#------------------------------------------------------------------------------
#$Date: 2017-03-02 19:20:33 +0200 (Thu, 02 Mar 2017) $
#$Revision: 192782 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/31/78/4317870.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4317870
loop_
_publ_author_name
'Carsten Knapp'
'Enno Lork'
'Paul G. Watson'
'Rüdiger Mews'
_publ_contact_author
;
          Rüdiger Mews
          Institute of Inorganic and Physical Chemistry
          University of Bremen
          P.O.330 440
          D - 28334 Bremen
          Germany
;
_publ_contact_author_fax         '+49 421 218 4267'
_publ_contact_author_phone       '+49 421 218 3354'
_publ_section_title
;
 Lithium Fluoroarylamidinates: Syntheses, Structures, and Reactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2014
_journal_page_last               2025
_journal_paper_doi               10.1021/ic011099t
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C40 H48 F8 Li2 N6 Si4'
_chemical_formula_weight         891.08
_chemical_name_systematic
;
   ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.87(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.282(4)
_cell_length_b                   18.171(4)
_cell_length_c                   14.203(3)
_cell_measurement_reflns_used    8000
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.05
_cell_measurement_theta_min      1.65
_cell_volume                     4786.7(19)
_computing_cell_refinement       'STOE cell'
_computing_data_collection       'STOE expose'
_computing_data_reduction        'STOE reduce'
_computing_molecular_graphics    Diamond
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'STOE IPDS'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1171
_diffrn_reflns_av_sigmaI/netI    0.0849
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            30701
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.95
_diffrn_standards_decay_%        'random variation +/-2.0'
_exptl_absorpt_coefficient_mu    0.189
_exptl_absorpt_correction_T_max  0.9454
_exptl_absorpt_correction_T_min  0.9113
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            'light brown'
_exptl_crystal_density_diffrn    1.236
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blocks
_exptl_crystal_F_000             1856
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.30
_refine_diff_density_max         0.355
_refine_diff_density_min         -0.277
_refine_diff_density_rms         0.062
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.810
_refine_ls_hydrogen_treatment    refU
_refine_ls_matrix_type           full
_refine_ls_number_parameters     277
_refine_ls_number_reflns         4220
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.810
_refine_ls_R_factor_all          0.1074
_refine_ls_R_factor_gt           0.0509
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0640P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1048
_refine_ls_wR_factor_ref         0.1169
_reflns_number_gt                2223
_reflns_number_total             4220
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic011099t_06.cif
_cod_data_source_block           3d
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:
data name '_publ_contact_autor' replaced with '_publ_contact_author'
as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 4998 2017-03-02 13:24:31Z antanas 
;
_cod_original_cell_volume        4786.7(18)
_cod_database_code               4317870
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Li1 Li -0.0194(3) 0.2850(3) 0.3249(4) 0.0497(14) Uani 1 1 d . . .
N1 N 0.01750(12) 0.18108(13) 0.33539(17) 0.0379(6) Uani 1 1 d . . .
Si1 Si 0.04478(5) 0.14488(5) 0.45185(6) 0.0394(2) Uani 1 1 d . . .
C6 C 0.12352(18) 0.0805(2) 0.4764(2) 0.0522(9) Uani 1 1 d . . .
H6A H 0.1086 0.0340 0.4419 0.087(3) Uiso 1 1 calc R . .
H6B H 0.1410 0.0712 0.5469 0.087(3) Uiso 1 1 calc R . .
H6C H 0.1622 0.1027 0.4531 0.087(3) Uiso 1 1 calc R . .
C7 C 0.07478(18) 0.22394(19) 0.5380(2) 0.0542(9) Uani 1 1 d . . .
H7A H 0.1169 0.2475 0.5247 0.087(3) Uiso 1 1 calc R . .
H7B H 0.0876 0.2059 0.6056 0.087(3) Uiso 1 1 calc R . .
H7C H 0.0355 0.2598 0.5287 0.087(3) Uiso 1 1 calc R . .
C8 C -0.03196(18) 0.09956(19) 0.4855(2) 0.0510(9) Uani 1 1 d . . .
H8A H -0.0687 0.1364 0.4871 0.087(3) Uiso 1 1 calc R . .
H8B H -0.0145 0.0767 0.5501 0.087(3) Uiso 1 1 calc R . .
H8C H -0.0530 0.0617 0.4368 0.087(3) Uiso 1 1 calc R . .
