#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:47:46 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179394 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/91/4329144.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4329144
loop_
_publ_author_name
'Sean K. Liew'
'S. M. Ibrahim Al-Rafia'
'James T. Goettel'
'Paul A. Lummis'
'Sean M. McDonald'
'Leah J. Miedema'
'Michael J. Ferguson'
'Robert McDonald'
'Eric Rivard'
_publ_contact_author_address
;
Department of Chemistry
University of Alberta
Edmonton
AB T6G 2G2
CANADA
;
_publ_contact_author_email       ERIVARD@UALBERTA.CA
_publ_contact_author_name        'E. Rivard'
_publ_section_title
;
 Expanding the Steric Coverage Offered by Bis(amidosilyl) Chelates:
 Isolation of Low-Coordinate N-Heterocyclic Germylene Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5471
_journal_page_last               5480
_journal_paper_doi               10.1021/ic300495k
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C56 H92 Ge2 N4 S2 Si4, C7 H8, C4 H8 O'
_chemical_formula_sum            'C67 H108 Ge2 N4 O S2 Si4'
_chemical_formula_weight         1307.23
_chemical_name_common            4
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.871(3)
_cell_angle_beta                 93.857(3)
_cell_angle_gamma                107.097(2)
_cell_formula_units_Z            1
_cell_length_a                   9.960(2)
_cell_length_b                   14.101(3)
_cell_length_c                   15.228(3)
_cell_measurement_reflns_used    5998
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      23.34
_cell_measurement_theta_min      2.16
_cell_volume                     1972.5(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0641
_diffrn_reflns_av_sigmaI/netI    0.0873
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            14188
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         25.25
_diffrn_reflns_theta_min         1.56
_exptl_absorpt_coefficient_mu    0.913
_exptl_absorpt_correction_T_max  0.9363
_exptl_absorpt_correction_T_min  0.7569
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.100
_exptl_crystal_description       rod
_exptl_crystal_F_000             698
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.865
_refine_diff_density_min         -1.461
_refine_diff_density_rms         0.164
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     363
_refine_ls_number_reflns         7124
_refine_ls_number_restraints     7
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.1149
_refine_ls_R_factor_gt           0.0870
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1643P)²+3.9378P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2477
_refine_ls_wR_factor_ref         0.2703
_reflns_number_gt                5240
_reflns_number_total             7124
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic300495k_si_001_3.cif
_cod_data_source_block           riv1142
_cod_original_cell_volume        1972.6(8)
_cod_database_code               4329144
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge Ge 0.53057(7) 0.60708(5) 0.06538(5) 0.0224(3) Uani 1 1 d .
S S 0.66642(16) 0.50587(12) 0.01898(12) 0.0273(4) Uani 1 1 d .
Si1 Si 0.72985(19) 0.82638(14) 0.12419(15) 0.0313(5) Uani 1 1 d .
Si2 Si 0.6308(2) 0.77738(16) 0.24595(14) 0.0365(5) Uani 1 1 d .
N1 N 0.6018(5) 0.7324(4) 0.0379(4) 0.0269(12) Uani 1 1 d .
N2 N 0.5333(5) 0.6467(4) 0.1892(4) 0.0289(13) Uani 1 1 d .
C1 C 0.9132(8) 0.8143(7) 0.1279(6) 0.046(2) Uani 1 1 d .
H1A H 0.9563 0.8350 0.0763 0.055 Uiso 1 1 calc R
H1B H 0.9072 0.7429 0.1243 0.055 Uiso 1 1 calc R
H1C H 0.9717 0.8586 0.1849 0.055 Uiso 1 1 calc R
C2 C 0.7363(8) 0.9569(6) 0.1146(6) 0.047(2) Uani 1 1 d .
H2A H 0.7801 0.9705 0.0611 0.056 Uiso 1 1 calc R
H2B H 0.7925 1.0080 0.1694 0.056 Uiso 1 1 calc R
H2C H 0.6397 0.9609 0.1084 0.056 Uiso 1 1 calc R
C3 C 0.7669(10) 0.7929(7) 0.3431(6) 0.060(3) Uani 1 1 d .
