#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:36:30 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179148 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/09/4310969.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4310969
loop_
_publ_author_name
'Éric Fournier'
'Frédéric Lebrun'
'Marc Drouin'
'Andreas Decken'
'Pierre D. Harvey'
_publ_section_title
;
 Preparation and Solid-State Characterization of Mixed-Ligand
 Coordination/Organometallic Oligomers and Polymers of Copper(I) and
 Silver(I) Using Diphosphine and Mono- and Diisocyanide Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3127
_journal_page_last               3135
_journal_paper_doi               10.1021/ic034806m
_journal_volume                  43
_journal_year                    2004
_chemical_formula_sum            'C70 H80 Ag2 Cl2 N4 O8 P2'
_chemical_formula_weight         1453.96
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.96
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.650
_cell_length_b                   13.315
_cell_length_c                   23.352
_cell_measurement_temperature    293(2)
_cell_volume                     6052.448
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_wavelength     0.70930
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.1411
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            10585
_diffrn_reflns_theta_full        24.94
_diffrn_reflns_theta_max         24.94
_diffrn_reflns_theta_min         1.71
_exptl_absorpt_coefficient_mu    0.852
_exptl_crystal_density_diffrn    1.596
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3000
_refine_diff_density_max         0.808
_refine_diff_density_min         -0.850
_refine_diff_density_rms         0.112
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.903
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     617
_refine_ls_number_reflns         10585
_refine_ls_number_restraints     50
_refine_ls_restrained_S_all      0.905
_refine_ls_R_factor_all          0.2167
_refine_ls_R_factor_gt           0.0918
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1148P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1989
_refine_ls_wR_factor_ref         0.2478
_reflns_number_gt                4030
_reflns_number_total             10585
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034806mrom20030711_100823.cif
_cod_data_source_block           shelx
_cod_original_cell_volume        6052.4
_cod_database_code               4310969
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3682(6) 0.4485(10) 0.0702(6) 0.060(3) Uani 1 1 d . . .
C2 C 0.3738(9) 0.5358(12) 0.1022(8) 0.093(5) Uani 1 1 d . . .
H2 H 0.3494 0.5915 0.0794 0.111 Uiso 1 1 calc . . .
C3 C 0.4134(9) 0.5460(14) 0.1663(10) 0.104(6) Uani 1 1 d . . .
H3 H 0.4170 0.6082 0.1856 0.124 Uiso 1 1 calc . . .
C4 C 0.4477(9) 0.4649(16) 0.2020(8) 0.097(5) Uani 1 1 d . . .
H4 H 0.4708 0.4694 0.2462 0.117 Uiso 1 1 calc . . .
C5 C 0.4473(8) 0.3773(14) 0.1715(8) 0.095(5) Uani 1 1 d . . .
H5 H 0.4748 0.3241 0.1945 0.114 Uiso 1 1 calc . . .
C6 C 0.4071(8) 0.3670(10) 0.1079(7) 0.074(4) Uani 1 1 d . . .
H6 H 0.4051 0.3051 0.0887 0.089 Uiso 1 1 calc . . .
C13 C 0.2351(5) 0.4941(8) -0.0367(5) 0.046(3) Uani 1 1 d . K .
H13A H 0.2437 0.5567 -0.0132 0.055 Uiso 1 1 calc . . .
H13B H 0.2160 0.5108 -0.0817 0.055 Uiso 1 1 calc . . .
C14 C 0.1939(6) 0.4415(9) 0.0615(6) 0.060(3) Uani 1 1 d . K .
C15 C 0.1880(6) 0.3646(10) 0.0960(6) 0.063(4) Uani 1 1 d . . .
H15 H 0.1733 0.3030 0.0758 0.075 Uiso 1 1 calc . . .
C16 C 0.2022(7) 0.3710(12) 0.1594(7) 0.077(4) Uani 1 1 d . . .
H16 H 0.1981 0.3151 0.1815 0.092 Uiso 1 1 calc . . .
C17 C 0.2226(8) 0.4623(14) 0.1893(7) 0.079(4) Uani 1 1 d . . .
H17 H 0.2306 0.4700 0.2316 0.095 Uiso 1 1 calc . . .
C18 C 0.2307(8) 0.5401(13) 0.1567(8) 0.093(5) Uani 1 1 d . . .
H18 H 0.2467 0.6010 0.1774 0.112 Uiso 1 1 calc . . .
C19 C 0.2159(7) 0.5316(9) 0.0929(6) 0.062(4) Uani 1 1 d . . .
H19 H 0.2208 0.5872 0.0711 0.074 Uiso 1 1 calc . . .
C20 C 0.0934(6) 0.4973(8) -0.0664(6) 0.047(3) Uani 1 1 d . K .
C21 C 0.0672(6) 0.5013(10) -0.1320(6) 0.062(4) Uani 1 1 d . . .
H21 H 0.0905 0.4695 -0.1522 0.074 Uiso 1 1 calc . . .
C22 C 0.0073(8) 0.5516(11) -0.1676(7) 0.080(4) Uani 1 1 d . . .
H22 H -0.0108 0.5527 -0.2118 0.096 Uiso 1 1 calc . . .
C23 C -0.0263(6) 0.6012(11) -0.1366(9) 0.080(5) Uani 1 1 d . . .
H23 H -0.0656 0.6386 -0.1601 0.096 Uiso 1 1 calc . . .
C24 C -0.0018(8) 0.5949(11) -0.0726(8) 0.082(4) Uani 1 1 d . . .
H24 H -0.0257 0.6255 -0.0525 0.099 Uiso 1 1 calc . . .
C25 C 0.0577(7) 0.5441(10) -0.0371(6) 0.064(4) Uani 1 1 d . . .
H25 H 0.0743 0.5409 0.0069 0.077 Uiso 1 1 calc . . .
C32 C 0.1534(6) -0.0290(9) -0.0391(6) 0.049(3) Uani 1 1 d . K .
C33 C 0.1618(7) -0.1211(10) -0.0094(6) 0.068(4) Uani 1 1 d . . .
H33 H 0.1844 -0.1230 0.0348 0.082 Uiso 1 1 calc . . .
C34 C 0.1395(10) -0.2078(12) -0.0405(13) 0.107(7) Uani 1 1 d . . .
H34 H 0.1448 -0.2683 -0.0190 0.128 Uiso 1 1 calc . . .
C35 C 0.1073(9) -0.2030(15) -0.1078(12) 0.104(7) Uani 1 1 d . . .
H35 H 0.0900 -0.2615 -0.1311 0.124 Uiso 1 1 calc . . .
C36 C 0.1012(9) -0.1164(16) -0.1384(9) 0.110(7) Uani 1 1 d . . .
H36 H 0.0827 -0.1151 -0.1826 0.132 Uiso 1 1 calc . . .
C37 C 0.1228(7) -0.0283(10) -0.1037(7) 0.073(4) Uani 1 1 d . . .
H37 H 0.1162 0.0326 -0.1251 0.088 Uiso 1 1 calc . . .
C26 C 0.1436(6) 0.0851(9) 0.0603(6) 0.051(3) Uani 1 1 d . K .
C27 C 0.1808(6) 0.0829(12) 0.1243(6) 0.074(4) Uani 1 1 d . . .
H27 H 0.2281 0.0735 0.1420 0.088 Uiso 1 1 calc . . .
C28 C 0.1475(9) 0.0951(13) 0.1642(7) 0.098(5) Uani 1 1 d . . .
H28 H 0.1727 0.0941 0.2083 0.118 Uiso 1 1 calc . . .
C29 C 0.0795(8) 0.1079(12) 0.1378(8) 0.087(5) Uani 1 1 d . . .
H29 H 0.0571 0.1169 0.1635 0.104 Uiso 1 1 calc . . .
C30 C 0.0425(7) 0.1078(14) 0.0722(8) 0.095(5) Uani 1 1 d . . .
