H12 H -0.0965 0.6678 0.3451 0.107 Uiso 1 1 calc R
C13 C -0.1060(9) 0.0672(10) 0.1960(8) 0.069(4) Uani 1 1 d .
H13 H -0.0553 0.0506 0.2154 0.083 Uiso 1 1 calc R
C14 C -0.1592(8) 0.0118(10) 0.1967(8) 0.069(4) Uani 1 1 d .
H14 H -0.1461 -0.0417 0.2119 0.082 Uiso 1 1 calc R
C15 C -0.2340(8) 0.0402(10) 0.1734(8) 0.067(4) Uani 1 1 d .
C16 C -0.2484(9) 0.1174(11) 0.1504(9) 0.082(5) Uani 1 1 d .
H16 H -0.2979 0.1372 0.1353 0.098 Uiso 1 1 calc R
C17 C -0.1927(9) 0.1684(9) 0.1482(8) 0.071(4) Uani 1 1 d .
H17 H -0.2054 0.2215 0.1314 0.085 Uiso 1 1 calc R
C18 C -0.2798(12) -0.1410(11) 0.1773(13) 0.120(8) Uani 1 1 d .
H18A H -0.2344 -0.1514 0.2190 0.180 Uiso 1 1 calc R
H18B H -0.2698 -0.1507 0.1362 0.180 Uiso 1 1 calc R
H18C H -0.3197 -0.1769 0.1766 0.180 Uiso 1 1 calc R
C19 C -0.3271(14) -0.0078(17) 0.2579(11) 0.134(10) Uani 1 1 d .
H19A H -0.2815 -0.0174 0.2996 0.202 Uiso 1 1 calc R
H19B H -0.3674 -0.0416 0.2592 0.202 Uiso 1 1 calc R
H19C H -0.3413 0.0487 0.2562 0.202 Uiso 1 1 calc R
C20 C -0.3984(7) -0.0155(8) 0.0961(8) 0.057(4) Uani 1 1 d .
C21 C -0.4707(8) -0.0385(10) 0.0952(9) 0.076(4) Uani 1 1 d .
H21 H -0.4747 -0.0591 0.1353 0.091 Uiso 1 1 calc R
C22 C -0.5340(9) -0.0288(10) 0.0330(9) 0.072(4) Uani 1 1 d .
H22 H -0.5802 -0.0467 0.0323 0.086 Uiso 1 1 calc R
C23 C -0.4683(9) 0.0241(11) -0.0250(9) 0.079(5) Uani 1 1 d .
H23 H -0.4673 0.0452 -0.0662 0.095 Uiso 1 1 calc R
C24 C -0.4010(8) 0.0164(11) 0.0320(8) 0.072(4) Uani 1 1 d .
H24 H -0.3560 0.0324 0.0287 0.086 Uiso 1 1 calc R
C25 C -0.0621(10) 0.2369(14) 0.0073(9) 0.095(6) Uani 1 1 d .
H25 H -0.1081 0.2549 0.0072 0.114 Uiso 1 1 calc R
C26 C -0.0565(10) 0.2300(14) -0.0574(9) 0.096(6) Uani 1 1 d .
H26 H -0.0976 0.2448 -0.0987 0.115 Uiso 1 1 calc R
C27 C 0.0080(8) 0.2020(10) -0.0611(8) 0.066(4) Uani 1 1 d .
C28 C 0.0685(9) 0.1851(10) 0.0036(9) 0.069(4) Uani 1 1 d .
H28 H 0.1150 0.1673 0.0047 0.083 Uiso 1 1 calc R
C29 C 0.0590(8) 0.1949(8) 0.0664(9) 0.062(4) Uani 1 1 d .
H29 H 0.1000 0.1839 0.1089 0.074 Uiso 1 1 calc R
C30 C -0.0152(15) 0.2840(18) -0.1980(13) 0.164(14) Uani 1 1 d .
H30A H -0.0142 0.2769 -0.2435 0.245 Uiso 1 1 calc R
H30B H 0.0204 0.3259 -0.1725 0.245 Uiso 1 1 calc R
H30C H -0.0656 0.2998 -0.2038 0.245 Uiso 1 1 calc R
C31 C -0.0578(11) 0.101(2) -0.1916(11) 0.156(13) Uani 1 1 d .
H31A H -0.0599 0.0913 -0.2379 0.235 Uiso 1 1 calc R
H31B H -0.1076 0.1160 -0.1951 0.235 Uiso 1 1 calc R
H31C H -0.0409 0.0527 -0.1635 0.235 Uiso 1 1 calc R
C32 C 0.1076(9) 0.1506(11) -0.1392(7) 0.072(4) Uani 1 1 d .
C33 C 0.1481(9) 0.1868(11) -0.1712(10) 0.084(5) Uani 1 1 d .
H33 H 0.1297 0.2335 -0.1984 0.101 Uiso 1 1 calc R
C34 C 0.2182(9) 0.1532(13) -0.1629(10) 0.087(5) Uani 1 1 d .