H3A H 0.7194 0.7710 0.3929 0.072 Uiso 1 1 calc R
H3B H 0.8255 0.8651 0.3643 0.072 Uiso 1 1 calc R
H3C H 0.8271 0.7507 0.3231 0.072 Uiso 1 1 calc R
C4 C 0.5173(9) 0.8551(7) 0.2944(7) 0.059(3) Uani 1 1 d .
H4A H 0.4778 0.8313 0.3458 0.070 Uiso 1 1 calc R
H4B H 0.4398 0.8472 0.2474 0.070 Uiso 1 1 calc R
H4C H 0.5749 0.9276 0.3154 0.070 Uiso 1 1 calc R
C11 C 0.5528(7) 0.7632(5) -0.0386(5) 0.0303(16) Uani 1 1 d .
C12 C 0.4242(7) 0.7837(5) -0.0438(5) 0.0322(16) Uani 1 1 d .
C13 C 0.3854(8) 0.8225(6) -0.1171(6) 0.0420(19) Uani 1 1 d .
H13 H 0.2965 0.8345 -0.1223 0.050 Uiso 1 1 calc R
C14 C 0.4730(9) 0.8424(6) -0.1795(6) 0.046(2) Uani 1 1 d .
H14 H 0.4459 0.8685 -0.2278 0.056 Uiso 1 1 calc R
C15 C 0.6027(8) 0.8245(6) -0.1726(6) 0.044(2) Uani 1 1 d .
H15 H 0.6646 0.8408 -0.2157 0.053 Uiso 1 1 calc R
C16 C 0.6445(7) 0.7839(5) -0.1052(5) 0.0318(16) Uani 1 1 d .
C17 C 0.3236(7) 0.7715(6) 0.0258(5) 0.0355(17) Uani 1 1 d .
H17 H 0.3629 0.7419 0.0715 0.043 Uiso 1 1 calc R
C18 C 0.1748(7) 0.6971(6) -0.0171(6) 0.044(2) Uani 1 1 d .
H18A H 0.1829 0.6313 -0.0500 0.052 Uiso 1 1 calc R
H18B H 0.1312 0.7263 -0.0594 0.052 Uiso 1 1 calc R
H18C H 0.1156 0.6863 0.0310 0.052 Uiso 1 1 calc R
C19 C 0.3115(9) 0.8739(7) 0.0763(7) 0.052(2) Uani 1 1 d .
H19A H 0.4062 0.9211 0.1036 0.063 Uiso 1 1 calc R
H19B H 0.2520 0.8636 0.1242 0.063 Uiso 1 1 calc R
H19C H 0.2686 0.9030 0.0335 0.063 Uiso 1 1 calc R
C20 C 0.7858(8) 0.7647(6) -0.1041(6) 0.0414(19) Uani 1 1 d .
H20 H 0.8011 0.7374 -0.0503 0.050 Uiso 1 1 calc R
C21 C 0.9096(8) 0.8645(7) -0.0960(7) 0.055(2) Uani 1 1 d .
H21A H 0.9096 0.9158 -0.0408 0.066 Uiso 1 1 calc R
H21B H 0.8978 0.8909 -0.1493 0.066 Uiso 1 1 calc R
H21C H 0.9998 0.8498 -0.0928 0.066 Uiso 1 1 calc R
C22 C 0.7874(9) 0.6863(7) -0.1892(6) 0.051(2) Uani 1 1 d .
H22A H 0.7097 0.6227 -0.1947 0.061 Uiso 1 1 calc R
H22B H 0.8782 0.6725 -0.1858 0.061 Uiso 1 1 calc R
H22C H 0.7754 0.7129 -0.2424 0.061 Uiso 1 1 calc R
C31 C 0.4635(7) 0.5895(6) 0.2505(4) 0.0304(15) Uani 1 1 d .
C32 C 0.3217(8) 0.5864(6) 0.2666(5) 0.0379(17) Uani 1 1 d .
C33 C 0.2675(8) 0.5431(7) 0.3355(5) 0.048(2) Uani 1 1 d .
