#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:43:19 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179259 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/79/4317906.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4317906
loop_
_publ_author_name
'Eric Bosch'
'Charles L. Barnes'
_publ_section_title
;
 One- and Two-Dimensional Silver-Coordination Networks Containing
 π-Sandwiched Silver-Silver Interactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2543
_journal_page_last               2547
_journal_paper_doi               10.1021/ic010795q
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C34 H33 Ag2 F6 N3 O4 S0'
_chemical_formula_weight         877.37
_chemical_name_systematic
;
   ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.5010(10)
_cell_angle_beta                 90.4280(10)
_cell_angle_gamma                117.5980(10)
_cell_formula_units_Z            2
_cell_length_a                   11.6549(8)
_cell_length_b                   11.7464(9)
_cell_length_c                   14.8121(11)
_cell_measurement_reflns_used    7513
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.2
_cell_measurement_theta_min      2.3
_cell_volume                     1721.7(2)
_computing_cell_refinement       'SMART (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'ORTEP-III (Burnett & Johnson, 1996)'
_computing_publication_material  'CIFTAB (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'Bruker SMART CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0180
_diffrn_reflns_av_sigmaI/netI    0.0252
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            12188
_diffrn_reflns_theta_full        27.18
_diffrn_reflns_theta_max         27.18
_diffrn_reflns_theta_min         1.43
_diffrn_standards_decay_%        0.0
_exptl_absorpt_coefficient_mu    1.211
_exptl_absorpt_correction_T_max  0.86
_exptl_absorpt_correction_T_min  0.62
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
   Data were corrected for decay and absorption using the program SADABS
   based on the method of R.H. Blessing (Acta Cryst. A51, 33-38, 1995).
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.692
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             876
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.885
_refine_diff_density_min         -0.448
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     451
_refine_ls_number_reflns         7403
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.0392
_refine_ls_R_factor_gt           0.0316
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0469P)²+0.8286P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0799
_refine_ls_wR_factor_ref         0.0841
_reflns_number_gt                6275
_reflns_number_total             7403
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic010795q_1.cif
_cod_data_source_block           N3M3-1D
_cod_database_code               4317906
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.09920(2) 0.97780(2) 0.447066(15) 0.03460(7) Uani 1 1 d . . .
Ag2 Ag 0.49137(2) 0.99439(2) 0.097373(15) 0.03531(7) Uani 1 1 d . . .
F1 F 0.38506(19) 1.3317(2) 0.73252(15) 0.0584(5) Uani 1 1 d . . .
F2 F 0.3368(2) 1.1472(2) 0.76544(14) 0.0554(5) Uani 1 1 d . . .
F3 F 0.2325(2) 1.2551(2) 0.81600(13) 0.0542(5) Uani 1 1 d . . .
F4 F 0.02438(18) 0.7829(2) -0.04002(16) 0.0574(5) Uani 1 1 d . . .
F5 F 0.0563(2) 0.6822(2) -0.17194(14) 0.0639(6) Uani 1 1 d . . .
F6 F 0.06552(18) 0.62059(18) -0.04888(15) 0.0520(5) Uani 1 1 d . . .
O1 O 0.2238(2) 1.0790(2) 0.58630(14) 0.0379(4) Uani 1 1 d . . .
O2 O 0.0863(2) 1.1510(2) 0.65185(15) 0.0413(5) Uani 1 1 d . . .
O3 O 0.29012(19) 0.8468(2) 0.02788(15) 0.0414(5) Uani 1 1 d . . .
O4 O 0.29459(19) 0.8850(2) -0.11469(15) 0.0381(5) Uani 1 1 d . . .
N1 N 0.2376(2) 1.0554(2) 0.32910(15) 0.0263(4) Uani 1 1 d . . .
N2 N 0.3938(2) 1.0795(2) 0.22421(15) 0.0256(4) Uani 1 1 d . . .
N3 N 0.3089(2) 1.2317(2) 0.25722(16) 0.0299(5) Uani 1 1 d . . .
C1 C 0.3160(2) 1.0153(2) 0.28155(17) 0.0249(5) Uani 1 1 d . . .
C2 C 0.3875(2) 1.1874(2) 0.21490(17) 0.0261(5) Uani 1 1 d . . .
C3 C 0.2366(2) 1.1633(2) 0.31364(18) 0.0254(5) Uani 1 1 d . . .
C4 C 0.3153(3) 0.8919(2) 0.29185(18) 0.0270(5) Uani 1 1 d . . .
