#------------------------------------------------------------------------------
#$Date: 2016-03-22 12:09:21 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178937 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/66/4116663.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4116663
loop_
_publ_author_name
'S. Kannan'
'Alan J. James'
'Paul R. Sharp'
_publ_contact_author
;
Paul R. Sharp
Department of Chemistry
University of Missouri
Columbia, MO 65211
;
_publ_contact_author_email       chemprs@showme.missouri.edu
_publ_contact_author_fax         1-573-882-2574
_publ_contact_author_phone       1-573-882-7715
_publ_section_title
;
 [Pd3(PPh3)4]2+, a New Palladium Triphenylphosphine Complex
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              215
_journal_page_last               216
_journal_paper_doi               10.1021/ja973411x
_journal_volume                  120
_journal_year                    1998
_chemical_formula_structural     '[Pd3(PPh3)4]2+   2BF4-'
_chemical_formula_sum            'C79 H78 B2 Cl2 F8 O2 P4 Pd3'
_chemical_formula_weight         1747.01
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 108.7850(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.1169(13)
_cell_length_b                   15.0359(8)
_cell_length_c                   21.0036(12)
_cell_measurement_temperature    173(2)
_cell_volume                     6911.6(7)
_computing_cell_refinement
'Siemens SMART Software Reference Manual (1994)'
_computing_data_collection
'Siemens SMART Software Reference Manual (1994)'
_computing_data_reduction        'Siemens SAINT version 4'
_computing_molecular_graphics    'Siemens SHELXTL'
_computing_publication_material  'Siemens SHELXTL'
_computing_structure_refinement  'SHELXLTL (Sheldrick, 1994)'
_computing_structure_solution
'SHELXTL version 5 (Sheldrick, 1994), RES2INS (Len Barbour, 1996)'
_diffrn_ambient_temperature      173(2)
_diffrn_measurement_device       'Siemens SMART CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0310
_diffrn_reflns_av_sigmaI/netI    0.0409
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            20244
_diffrn_reflns_theta_max         27.18
_diffrn_reflns_theta_min         1.64
_exptl_absorpt_coefficient_mu    1.014
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.812251
_exptl_absorpt_correction_type   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.679
_exptl_crystal_description       'rectangular prism'
_exptl_crystal_F_000             3528
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.964
_refine_diff_density_min         -2.331
_refine_diff_density_rms         0.144
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.072
_refine_ls_goodness_of_fit_obs   1.121
_refine_ls_matrix_type           full
_refine_ls_number_parameters     441
_refine_ls_number_reflns         7550
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.072
_refine_ls_restrained_S_obs      1.122
_refine_ls_R_factor_all          0.0654
_refine_ls_R_factor_obs          0.0480
_refine_ls_shift/esd_max         0.229
_refine_ls_shift/esd_mean        0.006
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0713P)²+45.7991P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1411
_refine_ls_wR_factor_obs         0.1307
_reflns_number_observed          5990
_reflns_number_total             7550
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ja973411x.cif
_cod_data_source_block           global
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0713P)^2^+45.7991P] where P=(Fo^2^+2Fc^2^)/3'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0713P)^2^+45.7991P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_database_code               4116663
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Pd1 Pd 0.24722(2) 0.65277(2) 0.10471(2) 0.01671(11) Uani 1 d .
Pd2 Pd 0.2500 0.7500 0.0000 0.01942(13) Uani 1 d S
Cl1 Cl 0.5542(2) 0.3549(2) 0.2277(2) 0.1257(12) Uani 1 d .
P1 P 0.24864(5) 0.55082(7) 0.18970(5) 0.0169(2) Uani 1 d .
P2 P 0.25390(5) 0.56115(7) 0.02238(5) 0.0179(2) Uani 1 d .
F1 F 0.4486(2) 0.8077(5) -0.0343(3) 0.130(3) Uani 1 d .
F2 F 0.5240(2) 0.7544(3) 0.0534(2) 0.0540(10) Uani 1 d .
F3 F 0.4261(2) 0.7638(4) 0.0537(3) 0.0793(15) Uani 1 d .
F4 F 0.4531(2) 0.6614(4) -0.0075(3) 0.098(2) Uani 1 d .