H34 H 0.2459 0.1805 -0.1841 0.104 Uiso 1 1 calc R
C35 C 0.2089(11) 0.0513(10) -0.0954(10) 0.082(5) Uani 1 1 d .
H35 H 0.2279 0.0042 -0.0690 0.099 Uiso 1 1 calc R
C36 C 0.1407(11) 0.0822(12) -0.0996(10) 0.093(6) Uani 1 1 d .
H36 H 0.1160 0.0562 -0.0749 0.111 Uiso 1 1 calc R
C37 C 0.3188(9) -0.0679(11) -0.2689(9) 0.074(4) Uani 1 1 d .
H37 H 0.3563 -0.0314 -0.2681 0.089 Uiso 1 1 calc R
C38 C 0.2836(8) -0.1147(10) -0.3297(8) 0.066(4) Uani 1 1 d .
H38 H 0.2967 -0.1082 -0.3679 0.079 Uiso 1 1 calc R
C39 C 0.2285(7) -0.1714(9) -0.3320(7) 0.053(3) Uani 1 1 d .
C40 C 0.2119(9) -0.1748(12) -0.2735(9) 0.083(5) Uani 1 1 d .
H40 H 0.1754 -0.2116 -0.2727 0.100 Uiso 1 1 calc R
C41 C 0.2485(10) -0.1249(11) -0.2162(9) 0.082(5) Uani 1 1 d .
H41 H 0.2347 -0.1283 -0.1783 0.099 Uiso 1 1 calc R
C42 C 0.1731(8) -0.1842(10) -0.4907(7) 0.068(4) Uani 1 1 d .
H42A H 0.1406 -0.1376 -0.4966 0.103 Uiso 1 1 calc R
H42B H 0.1512 -0.2194 -0.5311 0.103 Uiso 1 1 calc R
H42C H 0.2224 -0.1662 -0.4863 0.103 Uiso 1 1 calc R
C43 C 0.2452(10) -0.3309(10) -0.3935(10) 0.086(5) Uani 1 1 d .
H43A H 0.2241 -0.3684 -0.4323 0.129 Uiso 1 1 calc R
H43B H 0.2491 -0.3575 -0.3509 0.129 Uiso 1 1 calc R
H43C H 0.2949 -0.3139 -0.3886 0.129 Uiso 1 1 calc R
C44 C 0.0861(7) -0.2745(9) -0.4147(7) 0.055(3) Uani 1 1 d .
C45 C 0.0211(7) -0.2365(11) -0.4588(8) 0.070(4) Uani 1 1 d .
H45 H 0.0236 -0.1949 -0.4884 0.084 Uiso 1 1 calc R
C46 C -0.0484(8) -0.2596(12) -0.4598(9) 0.081(5) Uani 1 1 d .
H46 H -0.0922 -0.2328 -0.4902 0.097 Uiso 1 1 calc R
C47 C 0.0074(11) -0.3577(12) -0.3755(9) 0.082(5) Uani 1 1 d .
H47 H 0.0037 -0.4000 -0.3471 0.098 Uiso 1 1 calc R
C48 C 0.0796(8) -0.3361(11) -0.3717(8) 0.070(4) Uani 1 1 d .
H48 H 0.1228 -0.3630 -0.3405 0.084 Uiso 1 1 calc R
C49 C 0.4841(11) 0.3406(12) -0.2809(9) 0.093(6) Uani 1 1 d .
H49 H 0.4485 0.2998 -0.2857 0.112 Uiso 1 1 calc R
C50 C 0.4713(11) 0.3906(13) -0.3360(8) 0.095(6) Uani 1 1 d .
H50 H 0.4270 0.3846 -0.3769 0.114 Uiso 1 1 calc R
C51 C 0.5238(7) 0.4517(9) -0.3325(7) 0.053(3) Uani 1 1 d .
C52 C 0.5846(8) 0.4562(11) -0.2711(8) 0.079(5) Uani 1 1 d .
H52 H 0.6227 0.4942 -0.2656 0.095 Uiso 1 1 calc R
C53 C 0.5918(9) 0.4048(10) -0.2153(7) 0.068(4) Uani 1 1 d .
H53 H 0.6328 0.4125 -0.1721 0.082 Uiso 1 1 calc R
C54 C 0.4412(9) 0.4719(11) -0.4897(7) 0.080(5) Uani 1 1 d .
H54A H 0.4686 0.4261 -0.4966 0.120 Uiso 1 1 calc R
H54B H 0.4282 0.5088 -0.5289 0.120 Uiso 1 1 calc R
H54C H 0.3955 0.4530 -0.4864 0.120 Uiso 1 1 calc R
C55 C 0.4570(10) 0.6160(12) -0.3877(10) 0.090(6) Uani 1 1 d .
H55A H 0.4916 0.6402 -0.3443 0.136 Uiso 1 1 calc R
H55B H 0.4111 0.6000 -0.3833 0.136 Uiso 1 1 calc R
H55C H 0.4450 0.6551 -0.4253 0.136 Uiso 1 1 calc R
C56 C 0.5945(8) 0.5543(10) -0.4110(7) 0.060(4) Uani 1 1 d .