C5 C 0.2043(3) 0.7672(3) 0.2511(2) 0.0313(6) Uani 1 1 d . . .
C6 C 0.2053(3) 0.6536(3) 0.2631(2) 0.0393(7) Uani 1 1 d . . .
H6 H 0.1316 0.5682 0.2355 0.047 Uiso 1 1 calc R . .
C7 C 0.3102(3) 0.6611(3) 0.3138(2) 0.0420(7) Uani 1 1 d . . .
C8 C 0.4180(3) 0.7855(3) 0.3527(2) 0.0394(7) Uani 1 1 d . . .
H8 H 0.4902 0.7915 0.3877 0.047 Uiso 1 1 calc R . .
C9 C 0.4236(3) 0.9028(3) 0.3419(2) 0.0331(6) Uani 1 1 d . . .
C10 C 0.0883(3) 0.7537(3) 0.1945(2) 0.0393(7) Uani 1 1 d . . .
H10A H 0.0294 0.7685 0.2371 0.059 Uiso 1 1 calc R . .
H10B H 0.0415 0.6635 0.1503 0.059 Uiso 1 1 calc R . .
H10C H 0.1186 0.8203 0.1593 0.059 Uiso 1 1 calc R . .
C11 C 0.3058(4) 0.5349(4) 0.3258(3) 0.0646(11) Uani 1 1 d . . .
H11A H 0.2217 0.4804 0.3446 0.097 Uiso 1 1 calc R . .
H11B H 0.3771 0.5592 0.3745 0.097 Uiso 1 1 calc R . .
H11C H 0.3158 0.4836 0.2660 0.097 Uiso 1 1 calc R . .
C12 C 0.5447(3) 1.0360(3) 0.3843(2) 0.0440(7) Uani 1 1 d . . .
H12A H 0.6027 1.0243 0.4249 0.066 Uiso 1 1 calc R . .
H12B H 0.5195 1.1002 0.4217 0.066 Uiso 1 1 calc R . .
H12C H 0.5903 1.0699 0.3338 0.066 Uiso 1 1 calc R . .
C13 C 0.4714(3) 1.2613(2) 0.15128(18) 0.0277(5) Uani 1 1 d . . .
C14 C 0.4122(3) 1.2486(3) 0.0640(2) 0.0350(6) Uani 1 1 d . . .
C15 C 0.4928(3) 1.3201(3) 0.0063(2) 0.0421(7) Uani 1 1 d . . .
H15 H 0.4550 1.3111 -0.0538 0.051 Uiso 1 1 calc R . .
C16 C 0.6257(3) 1.4034(3) 0.0341(2) 0.0419(7) Uani 1 1 d . . .
C17 C 0.6800(3) 1.4154(3) 0.1212(2) 0.0383(7) Uani 1 1 d . . .
H17 H 0.7709 1.4744 0.1412 0.046 Uiso 1 1 calc R . .
C18 C 0.6060(3) 1.3441(3) 0.18103(19) 0.0318(6) Uani 1 1 d . . .
C19 C 0.2671(3) 1.1640(3) 0.0330(2) 0.0443(7) Uani 1 1 d . . .
H19A H 0.2223 1.2117 0.0658 0.066 Uiso 1 1 calc R . .
H19B H 0.2364 1.0789 0.0482 0.066 Uiso 1 1 calc R . .
H19C H 0.2481 1.1463 -0.0351 0.066 Uiso 1 1 calc R . .
C20 C 0.7100(4) 1.4794(4) -0.0304(3) 0.0609(10) Uani 1 1 d . . .
H20A H 0.7570 1.4333 -0.0616 0.091 Uiso 1 1 calc R . .
H20B H 0.7732 1.5706 0.0069 0.091 Uiso 1 1 calc R . .
H20C H 0.6544 1.4836 -0.0780 0.091 Uiso 1 1 calc R . .
C21 C 0.6697(3) 1.3569(3) 0.2750(2) 0.0456(8) Uani 1 1 d . . .
H21A H 0.6634 1.2707 0.2747 0.068 Uiso 1 1 calc R . .
H21B H 0.6249 1.3830 0.3253 0.068 Uiso 1 1 calc R . .
H21C H 0.7619 1.4254 0.2859 0.068 Uiso 1 1 calc R . .
C22 C 0.1455(3) 1.2061(2) 0.36207(18) 0.0272(5) Uani 1 1 d . . .