H30 H -0.0052 0.1122 0.0541 0.113 Uiso 1 1 calc . . .
C31 C 0.0752(6) 0.1013(12) 0.0335(6) 0.073(4) Uani 1 1 d . . .
H31 H 0.0506 0.1079 -0.0104 0.088 Uiso 1 1 calc . . .
C38 C 0.2751(5) 0.0662(8) 0.0532(5) 0.048(3) Uani 1 1 d . K .
H38A H 0.2913 0.1109 0.0897 0.058 Uiso 1 1 calc . . .
H38B H 0.2823 -0.0023 0.0689 0.058 Uiso 1 1 calc . . .
C45 C 0.4124(6) 0.0790(8) 0.0672(6) 0.050(3) Uani 1 1 d . . .
C46 C 0.4347(6) 0.0746(12) 0.1321(5) 0.069(4) Uani 1 1 d . . .
H46 H 0.4034 0.0660 0.1490 0.083 Uiso 1 1 calc . . .
C47 C 0.5031(7) 0.0830(12) 0.1712(6) 0.079(4) Uani 1 1 d . . .
H47 H 0.5166 0.0866 0.2148 0.095 Uiso 1 1 calc . . .
C48 C 0.5528(6) 0.0865(12) 0.1506(8) 0.088(5) Uani 1 1 d . . .
H48 H 0.5993 0.0872 0.1788 0.105 Uiso 1 1 calc . . .
C49 C 0.5309(7) 0.0889(14) 0.0859(7) 0.089(5) Uani 1 1 d . . .
H49 H 0.5634 0.0932 0.0699 0.107 Uiso 1 1 calc . . .
C50 C 0.4644(6) 0.0854(11) 0.0451(6) 0.068(4) Uani 1 1 d . . .
H50 H 0.4516 0.0872 0.0015 0.082 Uiso 1 1 calc . . .
C39 C 0.3097(6) -0.0219(8) -0.0432(6) 0.047(3) Uani 1 1 d . . .
C40 C 0.3234(7) -0.1179(9) -0.0150(7) 0.070(4) Uani 1 1 d . . .
H40 H 0.3392 -0.1291 0.0285 0.084 Uiso 1 1 calc . . .
C41 C 0.3102(9) -0.1966(11) -0.0611(12) 0.103(6) Uani 1 1 d . . .
H41 H 0.3159 -0.2630 -0.0473 0.124 Uiso 1 1 calc . . .
C43 C 0.2900(10) -0.1779(17) -0.1234(11) 0.108(7) Uani 1 1 d . . .
H43 H 0.2858 -0.2318 -0.1502 0.130 Uiso 1 1 calc . . .
C42 C 0.2762(8) -0.0890(15) -0.1478(7) 0.086(5) Uani 1 1 d . . .
H42 H 0.2602 -0.0793 -0.1914 0.104 Uiso 1 1 calc . . .
C44 C 0.2860(6) -0.0083(10) -0.1069(7) 0.066(4) Uani 1 1 d . . .
H44 H 0.2761 0.0564 -0.1236 0.079 Uiso 1 1 calc . . .
C7 C 0.3595(7) 0.5059(9) -0.0525(7) 0.061(4) Uani 1 1 d . . .
C8 C 0.3269(8) 0.5079(12) -0.1192(7) 0.088(5) Uani 1 1 d . . .
H8 H 0.2870 0.4711 -0.1416 0.106 Uiso 1 1 calc . . .
C9 C 0.3551(10) 0.5654(14) -0.1510(8) 0.106(6) Uani 1 1 d . . .
H9 H 0.3345 0.5676 -0.1953 0.127 Uiso 1 1 calc . . .
C10 C 0.4134(11) 0.6188(14) -0.1169(11) 0.110(7) Uani 1 1 d . . .
H10 H 0.4315 0.6590 -0.1384 0.132 Uiso 1 1 calc . . .
C11 C 0.4458(8) 0.6149(13) -0.0525(10) 0.100(6) Uani 1 1 d . . .
H11 H 0.4874 0.6480 -0.0305 0.120 Uiso 1 1 calc . . .
C12 C 0.4171(7) 0.5624(11) -0.0199(7) 0.077(4) Uani 1 1 d . . .
H12 H 0.4368 0.5650 0.0244 0.092 Uiso 1 1 calc . . .
Ag2 Ag 0.15601(5) 0.24621(7) -0.05363(5) 0.0606(3) Uani 1 1 d . K .
Ag1 Ag 0.31019(5) 0.25212(7) -0.04124(4) 0.0597(3) Uani 1 1 d . . .
P2 P 0.17159(17) 0.4231(2) -0.02256(15) 0.0490(8) Uani 1 1 d . . .
P1 P 0.31841(18) 0.4283(2) -0.01382(16) 0.0535(9) Uani 1 1 d . K .
P4 P 0.32456(15) 0.0881(2) 0.00840(13) 0.0418(7) Uani 1 1 d . K .
P3 P 0.18329(15) 0.0871(2) 0.00434(14) 0.0434(7) Uani 1 1 d . . .
Cl2 Cl 0.3301(2) 0.8190(3) 0.17532(19) 0.0821(11) Uiso 1 1 d D . .
O5 O 0.2921(12) 0.7680(16) 0.1187(8) 0.137(5) Uani 0.504(10) 1 d PD . .
O6 O 0.3109(12) 0.9138(12) 0.1783(12) 0.137(5) Uani 0.504(10) 1 d PD . .
O7 O 0.3978(8) 0.8220(17) 0.1830(11) 0.137(5) Uani 0.504(10) 1 d PD . .
O8 O 0.3278(13) 0.7600(16) 0.2232(10) 0.137(5) Uani 0.504(10) 1 d PD . .
O5' O 0.3490(13) 0.9193(12) 0.1903(12) 0.137(5) Uani 0.496(10) 1 d PD . .
O6' O 0.3345(14) 0.7906(17) 0.1217(9) 0.137(5) Uani 0.496(10) 1 d PD . .
O7' O 0.2637(8) 0.8115(17) 0.1685(11) 0.137(5) Uani 0.496(10) 1 d PD . .
O8' O 0.3720(12) 0.7625(17) 0.2275(9) 0.137(5) Uani 0.496(10) 1 d PD . .
Cl1 Cl 0.1714(2) 0.2669(3) -0.19720(17) 0.0918(13) Uani 1 1 d D . .
O1 O 0.2134(7) 0.2559(10) -0.2285(6) 0.162(3) Uani 1 1 d D K .
O2 O 0.1082(6) 0.2323(9) -0.2389(6) 0.162(3) Uani 1 1 d D K .
O3 O 0.1676(7) 0.3668(8) -0.1851(6) 0.162(3) Uani 1 1 d D K .
O4 O 0.1966(7) 0.2117(9) -0.1421(5) 0.162(3) Uani 1 1 d D K .
C51 C 0.0381(12) 0.2365(15) -0.1187(10) 0.132(7) Uiso 1 1 d . . .
N1 N -0.0191(14) 0.241(2) -0.1420(14) 0.267(14) Uiso 1 1 d D A .
C52 C -0.0923(15) 0.2514(18) -0.1696(13) 0.50(5) Uiso 1 1 d D . .
