#------------------------------------------------------------------------------
#$Date: 2016-03-23 02:49:54 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179209 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/40/4314069.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4314069
loop_
_publ_author_name
'Nate Schultheiss'
'Douglas R. Powell'
'Eric Bosch'
_publ_contact_author
; 
   Prof. Eric Bosch 
   Department of Chemistry 
   Southwest Missouri State University
   901 South National Avenue 
   Springfield, MO  65804  USA 
;
_publ_contact_author_email       erb625f@smsu.edu
_publ_contact_author_fax         1(417)8365507
_publ_contact_author_phone       1(417)8364277
_publ_section_title
;
 Silver(I) Coordination Chemistry of 2,6-Diarylpyrazines. π-Stacking,
 Anion Coordination, and Steric Control
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5304
_journal_page_last               5310
_journal_paper_doi               10.1021/ic034277m
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C24 H20 Ag2 F6 N2 O4'
_chemical_formula_sum            'C24 H20 Ag2 F6 N2 O4'
_chemical_formula_weight         730.16
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.434(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.5410(11)
_cell_length_b                   21.859(2)
_cell_length_c                   10.9825(11)
_cell_measurement_reflns_used    5477
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.00
_cell_measurement_theta_min      2.17
_cell_volume                     2488.7(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'ω scan frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0204
_diffrn_reflns_av_sigmaI/netI    0.0218
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            15378
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.10
_diffrn_standards_decay_%        0.32
_diffrn_standards_number         318
_exptl_absorpt_coefficient_mu    1.653
_exptl_absorpt_correction_T_max  0.8930
_exptl_absorpt_correction_T_min  0.4744
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, 2000'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.949
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needles
_exptl_crystal_F_000             1432
_exptl_crystal_size_max          0.53
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.366
_refine_diff_density_min         -0.595
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     343
_refine_ls_number_reflns         4884
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.0335
_refine_ls_R_factor_gt           0.0315
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1126
_refine_ls_wR_factor_ref         0.1151
_reflns_number_gt                4605
_reflns_number_total             4884
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034277msi20030313_100916_6.cif
_cod_data_source_block           compound_5_
_cod_database_code               4314069
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.604548(19) 0.202368(10) 0.96664(2) 0.01875(11) Uani 1 1 d . . .
Ag2 Ag 0.48381(2) 0.059398(11) 1.05538(2) 0.02884(12) Uani 1 1 d . . .
F1 F 0.1738(2) 0.23693(10) 0.9512(2) 0.0437(5) Uani 1 1 d . . .
F2 F 0.1873(2) 0.22808(11) 1.1460(2) 0.0468(6) Uani 1 1 d . . .
F3 F 0.3304(2) 0.27939(10) 1.0721(2) 0.0446(6) Uani 1 1 d . . .
F4 F 0.7701(2) 0.05661(10) 0.6924(3) 0.0545(7) Uani 1 1 d . . .
F5 F 0.6902(3) 0.14163(11) 0.7289(4) 0.0806(11) Uani 1 1 d . . .
F6 F 0.5775(3) 0.0800(2) 0.6049(3) 0.0964(13) Uani 1 1 d . . .
O1 O 0.4532(2) 0.17296(12) 1.1022(2) 0.0310(5) Uani 1 1 d . . .
O2 O 0.2746(3) 0.12628(13) 1.0113(4) 0.0576(9) Uani 1 1 d . . .
O3 O 0.56577(19) 0.08996(10) 0.8875(2) 0.0229(5) Uani 1 1 d . . .
O4 O 0.6026(2) -0.00278(10) 0.8119(2) 0.0298(5) Uani 1 1 d . . .
N1 N 0.7695(2) 0.23051(11) 1.1086(2) 0.0145(5) Uani 1 1 d . . .
N2 N 0.9554(2) 0.26872(11) 1.3055(2) 0.0179(5) Uani 1 1 d . . .
C1 C 0.7925(3) 0.29073(13) 1.1306(3) 0.0168(6) Uani 1 1 d . . .
C2 C 0.8843(3) 0.30914(13) 1.2299(3) 0.0177(6) Uani 1 1 d . . .
H2 H 0.8976 0.3516 1.2452 0.021 Uiso 1 1 calc R . .
