#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/88/4118848.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4118848
loop_
_publ_author_name
'Xun Zhang'
'Shuichi Suzuki'
'Masatoshi Kozaki'
'Keiji Okada'
_publ_contact_author_address
;
Department of Chemistry, Graduate School of Science, Osaka City University, 
Sumiyoshi-ku, Osaka 558-8585, Japan
;
_publ_contact_author_email       okadak@sci.osaka-cu.ac.jp
_publ_contact_author_fax         +81-666902709
_publ_contact_author_name        'Okada, K.'
_publ_contact_author_phone       +81-66052568
_publ_section_title
;
 NCN Pincer-Pt Complexes Coordinated by (Nitronyl Nitroxide)-2-ide Radical
 Anion
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              17866
_journal_page_last               17868
_journal_paper_doi               10.1021/ja308103g
_journal_volume                  134
_journal_year                    2012
_chemical_formula_moiety         'C23 H23 N4 O2 Pt, C H4 O'
_chemical_formula_sum            'C24 H27 N4 O3 Pt'
_chemical_formula_weight         614.59
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_author_name               'Tanaka, R.'
_audit_creation_date             2010-10-28
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.590(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.8985(12)
_cell_length_b                   15.6407(19)
_cell_length_c                   14.4655(18)
_cell_measurement_reflns_used    4845
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.4835
_cell_measurement_theta_min      4.0754
_cell_volume                     2219.9(5)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku, 2001)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et al.,  1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 7.32
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details
;
scan:
    Number of images: 360
               Slice: -80.0000 - 100.0000
         Image width: 0.5000
            Exp time: 3.0000
       Rotation axis: Phi
               Omega: 0.0000
                 Chi: 0.0000
                 Phi: 0.0000
                 XTD: 35.1687
              2theta: 9.8083
scan:
    Number of images: 100
               Slice: -30.0000 - 20.0000
         Image width: 0.5000
            Exp time: 3.0000
       Rotation axis: Omega
               Omega: 0.0000
                 Chi: 90.0000
                 Phi: 0.0000
                 XTD: 35.1687
              2theta: 9.8083
scan:
    Number of images: 100
               Slice: -30.0000 - 20.0000
         Image width: 0.5000
            Exp time: 3.0000
       Rotation axis: Omega
               Omega: 0.0000
                 Chi: 90.0000
                 Phi: 90.0000
                 XTD: 35.1687
              2theta: 9.8083
scan:
    Number of images: 100
               Slice: -30.0000 - 20.0000
         Image width: 0.5000
            Exp time: 3.0000
       Rotation axis: Omega
               Omega: 0.0000
                 Chi: 90.0000
                 Phi: 180.0000
                 XTD: 35.1687
              2theta: 9.8083

;
_diffrn_measurement_device       'Mercury CCD (2x2 bin mode)'
_diffrn_measurement_device_details 'AFC7: Eulerian 3-circle'
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       'ω or φ'
_diffrn_radiation_detector       CCD
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0461
_diffrn_reflns_av_sigmaI/netI    0.0409
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            21706
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         4.15
_diffrn_source_current           150.0000
_diffrn_source_power             7.5000
_diffrn_source_voltage           50.0000
_exptl_absorpt_coefficient_mu    6.355
_exptl_absorpt_correction_T_max  0.7017
_exptl_absorpt_correction_T_min  0.4113
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Jacobson, 1998)'
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.839
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1204
_exptl_crystal_preparation
'mounted on a glass fiber with epoxy resin and placed in N2 stream at 150(2) K'
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.024
_refine_diff_density_min         -1.168
_refine_diff_density_rms         0.132
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.186
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         5078
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.186
_refine_ls_R_factor_all          0.0443
_refine_ls_R_factor_gt           0.0360
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0092P)²+6.6108P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0621
_refine_ls_wR_factor_ref         0.0639
_reflns_number_gt                4615
_reflns_number_total             5078
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja308103g_si_002.cif
_cod_data_source_block           1(NN-Pt(NCN)-1)-MeOH
_cod_original_sg_symbol_Hall     '-P 2yn '
_cod_database_code               4118848
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.454138(15) 0.019004(11) 0.667395(11) 0.01185(6) Uani 1 1 d .
