#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:49:35 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179349 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/46/4324615.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4324615
loop_
_publ_author_name
'Jessica M. Morrison'
'Laura J. Moore-Shay'
'Peter C. Burns'
_publ_section_title
;
 U(VI) Uranyl Cation-Cation Interactions in Framework Germanates
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2272
_journal_page_last               2277
_journal_paper_doi               10.1021/ic1019444
_journal_volume                  50
_journal_year                    2011
_chemical_formula_moiety         'Li+, (UO2)2+, (UO6)6-, (GeO4)4-, (OH)-'
_chemical_formula_sum            'Ge2 Li3 O39 U11'
_chemical_formula_weight         3408.33
_chemical_name_systematic        'Lithium uranyl germanate hydroxide'
_space_group_IT_number           163
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-P 3 2c'
_symmetry_space_group_name_H-M   'P -3 1 c'
_atom_sites_solution_hydrogens   notdet
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   10.2668(5)
_cell_length_b                   10.2668(5)
_cell_length_c                   17.0558(11)
_cell_measurement_reflns_used    3634
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      2.29
_cell_volume                     1556.94(15)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'CrystalMaker v.8.2.3'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0606
_diffrn_reflns_av_sigmaI/netI    0.0240
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            16252
_diffrn_reflns_theta_full        27.57
_diffrn_reflns_theta_max         27.57
_diffrn_reflns_theta_min         2.29
_exptl_absorpt_coefficient_mu    59.005
_exptl_absorpt_correction_T_max  0.6828
_exptl_absorpt_correction_T_min  0.1765
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red-orange
_exptl_crystal_density_diffrn    7.270
_exptl_crystal_description       platy
_exptl_crystal_F_000             2794
_exptl_crystal_size_max          0.045
_exptl_crystal_size_mid          0.034
_exptl_crystal_size_min          0.007
_refine_diff_density_max         1.133
_refine_diff_density_min         -4.073
_refine_diff_density_rms         0.447
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.201
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     86
_refine_ls_number_reflns         1211
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.200
_refine_ls_R_factor_all          0.0287
_refine_ls_R_factor_gt           0.0236
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0243P)²+5.3953P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0521
_refine_ls_wR_factor_ref         0.0536
_reflns_number_gt                1083
_reflns_number_total             1211
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic1019444_si_002_4.cif
_cod_data_source_block           final_li
_cod_database_code               4324615
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-y, -x, -z+1/2'
'-x+y, y, -z+1/2'
'x, x-y, -z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'y, x, z-1/2'
'x-y, -y, z-1/2'
'-x, -x+y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
U1 U 0.6667 0.3333 0.60270(3) 0.00398(12) Uani 1 3 d S
U2 U 0.01782(3) 0.35693(3) 0.558966(19) 0.00598(10) Uani 1 1 d .
U3 U 0.86201(2) 0.13799(2) 0.7500 0.00638(12) Uani 1 2 d S
Ge1 Ge 0.0000 0.0000 0.10241(15) 0.0197(7) Uani 0.994(7) 3 d SPD
Ge2 Ge 0.0000 0.0000 0.1464(6) 0.0197(7) Uani 0.006(7) 3 d SPD
Li1 Li 0.235(3) 0.469(5) 0.7500 0.080(13) Uiso 1 2 d S
O1 O 0.8469(6) 0.8262(7) 0.6278(4) 0.0103(12) Uani 1 1 d .
O2 O 0.1366(7) 0.4858(7) 0.6312(4) 0.0140(14) Uani 1 1 d .
O3 O 0.8164(7) 0.2860(7) 0.6573(3) 0.0107(13) Uani 1 1 d .
O4 O 0.5944(7) 0.1373(7) 0.5339(4) 0.0108(13) Uani 1 1 d .
O5 O 0.9012(6) 0.2242(7) 0.4825(4) 0.0103(13) Uani 1 1 d .
O6 O 0.0000 0.0000 0.0000 0.023(4) Uani 1 6 d S
O7 O 0.6958(7) -0.0241(7) 0.7178(4) 0.0140(14) Uani 1 1 d .