C3 C 0.7184(3) 0.33703(12) 1.0464(3) 0.0171(6) Uani 1 1 d . . .
C4 C 0.7616(3) 0.35272(15) 0.9368(3) 0.0247(7) Uani 1 1 d . . .
C5 C 0.8750(3) 0.3202(2) 0.9008(3) 0.0372(8) Uani 1 1 d . . .
H5A H 0.8975 0.3398 0.8273 0.056 Uiso 1 1 d R . .
H5B H 0.8526 0.2773 0.8824 0.056 Uiso 1 1 d R . .
H5C H 0.9488 0.3224 0.9692 0.056 Uiso 1 1 d R . .
C6 C 0.6977(3) 0.39940(16) 0.8633(3) 0.0302(7) Uani 1 1 d . . .
H6 H 0.7261 0.4108 0.7892 0.036 Uiso 1 1 calc R . .
C7 C 0.5939(3) 0.42908(15) 0.8971(3) 0.0311(8) Uani 1 1 d . . .
H7 H 0.5517 0.4609 0.8463 0.037 Uiso 1 1 calc R . .
C8 C 0.5508(3) 0.41271(14) 1.0049(3) 0.0293(7) Uani 1 1 d . . .
H8 H 0.4784 0.4331 1.0263 0.035 Uiso 1 1 calc R . .
C9 C 0.6125(3) 0.36660(13) 1.0825(3) 0.0202(6) Uani 1 1 d . . .
C10 C 0.5687(3) 0.34933(16) 1.2010(3) 0.0277(7) Uani 1 1 d . . .
H10A H 0.4870 0.3699 1.2050 0.042 Uiso 1 1 d R . .
H10B H 0.6341 0.3619 1.2717 0.042 Uiso 1 1 d R . .
H10C H 0.5565 0.3049 1.2033 0.042 Uiso 1 1 d R . .
C11 C 0.8385(3) 0.18977(13) 1.1850(3) 0.0169(6) Uani 1 1 d . . .
C12 C 0.9323(3) 0.20952(14) 1.2827(3) 0.0217(6) Uani 1 1 d . . .
H12 H 0.9814 0.1800 1.3347 0.026 Uiso 1 1 calc R . .
C13 C 0.8131(3) 0.12292(13) 1.1637(3) 0.0173(6) Uani 1 1 d . . .
C14 C 0.8646(3) 0.09168(15) 1.0724(3) 0.0244(7) Uani 1 1 d . . .
C15 C 0.9420(3) 0.12466(18) 0.9911(4) 0.0394(9) Uani 1 1 d . . .
H15A H 0.9517 0.0985 0.9209 0.059 Uiso 1 1 d R . .
H15B H 1.0273 0.1346 1.0388 0.059 Uiso 1 1 d R . .
H15C H 0.8975 0.1625 0.9603 0.059 Uiso 1 1 d R . .
C16 C 0.8432(3) 0.02885(16) 1.0586(4) 0.0338(8) Uani 1 1 d . . .
H16 H 0.8760 0.0072 0.9960 0.041 Uiso 1 1 calc R . .
C17 C 0.7752(4) -0.00192(16) 1.1346(4) 0.0380(9) Uani 1 1 d . . .
H17 H 0.7630 -0.0448 1.1252 0.046 Uiso 1 1 calc R . .
C18 C 0.7241(3) 0.02870(15) 1.2249(4) 0.0341(8) Uani 1 1 d . . .
H18 H 0.6765 0.0067 1.2761 0.041 Uiso 1 1 calc R . .
C19 C 0.7419(3) 0.09203(14) 1.2416(3) 0.0237(6) Uani 1 1 d . . .
C20 C 0.6880(3) 0.12429(17) 1.3409(3) 0.0308(7) Uani 1 1 d . . .
H20A H 0.6281 0.0971 1.3733 0.046 Uiso 1 1 d R . .
H20B H 0.6421 0.1612 1.3065 0.046 Uiso 1 1 d R . .
H20C H 0.7586 0.1358 1.4080 0.046 Uiso 1 1 d R . .
C21 C 0.3369(3) 0.17053(15) 1.0566(3) 0.0254(7) Uani 1 1 d . . .
