#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:43:06 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179152 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/13/4311352.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4311352
loop_
_publ_author_name
'Cristina Tejel'
'Miguel A. Ciriano'
'Gustavo Ríos-Moreno'
'Isabel T. Dobrinovitch'
'Fernando J. Lahoz'
'Luis A. Oro'
'Miguel Parra-Hake'
_publ_contact_author_address
;
  Dr. Fernando J. Lahoz
  Departamento de Química Inorgánica - I.C.M.A.
  Facultad de Ciencias
  Universidad de Zaragoza - C.S.I.C.
  50009 Zaragoza, Spain
;
_publ_contact_author_email       lahoz@posta.unizar.es
_publ_contact_author_fax         '+34 976 761187'
_publ_contact_author_name        'Dr. Fernando J. Lahoz'
_publ_contact_author_phone       '+34 976 761147'
_publ_section_title
;
 Crescent-Shaped Rhodium(I) Complexes with
 Bis(o-carboxymethylphenyl)triazenide
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4719
_journal_page_last               4726
_journal_paper_doi               10.1021/ic049691g
_journal_volume                  43
_journal_year                    2004
_chemical_formula_moiety         'C20 H14 Cl2 N3 O8 Rh2, C6 H16 N'
_chemical_formula_sum            'C26 H30 Cl2 N4 O8 Rh2'
_chemical_formula_weight         803.26
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.3400(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   19.5308(13)
_cell_length_b                   9.9136(7)
_cell_length_c                   33.023(2)
_cell_measurement_reflns_used    6643
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.20
_cell_measurement_theta_min      2.32
_cell_volume                     6326.3(7)
_computing_cell_refinement       'SAINT+ v. 6.01 (Bruker AXS, 2000)'
_computing_data_collection       'SMART v. 5.611 (Bruker AXS, 2000)'
_computing_data_reduction        'SAINT+ v. 6.01 (Bruker AXS, 2000)'
_computing_molecular_graphics    'XP program, SHELXTL v6.12, Bruker2000'
_computing_publication_material  'XCIF program, SHELXTLv6.12, BrukerAXS'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART APEX CCD system'
_diffrn_measurement_method       'ω rotations with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0908
_diffrn_reflns_av_sigmaI/netI    0.0671
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            61739
_diffrn_reflns_theta_full        25.04
_diffrn_reflns_theta_max         25.04
_diffrn_reflns_theta_min         1.05
_diffrn_standards_decay_%        'no decay'
_exptl_absorpt_coefficient_mu    1.264
_exptl_absorpt_correction_T_max  0.914
_exptl_absorpt_correction_T_min  0.731
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
 SADABS: Area-Detector Absorption Correction. (1996)  Bruker-AXS 
 within SAINT+ package, v. 6.01.                    
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.687
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       lamina
_exptl_crystal_F_000             3216
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.07
_refine_diff_density_max         2.332
_refine_diff_density_min         -0.857
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     769
_refine_ls_number_reflns         11172
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0869
_refine_ls_R_factor_gt           0.0492
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0434P)²+14.1863P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0975
_refine_ls_wR_factor_ref         0.1102
_reflns_number_gt                7556
_reflns_number_total             11172
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic049691gsi20040310_075146_1.cif
_cod_data_source_block           compound4
_cod_database_code               4311352
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.06149(2) 0.64909(5) 0.077825(15) 0.01505(13) Uani 1 1 d . . .
Rh2 Rh 0.11080(2) 0.58949(5) 0.165396(15) 0.01425(12) Uani 1 1 d . . .
Rh3 Rh 0.38595(2) 0.33027(5) 0.330933(15) 0.01500(13) Uani 1 1 d . . .
Rh4 Rh 0.43554(2) 0.27216(5) 0.418275(15) 0.01473(13) Uani 1 1 d . . .
Cl1 Cl -0.03338(8) 0.78055(17) 0.09060(5) 0.0219(4) Uani 1 1 d . . .
Cl2 Cl 0.16711(9) 0.38713(16) 0.15340(5) 0.0231(4) Uani 1 1 d . . .
Cl3 Cl 0.32839(9) 0.53072(16) 0.34231(5) 0.0238(4) Uani 1 1 d . . .
Cl4 Cl 0.53044(8) 0.14350(17) 0.40425(5) 0.0212(4) Uani 1 1 d . . .
O1 O 0.2507(2) 1.1082(4) 0.14202(13) 0.0217(10) Uani 1 1 d . . .
O2 O 0.1547(2) 1.0252(4) 0.16192(12) 0.0184(10) Uani 1 1 d . . .
O3 O 0.3445(2) 0.9016(5) 0.10491(14) 0.0309(12) Uani 1 1 d . . .
O4 O 0.2917(2) 0.7083(5) 0.08361(13) 0.0239(11) Uani 1 1 d . . .
O5 O 0.1760(2) 0.4964(5) 0.04902(14) 0.0281(11) Uani 1 1 d . . .
O6 O -0.0370(3) 0.4330(5) 0.04430(15) 0.0381(13) Uani 1 1 d . . .
O7 O 0.0468(2) 0.8415(5) 0.19180(14) 0.0286(12) Uani 1 1 d . . .
O8 O 0.0084(2) 0.4261(5) 0.20307(14) 0.0313(12) Uani 1 1 d . . .
O9 O 0.1542(2) 0.0151(5) 0.39198(14) 0.0286(12) Uani 1 1 d . . .
O10 O 0.2071(2) 0.2062(5) 0.41459(13) 0.0220(11) Uani 1 1 d . . .
O11 O 0.2480(2) -0.1876(4) 0.35363(13) 0.0215(10) Uani 1 1 d . . .