C1 C -0.0506(5) 0.7201(8) -0.2997(5) 0.089(3) Uani 1 d D
C2 C 0.0290(8) 0.6170(11) -0.2985(7) 0.129(5) Uani 1 d D
C3 C -0.0191(10) 0.6398(14) -0.2818(7) 0.229(12) Uani 1 d D
C10 C 0.5000 0.2756(28) 0.2500 0.281(18) Uiso 1 d S
C11 C 0.1866(2) 0.5748(3) 0.2234(2) 0.0209(9) Uani 1 d .
C12 C 0.1324(2) 0.6083(4) 0.1795(2) 0.0297(11) Uani 1 d .
H12 H 0.1294(2) 0.6209(4) 0.1343(2) 0.036 Uiso 1 calc R
C13 C 0.0826(3) 0.6234(5) 0.2011(3) 0.0418(14) Uani 1 d .
H13 H 0.0457(3) 0.6464(5) 0.1708(3) 0.050 Uiso 1 calc R
C14 C 0.0869(3) 0.6049(4) 0.2674(3) 0.0397(14) Uani 1 d .
H14 H 0.0529(3) 0.6158(4) 0.2824(3) 0.048 Uiso 1 calc R
C15 C 0.1397(2) 0.5713(4) 0.3110(3) 0.0314(11) Uani 1 d .
H15 H 0.1421(2) 0.5579(4) 0.3560(3) 0.038 Uiso 1 calc R
C16 C 0.1899(2) 0.5567(3) 0.2899(2) 0.0236(10) Uani 1 d .
H16 H 0.2267(2) 0.5343(3) 0.3207(2) 0.028 Uiso 1 calc R
C21 C 0.3196(2) 0.5506(3) 0.2602(2) 0.0208(9) Uani 1 d .
C22 C 0.3326(2) 0.4861(3) 0.3104(2) 0.0250(10) Uani 1 d .
H22 H 0.3040(2) 0.4399(3) 0.3082(2) 0.030 Uiso 1 calc R
C23 C 0.3873(2) 0.4886(4) 0.3639(2) 0.0307(11) Uani 1 d .
H23 H 0.3957(2) 0.4445(4) 0.3981(2) 0.037 Uiso 1 calc R
C24 C 0.4292(2) 0.5562(4) 0.3669(3) 0.0322(11) Uani 1 d .
H24 H 0.4662(2) 0.5588(4) 0.4036(3) 0.039 Uiso 1 calc R
C25 C 0.4174(2) 0.6192(3) 0.3168(3) 0.0290(11) Uani 1 d .
H25 H 0.4464(2) 0.6647(3) 0.3188(3) 0.035 Uiso 1 calc R
C26 C 0.3629(2) 0.6164(3) 0.2631(2) 0.0237(10) Uani 1 d .
H26 H 0.3552(2) 0.6595(3) 0.2284(2) 0.028 Uiso 1 calc R
C31 C 0.2356(2) 0.4323(3) 0.1692(2) 0.0190(9) Uani 1 d .
C32 C 0.1779(2) 0.3950(3) 0.1522(2) 0.0234(10) Uani 1 d .
H32 H 0.1439(2) 0.4314(3) 0.1505(2) 0.028 Uiso 1 calc R
C33 C 0.1691(2) 0.3047(3) 0.1375(2) 0.0293(11) Uani 1 d .
H33 H 0.1291(2) 0.2801(3) 0.1256(2) 0.035 Uiso 1 calc R
C34 C 0.2182(3) 0.2512(3) 0.1403(2) 0.0315(12) Uani 1 d .
H34 H 0.2123(3) 0.1893(3) 0.1315(2) 0.038 Uiso 1 calc R
C35 C 0.2760(3) 0.2874(3) 0.1559(2) 0.0291(11) Uani 1 d .
H35 H 0.3098(3) 0.2506(3) 0.1570(2) 0.035 Uiso 1 calc R
C36 C 0.2849(2) 0.3776(3) 0.1700(2) 0.0256(10) Uani 1 d .
H36 H 0.3247(2) 0.4024(3) 0.1803(2) 0.031 Uiso 1 calc R
C41 C 0.3255(2) 0.5013(3) 0.0416(2) 0.0218(9) Uani 1 d .