C22 C 0.2578(3) 0.22960(15) 1.0564(3) 0.0276(7) Uani 1 1 d . . .
C23 C 0.6054(3) 0.05351(14) 0.8149(3) 0.0222(6) Uani 1 1 d . . .
C24 C 0.6637(4) 0.08337(18) 0.7107(4) 0.0388(9) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N2 146.46(9) . 4_565 ?
N1 Ag1 O1 99.22(8) . . ?
N2 Ag1 O1 96.47(8) 4_565 . ?
O4 Ag2 O3 162.54(8) 3_657 . ?
O4 Ag2 O1 108.95(8) 3_657 . ?
O3 Ag2 O1 87.61(7) . . ?
O4 Ag2 Ag2 82.58(6) 3_657 3_657 ?
O3 Ag2 Ag2 80.38(5) . 3_657 ?
O1 Ag2 Ag2 166.87(5) . 3_657 ?
C21 O1 Ag1 118.0(2) . . ?
C21 O1 Ag2 91.6(2) . . ?
Ag1 O1 Ag2 90.72(8) . . ?
C23 O3 Ag2 123.32(19) . . ?
C23 O4 Ag2 123.2(2) . 3_657 ?
C11 N1 C1 118.3(2) . . ?
C11 N1 Ag1 121.71(19) . . ?
C1 N1 Ag1 119.44(18) . . ?
C12 N2 C2 117.4(3) . . ?
C12 N2 Ag1 120.10(19) . 4_666 ?
C2 N2 Ag1 122.5(2) . 4_666 ?
N1 C1 C2 120.2(3) . . ?
N1 C1 C3 119.5(3) . . ?
C2 C1 C3 120.3(3) . . ?
N2 C2 C1 121.9(3) . . ?
N2 C2 H2 119.0 . . ?
C1 C2 H2 119.0 . . ?
C4 C3 C9 121.7(3) . . ?
C4 C3 C1 118.8(3) . . ?
C9 C3 C1 119.3(3) . . ?
C6 C4 C3 118.5(3) . . ?
C6 C4 C5 121.0(3) . . ?
C3 C4 C5 120.5(3) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C7 C6 C4 120.7(3) . . ?
C7 C6 H6 119.6 . . ?
C4 C6 H6 119.6 . . ?
C6 C7 C8 120.4(3) . . ?
C6 C7 H7 119.8 . . ?
C8 C7 H7 119.8 . . ?
C7 C8 C9 121.1(3) . . ?
C7 C8 H8 119.5 . . ?
C9 C8 H8 119.5 . . ?
C8 C9 C3 117.6(3) . . ?
C8 C9 C10 121.7(3) . . ?
C3 C9 C10 120.7(3) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N1 C11 C12 120.4(3) . . ?
N1 C11 C13 119.3(2) . . ?
C12 C11 C13 120.4(3) . . ?
N2 C12 C11 121.8(3) . . ?
N2 C12 H12 119.1 . . ?
C11 C12 H12 119.1 . . ?
C14 C13 C19 121.3(3) . . ?
C14 C13 C11 120.4(3) . . ?
C19 C13 C11 118.2(3) . . ?
C16 C14 C13 118.8(3) . . ?
C16 C14 C15 120.2(3) . . ?
C13 C14 C15 121.0(3) . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C17 C16 C14 120.6(3) . . ?
C17 C16 H16 119.7 . . ?
C14 C16 H16 119.7 . . ?
C16 C17 C18 120.9(3) . . ?
C16 C17 H17 119.6 . . ?
C18 C17 H17 119.6 . . ?
C17 C18 C19 120.7(3) . . ?
C17 C18 H18 119.7 . . ?
C19 C18 H18 119.7 . . ?
C18 C19 C13 117.8(3) . . ?
C18 C19 C20 120.1(3) . . ?
C13 C19 C20 122.1(3) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
O2 C21 O1 128.1(3) . . ?
O2 C21 C22 114.4(3) . . ?
O1 C21 C22 117.5(3) . . ?
F3 C22 F1 107.0(3) . . ?
F3 C22 F2 108.1(3) . . ?
F1 C22 F2 105.7(3) . . ?
F3 C22 C21 113.0(3) . . ?
F1 C22 C21 112.1(3) . . ?
F2 C22 C21 110.6(3) . . ?