C57 C 0.6253(9) 0.6330(12) -0.3890(10) 0.089(5) Uani 1 1 d .
H57 H 0.6022 0.6701 -0.3698 0.106 Uiso 1 1 calc R
C58 C 0.6909(11) 0.6524(13) -0.3971(10) 0.094(5) Uani 1 1 d .
H58 H 0.7089 0.7057 -0.3870 0.113 Uiso 1 1 calc R
C59 C 0.7025(8) 0.5275(12) -0.4360(8) 0.074(4) Uani 1 1 d .
H59 H 0.7293 0.4907 -0.4516 0.089 Uiso 1 1 calc R
C60 C 0.6369(8) 0.5017(9) -0.4334(8) 0.064(4) Uani 1 1 d .
H60 H 0.6200 0.4485 -0.4467 0.077 Uiso 1 1 calc R
C61 C 0.7204(10) 0.1481(13) -0.0599(9) 0.094(5) Uani 1 1 d .
H61 H 0.7348 0.1928 -0.0296 0.113 Uiso 1 1 calc R
C62 C 0.7718(11) 0.0833(11) -0.0452(11) 0.098(7) Uani 1 1 d .
H62 H 0.8184 0.0846 -0.0062 0.118 Uiso 1 1 calc R
C63 C 0.7515(8) 0.0177(9) -0.0900(9) 0.075(4) Uani 1 1 d .
C64 C 0.6826(7) 0.0237(10) -0.1489(7) 0.063(4) Uani 1 1 d .
H64 H 0.6688 -0.0173 -0.1829 0.076 Uiso 1 1 calc R
C65 C 0.6358(8) 0.0877(10) -0.1576(8) 0.063(4) Uani 1 1 d .
H65 H 0.5890 0.0876 -0.1963 0.075 Uiso 1 1 calc R
C66 C 0.7735(10) -0.1505(14) -0.0208(15) 0.133(10) Uani 1 1 d .
H66A H 0.7809 -0.1249 0.0231 0.200 Uiso 1 1 calc R
H66B H 0.8012 -0.2012 -0.0117 0.200 Uiso 1 1 calc R
H66C H 0.7202 -0.1612 -0.0473 0.200 Uiso 1 1 calc R
C67 C 0.8012(11) -0.1199(12) -0.1586(10) 0.110(8) Uani 1 1 d .
H67A H 0.8303 -0.1695 -0.1513 0.166 Uiso 1 1 calc R
H67B H 0.8203 -0.0802 -0.1815 0.166 Uiso 1 1 calc R
H67C H 0.7487 -0.1312 -0.1878 0.166 Uiso 1 1 calc R
C68 C 0.9124(7) -0.0548(9) -0.0165(8) 0.067(4) Uani 1 1 d .
C69 C 0.9676(9) -0.0658(11) -0.0398(9) 0.078(5) Uani 1 1 d .
H69 H 0.9539 -0.0832 -0.0861 0.094 Uiso 1 1 calc R
C70 C 1.0437(9) -0.0525(12) 0.0018(11) 0.088(6) Uani 1 1 d .
H70 H 1.0801 -0.0623 -0.0161 0.106 Uiso 1 1 calc R
C71 C 1.0119(10) -0.0147(12) 0.0940(10) 0.092(6) Uani 1 1 d .
H71 H 1.0255 0.0025 0.1402 0.110 Uiso 1 1 calc R
C72 C 0.9357(8) -0.0296(12) 0.0505(11) 0.094(6) Uani 1 1 d .
H72 H 0.8993 -0.0217 0.0688 0.113 Uiso 1 1 calc R
C73 C 0.4612(10) 0.2428(11) -0.0479(8) 0.081(5) Uani 1 1 d .
H73 H 0.4232 0.2347 -0.0928 0.097 Uiso 1 1 calc R
C74 C 0.4423(9) 0.2441(11) 0.0105(7) 0.074(5) Uani 1 1 d .
H74 H 0.3915 0.2392 0.0033 0.088 Uiso 1 1 calc R
C75 C 0.4964(7) 0.2525(9) 0.0775(7) 0.052(3) Uani 1 1 d .
C76 C 0.5708(8) 0.2629(11) 0.0826(7) 0.070(4) Uani 1 1 d .
H76 H 0.6104 0.2703 0.1267 0.084 Uiso 1 1 calc R
C77 C 0.5867(10) 0.2624(12) 0.0232(9) 0.079(5) Uani 1 1 d .
H77 H 0.6369 0.2690 0.0286 0.095 Uiso 1 1 calc R
C78 C 0.4584(10) 0.3708(10) 0.1706(10) 0.083(5) Uani 1 1 d .
