#------------------------------------------------------------------------------
#$Date: 2016-03-23 02:35:23 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179191 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/33/4313371.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4313371
loop_
_publ_author_name
'Richard D. Adams'
'Burjor Captain'
'Wei Fu'
'Perry J. Pellechia'
'Mark D. Smith'
_publ_section_title
;
 Remarkable Dynamical Opening and Closing of Platinum and Palladium
 Pentaruthenium Carbido Carbonyl Cluster Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2094
_journal_page_last               2101
_journal_paper_doi               10.1021/ic020656o
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C28 H27 O15 P Pt Ru5'
_chemical_formula_weight         1334.91
_chemical_name_systematic
;
  ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.613(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.4684(10)
_cell_length_b                   17.9669(15)
_cell_length_c                   17.3482(14)
_cell_measurement_reflns_used    5552
_cell_measurement_temperature    190(2)
_cell_measurement_theta_max      25.03
_cell_measurement_theta_min      2.46
_cell_volume                     3704.1(5)
_computing_cell_refinement       'SAINT+ NT V6.02a (Bruker, 1998)'
_computing_data_collection       'SMART NT V5.619 (Bruker, 2000)'
_computing_data_reduction        'SAINT+ NT V6.02a'
_computing_molecular_graphics    'SHELXTL V5.1 (Sheldrick, 1997)'
_computing_publication_material  'SHELXTL V5.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      190(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0533
_diffrn_reflns_av_sigmaI/netI    0.0497
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            24504
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.67
_diffrn_standards_decay_%        <1
_exptl_absorpt_coefficient_mu    5.857
_exptl_absorpt_correction_T_max  0.831
_exptl_absorpt_correction_T_min  0.616
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 1997)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.394
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             2512
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.02
_refine_diff_density_max         2.397
_refine_diff_density_min         -0.845
_refine_diff_density_rms         0.201
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.105
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     458
_refine_ls_number_reflns         6558
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.105
_refine_ls_R_factor_all          0.0565
_refine_ls_R_factor_gt           0.0463
_refine_ls_shift/su_max          0.019
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0510P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0996
_refine_ls_wR_factor_ref         0.1034
_reflns_number_gt                5594
_reflns_number_total             6558
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic020656o_2.cif
_cod_data_source_block           bc3521s
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4313371
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.94389(3) 0.22679(2) 0.18142(2) 0.02417(11) Uani 1 1 d . . .
Ru1 Ru 0.72554(5) 0.21401(4) 0.19516(4) 0.02230(17) Uani 1 1 d . . .
Ru2 Ru 0.77694(6) 0.08768(4) 0.10660(4) 0.02732(18) Uani 1 1 d . . .
Ru3 Ru 0.97565(6) 0.06101(4) 0.24235(4) 0.02785(18) Uani 1 1 d . . .
Ru4 Ru 0.91200(5) 0.17167(4) 0.33710(4) 0.02322(17) Uani 1 1 d . . .
Ru5 Ru 0.75247(6) 0.06483(4) 0.25869(4) 0.02611(17) Uani 1 1 d . . .
P1 P 1.07825(18) 0.29470(14) 0.13923(13) 0.0270(5) Uani 1 1 d . . .
O11 O 0.6122(6) 0.3122(4) 0.2911(4) 0.051(2) Uani 1 1 d . . .
O12 O 0.5278(5) 0.2521(4) 0.0507(4) 0.0441(18) Uani 1 1 d . . .
O13 O 0.7947(5) 0.3604(4) 0.1402(4) 0.0454(18) Uani 1 1 d . . .
O21 O 0.8223(6) 0.1394(4) -0.0479(4) 0.0494(19) Uani 1 1 d . . .
O22 O 0.5263(6) 0.0820(5) 0.0173(5) 0.062(2) Uani 1 1 d . . .
O23 O 0.8036(7) -0.0701(4) 0.0541(5) 0.061(2) Uani 1 1 d . . .
O31 O 1.2073(5) 0.0976(4) 0.3576(4) 0.054(2) Uani 1 1 d . . .
O32 O 1.0724(7) -0.0135(6) 0.1202(5) 0.079(3) Uani 1 1 d . . .
O33 O 0.9644(7) -0.0787(4) 0.3373(5) 0.055(2) Uani 1 1 d . . .