H33 H 0.1745 0.5413 0.3473 0.057 Uiso 1 1 calc R
C34 C 0.3425(9) 0.5035(8) 0.3862(6) 0.057(3) Uani 1 1 d .
H34 H 0.3028 0.4762 0.4338 0.069 Uiso 1 1 calc R
C35 C 0.4760(9) 0.5025(8) 0.3693(6) 0.055(2) Uani 1 1 d .
H35 H 0.5264 0.4721 0.4038 0.066 Uiso 1 1 calc R
C36 C 0.5384(7) 0.5458(6) 0.3018(5) 0.0379(18) Uani 1 1 d .
C37 C 0.2279(8) 0.6244(6) 0.2106(5) 0.0411(18) Uani 1 1 d .
H37 H 0.2861 0.6595 0.1691 0.049 Uiso 1 1 calc R
C38 C 0.1044(8) 0.5330(7) 0.1513(6) 0.049(2) Uani 1 1 d .
H38A H 0.1428 0.4843 0.1133 0.059 Uiso 1 1 calc R
H38B H 0.0480 0.5581 0.1122 0.059 Uiso 1 1 calc R
H38C H 0.0441 0.4988 0.1906 0.059 Uiso 1 1 calc R
C39 C 0.1664(10) 0.7010(8) 0.2683(7) 0.061(3) Uani 1 1 d .
H39A H 0.2440 0.7594 0.3059 0.073 Uiso 1 1 calc R
H39B H 0.1053 0.6672 0.3076 0.073 Uiso 1 1 calc R
H39C H 0.1104 0.7253 0.2282 0.073 Uiso 1 1 calc R
C40 C 0.6864(7) 0.5377(6) 0.2849(5) 0.0375(17) Uani 1 1 d .
H40 H 0.7282 0.5863 0.2477 0.045 Uiso 1 1 calc R
C41 C 0.7881(9) 0.5642(7) 0.3723(6) 0.051(2) Uani 1 1 d .
H41A H 0.8800 0.5583 0.3575 0.061 Uiso 1 1 calc R
H41B H 0.7491 0.5167 0.4093 0.061 Uiso 1 1 calc R
H41C H 0.8007 0.6346 0.4065 0.061 Uiso 1 1 calc R
C42 C 0.6719(10) 0.4302(7) 0.2318(6) 0.051(2) Uani 1 1 d .
H42A H 0.6067 0.4123 0.1752 0.061 Uiso 1 1 calc R
H42B H 0.6345 0.3819 0.2683 0.061 Uiso 1 1 calc R
H42C H 0.7651 0.4268 0.2175 0.061 Uiso 1 1 calc R
O10S O 0.119(2) 0.807(2) 0.6790(11) 0.130(9) Uani 0.50 1 d PD
C11S C 0.175(2) 0.8580(15) 0.6128(17) 0.090(8) Uani 0.50 1 d PD
H11A H 0.2787 0.8932 0.6293 0.108 Uiso 0.50 1 calc PR
H11B H 0.1276 0.9085 0.6045 0.108 Uiso 0.50 1 calc PR
C13S C 0.119(3) 0.665(2) 0.5476(16) 0.125(12) Uani 0.50 1 d PD
H13A H 0.0431 0.6096 0.5044 0.150 Uiso 0.50 1 calc PR
H13B H 0.2074 0.6466 0.5522 0.150 Uiso 0.50 1 calc PR
C12S C 0.142(3) 0.7696(19) 0.5277(13) 0.104(10) Uani 0.50 1 d PD
H12A H 0.0562 0.7676 0.4901 0.125 Uiso 0.50 1 calc PR
H12B H 0.2219 0.7828 0.4917 0.125 Uiso 0.50 1 calc PR
C14S C 0.075(3) 0.7002(19) 0.639(2) 0.135(15) Uani 0.50 1 d PD
H14A H -0.0302 0.6745 0.6320 0.162 Uiso 0.50 1 calc PR
H14B H 0.1111 0.6671 0.6818 0.162 Uiso 0.50 1 calc PR
C21S C 0.6395(15) 0.8336(10) 0.5816(11) 0.090(3) Uiso 0.50 1 d PG