O8 O 0.0000 0.0000 0.7500 0.027(5) Uani 1 6 d S
O9 O 0.3333 0.6667 0.7500 0.026(4) Uani 1 6 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 U1 O3 101.0(2) 3_665 2_655
O3 U1 O3 101.0(2) 3_665 .
O3 U1 O3 101.0(2) 2_655 .
O3 U1 O4 170.3(2) 3_665 2_655
O3 U1 O4 88.5(2) 2_655 2_655
O3 U1 O4 78.1(2) . 2_655
O3 U1 O4 78.1(2) 3_665 .
O3 U1 O4 170.3(2) 2_655 .
O3 U1 O4 88.5(2) . .
O4 U1 O4 92.2(2) 2_655 .
O3 U1 O4 88.5(2) 3_665 3_665
O3 U1 O4 78.1(2) 2_655 3_665
O3 U1 O4 170.3(2) . 3_665
O4 U1 O4 92.3(2) 2_655 3_665
O4 U1 O4 92.3(2) . 3_665
O3 U1 U2 136.85(17) 3_665 1_655
O3 U1 U2 107.14(17) 2_655 1_655
O3 U1 U2 42.29(17) . 1_655
O4 U1 U2 38.63(16) 2_655 1_655
O4 U1 U2 79.09(16) . 1_655
O4 U1 U2 128.53(17) 3_665 1_655
O3 U1 U2 42.29(17) 3_665 3
O3 U1 U2 136.85(17) 2_655 3
O3 U1 U2 107.14(17) . 3
O4 U1 U2 128.53(17) 2_655 3
O4 U1 U2 38.63(16) . 3
O4 U1 U2 79.09(16) 3_665 3
U2 U1 U2 115.753(7) 1_655 3
O3 U1 U2 107.14(17) 3_665 2_665
O3 U1 U2 42.29(17) 2_655 2_665
O3 U1 U2 136.84(17) . 2_665
O4 U1 U2 79.09(16) 2_655 2_665
O4 U1 U2 128.53(17) . 2_665
O4 U1 U2 38.63(16) 3_665 2_665
U2 U1 U2 115.753(7) 1_655 2_665
U2 U1 U2 115.753(7) 3 2_665
O2 U2 O5 177.9(3) . 1_455
O2 U2 O1 93.8(3) . 3_565
O5 U2 O1 86.3(2) 1_455 3_565
O2 U2 O4 88.7(3) . 8_566
O5 U2 O4 90.3(2) 1_455 8_566
O1 U2 O4 154.1(2) 3_565 8_566
O2 U2 O4 99.5(2) . 2
O5 U2 O4 82.0(2) 1_455 2
O1 U2 O4 131.7(2) 3_565 2
O4 U2 O4 72.9(2) 8_566 2
O2 U2 O5 89.2(2) . 8_566
O5 U2 O5 88.8(2) 1_455 8_566
O1 U2 O5 77.2(2) 3_565 8_566
O4 U2 O5 77.1(2) 8_566 8_566
O4 U2 O5 148.5(2) 2 8_566
O2 U2 O3 84.8(3) . 1_455
O5 U2 O3 97.2(2) 1_455 1_455
O1 U2 O3 68.9(2) 3_565 1_455
O4 U2 O3 136.9(2) 8_566 1_455
O4 U2 O3 66.3(2) 2 1_455
O5 U2 O3 145.06(19) 8_566 1_455
O2 U2 U1 101.5(2) . 1_455
O5 U2 U1 80.57(18) 1_455 1_455
O1 U2 U1 97.22(15) 3_565 1_455
O4 U2 U1 107.50(15) 8_566 1_455
O4 U2 U1 34.64(14) 2 1_455
O5 U2 U1 168.32(14) 8_566 1_455
O3 U2 U1 33.97(13) 1_455 1_455
O2 U2 U2 95.1(2) . 7_566
O5 U2 U2 85.22(19) 1_455 7_566
O1 U2 U2 166.36(15) 3_565 7_566
O4 U2 U2 36.64(15) 8_566 7_566
O4 U2 U2 36.25(14) 2 7_566
O5 U2 U2 113.22(14) 8_566 7_566
O3 U2 U2 101.60(13) 1_455 7_566
U1 U2 U2 70.870(10) 1_455 7_566
O2 U2 Li1 25.1(7) . .