C53 C -0.1096(18) 0.294(3) -0.1269(17) 0.337(13) Uiso 1 1 d D A 1
H53A H -0.0790 0.3488 -0.1066 0.506 Uiso 1 1 calc . B 1
H53B H -0.1063 0.2451 -0.0954 0.506 Uiso 1 1 calc . C 1
H53C H -0.1559 0.3185 -0.1479 0.506 Uiso 1 1 calc . D 1
C54 C -0.1231(17) 0.163(2) -0.1834(18) 0.337(13) Uiso 1 1 d D A 1
H54A H -0.1230 0.1375 -0.2219 0.506 Uiso 1 1 calc . E 1
H54B H -0.1696 0.1698 -0.1892 0.506 Uiso 1 1 calc . F 1
H54C H -0.0990 0.1168 -0.1492 0.506 Uiso 1 1 calc . G 1
C55 C -0.1186(18) 0.306(3) -0.2231(15) 0.337(13) Uiso 1 1 d D A 1
H55A H -0.1011 0.2814 -0.2518 0.506 Uiso 1 1 calc . H 1
H55B H -0.1058 0.3749 -0.2131 0.506 Uiso 1 1 calc . I 1
H55C H -0.1677 0.3001 -0.2427 0.506 Uiso 1 1 calc . J 1
C56 C 0.3865(10) 0.2434(14) -0.0920(9) 0.116(6) Uiso 1 1 d . K 1
N2 N 0.4031(15) 0.232(2) -0.1310(13) 0.263(13) Uiso 1 1 d D K 1
C57 C 0.4269(13) 0.2317(17) -0.1817(12) 0.353(13) Uiso 1 1 d D K 1
C58 C 0.3882(19) 0.176(3) -0.2317(15) 0.353(13) Uiso 1 1 d D K 1
H58A H 0.3443 0.2079 -0.2545 0.529 Uiso 1 1 calc . L 1
H58B H 0.3819 0.1109 -0.2176 0.529 Uiso 1 1 calc . M 1
H58C H 0.4104 0.1695 -0.2592 0.529 Uiso 1 1 calc . N 1
C59 C 0.4902(15) 0.198(3) -0.1569(18) 0.353(13) Uiso 1 1 d D K 1
H59A H 0.5175 0.2364 -0.1193 0.529 Uiso 1 1 calc . O 1
H59B H 0.5087 0.2057 -0.1872 0.529 Uiso 1 1 calc . P 1
H59C H 0.4907 0.1288 -0.1459 0.529 Uiso 1 1 calc . Q 1
C60 C 0.426(2) 0.326(2) -0.1999(17) 0.353(13) Uiso 1 1 d D K 1
H60A H 0.4597 0.3641 -0.1655 0.529 Uiso 1 1 calc . R 1
H60B H 0.3813 0.3542 -0.2116 0.529 Uiso 1 1 calc . S 1
H60C H 0.4365 0.3281 -0.2358 0.529 Uiso 1 1 calc . T 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 115.2(13) . . ?
C2 C1 P1 126.5(12) . . ?
C6 C1 P1 118.2(10) . . ?
C3 C2 C1 123.3(16) . . ?
C3 C2 H2 118.3 . . ?
C1 C2 H2 118.3 . . ?
C2 C3 C4 120.2(16) . . ?
C2 C3 H3 119.9 . . ?
C4 C3 H3 119.9 . . ?
C5 C4 C3 118.6(15) . . ?
C5 C4 H4 120.7 . . ?
C3 C4 H4 120.7 . . ?
C6 C5 C4 120.7(17) . . ?
C6 C5 H5 119.6 . . ?
C4 C5 H5 119.6 . . ?
C5 C6 C1 121.5(14) . . ?
C5 C6 H6 119.2 . . ?
C1 C6 H6 119.2 . . ?
P2 C13 P1 114.7(6) . . ?
P2 C13 H13A 108.6 . . ?
P1 C13 H13A 108.6 . . ?
P2 C13 H13B 108.6 . . ?
P1 C13 H13B 108.6 . . ?
H13A C13 H13B 107.6 . . ?
C15 C14 C19 116.4(12) . . ?
C15 C14 P2 119.6(10) . . ?
C19 C14 P2 123.9(10) . . ?
C14 C15 C16 124.3(13) . . ?
C14 C15 H15 117.9 . . ?
C16 C15 H15 117.9 . . ?
C15 C16 C17 118.2(13) . . ?
C15 C16 H16 120.9 . . ?
C17 C16 H16 120.9 . . ?
C18 C17 C16 119.1(14) . . ?
C18 C17 H17 120.4 . . ?
C16 C17 H17 120.4 . . ?
C19 C18 C17 121.4(15) . . ?
C19 C18 H18 119.3 . . ?
C17 C18 H18 119.3 . . ?
C18 C19 C14 120.5(13) . . ?
C18 C19 H19 119.7 . . ?
C14 C19 H19 119.7 . . ?
C21 C20 C25 118.9(11) . . ?
C21 C20 P2 118.0(9) . . ?
C25 C20 P2 123.0(9) . . ?
C22 C21 C20 120.8(12) . . ?
C22 C21 H21 119.6 . . ?
C20 C21 H21 119.6 . . ?
C23 C22 C21 119.1(13) . . ?
C23 C22 H22 120.5 . . ?
C21 C22 H22 120.5 . . ?
C24 C23 C22 120.2(12) . . ?
C24 C23 H23 119.9 . . ?
C22 C23 H23 119.9 . . ?
C23 C24 C25 120.6(14) . . ?
C23 C24 H24 119.7 . . ?
C25 C24 H24 119.7 . . ?
C24 C25 C20 120.4(13) . . ?
C24 C25 H25 119.8 . . ?
C20 C25 H25 119.8 . . ?
C37 C32 C33 117.2(12) . . ?
C37 C32 P3 119.9(10) . . ?
C33 C32 P3 122.8(10) . . ?
C34 C33 C32 123.9(15) . . ?
C34 C33 H33 118.1 . . ?
C32 C33 H33 118.1 . . ?
C33 C34 C35 116.8(17) . . ?
C33 C34 H34 121.6 . . ?
C35 C34 H34 121.6 . . ?
C36 C35 C34 121.3(17) . . ?
C36 C35 H35 119.4 . . ?
C34 C35 H35 119.4 . . ?
C35 C36 C37 119.3(17) . . ?
C35 C36 H36 120.3 . . ?
C37 C36 H36 120.3 . . ?
C32 C37 C36 121.4(15) . . ?
C32 C37 H37 119.3 . . ?
C36 C37 H37 119.3 . . ?
C27 C26 C31 121.1(11) . . ?
C27 C26 P3 122.9(9) . . ?
C31 C26 P3 115.2(9) . . ?
C26 C27 C28 119.8(12) . . ?
C26 C27 H27 120.1 . . ?
C28 C27 H27 120.1 . . ?
C29 C28 C27 119.2(14) . . ?
C29 C28 H28 120.4 . . ?
C27 C28 H28 120.4 . . ?
C28 C29 C30 119.9(14) . . ?
C28 C29 H29 120.1 . . ?
C30 C29 H29 120.1 . . ?
C31 C30 C29 120.9(13) . . ?
C31 C30 H30 119.6 . . ?
C29 C30 H30 119.6 . . ?
C26 C31 C30 118.9(12) . . ?
C26 C31 H31 120.6 . . ?
C30 C31 H31 120.6 . . ?
P4 C38 P3 111.7(6) . . ?
P4 C38 H38A 109.3 . . ?
P3 C38 H38A 109.3 . . ?
P4 C38 H38B 109.3 . . ?
P3 C38 H38B 109.3 . . ?
H38A C38 H38B 107.9 . . ?
C46 C45 C50 116.6(11) . . ?
C46 C45 P4 126.0(9) . . ?
C50 C45 P4 117.2(9) . . ?
C47 C46 C45 119.4(12) . . ?
C47 C46 H46 120.3 . . ?
C45 C46 H46 120.3 . . ?
C46 C47 C48 124.1(13) . . ?
C46 C47 H47 117.9 . . ?
C48 C47 H47 117.9 . . ?
C47 C48 C49 116.5(12) . . ?
C47 C48 H48 121.8 . . ?
C49 C48 H48 121.8 . . ?
C50 C49 C48 122.0(13) . . ?
C50 C49 H49 119.0 . . ?
C48 C49 H49 119.0 . . ?
C49 C50 C45 121.2(12) . . ?
C49 C50 H50 119.4 . . ?
C45 C50 H50 119.4 . . ?