H78A H 0.4142 0.3880 0.1302 0.124 Uiso 1 1 calc R
H78B H 0.5012 0.4041 0.1747 0.124 Uiso 1 1 calc R
H78C H 0.4490 0.3766 0.2123 0.124 Uiso 1 1 calc R
C79 C 0.5616(8) 0.2242(12) 0.2350(8) 0.078(5) Uani 1 1 d .
H79A H 0.6050 0.2579 0.2418 0.117 Uiso 1 1 calc R
H79B H 0.5721 0.1687 0.2266 0.117 Uiso 1 1 calc R
H79C H 0.5512 0.2263 0.2764 0.117 Uiso 1 1 calc R
C80 C 0.3972(7) 0.1938(7) 0.1495(6) 0.047(3) Uani 1 1 d .
C81 C 0.3755(10) 0.1272(10) 0.1065(8) 0.076(4) Uani 1 1 d .
H81 H 0.4017 0.1145 0.0787 0.092 Uiso 1 1 calc R
C82 C 0.3147(10) 0.0773(11) 0.1028(9) 0.077(5) Uani 1 1 d .
H82 H 0.3017 0.0330 0.0720 0.093 Uiso 1 1 calc R
C83 C 0.2941(8) 0.1563(10) 0.1837(8) 0.065(4) Uani 1 1 d .
H83 H 0.2660 0.1676 0.2101 0.078 Uiso 1 1 calc R
C84 C 0.3541(7) 0.2078(9) 0.1895(8) 0.062(4) Uani 1 1 d .
H84 H 0.3659 0.2522 0.2202 0.074 Uiso 1 1 calc R
C85 C 0.2423(9) -0.1857(9) 0.1908(8) 0.065(4) Uani 1 1 d .
H85 H 0.2404 -0.1880 0.1453 0.077 Uiso 1 1 calc R
C86 C 0.2655(9) -0.2560(10) 0.2342(7) 0.070(4) Uani 1 1 d .
H86 H 0.2755 -0.3042 0.2157 0.084 Uiso 1 1 calc R
C87 C 0.2735(8) -0.2548(9) 0.3018(8) 0.062(4) Uani 1 1 d .
C88 C 0.2524(9) -0.1820(11) 0.3244(8) 0.077(5) Uani 1 1 d .
H88 H 0.2543 -0.1782 0.3698 0.092 Uiso 1 1 calc R
C89 C 0.2288(11) -0.1157(11) 0.2795(10) 0.090(5) Uani 1 1 d .
H89 H 0.2158 -0.0675 0.2957 0.108 Uiso 1 1 calc R
C90 C 0.2636(9) -0.4434(10) 0.3157(11) 0.096(6) Uani 1 1 d .
H90A H 0.2102 -0.4425 0.3056 0.143 Uiso 1 1 calc R
H90B H 0.2872 -0.4892 0.3457 0.143 Uiso 1 1 calc R
H90C H 0.2702 -0.4482 0.2725 0.143 Uiso 1 1 calc R
C91 C 0.2951(10) -0.3275(14) 0.4440(9) 0.096(7) Uani 1 1 d .
H91A H 0.2416 -0.3249 0.4331 0.145 Uiso 1 1 calc R
H91B H 0.3187 -0.2766 0.4647 0.145 Uiso 1 1 calc R
H91C H 0.3178 -0.3712 0.4767 0.145 Uiso 1 1 calc R
C92 C 0.4102(8) -0.3511(9) 0.3790(7) 0.059(3) Uani 1 1 d .
C93 C 0.4415(9) -0.4156(10) 0.3529(8) 0.066(4) Uani 1 1 d .
H93 H 0.4112 -0.4582 0.3264 0.079 Uiso 1 1 calc R
C94 C 0.5196(11) -0.4125(12) 0.3686(10) 0.084(5) Uani 1 1 d .
H94 H 0.5391 -0.4547 0.3508 0.101 Uiso 1 1 calc R
C95 C 0.5380(9) -0.2973(14) 0.4314(10) 0.093(6) Uani 1 1 d .
H95 H 0.5692 -0.2549 0.4573 0.112 Uiso 1 1 calc R
C96 C 0.4633(10) -0.2962(11) 0.4214(9) 0.084(5) Uani 1 1 d .
H96 H 0.4475 -0.2563 0.4444 0.101 Uiso 1 1 calc R
N17 N 0.7593(8) 0.3661(8) 0.0007(9) 0.076(4) Uani 1 1 d .
N18 N 0.5739(15) 0.3563(14) 0.4185(12) 0.115(6) Uani 1 1 d .
N19 N 0.4099(12) 0.1396(12) -0.2171(9) 0.100(5) Uani 1 1 d .
O1 O 0.4495(11) 0.088(2) -0.1813(13) 0.201(11) Uani 1 1 d .
O2 O 0.5467(12) 0.3794(14) 0.3605(11) 0.153(7) Uani 1 1 d .
O3 O 0.7882(12) 0.3994(15) -0.0311(11) 0.174(9) Uani 1 1 d .
O4 O 0.7954(12) 0.3328(11) 0.0538(8) 0.158(8) Uani 1 1 d .
