#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:53:07 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179133 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/95/4309599.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4309599
loop_
_publ_author_name
'Catelijne H. M. Amijs'
'Alexsandro Berger'
'Fouad Soulimani'
'Tom Visser'
'Gerard P. M. van Klink'
'Martin Lutz'
'Anthony L. Spek'
'Gerard van Koten'
_publ_contact_author_address
; Bijvoet Center for Biomolecular Research
  Dep. Crystal and Structural Chemistry
  Utrecht University
  Padualaan 8
  3584 CH Utrecht
  The Netherlands
;
_publ_contact_author_email       m.lutz@chem.uu.nl
_publ_contact_author_fax         '[+31] 30 2533940'
_publ_contact_author_name        'Martin Lutz'
_publ_contact_author_phone       '[+31] 30 2533902'
_publ_section_title
;
Neutral Pyridyl-Functionalized C,N-ortho-Chelated Aminoaryl Platinum(II)
Corner Building Blocks for Application in Coordination Reactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6567
_journal_page_last               6578
_journal_paper_doi               10.1021/ic050697v
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C28 H30 N4 Pt'
_chemical_formula_sum            'C28 H30 N4 Pt'
_chemical_formula_weight         617.65
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.903(7)
_cell_angle_beta                 103.582(6)
_cell_angle_gamma                92.374(10)
_cell_formula_units_Z            2
_cell_length_a                   9.1884(10)
_cell_length_b                   10.7555(17)
_cell_length_c                   12.6573(10)
_cell_measurement_reflns_used    42
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      13.25
_cell_measurement_theta_min      3.17
_cell_volume                     1197.3(3)
_computing_cell_refinement       Dirax
_computing_data_collection       'Nonius COLLECT'
_computing_data_reduction        'EvalCCD, Sadabs'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF-99 (Beurskens et al., 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0346
_diffrn_reflns_av_sigmaI/netI    0.0347
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            17000
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.68
_exptl_absorpt_coefficient_mu    5.883
_exptl_absorpt_correction_T_max  0.70
_exptl_absorpt_correction_T_min  0.29
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellowish
_exptl_crystal_density_diffrn    1.713
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             608
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.511
_refine_diff_density_min         -1.240
_refine_diff_density_rms         0.128
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     302
_refine_ls_number_reflns         5481
_refine_ls_number_restraints     58
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.0326
_refine_ls_R_factor_gt           0.0267
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0321P)²+1.7708P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0641
_refine_ls_wR_factor_ref         0.0664
_reflns_number_gt                4953
_reflns_number_total             5481
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic050697vsi20050504_091400_2.cif
_cod_data_source_block           s3081a
_cod_database_code               4309599
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 1.003863(15) 0.239949(13) 0.478491(12) 0.02138(6) Uani 1 1 d . . .
N11 N 1.0902(4) 0.1072(3) 0.3629(3) 0.0247(7) Uani 1 1 d . . .
N12 N 0.1725(5) -0.1574(5) -0.0230(4) 0.0478(10) Uani 1 1 d U . .
N21 N 1.2094(3) 0.3533(3) 0.5775(3) 0.0247(7) Uani 1 1 d . . .
N22 N 0.7115(6) 0.6858(4) 1.0567(4) 0.0494(10) Uani 1 1 d U . .
C11 C 0.8114(4) 0.1615(4) 0.3793(3) 0.0242(7) Uani 1 1 d U . .
C12 C 0.8206(4) 0.0478(4) 0.3095(3) 0.0239(7) Uani 1 1 d U . .
C13 C 0.6990(4) -0.0131(4) 0.2300(3) 0.0268(7) Uani 1 1 d U . .
H13 H 0.7097 -0.0905 0.1860 0.032 Uiso 1 1 calc R . .
C14 C 0.5587(4) 0.0388(4) 0.2134(3) 0.0275(7) Uani 1 1 d U . .
C15 C 0.5488(4) 0.1528(4) 0.2786(3) 0.0281(8) Uani 1 1 d U . .
H15 H 0.4563 0.1911 0.2673 0.034 Uiso 1 1 calc R . .
C16 C 0.6711(4) 0.2120(4) 0.3598(3) 0.0267(8) Uani 1 1 d U . .
H16 H 0.6595 0.2892 0.4037 0.032 Uiso 1 1 calc R . .