O41 O 1.1097(7) 0.2760(5) 0.4008(4) 0.061(2) Uani 1 1 d . . .
O42 O 0.7927(6) 0.2639(5) 0.4333(4) 0.060(2) Uani 1 1 d . . .
O43 O 1.0258(6) 0.0785(4) 0.4845(4) 0.057(2) Uani 1 1 d . . .
O51 O 0.7625(6) 0.0203(4) 0.4310(4) 0.0446(18) Uani 1 1 d . . .
O52 O 0.6543(6) -0.0839(4) 0.1817(4) 0.053(2) Uani 1 1 d . . .
O53 O 0.5171(5) 0.1206(4) 0.2403(5) 0.054(2) Uani 1 1 d . . .
C1 C 0.8550(6) 0.1412(5) 0.2150(5) 0.0216(18) Uani 1 1 d . . .
C11 C 0.6593(8) 0.2773(5) 0.2570(5) 0.031(2) Uani 1 1 d . . .
C12 C 0.6023(7) 0.2362(5) 0.1047(5) 0.030(2) Uani 1 1 d . . .
C13 C 0.8122(7) 0.2993(6) 0.1609(5) 0.028(2) Uani 1 1 d . . .
C21 C 0.8097(7) 0.1246(6) 0.0130(6) 0.036(2) Uani 1 1 d . . .
C22 C 0.6186(9) 0.0851(6) 0.0515(6) 0.044(3) Uani 1 1 d . . .
C23 C 0.7963(8) -0.0122(6) 0.0748(5) 0.040(2) Uani 1 1 d . . .
C31 C 1.1196(9) 0.0850(6) 0.3140(6) 0.043(3) Uani 1 1 d . . .
C32 C 1.0329(8) 0.0122(7) 0.1660(6) 0.051(3) Uani 1 1 d . . .
C33 C 0.9599(8) -0.0268(6) 0.3011(6) 0.042(3) Uani 1 1 d . . .
C41 C 1.0354(8) 0.2387(6) 0.3697(6) 0.039(2) Uani 1 1 d . . .
C42 C 0.8339(7) 0.2301(6) 0.3944(5) 0.034(2) Uani 1 1 d . . .
C43 C 0.9812(8) 0.1130(6) 0.4297(5) 0.036(2) Uani 1 1 d . . .
C51 C 0.7613(7) 0.0371(5) 0.3668(5) 0.032(2) Uani 1 1 d . . .
C52 C 0.6916(7) -0.0276(6) 0.2104(5) 0.033(2) Uani 1 1 d . . .
C53 C 0.6092(9) 0.1098(6) 0.2421(6) 0.044(3) Uani 1 1 d . . .
C60 C 1.0350(7) 0.2999(6) 0.0234(5) 0.033(2) Uani 1 1 d . . .
C61 C 1.1005(9) 0.3573(7) -0.0108(6) 0.050(3) Uani 1 1 d . . .
H61A H 1.1806 0.3443 0.0064 0.075 Uiso 1 1 calc R . .
H61B H 1.0907 0.4069 0.0094 0.075 Uiso 1 1 calc R . .
H61C H 1.0719 0.3570 -0.0700 0.075 Uiso 1 1 calc R . .
C62 C 1.0517(8) 0.2234(6) -0.0090(6) 0.046(3) Uani 1 1 d . . .
H62A H 1.0171 0.1855 0.0165 0.068 Uiso 1 1 calc R . .
H62B H 1.1323 0.2132 0.0034 0.068 Uiso 1 1 calc R . .
H62C H 1.0163 0.2223 -0.0677 0.068 Uiso 1 1 calc R . .
C63 C 0.9091(8) 0.3181(6) -0.0076(5) 0.041(3) Uani 1 1 d . . .
H63A H 0.8822 0.3119 -0.0665 0.061 Uiso 1 1 calc R . .
H63B H 0.8969 0.3696 0.0063 0.061 Uiso 1 1 calc R . .
H63C H 0.8677 0.2843 0.0175 0.061 Uiso 1 1 calc R . .
C70 C 1.2233(7) 0.2453(6) 0.1752(5) 0.030(2) Uani 1 1 d . . .
C71 C 1.3144(8) 0.2739(6) 0.1383(6) 0.046(3) Uani 1 1 d . . .