O12 O 0.3428(2) -0.1003(4) 0.33237(12) 0.0207(10) Uani 1 1 d . . .
O13 O 0.4526(2) 0.0804(5) 0.30429(14) 0.0282(12) Uani 1 1 d . . .
O14 O 0.4901(2) 0.4946(5) 0.29516(15) 0.0325(12) Uani 1 1 d . . .
O15 O 0.3210(2) 0.4216(5) 0.44832(14) 0.0298(12) Uani 1 1 d . . .
O16 O 0.5319(2) 0.4912(5) 0.45257(14) 0.0309(12) Uani 1 1 d . . .
N1 N 0.1295(2) 0.8082(5) 0.09613(14) 0.0119(11) Uani 1 1 d . . .
N2 N 0.1869(2) 0.8007(5) 0.12198(15) 0.0151(11) Uani 1 1 d . . .
N3 N 0.1928(2) 0.7000(5) 0.14714(15) 0.0146(11) Uani 1 1 d . . .
N4 N 0.3044(2) 0.2184(5) 0.34953(15) 0.0147(12) Uani 1 1 d . . .
N5 N 0.3116(2) 0.1175(5) 0.37465(14) 0.0133(11) Uani 1 1 d . . .
N6 N 0.3687(2) 0.1109(5) 0.40002(14) 0.0128(11) Uani 1 1 d . . .
N7 N 0.1395(3) 0.6505(6) 0.37060(16) 0.0230(13) Uani 1 1 d . . .
H1N H 0.1694 0.7207 0.3696 0.017(18) Uiso 1 1 d R . .
N8 N 0.3611(3) 0.2728(6) 0.12874(16) 0.0241(13) Uani 1 1 d . . .
H2N H 0.3275 0.2080 0.1293 0.015(17) Uiso 1 1 d R . .
C1 C 0.1929(3) 1.0635(6) 0.13330(19) 0.0162(14) Uani 1 1 d . . .
C2 C 0.1903(4) 1.0263(7) 0.20320(19) 0.0300(18) Uani 1 1 d . . .
H2A H 0.2281 0.9604 0.2059 0.045 Uiso 1 1 calc R . .
H2B H 0.1578 1.0027 0.2221 0.045 Uiso 1 1 calc R . .
H2C H 0.2092 1.1165 0.2098 0.045 Uiso 1 1 calc R . .
C3 C 0.1556(3) 1.0513(6) 0.09104(19) 0.0156(14) Uani 1 1 d . . .
C4 C 0.1513(3) 1.1681(6) 0.0670(2) 0.0207(15) Uani 1 1 d . . .
H4 H 0.1736 1.2482 0.0777 0.025 Uiso 1 1 calc R . .
C5 C 0.1154(3) 1.1685(7) 0.0283(2) 0.0222(15) Uani 1 1 d . . .
H5 H 0.1117 1.2493 0.0127 0.027 Uiso 1 1 calc R . .
C6 C 0.0846(3) 1.0526(7) 0.0120(2) 0.0212(15) Uani 1 1 d . . .
H6 H 0.0600 1.0527 -0.0151 0.025 Uiso 1 1 calc R . .
C7 C 0.0895(3) 0.9359(7) 0.03489(19) 0.0201(15) Uani 1 1 d . . .
H7 H 0.0685 0.8558 0.0231 0.024 Uiso 1 1 calc R . .
C8 C 0.1241(3) 0.9318(6) 0.07463(19) 0.0150(14) Uani 1 1 d . . .
C9 C 0.2604(3) 0.6934(6) 0.16967(18) 0.0160(14) Uani 1 1 d . . .
C10 C 0.2686(3) 0.6356(6) 0.20856(18) 0.0164(14) Uani 1 1 d . . .
H10 H 0.2293 0.5997 0.2187 0.020 Uiso 1 1 calc R . .
C11 C 0.3325(3) 0.6296(7) 0.23254(19) 0.0212(15) Uani 1 1 d . . .
H11 H 0.3372 0.5892 0.2589 0.025 Uiso 1 1 calc R . .
C12 C 0.3893(3) 0.6824(7) 0.2181(2) 0.0243(16) Uani 1 1 d . . .
H12 H 0.4333 0.6809 0.2348 0.029 Uiso 1 1 calc R . .
C13 C 0.3828(3) 0.7373(7) 0.1795(2) 0.0243(16) Uani 1 1 d . . .
H13 H 0.4224 0.7729 0.1697 0.029 Uiso 1 1 calc R . .
C14 C 0.3189(3) 0.7417(6) 0.15460(18) 0.0172(14) Uani 1 1 d . . .
C15 C 0.3194(3) 0.7959(7) 0.1124(2) 0.0213(15) Uani 1 1 d . . .
C16 C 0.2897(4) 0.7576(9) 0.0425(2) 0.040(2) Uani 1 1 d . . .
H16A H 0.2614 0.8395 0.0389 0.061 Uiso 1 1 calc R . .
H16B H 0.2696 0.6886 0.0231 0.061 Uiso 1 1 calc R . .
H16C H 0.3369 0.7782 0.0375 0.061 Uiso 1 1 calc R . .
C17 C 0.1337(3) 0.5533(6) 0.06130(19) 0.0192(15) Uani 1 1 d . . .
C18 C 0.0001(4) 0.5135(7) 0.05764(19) 0.0245(16) Uani 1 1 d . . .
C19 C 0.0704(3) 0.7479(7) 0.18049(18) 0.0153(14) Uani 1 1 d . . .
C20 C 0.0463(3) 0.4894(6) 0.18772(19) 0.0190(14) Uani 1 1 d . . .