O5 U2 Li1 154.8(7) 1_455 .
O1 U2 Li1 68.8(7) 3_565 .
O4 U2 Li1 110.5(7) 8_566 .
O4 U2 Li1 116.8(4) 2 .
O5 U2 Li1 82.61(19) 8_566 .
O3 U2 Li1 77.5(3) 1_455 .
U1 U2 Li1 105.123(15) 1_455 .
U2 U2 Li1 119.9(7) 7_566 .
O2 U2 U3 77.1(2) . 1_455
O5 U2 U3 104.10(19) 1_455 1_455
O1 U2 U3 35.26(15) 3_565 1_455
O4 U2 U3 164.73(15) 8_566 1_455
O4 U2 U3 103.82(14) 2 1_455
O5 U2 U3 107.66(15) 8_566 1_455
O3 U2 U3 37.50(13) 1_455 1_455
U1 U2 U3 70.771(11) 1_455 1_455
U2 U2 U3 138.246(15) 7_566 1_455
Li1 U2 U3 57.0(6) . 1_455
O7 U3 O7 177.6(4) . 4_666
O7 U3 O1 90.4(3) . 6_556
O7 U3 O1 90.5(3) 4_666 6_556
O7 U3 O1 90.5(3) . 3_665
O7 U3 O1 90.4(3) 4_666 3_665
O1 U3 O1 135.0(3) 6_556 3_665
O7 U3 O3 89.4(3) . .
O7 U3 O3 88.9(3) 4_666 .
O1 U3 O3 156.6(2) 6_556 .
O1 U3 O3 68.4(2) 3_665 .
O7 U3 O3 88.9(3) . 4_666
O7 U3 O3 89.4(3) 4_666 4_666
O1 U3 O3 68.4(2) 6_556 4_666
O1 U3 O3 156.6(2) 3_665 4_666
O3 U3 O3 88.1(3) . 4_666
O7 U3 O8 91.2(2) . 1_655
O7 U3 O8 91.2(2) 4_666 1_655
O1 U3 O8 67.49(14) 6_556 1_655
O1 U3 O8 67.48(14) 3_665 1_655
O3 U3 O8 135.93(15) . 1_655
O3 U3 O8 135.93(15) 4_666 1_655
O7 U3 Ge2 101.4(2) . 7_656
O7 U3 Ge2 80.6(2) 4_666 7_656
O1 U3 Ge2 34.5(2) 6_556 7_656
O1 U3 Ge2 101.7(2) 3_665 7_656
O3 U3 Ge2 165.63(17) . 7_656
O3 U3 Ge2 101.4(2) 4_666 7_656
O8 U3 Ge2 35.76(17) 1_655 7_656
O7 U3 Ge2 80.6(2) . 10_656
O7 U3 Ge2 101.4(2) 4_666 10_656
O1 U3 Ge2 101.7(2) 6_556 10_656
O1 U3 Ge2 34.5(2) 3_665 10_656
O3 U3 Ge2 101.4(2) . 10_656
O3 U3 Ge2 165.64(17) 4_666 10_656
O8 U3 Ge2 35.76(17) 1_655 10_656
Ge2 U3 Ge2 71.5(3) 7_656 10_656
O7 U3 Ge1 103.7(2) . 7_656
O7 U3 Ge1 78.1(2) 4_666 7_656
O1 U3 Ge1 26.35(14) 6_556 7_656
O1 U3 Ge1 111.19(15) 3_665 7_656
O3 U3 Ge1 166.94(15) . 7_656
O3 U3 Ge1 91.66(15) 4_666 7_656
O8 U3 Ge1 45.73(3) 1_655 7_656
Ge2 U3 Ge1 9.97(16) 7_656 7_656
Ge2 U3 Ge1 81.49(18) 10_656 7_656
O7 U3 Ge1 78.1(2) . 10_656
O7 U3 Ge1 103.7(2) 4_666 10_656
O1 U3 Ge1 111.19(15) 6_556 10_656
O1 U3 Ge1 26.35(14) 3_665 10_656
O3 U3 Ge1 91.66(15) . 10_656
O3 U3 Ge1 166.94(15) 4_666 10_656
O8 U3 Ge1 45.73(3) 1_655 10_656
Ge2 U3 Ge1 81.49(18) 7_656 10_656
Ge2 U3 Ge1 9.97(16) 10_656 10_656