O5 O 0.6935(11) 0.3747(16) -0.0247(15) 0.214(12) Uani 1 1 d .
O6 O 0.5315(17) 0.3290(14) 0.4444(13) 0.192(10) Uani 1 1 d .
O7 O 0.6408(13) 0.3575(19) 0.4551(11) 0.198(12) Uani 1 1 d .
O8 O 0.3519(12) 0.1402(18) -0.2113(13) 0.190(10) Uani 1 1 d .
O9 O 0.4373(19) 0.1774(16) -0.2387(16) 0.273(17) Uani 1 1 d .
N20 N 0.1271(8) 0.1251(12) 0.2461(7) 0.080(4) Uani 1 1 d .
O10 O 0.1500(11) 0.1935(11) 0.2371(10) 0.136(6) Uani 1 1 d .
O11 O 0.0724(8) 0.1226(16) 0.2561(9) 0.165(8) Uani 1 1 d .
O12 O 0.1689(12) 0.0712(10) 0.2452(10) 0.151(7) Uani 1 1 d .
N21 N 0.742(3) 0.825(3) 0.496(2) 0.21(2) Uani 1 1 d .
013 O 0.7409(12) 0.903(2) 0.5055(17) 0.240(14) Uani 1 1 d .
O14 O 0.705(2) 0.797(2) 0.441(3) 0.37(3) Uani 1 1 d .
O15 O 0.768(2) 0.804(3) 0.548(3) 0.48(5) Uani 1 1 d .
N22 N -0.0504(16) -0.132(2) -0.6556(16) 0.185(11) Uani 1 1 d .
O16 O -0.0973(15) -0.1691(15) -0.6940(15) 0.246(12) Uani 1 1 d .
O17 O -0.022(2) -0.069(3) -0.677(3) 0.45(2) Uani 1 1 d .
O18 O -0.0054(18) -0.121(2) -0.6037(13) 0.269(15) Uani 1 1 d .
OW1 O 0.3765(10) 0.3762(13) 0.3087(9) 0.081(7) Uani 0.50 1 d P
OW2 O 0.1177(10) 0.9743(12) 0.3738(10) 0.153(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N5 126.8(5) . .
N1 Ag1 N3 114.6(5) . .
N5 Ag1 N3 112.5(4) . .
N4 Ag2 N7 126.2(4) 1_655 .
N4 Ag2 N6 125.4(5) 1_655 .
N7 Ag2 N6 99.6(5) . .
N10 Ag3 N8 176.7(6) 1_445 .
N9 Ag4 N13 133.5(4) . .
N9 Ag4 N11 121.2(4) . .
N13 Ag4 N11 104.6(4) . .
N14 Ag5 N12 132.4(5) . 1_455
N14 Ag5 N15 123.1(4) . .
N12 Ag5 N15 103.5(5) 1_455 .
N2 Ag6 N16 160.1(6) 1_645 .
N2 Ag6 O14 103.9(13) 1_645 1_545
N16 Ag6 O14 95.9(12) . 1_545
C7 Si1 C8 108.5(10) . .
C7 Si1 C6 110.5(13) . .
C8 Si1 C6 110.8(8) . .
C7 Si1 C3 107.3(8) . .
C8 Si1 C3 109.8(7) . .
C6 Si1 C3 109.9(9) . .
C18 Si2 C20 108.4(8) . .
C18 Si2 C19 112.5(12) . .
C20 Si2 C19 109.8(10) . .
C18 Si2 C15 110.9(9) . .
C20 Si2 C15 106.8(6) . .
C19 Si2 C15 108.2(8) . .
C30 Si3 C27 109.0(9) . .
C30 Si3 C31 113.6(13) . .
C27 Si3 C31 105.2(9) . .
C30 Si3 C32 111.6(10) . .
C27 Si3 C32 111.0(7) . .
C31 Si3 C32 106.3(10) . .
C43 Si4 C42 112.7(8) . .
C43 Si4 C39 106.5(7) . .
C42 Si4 C39 108.3(7) . .
C43 Si4 C44 109.2(8) . .
C42 Si4 C44 111.1(6) . .
C39 Si4 C44 108.9(6) . .
C54 Si5 C55 114.5(8) . .
C54 Si5 C51 107.8(7) . .
C55 Si5 C51 107.6(7) . .
C54 Si5 C56 109.3(7) . .
C55 Si5 C56 110.3(8) . .
C51 Si5 C56 107.1(6) . .
C67 Si6 C63 108.4(8) . .
C67 Si6 C66 115.3(12) . .
C63 Si6 C66 106.7(9) . .
C67 Si6 C68 110.0(9) . .
C63 Si6 C68 108.6(7) . .
C66 Si6 C68 107.6(9) . .
C79 Si7 C75 110.3(7) . .
C79 Si7 C80 107.4(7) . .
C75 Si7 C80 107.7(6) . .
C79 Si7 C78 111.9(9) . .
C75 Si7 C78 108.1(7) . .
C80 Si7 C78 111.4(6) . .
