#------------------------------------------------------------------------------
#$Date: 2016-03-22 11:56:50 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178925 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/54/4115425.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4115425
loop_
_publ_author_name
'Tadashi Yamaguchi'
'Fumie Yamazaki'
'Tasuku Ito'
_publ_contact_author_address
;
Department of Chemistry, Graduate School of Science,
Tohoku University,Sendai  980-8578, JAPAN
;
_publ_contact_author_email       ' yamaguchi@agnus.chem.tohoku.ac.jp '
_publ_contact_author_fax         ' +81 22 217 6548 '
_publ_contact_author_name        ' Tadashi YAMAGUCHI '
_publ_contact_author_phone       ' +81 22 217 6544 '
_publ_section_title
;
 A Helical Metal-Metal Bonded Chain via the Pt\\rightarrowAg Dative Bond
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              743
_journal_page_last               744
_journal_paper_doi               10.1021/ja002906a
_journal_volume                  123
_journal_year                    2001
_chemical_formula_sum            'C53 H50 Ag2 Cl2 N4 O11 Pt2'
_chemical_formula_weight         1595.79
_space_group_IT_number           169
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 61'
_symmetry_space_group_name_H-M   'P 61'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   14.8050(6)
_cell_length_b                   14.8050(6)
_cell_length_c                   41.608(2)
_cell_measurement_temperature    203(2)
_cell_volume                     7898.1(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    ORTEP
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF PATTY'
_diffrn_ambient_temperature      203(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0442
_diffrn_reflns_av_sigmaI/netI    0.0577
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       53
_diffrn_reflns_limit_l_min       -52
_diffrn_reflns_number            40720
_diffrn_reflns_theta_full        27.58
_diffrn_reflns_theta_max         27.58
_diffrn_reflns_theta_min         1.59
_exptl_absorpt_coefficient_mu    6.195
_exptl_absorpt_correction_T_max  0.525878
_exptl_absorpt_correction_T_min  0.400611
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.013
_exptl_crystal_description       'hexagonal prism'
_exptl_crystal_F_000             4608
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.131
_refine_diff_density_min         -0.993
_refine_diff_density_rms         0.116
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.006(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.748
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     667
_refine_ls_number_reflns         12042
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.748