C23 C 0.0234(3) 1.1634(3) 0.31276(19) 0.0302(5) Uani 1 1 d . . .
C24 C -0.0611(3) 1.2032(3) 0.3580(2) 0.0356(6) Uani 1 1 d . . .
H24 H -0.1441 1.1754 0.3248 0.043 Uiso 1 1 calc R . .
C25 C -0.0273(3) 1.2830(3) 0.4511(2) 0.0360(6) Uani 1 1 d . . .
C26 C 0.0952(3) 1.3256(3) 0.4982(2) 0.0347(6) Uani 1 1 d . . .
H26 H 0.1189 1.3807 0.5615 0.042 Uiso 1 1 calc R . .
C27 C 0.1846(3) 1.2899(3) 0.45507(19) 0.0295(5) Uani 1 1 d . . .
C28 C -0.0153(3) 1.0755(3) 0.2120(2) 0.0410(7) Uani 1 1 d . . .
H28A H -0.1039 1.0544 0.1888 0.061 Uiso 1 1 calc R . .
H28B H -0.0132 0.9922 0.2092 0.061 Uiso 1 1 calc R . .
H28C H 0.0462 1.1228 0.1727 0.061 Uiso 1 1 calc R . .
C29 C -0.1222(3) 1.3222(4) 0.5002(3) 0.0517(8) Uani 1 1 d . . .
H29A H -0.1845 1.2488 0.5234 0.078 Uiso 1 1 calc R . .
H29B H -0.1697 1.3404 0.4557 0.078 Uiso 1 1 calc R . .
H29C H -0.0740 1.4029 0.5533 0.078 Uiso 1 1 calc R . .
C30 C 0.3211(3) 1.3452(3) 0.5043(2) 0.0392(7) Uani 1 1 d . . .
H30A H 0.3839 1.4103 0.4750 0.059 Uiso 1 1 calc R . .
H30B H 0.3414 1.2719 0.4989 0.059 Uiso 1 1 calc R . .
H30C H 0.3268 1.3895 0.5710 0.059 Uiso 1 1 calc R . .
C31 C 0.1876(3) 1.1405(3) 0.6507(2) 0.0340(6) Uani 1 1 d . . .
C32 C 0.2860(3) 1.2197(3) 0.7424(2) 0.0438(7) Uani 1 1 d . . .
C33 C 0.2437(3) 0.8304(3) -0.0530(2) 0.0340(6) Uani 1 1 d . . .
C34 C 0.0963(3) 0.7276(3) -0.0793(2) 0.0435(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 O2 155.92(8) . 2_576 ?
O1 Ag1 N1 107.60(8) . . ?
O2 Ag1 N1 96.37(8) 2_576 . ?
O1 Ag1 Ag1 83.89(5) . 2_576 ?
O2 Ag1 Ag1 75.97(6) 2_576 2_576 ?
N1 Ag1 Ag1 140.30(5) . 2_576 ?
O4 Ag2 O3 159.03(8) 2_675 . ?
O4 Ag2 N2 113.15(7) 2_675 . ?
O3 Ag2 N2 87.13(7) . . ?
O4 Ag2 Ag2 83.46(5) 2_675 2_675 ?
O3 Ag2 Ag2 78.32(5) . 2_675 ?
N2 Ag2 Ag2 133.40(5) . 2_675 ?
C31 O1 Ag1 118.06(19) . . ?
C31 O2 Ag1 127.45(19) . 2_576 ?
C33 O3 Ag2 125.63(18) . . ?
C33 O4 Ag2 118.93(19) . 2_675 ?
C1 N1 C3 115.9(2) . . ?
C1 N1 Ag1 132.61(16) . . ?
C3 N1 Ag1 111.44(16) . . ?
C2 N2 C1 116.1(2) . . ?
C2 N2 Ag2 112.04(16) . . ?
C1 N2 Ag2 128.74(16) . . ?
C3 N3 C2 115.5(2) . . ?
N1 C1 N2 123.4(2) . . ?
N1 C1 C4 118.1(2) . . ?
N2 C1 C4 118.5(2) . . ?
N3 C2 N2 124.4(2) . . ?
N3 C2 C13 117.6(2) . . ?
N2 C2 C13 118.0(2) . . ?
N3 C3 N1 124.7(2) . . ?
N3 C3 C22 118.4(2) . . ?
N1 C3 C22 117.0(2) . . ?
C9 C4 C5 121.7(2) . . ?
