#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:13:54 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179403 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/00/4330080.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4330080
loop_
_publ_author_name
'Elena Chelebaeva'
'Jérôme Long'
'Joulia Larionova'
'Rute A. S. Ferreira'
'Luis D. Carlos'
'Filipe A. Almeida Paz'
'José B. R. Gomes'
'Alexander Trifonov'
'Christian Guérin'
'Yannick Guari'
_publ_contact_author_address
; Institut Charles Gerhardt Montpellier
  UMR 5253
  CNRS-UM2-ENSCM-UM1
  Chimie Moleculaire et Organisation du Solide
  Universite Montpellier II
  Place E. Bataillon
  34095 Montpellier cedex 5
  France
;
_publ_contact_author_email       joulia@univ-montp2.fr
_publ_contact_author_name        'Professor Joulia Larionova'
_publ_section_title
;
 Bifunctional Mixed-Lanthanide Cyano-Bridged Coordination Polymers
 Ln0.5Ln'0.5(H2O)5[W(CN)8] (Ln/Ln' = Eu3+/Tb3+, Eu3+/Gd3+, Tb3+/Sm3+)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9005
_journal_page_last               9016
_journal_paper_doi               10.1021/ic301144j
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C16 H20 Eu N16 O10 Tb W2'
_chemical_formula_sum            'C16 H20 Eu N16 O10 Tb W2'
_chemical_formula_weight         1275.06
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           129
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-P 4a 2a'
_symmetry_space_group_name_H-M   'P 4/n m m :2'
_atom_sites_solution_hydrogens   none
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             '26 January 2012'
_audit_creation_method           'SHELXL-97, manual editing plus enCIFer'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   10.95080(10)
_cell_length_b                   10.95080(10)
_cell_length_c                   7.11970(10)
_cell_measurement_reflns_used    9094
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      45.28
_cell_measurement_theta_min      2.63
_cell_volume                     853.795(16)
_computing_cell_refinement       'APEX2 (Bruker, 2006)'
_computing_data_collection       'APEX2 (Bruker, 2006)'
_computing_data_reduction        'SAINT+ (Bruker, 2005)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2009)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker X8 Kappa CCD APEX II'
_diffrn_measurement_method       'ω / φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0258
_diffrn_reflns_av_sigmaI/netI    0.0092
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            22394
_diffrn_reflns_theta_full        36.27
_diffrn_reflns_theta_max         36.27
_diffrn_reflns_theta_min         3.72
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    10.639
_exptl_absorpt_correction_T_max  0.2809
_exptl_absorpt_correction_T_min  0.1845
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS (Sheldrick, 1997)
;
_exptl_crystal_colour            Orange
_exptl_crystal_density_diffrn    2.480
_exptl_crystal_description       Prism
_exptl_crystal_F_000             584
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.816
_refine_diff_density_min         -4.536
_refine_diff_density_rms         0.232
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.255
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     60
_refine_ls_number_reflns         1176
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.255
_refine_ls_R_factor_all          0.0139
_refine_ls_R_factor_gt           0.0138
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0083P)²+1.7356P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0326
_refine_ls_wR_factor_ref         0.0326
_reflns_number_gt                1173
_reflns_number_total             1176
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic301144j_si_002_1.cif
_cod_data_source_block           I-CCDC_753631
_cod_original_sg_symbol_H-M      'P 4/n m m'
_cod_database_code               4330080
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'-y+1/2, x, z'
'y, -x+1/2, z'
'-x, y+1/2, -z'
'x+1/2, -y, -z'
'y+1/2, x+1/2, -z'
'-y, -x, -z'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'y-1/2, -x, -z'
'-y, x-1/2, -z'
'x, -y-1/2, z'
'-x-1/2, y, z'
'-y-1/2, -x-1/2, z'
'y, x, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.2500 0.2500 0.24284(3) 0.00759(4) Uani 0.50 8 d SP
Tb1 Tb 0.2500 0.2500 0.24284(3) 0.00759(4) Uani 0.50 8 d SP
W1 W 0.2500 -0.2500 0.5000 0.00695(4) Uani 1 8 d S
O1W O 0.2500 0.2500 0.5965(6) 0.0274(9) Uani 1 8 d S
O2W O 0.0989(4) 0.3685(4) 0.0589(7) 0.0243(11) Uani 0.30 1 d P
O3W O 0.1437(4) 0.3563(4) -0.0021(9) 0.0340(15) Uani 0.40 2 d SP
N1 N 0.2787(4) 0.0368(3) 0.3635(5) 0.0276(10) Uani 0.50 1 d P
C1 C 0.2745(3) -0.0642(3) 0.4098(4) 0.0181(8) Uani 0.50 1 d P
N2 N 0.4300(3) -0.2014(4) 0.1347(5) 0.0321(8) Uani 0.50 1 d P
C2 C 0.3673(3) -0.2224(3) 0.2610(4) 0.0171(6) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3W Eu1 O3W 58.1(2) 3 .