N1 N 0.3194(3) 0.0231(3) 0.5469(3) 0.0142(7) Uani 1 1 d .
C1 C 0.2122(4) -0.0288(3) 0.5246(3) 0.0171(9) Uani 1 1 d .
H1A H 0.1922 -0.0709 0.5683 0.020 Uiso 1 1 calc R
C2 C 0.1299(4) -0.0229(3) 0.4399(3) 0.0209(10) Uani 1 1 d .
H2A H 0.0543 -0.0603 0.4260 0.025 Uiso 1 1 calc R
C3 C 0.1580(5) 0.0374(3) 0.3758(3) 0.0199(10) Uani 1 1 d .
H3A H 0.1022 0.0420 0.3173 0.024 Uiso 1 1 calc R
C4 C 0.2681(4) 0.0912(3) 0.3975(3) 0.0182(10) Uani 1 1 d .
H4A H 0.2884 0.1331 0.3538 0.022 Uiso 1 1 calc R
C5 C 0.3495(4) 0.0841(3) 0.4833(3) 0.0141(9) Uani 1 1 d .
C6 C 0.5307(4) 0.1134(3) 0.6040(3) 0.0136(9) Uani 1 1 d .
C7 C 0.4699(4) 0.1364(3) 0.5152(3) 0.0141(9) Uani 1 1 d .
C8 C 0.5273(4) 0.2015(3) 0.4677(3) 0.0183(10) Uani 1 1 d .
H8A H 0.4886 0.2173 0.4065 0.022 Uiso 1 1 calc R
C9 C 0.6429(5) 0.2433(3) 0.5119(3) 0.0201(10) Uani 1 1 d .
H9A H 0.6815 0.2885 0.4801 0.024 Uiso 1 1 calc R
C10 C 0.7032(4) 0.2209(3) 0.6008(3) 0.0180(10) Uani 1 1 d .
H10A H 0.7816 0.2504 0.6295 0.022 Uiso 1 1 calc R
C11 C 0.6465(4) 0.1543(3) 0.6473(3) 0.0150(9) Uani 1 1 d .
N2 N 0.6219(3) 0.0466(3) 0.7611(3) 0.0151(8) Uani 1 1 d .
C12 C 0.6989(4) 0.1147(3) 0.7370(3) 0.0145(9) Uani 1 1 d .
C13 C 0.8183(4) 0.1376(3) 0.7934(3) 0.0197(10) Uani 1 1 d .
H13A H 0.8694 0.1855 0.7776 0.024 Uiso 1 1 calc R
C14 C 0.8620(5) 0.0906(3) 0.8719(3) 0.0233(11) Uani 1 1 d .
H14A H 0.9442 0.1056 0.9100 0.028 Uiso 1 1 calc R
C15 C 0.7869(5) 0.0221(3) 0.8954(3) 0.0226(10) Uani 1 1 d .
H15A H 0.8163 -0.0109 0.9494 0.027 Uiso 1 1 calc R
C16 C 0.6668(4) 0.0020(3) 0.8383(3) 0.0180(10) Uani 1 1 d .
H16A H 0.6144 -0.0453 0.8547 0.022 Uiso 1 1 calc R
C17 C 0.3662(4) -0.0817(3) 0.7355(3) 0.0147(9) Uani 1 1 d .
N3 N 0.4192(3) -0.1543(3) 0.7672(3) 0.0160(8) Uani 1 1 d .
C18 C 0.3290(4) -0.2082(3) 0.8224(3) 0.0195(10) Uani 1 1 d .
C19 C 0.1895(4) -0.1661(3) 0.7873(3) 0.0183(10) Uani 1 1 d .
N4 N 0.2354(4) -0.0820(3) 0.7534(3) 0.0169(8) Uani 1 1 d .
O1 O 0.5439(3) -0.1797(2) 0.7656(2) 0.0208(7) Uani 1 1 d .
O2 O 0.1478(3) -0.0196(2) 0.7356(2) 0.0194(7) Uani 1 1 d .
C20 C 0.3779(5) -0.1941(4) 0.9255(4) 0.0301(12) Uani 1 1 d .