C21 C 0.1790(3) 0.1214(7) 0.3856(2) 0.0199(15) Uani 1 1 d . . .
C22 C 0.2101(4) 0.1534(8) 0.45545(19) 0.0334(19) Uani 1 1 d . . .
H22A H 0.1640 0.1227 0.4597 0.050 Uiso 1 1 calc R . .
H22B H 0.2260 0.2241 0.4753 0.050 Uiso 1 1 calc R . .
H22C H 0.2425 0.0773 0.4591 0.050 Uiso 1 1 calc R . .
C23 C 0.1779(3) 0.1807(6) 0.34390(18) 0.0167(14) Uani 1 1 d . . .
C24 C 0.1135(3) 0.1867(7) 0.31955(19) 0.0223(16) Uani 1 1 d . . .
H24 H 0.0742 0.1515 0.3298 0.027 Uiso 1 1 calc R . .
C25 C 0.1053(3) 0.2423(7) 0.2811(2) 0.0264(17) Uani 1 1 d . . .
H25 H 0.0608 0.2455 0.2651 0.032 Uiso 1 1 calc R . .
C26 C 0.1625(3) 0.2939(7) 0.26564(19) 0.0227(16) Uani 1 1 d . . .
H26 H 0.1573 0.3347 0.2393 0.027 Uiso 1 1 calc R . .
C27 C 0.2272(3) 0.2849(6) 0.28910(18) 0.0179(14) Uani 1 1 d . . .
H27 H 0.2665 0.3187 0.2784 0.022 Uiso 1 1 calc R . .
C28 C 0.2358(3) 0.2279(6) 0.32770(18) 0.0156(14) Uani 1 1 d . . .
C29 C 0.3754(3) -0.0156(6) 0.42076(18) 0.0154(14) Uani 1 1 d . . .
C30 C 0.4123(3) -0.0175(7) 0.45985(19) 0.0194(15) Uani 1 1 d . . .
H30 H 0.4319 0.0634 0.4718 0.023 Uiso 1 1 calc R . .
C31 C 0.4205(3) -0.1364(7) 0.4814(2) 0.0213(15) Uani 1 1 d . . .
H31 H 0.4462 -0.1374 0.5081 0.026 Uiso 1 1 calc R . .
C32 C 0.3915(3) -0.2557(7) 0.46428(19) 0.0212(15) Uani 1 1 d . . .
H32 H 0.3981 -0.3381 0.4790 0.025 Uiso 1 1 calc R . .
C33 C 0.3536(3) -0.2525(6) 0.42613(19) 0.0180(14) Uani 1 1 d . . .
H33 H 0.3319 -0.3330 0.4151 0.022 Uiso 1 1 calc R . .
C34 C 0.3458(3) -0.1349(6) 0.40288(18) 0.0156(14) Uani 1 1 d . . .
C35 C 0.3057(3) -0.1420(6) 0.36133(19) 0.0178(14) Uani 1 1 d . . .
C36 C 0.3046(4) -0.0980(7) 0.2915(2) 0.0323(18) Uani 1 1 d . . .
H36A H 0.2869 -0.1886 0.2841 0.048 Uiso 1 1 calc R . .
H36B H 0.3352 -0.0689 0.2721 0.048 Uiso 1 1 calc R . .
H36C H 0.2657 -0.0350 0.2906 0.048 Uiso 1 1 calc R . .
C37 C 0.4278(3) 0.1728(7) 0.3159(2) 0.0211(15) Uani 1 1 d . . .
C38 C 0.4514(3) 0.4313(7) 0.30959(19) 0.0196(15) Uani 1 1 d . . .
C39 C 0.3632(3) 0.3652(7) 0.4354(2) 0.0211(15) Uani 1 1 d . . .
C40 C 0.4953(3) 0.4085(7) 0.43866(19) 0.0207(15) Uani 1 1 d . . .
C41 C 0.1635(4) 0.5666(8) 0.4074(2) 0.0308(18) Uani 1 1 d . . .
H41A H 0.2055 0.5162 0.4027 0.037 Uiso 1 1 calc R . .
H41B H 0.1272 0.5000 0.4111 0.037 Uiso 1 1 calc R . .
C42 C 0.1798(4) 0.6493(8) 0.4458(2) 0.038(2) Uani 1 1 d . . .
H42A H 0.2098 0.7249 0.4408 0.057 Uiso 1 1 calc R . .
H42B H 0.2036 0.5927 0.4678 0.057 Uiso 1 1 calc R . .
H42C H 0.1367 0.6840 0.4537 0.057 Uiso 1 1 calc R . .
C43 C 0.0762(3) 0.7344(7) 0.3748(2) 0.0246(16) Uani 1 1 d . . .
H43A H 0.0866 0.7922 0.3994 0.030 Uiso 1 1 calc R . .
H43B H 0.0666 0.7946 0.3508 0.030 Uiso 1 1 calc R . .
C44 C 0.0120(4) 0.6535(8) 0.3784(3) 0.044(2) Uani 1 1 d . . .
H44A H 0.0001 0.5981 0.3538 0.066 Uiso 1 1 calc R . .
H44B H -0.0264 0.7148 0.3812 0.066 Uiso 1 1 calc R . .
H44C H 0.0205 0.5948 0.4025 0.066 Uiso 1 1 calc R . .
C45 C 0.1318(4) 0.5676(8) 0.3329(2) 0.0343(19) Uani 1 1 d . . .
H45A H 0.0955 0.4989 0.3346 0.041 Uiso 1 1 calc R . .