C92 Si8 C90 107.4(8) . .
C92 Si8 C91 111.5(7) . .
C90 Si8 C91 113.2(10) . .
C92 Si8 C87 103.6(6) . .
C90 Si8 C87 111.6(7) . .
C91 Si8 C87 109.1(8) . .
C5 N1 C1 115.8(13) . .
C5 N1 Ag1 119.3(11) . .
C1 N1 Ag1 124.3(10) . .
C10 N2 C11 117.2(14) . .
C10 N2 Ag6 121.1(12) . 1_465
C11 N2 Ag6 121.4(13) . 1_465
C13 N3 C17 116.1(14) . .
C13 N3 Ag1 122.3(10) . .
C17 N3 Ag1 121.4(11) . .
C22 N4 C23 115.7(14) . .
C22 N4 Ag2 123.5(9) . 1_455
C23 N4 Ag2 120.7(12) . 1_455
C25 N5 C29 116.9(13) . .
C25 N5 Ag1 120.1(10) . .
C29 N5 Ag1 122.9(11) . .
C35 N6 C34 115.4(14) . .
C35 N6 Ag2 119.4(11) . .
C34 N6 Ag2 125.1(12) . .
C37 N7 C41 114.7(13) . .
C37 N7 Ag2 120.8(11) . .
C41 N7 Ag2 124.0(11) . .
C47 N8 C46 117.8(13) . .
C47 N8 Ag3 120.1(11) . .
C46 N8 Ag3 122.2(11) . .
C49 N9 C53 116.8(14) . .
C49 N9 Ag4 122.1(12) . .
C53 N9 Ag4 121.1(10) . .
C59 N10 C58 117.0(14) . .
C59 N10 Ag3 124.9(13) . 1_665
C58 N10 Ag3 118.1(13) . 1_665
C61 N11 C65 115.6(14) . .
C61 N11 Ag4 124.7(12) . .
C65 N11 Ag4 119.7(9) . .
C71 N12 C70 118.3(14) . .
C71 N12 Ag5 119.5(12) . 1_655
C70 N12 Ag5 122.1(11) . 1_655
C77 N13 C73 119.3(13) . .
C77 N13 Ag4 118.9(10) . .
C73 N13 Ag4 121.8(11) . .
C82 N14 C83 117.4(13) . .
C82 N14 Ag5 120.8(11) . .
C83 N14 Ag5 121.5(9) . .
C85 N15 C89 118.1(14) . .
C85 N15 Ag5 121.4(11) . .
C89 N15 Ag5 120.4(11) . .
C95 N16 C94 113.8(14) . .
C95 N16 Ag6 125.0(13) . .
C94 N16 Ag6 120.7(12) . .
N1 C1 C2 123.4(14) . .
C1 C2 C3 121.3(14) . .
C4 C3 C2 114.1(13) . .
C4 C3 Si1 124.2(12) . .
C2 C3 Si1 121.7(12) . .
C3 C4 C5 121.3(15) . .
N1 C5 C4 123.8(16) . .
C12 C8 C9 115.7(15) . .
C12 C8 Si1 125.6(13) . .
C9 C8 Si1 118.7(14) . .
C8 C9 C10 119.0(19) . .
N2 C10 C9 121.1(17) . .
N2 C11 C12 124.6(19) . .
C8 C12 C11 122.4(18) . .
C14 C13 N3 125.6(14) . .
C13 C14 C15 116.4(15) . .
C16 C15 C14 118.1(14) . .
C16 C15 Si2 124.0(12) . .
C14 C15 Si2 117.9(12) . .
C15 C16 C17 122.3(15) . .
C16 C17 N3 121.3(15) . .
C24 C20 C21 115.0(13) . .
C24 C20 Si2 125.3(10) . .
C21 C20 Si2 119.5(12) . .
C22 C21 C20 117.6(15) . .
N4 C22 C21 126.4(14) . .
N4 C23 C24 124.4(17) . .
C20 C24 C23 120.7(14) . .
N5 C25 C26 123.9(15) . .
C25 C26 C27 120.9(16) . .
C26 C27 C28 115.9(15) . .
C26 C27 Si3 119.4(12) . .
C28 C27 Si3 124.7(11) . .
C29 C28 C27 119.9(14) . .
C28 C29 N5 122.4(15) . .
C33 C32 C36 115.5(15) . .
C33 C32 Si3 123.4(14) . .
C36 C32 Si3 121.1(13) . .
C32 C33 C34 119.3(16) . .
N6 C34 C33 124.8(15) . .
N6 C35 C36 122.9(16) . .
C35 C36 C32 122.1(16) . .
N7 C37 C38 126.0(15) . .
C39 C38 C37 118.5(13) . .
C40 C39 C38 116.3(13) . .
C40 C39 Si4 122.6(11) . .
C38 C39 Si4 121.0(10) . .
C41 C40 C39 121.1(15) . .
N7 C41 C40 123.3(15) . .
C45 C44 C48 117.8(13) . .
