#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:10:36 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179365 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/62/4326275.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4326275
loop_
_publ_author_name
'Qiang Gao'
'Xiqu Wang'
'Allan J. Jacobson'
_publ_section_title
;
 Homochiral Frameworks Formed by Reactions of Lanthanide Ions with a
 Chiral Antimony Tartrate Secondary Building Unit
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9073
_journal_page_last               9082
_journal_paper_doi               10.1021/ic201274c
_journal_volume                  50
_journal_year                    2011
_chemical_absolute_configuration rm
_chemical_formula_sum            'C24 H42 Ce2 O51 Sb6'
_chemical_formula_weight         2157.32
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.32
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.475(3)
_cell_length_b                   26.271(8)
_cell_length_c                   12.204(4)
_cell_measurement_reflns_used    9904
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.38
_cell_measurement_theta_min      2.36
_cell_volume                     2548.1(15)
_computing_cell_refinement       Bruker-ApexII
_computing_data_collection       Bruker-ApexII
_computing_data_reduction        Bruker-ApexII
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.912
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0268
_diffrn_reflns_av_sigmaI/netI    0.0311
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15325
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.39
_diffrn_reflns_theta_min         1.78
_exptl_absorpt_coefficient_mu    5.014
_exptl_absorpt_correction_T_max  0.279
_exptl_absorpt_correction_T_min  0.221
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.812
_exptl_crystal_description       plate
_exptl_crystal_F_000             2032
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.055
_refine_diff_density_min         -0.983
_refine_diff_density_rms         0.143
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.003(14)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constrain
_refine_ls_matrix_type           full
_refine_ls_number_parameters     748
_refine_ls_number_reflns         9282
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.0286
_refine_ls_R_factor_gt           0.0269
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0462P)²+4.6537P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0731
_refine_ls_wR_factor_ref         0.0747
_reflns_number_gt                8969
_reflns_number_total             9282
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic201274c_si_004_2.cif
_cod_data_source_block           2DI-Ce
_cod_original_cell_volume        2548.0(13)
_cod_database_code               4326275
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ce1 Ce 1.37081(5) 0.797009(15) 0.81969(3) 0.01732(8) Uani 1 1 d .
Ce2 Ce 0.20180(5) 0.511402(15) 0.49851(3) 0.01758(8) Uani 1 1 d .
Sb1 Sb 0.65862(6) 0.708606(19) 0.46606(4) 0.02044(10) Uani 1 1 d .
Sb2 Sb 0.83805(6) 0.598581(19) 0.83675(4) 0.02104(10) Uani 1 1 d .
Sb3 Sb 0.14484(6) 0.449557(19) 0.97757(4) 0.02149(10) Uani 1 1 d .
Sb4 Sb 0.58024(8) 0.59309(2) 1.07375(5) 0.03508(14) Uani 1 1 d .
Sb5 Sb -0.12016(6) 0.85726(2) 0.33196(4) 0.02167(10) Uani 1 1 d .
Sb6 Sb 0.22730(7) 0.72541(2) 0.22553(5) 0.02776(12) Uani 1 1 d .
O1 O 1.1306(8) 0.7466(2) 0.6957(6) 0.0398(16) Uani 1 1 d .
O2 O 0.8594(7) 0.7525(2) 0.5938(5) 0.0270(12) Uani 1 1 d .
O3 O 0.8292(7) 0.6553(2) 0.5299(5) 0.0239(11) Uani 1 1 d .
O4 O 0.9247(7) 0.5593(2) 0.7113(5) 0.0281(12) Uani 1 1 d .
O5 O 0.9490(7) 0.6540(2) 0.7835(4) 0.0220(11) Uani 1 1 d .
O6 O 1.1156(8) 0.5682(3) 0.6268(6) 0.0354(14) Uani 1 1 d .
O7 O 0.4841(7) 0.6448(2) 0.4177(5) 0.0275(12) Uani 1 1 d .