C22S C 0.5971(14) 0.9140(12) 0.5644(11) 0.090(3) Uiso 0.50 1 d PGD
H22S H 0.5005 0.9029 0.5432 0.108 Uiso 0.50 1 calc PR
C23S C 0.6962(18) 1.0108(10) 0.5782(11) 0.090(3) Uiso 0.50 1 d PG
H23S H 0.6672 1.0658 0.5664 0.108 Uiso 0.50 1 calc PR
C24S C 0.8377(16) 1.0271(10) 0.6091(11) 0.090(3) Uiso 0.50 1 d PG
H24S H 0.9054 1.0932 0.6186 0.108 Uiso 0.50 1 calc PR
C25S C 0.8800(13) 0.9467(13) 0.6263(11) 0.090(3) Uiso 0.50 1 d PG
H25S H 0.9767 0.9578 0.6475 0.108 Uiso 0.50 1 calc PR
C26S C 0.7810(16) 0.8499(11) 0.6126(11) 0.090(3) Uiso 0.50 1 d PGD
H26S H 0.8099 0.7950 0.6243 0.108 Uiso 0.50 1 calc PR
C27S C 0.541(2) 0.7300(14) 0.5574(17) 0.090(3) Uiso 0.50 1 d PD
H27A H 0.4495 0.7298 0.5287 0.108 Uiso 0.50 1 calc PR
H27B H 0.5269 0.7052 0.6124 0.108 Uiso 0.50 1 calc PR
H27C H 0.5789 0.6850 0.5148 0.108 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ge N1 101.7(2) . .
N2 Ge S 118.47(17) . 2_665
N1 Ge S 118.32(18) . 2_665
N2 Ge S 115.24(18) . .
N1 Ge S 110.17(18) . .
S Ge S 93.39(6) 2_665 .
Ge S Ge 86.61(6) 2_665 .
N1 Si1 C2 110.1(3) . .
N1 Si1 C1 114.9(3) . .
C2 Si1 C1 110.1(4) . .
N1 Si1 Si2 96.9(2) . .
C2 Si1 Si2 115.7(3) . .
C1 Si1 Si2 108.9(3) . .
N2 Si2 C3 114.3(4) . .
N2 Si2 C4 114.0(3) . .
C3 Si2 C4 105.2(5) . .
N2 Si2 Si1 98.2(2) . .
C3 Si2 Si1 112.7(3) . .
C4 Si2 Si1 112.7(4) . .
C11 N1 Si1 118.0(4) . .
C11 N1 Ge 127.3(4) . .
Si1 N1 Ge 114.2(3) . .
C31 N2 Si2 112.6(5) . .
C31 N2 Ge 130.2(4) . .
Si2 N2 Ge 117.1(3) . .
C12 C11 C16 119.6(6) . .
C12 C11 N1 120.9(6) . .
C16 C11 N1 119.1(6) . .
C11 C12 C13 119.0(7) . .
C11 C12 C17 124.2(6) . .
C13 C12 C17 116.8(6) . .
C14 C13 C12 121.1(7) . .
C13 C14 C15 119.7(7) . .
C16 C15 C14 122.1(7) . .
C15 C16 C11 118.5(7) . .
C15 C16 C20 118.6(7) . .
C11 C16 C20 122.9(6) . .
C12 C17 C19 111.9(6) . .
C12 C17 C18 112.1(7) . .
C19 C17 C18 109.6(6) . .
C16 C20 C22 110.8(7) . .
C16 C20 C21 111.7(6) . .
C22 C20 C21 108.9(7) . .
C36 C31 C32 119.1(6) . .
C36 C31 N2 120.1(6) . .
C32 C31 N2 120.4(6) . .
C33 C32 C31 117.9(7) . .
C33 C32 C37 118.7(7) . .
C31 C32 C37 123.4(7) . .
C34 C33 C32 122.3(7) . .
C33 C34 C35 120.3(8) . .
C34 C35 C36 120.7(8) . .
C31 C36 C35 119.5(7) . .
C31 C36 C40 123.1(6) . .
C35 C36 C40 117.3(7) . .