C9 C4 C1 119.6(2) . . ?
C5 C4 C1 118.7(2) . . ?
C6 C5 C4 117.5(3) . . ?
C6 C5 C10 120.2(3) . . ?
C4 C5 C10 122.2(2) . . ?
C7 C6 C5 122.2(3) . . ?
C8 C7 C6 118.6(3) . . ?
C8 C7 C11 121.2(3) . . ?
C6 C7 C11 120.2(3) . . ?
C7 C8 C9 121.8(3) . . ?
C4 C9 C8 118.1(3) . . ?
C4 C9 C12 122.3(2) . . ?
C8 C9 C12 119.7(3) . . ?
C18 C13 C14 121.6(2) . . ?
C18 C13 C2 119.5(2) . . ?
C14 C13 C2 118.8(2) . . ?
C15 C14 C13 117.6(3) . . ?
C15 C14 C19 120.4(3) . . ?
C13 C14 C19 121.9(2) . . ?
C16 C15 C14 122.1(3) . . ?
C17 C16 C15 118.6(3) . . ?
C17 C16 C20 120.8(3) . . ?
C15 C16 C20 120.6(3) . . ?
C16 C17 C18 122.2(3) . . ?
C17 C18 C13 117.8(3) . . ?
C17 C18 C21 120.8(3) . . ?
C13 C18 C21 121.5(2) . . ?
C23 C22 C27 121.4(2) . . ?
C23 C22 C3 118.9(2) . . ?
C27 C22 C3 119.7(2) . . ?
C24 C23 C22 118.7(3) . . ?
C24 C23 C28 120.9(3) . . ?
C22 C23 C28 120.4(2) . . ?
C23 C24 C25 121.5(3) . . ?
C26 C25 C24 118.8(3) . . ?
C26 C25 C29 120.5(3) . . ?
C24 C25 C29 120.7(3) . . ?
C25 C26 C27 121.9(3) . . ?
C26 C27 C22 117.7(3) . . ?
C26 C27 C30 121.4(3) . . ?
C22 C27 C30 120.8(2) . . ?
O2 C31 O1 130.2(3) . . ?
O2 C31 C32 114.9(3) . . ?
O1 C31 C32 114.9(3) . . ?
F3 C32 F1 107.4(3) . . ?
F3 C32 F2 106.9(3) . . ?
F1 C32 F2 107.5(3) . . ?
F3 C32 C31 113.0(3) . . ?
F1 C32 C31 110.8(3) . . ?
F2 C32 C31 111.2(3) . . ?
O3 C33 O4 131.0(3) . . ?
O3 C33 C34 113.8(2) . . ?
O4 C33 C34 115.2(3) . . ?
F5 C34 F6 106.8(3) . . ?
F5 C34 F4 107.2(3) . . ?
F6 C34 F4 106.9(3) . . ?
F5 C34 C33 113.1(3) . . ?
F6 C34 C33 112.1(3) . . ?
F4 C34 C33 110.4(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.214(2) . ?
Ag1 O2 2.218(2) 2_576 ?
Ag1 N1 2.442(2) . ?
Ag1 Ag1 2.9731(4) 2_576 ?
Ag2 O4 2.1977(19) 2_675 ?
Ag2 O3 2.207(2) . ?
Ag2 N2 2.442(2) . ?
Ag2 Ag2 2.9246(5) 2_675 ?
F1 C32 1.333(4) . ?
F2 C32 1.343(4) . ?
F3 C32 1.332(4) . ?
F4 C34 1.337(4) . ?
F5 C34 1.333(4) . ?
F6 C34 1.334(4) . ?
O1 C31 1.246(3) . ?
O2 C31 1.242(4) . ?
O2 Ag1 2.218(2) 2_576 ?
O3 C33 1.243(4) . ?
O4 C33 1.243(3) . ?
O4 Ag2 2.1977(19) 2_675 ?
N1 C1 1.340(3) . ?
N1 C3 1.348(3) . ?
N2 C2 1.344(3) . ?
N2 C1 1.346(3) . ?
N3 C3 1.332(3) . ?
N3 C2 1.338(3) . ?
C1 C4 1.491(3) . ?
C2 C13 1.494(3) . ?
C3 C22 1.490(3) . ?
C4 C9 1.395(4) . ?
C4 C5 1.405(4) . ?
C5 C6 1.394(4) . ?
C5 C10 1.508(4) . ?
C6 C7 1.386(5) . ?