C45 C44 Si4 120.9(11) . .
C48 C44 Si4 121.3(11) . .
C44 C45 C46 120.1(15) . .
N8 C46 C45 122.2(15) . .
N8 C47 C48 122.4(15) . .
C44 C48 C47 119.6(14) . .
N9 C49 C50 123.5(17) . .
C49 C50 C51 120.8(16) . .
C52 C51 C50 114.9(13) . .
C52 C51 Si5 124.8(12) . .
C50 C51 Si5 120.0(11) . .
C53 C52 C51 120.8(15) . .
N9 C53 C52 122.9(13) . .
C60 C56 C57 116.5(13) . .
C60 C56 Si5 123.8(11) . .
C57 C56 Si5 119.6(12) . .
C58 C57 C56 117.0(17) . .
N10 C58 C57 124.8(19) . .
N10 C59 C60 124.1(16) . .
C59 C60 C56 120.3(15) . .
N11 C61 C62 125.4(16) . .
C61 C62 C63 117.7(15) . .
C64 C63 C62 116.6(14) . .
C64 C63 Si6 119.7(12) . .
C62 C63 Si6 123.6(12) . .
C65 C64 C63 121.2(15) . .
N11 C65 C64 123.3(13) . .
C69 C68 C72 115.9(13) . .
C69 C68 Si6 121.4(12) . .
C72 C68 Si6 122.6(13) . .
C68 C69 C70 122.9(17) . .
N12 C70 C69 119.9(18) . .
N12 C71 C72 120.0(17) . .
C68 C72 C71 123.0(17) . .
N13 C73 C74 120.8(14) . .
C75 C74 C73 121.7(14) . .
C74 C75 C76 114.8(12) . .
C74 C75 Si7 126.6(10) . .
C76 C75 Si7 118.2(10) . .
C77 C76 C75 121.4(14) . .
N13 C77 C76 121.9(15) . .
C81 C80 C84 114.8(13) . .
C81 C80 Si7 124.5(11) . .
C84 C80 Si7 120.7(10) . .
C80 C81 C82 121.8(15) . .
N14 C82 C81 123.4(15) . .
N14 C83 C84 121.5(13) . .
C83 C84 C80 121.1(13) . .
N15 C85 C86 122.0(14) . .
C87 C86 C85 121.5(14) . .
C86 C87 C88 115.9(14) . .
C86 C87 Si8 122.1(11) . .
C88 C87 Si8 122.0(11) . .
C89 C88 C87 120.1(14) . .
N15 C89 C88 122.3(16) . .
C96 C92 C93 114.1(13) . .
C96 C92 Si8 123.3(12) . .
C93 C92 Si8 122.5(12) . .
C94 C93 C92 117.5(15) . .
N16 C94 C93 126.7(16) . .
N16 C95 C96 124.2(19) . .
C95 C96 C92 123.3(17) . .
O3 N17 O4 121.2(19) . .
O3 N17 O5 112(2) . .
O4 N17 O5 127(2) . .
O2 N18 O7 124(3) . .
O2 N18 O6 118(3) . .
O7 N18 O6 118(3) . .
O9 N19 O8 136(3) . .
O9 N19 O1 113(3) . .
O8 N19 O1 110(2) . .
O11 N20 O10 118(2) . .
O11 N20 O12 130(2) . .
O10 N20 O12 112.2(18) . .
O15 N21 O14 137(7) . .
O15 N21 013 101(5) . .
O14 N21 013 120(6) . .
N21 013 O15 35(3) . .
N21 O14 Ag6 127(4) . 1_565
N21 O15 013 45(3) . .
O16 N22 O18 152(4) . .
O16 N22 O17 121(4) . .
O18 N22 O17 86(3) . .
N22 O17 O18 41(2) . .
N22 O18 O17 53(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.212(11) .
Ag1 N5 2.256(13) .
Ag1 N3 2.340(12) .
Ag2 N4 2.237(12) 1_655
Ag2 N7 2.280(12) .
Ag2 N6 2.315(13) .
Ag3 N10 2.168(13) 1_445
Ag3 N8 2.148(13) .
Ag4 N9 2.226(12) .
Ag4 N13 2.272(11) .
Ag4 N11 2.323(12) .
Ag5 N14 2.236(13) .
Ag5 N12 2.288(12) 1_455
Ag5 N15 2.313(13) .
Ag6 N2 2.158(12) 1_645
Ag6 N16 2.138(12) .
Ag6 O14 2.51(4) 1_545
Si1 C7 1.83(2) .
Si1 C8 1.880(15) .
Si1 C6 1.83(2) .
Si1 C3 1.873(14) .
Si2 C18 1.85(2) .
Si2 C20 1.873(14) .
Si2 C19 1.88(2) .
Si2 C15 1.916(15) .
Si3 C30 1.83(2) .
Si3 C27 1.859(16) .
Si3 C31 1.89(3) .
Si3 C32 1.886(16) .
Si4 C43 1.837(16) .
Si4 C42 1.858(15) .