Ge1 U3 Ge1 91.46(6) 7_656 10_656
O7 U3 Li1 19.3(3) . 2_655
O7 U3 Li1 161.4(2) 4_666 2_655
O1 U3 Li1 71.1(2) 6_556 2_655
O1 U3 Li1 104.3(2) 3_665 2_655
O3 U3 Li1 106.9(4) . 2_655
O3 U3 Li1 81.6(4) 4_666 2_655
O8 U3 Li1 84.2(4) 1_655 2_655
Ge2 U3 Li1 85.3(4) 7_656 2_655
Ge2 U3 Li1 85.3(4) 10_656 2_655
Ge1 U3 Li1 86.0(3) 7_656 2_655
Ge1 U3 Li1 86.0(3) 10_656 2_655
Ge2 Ge1 O1 75.6(2) . 12_655
Ge2 Ge1 O1 75.6(2) . 10_445
O1 Ge1 O1 114.03(17) 12_655 10_445
Ge2 Ge1 O1 75.6(2) . 11_565
O1 Ge1 O1 114.03(17) 12_655 11_565
O1 Ge1 O1 114.03(17) 10_445 11_565
Ge2 Ge1 O6 180.000(1) . .
O1 Ge1 O6 104.4(2) 12_655 .
O1 Ge1 O6 104.4(2) 10_445 .
O1 Ge1 O6 104.4(2) 11_565 .
O1 Ge1 U3 84.0(2) 12_655 8_566
O1 Ge1 U3 111.5(2) 10_445 8_566
O6 Ge1 U3 135.73(3) . 8_566
O1 Ge1 U3 84.0(2) 10_445 7_656
O1 Ge1 U3 111.5(2) 11_565 7_656
O6 Ge1 U3 135.73(3) . 7_656
U3 Ge1 U3 74.39(5) 8_566 7_656
O1 Ge1 U3 111.5(2) 12_655 9_446
O1 Ge1 U3 84.0(2) 11_565 9_446
O6 Ge1 U3 135.73(3) . 9_446
U3 Ge1 U3 74.39(5) 8_566 9_446
U3 Ge1 U3 74.39(5) 7_656 9_446
Ge1 Ge2 O1 79.4(4) . 12_655
Ge1 Ge2 O1 79.4(4) . 10_445
O1 Ge2 O1 116.7(2) 12_655 10_445
Ge1 Ge2 O1 79.4(4) . 11_565
O1 Ge2 O1 116.7(2) 12_655 11_565
O1 Ge2 O1 116.7(2) 10_445 11_565
Ge1 Ge2 O8 180.0 . 7_556
O1 Ge2 O8 100.6(4) 12_655 7_556
O1 Ge2 O8 100.6(4) 10_445 7_556
O1 Ge2 O8 100.6(4) 11_565 7_556
Ge1 Ge2 U3 125.76(17) . 8_566
O1 Ge2 U3 101.2(3) 12_655 8_566
O1 Ge2 U3 138.7(4) 10_445 8_566
O1 Ge2 U3 51.5(3) 11_565 8_566
O8 Ge2 U3 54.24(17) 7_556 8_566
Ge1 Ge2 U3 125.76(17) . 7_656
O1 Ge2 U3 51.5(3) 12_655 7_656
O1 Ge2 U3 101.2(3) 10_445 7_656
O1 Ge2 U3 138.7(4) 11_565 7_656
O8 Ge2 U3 54.24(17) 7_556 7_656
U3 Ge2 U3 89.3(2) 8_566 7_656
Ge1 Ge2 U3 125.76(16) . 9_446
O1 Ge2 U3 138.7(4) 12_655 9_446
O1 Ge2 U3 51.5(3) 10_445 9_446
O1 Ge2 U3 101.2(3) 11_565 9_446
O8 Ge2 U3 54.24(17) 7_556 9_446
U3 Ge2 U3 89.3(2) 8_566 9_446
U3 Ge2 U3 89.3(2) 7_656 9_446
O9 Li1 O7 135.9(9) . 3_665
O9 Li1 O7 135.9(9) . 4_566
O7 Li1 O7 88.3(19) 3_665 4_566
O9 Li1 O2 86.4(12) . 5_556
O7 Li1 O2 88.7(8) 3_665 5_556
O7 Li1 O2 96.5(9) 4_566 5_556
O9 Li1 O2 86.4(12) . .