H71A H 1.3174 0.3284 0.1410 0.070 Uiso 1 1 calc R . .
H71B H 1.2955 0.2581 0.0817 0.070 Uiso 1 1 calc R . .
H71C H 1.3878 0.2534 0.1688 0.070 Uiso 1 1 calc R . .
C72 C 1.2100(8) 0.1610(7) 0.1581(6) 0.050(3) Uani 1 1 d . . .
H72A H 1.2773 0.1350 0.1913 0.075 Uiso 1 1 calc R . .
H72B H 1.2007 0.1518 0.1008 0.075 Uiso 1 1 calc R . .
H72C H 1.1438 0.1427 0.1715 0.075 Uiso 1 1 calc R . .
C73 C 1.2704(8) 0.2563(7) 0.2669(6) 0.046(3) Uani 1 1 d . . .
H73A H 1.2140 0.2409 0.2926 0.068 Uiso 1 1 calc R . .
H73B H 1.2891 0.3088 0.2787 0.068 Uiso 1 1 calc R . .
H73C H 1.3384 0.2260 0.2879 0.068 Uiso 1 1 calc R . .
C80 C 1.0995(8) 0.3958(6) 0.1813(6) 0.041(2) Uani 1 1 d . . .
C81 C 1.2138(9) 0.4321(7) 0.1846(7) 0.052(3) Uani 1 1 d . . .
H81A H 1.2120 0.4851 0.1974 0.079 Uiso 1 1 calc R . .
H81B H 1.2270 0.4264 0.1320 0.079 Uiso 1 1 calc R . .
H81C H 1.2744 0.4076 0.2265 0.079 Uiso 1 1 calc R . .
C82 C 1.0897(8) 0.3952(6) 0.2665(6) 0.049(3) Uani 1 1 d . . .
H82A H 1.0977 0.4460 0.2879 0.073 Uiso 1 1 calc R . .
H82B H 1.1491 0.3637 0.3012 0.073 Uiso 1 1 calc R . .
H82C H 1.0160 0.3754 0.2654 0.073 Uiso 1 1 calc R . .
C83 C 1.0069(8) 0.4488(6) 0.1321(7) 0.047(3) Uani 1 1 d . . .
H83A H 0.9335 0.4317 0.1348 0.071 Uiso 1 1 calc R . .
H83B H 1.0068 0.4492 0.0756 0.071 Uiso 1 1 calc R . .
H83C H 1.0214 0.4992 0.1545 0.071 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C13 Pt1 C1 93.0(3) . . ?
C13 Pt1 P1 103.0(3) . . ?
C1 Pt1 P1 163.3(2) . . ?
C13 Pt1 Ru1 47.1(3) . . ?
C1 Pt1 Ru1 45.9(2) . . ?
P1 Pt1 Ru1 149.79(6) . . ?
C13 Pt1 Ru4 92.8(2) . . ?
C1 Pt1 Ru4 43.9(2) . . ?
P1 Pt1 Ru4 138.25(6) . . ?
Ru1 Pt1 Ru4 60.246(19) . . ?
C13 Pt1 Ru3 132.5(3) . . ?
C1 Pt1 Ru3 39.6(2) . . ?
P1 Pt1 Ru3 124.38(6) . . ?
Ru1 Pt1 Ru3 85.46(2) . . ?
Ru4 Pt1 Ru3 54.897(19) . . ?
C12 Ru1 C11 87.7(4) . . ?
C12 Ru1 C1 133.5(3) . . ?
C11 Ru1 C1 138.3(3) . . ?
C12 Ru1 C13 88.2(4) . . ?
C11 Ru1 C13 94.1(4) . . ?
C1 Ru1 C13 93.9(3) . . ?
C12 Ru1 Pt1 118.7(3) . . ?
C11 Ru1 Pt1 126.3(3) . . ?
C1 Ru1 Pt1 47.5(2) . . ?
C13 Ru1 Pt1 46.4(2) . . ?
C12 Ru1 Ru5 119.3(3) . . ?
C11 Ru1 Ru5 111.0(3) . . ?
C1 Ru1 Ru5 48.6(2) . . ?
C13 Ru1 Ru5 142.3(2) . . ?
Pt1 Ru1 Ru5 96.01(2) . . ?
C12 Ru1 Ru2 88.8(3) . . ?