_refine_ls_R_factor_all          0.0579
_refine_ls_R_factor_gt           0.0405
_refine_ls_shift/su_max          0.046
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1035
_refine_ls_wR_factor_ref         0.1132
_reflns_number_gt                9611
_reflns_number_total             12042
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja002906a_1.cif
_cod_data_source_block           PtphAgClO4
_cod_database_code               4115425
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z+1/3'
'-x+y, -x, z+2/3'
'-x, -y, z+1/2'
'y, -x+y, z+5/6'
'x-y, x, z+1/6'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
Pt1 Pt 0.27977(3) 0.26688(3) 0.695394(8) 0.04449(10) Uani 1 1 d
Pt2 Pt 0.21541(3) 0.48199(3) 0.764827(9) 0.03765(9) Uani 1 1 d
Ag1 Ag 0.40060(7) 0.34564(8) 0.63937(2) 0.0576(2) Uani 1 1 d
Ag2 Ag 0.34859(6) 0.40789(6) 0.746792(19) 0.05128(19) Uani 1 1 d
Cl1 Cl 0.5625(2) 0.5262(2) 0.91800(7) 0.0622(7) Uani 1 1 d
Cl2 Cl -0.0720(3) -0.2380(5) 0.69251(11) 0.139(3) Uani 1 1 d
O1 O 0.5634(7) 0.5037(7) 0.6283(2) 0.071(2) Uani 1 1 d
O2 O 0.4861(7) 0.5775(7) 0.7598(2) 0.071(2) Uani 1 1 d
O3 O -0.3315(14) -0.1706(12) 0.6499(3) 0.135(5) Uani 1 1 d
O4 O 0.5958(17) 0.5192(15) 0.8853(4) 0.179(8) Uani 1 1 d
O5 O 0.5097(11) 0.4214(10) 0.9254(5) 0.147(6) Uani 1 1 d
O6 O 0.5032(15) 0.5672(13) 0.9158(4) 0.182(9) Uani 1 1 d
O7 O 0.6545(11) 0.5871(11) 0.9354(4) 0.137(5) Uani 1 1 d
O8 O 0.0296(12) -0.1856(16) 0.6940(5) 0.185(8) Uani 1 1 d
O9 O -0.098(2) -0.213(4) 0.7240(5) 0.31(2) Uani 1 1 d
O10 O -0.1259(13) -0.2225(16) 0.6671(3) 0.153(6) Uani 1 1 d
O11 O -0.119(3) -0.3310(14) 0.6981(12) 0.46(4) Uani 1 1 d
N1 N 0.2520(7) 0.1474(6) 0.72841(18) 0.0428(18) Uani 1 1 d
N2 N 0.1427(7) 0.1880(9) 0.6664(2) 0.057(3) Uani 1 1 d
N3 N 0.2158(7) 0.5799(6) 0.7278(2) 0.0453(18) Uani 1 1 d
N4 N 0.3066(6) 0.5941(6) 0.80041(19) 0.0422(18) Uani 1 1 d
C1 C 0.4267(8) 0.3266(8) 0.7149(2) 0.045(2) Uani 1 1 d
C2 C 0.5191(8) 0.4171(8) 0.7063(3) 0.050(2) Uani 1 1 d
H1 H 0.5154 0.4652 0.6915 0.050 Uiso 1 1 d
C3 C 0.6147(9) 0.4397(9) 0.7186(3) 0.059(3) Uani 1 1 d
H2 H 0.6776 0.5032 0.7125 0.059 Uiso 1 1 d
C4 C 0.6183(9) 0.3709(10) 0.7402(3) 0.066(3) Uani 1 1 d
H3 H 0.6857 0.3869 0.7485 0.066 Uiso 1 1 d
C5 C 0.5313(9) 0.2826(9) 0.7494(3) 0.059(3) Uani 1 1 d
H4 H 0.5358 0.2369 0.7654 0.059 Uiso 1 1 d
C6 C 0.4348(8) 0.2578(8) 0.7359(2) 0.042(2) Uani 1 1 d
C7 C 0.3392(8) 0.1595(7) 0.7435(2) 0.045(2) Uani 1 1 d
C8 C 0.3362(9) 0.0842(9) 0.7635(3) 0.058(3) Uani 1 1 d
H5 H 0.3994 0.0916 0.7719 0.058 Uiso 1 1 d
C9 C 0.2378(12) -0.0026(10) 0.7714(3) 0.068(3) Uani 1 1 d
H6 H 0.2335 -0.0576 0.7861 0.068 Uiso 1 1 d
C10 C 0.1502(10) -0.0106(9) 0.7571(3) 0.065(3) Uani 1 1 d
H7 H 0.0820 -0.0692 0.7619 0.065 Uiso 1 1 d