C42 C 0.3377(2) 0.4439(3) -0.0052(2) 0.0276(10) Uani 1 d .
H42 H 0.3079(2) 0.4358(3) -0.0481(2) 0.033 Uiso 1 calc R
C43 C 0.3928(3) 0.3992(4) 0.0105(3) 0.0343(12) Uani 1 d .
H43 H 0.4002(3) 0.3595(4) -0.0212(3) 0.041 Uiso 1 calc R
C44 C 0.4373(3) 0.4121(4) 0.0726(3) 0.0410(14) Uani 1 d .
H44 H 0.4750(3) 0.3810(4) 0.0836(3) 0.049 Uiso 1 calc R
C45 C 0.4262(3) 0.4704(4) 0.1180(3) 0.0427(14) Uani 1 d .
H45 H 0.4568(3) 0.4803(4) 0.1602(3) 0.051 Uiso 1 calc R
C46 C 0.3705(2) 0.5148(4) 0.1027(2) 0.0297(11) Uani 1 d .
H46 H 0.3634(2) 0.5547(4) 0.1345(2) 0.036 Uiso 1 calc R
C51 C 0.1906(2) 0.4834(3) -0.0029(2) 0.0245(10) Uani 1 d .
C52 C 0.1980(3) 0.3923(3) -0.0099(2) 0.0303(11) Uani 1 d .
H52 H 0.2377(3) 0.3683(3) -0.0020(2) 0.036 Uiso 1 calc R
C53 C 0.1476(3) 0.3364(4) -0.0283(3) 0.0417(15) Uani 1 d .
H53 H 0.1531(3) 0.2744(4) -0.0327(3) 0.050 Uiso 1 calc R
C54 C 0.0898(3) 0.3700(5) -0.0401(3) 0.047(2) Uani 1 d .
H54 H 0.0555(3) 0.3314(5) -0.0534(3) 0.056 Uiso 1 calc R
C55 C 0.0817(3) 0.4604(5) -0.0326(3) 0.047(2) Uani 1 d .
H55 H 0.0417(3) 0.4835(5) -0.0407(3) 0.056 Uiso 1 calc R
C56 C 0.1318(2) 0.5172(4) -0.0133(3) 0.0323(11) Uani 1 d .
H56 H 0.1261(2) 0.5788(4) -0.0072(3) 0.039 Uiso 1 calc R
C61 C 0.2515(2) 0.6246(3) -0.0518(2) 0.0188(9) Uani 1 d .
C62 C 0.3066(2) 0.6680(3) -0.0524(2) 0.0219(9) Uani 1 d .
H62 H 0.3420(2) 0.6654(3) -0.0138(2) 0.026 Uiso 1 calc R
C63 C 0.3084(2) 0.7144(3) -0.1098(2) 0.0250(10) Uani 1 d .
H63 H 0.3458(2) 0.7402(3) -0.1103(2) 0.030 Uiso 1 calc R
C64 C 0.2561(2) 0.7233(3) -0.1666(2) 0.0247(10) Uani 1 d .
H64 H 0.2578(2) 0.7533(3) -0.2058(2) 0.030 Uiso 1 calc R
C65 C 0.2008(2) 0.6863(3) -0.1637(2) 0.0276(11) Uani 1 d .
H65 H 0.1648(2) 0.6935(3) -0.2011(2) 0.033 Uiso 1 calc R
C66 C 0.1976(2) 0.6402(3) -0.1083(2) 0.0240(10) Uani 1 d .
H66 H 0.1592(2) 0.6185(3) -0.1074(2) 0.029 Uiso 1 calc R
B1 B 0.4640(3) 0.7472(5) 0.0160(4) 0.044(2) Uani 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P2 Pd1 C64 163.10(12) . 7_565
P2 Pd1 P1 101.35(4) . .
C64 Pd1 P1 95.41(12) 7_565 .
P2 Pd1 C63 135.55(12) . 7_565
C64 Pd1 C63 34.8(2) 7_565 7_565
P1 Pd1 C63 112.73(11) . 7_565
P2 Pd1 Pd2 71.08(3) . .
C64 Pd1 Pd2 92.10(11) 7_565 .
P1 Pd1 Pd2 172.27(3) . .