C11 Ru1 Ru2 163.3(3) . . ?
C1 Ru1 Ru2 45.3(2) . . ?
C13 Ru1 Ru2 102.0(3) . . ?
Pt1 Ru1 Ru2 69.31(2) . . ?
Ru5 Ru1 Ru2 57.23(2) . . ?
C12 Ru1 Ru4 176.9(3) . . ?
C11 Ru1 Ru4 92.9(3) . . ?
C1 Ru1 Ru4 45.6(2) . . ?
C13 Ru1 Ru4 94.8(2) . . ?
Pt1 Ru1 Ru4 63.27(2) . . ?
Ru5 Ru1 Ru4 57.69(2) . . ?
Ru2 Ru1 Ru4 89.75(3) . . ?
C21 Ru2 C23 90.1(4) . . ?
C21 Ru2 C22 92.1(4) . . ?
C23 Ru2 C22 92.0(4) . . ?
C21 Ru2 C1 116.6(4) . . ?
C23 Ru2 C1 129.1(4) . . ?
C22 Ru2 C1 126.4(4) . . ?
C21 Ru2 Ru5 166.6(3) . . ?
C23 Ru2 Ru5 101.2(3) . . ?
C22 Ru2 Ru5 94.5(3) . . ?
C1 Ru2 Ru5 50.5(2) . . ?
C21 Ru2 Ru3 113.5(3) . . ?
C23 Ru2 Ru3 85.8(3) . . ?
C22 Ru2 Ru3 154.3(3) . . ?
C1 Ru2 Ru3 44.6(2) . . ?
Ru5 Ru2 Ru3 61.03(2) . . ?
C21 Ru2 Ru1 108.4(3) . . ?
C23 Ru2 Ru1 161.4(3) . . ?
C22 Ru2 Ru1 85.6(3) . . ?
C1 Ru2 Ru1 43.9(2) . . ?
Ru5 Ru2 Ru1 60.66(2) . . ?
Ru3 Ru2 Ru1 88.32(3) . . ?
C31 Ru3 C32 94.7(4) . . ?
C31 Ru3 C33 93.8(4) . . ?
C32 Ru3 C33 96.4(5) . . ?
C31 Ru3 C1 118.6(4) . . ?
C32 Ru3 C1 124.9(4) . . ?
C33 Ru3 C1 121.2(4) . . ?
C31 Ru3 Ru4 80.6(3) . . ?
C32 Ru3 Ru4 163.0(4) . . ?
C33 Ru3 Ru4 100.1(3) . . ?
C1 Ru3 Ru4 47.4(2) . . ?
C31 Ru3 Ru5 132.8(3) . . ?
C32 Ru3 Ru5 131.1(3) . . ?
C33 Ru3 Ru5 73.2(3) . . ?
C1 Ru3 Ru5 48.5(2) . . ?
Ru4 Ru3 Ru5 58.63(2) . . ?
C31 Ru3 Ru2 154.4(3) . . ?
C32 Ru3 Ru2 85.3(3) . . ?
C33 Ru3 Ru2 111.6(3) . . ?
C1 Ru3 Ru2 45.7(2) . . ?
Ru4 Ru3 Ru2 91.98(3) . . ?
Ru5 Ru3 Ru2 57.45(2) . . ?
C31 Ru3 Pt1 90.2(3) . . ?
C32 Ru3 Pt1 103.8(4) . . ?
C33 Ru3 Pt1 159.0(3) . . ?
C1 Ru3 Pt1 40.6(2) . . ?
Ru4 Ru3 Pt1 60.20(2) . . ?
Ru5 Ru3 Pt1 89.05(2) . . ?
Ru2 Ru3 Pt1 65.18(2) . . ?
C43 Ru4 C41 88.9(4) . . ?
C43 Ru4 C42 92.2(4) . . ?
C41 Ru4 C42 89.5(4) . . ?
C43 Ru4 C1 129.8(4) . . ?
C41 Ru4 C1 117.6(4) . . ?
C42 Ru4 C1 127.0(3) . . ?
C43 Ru4 Ru5 96.0(3) . . ?
C41 Ru4 Ru5 166.0(3) . . ?
C42 Ru4 Ru5 103.4(3) . . ?
C1 Ru4 Ru5 49.9(2) . . ?