C11 C 0.1592(8) 0.0662(8) 0.7358(3) 0.047(2) Uani 1 1 d
H8 H 0.0977 0.0612 0.7264 0.047 Uiso 1 1 d
C12 C 0.2898(11) 0.3851(11) 0.6698(3) 0.065(3) Uani 1 1 d
C13 C 0.3587(12) 0.4941(12) 0.6744(3) 0.076(4) Uani 1 1 d
H9 H 0.4144 0.5169 0.6907 0.076 Uiso 1 1 d
C14 C 0.3517(14) 0.5700(14) 0.6580(4) 0.100(6) Uani 1 1 d
H10 H 0.4025 0.6433 0.6610 0.100 Uiso 1 1 d
C15 C 0.272(2) 0.542(2) 0.6363(5) 0.142(11) Uani 1 1 d
H11 H 0.2623 0.5937 0.6262 0.142 Uiso 1 1 d
C16 C 0.1973(17) 0.435(2) 0.6307(5) 0.124(9) Uani 1 1 d
H12 H 0.1423 0.4147 0.6149 0.124 Uiso 1 1 d
C17 C 0.2078(13) 0.3585(15) 0.6480(3) 0.080(5) Uani 1 1 d
C18 C 0.1330(12) 0.2505(17) 0.6462(3) 0.085(5) Uani 1 1 d
C19 C 0.0474(14) 0.203(2) 0.6231(4) 0.100(6) Uani 1 1 d
H13 H 0.0383 0.2491 0.6083 0.100 Uiso 1 1 d
C20 C -0.0195(15) 0.098(2) 0.6233(4) 0.125(9) Uani 1 1 d
H14 H -0.0806 0.0659 0.6097 0.125 Uiso 1 1 d
C21 C -0.0024(10) 0.0362(14) 0.6437(3) 0.086(5) Uani 1 1 d
H15 H -0.0465 -0.0420 0.6442 0.086 Uiso 1 1 d
C22 C 0.0836(10) 0.0898(13) 0.6642(3) 0.072(4) Uani 1 1 d
H16 H 0.1013 0.0484 0.6788 0.072 Uiso 1 1 d
C23 C 0.1003(7) 0.3748(7) 0.7368(2) 0.043(2) Uani 1 1 d
C24 C 0.0363(8) 0.2686(9) 0.7413(3) 0.056(3) Uani 1 1 d
H17 H 0.0487 0.2370 0.7597 0.056 Uiso 1 1 d
C25 C -0.0420(9) 0.2081(9) 0.7205(3) 0.059(3) Uani 1 1 d
H18 H -0.0837 0.1342 0.7245 0.059 Uiso 1 1 d
C26 C -0.0615(9) 0.2495(10) 0.6944(3) 0.064(3) Uani 1 1 d
H19 H -0.1142 0.2049 0.6794 0.064 Uiso 1 1 d
C27 C -0.0027(8) 0.3574(9) 0.6880(2) 0.053(3) Uani 1 1 d
H20 H -0.0164 0.3888 0.6696 0.053 Uiso 1 1 d
C28 C 0.0753(8) 0.4177(8) 0.7104(2) 0.044(2) Uani 1 1 d
C29 C 0.1387(8) 0.5327(8) 0.7059(3) 0.051(2) Uani 1 1 d
C30 C 0.1252(11) 0.5932(10) 0.6824(3) 0.070(4) Uani 1 1 d
H21 H 0.0667 0.5614 0.6682 0.070 Uiso 1 1 d
C31 C 0.1950(11) 0.6962(10) 0.6798(3) 0.071(4) Uani 1 1 d
H22 H 0.1853 0.7371 0.6639 0.071 Uiso 1 1 d
C32 C 0.2789(12) 0.7420(8) 0.7004(3) 0.076(4) Uani 1 1 d
H23 H 0.3323 0.8133 0.6978 0.076 Uiso 1 1 d
C33 C 0.2882(8) 0.6797(8) 0.7241(3) 0.052(3) Uani 1 1 d
H24 H 0.3456 0.7102 0.7387 0.052 Uiso 1 1 d
C34 C 0.2399(8) 0.3906(8) 0.7960(2) 0.047(2) Uani 1 1 d
C35 C 0.2156(8) 0.2854(7) 0.7932(2) 0.042(2) Uani 1 1 d
H25 H 0.1763 0.2450 0.7749 0.042 Uiso 1 1 d
C36 C 0.2473(10) 0.2399(9) 0.8159(3) 0.056(3) Uani 1 1 d
H26 H 0.2270 0.1678 0.8134 0.056 Uiso 1 1 d
C37 C 0.3075(9) 0.2945(10) 0.8420(3) 0.055(3) Uani 1 1 d
H27 H 0.3279 0.2610 0.8581 0.055 Uiso 1 1 d
C38 C 0.3383(8) 0.3965(9) 0.8449(3) 0.050(2) Uani 1 1 d
H28 H 0.3804 0.4363 0.8630 0.050 Uiso 1 1 d
C39 C 0.3073(7) 0.4476(7) 0.8225(2) 0.041(2) Uani 1 1 d
C40 C 0.3417(7) 0.5605(8) 0.8245(2) 0.045(2) Uani 1 1 d
C41 C 0.4027(9) 0.6265(9) 0.8480(3) 0.057(3) Uani 1 1 d
H29 H 0.4303 0.6008 0.8643 0.057 Uiso 1 1 d