Si4 C39 1.878(14) .
Si4 C44 1.901(13) .
Si5 C54 1.848(16) .
Si5 C55 1.833(19) .
Si5 C51 1.877(14) .
Si5 C56 1.877(14) .
Si6 C67 1.83(2) .
Si6 C63 1.895(15) .
Si6 C66 1.91(2) .
Si6 C68 1.889(13) .
Si7 C79 1.814(15) .
Si7 C75 1.869(13) .
Si7 C80 1.868(13) .
Si7 C78 1.867(17) .
Si8 C92 1.829(14) .
Si8 C90 1.876(19) .
Si8 C91 1.860(17) .
Si8 C87 1.883(15) .
N1 C5 1.31(2) .
N1 C1 1.32(2) .
N2 C10 1.29(2) .
N2 C11 1.31(2) .
N2 Ag6 2.158(12) 1_465
N3 C13 1.34(2) .
N3 C17 1.331(19) .
N4 C22 1.318(19) .
N4 C23 1.329(19) .
N4 Ag2 2.237(12) 1_455
N5 C25 1.30(2) .
N5 C29 1.345(19) .
N6 C35 1.31(2) .
N6 C34 1.33(2) .
N7 C37 1.32(2) .
N7 C41 1.36(2) .
N8 C47 1.31(2) .
N8 C46 1.36(2) .
N9 C49 1.31(2) .
N9 C53 1.302(19) .
N10 C59 1.30(2) .
N10 C58 1.33(2) .
N10 Ag3 2.168(12) 1_665
N11 C61 1.32(2) .
N11 C65 1.334(19) .
N12 C71 1.33(2) .
N12 C70 1.36(2) .
N12 Ag5 2.288(12) 1_655
N13 C77 1.30(2) .
N13 C73 1.34(2) .
N14 C82 1.30(2) .
N14 C83 1.37(2) .
N15 C85 1.291(19) .
N15 C89 1.36(2) .
N16 C95 1.33(2) .
N16 C94 1.34(2) .
C1 C2 1.39(2) .
C2 C3 1.38(2) .
C3 C4 1.37(2) .
C4 C5 1.39(2) .
C8 C12 1.33(2) .
C8 C9 1.37(2) .
C9 C10 1.46(2) .
C11 C12 1.33(2) .
C13 C14 1.37(2) .
C14 C15 1.40(2) .
C15 C16 1.34(2) .
C16 C17 1.37(2) .
C20 C24 1.41(2) .
C20 C21 1.433(19) .
C21 C22 1.38(2) .
C23 C24 1.36(2) .
C25 C26 1.40(2) .
C26 C27 1.35(2) .
C27 C28 1.40(2) .
C28 C29 1.40(2) .
C32 C33 1.35(2) .
C32 C36 1.38(2) .
C33 C34 1.40(2) .
C35 C36 1.37(2) .
C37 C38 1.39(2) .
C38 C39 1.39(2) .
C39 C40 1.38(2) .
C40 C41 1.37(2) .
C44 C45 1.36(2) .
C44 C48 1.38(2) .
C45 C46 1.38(2) .
C47 C48 1.40(2) .
C49 C50 1.34(2) .
C50 C51 1.40(2) .
C51 C52 1.334(18) .
C52 C53 1.39(2) .
C56 C60 1.39(2) .
C56 C57 1.41(2) .
C57 C58 1.38(2) .
C59 C60 1.352(19) .
C61 C62 1.40(3) .
C62 C63 1.37(2) .
C63 C64 1.393(19) .
C64 C65 1.34(2) .
C68 C69 1.35(2) .
C68 C72 1.34(2) .
C69 C70 1.38(2) .
C71 C72 1.39(2) .
C73 C74 1.40(2) .
C74 C75 1.361(19) .
C75 C76 1.402(18) .
C76 C77 1.38(2) .
C80 C81 1.36(2) .
C80 C84 1.409(18) .
C81 C82 1.40(2) .
C83 C84 1.393(19) .
C85 C86 1.42(2) .
C86 C87 1.347(19) .
C87 C88 1.40(2) .
C88 C89 1.38(2) .
C92 C96 1.37(2) .
C92 C93 1.43(2) .
C93 C94 1.40(2) .
C95 C96 1.36(2) .
N17 O3 1.157(19) .
N17 O4 1.171(18) .
N17 O5 1.16(2) .
N18 O2 1.16(2) .
N18 O7 1.20(3) .
N18 O6 1.23(3) .
N19 O9 1.03(2) .
N19 O8 1.17(2) .
N19 O1 1.18(3) .
N20 O11 1.152(18) .
N20 O10 1.24(2) .
N20 O12 1.20(2) .
N21 O15 1.05(5) .
N21 O14 1.15(4) .
N21 013 1.30(5) .
013 O15 1.81(5) .
O14 Ag6 2.51(4) 1_565
N22 O16 1.11(3) .
N22 O18 1.09(3) .
N22 O17 1.31(5) .
O17 O18 1.65(5) .