O3W Eu1 O3W 58.1(2) 3 2
O3W Eu1 O3W 86.7(3) . 2
O3W Eu1 O3W 86.7(3) 3 4
O3W Eu1 O3W 58.1(2) . 4
O3W Eu1 O3W 58.1(2) 2 4
O3W Eu1 O2W 15.65(16) 3 13_565
O3W Eu1 O2W 62.98(13) . 13_565
O3W Eu1 O2W 71.68(16) 2 13_565
O3W Eu1 O2W 101.2(2) 4 13_565
O3W Eu1 O2W 15.65(16) 3 3
O3W Eu1 O2W 71.68(16) . 3
O3W Eu1 O2W 62.98(13) 2 3
O3W Eu1 O2W 101.2(2) 4 3
O2W Eu1 O2W 11.70(18) 13_565 3
O3W Eu1 O2W 62.98(13) 3 16
O3W Eu1 O2W 101.2(2) . 16
O3W Eu1 O2W 15.65(16) 2 16
O3W Eu1 O2W 71.68(16) 4 16
O2W Eu1 O2W 73.77(12) 13_565 16
O2W Eu1 O2W 63.2(2) 3 16
O3W Eu1 O2W 101.2(2) 3 4
O3W Eu1 O2W 62.98(13) . 4
O3W Eu1 O2W 71.68(16) 2 4
O3W Eu1 O2W 15.65(16) 4 4
O2W Eu1 O2W 114.9(3) 13_565 4
O2W Eu1 O2W 116.2(3) 3 4
O2W Eu1 O2W 83.8(2) 16 4
O3W Eu1 O2W 101.2(2) 3 14_655
O3W Eu1 O2W 71.68(16) . 14_655
O3W Eu1 O2W 62.98(13) 2 14_655
O3W Eu1 O2W 15.65(16) 4 14_655
O2W Eu1 O2W 116.2(3) 13_565 14_655
O2W Eu1 O2W 114.9(3) 3 14_655
O2W Eu1 O2W 73.77(12) 16 14_655
O2W Eu1 O2W 11.70(18) 4 14_655
O3W Eu1 O2W 62.98(13) 3 .
O3W Eu1 O2W 15.65(16) . .
O3W Eu1 O2W 101.2(2) 2 .
O3W Eu1 O2W 71.68(16) 4 .
O2W Eu1 O2W 63.2(2) 13_565 .
O2W Eu1 O2W 73.77(12) 3 .
O2W Eu1 O2W 114.9(3) 16 .
O2W Eu1 O2W 73.77(12) 4 .
O2W Eu1 O2W 83.8(2) 14_655 .
O3W Eu1 O2W 71.68(16) 3 2
O3W Eu1 O2W 101.2(2) . 2
O3W Eu1 O2W 15.65(16) 2 2
O3W Eu1 O2W 62.98(13) 4 2
O2W Eu1 O2W 83.8(2) 13_565 2
O2W Eu1 O2W 73.77(12) 3 2
O2W Eu1 O2W 11.70(18) 16 2
O2W Eu1 O2W 73.77(12) 4 2
O2W Eu1 O2W 63.2(2) 14_655 2
O2W Eu1 O2W 116.2(3) . 2
O3W Eu1 O2W 71.68(16) 3 15_665
O3W Eu1 O2W 15.65(16) . 15_665
O3W Eu1 O2W 101.2(2) 2 15_665
O3W Eu1 O2W 62.98(13) 4 15_665
O2W Eu1 O2W 73.77(12) 13_565 15_665
O2W Eu1 O2W 83.8(2) 3 15_665
O2W Eu1 O2W 116.2(3) 16 15_665
O2W Eu1 O2W 63.2(2) 4 15_665
O2W Eu1 O2W 73.77(12) 14_655 15_665
O2W Eu1 O2W 11.70(18) . 15_665
O2W Eu1 O2W 114.9(3) 2 15_665
O3W Eu1 N1 139.63(11) 3 3
O3W Eu1 N1 129.82(9) . 3
O3W Eu1 N1 81.83(14) 2 3
O3W Eu1 N1 74.72(16) 4 3
O2W Eu1 N1 150.30(12) 13_565 3
O2W Eu1 N1 138.80(13) 3 3
O2W Eu1 N1 77.12(13) 16 3
O2W Eu1 N1 67.04(14) 4 3
O2W Eu1 N1 59.58(14) 14_655 3
O2W Eu1 N1 137.52(13) . 3
O2W Eu1 N1 67.96(13) 2 3
O2W Eu1 N1 125.82(13) 15_665 3
O3W Eu1 N1 139.63(11) 3 13_565
O3W Eu1 N1 81.83(14) . 13_565
O3W Eu1 N1 129.82(9) 2 13_565
O3W Eu1 N1 74.72(16) 4 13_565
O2W Eu1 N1 138.80(13) 13_565 13_565
O2W Eu1 N1 150.30(12) 3 13_565
O2W Eu1 N1 137.52(13) 16 13_565
O2W Eu1 N1 59.58(14) 4 13_565
O2W Eu1 N1 67.04(14) 14_655 13_565