C42 C 0.4261(11) 0.7264(10) 0.8489(3) 0.069(3) Uani 1 1 d
H30 H 0.4716 0.7730 0.8648 0.069 Uiso 1 1 d
C43 C 0.3797(10) 0.7596(8) 0.8258(3) 0.062(3) Uani 1 1 d
H31 H 0.3857 0.8275 0.8271 0.062 Uiso 1 1 d
C44 C 0.3243(9) 0.6919(8) 0.8015(3) 0.056(3) Uani 1 1 d
H32 H 0.2952 0.7146 0.7846 0.056 Uiso 1 1 d
C45 C 0.5935(9) 0.5743(10) 0.6092(3) 0.056(3) Uani 1 1 d
C46 C 0.7074(11) 0.6464(12) 0.6049(4) 0.078(4) Uani 1 1 d
H33 H 0.7406 0.6074 0.5977 0.078 Uiso 1 1 d
H34 H 0.7392 0.6802 0.6243 0.078 Uiso 1 1 d
H35 H 0.7192 0.6968 0.5887 0.078 Uiso 1 1 d
C47 C 0.5194(13) 0.5925(13) 0.5906(3) 0.079(4) Uani 1 1 d
H36 H 0.5543 0.6500 0.5760 0.079 Uiso 1 1 d
H37 H 0.4742 0.6042 0.6039 0.079 Uiso 1 1 d
H38 H 0.4745 0.5314 0.5771 0.079 Uiso 1 1 d
C48 C 0.5544(12) 0.6037(11) 0.7798(4) 0.082(4) Uani 1 1 d
C49 C 0.6228(19) 0.7176(15) 0.7889(6) 0.149(10) Uani 1 1 d
H39 H 0.6609 0.7572 0.7705 0.149 Uiso 1 1 d
H40 H 0.5831 0.7451 0.7974 0.149 Uiso 1 1 d
H41 H 0.6750 0.7263 0.8050 0.149 Uiso 1 1 d
C50 C 0.5703(12) 0.5267(12) 0.7984(3) 0.082(4) Uani 1 1 d
H42 H 0.5841 0.4840 0.7839 0.082 Uiso 1 1 d
H43 H 0.6267 0.5596 0.8130 0.082 Uiso 1 1 d
H44 H 0.5082 0.4808 0.8102 0.082 Uiso 1 1 d
C51 C -0.3193(15) -0.1758(14) 0.6776(3) 0.089(5) Uani 1 1 d
C52 C -0.2472(15) -0.0832(12) 0.6955(5) 0.103(5) Uani 1 1 d
H45 H -0.2659 -0.0312 0.6946 0.103 Uiso 1 1 d
H46 H -0.1770 -0.0543 0.6868 0.103 Uiso 1 1 d
H47 H -0.2437 -0.1001 0.7176 0.103 Uiso 1 1 d
C53 C -0.3629(16) -0.2779(17) 0.6939(7) 0.144(9) Uani 1 1 d
H48 H -0.4368 -0.3175 0.6922 0.144 Uiso 1 1 d
H49 H -0.3353 -0.3196 0.6847 0.144 Uiso 1 1 d
H50 H -0.3453 -0.2709 0.7166 0.144 Uiso 1 1 d
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C12 Pt1 C1 103.6(5) . .
C12 Pt1 N1 169.4(4) . .
C1 Pt1 N1 79.9(4) . .
C12 Pt1 N2 79.1(5) . .
C1 Pt1 N2 165.2(3) . .
N1 Pt1 N2 100.1(4) . .
C12 Pt1 Ag2 85.1(4) . .
C1 Pt1 Ag2 57.8(3) . .
N1 Pt1 Ag2 88.5(2) . .
N2 Pt1 Ag2 136.9(2) . .
C12 Pt1 Ag1 55.9(3) . .
C1 Pt1 Ag1 80.4(3) . .
N1 Pt1 Ag1 134.7(2) . .
N2 Pt1 Ag1 89.6(3) . .
Ag2 Pt1 Ag1 113.89(3) . .
C23 Pt2 C34 101.9(4) . .
C23 Pt2 N3 80.2(4) . .
C34 Pt2 N3 168.9(4) . .
C23 Pt2 N4 166.4(4) . .
C34 Pt2 N4 79.6(4) . .
N3 Pt2 N4 100.9(3) . .
C23 Pt2 Ag1 78.8(3) . 6
C34 Pt2 Ag1 72.9(3) . 6
N3 Pt2 Ag1 118.2(2) . 6
N4 Pt2 Ag1 88.8(2) . 6
C23 Pt2 Ag2 91.1(3) . .
C34 Pt2 Ag2 61.0(3) . .
N3 Pt2 Ag2 108.2(2) . .
N4 Pt2 Ag2 101.3(2) . .
Ag1 Pt2 Ag2 129.51(3) 6 .
C12 Ag1 O1 109.9(4) . .
C12 Ag1 Pt2 165.9(4) . 5_554
O1 Ag1 Pt2 81.5(2) . 5_554
C12 Ag1 Pt1 44.2(3) . .
O1 Ag1 Pt1 132.7(2) . .
Pt2 Ag1 Pt1 132.96(4) 5_554 .
O2 Ag2 C1 106.2(3) . .
O2 Ag2 C34 95.0(3) . .
C1 Ag2 C34 145.4(3) . .
O2 Ag2 C35 119.9(3) . .
C1 Ag2 C35 115.1(3) . .
C34 Ag2 C35 31.2(3) . .
O2 Ag2 Pt2 85.6(2) . .
C1 Ag2 Pt2 160.4(3) . .