C32 C37 C39 113.3(7) . .
C32 C37 C38 110.2(7) . .
C39 C37 C38 108.9(7) . .
C42 C40 C41 108.7(7) . .
C42 C40 C36 109.8(6) . .
C41 C40 C36 113.0(6) . .
C11S O10S C14S 108.0(17) . .
O10S C11S C12S 102.2(15) . .
C14S C13S C12S 92.3(19) . .
C13S C12S C11S 113.8(17) . .
O10S C14S C13S 116.9(19) . .
C22S C21S C26S 120.0 . .
C22S C21S C27S 120.3(10) . .
C26S C21S C27S 119.3(9) . .
C23S C22S C21S 120.0 . .
C22S C23S C24S 120.0 . .
C23S C24S C25S 120.0 . .
C26S C25S C24S 120.0 . .
C25S C26S C21S 120.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge N2 1.840(6) .
Ge N1 1.853(5) .
Ge S 2.2245(17) 2_665
Ge S 2.2763(17) .
S Ge 2.2245(17) 2_665
Si1 N1 1.765(6) .
Si1 C2 1.861(8) .
Si1 C1 1.882(8) .
Si1 Si2 2.303(3) .
Si2 N2 1.792(6) .
Si2 C3 1.867(9) .
Si2 C4 1.872(9) .
N1 C11 1.435(9) .
N2 C31 1.448(8) .
C11 C12 1.394(9) .
C11 C16 1.431(10) .
C12 C13 1.426(11) .
C12 C17 1.509(10) .
C13 C14 1.352(12) .
C14 C15 1.389(11) .
C15 C16 1.377(10) .
C16 C20 1.509(10) .
C17 C19 1.520(11) .
C17 C18 1.541(10) .
C20 C22 1.509(12) .
C20 C21 1.548(11) .
C31 C36 1.398(10) .
C31 C32 1.439(9) .
C32 C33 1.390(11) .
C32 C37 1.510(11) .
C33 C34 1.352(12) .
C34 C35 1.374(12) .
C35 C36 1.399(11) .
C36 C40 1.546(10) .
C37 C39 1.534(12) .
C37 C38 1.546(11) .
C40 C42 1.510(12) .
C40 C41 1.521(11) .
O10S C11S 1.414(10) .
O10S C14S 1.416(10) .
C11S C12S 1.524(10) .
C13S C14S 1.510(10) .
C13S C12S 1.521(10) .
C21S C22S 1.3900 .
C21S C26S 1.3900 .
C21S C27S 1.451(14) .
C22S C23S 1.3900 .
C23S C24S 1.3900 .
C24S C25S 1.3900 .
C25S C26S 1.3900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Ge S Ge 123.77(18) . 2_665
N1 Ge S Ge -121.86(19) . 2_665
S Ge S Ge 0.0 2_665 2_665
N1 Si1 Si2 N2 23.6(3) . .
C2 Si1 Si2 N2 139.8(3) . .
C1 Si1 Si2 N2 -95.6(4) . .
N1 Si1 Si2 C3 144.3(4) . .
C2 Si1 Si2 C3 -99.5(5) . .
C1 Si1 Si2 C3 25.1(5) . .
N1 Si1 Si2 C4 -96.7(4) . .
C2 Si1 Si2 C4 19.5(4) . .
C1 Si1 Si2 C4 144.0(4) . .
C2 Si1 N1 C11 17.0(6) . .
C1 Si1 N1 C11 -107.8(5) . .
Si2 Si1 N1 C11 137.6(5) . .
C2 Si1 N1 Ge -155.7(4) . .
C1 Si1 N1 Ge 79.4(4) . .
Si2 Si1 N1 Ge -35.1(3) . .
N2 Ge N1 C11 -138.5(6) . .
S Ge N1 C11 -6.8(6) 2_665 .
S Ge N1 C11 98.8(5) . .
N2 Ge N1 Si1 33.5(3) . .
S Ge N1 Si1 165.2(2) 2_665 .
S Ge N1 Si1 -89.2(3) . .
C3 Si2 N2 C31 56.4(6) . .