H45B H 0.1758 0.5193 0.3317 0.041 Uiso 1 1 calc R . .
C46 C 0.1132(4) 0.6463(8) 0.2943(2) 0.044(2) Uani 1 1 d . . .
H46A H 0.0654 0.6781 0.2923 0.065 Uiso 1 1 calc R . .
H46B H 0.1179 0.5886 0.2707 0.065 Uiso 1 1 calc R . .
H46C H 0.1444 0.7239 0.2944 0.065 Uiso 1 1 calc R . .
C47 C 0.3642(4) 0.3529(8) 0.1676(2) 0.041(2) Uani 1 1 d . . .
H47A H 0.4013 0.4214 0.1684 0.049 Uiso 1 1 calc R . .
H47B H 0.3198 0.4011 0.1675 0.049 Uiso 1 1 calc R . .
C48 C 0.3777(4) 0.2668(10) 0.2054(2) 0.052(3) Uani 1 1 d . . .
H48A H 0.3465 0.1890 0.2025 0.079 Uiso 1 1 calc R . .
H48B H 0.3698 0.3201 0.2292 0.079 Uiso 1 1 calc R . .
H48C H 0.4258 0.2353 0.2090 0.079 Uiso 1 1 calc R . .
C49 C 0.4243(3) 0.1870(7) 0.1272(2) 0.0261(16) Uani 1 1 d . . .
H49A H 0.4174 0.1333 0.1016 0.031 Uiso 1 1 calc R . .
H49B H 0.4293 0.1232 0.1505 0.031 Uiso 1 1 calc R . .
C50 C 0.4904(4) 0.2666(8) 0.1287(3) 0.041(2) Uani 1 1 d . . .
H50A H 0.4866 0.3283 0.1053 0.062 Uiso 1 1 calc R . .
H50B H 0.5292 0.2047 0.1277 0.062 Uiso 1 1 calc R . .
H50C H 0.4983 0.3187 0.1542 0.062 Uiso 1 1 calc R . .
C51 C 0.3434(4) 0.3648(8) 0.0930(2) 0.040(2) Uani 1 1 d . . .
H51A H 0.2990 0.4104 0.0954 0.048 Uiso 1 1 calc R . .
H51B H 0.3795 0.4352 0.0940 0.048 Uiso 1 1 calc R . .
C52 C 0.3370(4) 0.2946(10) 0.0524(2) 0.061(3) Uani 1 1 d . . .
H52A H 0.3830 0.2656 0.0472 0.092 Uiso 1 1 calc R . .
H52B H 0.3171 0.3567 0.0307 0.092 Uiso 1 1 calc R . .
H52C H 0.3069 0.2156 0.0527 0.092 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C17 Rh1 C18 90.1(3) . . ?
C17 Rh1 N1 89.6(2) . . ?
C18 Rh1 N1 175.7(2) . . ?
C17 Rh1 Cl1 173.01(19) . . ?
C18 Rh1 Cl1 88.9(2) . . ?
N1 Rh1 Cl1 90.80(14) . . ?
C17 Rh1 Rh2 91.82(19) . . ?
C18 Rh1 Rh2 107.8(2) . . ?
N1 Rh1 Rh2 76.50(13) . . ?
Cl1 Rh1 Rh2 95.06(4) . . ?
C20 Rh2 C19 90.3(3) . . ?
C20 Rh2 N3 172.6(2) . . ?
C19 Rh2 N3 90.4(2) . . ?
C20 Rh2 Cl2 88.4(2) . . ?
C19 Rh2 Cl2 174.10(19) . . ?
N3 Rh2 Cl2 90.11(14) . . ?
C20 Rh2 Rh1 110.7(2) . . ?
C19 Rh2 Rh1 90.15(19) . . ?
N3 Rh2 Rh1 76.69(13) . . ?
Cl2 Rh2 Rh1 95.69(4) . . ?
C38 Rh3 C37 89.8(3) . . ?
C38 Rh3 N4 174.0(2) . . ?
C37 Rh3 N4 91.0(2) . . ?
C38 Rh3 Cl3 88.6(2) . . ?
C37 Rh3 Cl3 173.8(2) . . ?
N4 Rh3 Cl3 89.95(14) . . ?
C38 Rh3 Rh4 109.35(19) . . ?
C37 Rh3 Rh4 90.16(19) . . ?
N4 Rh3 Rh4 76.58(13) . . ?
Cl3 Rh3 Rh4 96.06(4) . . ?
C39 Rh4 C40 89.6(3) . . ?
C39 Rh4 N6 89.9(2) . . ?
C40 Rh4 N6 175.3(2) . . ?
C39 Rh4 Cl4 173.3(2) . . ?
C40 Rh4 Cl4 89.6(2) . . ?
N6 Rh4 Cl4 90.31(14) . . ?
C39 Rh4 Rh3 92.60(19) . . ?
C40 Rh4 Rh3 108.21(19) . . ?
N6 Rh4 Rh3 76.48(13) . . ?
Cl4 Rh4 Rh3 93.98(4) . . ?
C1 O2 C2 115.2(5) . . ?
C15 O4 C16 113.7(5) . . ?
C21 O10 C22 113.6(5) . . ?
C35 O12 C36 114.2(5) . . ?
N2 N1 C8 111.9(5) . . ?
N2 N1 Rh1 126.3(4) . . ?
C8 N1 Rh1 120.7(4) . . ?
N3 N2 N1 116.8(5) . . ?
N2 N3 C9 111.2(5) . . ?
N2 N3 Rh2 125.9(4) . . ?
C9 N3 Rh2 121.1(4) . . ?
N5 N4 C28 112.4(5) . . ?