O8 O 0.3124(7) 0.5984(2) 0.4780(5) 0.0305(12) Uani 1 1 d .
O9 O 0.5697(6) 0.7071(2) 0.5965(4) 0.0226(11) Uani 1 1 d .
O10 O 0.7108(7) 0.6621(2) 0.8839(5) 0.0286(12) Uani 1 1 d .
O11 O 0.4698(8) 0.7053(2) 0.8255(6) 0.0308(13) Uani 1 1 d .
O12 O 0.6234(6) 0.6020(2) 0.7003(4) 0.0231(11) Uani 1 1 d .
O13 O 0.2422(8) 0.4527(2) 1.1694(5) 0.0279(12) Uani 1 1 d .
O14 O 0.2725(8) 0.5046(2) 1.3176(5) 0.0339(14) Uani 1 1 d .
O15 O 0.1240(7) 0.5226(2) 1.0076(4) 0.0241(11) Uani 1 1 d .
O16 O 0.3368(10) 0.6312(3) 1.0031(6) 0.0442(17) Uani 1 1 d .
O17 O 0.0973(9) 0.6429(2) 1.0391(5) 0.0417(16) Uani 1 1 d .
O18 O 0.4578(7) 0.5627(2) 1.1677(5) 0.0313(13) Uani 1 1 d .
O19 O 0.3228(7) 0.4798(2) 0.7089(5) 0.0294(13) Uani 1 1 d .
O20 O 0.1500(7) 0.4716(2) 0.8085(5) 0.0271(12) Uani 1 1 d .
O21 O 0.3909(6) 0.4510(2) 1.0073(4) 0.0221(11) Uani 1 1 d .
O22 O 0.7402(8) 0.5257(3) 1.1313(6) 0.0476(19) Uani 1 1 d .
O23 O 0.7999(8) 0.4518(3) 1.0685(7) 0.0487(18) Uani 1 1 d .
O24 O 0.4981(8) 0.5499(2) 0.9344(5) 0.0315(13) Uani 1 1 d .
O25 O -0.2219(7) 0.8544(2) 0.1394(5) 0.0271(12) Uani 1 1 d .
O26 O -0.3678(8) 0.8039(3) -0.0058(5) 0.0348(14) Uani 1 1 d .
O27 O -0.1711(8) 0.7845(2) 0.3019(5) 0.0275(12) Uani 1 1 d .
O28 O 0.0797(9) 0.6807(2) 0.2970(5) 0.0393(15) Uani 1 1 d .
O29 O -0.1877(10) 0.6653(3) 0.2809(6) 0.0486(18) Uani 1 1 d .
O30 O -0.0006(7) 0.7527(2) 0.1373(5) 0.0260(11) Uani 1 1 d .
O31 O 0.0457(7) 0.8306(2) 0.5016(5) 0.0274(12) Uani 1 1 d .
O32 O 0.3169(7) 0.8210(2) 0.6095(5) 0.0304(13) Uani 1 1 d .
O33 O 0.1051(7) 0.8609(2) 0.3151(4) 0.0235(11) Uani 1 1 d .
O34 O 0.3224(7) 0.8005(3) 0.1860(5) 0.0336(13) Uani 1 1 d .
O35 O 0.4718(9) 0.8671(3) 0.2801(6) 0.0417(16) Uani 1 1 d .
O36 O 0.2839(8) 0.7631(2) 0.3755(5) 0.0295(12) Uani 1 1 d .
O37W O 1.0872(9) 0.8497(3) 0.7344(6) 0.0505(19) Uani 1 1 d .
O38W O 1.2922(9) 0.8469(3) 0.9714(5) 0.0391(15) Uani 1 1 d .
O39W O 1.4494(8) 0.8880(2) 0.8088(5) 0.0320(13) Uani 1 1 d .
O40W O 1.6290(7) 0.7864(2) 0.7557(5) 0.0250(11) Uani 1 1 d .
O41W O 1.2805(8) 0.7409(2) 0.9554(5) 0.0305(13) Uani 1 1 d .