C43 Ru4 Ru3 88.1(3) . . ?
C41 Ru4 Ru3 105.8(3) . . ?
C42 Ru4 Ru3 164.7(3) . . ?
C1 Ru4 Ru3 45.6(2) . . ?
Ru5 Ru4 Ru3 61.41(3) . . ?
C43 Ru4 Ru1 153.9(3) . . ?
C41 Ru4 Ru1 116.8(3) . . ?
C42 Ru4 Ru1 83.9(3) . . ?
C1 Ru4 Ru1 43.7(2) . . ?
Ru5 Ru4 Ru1 60.24(2) . . ?
Ru3 Ru4 Ru1 89.14(3) . . ?
C43 Ru4 Pt1 142.4(3) . . ?
C41 Ru4 Pt1 75.2(3) . . ?
C42 Ru4 Pt1 120.9(3) . . ?
C1 Ru4 Pt1 43.6(2) . . ?
Ru5 Ru4 Pt1 93.26(2) . . ?
Ru3 Ru4 Pt1 64.90(2) . . ?
Ru1 Ru4 Pt1 56.481(19) . . ?
C53 Ru5 C52 94.2(4) . . ?
C53 Ru5 C51 91.8(4) . . ?
C52 Ru5 C51 95.8(4) . . ?
C53 Ru5 C1 107.8(4) . . ?
C52 Ru5 C1 126.6(3) . . ?
C51 Ru5 C1 130.1(3) . . ?
C53 Ru5 Ru2 99.3(3) . . ?
C52 Ru5 Ru2 81.7(3) . . ?
C51 Ru5 Ru2 168.7(3) . . ?
C1 Ru5 Ru2 47.7(2) . . ?
C53 Ru5 Ru4 106.2(3) . . ?
C52 Ru5 Ru4 159.6(3) . . ?
C51 Ru5 Ru4 83.1(3) . . ?
C1 Ru5 Ru4 47.8(2) . . ?
Ru2 Ru5 Ru4 95.40(3) . . ?
C53 Ru5 Ru1 63.3(3) . . ?
C52 Ru5 Ru1 131.0(3) . . ?
C51 Ru5 Ru1 125.7(3) . . ?
C1 Ru5 Ru1 44.6(2) . . ?
Ru2 Ru5 Ru1 62.11(2) . . ?
Ru4 Ru5 Ru1 62.07(2) . . ?
C53 Ru5 Ru3 152.4(3) . . ?
C52 Ru5 Ru3 101.7(3) . . ?
C51 Ru5 Ru3 108.6(3) . . ?
C1 Ru5 Ru3 44.8(2) . . ?
Ru2 Ru5 Ru3 61.51(2) . . ?
Ru4 Ru5 Ru3 59.96(2) . . ?
Ru1 Ru5 Ru3 89.36(3) . . ?
C60 P1 C70 107.4(4) . . ?
C60 P1 C80 108.1(5) . . ?
C70 P1 C80 107.4(4) . . ?
C60 P1 Pt1 110.4(3) . . ?
C70 P1 Pt1 110.1(3) . . ?
C80 P1 Pt1 113.3(3) . . ?
Ru1 C1 Ru3 173.3(5) . . ?
Ru1 C1 Ru2 90.8(3) . . ?
Ru3 C1 Ru2 89.6(3) . . ?
Ru1 C1 Pt1 86.6(3) . . ?
Ru3 C1 Pt1 99.8(3) . . ?
Ru2 C1 Pt1 103.5(3) . . ?
Ru1 C1 Ru4 90.7(3) . . ?
Ru3 C1 Ru4 87.0(3) . . ?
Ru2 C1 Ru4 164.0(5) . . ?
Pt1 C1 Ru4 92.5(3) . . ?
Ru1 C1 Ru5 86.8(3) . . ?
Ru3 C1 Ru5 86.7(3) . . ?
Ru2 C1 Ru5 81.9(3) . . ?
Pt1 C1 Ru5 171.6(4) . . ?
Ru4 C1 Ru5 82.3(3) . . ?
O11 C11 Ru1 174.7(9) . . ?
O12 C12 Ru1 177.6(9) . . ?
O13 C13 Pt1 136.6(7) . . ?
O13 C13 Ru1 136.8(7) . . ?
Pt1 C13 Ru1 86.5(4) . . ?