C44 C39 C40 122.4(11) . . ?
C44 C39 P4 119.1(9) . . ?
C40 C39 P4 118.4(9) . . ?
C39 C40 C41 112.2(14) . . ?
C39 C40 H40 123.9 . . ?
C41 C40 H40 123.9 . . ?
C43 C41 C40 122.6(16) . . ?
C43 C41 H41 118.7 . . ?
C40 C41 H41 118.7 . . ?
C42 C43 C41 123.3(19) . . ?
C42 C43 H43 118.3 . . ?
C41 C43 H43 118.3 . . ?
C43 C42 C44 118.0(16) . . ?
C43 C42 H42 121.0 . . ?
C44 C42 H42 121.0 . . ?
C39 C44 C42 121.3(14) . . ?
C39 C44 H44 119.4 . . ?
C42 C44 H44 119.4 . . ?
C12 C7 C8 120.1(13) . . ?
C12 C7 P1 123.7(11) . . ?
C8 C7 P1 116.2(11) . . ?
C9 C8 C7 118.9(15) . . ?
C9 C8 H8 120.6 . . ?
C7 C8 H8 120.6 . . ?
C10 C9 C8 119.3(16) . . ?
C10 C9 H9 120.4 . . ?
C8 C9 H9 120.4 . . ?
C11 C10 C9 121.8(15) . . ?
C11 C10 H10 119.1 . . ?
C9 C10 H10 119.1 . . ?
C10 C11 C12 119.8(17) . . ?
C10 C11 H11 120.1 . . ?
C12 C11 H11 120.1 . . ?
C7 C12 C11 119.8(15) . . ?
C7 C12 H12 120.1 . . ?
C11 C12 H12 120.1 . . ?
C51 Ag2 P3 104.1(5) . . ?
C51 Ag2 P2 102.5(5) . . ?
P3 Ag2 P2 134.62(11) . . ?
C51 Ag2 O4 97.3(6) . . ?
P3 Ag2 O4 101.7(3) . . ?
P2 Ag2 O4 110.7(3) . . ?
C51 Ag2 Ag1 148.7(5) . . ?
P3 Ag2 Ag1 88.96(7) . . ?
P2 Ag2 Ag1 86.96(8) . . ?
O4 Ag2 Ag1 51.8(3) . . ?
P1 Ag1 P4 140.10(12) . . ?
P1 Ag1 C56 100.9(5) . . ?
P4 Ag1 C56 102.6(4) . . ?
P1 Ag1 O4 111.7(3) . . ?
P4 Ag1 O4 96.8(3) . . ?
C56 Ag1 O4 97.1(5) . . ?
P1 Ag1 Ag2 90.05(8) . . ?
P4 Ag1 Ag2 86.11(7) . . ?
C56 Ag1 Ag2 148.9(5) . . ?
O4 Ag1 Ag2 52.0(3) . . ?
C13 P2 C14 105.2(6) . . ?
C13 P2 C20 101.8(5) . . ?
C14 P2 C20 105.9(6) . . ?
C13 P2 Ag2 117.7(4) . . ?
C14 P2 Ag2 112.8(4) . . ?
C20 P2 Ag2 112.3(4) . . ?
C1 P1 C7 105.4(6) . . ?
C1 P1 C13 106.6(5) . . ?
C7 P1 C13 102.2(5) . . ?
C1 P1 Ag1 111.9(4) . . ?
C7 P1 Ag1 114.2(4) . . ?
C13 P1 Ag1 115.5(4) . . ?
C45 P4 C38 104.1(5) . . ?
C45 P4 C39 105.7(5) . . ?
C38 P4 C39 105.8(5) . . ?
C45 P4 Ag1 107.3(4) . . ?
C38 P4 Ag1 115.7(4) . . ?
C39 P4 Ag1 117.1(4) . . ?
C32 P3 C38 104.1(5) . . ?
C32 P3 C26 102.8(5) . . ?
C38 P3 C26 105.7(5) . . ?
C32 P3 Ag2 119.4(4) . . ?
C38 P3 Ag2 114.3(4) . . ?
C26 P3 Ag2 109.2(4) . . ?
O6' Cl2 O6 117.5(16) . . ?
O6' Cl2 O8' 112.3(12) . . ?
O6 Cl2 O8' 124.5(15) . . ?
O6' Cl2 O7 68.4(13) . . ?
O6 Cl2 O7 107.4(12) . . ?
O8' Cl2 O7 69.9(13) . . ?
O6' Cl2 O5 40.1(13) . . ?
O6 Cl2 O5 116.2(13) . . ?
O8' Cl2 O5 117.3(14) . . ?
O7 Cl2 O5 106.7(12) . . ?
O6' Cl2 O8 129.1(14) . . ?
O6 Cl2 O8 111.7(13) . . ?
O8' Cl2 O8 38.8(12) . . ?
O7 Cl2 O8 108.6(12) . . ?
O5 Cl2 O8 105.9(12) . . ?
O6' Cl2 O5' 111.6(12) . . ?
O6 Cl2 O5' 31.7(14) . . ?
O8' Cl2 O5' 107.1(12) . . ?
O7 Cl2 O5' 76.4(13) . . ?
O5 Cl2 O5' 133.8(14) . . ?
O8 Cl2 O5' 116.8(15) . . ?
O6' Cl2 O7' 111.4(12) . . ?
O6 Cl2 O7' 75.1(14) . . ?
O8' Cl2 O7' 108.0(12) . . ?
O7 Cl2 O7' 177.3(13) . . ?
O5 Cl2 O7' 72.6(13) . . ?
O8 Cl2 O7' 69.3(13) . . ?
O5' Cl2 O7' 105.9(12) . . ?
O6' O5 Cl2 67.7(13) . . ?
O6' O5 O7' 119.4(18) . . ?
Cl2 O5 O7' 53.3(9) . . ?
O5' O6 Cl2 78.2(18) . . ?
O5' O6 O7' 130(2) . . ?
Cl2 O6 O7' 53.6(9) . . ?
Cl2 O7 O8' 54.6(8) . . ?
Cl2 O7 O6' 54.5(8) . . ?
O8' O7 O6' 92.8(13) . . ?
Cl2 O7 O5' 51.8(8) . . ?
O8' O7 O5' 84.5(12) . . ?
O6' O7 O5' 87.8(13) . . ?
O8' O8 Cl2 70.4(14) . . ?
O8' O8 O7' 125.5(18) . . ?
Cl2 O8 O7' 55.2(9) . . ?
O6 O5' Cl2 70.1(16) . . ?
O6 O5' O7 121(2) . . ?
Cl2 O5' O7 51.8(8) . . ?
O5 O6' Cl2 72.3(14) . . ?
O5 O6' O7 126.6(19) . . ?
Cl2 O6' O7 57.2(9) . . ?
Cl2 O7' O5 54.0(8) . . ?
Cl2 O7' O6 51.4(8) . . ?
O5 O7' O6 89.4(12) . . ?
Cl2 O7' O8 55.5(8) . . ?
O5 O7' O8 87.2(13) . . ?
O6 O7' O8 88.6(13) . . ?
O8 O8' Cl2 70.9(14) . . ?
O8 O8' O7 126.4(18) . . ?
Cl2 O8' O7 55.5(9) . . ?
O2 Cl1 O4 110.6(8) . . ?
O2 Cl1 O3 110.1(8) . . ?
O4 Cl1 O3 111.2(8) . . ?
O2 Cl1 O1 105.6(8) . . ?
O4 Cl1 O1 110.6(8) . . ?
O3 Cl1 O1 108.7(9) . . ?
Cl1 O4 Ag2 120.9(8) . . ?
Cl1 O4 Ag1 124.5(8) . . ?
Ag2 O4 Ag1 76.2(3) . . ?
N1 C51 Ag2 169(2) . . ?
C51 N1 C52 176(3) . . ?