N5 N4 Rh3 125.3(4) . . ?
C28 N4 Rh3 120.8(4) . . ?
N4 N5 N6 117.1(5) . . ?
N5 N6 C29 111.4(5) . . ?
N5 N6 Rh4 126.1(4) . . ?
C29 N6 Rh4 121.5(4) . . ?
C45 N7 C41 110.9(6) . . ?
C45 N7 C43 113.5(5) . . ?
C41 N7 C43 113.4(5) . . ?
C45 N7 H1N 112.3 . . ?
C41 N7 H1N 109.2 . . ?
C43 N7 H1N 96.9 . . ?
C51 N8 C47 109.1(6) . . ?
C51 N8 C49 114.6(5) . . ?
C47 N8 C49 113.4(5) . . ?
C51 N8 H2N 111.0 . . ?
C47 N8 H2N 106.9 . . ?
C49 N8 H2N 101.4 . . ?
O1 C1 O2 122.1(6) . . ?
O1 C1 C3 124.6(6) . . ?
O2 C1 C3 113.2(5) . . ?
O2 C2 H2A 109.5 . . ?
O2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
O2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C4 C3 C8 119.4(6) . . ?
C4 C3 C1 116.6(6) . . ?
C8 C3 C1 124.0(6) . . ?
C5 C4 C3 121.0(6) . . ?
C5 C4 H4 119.5 . . ?
C3 C4 H4 119.5 . . ?
C4 C5 C6 120.2(6) . . ?
C4 C5 H5 119.9 . . ?
C6 C5 H5 119.9 . . ?
C5 C6 C7 119.7(6) . . ?
C5 C6 H6 120.2 . . ?
C7 C6 H6 120.2 . . ?
C6 C7 C8 121.9(7) . . ?
C6 C7 H7 119.0 . . ?
C8 C7 H7 119.0 . . ?
C7 C8 C3 117.8(6) . . ?
C7 C8 N1 119.4(6) . . ?
C3 C8 N1 122.7(6) . . ?
C10 C9 C14 118.7(6) . . ?
C10 C9 N3 118.3(5) . . ?
C14 C9 N3 123.0(5) . . ?
C11 C10 C9 121.3(6) . . ?
C11 C10 H10 119.4 . . ?
C9 C10 H10 119.4 . . ?
C12 C11 C10 119.6(6) . . ?
C12 C11 H11 120.2 . . ?
C10 C11 H11 120.2 . . ?
C13 C12 C11 120.1(6) . . ?
C13 C12 H12 120.0 . . ?
C11 C12 H12 120.0 . . ?
C12 C13 C14 121.0(6) . . ?
C12 C13 H13 119.5 . . ?
C14 C13 H13 119.5 . . ?
C13 C14 C9 119.3(6) . . ?
C13 C14 C15 115.8(6) . . ?
C9 C14 C15 124.9(5) . . ?
O3 C15 O4 123.6(6) . . ?
O3 C15 C14 124.5(6) . . ?
O4 C15 C14 111.8(6) . . ?
O4 C16 H16A 109.5 . . ?
O4 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
O4 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O5 C17 Rh1 176.1(6) . . ?
O6 C18 Rh1 177.9(6) . . ?
O7 C19 Rh2 176.2(6) . . ?
O8 C20 Rh2 176.9(6) . . ?
O9 C21 O10 124.4(6) . . ?
O9 C21 C23 124.1(6) . . ?
O10 C21 C23 111.3(6) . . ?
O10 C22 H22A 109.5 . . ?
O10 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
O10 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C24 C23 C28 118.5(6) . . ?
C24 C23 C21 116.0(5) . . ?
C28 C23 C21 125.5(5) . . ?
C25 C24 C23 121.7(6) . . ?
C25 C24 H24 119.1 . . ?
C23 C24 H24 119.1 . . ?
C24 C25 C26 119.7(6) . . ?
C24 C25 H25 120.2 . . ?
C26 C25 H25 120.2 . . ?
C27 C26 C25 119.2(6) . . ?
C27 C26 H26 120.4 . . ?
C25 C26 H26 120.4 . . ?
C28 C27 C26 121.3(6) . . ?
C28 C27 H27 119.3 . . ?
C26 C27 H27 119.3 . . ?
C27 C28 C23 119.6(6) . . ?
C27 C28 N4 118.1(5) . . ?
C23 C28 N4 122.3(5) . . ?
C30 C29 C34 120.4(6) . . ?
C30 C29 N6 117.3(6) . . ?
C34 C29 N6 122.3(6) . . ?
C31 C30 C29 120.0(6) . . ?
C31 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
C30 C31 C32 120.6(6) . . ?
C30 C31 H31 119.7 . . ?
C32 C31 H31 119.7 . . ?
C33 C32 C31 119.2(6) . . ?
C33 C32 H32 120.4 . . ?
C31 C32 H32 120.4 . . ?
C32 C33 C34 122.0(6) . . ?
C32 C33 H33 119.0 . . ?
C34 C33 H33 119.0 . . ?
C33 C34 C29 117.8(6) . . ?
C33 C34 C35 118.2(6) . . ?
C29 C34 C35 124.0(6) . . ?
O11 C35 O12 123.3(6) . . ?
O11 C35 C34 124.4(6) . . ?
O12 C35 C34 112.2(5) . . ?
O12 C36 H36A 109.5 . . ?
O12 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
O12 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
O13 C37 Rh3 175.6(6) . . ?
O14 C38 Rh3 177.5(6) . . ?
O15 C39 Rh4 175.8(6) . . ?
O16 C40 Rh4 177.6(6) . . ?