O7 Li1 O2 96.5(9) 3_665 .
O7 Li1 O2 88.7(8) 4_566 .
O2 Li1 O2 173(2) 5_556 .
O9 Li1 Li1 30.000(6) . 2_665
O7 Li1 Li1 107.5(9) 3_665 2_665
O7 Li1 Li1 160.5(8) 4_566 2_665
O2 Li1 Li1 73.0(11) 5_556 2_665
O2 Li1 Li1 100.5(11) . 2_665
O9 Li1 Li1 30.0 . 3_565
O7 Li1 Li1 160.5(8) 3_665 3_565
O7 Li1 Li1 107.5(9) 4_566 3_565
O2 Li1 Li1 100.5(11) 5_556 3_565
O2 Li1 Li1 73.0(11) . 3_565
Li1 Li1 Li1 60.0 2_665 3_565
O9 Li1 U3 144.2(4) . 1_455
O7 Li1 U3 78.1(13) 3_665 1_455
O7 Li1 U3 16.7(5) 4_566 1_455
O2 Li1 U3 109.2(12) 5_556 1_455
O2 Li1 U3 77.0(8) . 1_455
Li1 Li1 U3 174.2(4) 2_665 1_455
Li1 Li1 U3 114.2(4) 3_565 1_455
O9 Li1 U3 144.2(4) . 3_665
O7 Li1 U3 16.7(5) 3_665 3_665
O7 Li1 U3 78.1(13) 4_566 3_665
O2 Li1 U3 77.0(8) 5_556 3_665
O2 Li1 U3 109.2(11) . 3_665
Li1 Li1 U3 114.2(4) 2_665 3_665
Li1 Li1 U3 174.2(4) 3_565 3_665
U3 Li1 U3 71.6(9) 1_455 3_665
O9 Li1 U2 105.3(7) . 5_556
O7 Li1 U2 76.2(6) 3_665 5_556
O7 Li1 U2 81.9(7) 4_566 5_556
O2 Li1 U2 19.0(5) 5_556 5_556
O2 Li1 U2 168.2(19) . 5_556
Li1 Li1 U2 90.6(6) 2_665 5_556
Li1 Li1 U2 116.5(6) 3_565 5_556
U3 Li1 U2 92.3(8) 1_455 5_556
U3 Li1 U2 62.0(5) 3_665 5_556
O9 Li1 U2 105.3(7) . .
O7 Li1 U2 81.9(7) 3_665 .
O7 Li1 U2 76.2(6) 4_566 .
O2 Li1 U2 168.2(18) 5_556 .
O2 Li1 U2 19.0(5) . .
Li1 Li1 U2 116.5(6) 2_665 .
Li1 Li1 U2 90.6(6) 3_565 .
U3 Li1 U2 62.0(5) 1_455 .
U3 Li1 U2 92.3(8) 3_665 .
U2 Li1 U2 149.4(14) 5_556 .