C17 C 0.9731(4) -0.0020(4) 0.3276(3) 0.0258(8) Uani 1 1 d . . .
H17A H 0.9853 -0.0561 0.3852 0.031 Uiso 1 1 calc R . .
H17B H 0.9844 -0.0537 0.2586 0.031 Uiso 1 1 calc R . .
C18 C 1.1016(5) 0.1635(4) 0.2648(3) 0.0302(9) Uani 1 1 d . . .
H18A H 1.1720 0.2392 0.2880 0.045 Uiso 1 1 calc R . .
H18B H 1.0024 0.1864 0.2283 0.045 Uiso 1 1 calc R . .
H18C H 1.1378 0.1020 0.2133 0.045 Uiso 1 1 calc R . .
C19 C 1.2352(4) 0.0557(4) 0.4073(4) 0.0315(9) Uani 1 1 d . . .
H19A H 1.2545 -0.0116 0.3519 0.047 Uiso 1 1 calc R . .
H19B H 1.2305 0.0216 0.4740 0.047 Uiso 1 1 calc R . .
H19C H 1.3165 0.1233 0.4255 0.047 Uiso 1 1 calc R . .
C21 C 0.9184(4) 0.3365(4) 0.5928(3) 0.0231(7) Uani 1 1 d U . .
C22 C 1.0127(4) 0.4407(4) 0.6616(3) 0.0236(7) Uani 1 1 d U . .
C23 C 0.9728(4) 0.5113(4) 0.7500(3) 0.0265(7) Uani 1 1 d U . .
H23 H 1.0382 0.5808 0.7933 0.032 Uiso 1 1 calc R . .
C24 C 0.8376(4) 0.4816(4) 0.7764(3) 0.0276(7) Uani 1 1 d U . .
C25 C 0.7469(5) 0.3773(4) 0.7119(3) 0.0289(8) Uani 1 1 d U . .
H25 H 0.6553 0.3539 0.7290 0.035 Uiso 1 1 calc R . .
C26 C 0.7868(4) 0.3070(4) 0.6237(3) 0.0267(8) Uani 1 1 d U . .
H26 H 0.7222 0.2359 0.5825 0.032 Uiso 1 1 calc R . .
C27 C 1.1543(4) 0.4722(4) 0.6287(3) 0.0263(8) Uani 1 1 d . . .
H27A H 1.2319 0.5139 0.6943 0.032 Uiso 1 1 calc R . .
H27B H 1.1350 0.5312 0.5751 0.032 Uiso 1 1 calc R . .
C28 C 1.2878(5) 0.2883(4) 0.6671(4) 0.0314(9) Uani 1 1 d . . .
H28A H 1.3248 0.2107 0.6351 0.047 Uiso 1 1 calc R . .
H28B H 1.2178 0.2673 0.7106 0.047 Uiso 1 1 calc R . .
H28C H 1.3727 0.3440 0.7149 0.047 Uiso 1 1 calc R . .
C29 C 1.3165(5) 0.3908(4) 0.5155(4) 0.0312(9) Uani 1 1 d . . .
H29A H 1.3936 0.4534 0.5639 0.047 Uiso 1 1 calc R . .
H29B H 1.2629 0.4275 0.4527 0.047 Uiso 1 1 calc R . .
H29C H 1.3641 0.3165 0.4887 0.047 Uiso 1 1 calc R . .
C110 C 0.4188(4) -0.0310(4) 0.1238(3) 0.0272(7) Uani 1 1 d U . .
C111 C 0.3190(5) 0.0345(5) 0.0711(4) 0.0351(8) Uani 1 1 d U . .
H111 H 0.3308 0.1242 0.0833 0.042 Uiso 1 1 calc R . .
C112 C 0.1939(5) -0.0324(5) -0.0043(4) 0.0406(9) Uani 1 1 d U . .
H112 H 0.1205 0.0140 -0.0441 0.049 Uiso 1 1 calc R . .
C113 C 0.2795(6) -0.2177(5) 0.0347(5) 0.0519(13) Uani 1 1 d U . .
H113 H 0.2674 -0.3073 0.0236 0.062 Uiso 1 1 calc R . .
C114 C 0.4071(5) -0.1577(5) 0.1098(4) 0.0428(11) Uani 1 1 d U . .
H114 H 0.4818 -0.2034 0.1491 0.051 Uiso 1 1 calc R . .