C54 C52 C53 106.5(19) . . ?
C54 C52 C55 107.0(19) . . ?
C53 C52 C55 109(2) . . ?
C54 C52 N1 111.2(19) . . ?
C53 C52 N1 108.8(18) . . ?
C55 C52 N1 114.2(19) . . ?
C52 C53 H53A 109.5 . . ?
C52 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C52 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C52 C54 H54A 109.5 . . ?
C52 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C52 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C52 C55 H55A 109.5 . . ?
C52 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C52 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
N2 C56 Ag1 159(2) . . ?
C56 N2 C57 173(3) . . ?
C59 C57 C58 109.6(19) . . ?
C59 C57 C60 109(2) . . ?
C58 C57 C60 109.4(19) . . ?
C59 C57 N2 108.0(18) . . ?
C58 C57 N2 113.7(19) . . ?
C60 C57 N2 106.8(18) . . ?
C57 C58 H58A 109.5 . . ?
C57 C58 H58B 109.5 . . ?
H58A C58 H58B 109.5 . . ?
C57 C58 H58C 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C57 C59 H59A 109.5 . . ?
C57 C59 H59B 109.5 . . ?
H59A C59 H59B 109.5 . . ?
C57 C59 H59C 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
C57 C60 H60A 109.5 . . ?
C57 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C57 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.359(18) . ?
C1 C6 1.419(17) . ?
C1 P1 1.797(14) . ?
C2 C3 1.37(2) . ?
C2 H2 0.9300 . ?
C3 C4 1.37(2) . ?
C3 H3 0.9300 . ?
C4 C5 1.36(2) . ?
C4 H4 0.9300 . ?
C5 C6 1.361(19) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C13 P2 1.814(11) . ?
C13 P1 1.862(11) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C15 1.344(16) . ?
C14 C19 1.379(16) . ?
C14 P2 1.821(13) . ?
C15 C16 1.377(17) . ?
C15 H15 0.9300 . ?
C16 C17 1.374(19) . ?
C16 H16 0.9300 . ?
C17 C18 1.34(2) . ?
C17 H17 0.9300 . ?
C18 C19 1.384(18) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 C21 1.382(15) . ?
C20 C25 1.383(16) . ?
C20 P2 1.836(12) . ?
C21 C22 1.371(17) . ?
C21 H21 0.9300 . ?
C22 C23 1.39(2) . ?
C22 H22 0.9300 . ?
C23 C24 1.35(2) . ?
C23 H23 0.9300 . ?
C24 C25 1.368(17) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C32 C37 1.357(16) . ?
C32 C33 1.382(16) . ?
C32 P3 1.806(12) . ?
C33 C34 1.34(2) . ?
C33 H33 0.9300 . ?
C34 C35 1.41(3) . ?
C34 H34 0.9300 . ?
C35 C36 1.33(3) . ?
C35 H35 0.9300 . ?
C36 C37 1.39(2) . ?
C36 H36 0.9300 . ?
C37 H37 0.9300 . ?
C26 C27 1.352(15) . ?
C26 C31 1.350(15) . ?
C26 P3 1.851(11) . ?
C27 C28 1.416(18) . ?
C27 H27 0.9300 . ?
C28 C29 1.335(19) . ?
C28 H28 0.9300 . ?
C29 C30 1.38(2) . ?
C29 H29 0.9300 . ?
C30 C31 1.372(18) . ?
C30 H30 0.9300 . ?
C31 H31 0.9300 . ?
C38 P4 1.819(11) . ?
C38 P3 1.829(11) . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C45 C46 1.375(15) . ?
C45 C50 1.430(15) . ?
C45 P4 1.798(12) . ?
C46 C47 1.361(17) . ?
C46 H46 0.9300 . ?
C47 C48 1.361(19) . ?
C47 H47 0.9300 . ?
C48 C49 1.371(19) . ?
C48 H48 0.9300 . ?
C49 C50 1.336(17) . ?
C49 H49 0.9300 . ?
C50 H50 0.9300 . ?
C39 C44 1.357(16) . ?
C39 C40 1.409(15) . ?
C39 P4 1.834(11) . ?
C40 C41 1.44(2) . ?
C40 H40 0.9300 . ?
C41 C43 1.35(2) . ?
C41 H41 0.9300 . ?
C43 C42 1.29(2) . ?
C43 H43 0.9300 . ?
C42 C44 1.391(18) . ?
C42 H42 0.9300 . ?
C44 H44 0.9300 . ?
C7 C12 1.369(17) . ?
C7 C8 1.400(18) . ?
C7 P1 1.837(12) . ?
C8 C9 1.382(19) . ?
C8 H8 0.9300 . ?
C9 C10 1.36(2) . ?
C9 H9 0.9300 . ?
C10 C11 1.35(2) . ?
C10 H10 0.9300 . ?
C11 C12 1.367(19) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
Ag2 C51 2.33(2) . ?
Ag2 P3 2.443(3) . ?
Ag2 P2 2.444(3) . ?
Ag2 O4 2.615(14) . ?
Ag2 Ag1 3.2227(13) . ?
Ag1 P1 2.418(3) . ?
Ag1 P4 2.427(3) . ?
Ag1 C56 2.42(2) . ?
Ag1 O4 2.610(13) . ?
Cl2 O6' 1.352(14) . ?
Cl2 O6 1.340(14) . ?
Cl2 O8' 1.381(15) . ?
Cl2 O7 1.396(14) . ?
Cl2 O5 1.392(15) . ?
Cl2 O8 1.386(14) . ?
Cl2 O5' 1.395(15) . ?
Cl2 O7' 1.379(14) . ?
O5 O6' 0.94(3) . ?
O5 O7' 1.64(3) . ?
O6 O5' 0.75(3) . ?
O6 O7' 1.66(3) . ?
O7 O8' 1.59(3) . ?
O7 O6' 1.54(3) . ?
O7 O5' 1.73(3) . ?
O8 O8' 0.92(3) . ?
O8 O7' 1.57(3) . ?
Cl1 O2 1.367(11) . ?
Cl1 O4 1.371(11) . ?
Cl1 O3 1.369(11) . ?
Cl1 O1 1.402(12) . ?
C51 N1 1.11(3) . ?
N1 C52 1.432(18) . ?
C52 C54 1.32(3) . ?
C52 C53 1.33(3) . ?
C52 C55 1.34(3) . ?
C53 H53A 0.9600 . ?
C53 H53B 0.9600 . ?
C53 H53C 0.9600 . ?
C54 H54A 0.9600 . ?
C54 H54B 0.9600 . ?
C54 H54C 0.9600 . ?
C55 H55A 0.9600 . ?
C55 H55B 0.9600 . ?
C55 H55C 0.9600 . ?
C56 N2 1.12(3) . ?
N2 C57 1.483(18) . ?
C57 C59 1.31(3) . ?
C57 C58 1.32(3) . ?
C57 C60 1.32(3) . ?
C58 H58A 0.9600 . ?
C58 H58B 0.9600 . ?
C58 H58C 0.9600 . ?
C59 H59A 0.9600 . ?
C59 H59B 0.9600 . ?
C59 H59C 0.9600 . ?
C60 H60A 0.9600 . ?
C60 H60B 0.9600 . ?
C60 H60C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 0(2) . . . . ?
P1 C1 C2 C3 -179.2(13) . . . . ?
C1 C2 C3 C4 -3(3) . . . . ?
C2 C3 C4 C5 7(3) . . . . ?
C3 C4 C5 C6 -8(3) . . . . ?
C4 C5 C6 C1 5(2) . . . . ?
C2 C1 C6 C5 0(2) . . . . ?
P1 C1 C6 C5 178.4(12) . . . . ?
C19 C14 C15 C16 0(2) . . . . ?
P2 C14 C15 C16 -178.7(11) . . . . ?
C14 C15 C16 C17 1(2) . . . . ?