Ge2 O1 U2 154.2(4) 10_666 2_665
Ge1 O1 U2 131.6(3) 10_666 2_665
Ge2 O1 U3 94.0(4) 10_666 2_655
Ge1 O1 U3 116.5(3) 10_666 2_655
U2 O1 U3 111.5(2) 2_665 2_655
U2 O2 Li1 135.9(12) . .
U1 O3 U3 148.9(3) . .
U1 O3 U2 103.7(2) . 1_655
U3 O3 U2 103.6(2) . 1_655
U1 O4 U2 146.1(3) . 9_656
U1 O4 U2 106.7(2) . 3
U2 O4 U2 107.1(2) 9_656 3
U2 O5 U2 149.3(3) 1_655 9_656
Ge1 O6 Ge1 180.0 . 7
U3 O7 Li1 144.0(7) . 2_655
Ge2 O8 Ge2 180.000(2) 10_556 7_556
Ge2 O8 U3 90.000(2) 10_556 2_545
Ge2 O8 U3 90.000(2) 7_556 2_545
Ge2 O8 U3 90.000(2) 10_556 3_665
Ge2 O8 U3 90.000(2) 7_556 3_665
U3 O8 U3 120.0 2_545 3_665
Ge2 O8 U3 90.0 10_556 1_455
Ge2 O8 U3 90.0 7_556 1_455
U3 O8 U3 120.0 2_545 1_455
U3 O8 U3 120.0 3_665 1_455
Li1 O9 Li1 120.000(3) . 3_565
Li1 O9 Li1 120.000(5) . 2_665
Li1 O9 Li1 120.000(16) 3_565 2_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
U1 O3 2.053(6) 3_665
U1 O3 2.053(6) 2_655
U1 O3 2.053(6) .
U1 O4 2.118(6) 2_655
U1 O4 2.118(6) .
U1 O4 2.118(6) 3_665
U2 O2 1.772(6) .
U2 O5 1.833(6) 1_455
U2 O1 2.255(6) 3_565
U2 O4 2.305(6) 8_566
U2 O4 2.327(6) 2
U2 O5 2.418(6) 8_566
U2 O3 2.472(6) 1_455
U3 O7 1.773(6) .
U3 O7 1.773(6) 4_666
U3 O1 2.373(6) 6_556
U3 O1 2.373(6) 3_665
U3 O3 2.396(6) .
U3 O3 2.396(6) 4_666
U3 O8 2.4539(4) 1_655
Ge1 Ge2 0.750(10) .
Ge1 O1 1.743(6) 12_655
Ge1 O1 1.743(6) 10_445
Ge1 O1 1.743(6) 11_565
Ge1 O6 1.747(3) .
Ge2 O1 1.718(6) 12_655
Ge2 O1 1.718(6) 10_445
Ge2 O1 1.718(6) 11_565
Ge2 O8 1.767(11) 7_556
Li1 O9 1.75(5) .
Li1 O7 2.05(3) 3_665
Li1 O7 2.05(3) 4_566
Li1 O2 2.306(7) 5_556
Li1 O2 2.306(7) .
Li1 Li1 3.04(8) 2_665
Li1 Li1 3.04(8) 3_565
O1 Ge2 1.718(6) 10_666
O1 Ge1 1.743(6) 10_666
O1 U2 2.255(6) 2_665
O1 U3 2.373(6) 2_655
O3 U2 2.472(6) 1_655
O4 U2 2.305(6) 9_656
O4 U2 2.327(6) 3
O5 U2 1.833(6) 1_655
O5 U2 2.419(6) 9_656
O6 Ge1 1.747(3) 7
O7 Li1 2.05(3) 2_655
O8 Ge2 1.767(11) 10_556
O8 Ge2 1.767(11) 7_556
O8 U3 2.4539(4) 2_545
O8 U3 2.4539(5) 3_665
O8 U3 2.4539(4) 1_455
O9 Li1 1.75(5) 3_565
O9 Li1 1.75(5) 2_665