N7 C41 C42 112.7(6) . . ?
N7 C41 H41A 109.1 . . ?
C42 C41 H41A 109.1 . . ?
N7 C41 H41B 109.1 . . ?
C42 C41 H41B 109.1 . . ?
H41A C41 H41B 107.8 . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C44 C43 N7 114.5(6) . . ?
C44 C43 H43A 108.6 . . ?
N7 C43 H43A 108.6 . . ?
C44 C43 H43B 108.6 . . ?
N7 C43 H43B 108.6 . . ?
H43A C43 H43B 107.6 . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N7 C45 C46 114.2(6) . . ?
N7 C45 H45A 108.7 . . ?
C46 C45 H45A 108.7 . . ?
N7 C45 H45B 108.7 . . ?
C46 C45 H45B 108.7 . . ?
H45A C45 H45B 107.6 . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C48 C47 N8 112.9(6) . . ?
C48 C47 H47A 109.0 . . ?
N8 C47 H47A 109.0 . . ?
C48 C47 H47B 109.0 . . ?
N8 C47 H47B 109.0 . . ?
H47A C47 H47B 107.8 . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
N8 C49 C50 113.9(6) . . ?
N8 C49 H49A 108.8 . . ?
C50 C49 H49A 108.8 . . ?
N8 C49 H49B 108.8 . . ?
C50 C49 H49B 108.8 . . ?
H49A C49 H49B 107.7 . . ?
C49 C50 H50A 109.5 . . ?
C49 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C49 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C52 C51 N8 113.8(7) . . ?
C52 C51 H51A 108.8 . . ?
N8 C51 H51A 108.8 . . ?
C52 C51 H51B 108.8 . . ?
N8 C51 H51B 108.8 . . ?
H51A C51 H51B 107.7 . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C17 1.847(7) . ?
Rh1 C18 1.859(7) . ?
Rh1 N1 2.094(5) . ?
Rh1 Cl1 2.3529(16) . ?
Rh1 Rh2 2.9718(7) . ?
Rh2 C20 1.840(7) . ?
Rh2 C19 1.858(7) . ?
Rh2 N3 2.099(5) . ?
Rh2 Cl2 2.3489(16) . ?
Rh3 C38 1.842(7) . ?
Rh3 C37 1.863(7) . ?
Rh3 N4 2.105(5) . ?
Rh3 Cl3 2.3401(17) . ?
Rh3 Rh4 2.9628(7) . ?
Rh4 C39 1.844(7) . ?
Rh4 C40 1.848(7) . ?
Rh4 N6 2.096(5) . ?
Rh4 Cl4 2.3507(16) . ?
O1 C1 1.209(7) . ?
O2 C1 1.341(7) . ?
O2 C2 1.437(7) . ?
O3 C15 1.197(8) . ?
O4 C15 1.343(8) . ?
O4 C16 1.437(7) . ?
O5 C17 1.125(7) . ?
O6 C18 1.124(8) . ?
O7 C19 1.123(7) . ?
O8 C20 1.143(7) . ?
O9 C21 1.192(7) . ?
O10 C21 1.333(7) . ?
O10 C22 1.441(7) . ?
O11 C35 1.207(7) . ?
O12 C35 1.346(7) . ?
O12 C36 1.444(7) . ?
O13 C37 1.129(8) . ?
O14 C38 1.140(7) . ?
O15 C39 1.130(7) . ?
O16 C40 1.140(7) . ?
N1 N2 1.308(6) . ?
N1 C8 1.413(7) . ?
N2 N3 1.293(7) . ?
N3 C9 1.421(7) . ?
N4 N5 1.294(7) . ?
N4 C28 1.430(7) . ?
N5 N6 1.297(6) . ?
N6 C29 1.426(7) . ?
N7 C45 1.481(8) . ?
N7 C41 1.490(8) . ?
N7 C43 1.514(8) . ?
N7 H1N 0.9127 . ?
N8 C51 1.492(8) . ?
N8 C47 1.502(9) . ?
N8 C49 1.506(8) . ?
N8 H2N 0.9203 . ?
C1 C3 1.482(8) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 C4 1.399(8) . ?
C3 C8 1.407(8) . ?
C4 C5 1.364(9) . ?
C4 H4 0.9500 . ?
C5 C6 1.371(9) . ?
C5 H5 0.9500 . ?
C6 C7 1.379(9) . ?
C6 H6 0.9500 . ?
C7 C8 1.387(8) . ?
C7 H7 0.9500 . ?
C9 C10 1.394(8) . ?
C9 C14 1.395(8) . ?
C10 C11 1.380(8) . ?
C10 H10 0.9500 . ?
C11 C12 1.374(9) . ?
C11 H11 0.9500 . ?
C12 C13 1.374(9) . ?
C12 H12 0.9500 . ?
C13 C14 1.392(8) . ?
C13 H13 0.9500 . ?
C14 C15 1.495(8) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C21 C23 1.493(9) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 C24 1.393(8) . ?
C23 C28 1.398(8) . ?
C24 C25 1.373(9) . ?
C24 H24 0.9500 . ?
C25 C26 1.390(9) . ?
C25 H25 0.9500 . ?
C26 C27 1.386(8) . ?
C26 H26 0.9500 . ?
C27 C28 1.382(8) . ?
C27 H27 0.9500 . ?
C29 C30 1.384(8) . ?
C29 C34 1.408(8) . ?
C30 C31 1.374(9) . ?
C30 H30 0.9500 . ?
C31 C32 1.394(9) . ?
C31 H31 0.9500 . ?
C32 C33 1.366(8) . ?
C32 H32 0.9500 . ?