O42W O 0.5237(8) 0.5164(3) 0.5729(5) 0.0364(14) Uani 1 1 d .
O43W O 0.3228(9) 0.4230(2) 0.5130(5) 0.0370(15) Uani 1 1 d .
O44W O -0.0259(9) 0.4593(3) 0.3341(6) 0.0461(17) Uani 1 1 d .
O45W O -0.0389(8) 0.4702(3) 0.5531(6) 0.0418(16) Uani 1 1 d .
O46W O -0.0259(10) 0.5665(3) 0.3657(6) 0.054(2) Uani 1 1 d .
O47W O -0.0613(8) 0.7517(3) -0.1008(5) 0.0346(13) Uani 1 1 d .
O48W O 0.2591(12) 0.3715(3) 0.3153(7) 0.056(2) Uani 1 1 d .
O49W O 0.7535(11) 0.4552(3) 0.7463(7) 0.058(2) Uani 1 1 d .
O50W O 1.3682(13) 0.9563(6) 0.6143(10) 0.114(5) Uani 1 1 d .
O51W O -0.3163(17) 0.5548(5) 0.3954(12) 0.112(4) Uani 1 1 d .
C1 C 0.9968(10) 0.7277(3) 0.6343(7) 0.0250(16) Uani 1 1 d .
C2 C 0.9904(9) 0.6715(3) 0.6024(6) 0.0235(16) Uani 1 1 d .
H2 H 1.0697 0.6654 0.5614 0.028 Uiso 1 1 calc R
C3 C 1.0474(9) 0.6406(3) 0.7154(6) 0.0201(14) Uani 1 1 d .
H3 H 1.1658 0.6482 0.7593 0.024 Uiso 1 1 calc R
C4 C 1.0309(10) 0.5858(3) 0.6824(6) 0.0232(15) Uani 1 1 d .
C5 C 0.4100(9) 0.6353(3) 0.4891(6) 0.0218(15) Uani 1 1 d .
C6 C 0.4454(9) 0.6716(3) 0.5930(6) 0.0202(14) Uani 1 1 d .
H6 H 0.3415 0.6895 0.5875 0.024 Uiso 1 1 calc R
C7 C 0.5013(9) 0.6380(3) 0.7037(6) 0.0185(14) Uani 1 1 d .
H7 H 0.4026 0.6192 0.7060 0.022 Uiso 1 1 calc R
C8 C 0.5622(9) 0.6721(3) 0.8113(7) 0.0225(15) Uani 1 1 d .
C9 C 0.2967(10) 0.4717(3) 0.7996(6) 0.0228(15) Uani 1 1 d .
C10 C 0.4449(9) 0.4590(3) 0.9112(6) 0.0217(15) Uani 1 1 d .
H10 H 0.4980 0.4276 0.8976 0.026 Uiso 1 1 calc R
C11 C 0.5740(10) 0.5018(3) 0.9367(7) 0.0247(16) Uani 1 1 d .
H11 H 0.6235 0.5014 0.8751 0.030 Uiso 1 1 calc R
C12 C 0.7150(11) 0.4904(4) 1.0531(8) 0.035(2) Uani 1 1 d .
C13 C 0.2306(10) 0.4965(3) 1.2121(7) 0.0236(16) Uani 1 1 d .
C14 C 0.1634(10) 0.5395(3) 1.1243(7) 0.0241(15) Uani 1 1 d .
H14 H 0.0608 0.5530 1.1333 0.029 Uiso 1 1 calc R
C15 C 0.2957(11) 0.5814(3) 1.1548(7) 0.0289(17) Uani 1 1 d .
H15 H 0.3003 0.5968 1.2291 0.035 Uiso 1 1 calc R
C16 C 0.2328(13) 0.6219(3) 1.0583(7) 0.0327(19) Uani 1 1 d .
C17 C -0.2842(9) 0.8115(3) 0.0989(6) 0.0256(16) Uani 1 1 d .