C15 C16 C17 C18 -3(2) . . . . ?
C16 C17 C18 C19 3(2) . . . . ?
C17 C18 C19 C14 -2(2) . . . . ?
C15 C14 C19 C18 0(2) . . . . ?
P2 C14 C19 C18 178.8(11) . . . . ?
C25 C20 C21 C22 0.7(19) . . . . ?
P2 C20 C21 C22 177.0(11) . . . . ?
C20 C21 C22 C23 2(2) . . . . ?
C21 C22 C23 C24 -3(2) . . . . ?
C22 C23 C24 C25 3(2) . . . . ?
C23 C24 C25 C20 -1(2) . . . . ?
C21 C20 C25 C24 -1.2(19) . . . . ?
P2 C20 C25 C24 -177.3(11) . . . . ?
C37 C32 C33 C34 -3(2) . . . . ?
P3 C32 C33 C34 179.2(12) . . . . ?
C32 C33 C34 C35 2(2) . . . . ?
C33 C34 C35 C36 2(3) . . . . ?
C34 C35 C36 C37 -4(3) . . . . ?
C33 C32 C37 C36 0(2) . . . . ?
P3 C32 C37 C36 178.0(12) . . . . ?
C35 C36 C37 C32 4(2) . . . . ?
C31 C26 C27 C28 2(2) . . . . ?
P3 C26 C27 C28 171.5(12) . . . . ?
C26 C27 C28 C29 0(3) . . . . ?
C27 C28 C29 C30 1(3) . . . . ?
C28 C29 C30 C31 -4(3) . . . . ?
C27 C26 C31 C30 -5(2) . . . . ?
P3 C26 C31 C30 -175.6(13) . . . . ?
C29 C30 C31 C26 6(3) . . . . ?
C50 C45 C46 C47 4(2) . . . . ?
P4 C45 C46 C47 -170.1(12) . . . . ?
C45 C46 C47 C48 -6(3) . . . . ?
C46 C47 C48 C49 5(3) . . . . ?
C47 C48 C49 C50 -2(3) . . . . ?
C48 C49 C50 C45 0(3) . . . . ?
C46 C45 C50 C49 -1(2) . . . . ?
P4 C45 C50 C49 173.6(13) . . . . ?
C44 C39 C40 C41 0.7(18) . . . . ?
P4 C39 C40 C41 -179.3(10) . . . . ?
C39 C40 C41 C43 3(2) . . . . ?
C40 C41 C43 C42 -5(3) . . . . ?
C41 C43 C42 C44 3(3) . . . . ?
C40 C39 C44 C42 -2(2) . . . . ?
P4 C39 C44 C42 177.7(11) . . . . ?
C43 C42 C44 C39 0(2) . . . . ?
C12 C7 C8 C9 2(2) . . . . ?
P1 C7 C8 C9 179.6(12) . . . . ?
C7 C8 C9 C10 0(3) . . . . ?
C8 C9 C10 C11 2(3) . . . . ?
C9 C10 C11 C12 -5(3) . . . . ?
C8 C7 C12 C11 -5(2) . . . . ?
P1 C7 C12 C11 177.5(11) . . . . ?
C10 C11 C12 C7 6(2) . . . . ?
C51 Ag2 Ag1 P1 107.7(10) . . . . ?
P3 Ag2 Ag1 P1 -136.28(11) . . . . ?
P2 Ag2 Ag1 P1 -1.49(11) . . . . ?
O4 Ag2 Ag1 P1 118.0(3) . . . . ?
C51 Ag2 Ag1 P4 -112.0(10) . . . . ?
P3 Ag2 Ag1 P4 3.98(11) . . . . ?
P2 Ag2 Ag1 P4 138.77(10) . . . . ?
O4 Ag2 Ag1 P4 -101.8(3) . . . . ?
C51 Ag2 Ag1 C56 -3.9(13) . . . . ?
P3 Ag2 Ag1 C56 112.1(9) . . . . ?
P2 Ag2 Ag1 C56 -113.1(9) . . . . ?
O4 Ag2 Ag1 C56 6.4(9) . . . . ?
C51 Ag2 Ag1 O4 -10.2(10) . . . . ?
P3 Ag2 Ag1 O4 105.8(3) . . . . ?
P2 Ag2 Ag1 O4 -119.5(3) . . . . ?
P1 C13 P2 C14 82.0(7) . . . . ?
P1 C13 P2 C20 -167.8(6) . . . . ?
P1 C13 P2 Ag2 -44.6(7) . . . . ?
C15 C14 P2 C13 -141.5(10) . . . . ?
C19 C14 P2 C13 39.7(13) . . . . ?
C15 C14 P2 C20 111.2(11) . . . . ?
C19 C14 P2 C20 -67.6(12) . . . . ?
C15 C14 P2 Ag2 -11.9(12) . . . . ?
C19 C14 P2 Ag2 169.3(10) . . . . ?
C21 C20 P2 C13 66.7(10) . . . . ?
C25 C20 P2 C13 -117.2(10) . . . . ?
C21 C20 P2 C14 176.4(10) . . . . ?
C25 C20 P2 C14 -7.5(12) . . . . ?
C21 C20 P2 Ag2 -60.1(10) . . . . ?
C25 C20 P2 Ag2 116.0(10) . . . . ?
C51 Ag2 P2 C13 -126.1(7) . . . . ?
P3 Ag2 P2 C13 109.2(4) . . . . ?
O4 Ag2 P2 C13 -23.3(5) . . . . ?
Ag1 Ag2 P2 C13 23.7(4) . . . . ?
C51 Ag2 P2 C14 111.1(7) . . . . ?
P3 Ag2 P2 C14 -13.5(5) . . . . ?
O4 Ag2 P2 C14 -146.1(5) . . . . ?
Ag1 Ag2 P2 C14 -99.1(4) . . . . ?
C51 Ag2 P2 C20 -8.4(7) . . . . ?
P3 Ag2 P2 C20 -133.0(4) . . . . ?
O4 Ag2 P2 C20 94.4(5) . . . . ?
Ag1 Ag2 P2 C20 141.4(4) . . . . ?
C2 C1 P1 C7 66.1(14) . . . . ?
C6 C1 P1 C7 -112.6(11) . . . . ?
C2 C1 P1 C13 -41.9(14) . . . . ?
C6 C1 P1 C13 139.4(10) . . . . ?
C2 C1 P1 Ag1 -169.1(12) . . . . ?
C6 C1 P1 Ag1 12.2(11) . . . . ?
C12 C7 P1 C1 1.7(13) . . . . ?
C8 C7 P1 C1 -176.0(11) . . . . ?
C12 C7 P1 C13 113.0(11) . . . . ?
C8 C7 P1 C13 -64.8(11) . . . . ?
C12 C7 P1 Ag1 -121.5(11) . . . . ?
C8 C7 P1 Ag1 60.7(11) . . . . ?
P2 C13 P1 C1 -83.3(7) . . . . ?
P2 C13 P1 C7 166.3(6) . . . . ?
P2 C13 P1 Ag1 41.7(7) . . . . ?
P4 Ag1 P1 C1 18.7(5) . . . . ?
C56 Ag1 P1 C1 -106.5(6) . . . . ?
O4 Ag1 P1 C1 151.2(5) . . . . ?
Ag2 Ag1 P1 C1 102.7(4) . . . . ?
P4 Ag1 P1 C7 138.3(5) . . . . ?
C56 Ag1 P1 C7 13.1(7) . . . . ?
O4 Ag1 P1 C7 -89.2(6) . . . . ?
Ag2 Ag1 P1 C7 -137.7(5) . . . . ?
P4 Ag1 P1 C13 -103.6(4) . . . . ?
C56 Ag1 P1 C13 131.2(6) . . . . ?
O4 Ag1 P1 C13 28.9(5) . . . . ?
Ag2 Ag1 P1 C13 -19.6(4) . . . . ?