C1 C 0.0000 0.1466(2) 0.2500 0.0354(9) Uani 1 2 d S . .
C2 C 0.0000 0.0627(2) 0.2500 0.0386(10) Uani 1 2 d S . .
C3 C 0.06003(19) 0.02144(18) 0.2494(2) 0.0468(8) Uani 1 1 d . . .
F1 F 0.12133(10) 0.05830(11) 0.24854(14) 0.0596(5) Uani 1 1 d . . .
C4 C 0.0619(2) -0.0545(2) 0.2501(2) 0.0586(10) Uani 1 1 d . . .
H4 H 0.1049 -0.0803 0.2506 0.088(5) Uiso 1 1 calc R . .
C5 C 0.0000 -0.0917(3) 0.2500 0.0657(16) Uani 1 2 d S . .
H5 H 0.0000 -0.1440 0.2500 0.088(5) Uiso 1 2 calc SR . .
N2 N 0.05858(13) 0.36062(14) 0.29531(17) 0.0411(6) Uiso 1 1 d . . .
Si2 Si 0.14522(5) 0.38885(5) 0.35418(7) 0.0474(3) Uani 1 1 d . . .
C14 C 0.20119(18) 0.3043(2) 0.3603(3) 0.0650(11) Uani 1 1 d . . .
H14A H 0.1797 0.2638 0.3883 0.087(3) Uiso 1 1 calc R . .
H14B H 0.2501 0.3138 0.4016 0.087(3) Uiso 1 1 calc R . .
H14C H 0.2031 0.2909 0.2942 0.087(3) Uiso 1 1 calc R . .
C15 C 0.1526(2) 0.4236(2) 0.4798(3) 0.0687(11) Uani 1 1 d . . .
H15A H 0.1225 0.4676 0.4759 0.087(3) Uiso 1 1 calc R . .
H15B H 0.2029 0.4361 0.5121 0.087(3) Uiso 1 1 calc R . .
H15C H 0.1362 0.3855 0.5176 0.087(3) Uiso 1 1 calc R . .
C16 C 0.18097(19) 0.4612(2) 0.2868(3) 0.0677(11) Uani 1 1 d . . .
H16A H 0.1700 0.4479 0.2175 0.087(3) Uiso 1 1 calc R . .
H16B H 0.2333 0.4652 0.3143 0.087(3) Uiso 1 1 calc R . .
H16C H 0.1584 0.5085 0.2934 0.087(3) Uiso 1 1 calc R . .
C9 C 0.0000 0.3976(2) 0.2500 0.0355(10) Uani 1 2 d S . .
C10 C 0.0000 0.4804(2) 0.2500 0.0440(11) Uani 1 2 d S . .
C11 C -0.0136(2) 0.5198(2) 0.3256(4) 0.0740(13) Uani 1 1 d . . .
F2 F -0.02788(14) 0.48230(19) 0.39961(19) 0.1061(10) Uani 1 1 d . . .
C12 C -0.0135(3) 0.5963(3) 0.3253(6) 0.143(3) Uani 1 1 d . . .
H12 H -0.0230 0.6228 0.3781 0.088(5) Uiso 1 1 calc R . .
C13 C 0.0000 0.6324(6) 0.2500 0.212(11) Uani 1 2 d S . .
H13 H 0.0000 0.6846 0.2500 0.088(5) Uiso 1 2 calc SR . .
N3 N -0.08944(16) 0.30240(16) 0.4124(2) 0.0572(8) Uani 1 1 d . . .
C17 C -0.12693(18) 0.31034(18) 0.4617(3) 0.0494(8) Uani 1 1 d . . .
C18 C -0.17280(16) 0.32076(17) 0.5245(2) 0.0434(8) Uani 1 1 d . . .
C19 C -0.22979(18) 0.36974(19) 0.5018(3) 0.0539(9) Uani 1 1 d . . .
F3 F -0.24275(11) 0.40539(13) 0.41567(18) 0.0795(7) Uani 1 1 d . . .
C20 C -0.27311(19) 0.3825(2) 0.5621(4) 0.0670(11) Uani 1 1 d . . .
H20 H -0.3114 0.4172 0.5448 0.088(5) Uiso 1 1 calc R . .
C21 C -0.2598(2) 0.3440(2) 0.6478(4) 0.0713(12) Uani 1 1 d . . .
H21 H -0.2899 0.3518 0.6898 0.088(5) Uiso 1 1 calc R . .