C18 C -0.2510(10) 0.7685(3) 0.1860(6) 0.0225(15) Uani 1 1 d .
H18 H -0.3587 0.7527 0.1795 0.027 Uiso 1 1 calc R
C19 C -0.1402(11) 0.7281(3) 0.1539(7) 0.0265(16) Uani 1 1 d .
H19 H -0.2074 0.7112 0.0812 0.032 Uiso 1 1 calc R
C20 C -0.0835(14) 0.6887(3) 0.2522(8) 0.037(2) Uani 1 1 d .
C21 C 0.2033(10) 0.8315(3) 0.5190(6) 0.0240(16) Uani 1 1 d .
C22 C 0.2496(9) 0.8511(3) 0.4159(6) 0.0215(14) Uani 1 1 d .
H22 H 0.3150 0.8825 0.4391 0.026 Uiso 1 1 calc R
C23 C 0.3601(9) 0.8101(3) 0.3870(6) 0.0227(15) Uani 1 1 d .
H23 H 0.4686 0.8086 0.4512 0.027 Uiso 1 1 calc R
C24 C 0.3901(10) 0.8275(3) 0.2776(7) 0.0279(17) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ce Ce -0.2486 2.6331 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Ce1 O26 150.0(2) . 1_756
O1 Ce1 O39W 131.4(2) . .
O26 Ce1 O39W 78.5(2) 1_756 .
O1 Ce1 O32 72.0(2) . 1_655
O26 Ce1 O32 130.1(2) 1_756 1_655
O39W Ce1 O32 70.40(19) . 1_655
O1 Ce1 O41W 73.4(2) . .
O26 Ce1 O41W 82.2(2) 1_756 .
O39W Ce1 O41W 137.79(18) . .
O32 Ce1 O41W 145.3(2) 1_655 .
O1 Ce1 O38W 110.8(2) . .
O26 Ce1 O38W 73.7(2) 1_756 .
O39W Ce1 O38W 71.7(2) . .
O32 Ce1 O38W 127.7(2) 1_655 .
O41W Ce1 O38W 66.9(2) . .
O1 Ce1 O11 72.6(2) . 1_655
O26 Ce1 O11 81.9(2) 1_756 1_655
O39W Ce1 O11 144.73(19) . 1_655
O32 Ce1 O11 101.9(2) 1_655 1_655
O41W Ce1 O11 66.49(18) . 1_655
O38W Ce1 O11 129.5(2) . 1_655
O1 Ce1 O40W 111.3(2) . .
O26 Ce1 O40W 70.77(19) 1_756 .
O39W Ce1 O40W 79.49(19) . .
O32 Ce1 O40W 65.99(18) 1_655 .
O41W Ce1 O40W 128.07(19) . .
O38W Ce1 O40W 137.8(2) . .
O11 Ce1 O40W 66.42(18) 1_655 .
O1 Ce1 O37W 66.2(2) . .
O26 Ce1 O37W 135.5(2) 1_756 .
O39W Ce1 O37W 72.6(2) . .
O32 Ce1 O37W 69.6(2) 1_655 .
O41W Ce1 O37W 97.0(2) . .
O38W Ce1 O37W 65.5(2) . .
O11 Ce1 O37W 138.6(2) 1_655 .
O40W Ce1 O37W 133.3(2) . .
O6 Ce2 O14 145.9(2) 1_455 1_554
O6 Ce2 O46W 74.2(2) 1_455 .
O14 Ce2 O46W 80.6(3) 1_554 .
O6 Ce2 O43W 136.1(2) 1_455 .
O14 Ce2 O43W 77.2(2) 1_554 .
O46W Ce2 O43W 141.4(2) . .
O6 Ce2 O8 73.4(2) 1_455 .
O14 Ce2 O8 76.4(2) 1_554 .
O46W Ce2 O8 68.9(2) . .
O43W Ce2 O8 133.5(2) . .
O6 Ce2 O19 70.1(2) 1_455 .
O14 Ce2 O19 137.2(2) 1_554 .