C33 C34 1.392(8) . ?
C33 H33 0.9500 . ?
C34 C35 1.479(9) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C41 C42 1.504(10) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 C44 1.508(9) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 C46 1.496(10) . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 C48 1.503(11) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 C50 1.507(9) . ?
C49 H49A 0.9900 . ?
C49 H49B 0.9900 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 C52 1.501(11) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C17 Rh1 Rh2 C20 -117.1(3) . . . . ?
C18 Rh1 Rh2 C20 -26.4(3) . . . . ?
N1 Rh1 Rh2 C20 153.7(2) . . . . ?
Cl1 Rh1 Rh2 C20 64.1(2) . . . . ?
C17 Rh1 Rh2 C19 152.4(3) . . . . ?
C18 Rh1 Rh2 C19 -116.8(3) . . . . ?
N1 Rh1 Rh2 C19 63.3(2) . . . . ?
Cl1 Rh1 Rh2 C19 -26.31(18) . . . . ?
C17 Rh1 Rh2 N3 62.0(2) . . . . ?
C18 Rh1 Rh2 N3 152.8(3) . . . . ?
N1 Rh1 Rh2 N3 -27.12(19) . . . . ?
Cl1 Rh1 Rh2 N3 -116.73(14) . . . . ?
C17 Rh1 Rh2 Cl2 -26.73(19) . . . . ?
C18 Rh1 Rh2 Cl2 64.0(2) . . . . ?
N1 Rh1 Rh2 Cl2 -115.88(14) . . . . ?
Cl1 Rh1 Rh2 Cl2 154.51(6) . . . . ?
C38 Rh3 Rh4 C39 117.5(3) . . . . ?
C37 Rh3 Rh4 C39 -152.6(3) . . . . ?
N4 Rh3 Rh4 C39 -61.7(2) . . . . ?
Cl3 Rh3 Rh4 C39 26.8(2) . . . . ?
C38 Rh3 Rh4 C40 27.0(3) . . . . ?
C37 Rh3 Rh4 C40 116.9(3) . . . . ?
N4 Rh3 Rh4 C40 -152.1(3) . . . . ?
Cl3 Rh3 Rh4 C40 -63.6(2) . . . . ?
C38 Rh3 Rh4 N6 -153.3(3) . . . . ?
C37 Rh3 Rh4 N6 -63.4(2) . . . . ?
N4 Rh3 Rh4 N6 27.58(19) . . . . ?
Cl3 Rh3 Rh4 N6 116.07(14) . . . . ?
C38 Rh3 Rh4 Cl4 -63.9(2) . . . . ?
C37 Rh3 Rh4 Cl4 26.0(2) . . . . ?
N4 Rh3 Rh4 Cl4 116.93(15) . . . . ?
Cl3 Rh3 Rh4 Cl4 -154.57(6) . . . . ?
C17 Rh1 N1 N2 -56.0(5) . . . . ?
Cl1 Rh1 N1 N2 131.0(4) . . . . ?
Rh2 Rh1 N1 N2 36.0(4) . . . . ?
C17 Rh1 N1 C8 110.8(4) . . . . ?
Cl1 Rh1 N1 C8 -62.2(4) . . . . ?
Rh2 Rh1 N1 C8 -157.2(4) . . . . ?
C8 N1 N2 N3 170.9(5) . . . . ?
Rh1 N1 N2 N3 -21.3(7) . . . . ?
N1 N2 N3 C9 172.2(5) . . . . ?
N1 N2 N3 Rh2 -23.2(7) . . . . ?
C19 Rh2 N3 N2 -53.1(5) . . . . ?
Cl2 Rh2 N3 N2 132.8(5) . . . . ?
Rh1 Rh2 N3 N2 37.0(5) . . . . ?
C19 Rh2 N3 C9 110.1(5) . . . . ?
Cl2 Rh2 N3 C9 -64.1(4) . . . . ?
Rh1 Rh2 N3 C9 -159.9(4) . . . . ?
C37 Rh3 N4 N5 52.5(5) . . . . ?
Cl3 Rh3 N4 N5 -133.7(5) . . . . ?
Rh4 Rh3 N4 N5 -37.5(4) . . . . ?
C37 Rh3 N4 C28 -112.5(5) . . . . ?
Cl3 Rh3 N4 C28 61.4(4) . . . . ?
Rh4 Rh3 N4 C28 157.6(4) . . . . ?
C28 N4 N5 N6 -170.5(5) . . . . ?
Rh3 N4 N5 N6 23.5(7) . . . . ?
N4 N5 N6 C29 -169.7(5) . . . . ?
N4 N5 N6 Rh4 21.5(7) . . . . ?
C39 Rh4 N6 N5 56.1(5) . . . . ?
Cl4 Rh4 N6 N5 -130.7(4) . . . . ?
Rh3 Rh4 N6 N5 -36.6(4) . . . . ?
C39 Rh4 N6 C29 -111.7(5) . . . . ?
Cl4 Rh4 N6 C29 61.6(4) . . . . ?
Rh3 Rh4 N6 C29 155.6(4) . . . . ?
C2 O2 C1 O1 -6.9(8) . . . . ?
C2 O2 C1 C3 175.9(5) . . . . ?
O1 C1 C3 C4 -52.8(9) . . . . ?
O2 C1 C3 C4 124.3(6) . . . . ?
O1 C1 C3 C8 128.5(7) . . . . ?
O2 C1 C3 C8 -54.4(8) . . . . ?
C8 C3 C4 C5 1.7(9) . . . . ?
C1 C3 C4 C5 -177.1(6) . . . . ?
C3 C4 C5 C6 -1.9(10) . . . . ?