C63 Pd1 Pd2 74.66(11) 7_565 .
C61 Pd2 C61 180.0 . 7_565
C61 Pd2 C62 143.0(2) . 7_565
C61 Pd2 C62 37.0(2) 7_565 7_565
C61 Pd2 C62 37.0(2) . .
C61 Pd2 C62 143.0(2) 7_565 .
C62 Pd2 C62 180.0 7_565 .
C61 Pd2 Pd1 93.10(11) . 7_565
C61 Pd2 Pd1 86.90(11) 7_565 7_565
C62 Pd2 Pd1 105.56(11) 7_565 7_565
C62 Pd2 Pd1 74.44(11) . 7_565
C61 Pd2 Pd1 86.90(11) . .
C61 Pd2 Pd1 93.10(11) 7_565 .
C62 Pd2 Pd1 74.44(11) 7_565 .
C62 Pd2 Pd1 105.56(11) . .
Pd1 Pd2 Pd1 180.0 7_565 .
C61 Pd2 P2 140.93(11) . 7_565
C61 Pd2 P2 39.07(11) 7_565 7_565
C62 Pd2 P2 63.86(11) 7_565 7_565
C62 Pd2 P2 116.14(11) . 7_565
Pd1 Pd2 P2 47.89(2) 7_565 7_565
Pd1 Pd2 P2 132.11(2) . 7_565
C61 Pd2 P2 39.07(11) . .
C61 Pd2 P2 140.93(11) 7_565 .
C62 Pd2 P2 116.14(11) 7_565 .
C62 Pd2 P2 63.86(11) . .
Pd1 Pd2 P2 132.11(2) 7_565 .
Pd1 Pd2 P2 47.89(2) . .
P2 Pd2 P2 180.0 7_565 .
C21 P1 C11 107.4(2) . .
C21 P1 C31 103.0(2) . .
C11 P1 C31 101.1(2) . .
C21 P1 Pd1 114.1(2) . .
C11 P1 Pd1 110.19(15) . .
C31 P1 Pd1 119.68(13) . .
C41 P2 C61 103.0(2) . .
C41 P2 C51 109.8(2) . .
C61 P2 C51 106.8(2) . .
C41 P2 Pd1 114.6(2) . .
C61 P2 Pd1 110.30(15) . .
C51 P2 Pd1 111.7(2) . .
C41 P2 Pd2 120.4(2) . .
C61 P2 Pd2 49.37(14) . .
C51 P2 Pd2 127.5(2) . .
Pd1 P2 Pd2 61.03(3) . .
C3 C2 C3 47.8(11) . 2_554
C2 C3 C3 85.6(21) . 2_554
C2 C3 C1 124.5(22) . .
C3 C3 C1 112.7(11) 2_554 .
C2 C3 C2 124.9(11) . 2_554
C3 C3 C2 46.5(13) 2_554 2_554
C1 C3 C2 101.7(14) . 2_554
Cl1 C10 Cl1 102.0(20) 2_655 .
C12 C11 C16 118.7(4) . .
C12 C11 P1 117.9(3) . .
C16 C11 P1 123.4(4) . .
C13 C12 C11 120.6(5) . .
C12 C13 C14 119.8(5) . .
C15 C14 C13 120.3(5) . .
C14 C15 C16 120.2(5) . .
C15 C16 C11 120.4(5) . .
C22 C21 C26 119.0(4) . .
C22 C21 P1 122.4(4) . .
C26 C21 P1 118.7(3) . .
C21 C22 C23 120.7(5) . .
C24 C23 C22 119.5(5) . .
C25 C24 C23 120.3(5) . .
C24 C25 C26 120.2(5) . .
C21 C26 C25 120.3(4) . .
C32 C31 C36 118.5(4) . .
C32 C31 P1 121.8(4) . .
C36 C31 P1 119.7(4) . .
C31 C32 C33 120.9(5) . .
C34 C33 C32 120.0(5) . .
C33 C34 C35 120.0(5) . .
C34 C35 C36 120.0(5) . .
C35 C36 C31 120.5(5) . .
C46 C41 C42 118.6(5) . .
C46 C41 P2 119.6(4) . .
C42 C41 P2 121.7(4) . .
C43 C42 C41 120.7(5) . .