C7 C8 1.383(5) . ?
C7 C11 1.514(4) . ?
C8 C9 1.398(4) . ?
C9 C12 1.511(4) . ?
C13 C18 1.401(4) . ?
C13 C14 1.402(4) . ?
C14 C15 1.399(4) . ?
C14 C19 1.503(4) . ?
C15 C16 1.382(5) . ?
C16 C17 1.378(5) . ?
C16 C20 1.517(4) . ?
C17 C18 1.395(4) . ?
C18 C21 1.512(4) . ?
C22 C23 1.397(4) . ?
C22 C27 1.404(4) . ?
C23 C24 1.384(4) . ?
C23 C28 1.511(4) . ?
C24 C25 1.391(4) . ?
C25 C26 1.387(4) . ?
C25 C29 1.510(4) . ?
C26 C27 1.397(4) . ?
C27 C30 1.507(4) . ?
C31 C32 1.544(4) . ?
C33 C34 1.547(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 Ag1 O1 C31 -47.4(3) 2_576 . . . ?
N1 Ag1 O1 C31 126.9(2) . . . . ?
Ag1 Ag1 O1 C31 -14.19(19) 2_576 . . . ?
O4 Ag2 O3 C33 -41.6(4) 2_675 . . . ?
N2 Ag2 O3 C33 124.1(2) . . . . ?
Ag2 Ag2 O3 C33 -11.4(2) 2_675 . . . ?
O1 Ag1 N1 C1 85.0(2) . . . . ?
O2 Ag1 N1 C1 -97.4(2) 2_576 . . . ?
Ag1 Ag1 N1 C1 -173.06(18) 2_576 . . . ?
O1 Ag1 N1 C3 -91.79(17) . . . . ?
O2 Ag1 N1 C3 85.84(18) 2_576 . . . ?
Ag1 Ag1 N1 C3 10.2(2) 2_576 . . . ?
O4 Ag2 N2 C2 76.99(18) 2_675 . . . ?
O3 Ag2 N2 C2 -97.47(18) . . . . ?
Ag2 Ag2 N2 C2 -26.5(2) 2_675 . . . ?
O4 Ag2 N2 C1 -124.0(2) 2_675 . . . ?
O3 Ag2 N2 C1 61.6(2) . . . . ?
Ag2 Ag2 N2 C1 132.51(19) 2_675 . . . ?
C3 N1 C1 N2 2.5(4) . . . . ?
Ag1 N1 C1 N2 -174.18(17) . . . . ?
C3 N1 C1 C4 -176.6(2) . . . . ?
Ag1 N1 C1 C4 6.7(3) . . . . ?
C2 N2 C1 N1 -1.3(4) . . . . ?
Ag2 N2 C1 N1 -159.62(18) . . . . ?
C2 N2 C1 C4 177.8(2) . . . . ?
Ag2 N2 C1 C4 19.5(3) . . . . ?
C3 N3 C2 N2 1.9(4) . . . . ?
C3 N3 C2 C13 -179.6(2) . . . . ?
C1 N2 C2 N3 -1.0(4) . . . . ?
Ag2 N2 C2 N3 160.9(2) . . . . ?
C1 N2 C2 C13 -179.5(2) . . . . ?
Ag2 N2 C2 C13 -17.6(3) . . . . ?
C2 N3 C3 N1 -0.6(4) . . . . ?
C2 N3 C3 C22 -179.2(2) . . . . ?
C1 N1 C3 N3 -1.5(4) . . . . ?
Ag1 N1 C3 N3 175.9(2) . . . . ?
C1 N1 C3 C22 177.2(2) . . . . ?
Ag1 N1 C3 C22 -5.5(3) . . . . ?
N1 C1 C4 C9 -109.1(3) . . . . ?
N2 C1 C4 C9 71.8(3) . . . . ?
N1 C1 C4 C5 70.4(3) . . . . ?
N2 C1 C4 C5 -108.7(3) . . . . ?
C9 C4 C5 C6 0.5(4) . . . . ?
C1 C4 C5 C6 -179.0(2) . . . . ?
C9 C4 C5 C10 -178.2(3) . . . . ?
C1 C4 C5 C10 2.3(4) . . . . ?
C4 C5 C6 C7 0.7(4) . . . . ?
C10 C5 C6 C7 179.4(3) . . . . ?
C5 C6 C7 C8 -0.9(4) . . . . ?
C5 C6 C7 C11 179.2(3) . . . . ?