C34 Ag2 Pt2 44.5(3) . .
C35 Ag2 Pt2 69.6(2) . .
O2 Ag2 Pt1 139.7(2) . .
C1 Ag2 Pt1 45.7(3) . .
C34 Ag2 Pt1 124.4(2) . .
C35 Ag2 Pt1 100.0(2) . .
Pt2 Ag2 Pt1 115.62(3) . .
O6 Cl1 O5 114.0(12) . .
O6 Cl1 O7 113.8(9) . .
O5 Cl1 O7 115.6(10) . .
O6 Cl1 O4 107.4(12) . .
O5 Cl1 O4 98.4(12) . .
O7 Cl1 O4 105.7(11) . .
O11 Cl2 O8 120(2) . .
O11 Cl2 O10 106.4(17) . .
O8 Cl2 O10 121.1(13) . .
O11 Cl2 O9 93(3) . .
O8 Cl2 O9 100.3(14) . .
O10 Cl2 O9 112.4(12) . .
C45 O1 Ag1 136.1(8) . .
C48 O2 Ag2 129.2(10) . .
C11 N1 C7 119.6(9) . .
C11 N1 Pt1 125.9(7) . .
C7 N1 Pt1 114.5(6) . .
C22 N2 C18 120.3(13) . .
C22 N2 Pt1 126.0(9) . .
C18 N2 Pt1 112.7(11) . .
C33 N3 C29 120.0(9) . .
C33 N3 Pt2 124.8(7) . .
C29 N3 Pt2 115.1(7) . .
C40 N4 C44 118.4(9) . .
C40 N4 Pt2 116.5(7) . .
C44 N4 Pt2 124.9(7) . .
C6 C1 C2 117.4(10) . .
C6 C1 Pt1 113.1(7) . .
C2 C1 Pt1 128.7(8) . .
C6 C1 Ag2 104.8(6) . .
C2 C1 Ag2 98.4(6) . .
Pt1 C1 Ag2 76.5(3) . .
C3 C2 C1 122.0(10) . .
C2 C3 C4 118.5(11) . .
C5 C4 C3 121.9(11) . .
C4 C5 C6 119.6(11) . .
C1 C6 C5 120.5(10) . .
C1 C6 C7 117.8(9) . .
C5 C6 C7 121.7(9) . .
N1 C7 C8 121.9(10) . .
N1 C7 C6 114.2(8) . .
C8 C7 C6 123.9(10) . .
C7 C8 C9 118.6(11) . .
C10 C9 C8 118.2(11) . .
C9 C10 C11 120.2(10) . .
N1 C11 C10 121.1(10) . .
C17 C12 C13 115.6(12) . .
C17 C12 Pt1 115.2(11) . .
C13 C12 Pt1 128.3(10) . .
C17 C12 Ag1 101.2(8) . .
C13 C12 Ag1 99.2(8) . .
Pt1 C12 Ag1 79.9(4) . .
C14 C13 C12 124.1(17) . .
C13 C14 C15 119(2) . .
C14 C15 C16 120.5(14) . .
C17 C16 C15 118(2) . .
C12 C17 C16 122.1(19) . .
C12 C17 C18 115.3(11) . .
C16 C17 C18 122.5(17) . .
N2 C18 C17 117.4(14) . .
N2 C18 C19 117.2(18) . .
C17 C18 C19 125.4(15) . .
C20 C19 C18 120.4(16) . .
C21 C20 C19 119.7(14) . .
C20 C21 C22 115.0(18) . .
N2 C22 C21 127.0(15) . .
C24 C23 C28 115.8(9) . .
C24 C23 Pt2 130.0(8) . .
C28 C23 Pt2 113.9(7) . .
C25 C24 C23 122.3(11) . .
C26 C25 C24 121.2(11) . .
C25 C26 C27 121.1(10) . .
C28 C27 C26 116.2(10) . .
C27 C28 C23 123.3(9) . .
C27 C28 C29 119.5(9) . .
C23 C28 C29 117.2(9) . .
N3 C29 C30 119.4(10) . .
N3 C29 C28 113.2(9) . .
C30 C29 C28 127.4(10) . .
C31 C30 C29 120.1(10) . .
C30 C31 C32 119.9(10) . .
C31 C32 C33 118.4(10) . .
N3 C33 C32 121.4(9) . .
C35 C34 C39 115.3(9) . .
C35 C34 Pt2 130.3(7) . .
C39 C34 Pt2 113.6(7) . .
C35 C34 Ag2 81.0(6) . .