C22 C -0.2041(2) 0.2943(2) 0.6748(3) 0.0641(10) Uani 1 1 d . . .
H22 H -0.1952 0.2680 0.7347 0.088(5) Uiso 1 1 calc R . .
C23 C -0.16171(18) 0.28379(19) 0.6126(3) 0.0520(9) Uani 1 1 d . . .
F4 F -0.10676(11) 0.23492(12) 0.63606(15) 0.0704(6) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Li1 N3 111.8(3) . . ?
N1 Li1 N2 111.2(3) . . ?
N3 Li1 N2 128.0(3) . . ?
N1 Li1 N2 134.1(3) . 2 ?
N3 Li1 N2 103.3(2) . 2 ?
N2 Li1 N2 63.48(19) . 2 ?
N1 Li1 C9 138.2(3) . . ?
N3 Li1 C9 109.9(2) . . ?
N2 Li1 C9 33.34(10) . . ?
N2 Li1 C9 33.34(10) 2 . ?
N1 Li1 Li1 82.99(18) . 2 ?
N3 Li1 Li1 156.6(4) . 2 ?
N2 Li1 Li1 55.62(18) . 2 ?
N2 Li1 Li1 55.6(2) 2 2 ?
C9 Li1 Li1 59.19(14) . 2 ?
N1 Li1 Si1 29.25(11) . . ?
N3 Li1 Si1 89.9(2) . . ?
N2 Li1 Si1 116.0(2) . . ?
N2 Li1 Si1 163.4(3) 2 . ?
C9 Li1 Si1 149.3(2) . . ?
Li1 Li1 Si1 109.34(17) 2 . ?
C1 N1 Si1 129.3(2) . . ?
C1 N1 Li1 112.4(3) . . ?
Si1 N1 Li1 116.0(2) . . ?
N1 Si1 C8 111.02(14) . . ?
N1 Si1 C6 115.87(14) . . ?
C8 Si1 C6 109.64(16) . . ?
N1 Si1 C7 107.03(14) . . ?
C8 Si1 C7 107.24(16) . . ?
C6 Si1 C7 105.53(15) . . ?
N1 Si1 Li1 34.72(13) . . ?
C8 Si1 Li1 106.66(14) . . ?
C6 Si1 Li1 141.11(15) . . ?
C7 Si1 Li1 76.00(15) . . ?
N1 C1 N1 123.5(4) . 2 ?
N1 C1 C2 118.2(2) . . ?
N1 C1 C2 118.2(2) 2 . ?
C3 C2 C3 114.3(4) . 2 ?
C3 C2 C1 122.9(2) . . ?
C3 C2 C1 122.9(2) 2 . ?
F1 C3 C4 118.0(3) . . ?
F1 C3 C2 117.7(3) . . ?
C4 C3 C2 124.3(4) . . ?
C5 C4 C3 118.1(4) . . ?
C4 C5 C4 120.9(5) . 2 ?
C9 N2 Si2 132.0(2) . . ?
C9 N2 Li1 82.6(2) . . ?
Si2 N2 Li1 136.6(2) . . ?
C9 N2 Li1 82.6(2) . 2 ?
Si2 N2 Li1 130.83(19) . 2 ?
Li1 N2 Li1 68.8(3) . 2 ?
N2 Si2 C15 111.98(15) . . ?
N2 Si2 C16 113.88(15) . . ?
C15 Si2 C16 108.08(19) . . ?
N2 Si2 C14 104.38(15) . . ?
C15 Si2 C14 110.09(18) . . ?
C16 Si2 C14 108.30(18) . . ?
N2 C9 N2 118.8(4) 2 . ?
N2 C9 C10 120.60(19) 2 . ?
N2 C9 C10 120.60(19) . . ?
N2 C9 Li1 64.1(2) 2 2 ?
N2 C9 Li1 64.1(2) . 2 ?
C10 C9 Li1 149.19(15) . 2 ?
N2 C9 Li1 64.1(2) 2 . ?
N2 C9 Li1 64.1(2) . . ?
C10 C9 Li1 149.19(14) . . ?
Li1 C9 Li1 61.6(3) 2 . ?
C11 C10 C11 117.2(6) 2 . ?
C11 C10 C9 121.4(3) 2 . ?
C11 C10 C9 121.4(3) . . ?
F2 C11 C10 118.2(4) . . ?