O2W Eu1 N1 77.12(13) . 13_565
O2W Eu1 N1 125.82(13) 2 13_565
O2W Eu1 N1 67.96(13) 15_665 13_565
N1 Eu1 N1 69.48(17) 3 13_565
O3W Eu1 N1 129.82(9) 3 15_665
O3W Eu1 N1 139.63(11) . 15_665
O3W Eu1 N1 74.72(16) 2 15_665
O3W Eu1 N1 81.83(14) 4 15_665
O2W Eu1 N1 137.52(13) 13_565 15_665
O2W Eu1 N1 125.82(13) 3 15_665
O2W Eu1 N1 67.04(14) 16 15_665
O2W Eu1 N1 77.12(13) 4 15_665
O2W Eu1 N1 67.96(13) 14_655 15_665
O2W Eu1 N1 150.30(12) . 15_665
O2W Eu1 N1 59.58(14) 2 15_665
O2W Eu1 N1 138.80(13) 15_665 15_665
N1 Eu1 N1 14.38(18) 3 15_665
N1 Eu1 N1 83.26(5) 13_565 15_665
O3W Eu1 N1 129.82(9) 3 2
O3W Eu1 N1 74.72(16) . 2
O3W Eu1 N1 139.63(11) 2 2
O3W Eu1 N1 81.83(14) 4 2
O2W Eu1 N1 125.82(13) 13_565 2
O2W Eu1 N1 137.52(13) 3 2
O2W Eu1 N1 150.30(12) 16 2
O2W Eu1 N1 67.96(13) 4 2
O2W Eu1 N1 77.12(13) 14_655 2
O2W Eu1 N1 67.04(14) . 2
O2W Eu1 N1 138.80(13) 2 2
O2W Eu1 N1 59.58(14) 15_665 2
N1 Eu1 N1 83.26(5) 3 2
N1 Eu1 N1 14.38(18) 13_565 2
N1 Eu1 N1 96.64(18) 15_665 2
O3W Eu1 N1 74.72(16) 3 4
O3W Eu1 N1 81.83(14) . 4
O3W Eu1 N1 129.82(9) 2 4
O3W Eu1 N1 139.63(11) 4 4
O2W Eu1 N1 59.58(14) 13_565 4
O2W Eu1 N1 67.04(14) 3 4
O2W Eu1 N1 125.82(13) 16 4
O2W Eu1 N1 138.80(13) 4 4
O2W Eu1 N1 150.30(12) 14_655 4
O2W Eu1 N1 67.96(13) . 4
O2W Eu1 N1 137.52(13) 2 4
O2W Eu1 N1 77.12(13) 15_665 4
N1 Eu1 N1 139.92(15) 3 4
N1 Eu1 N1 96.64(18) 13_565 4
N1 Eu1 N1 137.21(15) 15_665 4
N1 Eu1 N1 83.26(5) 2 4
O3W Eu1 N1 74.72(16) 3 14_655
O3W Eu1 N1 129.82(9) . 14_655
O3W Eu1 N1 81.83(14) 2 14_655
O3W Eu1 N1 139.63(11) 4 14_655
O2W Eu1 N1 67.04(14) 13_565 14_655
O2W Eu1 N1 59.58(14) 3 14_655
O2W Eu1 N1 67.96(13) 16 14_655
O2W Eu1 N1 150.30(12) 4 14_655
O2W Eu1 N1 138.80(13) 14_655 14_655
O2W Eu1 N1 125.82(13) . 14_655
O2W Eu1 N1 77.12(13) 2 14_655
O2W Eu1 N1 137.52(13) 15_665 14_655
N1 Eu1 N1 96.64(18) 3 14_655
N1 Eu1 N1 139.92(15) 13_565 14_655
N1 Eu1 N1 83.26(5) 15_665 14_655
N1 Eu1 N1 137.21(15) 2 14_655
N1 Eu1 N1 69.48(17) 4 14_655
O3W Eu1 N1 81.83(14) 3 16
O3W Eu1 N1 74.72(16) . 16
O3W Eu1 N1 139.63(11) 2 16
O3W Eu1 N1 129.82(9) 4 16
O2W Eu1 N1 67.96(13) 13_565 16
O2W Eu1 N1 77.12(13) 3 16
O2W Eu1 N1 138.80(13) 16 16
O2W Eu1 N1 125.82(13) 4 16
O2W Eu1 N1 137.52(13) 14_655 16
O2W Eu1 N1 59.58(14) . 16
O2W Eu1 N1 150.30(12) 2 16
O2W Eu1 N1 67.04(14) 15_665 16
N1 Eu1 N1 137.21(15) 3 16
N1 Eu1 N1 83.26(5) 13_565 16
N1 Eu1 N1 139.92(15) 15_665 16
N1 Eu1 N1 69.48(17) 2 16
N1 Eu1 N1 14.38(18) 4 16
N1 Eu1 N1 83.26(5) 14_655 16
O3W Eu1 N1 81.83(14) 3 .