C39 C34 Ag2 109.9(6) . .
Pt2 C34 Ag2 74.6(3) . .
C36 C35 C34 121.4(10) . .
C36 C35 Ag2 120.5(7) . .
C34 C35 Ag2 67.8(5) . .
C35 C36 C37 122.3(10) . .
C38 C37 C36 119.0(9) . .
C37 C38 C39 121.5(10) . .
C38 C39 C34 120.4(9) . .
C38 C39 C40 123.0(9) . .
C34 C39 C40 116.6(8) . .
N4 C40 C41 121.1(10) . .
N4 C40 C39 113.5(8) . .
C41 C40 C39 125.4(10) . .
C42 C41 C40 121.6(11) . .
C41 C42 C43 117.8(11) . .
C44 C43 C42 117.8(11) . .
N4 C44 C43 122.6(10) . .
O1 C45 C47 121.2(12) . .
O1 C45 C46 119.7(12) . .
C47 C45 C46 119.1(13) . .
O2 C48 C50 122.5(13) . .
O2 C48 C49 120.8(19) . .
C50 C48 C49 116.5(18) . .
O3 C51 C52 120.5(18) . .
O3 C51 C53 121(2) . .
C52 C51 C53 118.0(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C12 1.990(11) .
Pt1 C1 2.062(11) .
Pt1 N1 2.111(8) .
Pt1 N2 2.136(9) .
Pt1 Ag2 2.8004(9) .
Pt1 Ag1 2.8121(9) .
Pt2 C23 2.020(9) .
Pt2 C34 2.032(11) .
Pt2 N3 2.113(8) .
Pt2 N4 2.128(8) .
Pt2 Ag1 2.6781(9) 6
Pt2 Ag2 2.7959(9) .
Ag1 C12 2.364(10) .
Ag1 O1 2.419(9) .
Ag1 Pt2 2.6781(9) 5_554
Ag2 O2 2.373(9) .
Ag2 C1 2.437(9) .
Ag2 C34 2.536(9) .
Ag2 C35 2.705(9) .
Cl1 O6 1.297(13) .
Cl1 O5 1.379(14) .
Cl1 O7 1.401(13) .
Cl1 O4 1.467(18) .
Cl2 O11 1.214(18) .
Cl2 O8 1.305(16) .
Cl2 O10 1.412(14) .
Cl2 O9 1.47(3) .
O1 C45 1.208(15) .
O2 C48 1.212(19) .
O3 C51 1.176(19) .
N1 C11 1.332(13) .
N1 C7 1.364(12) .
N2 C22 1.272(18) .
N2 C18 1.311(18) .
N3 C33 1.331(13) .
N3 C29 1.351(13) .
N4 C40 1.333(13) .
N4 C44 1.337(13) .
C1 C6 1.393(14) .
C1 C2 1.401(15) .
C2 C3 1.379(16) .
C3 C4 1.380(18) .
C4 C5 1.352(18) .
C5 C6 1.402(15) .
C6 C7 1.470(14) .
C7 C8 1.373(15) .
C8 C9 1.418(19) .
C9 C10 1.38(2) .
C10 C11 1.396(17) .
C12 C17 1.40(2) .
C12 C13 1.43(2) .
C13 C14 1.362(18) .
C14 C15 1.37(3) .
C15 C16 1.43(4) .
C16 C17 1.410(19) .
C17 C18 1.42(3) .
C18 C19 1.46(2) .
C19 C20 1.37(3) .
C20 C21 1.36(3) .
C21 C22 1.402(17) .
C23 C24 1.384(15) .
C23 C28 1.407(14) .
C24 C25 1.362(15) .
C25 C26 1.348(18) .
C26 C27 1.410(18) .
C27 C28 1.402(14) .
C28 C29 1.488(14) .
C29 C30 1.406(16) .
C30 C31 1.352(18) .
C31 C32 1.376(17) .
C32 C33 1.404(15) .
C34 C35 1.417(14) .
C34 C39 1.444(14) .
C35 C36 1.372(15) .
C36 C37 1.381(19) .
C37 C38 1.348(17) .
C38 C39 1.413(14) .
C39 C40 1.486(14) .
C40 C41 1.359(15) .
C41 C42 1.341(18) .
C42 C43 1.404(18) .
C43 C44 1.371(16) .
C45 C47 1.474(18) .
C45 C46 1.488(18) .
C48 C50 1.49(2) .
C48 C49 1.52(2) .
C51 C52 1.45(2) .
C51 C53 1.48(3) .