O4 C23 O3 130.1(3) . . ?
O4 C23 C24 114.5(3) . . ?
O3 C23 C24 115.3(3) . . ?
F5 C24 F4 107.0(3) . . ?
F5 C24 F6 106.1(4) . . ?
F4 C24 F6 107.9(4) . . ?
F5 C24 C23 113.6(3) . . ?
F4 C24 C23 113.1(3) . . ?
F6 C24 C23 108.7(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.202(2) . ?
Ag1 N2 2.235(2) 4_565 ?
Ag1 O1 2.457(2) . ?
Ag2 O4 2.229(2) 3_657 ?
Ag2 O3 2.274(2) . ?
Ag2 O1 2.567(3) . ?
Ag2 Ag2 2.9137(5) 3_657 ?
F1 C22 1.332(4) . ?
F2 C22 1.336(4) . ?
F3 C22 1.323(4) . ?
F4 C24 1.312(4) . ?
F5 C24 1.311(5) . ?
F6 C24 1.341(5) . ?
O1 C21 1.238(4) . ?
O2 C21 1.223(4) . ?
O3 C23 1.251(4) . ?
O4 C23 1.231(4) . ?
O4 Ag2 2.229(2) 3_657 ?
N1 C11 1.344(4) . ?
N1 C1 1.352(4) . ?
N2 C12 1.332(4) . ?
N2 C2 1.344(4) . ?
N2 Ag1 2.235(2) 4_666 ?
C1 C2 1.380(4) . ?
C1 C3 1.493(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.404(4) . ?
C3 C9 1.408(4) . ?
C4 C6 1.396(5) . ?
C4 C5 1.504(5) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 C7 1.379(5) . ?
C6 H6 0.9500 . ?
C7 C8 1.390(6) . ?
C7 H7 0.9500 . ?
C8 C9 1.401(4) . ?
C8 H8 0.9500 . ?
C9 C10 1.506(4) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.390(4) . ?
C11 C13 1.496(4) . ?
C12 H12 0.9500 . ?
C13 C14 1.401(4) . ?
C13 C19 1.408(4) . ?
C14 C16 1.396(5) . ?
C14 C15 1.499(5) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C17 1.371(6) . ?
C16 H16 0.9500 . ?
C17 C18 1.383(6) . ?
C17 H17 0.9500 . ?
C18 C19 1.404(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.495(5) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.537(4) . ?
C23 C24 1.539(5) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag1 O1 C21 160.2(2) . . . . ?
N2 Ag1 O1 C21 9.9(2) 4_565 . . . ?
N1 Ag1 O1 Ag2 -107.58(8) . . . . ?
N2 Ag1 O1 Ag2 102.17(8) 4_565 . . . ?
O4 Ag2 O1 C21 -74.0(2) 3_657 . . . ?
O3 Ag2 O1 C21 100.3(2) . . . . ?
Ag2 Ag2 O1 C21 76.5(3) 3_657 . . . ?
O4 Ag2 O1 Ag1 167.92(8) 3_657 . . . ?
O3 Ag2 O1 Ag1 -17.73(8) . . . . ?
Ag2 Ag2 O1 Ag1 -41.5(3) 3_657 . . . ?
O4 Ag2 O3 C23 -18.5(4) 3_657 . . . ?
O1 Ag2 O3 C23 179.5(2) . . . . ?
Ag2 Ag2 O3 C23 -5.8(2) 3_657 . . . ?
N2 Ag1 N1 C11 -173.97(19) 4_565 . . . ?
O1 Ag1 N1 C11 69.2(2) . . . . ?
N2 Ag1 N1 C1 14.6(3) 4_565 . . . ?
O1 Ag1 N1 C1 -102.3(2) . . . . ?
C11 N1 C1 C2 -0.4(4) . . . . ?
Ag1 N1 C1 C2 171.3(2) . . . . ?
C11 N1 C1 C3 179.3(3) . . . . ?
Ag1 N1 C1 C3 -9.0(3) . . . . ?
C12 N2 C2 C1 -1.3(4) . . . . ?
Ag1 N2 C2 C1 179.9(2) 4_666 . . . ?
N1 C1 C2 N2 1.6(4) . . . . ?