O46W Ce2 O19 142.1(2) . .
O43W Ce2 O19 67.52(19) . .
O8 Ce2 O19 111.23(19) . .
O6 Ce2 O42W 105.0(2) 1_455 .
O14 Ce2 O42W 76.3(2) 1_554 .
O46W Ce2 O42W 133.3(3) . .
O43W Ce2 O42W 70.5(2) . .
O8 Ce2 O42W 66.5(2) . .
O19 Ce2 O42W 69.71(19) . .
O6 Ce2 O45W 69.8(2) 1_455 .
O14 Ce2 O45W 130.7(2) 1_554 .
O46W Ce2 O45W 84.8(3) . .
O43W Ce2 O45W 86.2(2) . .
O8 Ce2 O45W 139.3(2) . .
O19 Ce2 O45W 71.5(2) . .
O42W Ce2 O45W 140.0(2) . .
O6 Ce2 O44W 120.1(2) 1_455 .
O14 Ce2 O44W 68.0(2) 1_554 .
O46W Ce2 O44W 67.1(2) . .
O43W Ce2 O44W 75.3(2) . .
O8 Ce2 O44W 126.6(2) . .
O19 Ce2 O44W 122.0(2) . .
O42W Ce2 O44W 134.9(2) . .
O45W Ce2 O44W 62.9(2) . .
O3 Sb1 O9 95.7(2) . .
O3 Sb1 O7 84.0(2) . .
O9 Sb1 O7 77.9(2) . .
O3 Sb1 O2 79.1(2) . .
O9 Sb1 O2 81.8(2) . .
O7 Sb1 O2 152.1(2) . .
O5 Sb2 O12 95.3(2) . .
O5 Sb2 O10 81.7(2) . .
O12 Sb2 O10 78.1(2) . .
O5 Sb2 O4 78.5(2) . .
O12 Sb2 O4 82.4(2) . .
O10 Sb2 O4 150.7(2) . .
O15 Sb3 O21 96.0(2) . .
O15 Sb3 O20 87.1(2) . .
O21 Sb3 O20 78.5(2) . .
O15 Sb3 O13 77.9(2) . .
O21 Sb3 O13 79.8(2) . .
O20 Sb3 O13 152.1(2) . .
O24 Sb4 O18 99.9(3) . .
O24 Sb4 O16 85.4(3) . .
O18 Sb4 O16 78.4(2) . .
O24 Sb4 O22 78.7(3) . .
O18 Sb4 O22 83.0(3) . .
O16 Sb4 O22 153.0(3) . .
O27 Sb5 O33 100.6(2) . .
O27 Sb5 O31 83.8(2) . .
O33 Sb5 O31 77.8(2) . .
O27 Sb5 O25 77.8(2) . .
O33 Sb5 O25 85.8(2) . .
O31 Sb5 O25 152.5(2) . .
O36 Sb6 O30 101.4(2) . .
O36 Sb6 O28 83.4(2) . .
O30 Sb6 O28 79.7(2) . .
O36 Sb6 O34 76.7(2) . .
O30 Sb6 O34 85.4(2) . .
O28 Sb6 O34 152.3(2) . .
C1 O1 Ce1 170.5(7) . .
C1 O2 Sb1 112.7(5) . .
C2 O3 Sb1 116.9(5) . .
C4 O4 Sb2 112.2(5) . .
C3 O5 Sb2 117.3(4) . .
C4 O6 Ce2 159.5(6) . 1_655
C5 O7 Sb1 114.7(5) . .
C5 O8 Ce2 161.5(5) . .
C6 O9 Sb1 118.7(4) . .
C8 O10 Sb2 115.5(5) . .
C8 O11 Ce1 153.2(5) . 1_455
C7 O12 Sb2 118.1(4) . .
C13 O13 Sb3 114.4(5) . .
C13 O14 Ce2 150.6(6) . 1_556
C14 O15 Sb3 119.1(4) . .
C16 O16 Sb4 115.2(6) . .
C15 O18 Sb4 118.9(5) . .