C46 C45 P4 C38 -10.4(13) . . . . ?
C50 C45 P4 C38 175.4(10) . . . . ?
C46 C45 P4 C39 -121.6(12) . . . . ?
C50 C45 P4 C39 64.2(11) . . . . ?
C46 C45 P4 Ag1 112.8(11) . . . . ?
C50 C45 P4 Ag1 -61.5(10) . . . . ?
P3 C38 P4 C45 173.1(6) . . . . ?
P3 C38 P4 C39 -75.8(7) . . . . ?
P3 C38 P4 Ag1 55.6(6) . . . . ?
C44 C39 P4 C45 -124.8(10) . . . . ?
C40 C39 P4 C45 55.2(11) . . . . ?
C44 C39 P4 C38 125.2(10) . . . . ?
C40 C39 P4 C38 -54.8(11) . . . . ?
C44 C39 P4 Ag1 -5.4(11) . . . . ?
C40 C39 P4 Ag1 174.5(8) . . . . ?
P1 Ag1 P4 C45 -61.2(4) . . . . ?
C56 Ag1 P4 C45 63.5(6) . . . . ?
O4 Ag1 P4 C45 162.4(5) . . . . ?
Ag2 Ag1 P4 C45 -146.6(4) . . . . ?
P1 Ag1 P4 C38 54.4(4) . . . . ?
C56 Ag1 P4 C38 179.1(6) . . . . ?
O4 Ag1 P4 C38 -82.0(5) . . . . ?
Ag2 Ag1 P4 C38 -31.0(4) . . . . ?
P1 Ag1 P4 C39 -179.7(4) . . . . ?
C56 Ag1 P4 C39 -55.0(6) . . . . ?
O4 Ag1 P4 C39 43.9(5) . . . . ?
Ag2 Ag1 P4 C39 94.9(4) . . . . ?
C37 C32 P3 C38 -121.7(11) . . . . ?
C33 C32 P3 C38 56.6(11) . . . . ?
C37 C32 P3 C26 128.2(11) . . . . ?
C33 C32 P3 C26 -53.5(11) . . . . ?
C37 C32 P3 Ag2 7.2(12) . . . . ?
C33 C32 P3 Ag2 -174.5(9) . . . . ?
P4 C38 P3 C32 82.3(7) . . . . ?
P4 C38 P3 C26 -169.7(6) . . . . ?
P4 C38 P3 Ag2 -49.6(6) . . . . ?
C27 C26 P3 C32 117.3(12) . . . . ?
C31 C26 P3 C32 -72.3(12) . . . . ?
C27 C26 P3 C38 8.4(13) . . . . ?
C31 C26 P3 C38 178.8(11) . . . . ?
C27 C26 P3 Ag2 -114.9(11) . . . . ?
C31 C26 P3 Ag2 55.4(11) . . . . ?
C51 Ag2 P3 C32 49.2(7) . . . . ?
P2 Ag2 P3 C32 173.2(4) . . . . ?
O4 Ag2 P3 C32 -51.5(5) . . . . ?
Ag1 Ag2 P3 C32 -102.1(4) . . . . ?
C51 Ag2 P3 C38 173.3(7) . . . . ?
P2 Ag2 P3 C38 -62.6(4) . . . . ?
O4 Ag2 P3 C38 72.7(5) . . . . ?
Ag1 Ag2 P3 C38 22.0(4) . . . . ?
C51 Ag2 P3 C26 -68.5(7) . . . . ?
P2 Ag2 P3 C26 55.5(4) . . . . ?
O4 Ag2 P3 C26 -169.2(5) . . . . ?
Ag1 Ag2 P3 C26 140.2(4) . . . . ?
O6 Cl2 O5 O6' 102(3) . . . . ?
O8' Cl2 O5 O6' -93(2) . . . . ?
O7 Cl2 O5 O6' -17(3) . . . . ?
O8 Cl2 O5 O6' -133(2) . . . . ?
O5' Cl2 O5 O6' 70(3) . . . . ?
O7' Cl2 O5 O6' 165(3) . . . . ?
O6' Cl2 O5 O7' -165(3) . . . . ?
O6 Cl2 O5 O7' -63.0(17) . . . . ?
O8' Cl2 O5 O7' 101.7(14) . . . . ?
O7 Cl2 O5 O7' 177.3(13) . . . . ?
O8 Cl2 O5 O7' 61.7(15) . . . . ?
O5' Cl2 O5 O7' -95.7(18) . . . . ?
O6' Cl2 O6 O5' -87(3) . . . . ?
O8' Cl2 O6 O5' 64(4) . . . . ?
O7 Cl2 O6 O5' -13(4) . . . . ?
O5 Cl2 O6 O5' -132(3) . . . . ?
O8 Cl2 O6 O5' 106(3) . . . . ?
O7' Cl2 O6 O5' 166(4) . . . . ?
O6' Cl2 O6 O7' 106.7(15) . . . . ?
O8' Cl2 O6 O7' -101.9(15) . . . . ?
O7 Cl2 O6 O7' -179.1(13) . . . . ?
O5 Cl2 O6 O7' 61.6(16) . . . . ?
O8 Cl2 O6 O7' -60.0(16) . . . . ?
O5' Cl2 O6 O7' -166(4) . . . . ?
O6' Cl2 O7 O8' -125.5(15) . . . . ?
O6 Cl2 O7 O8' 121.1(17) . . . . ?
O5 Cl2 O7 O8' -113.6(16) . . . . ?
O8 Cl2 O7 O8' 0.1(19) . . . . ?
O5' Cl2 O7 O8' 114.3(14) . . . . ?
O7' Cl2 O7 O8' -39(28) . . . . ?
O6 Cl2 O7 O6' -113.3(17) . . . . ?
O8' Cl2 O7 O6' 125.5(15) . . . . ?
O5 Cl2 O7 O6' 11.9(18) . . . . ?
O8 Cl2 O7 O6' 125.7(16) . . . . ?
O5' Cl2 O7 O6' -120.2(14) . . . . ?
O7' Cl2 O7 O6' 87(28) . . . . ?
O6' Cl2 O7 O5' 120.2(14) . . . . ?
O6 Cl2 O7 O5' 7(2) . . . . ?
O8' Cl2 O7 O5' -114.3(14) . . . . ?
O5 Cl2 O7 O5' 132.1(15) . . . . ?
O8 Cl2 O7 O5' -114.1(16) . . . . ?
O7' Cl2 O7 O5' -153(27) . . . . ?
O6' Cl2 O8 O8' 77(3) . . . . ?
O6 Cl2 O8 O8' -119(3) . . . . ?
O7 Cl2 O8 O8' 0(3) . . . . ?
O5 Cl2 O8 O8' 114(3) . . . . ?
O5' Cl2 O8 O8' -84(3) . . . . ?
O7' Cl2 O8 O8' 178(3) . . . . ?
O6' Cl2 O8 O7' -101.3(17) . . . . ?
O6 Cl2 O8 O7' 63.5(17) . . . . ?
O8' Cl2 O8 O7' -178(3) . . . . ?
O7 Cl2 O8 O7' -178.2(14) . . . . ?
O5 Cl2 O8 O7' -63.9(16) . . . . ?
O5' Cl2 O8 O7' 97.9(15) . . . . ?
O7' O6 O5' Cl2 14(4) . . . . ?
Cl2 O6 O5' O7 11(3) . . . . ?
O7' O6 O5' O7 26(7) . . . . ?
O6' Cl2 O5' O6 108(3) . . . . ?
O8' Cl2 O5' O6 -129(3) . . . . ?
O7 Cl2 O5' O6 167(4) . . . . ?
O5 Cl2 O5' O6 67(4) . . . . ?
O8 Cl2 O5' O6 -88(3) . . . . ?
O7' Cl2 O5' O6 -14(4) . . . . ?
O6' Cl2 O5' O7 -59.8(16) . . . . ?