O3W Eu1 N1 139.63(11) . .
O3W Eu1 N1 74.72(16) 2 .
O3W Eu1 N1 129.82(9) 4 .
O2W Eu1 N1 77.12(13) 13_565 .
O2W Eu1 N1 67.96(13) 3 .
O2W Eu1 N1 59.58(14) 16 .
O2W Eu1 N1 137.52(13) 4 .
O2W Eu1 N1 125.82(13) 14_655 .
O2W Eu1 N1 138.80(13) . .
O2W Eu1 N1 67.04(14) 2 .
O2W Eu1 N1 150.30(12) 15_665 .
N1 Eu1 N1 83.26(5) 3 .
N1 Eu1 N1 137.21(15) 13_565 .
N1 Eu1 N1 69.48(17) 15_665 .
N1 Eu1 N1 139.92(15) 2 .
N1 Eu1 N1 83.26(5) 4 .
N1 Eu1 N1 14.38(18) 14_655 .
N1 Eu1 N1 96.64(18) 16 .
O3W Eu1 O1W 136.64(17) 3 .
O3W Eu1 O1W 136.64(17) . .
O3W Eu1 O1W 136.64(17) 2 .
O3W Eu1 O1W 136.64(17) 4 .
O2W Eu1 O1W 121.91(13) 13_565 .
O2W Eu1 O1W 121.91(13) 3 .
O2W Eu1 O1W 121.91(13) 16 .
O2W Eu1 O1W 121.91(13) 4 .
O2W Eu1 O1W 121.91(13) 14_655 .
O2W Eu1 O1W 121.91(13) . .
O2W Eu1 O1W 121.91(13) 2 .
O2W Eu1 O1W 121.91(13) 15_665 .
N1 Eu1 O1W 69.96(8) 3 .
N1 Eu1 O1W 69.96(8) 13_565 .
N1 Eu1 O1W 69.96(8) 15_665 .
N1 Eu1 O1W 69.96(8) 2 .
N1 Eu1 O1W 69.96(8) 4 .
N1 Eu1 O1W 69.96(8) 14_655 .
N1 Eu1 O1W 69.96(8) 16 .
N1 Eu1 O1W 69.96(8) . .
C1 W1 C1 81.53(17) 8_556 2_545
C1 W1 C1 14.35(18) 8_556 12_556
C1 W1 C1 95.11(5) 2_545 12_556
C1 W1 C1 145.25(17) 8_556 7_546
C1 W1 C1 109.00(18) 2_545 7_546
C1 W1 C1 142.23(17) 12_556 7_546
C1 W1 C1 95.11(5) 8_556 13
C1 W1 C1 14.35(18) 2_545 13
C1 W1 C1 109.00(18) 12_556 13
C1 W1 C1 95.11(5) 7_546 13
C1 W1 C1 109.00(18) 8_556 .
C1 W1 C1 145.25(17) 2_545 .
C1 W1 C1 95.11(5) 12_556 .
C1 W1 C1 81.53(17) 7_546 .
C1 W1 C1 142.23(17) 13 .