C210 C 0.7898(5) 0.5602(4) 0.8757(3) 0.0279(7) Uani 1 1 d U . .
C211 C 0.6471(6) 0.5637(5) 0.8752(5) 0.0494(12) Uani 1 1 d U . .
H211 H 0.5717 0.5228 0.8131 0.059 Uiso 1 1 calc R . .
C212 C 0.6086(7) 0.6285(6) 0.9673(5) 0.0576(14) Uani 1 1 d U . .
H212 H 0.5053 0.6322 0.9667 0.069 Uiso 1 1 calc R . .
C213 C 0.8523(6) 0.6806(5) 1.0513(4) 0.0460(11) Uani 1 1 d U . .
H213 H 0.9276 0.7219 1.1132 0.055 Uiso 1 1 calc R . .
C214 C 0.8990(6) 0.6195(5) 0.9622(4) 0.0399(10) Uani 1 1 d U . .
H214 H 1.0023 0.6191 0.9618 0.048 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Pt1 C21 97.28(15) . . ?
C11 Pt1 N11 80.44(14) . . ?
C21 Pt1 N11 171.04(14) . . ?
C11 Pt1 N21 171.21(14) . . ?
C21 Pt1 N21 81.16(14) . . ?
N11 Pt1 N21 102.39(12) . . ?
C19 N11 C18 108.8(3) . . ?
C19 N11 C17 107.0(3) . . ?
C18 N11 C17 109.0(3) . . ?
C19 N11 Pt1 116.9(3) . . ?
C18 N11 Pt1 110.7(2) . . ?
C17 N11 Pt1 104.1(2) . . ?
C112 N12 C113 115.9(4) . . ?
C29 N21 C28 109.6(3) . . ?
C29 N21 C27 107.3(3) . . ?
C28 N21 C27 108.4(3) . . ?
C29 N21 Pt1 115.8(3) . . ?
C28 N21 Pt1 110.7(2) . . ?
C27 N21 Pt1 104.5(2) . . ?
C213 N22 C212 115.9(5) . . ?
C16 C11 C12 115.6(4) . . ?
C16 C11 Pt1 128.2(3) . . ?
C12 C11 Pt1 115.7(3) . . ?
C13 C12 C11 122.6(4) . . ?
C13 C12 C17 122.2(4) . . ?
C11 C12 C17 115.1(3) . . ?
C12 C13 C14 120.4(4) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 H13 119.8 . . ?
C15 C14 C13 117.7(4) . . ?
C15 C14 C110 121.5(3) . . ?
C13 C14 C110 120.8(4) . . ?
C16 C15 C14 121.3(4) . . ?
C16 C15 H15 119.3 . . ?
C14 C15 H15 119.3 . . ?
C15 C16 C11 122.1(4) . . ?
C15 C16 H16 118.9 . . ?
C11 C16 H16 118.9 . . ?
N11 C17 C12 108.9(3) . . ?
N11 C17 H17A 109.9 . . ?
C12 C17 H17A 109.9 . . ?
N11 C17 H17B 109.9 . . ?
C12 C17 H17B 109.9 . . ?
H17A C17 H17B 108.3 . . ?
N11 C18 H18A 109.5 . . ?
N11 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N11 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N11 C19 H19A 109.5 . . ?
N11 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
N11 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C26 C21 C22 115.4(4) . . ?
C26 C21 Pt1 128.5(3) . . ?
C22 C21 Pt1 115.6(3) . . ?
C23 C22 C21 122.1(4) . . ?
C23 C22 C27 122.4(4) . . ?
C21 C22 C27 115.4(3) . . ?
C22 C23 C24 120.9(4) . . ?
C22 C23 H23 119.5 . . ?
C24 C23 H23 119.5 . . ?
C25 C24 C23 117.4(4) . . ?
C25 C24 C210 120.8(4) . . ?
C23 C24 C210 121.8(4) . . ?
C26 C25 C24 121.6(4) . . ?
C26 C25 H25 119.2 . . ?
C24 C25 H25 119.2 . . ?
C25 C26 C21 122.4(4) . . ?
C25 C26 H26 118.8 . . ?
C21 C26 H26 118.8 . . ?
C22 C27 N21 109.6(3) . . ?
C22 C27 H27A 109.7 . . ?
N21 C27 H27A 109.7 . . ?
C22 C27 H27B 109.7 . . ?