H20A H 0.3214 -0.2275 0.9629 0.045 Uiso 1 1 calc R
H20B H 0.3707 -0.1333 0.9403 0.045 Uiso 1 1 calc R
H20C H 0.4731 -0.2123 0.9395 0.045 Uiso 1 1 calc R
C21 C 0.3417(5) -0.3019(3) 0.7996(4) 0.0291(12) Uani 1 1 d .
H21A H 0.4324 -0.3224 0.8254 0.044 Uiso 1 1 calc R
H21B H 0.3289 -0.3095 0.7317 0.044 Uiso 1 1 calc R
H21C H 0.2721 -0.3344 0.8268 0.044 Uiso 1 1 calc R
C22 C 0.0956(5) -0.1515(3) 0.8610(4) 0.0270(12) Uani 1 1 d .
H22A H 0.1422 -0.1161 0.9112 0.040 Uiso 1 1 calc R
H22B H 0.0714 -0.2067 0.8864 0.040 Uiso 1 1 calc R
H22C H 0.0126 -0.1224 0.8327 0.040 Uiso 1 1 calc R
C23 C 0.1109(5) -0.2119(3) 0.7027(4) 0.0261(11) Uani 1 1 d .
H23A H 0.0320 -0.1772 0.6775 0.039 Uiso 1 1 calc R
H23B H 0.0796 -0.2677 0.7221 0.039 Uiso 1 1 calc R
H23C H 0.1708 -0.2199 0.6547 0.039 Uiso 1 1 calc R
O3 O 0.2019(3) 0.0723(3) 0.8974(3) 0.0279(8) Uani 1 1 d .
H3O H 0.171(7) 0.034(5) 0.844(6) 0.07(2) Uiso 1 1 d .
C24 C 0.3462(5) 0.0766(4) 0.9118(4) 0.0261(11) Uani 1 1 d .
H24A H 0.3754 0.1207 0.9582 0.039 Uiso 1 1 calc R
H24B H 0.3797 0.0908 0.8528 0.039 Uiso 1 1 calc R
H24C H 0.3833 0.0211 0.9341 0.039 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C6 Pt1 N2 79.60(17)
C6 Pt1 N1 79.98(17)
N2 Pt1 N1 159.43(15)
C6 Pt1 C17 178.50(16)
N2 Pt1 C17 101.37(16)
N1 Pt1 C17 99.10(16)
C1 N1 C5 119.4(4)
C1 N1 Pt1 126.2(3)
C5 N1 Pt1 114.3(3)
N1 C1 C2 121.8(4)
N1 C1 H1A 119.1
C2 C1 H1A 119.1
C3 C2 C1 119.7(4)
C3 C2 H2A 120.1
C1 C2 H2A 120.1
C2 C3 C4 119.2(4)
C2 C3 H3A 120.4
C4 C3 H3A 120.4
C3 C4 C5 120.1(4)
C3 C4 H4A 119.9
C5 C4 H4A 119.9
N1 C5 C4 119.7(4)
N1 C5 C7 114.3(4)
C4 C5 C7 125.9(4)
C11 C6 C7 121.9(4)
C11 C6 Pt1 119.2(3)
C7 C6 Pt1 118.9(3)
C6 C7 C8 119.4(4)
C6 C7 C5 112.4(4)
C8 C7 C5 128.3(4)
C7 C8 C9 118.7(4)
C7 C8 H8A 120.7
C9 C8 H8A 120.7
C10 C9 C8 122.1(4)
C10 C9 H9A 119.0
C8 C9 H9A 119.0
C9 C10 C11 118.9(4)
C9 C10 H10A 120.6
C11 C10 H10A 120.6
C6 C11 C10 119.2(4)
C6 C11 C12 112.2(4)
C10 C11 C12 128.5(4)
C16 N2 C12 118.6(4)
C16 N2 Pt1 126.3(3)
C12 N2 Pt1 114.9(3)
N2 C12 C13 120.3(4)
N2 C12 C11 114.0(4)
C13 C12 C11 125.6(4)
C14 C13 C12 119.8(4)
C14 C13 H13A 120.1
C12 C13 H13A 120.1
C15 C14 C13 120.0(4)
C15 C14 H14A 120.0
C13 C14 H14A 120.0
C14 C15 C16 118.6(4)
C14 C15 H15A 120.7