O6 Cl2 O5' O7 -167(4) . . . . ?
O8' Cl2 O5' O7 63.6(15) . . . . ?
O5 Cl2 O5' O7 -100.3(18) . . . . ?
O8 Cl2 O5' O7 104.2(14) . . . . ?
O7' Cl2 O5' O7 178.7(13) . . . . ?
Cl2 O7 O5' O6 -14(4) . . . . ?
O8' O7 O5' O6 -62(4) . . . . ?
O6' O7 O5' O6 31(4) . . . . ?
O8' O7 O5' Cl2 -48.3(10) . . . . ?
O6' O7 O5' Cl2 44.7(10) . . . . ?
O7' O5 O6' Cl2 13(2) . . . . ?
Cl2 O5 O6' O7 19(3) . . . . ?
O7' O5 O6' O7 32(5) . . . . ?
O6 Cl2 O6' O5 -99(2) . . . . ?
O8' Cl2 O6' O5 106(2) . . . . ?
O7 Cl2 O6' O5 162(3) . . . . ?
O8 Cl2 O6' O5 65(3) . . . . ?
O5' Cl2 O6' O5 -133(2) . . . . ?
O7' Cl2 O6' O5 -15(3) . . . . ?
O6 Cl2 O6' O7 99.0(15) . . . . ?
O8' Cl2 O6' O7 -55.7(16) . . . . ?
O5 Cl2 O6' O7 -162(3) . . . . ?
O8 Cl2 O6' O7 -96.9(17) . . . . ?
O5' Cl2 O6' O7 64.6(16) . . . . ?
O7' Cl2 O6' O7 -177.1(14) . . . . ?
Cl2 O7 O6' O5 -21(3) . . . . ?
O8' O7 O6' O5 20(4) . . . . ?
O5' O7 O6' O5 -64(4) . . . . ?
O8' O7 O6' Cl2 41.6(11) . . . . ?
O5' O7 O6' Cl2 -42.8(10) . . . . ?
O6' Cl2 O7' O5 10.0(18) . . . . ?
O6 Cl2 O7' O5 124.2(15) . . . . ?
O8' Cl2 O7' O5 -113.8(16) . . . . ?
O7 Cl2 O7' O5 -76(28) . . . . ?
O8 Cl2 O7' O5 -115.2(14) . . . . ?
O5' Cl2 O7' O5 131.7(15) . . . . ?
O6' Cl2 O7' O6 -114.1(17) . . . . ?
O8' Cl2 O7' O6 122.0(17) . . . . ?
O7 Cl2 O7' O6 160(28) . . . . ?
O5 Cl2 O7' O6 -124.2(15) . . . . ?
O8 Cl2 O7' O6 120.7(15) . . . . ?
O5' Cl2 O7' O6 7(2) . . . . ?
O6' Cl2 O7' O8 125.2(16) . . . . ?
O6 Cl2 O7' O8 -120.7(15) . . . . ?
O8' Cl2 O7' O8 1(2) . . . . ?
O7 Cl2 O7' O8 40(28) . . . . ?
O5 Cl2 O7' O8 115.2(14) . . . . ?
O5' Cl2 O7' O8 -113.2(17) . . . . ?
O6' O5 O7' Cl2 -16(3) . . . . ?
O6' O5 O7' O6 25(3) . . . . ?
Cl2 O5 O7' O6 40.3(10) . . . . ?
O6' O5 O7' O8 -64(3) . . . . ?
Cl2 O5 O7' O8 -48.3(10) . . . . ?
O5' O6 O7' Cl2 -18(4) . . . . ?
O5' O6 O7' O5 -60(5) . . . . ?
Cl2 O6 O7' O5 -42.0(11) . . . . ?
O5' O6 O7' O8 28(5) . . . . ?
Cl2 O6 O7' O8 45.2(11) . . . . ?
O8' O8 O7' Cl2 -2(3) . . . . ?
O8' O8 O7' O5 45(4) . . . . ?
Cl2 O8 O7' O5 47.2(9) . . . . ?
O8' O8 O7' O6 -45(4) . . . . ?
Cl2 O8 O7' O6 -42.2(10) . . . . ?
O7' O8 O8' Cl2 2(3) . . . . ?
Cl2 O8 O8' O7 0(3) . . . . ?
O7' O8 O8' O7 2(6) . . . . ?
O6' Cl2 O8' O8 -125(2) . . . . ?
O6 Cl2 O8' O8 82(3) . . . . ?
O7 Cl2 O8' O8 180(3) . . . . ?
O5 Cl2 O8' O8 -81(3) . . . . ?
O5' Cl2 O8' O8 112(3) . . . . ?
O7' Cl2 O8' O8 -2(3) . . . . ?
O6' Cl2 O8' O7 54.9(16) . . . . ?
O6 Cl2 O8' O7 -97.8(16) . . . . ?
O5 Cl2 O8' O7 98.9(14) . . . . ?
O8 Cl2 O8' O7 -180(3) . . . . ?
O5' Cl2 O8' O7 -68.0(16) . . . . ?
O7' Cl2 O8' O7 178.2(14) . . . . ?
Cl2 O7 O8' O8 0(3) . . . . ?
O6' O7 O8' O8 -42(4) . . . . ?
O5' O7 O8' O8 46(4) . . . . ?
O6' O7 O8' Cl2 -41.5(11) . . . . ?
O5' O7 O8' Cl2 46.0(9) . . . . ?
O2 Cl1 O4 Ag2 -80.2(11) . . . . ?
O3 Cl1 O4 Ag2 42.4(12) . . . . ?
O1 Cl1 O4 Ag2 163.2(8) . . . . ?
O2 Cl1 O4 Ag1 -174.5(8) . . . . ?
O3 Cl1 O4 Ag1 -51.9(12) . . . . ?
O1 Cl1 O4 Ag1 69.0(11) . . . . ?
C51 Ag2 O4 Cl1 52.4(11) . . . . ?
P3 Ag2 O4 Cl1 158.5(9) . . . . ?
P2 Ag2 O4 Cl1 -53.9(10) . . . . ?
Ag1 Ag2 O4 Cl1 -122.2(10) . . . . ?
C51 Ag2 O4 Ag1 174.7(5) . . . . ?
P3 Ag2 O4 Ag1 -79.3(2) . . . . ?
P2 Ag2 O4 Ag1 68.4(3) . . . . ?
P1 Ag1 O4 Cl1 46.3(10) . . . . ?
P4 Ag1 O4 Cl1 -162.1(9) . . . . ?
C56 Ag1 O4 Cl1 -58.5(11) . . . . ?
Ag2 Ag1 O4 Cl1 118.2(11) . . . . ?
P1 Ag1 O4 Ag2 -71.9(3) . . . . ?
P4 Ag1 O4 Ag2 79.6(2) . . . . ?
C56 Ag1 O4 Ag2 -176.7(5) . . . . ?
P3 Ag2 C51 N1 97(12) . . . . ?
P2 Ag2 C51 N1 -46(12) . . . . ?
O4 Ag2 C51 N1 -159(12) . . . . ?
Ag1 Ag2 C51 N1 -151(12) . . . . ?
Ag2 C51 N1 C52 23(63) . . . . ?
C51 N1 C52 C54 -146(53) . . . . ?
C51 N1 C52 C53 -29(54) . . . . ?
C51 N1 C52 C55 92(53) . . . . ?
P1 Ag1 C56 N2 -115(6) . . . . ?
P4 Ag1 C56 N2 98(6) . . . . ?
O4 Ag1 C56 N2 -1(6) . . . . ?
Ag2 Ag1 C56 N2 -6(7) . . . . ?
Ag1 C56 N2 C57 112(23) . . . . ?
C56 N2 C57 C59 101(24) . . . . ?
C56 N2 C57 C58 -137(24) . . . . ?
C56 N2 C57 C60 -17(25) . . . . ?