F2 C11 C12 120.6(5) . . ?
C10 C11 C12 121.2(6) . . ?
C13 C12 C11 119.5(9) . . ?
C12 C13 C12 121.4(10) 2 . ?
C17 N3 Li1 178.2(3) . . ?
N3 C17 C18 179.0(4) . . ?
C19 C18 C23 116.1(3) . . ?
C19 C18 C17 121.9(3) . . ?
C23 C18 C17 122.1(3) . . ?
F3 C19 C20 119.6(3) . . ?
F3 C19 C18 117.4(3) . . ?
C20 C19 C18 123.1(4) . . ?
C21 C20 C19 118.2(4) . . ?
C20 C21 C22 121.8(4) . . ?
C23 C22 C21 118.0(4) . . ?
F4 C23 C22 119.8(3) . . ?
F4 C23 C18 117.3(3) . . ?
C22 C23 C18 122.9(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Li1 N1 2.009(6) . ?
Li1 N3 2.094(6) . ?
Li1 N2 2.161(6) . ?
Li1 N2 2.161(6) 2 ?
Li1 C9 2.383(6) . ?
Li1 Li1 2.441(11) 2 ?
Li1 Si1 3.169(5) . ?
N1 C1 1.324(3) . ?
N1 Si1 1.723(3) . ?
Si1 C8 1.866(3) . ?
Si1 C6 1.872(3) . ?
Si1 C7 1.873(3) . ?
C1 N1 1.324(3) 2 ?
C1 C2 1.525(6) . ?
C2 C3 1.381(4) . ?
C2 C3 1.381(4) 2 ?
C3 F1 1.362(4) . ?
C3 C4 1.381(5) . ?
C4 C5 1.372(4) . ?
C5 C4 1.372(4) 2 ?
N2 C9 1.321(3) . ?
N2 Si2 1.729(3) . ?
N2 Li1 2.161(6) 2 ?
Si2 C15 1.862(4) . ?
Si2 C16 1.865(4) . ?
Si2 C14 1.866(4) . ?
C9 N2 1.321(3) 2 ?
C9 C10 1.504(6) . ?
C9 Li1 2.383(6) 2 ?
C10 C11 1.374(5) 2 ?
C10 C11 1.374(5) . ?
C11 F2 1.343(5) . ?
C11 C12 1.390(7) . ?
C12 C13 1.340(8) . ?
C13 C12 1.340(8) 2 ?
N3 C17 1.144(4) . ?
C17 C18 1.430(5) . ?
C18 C19 1.382(4) . ?
C18 C23 1.384(5) . ?
C19 F3 1.346(4) . ?
C19 C20 1.369(5) . ?
C20 C21 1.366(6) . ?
C21 C22 1.376(6) . ?
C22 C23 1.370(5) . ?
C23 F4 1.353(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 Li1 N1 C1 120.0(3) . . . . ?
N2 Li1 N1 C1 -90.1(3) . . . . ?
N2 Li1 N1 C1 -17.0(5) 2 . . . ?
C9 Li1 N1 C1 -65.6(5) . . . . ?
Li1 Li1 N1 C1 -41.2(3) 2 . . . ?
Si1 Li1 N1 C1 164.3(3) . . . . ?
N3 Li1 N1 Si1 -44.3(3) . . . . ?
N2 Li1 N1 Si1 105.6(3) . . . . ?
N2 Li1 N1 Si1 178.6(3) 2 . . . ?
C9 Li1 N1 Si1 130.0(4) . . . . ?
Li1 Li1 N1 Si1 154.5(2) 2 . . . ?
C1 N1 Si1 C8 -72.0(2) . . . . ?
Li1 N1 Si1 C8 89.1(2) . . . . ?
C1 N1 Si1 C6 53.9(3) . . . . ?
Li1 N1 Si1 C6 -145.0(2) . . . . ?
C1 N1 Si1 C7 171.2(2) . . . . ?
Li1 N1 Si1 C7 -27.6(2) . . . . ?
C1 N1 Si1 Li1 -161.2(3) . . . . ?
N3 Li1 Si1 N1 139.6(3) . . . . ?
N2 Li1 Si1 N1 -87.3(3) . . . . ?
N2 Li1 Si1 N1 -3.4(7) 2 . . . ?
C9 Li1 Si1 N1 -88.8(5) . . . . ?
Li1 Li1 Si1 N1 -27.0(2) 2 . . . ?