C16 C15 H15A 120.7
N2 C16 C15 122.6(4)
N2 C16 H16A 118.7
C15 C16 H16A 118.7
N3 C17 N4 106.2(4)
N3 C17 Pt1 129.9(3)
N4 C17 Pt1 123.9(3)
O1 N3 C17 126.7(4)
O1 N3 C18 117.5(4)
C17 N3 C18 115.3(3)
C21 C18 C20 109.3(4)
C21 C18 N3 110.5(4)
C20 C18 N3 107.5(4)
C21 C18 C19 115.8(4)
C20 C18 C19 114.4(4)
N3 C18 C19 98.6(3)
N4 C19 C22 109.8(4)
N4 C19 C23 107.0(4)
C22 C19 C23 109.6(4)
N4 C19 C18 100.6(3)
C22 C19 C18 115.7(4)
C23 C19 C18 113.4(4)
O2 N4 C17 125.9(4)
O2 N4 C19 119.9(3)
C17 N4 C19 113.9(4)
C18 C20 H20A 109.5
C18 C20 H20B 109.5
H20A C20 H20B 109.5
C18 C20 H20C 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
C18 C21 H21A 109.5
C18 C21 H21B 109.5
H21A C21 H21B 109.5
C18 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
C19 C22 H22A 109.5
C19 C22 H22B 109.5
H22A C22 H22B 109.5
C19 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C19 C23 H23A 109.5
C19 C23 H23B 109.5
H23A C23 H23B 109.5
C19 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
C24 O3 H3O 110(4)
O3 C24 H24A 109.5
O3 C24 H24B 109.5
H24A C24 H24B 109.5
O3 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Pt1 C6 1.944(4)
Pt1 N2 2.046(4)
Pt1 N1 2.051(4)
Pt1 C17 2.106(4)
N1 C1 1.341(6)
N1 C5 1.385(6)
C1 C2 1.381(6)
C1 H1A 0.9500
C2 C3 1.378(7)
C2 H2A 0.9500
C3 C4 1.379(7)
C3 H3A 0.9500
C4 C5 1.392(6)
C4 H4A 0.9500
C5 C7 1.468(6)
C6 C11 1.387(6)
C6 C7 1.391(6)
C7 C8 1.392(6)
C8 C9 1.397(7)
C8 H8A 0.9500
C9 C10 1.389(7)
C9 H9A 0.9500
C10 C11 1.397(6)
C10 H10A 0.9500
C11 C12 1.470(6)
N2 C16 1.342(6)
N2 C12 1.381(6)
C12 C13 1.391(6)
C13 C14 1.374(7)
C13 H13A 0.9500
C14 C15 1.373(7)
C14 H14A 0.9500
C15 C16 1.391(6)
C15 H15A 0.9500
C16 H16A 0.9500
C17 N3 1.308(6)
C17 N4 1.353(5)
N3 O1 1.300(4)
N3 C18 1.528(6)
C18 C21 1.511(7)
C18 C20 1.522(7)
C18 C19 1.554(6)
C19 N4 1.496(6)
C19 C22 1.521(6)
C19 C23 1.537(7)
N4 O2 1.308(5)
C20 H20A 0.9800
C20 H20B 0.9800
C20 H20C 0.9800
C21 H21A 0.9800
C21 H21B 0.9800
C21 H21C 0.9800
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 H23A 0.9800
C23 H23B 0.9800
C23 H23C 0.9800
O3 C24 1.417(6)
O3 H3O 0.99(8)
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
O3 H3O O2 0.99(8) 1.77(9) 2.739(5) 165(7)
O3 H3O N4 0.99(8) 2.37(8) 3.233(5) 145(6)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C6 Pt1 N1 C1 179.4(4)