C1 W1 C1 142.23(17) 8_556 11_656
C1 W1 C1 95.11(5) 2_545 11_656
C1 W1 C1 145.25(17) 12_556 11_656
C1 W1 C1 14.35(18) 7_546 11_656
C1 W1 C1 81.53(17) 13 11_656
C1 W1 C1 95.11(5) . 11_656
C1 W1 C1 95.11(5) 8_556 14_655
C1 W1 C1 142.23(17) 2_545 14_655
C1 W1 C1 81.53(17) 12_556 14_655
C1 W1 C1 95.11(5) 7_546 14_655
C1 W1 C1 145.25(17) 13 14_655
C1 W1 C1 14.35(18) . 14_655
C1 W1 C1 109.00(18) 11_656 14_655
C1 W1 C2 88.35(12) 8_556 7_546
C1 W1 C2 144.87(12) 2_545 7_546
C1 W1 C2 79.76(12) 12_556 7_546
C1 W1 C2 63.69(12) 7_546 7_546
C1 W1 C2 141.52(12) 13 7_546
C1 W1 C2 69.77(12) . 7_546
C1 W1 C2 72.89(12) 11_656 7_546
C1 W1 C2 71.89(12) 14_655 7_546
C1 W1 C2 69.77(12) 8_556 2_545
C1 W1 C2 63.69(12) 2_545 2_545
C1 W1 C2 71.89(12) 12_556 2_545
C1 W1 C2 144.87(12) 7_546 2_545
C1 W1 C2 72.89(12) 13 2_545
C1 W1 C2 88.35(12) . 2_545
C1 W1 C2 141.52(12) 11_656 2_545
C1 W1 C2 79.76(12) 14_655 2_545
C2 W1 C2 142.36(17) 7_546 2_545
C1 W1 C2 72.89(12) 8_556 12_556
C1 W1 C2 141.52(12) 2_545 12_556
C1 W1 C2 63.69(12) 12_556 12_556
C1 W1 C2 79.76(12) 7_546 12_556
C1 W1 C2 144.87(12) 13 12_556
C1 W1 C2 71.89(12) . 12_556
C1 W1 C2 88.35(12) 11_656 12_556
C1 W1 C2 69.77(12) 14_655 12_556
C2 W1 C2 16.13(17) 7_546 12_556
C2 W1 C2 128.65(11) 2_545 12_556
C1 W1 C2 71.89(12) 8_556 14_655
C1 W1 C2 79.76(12) 2_545 14_655
C1 W1 C2 69.77(12) 12_556 14_655
C1 W1 C2 141.52(12) 7_546 14_655
C1 W1 C2 88.35(12) 13 14_655
C1 W1 C2 72.89(12) . 14_655
C1 W1 C2 144.87(12) 11_656 14_655
C1 W1 C2 63.69(12) 14_655 14_655
C2 W1 C2 128.65(11) 7_546 14_655
C2 W1 C2 16.13(17) 2_545 14_655
C2 W1 C2 117.21(17) 12_556 14_655
C1 W1 C2 63.69(12) 8_556 8_556
C1 W1 C2 69.77(12) 2_545 8_556
C1 W1 C2 72.89(12) 12_556 8_556
C1 W1 C2 88.35(12) 7_546 8_556
C1 W1 C2 71.89(12) 13 8_556
C1 W1 C2 144.87(12) . 8_556
C1 W1 C2 79.76(12) 11_656 8_556
C1 W1 C2 141.52(12) 14_655 8_556
C2 W1 C2 75.57(17) 7_546 8_556
C2 W1 C2 117.21(17) 2_545 8_556
C2 W1 C2 73.23(17) 12_556 8_556
C2 W1 C2 128.65(11) 14_655 8_556
C1 W1 C2 79.76(12) 8_556 11_656
C1 W1 C2 71.89(12) 2_545 11_656
C1 W1 C2 88.35(12) 12_556 11_656
C1 W1 C2 72.89(12) 7_546 11_656
C1 W1 C2 69.77(12) 13 11_656
C1 W1 C2 141.52(12) . 11_656
C1 W1 C2 63.69(12) 11_656 11_656
C1 W1 C2 144.87(12) 14_655 11_656
C2 W1 C2 73.23(17) 7_546 11_656
C2 W1 C2 128.65(11) 2_545 11_656
C2 W1 C2 75.57(17) 12_556 11_656
C2 W1 C2 142.36(17) 14_655 11_656
C2 W1 C2 16.13(17) 8_556 11_656
C1 W1 C2 144.87(12) 8_556 .
C1 W1 C2 88.35(12) 2_545 .
C1 W1 C2 141.52(12) 12_556 .
C1 W1 C2 69.77(12) 7_546 .
C1 W1 C2 79.76(12) 13 .
C1 W1 C2 63.69(12) . .
C1 W1 C2 71.89(12) 11_656 .
C1 W1 C2 72.89(12) 14_655 .
C2 W1 C2 117.21(17) 7_546 .
C2 W1 C2 75.57(17) 2_545 .
C2 W1 C2 128.65(11) 12_556 .
C2 W1 C2 73.23(17) 14_655 .
C2 W1 C2 142.36(17) 8_556 .
C2 W1 C2 128.65(11) 11_656 .
C1 W1 C2 141.52(12) 8_556 13
C1 W1 C2 72.89(12) 2_545 13
C1 W1 C2 144.87(12) 12_556 13
C1 W1 C2 71.89(12) 7_546 13
C1 W1 C2 63.69(12) 13 13
C1 W1 C2 79.76(12) . 13
C1 W1 C2 69.77(12) 11_656 13
C1 W1 C2 88.35(12) 14_655 13
C2 W1 C2 128.65(11) 7_546 13
C2 W1 C2 73.23(17) 2_545 13
C2 W1 C2 142.36(17) 12_556 13
C2 W1 C2 75.57(17) 14_655 13
C2 W1 C2 128.65(11) 8_556 13
C2 W1 C2 117.21(17) 11_656 13
C2 W1 C2 16.13(17) . 13
O2W O2W O3W 67.8(4) 15_665 .