N1 Li1 Si1 C8 -103.0(2) . . . . ?
N3 Li1 Si1 C8 36.5(2) . . . . ?
N2 Li1 Si1 C8 169.6(2) . . . . ?
N2 Li1 Si1 C8 -106.4(8) 2 . . . ?
C9 Li1 Si1 C8 168.1(4) . . . . ?
Li1 Li1 Si1 C8 -130.0(3) 2 . . . ?
N1 Li1 Si1 C6 55.3(3) . . . . ?
N3 Li1 Si1 C6 -165.1(2) . . . . ?
N2 Li1 Si1 C6 -32.0(4) . . . . ?
N2 Li1 Si1 C6 51.9(9) 2 . . . ?
C9 Li1 Si1 C6 -33.5(6) . . . . ?
Li1 Li1 Si1 C6 28.4(4) 2 . . . ?
N1 Li1 Si1 C7 152.8(2) . . . . ?
N3 Li1 Si1 C7 -67.6(2) . . . . ?
N2 Li1 Si1 C7 65.5(3) . . . . ?
N2 Li1 Si1 C7 149.4(9) 2 . . . ?
C9 Li1 Si1 C7 64.0(5) . . . . ?
Li1 Li1 Si1 C7 125.8(3) 2 . . . ?
Si1 N1 C1 N1 -177.2(2) . . . 2 ?
Li1 N1 C1 N1 21.13(18) . . . 2 ?
Si1 N1 C1 C2 2.8(2) . . . . ?
Li1 N1 C1 C2 -158.87(18) . . . . ?
N1 C1 C2 C3 -90.12(18) . . . . ?
N1 C1 C2 C3 89.88(18) 2 . . . ?
N1 C1 C2 C3 89.88(18) . . . 2 ?
N1 C1 C2 C3 -90.12(18) 2 . . 2 ?
C3 C2 C3 F1 179.8(3) 2 . . . ?
C1 C2 C3 F1 -0.2(3) . . . . ?
C3 C2 C3 C4 -0.5(2) 2 . . . ?
C1 C2 C3 C4 179.5(2) . . . . ?
F1 C3 C4 C5 -179.4(2) . . . . ?
C2 C3 C4 C5 0.9(4) . . . . ?
C3 C4 C5 C4 -0.4(2) . . . 2 ?
N1 Li1 N2 C9 149.8(3) . . . . ?
N3 Li1 N2 C9 -66.4(4) . . . . ?
N2 Li1 N2 C9 19.93(14) 2 . . . ?
Li1 Li1 N2 C9 84.9(2) 2 . . . ?
Si1 Li1 N2 C9 -178.6(2) . . . . ?
N1 Li1 N2 Si2 -62.6(4) . . . . ?
N3 Li1 N2 Si2 81.1(4) . . . . ?
N2 Li1 N2 Si2 167.5(2) 2 . . . ?
C9 Li1 N2 Si2 147.5(3) . . . . ?
Li1 Li1 N2 Si2 -127.6(3) 2 . . . ?
Si1 Li1 N2 Si2 -31.1(4) . . . . ?
N1 Li1 N2 Li1 64.94(19) . . . 2 ?
N3 Li1 N2 Li1 -151.3(5) . . . 2 ?
N2 Li1 N2 Li1 -65.0(2) 2 . . 2 ?
C9 Li1 N2 Li1 -84.9(2) . . . 2 ?
Si1 Li1 N2 Li1 96.50(19) . . . 2 ?
C9 N2 Si2 C15 79.5(3) . . . . ?
Li1 N2 Si2 C15 -54.8(3) . . . . ?
Li1 N2 Si2 C15 -157.2(3) 2 . . . ?
C9 N2 Si2 C16 -43.5(3) . . . . ?
Li1 N2 Si2 C16 -177.8(3) . . . . ?
Li1 N2 Si2 C16 79.7(3) 2 . . . ?
C9 N2 Si2 C14 -161.4(2) . . . . ?
Li1 N2 Si2 C14 64.3(3) . . . . ?
Li1 N2 Si2 C14 -38.2(3) 2 . . . ?
Si2 N2 C9 N2 175.1(3) . . . 2 ?
Li1 N2 C9 N2 -34.71(16) . . . 2 ?
Li1 N2 C9 N2 34.71(15) 2 . . 2 ?
Si2 N2 C9 C10 -4.9(3) . . . . ?