N21 C27 H27B 109.7 . . ?
H27A C27 H27B 108.2 . . ?
N21 C28 H28A 109.5 . . ?
N21 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
N21 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N21 C29 H29A 109.5 . . ?
N21 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
N21 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C111 C110 C114 123.7(4) . . ?
C111 C110 C14 119.7(4) . . ?
C114 C110 C14 116.5(4) . . ?
C110 C111 C112 117.3(5) . . ?
C110 C111 H111 121.4 . . ?
C112 C111 H111 121.4 . . ?
N12 C112 C111 123.2(5) . . ?
N12 C112 H112 118.4 . . ?
C111 C112 H112 118.4 . . ?
N12 C113 C114 124.0(5) . . ?
N12 C113 H113 118.0 . . ?
C114 C113 H113 118.0 . . ?
C110 C114 C113 115.9(5) . . ?
C110 C114 H114 122.0 . . ?
C113 C114 H114 122.0 . . ?
C211 C210 C214 121.8(5) . . ?
C211 C210 C24 120.0(4) . . ?
C214 C210 C24 118.3(4) . . ?
C210 C211 C212 118.6(5) . . ?
C210 C211 H211 120.7 . . ?
C212 C211 H211 120.7 . . ?
N22 C212 C211 122.5(5) . . ?
N22 C212 H212 118.8 . . ?
C211 C212 H212 118.8 . . ?
N22 C213 C214 124.9(5) . . ?
N22 C213 H213 117.6 . . ?
C214 C213 H213 117.6 . . ?
C210 C214 C213 116.4(5) . . ?
C210 C214 H214 121.8 . . ?
C213 C214 H214 121.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C11 1.980(4) . ?
Pt1 C21 1.981(4) . ?
Pt1 N11 2.191(3) . ?
Pt1 N21 2.202(3) . ?
N11 C19 1.484(5) . ?
N11 C18 1.487(5) . ?
N11 C17 1.498(5) . ?
N12 C112 1.327(7) . ?
N12 C113 1.336(7) . ?
N21 C29 1.474(5) . ?
N21 C28 1.482(5) . ?
N21 C27 1.504(5) . ?
N22 C213 1.315(7) . ?
N22 C212 1.336(7) . ?
C11 C16 1.403(5) . ?
C11 C12 1.411(6) . ?
C12 C13 1.378(6) . ?
C12 C17 1.501(5) . ?
C13 C14 1.409(5) . ?
C13 H13 0.9500 . ?
C14 C15 1.387(6) . ?
C14 C110 1.573(6) . ?
C15 C16 1.385(6) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C21 C26 1.395(5) . ?
C21 C22 1.424(5) . ?
C22 C23 1.384(6) . ?
C22 C27 1.497(5) . ?
C23 C24 1.397(6) . ?
C23 H23 0.9500 . ?
C24 C25 1.392(6) . ?
C24 C210 1.565(6) . ?
C25 C26 1.380(6) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C110 C111 1.302(6) . ?
C110 C114 1.344(6) . ?
C111 C112 1.398(6) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
C113 C114 1.385(7) . ?
C113 H113 0.9500 . ?
C114 H114 0.9500 . ?
C210 C211 1.312(7) . ?
C210 C214 1.352(6) . ?
C211 C212 1.391(7) . ?
C211 H211 0.9500 . ?
C212 H212 0.9500 . ?
C213 C214 1.382(7) . ?
C213 H213 0.9500 . ?
C214 H214 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C11 Pt1 N11 C19 -149.1(3) . . . . ?
N21 Pt1 N11 C19 39.3(3) . . . . ?
C11 Pt1 N11 C18 85.6(3) . . . . ?
N21 Pt1 N11 C18 -86.0(3) . . . . ?
C11 Pt1 N11 C17 -31.4(2) . . . . ?
N21 Pt1 N11 C17 157.1(2) . . . . ?
C21 Pt1 N21 C29 -146.0(3) . . . . ?
N11 Pt1 N21 C29 42.3(3) . . . . ?
C21 Pt1 N21 C28 88.4(3) . . . . ?
N11 Pt1 N21 C28 -83.2(3) . . . . ?
C21 Pt1 N21 C27 -28.2(2) . . . . ?
N11 Pt1 N21 C27 160.2(2) . . . . ?
C21 Pt1 C11 C16 32.8(4) . . . . ?