C9 O19 Ce2 146.5(5) . .
C9 O20 Sb3 115.0(5) . .
C10 O21 Sb3 118.2(4) . .
C12 O22 Sb4 114.6(6) . .
C11 O24 Sb4 118.5(5) . .
C17 O25 Sb5 113.7(5) . .
C17 O26 Ce1 155.7(5) . 1_354
C18 O27 Sb5 118.5(5) . .
C20 O28 Sb6 115.2(5) . .
C19 O30 Sb6 117.3(5) . .
C21 O31 Sb5 116.4(5) . .
C21 O32 Ce1 141.7(5) . 1_455
C22 O33 Sb5 118.0(4) . .
C24 O34 Sb6 112.7(5) . .
C23 O36 Sb6 119.7(4) . .
O1 C1 O2 123.9(8) . .
O1 C1 C2 119.5(8) . .
O2 C1 C2 116.7(7) . .
O3 C2 C1 113.1(6) . .
O3 C2 C3 109.9(6) . .
C1 C2 C3 108.2(6) . .
O5 C3 C4 112.4(6) . .
O5 C3 C2 109.4(6) . .
C4 C3 C2 107.4(6) . .
O6 C4 O4 123.2(7) . .
O6 C4 C3 119.4(7) . .
O4 C4 C3 117.4(6) . .
O8 C5 O7 123.1(7) . .
O8 C5 C6 120.3(7) . .
O7 C5 C6 116.5(7) . .
O9 C6 C5 111.8(6) . .
O9 C6 C7 110.9(6) . .
C5 C6 C7 106.3(6) . .
O12 C7 C8 112.7(6) . .
O12 C7 C6 111.3(6) . .
C8 C7 C6 109.1(6) . .
O11 C8 O10 124.5(8) . .
O11 C8 C7 120.0(7) . .
O10 C8 C7 115.5(6) . .
O19 C9 O20 124.2(7) . .
O19 C9 C10 119.5(7) . .
O20 C9 C10 116.3(6) . .
O21 C10 C11 110.8(6) . .
O21 C10 C9 111.6(6) . .
C11 C10 C9 109.2(6) . .
O24 C11 C10 111.5(6) . .
O24 C11 C12 113.3(7) . .
C10 C11 C12 108.6(6) . .
O23 C12 O22 123.0(9) . .
O23 C12 C11 122.2(9) . .
O22 C12 C11 114.8(8) . .
O14 C13 O13 123.1(7) . .
O14 C13 C14 120.7(7) . .
O13 C13 C14 116.2(7) . .
O15 C14 C15 111.7(6) . .
O15 C14 C13 112.0(6) . .
C15 C14 C13 107.5(6) . .
O18 C15 C14 112.3(7) . .
O18 C15 C16 113.0(7) . .
C14 C15 C16 106.4(7) . .
O17 C16 O16 125.2(8) . .
O17 C16 C15 120.7(8) . .
O16 C16 C15 114.1(8) . .
O26 C17 O25 123.6(8) . .
O26 C17 C18 120.3(8) . .
O25 C17 C18 116.1(6) . .
O27 C18 C17 113.1(6) . .
O27 C18 C19 109.6(6) . .
C17 C18 C19 108.3(6) . .
O30 C19 C20 111.6(7) . .
O30 C19 C18 109.4(6) . .
C20 C19 C18 108.4(7) . .
O29 C20 O28 124.0(9) . .
O29 C20 C19 120.3(9) . .
O28 C20 C19 115.7(8) . .
O32 C21 O31 126.7(7) . .
O32 C21 C22 118.3(7) . .
O31 C21 C22 114.9(6) . .
O33 C22 C21 112.4(6) . .
O33 C22 C23 109.7(6) . .
C21 C22 C23 107.6(6) . .
O36 C23 C24 113.4(6) . .
O36 C23 C22 110.3(6) . .
C24 C23 C22 107.0(6) . .
O35 C24 O34 124.3(8) . .