N2 Pt1 N1 C1 172.4(4)
C17 Pt1 N1 C1 -1.8(4)
C6 Pt1 N1 C5 2.0(3)
N2 Pt1 N1 C5 -5.0(6)
C17 Pt1 N1 C5 -179.2(3)
C5 N1 C1 C2 -0.4(6)
Pt1 N1 C1 C2 -177.6(3)
N1 C1 C2 C3 0.3(7)
C1 C2 C3 C4 -0.1(7)
C2 C3 C4 C5 0.0(7)
C1 N1 C5 C4 0.3(6)
Pt1 N1 C5 C4 177.8(3)
C1 N1 C5 C7 -179.3(4)
Pt1 N1 C5 C7 -1.8(5)
C3 C4 C5 N1 -0.1(6)
C3 C4 C5 C7 179.5(4)
N2 Pt1 C6 C11 -2.6(3)
N1 Pt1 C6 C11 179.9(4)
C17 Pt1 C6 C11 128(7)
N2 Pt1 C6 C7 175.6(4)
N1 Pt1 C6 C7 -1.9(3)
C17 Pt1 C6 C7 -54(7)
C11 C6 C7 C8 0.8(7)
Pt1 C6 C7 C8 -177.4(3)
C11 C6 C7 C5 179.7(4)
Pt1 C6 C7 C5 1.5(5)
N1 C5 C7 C6 0.3(5)
C4 C5 C7 C6 -179.3(4)
N1 C5 C7 C8 179.0(4)
C4 C5 C7 C8 -0.6(7)
C6 C7 C8 C9 -1.5(6)
C5 C7 C8 C9 179.8(4)
C7 C8 C9 C10 1.1(7)
C8 C9 C10 C11 0.2(7)
C7 C6 C11 C10 0.4(7)
Pt1 C6 C11 C10 178.6(3)
C7 C6 C11 C12 -175.2(4)
Pt1 C6 C11 C12 2.9(5)
C9 C10 C11 C6 -0.9(7)
C9 C10 C11 C12 174.0(4)
C6 Pt1 N2 C16 -173.6(4)
N1 Pt1 N2 C16 -166.7(4)
C17 Pt1 N2 C16 7.5(4)
C6 Pt1 N2 C12 1.7(3)
N1 Pt1 N2 C12 8.7(6)
C17 Pt1 N2 C12 -177.1(3)
C16 N2 C12 C13 -1.8(6)
Pt1 N2 C12 C13 -177.5(3)
C16 N2 C12 C11 175.1(4)
Pt1 N2 C12 C11 -0.7(5)
C6 C11 C12 N2 -1.3(5)
C10 C11 C12 N2 -176.5(4)
C6 C11 C12 C13 175.3(4)
C10 C11 C12 C13 0.2(8)
N2 C12 C13 C14 2.0(7)
C11 C12 C13 C14 -174.5(5)
C12 C13 C14 C15 -1.0(8)
C13 C14 C15 C16 -0.2(8)
C12 N2 C16 C15 0.6(7)
Pt1 N2 C16 C15 175.8(4)
C14 C15 C16 N2 0.4(8)
C6 Pt1 C17 N3 174(18)
N2 Pt1 C17 N3 -55.3(4)
N1 Pt1 C17 N3 122.6(4)
C6 Pt1 C17 N4 -4(7)
N2 Pt1 C17 N4 125.9(4)
N1 Pt1 C17 N4 -56.2(4)
N4 C17 N3 O1 -178.8(4)
Pt1 C17 N3 O1 2.3(7)
N4 C17 N3 C18 -7.3(5)
Pt1 C17 N3 C18 173.7(3)
O1 N3 C18 C21 -46.8(5)
C17 N3 C18 C21 140.9(4)
O1 N3 C18 C20 72.3(5)
C17 N3 C18 C20 -100.0(5)
O1 N3 C18 C19 -168.7(4)
C17 N3 C18 C19 19.1(5)
C21 C18 C19 N4 -138.6(4)
C20 C18 C19 N4 92.9(4)
N3 C18 C19 N4 -20.8(4)
C21 C18 C19 C22 103.2(5)
C20 C18 C19 C22 -25.3(6)
N3 C18 C19 C22 -139.0(4)
C21 C18 C19 C23 -24.6(6)
C20 C18 C19 C23 -153.1(4)
N3 C18 C19 C23 93.2(4)
N3 C17 N4 O2 177.6(4)
Pt1 C17 N4 O2 -3.4(6)
N3 C17 N4 C19 -9.1(5)
Pt1 C17 N4 C19 170.0(3)
C22 C19 N4 O2 -43.4(5)
C23 C19 N4 O2 75.4(5)
C18 C19 N4 O2 -165.9(4)
C22 C19 N4 C17 142.8(4)
C23 C19 N4 C17 -98.4(4)
C18 C19 N4 C17 20.3(5)