C4 C5 C6 C7 0.6(10) . . . . ?
C5 C6 C7 C8 0.8(9) . . . . ?
C6 C7 C8 C3 -1.0(9) . . . . ?
C6 C7 C8 N1 -177.7(5) . . . . ?
C4 C3 C8 C7 -0.3(9) . . . . ?
C1 C3 C8 C7 178.4(6) . . . . ?
C4 C3 C8 N1 176.4(5) . . . . ?
C1 C3 C8 N1 -4.9(9) . . . . ?
N2 N1 C8 C7 148.6(5) . . . . ?
Rh1 N1 C8 C7 -20.0(7) . . . . ?
N2 N1 C8 C3 -28.0(8) . . . . ?
Rh1 N1 C8 C3 163.4(4) . . . . ?
N2 N3 C9 C10 152.1(5) . . . . ?
Rh2 N3 C9 C10 -13.4(7) . . . . ?
N2 N3 C9 C14 -28.1(8) . . . . ?
Rh2 N3 C9 C14 166.5(5) . . . . ?
C14 C9 C10 C11 2.1(9) . . . . ?
N3 C9 C10 C11 -178.1(6) . . . . ?
C9 C10 C11 C12 0.5(10) . . . . ?
C10 C11 C12 C13 -1.8(10) . . . . ?
C11 C12 C13 C14 0.5(10) . . . . ?
C12 C13 C14 C9 2.1(10) . . . . ?
C12 C13 C14 C15 -176.3(6) . . . . ?
C10 C9 C14 C13 -3.3(9) . . . . ?
N3 C9 C14 C13 176.8(6) . . . . ?
C10 C9 C14 C15 174.9(6) . . . . ?
N3 C9 C14 C15 -5.0(10) . . . . ?
C16 O4 C15 O3 -4.8(9) . . . . ?
C16 O4 C15 C14 178.8(5) . . . . ?
C13 C14 C15 O3 -52.1(9) . . . . ?
C9 C14 C15 O3 129.6(7) . . . . ?
C13 C14 C15 O4 124.3(6) . . . . ?
C9 C14 C15 O4 -53.9(8) . . . . ?
C22 O10 C21 O9 4.7(9) . . . . ?
C22 O10 C21 C23 -179.3(5) . . . . ?
O9 C21 C23 C24 51.7(9) . . . . ?
O10 C21 C23 C24 -124.4(6) . . . . ?
O9 C21 C23 C28 -127.5(7) . . . . ?
O10 C21 C23 C28 56.4(8) . . . . ?
C28 C23 C24 C25 -2.6(10) . . . . ?
C21 C23 C24 C25 178.2(6) . . . . ?
C23 C24 C25 C26 0.2(10) . . . . ?
C24 C25 C26 C27 1.7(10) . . . . ?
C25 C26 C27 C28 -1.1(10) . . . . ?
C26 C27 C28 C23 -1.3(9) . . . . ?
C26 C27 C28 N4 178.0(6) . . . . ?
C24 C23 C28 C27 3.1(9) . . . . ?
C21 C23 C28 C27 -177.7(6) . . . . ?
C24 C23 C28 N4 -176.2(6) . . . . ?
C21 C23 C28 N4 2.9(10) . . . . ?
N5 N4 C28 C27 -151.3(5) . . . . ?
Rh3 N4 C28 C27 15.5(7) . . . . ?
N5 N4 C28 C23 28.1(8) . . . . ?
Rh3 N4 C28 C23 -165.2(5) . . . . ?
N5 N6 C29 C30 -150.3(5) . . . . ?
Rh4 N6 C29 C30 19.1(7) . . . . ?
N5 N6 C29 C34 29.3(7) . . . . ?
Rh4 N6 C29 C34 -161.3(4) . . . . ?
C34 C29 C30 C31 0.4(9) . . . . ?
N6 C29 C30 C31 -180.0(5) . . . . ?
C29 C30 C31 C32 -0.5(9) . . . . ?
C30 C31 C32 C33 -1.3(9) . . . . ?
C31 C32 C33 C34 3.2(10) . . . . ?
C32 C33 C34 C29 -3.3(9) . . . . ?
C32 C33 C34 C35 178.0(6) . . . . ?
C30 C29 C34 C33 1.4(9) . . . . ?
N6 C29 C34 C33 -178.2(5) . . . . ?
C30 C29 C34 C35 -180.0(6) . . . . ?
N6 C29 C34 C35 0.4(9) . . . . ?
C36 O12 C35 O11 7.8(9) . . . . ?
C36 O12 C35 C34 -176.6(5) . . . . ?
C33 C34 C35 O11 52.7(9) . . . . ?
C29 C34 C35 O11 -125.9(7) . . . . ?
C33 C34 C35 O12 -122.9(6) . . . . ?
C29 C34 C35 O12 58.5(8) . . . . ?
C45 N7 C41 C42 173.5(6) . . . . ?
C43 N7 C41 C42 -57.5(7) . . . . ?
C45 N7 C43 C44 62.9(8) . . . . ?
C41 N7 C43 C44 -64.7(8) . . . . ?
C41 N7 C45 C46 -175.3(6) . . . . ?
C43 N7 C45 C46 55.7(8) . . . . ?
C51 N8 C47 C48 176.6(6) . . . . ?
C49 N8 C47 C48 -54.4(8) . . . . ?
C51 N8 C49 C50 64.2(8) . . . . ?
C47 N8 C49 C50 -61.9(8) . . . . ?
C47 N8 C51 C52 -178.5(6) . . . . ?
C49 N8 C51 C52 53.2(8) . . . . ?