C6 C7 C8 C9 -0.1(5) . . . . ?
C11 C7 C8 C9 179.7(3) . . . . ?
C5 C4 C9 C8 -1.5(4) . . . . ?
C1 C4 C9 C8 178.0(2) . . . . ?
C5 C4 C9 C12 178.7(3) . . . . ?
C1 C4 C9 C12 -1.8(4) . . . . ?
C7 C8 C9 C4 1.3(4) . . . . ?
C7 C8 C9 C12 -178.9(3) . . . . ?
N3 C2 C13 C18 106.4(3) . . . . ?
N2 C2 C13 C18 -75.1(3) . . . . ?
N3 C2 C13 C14 -71.9(3) . . . . ?
N2 C2 C13 C14 106.7(3) . . . . ?
C18 C13 C14 C15 1.1(4) . . . . ?
C2 C13 C14 C15 179.3(2) . . . . ?
C18 C13 C14 C19 -177.7(3) . . . . ?
C2 C13 C14 C19 0.5(4) . . . . ?
C13 C14 C15 C16 -1.6(4) . . . . ?
C19 C14 C15 C16 177.2(3) . . . . ?
C14 C15 C16 C17 0.3(5) . . . . ?
C14 C15 C16 C20 -179.9(3) . . . . ?
C15 C16 C17 C18 1.6(5) . . . . ?
C20 C16 C17 C18 -178.2(3) . . . . ?
C16 C17 C18 C13 -2.1(4) . . . . ?
C16 C17 C18 C21 178.2(3) . . . . ?
C14 C13 C18 C17 0.7(4) . . . . ?
C2 C13 C18 C17 -177.5(2) . . . . ?
C14 C13 C18 C21 -179.6(3) . . . . ?
C2 C13 C18 C21 2.1(4) . . . . ?
N3 C3 C22 C23 82.1(3) . . . . ?
N1 C3 C22 C23 -96.7(3) . . . . ?
N3 C3 C22 C27 -96.7(3) . . . . ?
N1 C3 C22 C27 84.5(3) . . . . ?
C27 C22 C23 C24 -1.3(4) . . . . ?
C3 C22 C23 C24 179.9(2) . . . . ?
C27 C22 C23 C28 178.7(2) . . . . ?
C3 C22 C23 C28 0.0(4) . . . . ?
C22 C23 C24 C25 -0.6(4) . . . . ?
C28 C23 C24 C25 179.3(3) . . . . ?
C23 C24 C25 C26 1.5(4) . . . . ?
C23 C24 C25 C29 -178.3(3) . . . . ?
C24 C25 C26 C27 -0.5(4) . . . . ?
C29 C25 C26 C27 179.3(3) . . . . ?
C25 C26 C27 C22 -1.4(4) . . . . ?
C25 C26 C27 C30 175.3(3) . . . . ?
C23 C22 C27 C26 2.3(4) . . . . ?
C3 C22 C27 C26 -179.0(2) . . . . ?
C23 C22 C27 C30 -174.4(2) . . . . ?
C3 C22 C27 C30 4.3(4) . . . . ?
Ag1 O2 C31 O1 17.7(4) 2_576 . . . ?
Ag1 O2 C31 C32 -164.48(19) 2_576 . . . ?
Ag1 O1 C31 O2 3.6(4) . . . . ?
Ag1 O1 C31 C32 -174.26(19) . . . . ?
O2 C31 C32 F3 17.9(4) . . . . ?
O1 C31 C32 F3 -163.9(3) . . . . ?
O2 C31 C32 F1 -102.6(3) . . . . ?
O1 C31 C32 F1 75.6(3) . . . . ?
O2 C31 C32 F2 138.0(3) . . . . ?
O1 C31 C32 F2 -43.8(4) . . . . ?
Ag2 O3 C33 O4 2.6(5) . . . . ?
Ag2 O3 C33 C34 -175.11(19) . . . . ?
Ag2 O4 C33 O3 12.9(4) 2_675 . . . ?
Ag2 O4 C33 C34 -169.40(19) 2_675 . . . ?
O3 C33 C34 F5 -161.9(3) . . . . ?
O4 C33 C34 F5 19.9(4) . . . . ?
O3 C33 C34 F6 -41.1(4) . . . . ?
O4 C33 C34 F6 140.8(3) . . . . ?
O3 C33 C34 F4 78.0(3) . . . . ?
O4 C33 C34 F4 -100.2(3) . . . . ?