N11 Pt1 C11 C16 -155.9(4) . . . . ?
C21 Pt1 C11 C12 -155.8(3) . . . . ?
N11 Pt1 C11 C12 15.4(3) . . . . ?
C16 C11 C12 C13 -2.4(6) . . . . ?
Pt1 C11 C12 C13 -174.9(3) . . . . ?
C16 C11 C12 C17 177.3(3) . . . . ?
Pt1 C11 C12 C17 4.8(5) . . . . ?
C11 C12 C13 C14 1.5(6) . . . . ?
C17 C12 C13 C14 -178.1(4) . . . . ?
C12 C13 C14 C15 0.8(6) . . . . ?
C12 C13 C14 C110 -179.2(3) . . . . ?
C13 C14 C15 C16 -2.1(6) . . . . ?
C110 C14 C15 C16 177.9(4) . . . . ?
C14 C15 C16 C11 1.2(6) . . . . ?
C12 C11 C16 C15 1.1(6) . . . . ?
Pt1 C11 C16 C15 172.4(3) . . . . ?
C19 N11 C17 C12 165.7(3) . . . . ?
C18 N11 C17 C12 -76.9(4) . . . . ?
Pt1 N11 C17 C12 41.2(3) . . . . ?
C13 C12 C17 N11 146.7(4) . . . . ?
C11 C12 C17 N11 -32.9(5) . . . . ?
C11 Pt1 C21 C26 29.8(4) . . . . ?
N21 Pt1 C21 C26 -159.0(4) . . . . ?
C11 Pt1 C21 C22 -159.0(3) . . . . ?
N21 Pt1 C21 C22 12.2(3) . . . . ?
C26 C21 C22 C23 -2.9(5) . . . . ?
Pt1 C21 C22 C23 -175.2(3) . . . . ?
C26 C21 C22 C27 179.8(3) . . . . ?
Pt1 C21 C22 C27 7.4(4) . . . . ?
C21 C22 C23 C24 0.9(6) . . . . ?
C27 C22 C23 C24 178.0(4) . . . . ?
C22 C23 C24 C25 1.3(6) . . . . ?
C22 C23 C24 C210 -179.8(3) . . . . ?
C23 C24 C25 C26 -1.3(6) . . . . ?
C210 C24 C25 C26 179.8(4) . . . . ?
C24 C25 C26 C21 -0.9(6) . . . . ?
C22 C21 C26 C25 2.9(6) . . . . ?
Pt1 C21 C26 C25 174.0(3) . . . . ?
C23 C22 C27 N21 149.9(4) . . . . ?
C21 C22 C27 N21 -32.7(4) . . . . ?
C29 N21 C27 C22 162.2(3) . . . . ?
C28 N21 C27 C22 -79.5(4) . . . . ?
Pt1 N21 C27 C22 38.7(3) . . . . ?
C15 C14 C110 C111 33.5(6) . . . . ?
C13 C14 C110 C111 -146.6(4) . . . . ?
C15 C14 C110 C114 -143.8(4) . . . . ?
C13 C14 C110 C114 36.1(5) . . . . ?
C114 C110 C111 C112 -0.3(7) . . . . ?
C14 C110 C111 C112 -177.4(4) . . . . ?
C113 N12 C112 C111 -0.4(8) . . . . ?
C110 C111 C112 N12 0.7(7) . . . . ?
C112 N12 C113 C114 -0.3(9) . . . . ?
C111 C110 C114 C113 -0.3(7) . . . . ?
C14 C110 C114 C113 176.9(4) . . . . ?
N12 C113 C114 C110 0.7(9) . . . . ?
C25 C24 C210 C211 -26.9(6) . . . . ?
C23 C24 C210 C211 154.2(5) . . . . ?
C25 C24 C210 C214 150.8(4) . . . . ?
C23 C24 C210 C214 -28.1(6) . . . . ?
C214 C210 C211 C212 -1.2(8) . . . . ?
C24 C210 C211 C212 176.4(5) . . . . ?
C213 N22 C212 C211 2.0(9) . . . . ?
C210 C211 C212 N22 -0.9(10) . . . . ?
C212 N22 C213 C214 -1.1(8) . . . . ?
C211 C210 C214 C213 1.9(7) . . . . ?
C24 C210 C214 C213 -175.7(4) . . . . ?
N22 C213 C214 C210 -0.7(8) . . . . ?