O35 C24 C23 119.5(7) . .
O34 C24 C23 116.2(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ce1 O1 2.459(6) .
Ce1 O26 2.490(6) 1_756
Ce1 O39W 2.497(6) .
Ce1 O32 2.525(5) 1_655
Ce1 O41W 2.527(6) .
Ce1 O38W 2.539(6) .
Ce1 O11 2.544(6) 1_655
Ce1 O40W 2.581(5) .
Ce1 O37W 2.653(7) .
Ce2 O6 2.451(6) 1_455
Ce2 O14 2.487(5) 1_554
Ce2 O46W 2.505(7) .
Ce2 O43W 2.520(6) .
Ce2 O8 2.516(6) .
Ce2 O19 2.550(5) .
Ce2 O42W 2.562(6) .
Ce2 O45W 2.592(6) .
Ce2 O44W 2.634(7) .
Sb1 O3 1.969(5) .
Sb1 O9 1.984(5) .
Sb1 O7 2.178(6) .
Sb1 O2 2.193(6) .
Sb2 O5 1.963(5) .
Sb2 O12 1.997(5) .
Sb2 O10 2.170(6) .
Sb2 O4 2.175(5) .
Sb3 O15 1.973(5) .
Sb3 O21 1.989(5) .
Sb3 O20 2.158(5) .
Sb3 O13 2.197(6) .
Sb4 O24 1.960(6) .
Sb4 O18 1.963(6) .
Sb4 O16 2.183(8) .
Sb4 O22 2.192(8) .
Sb5 O27 1.966(6) .
Sb5 O33 1.992(5) .
Sb5 O31 2.175(5) .
Sb5 O25 2.206(5) .
Sb6 O36 1.987(5) .
Sb6 O30 1.990(6) .
Sb6 O28 2.113(7) .
Sb6 O34 2.245(7) .
O1 C1 1.226(10) .
O2 C1 1.275(10) .
O3 C2 1.411(9) .
O4 C4 1.279(10) .
O5 C3 1.412(8) .
O6 C4 1.235(9) .
O6 Ce2 2.451(6) 1_655
O7 C5 1.264(9) .
O8 C5 1.249(9) .
O9 C6 1.398(9) .
O10 C8 1.291(10) .
O11 C8 1.224(10) .
O11 Ce1 2.544(6) 1_455
O12 C7 1.411(9) .
O13 C13 1.281(10) .
O14 C13 1.229(9) .
O14 Ce2 2.487(5) 1_556
O15 C14 1.416(9) .
O16 C16 1.305(12) .
O17 C16 1.220(12) .
O18 C15 1.416(10) .
O19 C9 1.221(9) .
O20 C9 1.285(10) .
O21 C10 1.415(8) .
O22 C12 1.294(12) .
O23 C12 1.220(12) .
O24 C11 1.415(10) .
O25 C17 1.269(10) .
O26 C17 1.243(9) .
O26 Ce1 2.490(6) 1_354
O27 C18 1.403(9) .
O28 C20 1.316(13) .
O29 C20 1.224(12) .
O30 C19 1.423(10) .
O31 C21 1.278(9) .
O32 C21 1.218(9) .
O32 Ce1 2.525(5) 1_455
O33 C22 1.426(9) .
O34 C24 1.280(10) .
O35 C24 1.245(11) .
O36 C23 1.379(10) .
C1 C2 1.524(12) .
C2 C3 1.526(11) .
C3 C4 1.489(10) .
C5 C6 1.530(10) .
C6 C7 1.544(10) .
C7 C8 1.524(10) .
C9 C10 1.535(10) .
C10 C11 1.524(11) .
C11 C12 1.534(12) .
C13 C14 1.525(10) .
C14 C15 1.523(12) .
C15 C16 1.539(11) .
C17 C18 1.510(11) .
C18 C19 1.553(11) .
C19 C20 1.530(12) .
C21 C22 1.532(10) .
C22 C23 1.545(10) .
C23 C24 1.514(11) .