C4 Si2 N2 C31 -64.6(6) . .
Si1 Si2 N2 C31 176.0(4) . .
C3 Si2 N2 Ge -125.8(4) . .
C4 Si2 N2 Ge 113.1(5) . .
Si1 Si2 N2 Ge -6.3(3) . .
N1 Ge N2 C31 164.5(6) . .
S Ge N2 C31 32.9(6) 2_665 .
S Ge N2 C31 -76.3(6) . .
N1 Ge N2 Si2 -12.8(4) . .
S Ge N2 Si2 -144.3(2) 2_665 .
S Ge N2 Si2 106.4(3) . .
Si1 N1 C11 C12 -99.6(7) . .
Ge N1 C11 C12 72.1(8) . .
Si1 N1 C11 C16 73.5(7) . .
Ge N1 C11 C16 -114.8(6) . .
C16 C11 C12 C13 1.6(10) . .
N1 C11 C12 C13 174.7(6) . .
C16 C11 C12 C17 -175.8(6) . .
N1 C11 C12 C17 -2.7(11) . .
C11 C12 C13 C14 -2.1(11) . .
C17 C12 C13 C14 175.6(7) . .
C12 C13 C14 C15 0.3(13) . .
C13 C14 C15 C16 1.9(13) . .
C14 C15 C16 C11 -2.3(12) . .
C14 C15 C16 C20 178.6(8) . .
C12 C11 C16 C15 0.5(11) . .
N1 C11 C16 C15 -172.8(7) . .
C12 C11 C16 C20 179.5(7) . .
N1 C11 C16 C20 6.3(10) . .
C11 C12 C17 C19 114.0(8) . .
C13 C12 C17 C19 -63.5(9) . .
C11 C12 C17 C18 -122.5(7) . .
C13 C12 C17 C18 60.0(8) . .
C15 C16 C20 C22 -62.7(9) . .
C11 C16 C20 C22 118.2(8) . .
C15 C16 C20 C21 58.8(10) . .
C11 C16 C20 C21 -120.3(8) . .
Si2 N2 C31 C36 -83.7(7) . .
Ge N2 C31 C36 98.9(7) . .
Si2 N2 C31 C32 89.7(7) . .
Ge N2 C31 C32 -87.7(8) . .
C36 C31 C32 C33 2.5(11) . .
N2 C31 C32 C33 -170.9(7) . .
C36 C31 C32 C37 -175.5(7) . .
N2 C31 C32 C37 11.1(11) . .
C31 C32 C33 C34 -0.8(13) . .
C37 C32 C33 C34 177.3(9) . .
C32 C33 C34 C35 -1.7(15) . .
C33 C34 C35 C36 2.4(15) . .
C32 C31 C36 C35 -1.8(12) . .
N2 C31 C36 C35 171.6(7) . .
C32 C31 C36 C40 175.2(7) . .
N2 C31 C36 C40 -11.4(11) . .
C34 C35 C36 C31 -0.6(14) . .
C34 C35 C36 C40 -177.8(8) . .
C33 C32 C37 C39 54.3(10) . .
C31 C32 C37 C39 -127.7(8) . .
C33 C32 C37 C38 -67.9(10) . .
C31 C32 C37 C38 110.0(8) . .
C31 C36 C40 C42 -100.9(9) . .
C35 C36 C40 C42 76.2(9) . .
C31 C36 C40 C41 137.6(8) . .
C35 C36 C40 C41 -45.3(11) . .
C14S O10S C11S C12S 6(3) . .
C14S C13S C12S C11S 25(3) . .
O10S C11S C12S C13S -22(3) . .
C11S O10S C14S C13S 11(4) . .
C12S C13S C14S O10S -22(4) . .
C26S C21S C22S C23S 0.0 . .
C27S C21S C22S C23S -172.8(19) . .
C21S C22S C23S C24S 0.0 . .
C22S C23S C24S C25S 0.0 . .
C23S C24S C25S C26S 0.0 . .
C24S C25S C26S C21S 0.0 . .
C22S C21S C26S C25S 0.0 . .
C27S C21S C26S C25S 172.8(18) . .