Li1 N2 C9 C10 145.29(16) . . . . ?
Li1 N2 C9 C10 -145.29(15) 2 . . . ?
Si2 N2 C9 Li1 140.3(3) . . . 2 ?
Li1 N2 C9 Li1 -69.4(3) . . . 2 ?
Si2 N2 C9 Li1 -150.2(3) . . . . ?
Li1 N2 C9 Li1 69.4(3) 2 . . . ?
N1 Li1 C9 N2 101.7(5) . . . 2 ?
N3 Li1 C9 N2 -83.9(3) . . . 2 ?
N2 Li1 C9 N2 146.3(2) . . . 2 ?
Li1 Li1 C9 N2 73.1(3) 2 . . 2 ?
Si1 Li1 C9 N2 148.7(5) . . . 2 ?
N1 Li1 C9 N2 -44.6(4) . . . . ?
N3 Li1 C9 N2 129.8(3) . . . . ?
N2 Li1 C9 N2 -146.3(2) 2 . . . ?
Li1 Li1 C9 N2 -73.2(2) 2 . . . ?
Si1 Li1 C9 N2 2.5(4) . . . . ?
N1 Li1 C9 C10 -151.5(3) . . . . ?
N3 Li1 C9 C10 22.9(4) . . . . ?
N2 Li1 C9 C10 -106.8(2) . . . . ?
N2 Li1 C9 C10 106.9(3) 2 . . . ?
Li1 Li1 C9 C10 180.0 2 . . . ?
Si1 Li1 C9 C10 -104.4(4) . . . . ?
N1 Li1 C9 Li1 28.5(3) . . . 2 ?
N3 Li1 C9 Li1 -157.1(4) . . . 2 ?
N2 Li1 C9 Li1 73.2(2) . . . 2 ?
N2 Li1 C9 Li1 -73.1(3) 2 . . 2 ?
Si1 Li1 C9 Li1 75.6(4) . . . 2 ?
N2 C9 C10 C11 -85.3(2) 2 . . 2 ?
N2 C9 C10 C11 94.7(2) . . . 2 ?
Li1 C9 C10 C11 4.7(3) 2 . . 2 ?
Li1 C9 C10 C11 -175.3(3) . . . 2 ?
N2 C9 C10 C11 94.7(2) 2 . . . ?
N2 C9 C10 C11 -85.3(2) . . . . ?
Li1 C9 C10 C11 -175.3(3) 2 . . . ?
Li1 C9 C10 C11 4.7(3) . . . . ?
C11 C10 C11 F2 179.2(4) 2 . . . ?
C9 C10 C11 F2 -0.8(4) . . . . ?
C11 C10 C11 C12 0.0(3) 2 . . . ?
C9 C10 C11 C12 -180.0(3) . . . . ?
F2 C11 C12 C13 -179.2(3) . . . . ?
C10 C11 C12 C13 0.0(6) . . . . ?
C11 C12 C13 C12 0.0(3) . . . 2 ?
N1 Li1 N3 C17 22(11) . . . . ?
N2 Li1 N3 C17 -122(11) . . . . ?
N2 Li1 N3 C17 172(11) 2 . . . ?
C9 Li1 N3 C17 -154(11) . . . . ?
Li1 Li1 N3 C17 148(11) 2 . . . ?
Si1 Li1 N3 C17 2(11) . . . . ?
Li1 N3 C17 C18 75(28) . . . . ?
N3 C17 C18 C19 114(24) . . . . ?
N3 C17 C18 C23 -64(24) . . . . ?
C23 C18 C19 F3 -178.7(3) . . . . ?
C17 C18 C19 F3 2.8(5) . . . . ?
C23 C18 C19 C20 0.6(5) . . . . ?
C17 C18 C19 C20 -177.9(3) . . . . ?
F3 C19 C20 C21 178.2(3) . . . . ?
C18 C19 C20 C21 -1.1(5) . . . . ?
C19 C20 C21 C22 0.9(6) . . . . ?
C20 C21 C22 C23 -0.3(6) . . . . ?
C21 C22 C23 F4 -179.4(3) . . . . ?
C21 C22 C23 C18 -0.2(5) . . . . ?
C19 C18 C23 F4 179.3(3) . . . . ?
C17 C18 C23 F4 -2.2(5) . . . . ?
C19 C18 C23 C22 0.0(5) . . . . ?
C17 C18 C23 C22 178.5(3) . . . . ?