C42 C43 C44 120.2(5) . .
C45 C44 C43 119.5(5) . .
C44 C45 C46 120.6(6) . .
C41 C46 C45 120.5(5) . .
C52 C51 C56 119.0(5) . .
C52 C51 P2 123.3(4) . .
C56 C51 P2 117.6(4) . .
C53 C52 C51 120.3(6) . .
C54 C53 C52 120.6(6) . .
C53 C54 C55 120.0(5) . .
C54 C55 C56 120.3(6) . .
C55 C56 C51 119.9(6) . .
C62 C61 C66 117.0(4) . .
C62 C61 P2 117.8(3) . .
C66 C61 P2 125.0(3) . .
C62 C61 Pd2 76.6(3) . .
C66 C61 Pd2 97.0(3) . .
P2 C61 Pd2 91.6(2) . .
C63 C62 C61 120.4(4) . .
C63 C62 Pd2 108.8(3) . .
C61 C62 Pd2 66.4(2) . .
C64 C63 C62 121.3(5) . .
C64 C63 Pd1 68.3(3) . 7_565
C62 C63 Pd1 102.1(3) . 7_565
C63 C64 C65 117.9(4) . .
C63 C64 Pd1 76.9(3) . 7_565
C65 C64 Pd1 95.7(3) . 7_565
C66 C65 C64 122.1(5) . .
C65 C66 C61 120.7(5) . .
F1 B1 F2 111.1(6) . .
F1 B1 F4 112.2(7) . .
F2 B1 F4 108.4(6) . .
F1 B1 F3 105.9(7) . .
F2 B1 F3 111.8(6) . .
F4 B1 F3 107.4(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 P2 2.2547(11) .
Pd1 C64 2.288(4) 7_565
Pd1 P1 2.3453(11) .
Pd1 C63 2.397(5) 7_565
Pd1 Pd2 2.6587(3) .
Pd2 C61 2.183(4) .
Pd2 C61 2.183(4) 7_565
Pd2 C62 2.317(4) 7_565
Pd2 C62 2.317(4) .
Pd2 Pd1 2.6587(3) 7_565
Pd2 P2 2.8748(11) 7_565
Pd2 P2 2.8748(11) .
Cl1 C10 1.89(3) .
P1 C21 1.823(5) .
P1 C11 1.828(5) .
P1 C31 1.835(4) .
P2 C41 1.811(5) .
P2 C61 1.813(4) .
P2 C51 1.813(5) .
F1 B1 1.352(9) .
F2 B1 1.361(8) .
F3 B1 1.378(8) .
F4 B1 1.376(9) .
C1 C3 1.40(2) .
C2 C3 1.31(2) .
C2 C3 1.81(3) 2_554
C3 C3 1.34(2) 2_554
C3 C2 1.81(3) 2_554
C10 Cl1 1.89(3) 2_655
C11 C12 1.389(7) .
C11 C16 1.402(6) .
C12 C13 1.383(7) .
C13 C14 1.393(8) .
C14 C15 1.366(8) .
C15 C16 1.386(7) .
C21 C22 1.391(6) .
C21 C26 1.394(7) .
C22 C23 1.395(7) .
C23 C24 1.393(8) .
C24 C25 1.375(7) .
C25 C26 1.395(7) .
C31 C32 1.383(7) .
C31 C36 1.402(7) .
C32 C33 1.392(7) .
C33 C34 1.378(8) .
C34 C35 1.383(8) .
C35 C36 1.389(7) .
C41 C46 1.383(7) .
C41 C42 1.403(6) .
C42 C43 1.383(7) .
C43 C44 1.389(8) .
C44 C45 1.379(8) .
C45 C46 1.393(8) .
C51 C52 1.395(7) .
C51 C56 1.402(7) .
C52 C53 1.386(8) .
C53 C54 1.374(10) .
C54 C55 1.387(10) .
C55 C56 1.390(8) .
C61 C62 1.434(7) .
C61 C66 1.437(6) .
C62 C63 1.406(6) .
C63 C64 1.405(7) .
C63 Pd1 2.397(5) 7_565
C64 C65 1.413(7) .
C64 Pd1 2.288(4) 7_565
C65 C66 1.377(7) .