O2W O2W Eu1 84.15(9) 15_665 .
O3W O2W Eu1 75.4(7) . .
O2W O3W Eu1 88.9(8) 15_665 .
O2W O3W Eu1 88.9(8) . .
N1 N1 C1 87.8(3) 14_655 .
N1 N1 C1 63.2(2) 14_655 14_655
N1 N1 Eu1 82.81(9) 14_655 .
C1 N1 Eu1 169.9(3) . .
C1 N1 Eu1 145.9(3) 14_655 .
C1 C1 N1 92.2(3) 14_655 .
C1 C1 N1 63.2(2) 14_655 14_655
C1 C1 W1 82.82(9) 14_655 .
N1 C1 W1 175.0(3) . .
N1 C1 W1 146.0(3) 14_655 .
N2 N2 C2 78.5(3) 13 .
N2 N2 C2 53.6(2) 13 13
C2 C2 N2 101.5(3) 13 .
C2 C2 N2 53.6(2) 13 13
N2 C2 N2 47.9(4) . 13
C2 C2 W1 81.94(9) 13 .
N2 C2 W1 176.5(3) . .
N2 C2 W1 135.5(3) 13 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O3W 2.398(6) 3
Eu1 O3W 2.398(6) .
Eu1 O3W 2.398(6) 2
Eu1 O3W 2.398(6) 4
Eu1 O2W 2.477(5) 13_565
Eu1 O2W 2.477(5) 3
Eu1 O2W 2.477(5) 16
Eu1 O2W 2.477(5) 4
Eu1 O2W 2.477(5) 14_655
Eu1 O2W 2.477(5) .
Eu1 O2W 2.477(5) 2
Eu1 O2W 2.477(5) 15_665
Eu1 N1 2.507(3) 3
Eu1 N1 2.507(3) 13_565
Eu1 N1 2.507(3) 15_665
Eu1 N1 2.507(3) 2
Eu1 N1 2.507(3) 4
Eu1 N1 2.507(3) 14_655
Eu1 N1 2.507(3) 16
Eu1 N1 2.507(3) .
Eu1 O1W 2.518(4) .
W1 C1 2.150(3) 8_556
W1 C1 2.150(3) 2_545
W1 C1 2.150(3) 12_556
W1 C1 2.150(3) 7_546
W1 C1 2.150(3) 13
W1 C1 2.150(3) .
W1 C1 2.150(3) 11_656
W1 C1 2.150(3) 14_655
W1 C2 2.153(3) 7_546
W1 C2 2.153(3) 2_545
W1 C2 2.153(3) 12_556
W1 C2 2.153(3) 14_655
W1 C2 2.153(3) 8_556
W1 C2 2.153(3) 11_656
W1 C2 2.153(3) .
W1 C2 2.153(3) 13
O2W O2W 0.505(8) 15_665
O2W O3W 0.669(7) .
O3W O2W 0.669(7) 15_665
N1 N1 0.628(8) 14_655
N1 C1 1.155(4) .
N1 C1 1.293(4) 14_655
C1 C1 0.537(7) 14_655
C1 N1 1.293(4) 14_655
N2 N2 1.065(9) 13
N2 C2 1.155(4) .
N2 C2 1.406(5) 13
C2 C2 0.604(6) 13
C2 N2 1.406(5) 13
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3W Eu1 O2W O2W -136.26(17) 3 15_665
O3W Eu1 O2W O2W -68.5(4) . 15_665
O3W Eu1 O2W O2W -91.16(3) 2 15_665
O3W Eu1 O2W O2W -40.46(16) 4 15_665
O2W Eu1 O2W O2W -153.83(9) 13_565 15_665
O2W Eu1 O2W O2W -148.48(12) 3 15_665
O2W Eu1 O2W O2W -99.23(15) 16 15_665
O2W Eu1 O2W O2W -24.20(9) 4 15_665
O2W Eu1 O2W O2W -30.33(10) 14_655 15_665
O2W Eu1 O2W O2W -86.34(6) 2 15_665
N1 Eu1 O2W O2W -1.06(17) 3 15_665
N1 Eu1 O2W O2W 37.48(9) 13_565 15_665
N1 Eu1 O2W O2W -12.4(3) 15_665 15_665
N1 Eu1 O2W O2W 48.27(10) 2 15_665
N1 Eu1 O2W O2W 140.22(10) 4 15_665
N1 Eu1 O2W O2W -179.11(14) 14_655 15_665
N1 Eu1 O2W O2W 127.17(11) 16 15_665
N1 Eu1 O2W O2W -170.7(2) . 15_665
O1W Eu1 O2W O2W 93.66(6) . 15_665
O3W Eu1 O2W O3W -67.7(5) 3 .
O3W Eu1 O2W O3W -22.6(5) 2 .
O3W Eu1 O2W O3W 28.1(3) 4 .