C3 C1 C2 N2 -178.1(3) . . . . ?
N1 C1 C3 C4 -84.2(3) . . . . ?
C2 C1 C3 C4 95.5(3) . . . . ?
N1 C1 C3 C9 99.9(3) . . . . ?
C2 C1 C3 C9 -80.4(4) . . . . ?
C9 C3 C4 C6 0.7(4) . . . . ?
C1 C3 C4 C6 -175.1(3) . . . . ?
C9 C3 C4 C5 -180.0(3) . . . . ?
C1 C3 C4 C5 4.2(4) . . . . ?
C3 C4 C6 C7 -0.5(5) . . . . ?
C5 C4 C6 C7 -179.9(3) . . . . ?
C4 C6 C7 C8 -0.3(5) . . . . ?
C6 C7 C8 C9 1.0(5) . . . . ?
C7 C8 C9 C3 -0.8(5) . . . . ?
C7 C8 C9 C10 178.6(3) . . . . ?
C4 C3 C9 C8 0.0(4) . . . . ?
C1 C3 C9 C8 175.8(3) . . . . ?
C4 C3 C9 C10 -179.5(3) . . . . ?
C1 C3 C9 C10 -3.7(4) . . . . ?
C1 N1 C11 C12 -1.0(4) . . . . ?
Ag1 N1 C11 C12 -172.5(2) . . . . ?
C1 N1 C11 C13 179.0(2) . . . . ?
Ag1 N1 C11 C13 7.4(3) . . . . ?
C2 N2 C12 C11 -0.1(4) . . . . ?
Ag1 N2 C12 C11 178.6(2) 4_666 . . . ?
N1 C11 C12 N2 1.3(5) . . . . ?
C13 C11 C12 N2 -178.7(3) . . . . ?
N1 C11 C13 C14 79.6(3) . . . . ?
C12 C11 C13 C14 -100.4(3) . . . . ?
N1 C11 C13 C19 -103.4(3) . . . . ?
C12 C11 C13 C19 76.6(4) . . . . ?
C19 C13 C14 C16 0.6(4) . . . . ?
C11 C13 C14 C16 177.5(3) . . . . ?
C19 C13 C14 C15 -179.1(3) . . . . ?
C11 C13 C14 C15 -2.2(4) . . . . ?
C13 C14 C16 C17 -1.3(5) . . . . ?
C15 C14 C16 C17 178.4(3) . . . . ?
C14 C16 C17 C18 1.3(5) . . . . ?
C16 C17 C18 C19 -0.7(5) . . . . ?
C17 C18 C19 C13 0.0(5) . . . . ?
C17 C18 C19 C20 -178.9(3) . . . . ?
C14 C13 C19 C18 0.1(4) . . . . ?
C11 C13 C19 C18 -176.9(3) . . . . ?
C14 C13 C19 C20 179.0(3) . . . . ?
C11 C13 C19 C20 2.0(4) . . . . ?
Ag1 O1 C21 O2 92.5(4) . . . . ?
Ag2 O1 C21 O2 0.8(4) . . . . ?
Ag1 O1 C21 C22 -88.1(3) . . . . ?
Ag2 O1 C21 C22 -179.8(3) . . . . ?
O2 C21 C22 F3 -161.9(3) . . . . ?
O1 C21 C22 F3 18.6(4) . . . . ?
O2 C21 C22 F1 -41.0(4) . . . . ?
O1 C21 C22 F1 139.6(3) . . . . ?
O2 C21 C22 F2 76.8(4) . . . . ?
O1 C21 C22 F2 -102.7(3) . . . . ?
Ag2 O4 C23 O3 1.1(5) 3_657 . . . ?
Ag2 O4 C23 C24 -177.2(2) 3_657 . . . ?
Ag2 O3 C23 O4 4.8(5) . . . . ?
Ag2 O3 C23 C24 -177.0(2) . . . . ?
O4 C23 C24 F5 -166.8(3) . . . . ?
O3 C23 C24 F5 14.6(5) . . . . ?
O4 C23 C24 F4 -44.6(5) . . . . ?
O3 C23 C24 F4 136.9(3) . . . . ?
O4 C23 C24 F6 75.2(4) . . . . ?
O3 C23 C24 F6 -103.3(4) . . . . ?