O21 C21 Ru2 171.7(9) . . ?
O22 C22 Ru2 177.6(10) . . ?
O23 C23 Ru2 177.2(10) . . ?
O31 C31 Ru3 178.2(9) . . ?
O32 C32 Ru3 175.5(11) . . ?
O33 C33 Ru3 171.5(10) . . ?
O41 C41 Ru4 169.6(9) . . ?
O42 C42 Ru4 175.4(8) . . ?
O43 C43 Ru4 177.8(9) . . ?
O51 C51 Ru5 177.5(8) . . ?
O52 C52 Ru5 179.3(8) . . ?
O53 C53 Ru5 162.9(9) . . ?
C62 C60 C63 107.6(8) . . ?
C62 C60 C61 108.3(8) . . ?
C63 C60 C61 109.2(8) . . ?
C62 C60 P1 108.4(7) . . ?
C63 C60 P1 108.1(6) . . ?
C61 C60 P1 115.0(7) . . ?
C73 C70 C72 108.1(8) . . ?
C73 C70 C71 106.7(7) . . ?
C72 C70 C71 107.2(8) . . ?
C73 C70 P1 107.7(6) . . ?
C72 C70 P1 110.6(6) . . ?
C71 C70 P1 116.3(7) . . ?
C82 C80 C83 106.1(8) . . ?
C82 C80 C81 108.1(8) . . ?
C83 C80 C81 106.6(8) . . ?
C82 C80 P1 108.5(7) . . ?
C83 C80 P1 112.0(7) . . ?
C81 C80 P1 115.2(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C13 2.042(9) . ?
Pt1 C1 2.079(8) . ?
Pt1 P1 2.361(2) . ?
Pt1 Ru1 2.8133(7) . ?
Pt1 Ru4 3.0139(8) . ?
Pt1 Ru3 3.1454(9) . ?
Ru1 C12 1.878(9) . ?
Ru1 C11 1.914(9) . ?
Ru1 C1 2.024(8) . ?
Ru1 C13 2.064(9) . ?
Ru1 Ru5 2.8786(10) . ?
Ru1 Ru2 2.9186(10) . ?
Ru1 Ru4 2.9295(9) . ?
Ru2 C21 1.910(10) . ?
Ru2 C23 1.914(11) . ?
Ru2 C22 1.916(10) . ?
Ru2 C1 2.074(8) . ?
Ru2 Ru5 2.7767(10) . ?
Ru2 Ru3 2.8953(10) . ?
Ru3 C31 1.898(10) . ?
Ru3 C32 1.899(10) . ?
Ru3 C33 1.920(12) . ?
Ru3 C1 2.034(8) . ?
Ru3 Ru4 2.8415(10) . ?
Ru3 Ru5 2.8820(10) . ?
Ru4 C43 1.897(9) . ?
Ru4 C41 1.900(10) . ?
Ru4 C42 1.904(10) . ?
Ru4 C1 2.093(8) . ?
Ru4 Ru5 2.8025(10) . ?
Ru5 C53 1.901(10) . ?
Ru5 C52 1.911(11) . ?
Ru5 C51 1.911(9) . ?
Ru5 C1 2.163(8) . ?
P1 C60 1.918(9) . ?
P1 C70 1.940(9) . ?
P1 C80 1.945(10) . ?
O11 C11 1.139(10) . ?
O12 C12 1.138(10) . ?
O13 C13 1.155(11) . ?
O21 C21 1.144(11) . ?
O22 C22 1.126(11) . ?
O23 C23 1.115(11) . ?
O31 C31 1.149(11) . ?
O32 C32 1.150(11) . ?
O33 C33 1.117(12) . ?
O41 C41 1.139(11) . ?
O42 C42 1.139(11) . ?
O43 C43 1.131(10) . ?
O51 C51 1.150(10) . ?
O52 C52 1.161(11) . ?
O53 C53 1.155(11) . ?
C60 C62 1.523(14) . ?
C60 C63 1.533(12) . ?
C60 C61 1.541(13) . ?
C70 C73 1.532(13) . ?
C70 C72 1.543(15) . ?
C70 C71 1.551(12) . ?
C80 C82 1.519(13) . ?
C80 C83 1.541(14) . ?
C80 C81 1.552(13) . ?