O2W Eu1 O2W O3W -85.3(4) 13_565 .
O2W Eu1 O2W O3W -79.9(4) 3 .
O2W Eu1 O2W O3W -30.7(5) 16 .
O2W Eu1 O2W O3W 44.3(4) 4 .
O2W Eu1 O2W O3W 38.2(5) 14_655 .
O2W Eu1 O2W O3W -17.8(4) 2 .
O2W Eu1 O2W O3W 68.5(4) 15_665 .
N1 Eu1 O2W O3W 67.5(5) 3 .
N1 Eu1 O2W O3W 106.0(4) 13_565 .
N1 Eu1 O2W O3W 56.1(6) 15_665 .
N1 Eu1 O2W O3W 116.8(5) 2 .
N1 Eu1 O2W O3W -151.2(5) 4 .
N1 Eu1 O2W O3W -110.6(4) 14_655 .
N1 Eu1 O2W O3W -164.3(5) 16 .
N1 Eu1 O2W O3W -102.1(5) . .
O1W Eu1 O2W O3W 162.2(4) . .
Eu1 O2W O3W O2W -89.6(3) . 15_665
O2W O2W O3W Eu1 89.6(3) 15_665 .
O3W Eu1 O3W O2W 148.2(4) 3 15_665
O3W Eu1 O3W O2W -157.8(4) 2 15_665
O3W Eu1 O3W O2W -103.8(5) 4 15_665
O2W Eu1 O3W O2W 131.1(5) 13_565 15_665
O2W Eu1 O3W O2W 139.6(5) 3 15_665
O2W Eu1 O3W O2W -163.8(4) 16 15_665
O2W Eu1 O3W O2W -86.7(4) 4 15_665
O2W Eu1 O3W O2W -95.2(3) 14_655 15_665
O2W Eu1 O3W O2W 44.4(9) . 15_665
O2W Eu1 O3W O2W -151.8(5) 2 15_665
N1 Eu1 O3W O2W -81.3(5) 3 15_665
N1 Eu1 O3W O2W -26.8(4) 13_565 15_665
N1 Eu1 O3W O2W -96.2(6) 15_665 15_665
N1 Eu1 O3W O2W -14.0(4) 2 15_665
N1 Eu1 O3W O2W 71.2(5) 4 15_665
N1 Eu1 O3W O2W 125.7(4) 14_655 15_665
N1 Eu1 O3W O2W 58.4(5) 16 15_665
N1 Eu1 O3W O2W 140.6(4) . 15_665
O1W Eu1 O3W O2W 22.2(4) . 15_665
O3W Eu1 O3W O2W 103.8(5) 3 .
O3W Eu1 O3W O2W 157.8(4) 2 .
O3W Eu1 O3W O2W -148.2(4) 4 .
O2W Eu1 O3W O2W 86.7(4) 13_565 .
O2W Eu1 O3W O2W 95.2(3) 3 .
O2W Eu1 O3W O2W 151.8(5) 16 .
O2W Eu1 O3W O2W -131.1(5) 4 .
O2W Eu1 O3W O2W -139.6(5) 14_655 .
O2W Eu1 O3W O2W 163.8(4) 2 .
O2W Eu1 O3W O2W -44.4(9) 15_665 .
N1 Eu1 O3W O2W -125.7(4) 3 .
N1 Eu1 O3W O2W -71.2(5) 13_565 .
N1 Eu1 O3W O2W -140.6(4) 15_665 .
N1 Eu1 O3W O2W -58.4(5) 2 .
N1 Eu1 O3W O2W 26.8(4) 4 .
N1 Eu1 O3W O2W 81.3(5) 14_655 .
N1 Eu1 O3W O2W 14.0(4) 16 .
N1 Eu1 O3W O2W 96.2(6) . .
O1W Eu1 O3W O2W -22.2(4) . .
O3W Eu1 N1 N1 -59.18(13) 3 14_655
O3W Eu1 N1 N1 -52.6(3) . 14_655
O3W Eu1 N1 N1 -118.21(11) 2 14_655
O3W Eu1 N1 N1 -137.9(2) 4 14_655
O2W Eu1 N1 N1 -43.99(12) 13_565 14_655
O2W Eu1 N1 N1 -51.64(13) 3 14_655
O2W Eu1 N1 N1 -122.56(13) 16 14_655
O2W Eu1 N1 N1 -156.9(2) 4 14_655
O2W Eu1 N1 N1 -157.13(17) 14_655 14_655
O2W Eu1 N1 N1 -28.6(2) . 14_655
O2W Eu1 N1 N1 -132.67(12) 2 14_655
O2W Eu1 N1 N1 -32.4(3) 15_665 14_655
N1 Eu1 N1 N1 158.45(8) 3 14_655
N1 Eu1 N1 N1 108.8(2) 13_565 14_655
N1 Eu1 N1 N1 162.71(6) 15_665 14_655
N1 Eu1 N1 N1 87.36(3) 2 14_655
N1 Eu1 N1 N1 16.28(7) 4 14_655
N1 Eu1 N1 N1 21.55(8) 16 14_655
O1W Eu1 N1 N1 87.36(3) . 14_655
O3W Eu1 N1 C1 -38.1(17) 3 .
O3W Eu1 N1 C1 -31.6(18) . .
O3W Eu1 N1 C1 -97.1(17) 2 .
O3W Eu1 N1 C1 -116.9(17) 4 .
O2W Eu1 N1 C1 -22.9(17) 13_565 .
O2W Eu1 N1 C1 -30.6(17) 3 .
O2W Eu1 N1 C1 -101.5(17) 16 .
O2W Eu1 N1 C1 -135.8(17) 4 .
O2W Eu1 N1 C1 -136.1(17) 14_655 .
O2W Eu1 N1 C1 -7.5(18) . .
O2W Eu1 N1 C1 -111.6(17) 2 .
O2W Eu1 N1 C1 -11.3(19) 15_665 .
N1 Eu1 N1 C1 179.5(17) 3 .
N1 Eu1 N1 C1 129.8(16) 13_565 .
N1 Eu1 N1 C1 -176.2(17) 15_665 .
N1 Eu1 N1 C1 108.4(17) 2 .
N1 Eu1 N1 C1 37.4(18) 4 .
N1 Eu1 N1 C1 21.1(17) 14_655 .
N1 Eu1 N1 C1 42.6(18) 16 .
O1W Eu1 N1 C1 108.4(17) . .
O3W Eu1 N1 C1 -53.4(5) 3 14_655
O3W Eu1 N1 C1 -46.9(6) . 14_655
O3W Eu1 N1 C1 -112.5(5) 2 14_655
O3W Eu1 N1 C1 -132.2(5) 4 14_655
O2W Eu1 N1 C1 -38.2(5) 13_565 14_655
O2W Eu1 N1 C1 -45.9(5) 3 14_655
O2W Eu1 N1 C1 -116.8(5) 16 14_655
O2W Eu1 N1 C1 -151.1(4) 4 14_655
O2W Eu1 N1 C1 -151.4(5) 14_655 14_655
O2W Eu1 N1 C1 -22.8(6) . 14_655
O2W Eu1 N1 C1 -126.9(5) 2 14_655
O2W Eu1 N1 C1 -26.6(6) 15_665 14_655
N1 Eu1 N1 C1 164.2(4) 3 14_655
N1 Eu1 N1 C1 114.5(4) 13_565 14_655
N1 Eu1 N1 C1 168.5(4) 15_665 14_655
N1 Eu1 N1 C1 93.1(5) 2 14_655
N1 Eu1 N1 C1 22.0(5) 4 14_655
N1 Eu1 N1 C1 5.8(5) 14_655 14_655
N1 Eu1 N1 C1 27.3(5) 16 14_655
O1W Eu1 N1 C1 93.1(5) . 14_655
N1 N1 C1 C1 0.0 14_655 14_655
Eu1 N1 C1 C1 -20.9(17) . 14_655
C1 N1 C1 N1 0.0 14_655 14_655
Eu1 N1 C1 N1 -20.9(17) . 14_655
C1 W1 C1 C1 -15.15(7) 8_556 14_655
C1 W1 C1 C1 87.74(3) 2_545 14_655
C1 W1 C1 C1 -18.88(9) 12_556 14_655
C1 W1 C1 C1 -160.98(9) 7_546 14_655
C1 W1 C1 C1 111.6(3) 13 14_655
C1 W1 C1 C1 -165.63(7) 11_656 14_655
C2 W1 C1 C1 -95.98(10) 7_546 14_655
C2 W1 C1 C1 52.77(9) 2_545 14_655
C2 W1 C1 C1 -79.05(10) 12_556 14_655
C2 W1 C1 C1 48.11(10) 14_655 14_655
C2 W1 C1 C1 -86.17(19) 8_556 14_655
C2 W1 C1 C1 -112.68(18) 11_656 14_655
C2 W1 C1 C1 127.47(10) . 14_655
C2 W1 C1 C1 126.02(9) 13 14_655
C1 W1 C1 N1 -13.7(4) 8_556 14_655
C1 W1 C1 N1 89.2(5) 2_545 14_655
C1 W1 C1 N1 -17.4(4) 12_556 14_655
C1 W1 C1 N1 -159.5(5) 7_546 14_655
C1 W1 C1 N1 113.1(5) 13 14_655
C1 W1 C1 N1 -164.2(5) 11_656 14_655
C1 W1 C1 N1 1.5(5) 14_655 14_655
C2 W1 C1 N1 -94.5(5) 7_546 14_655
C2 W1 C1 N1 54.2(5) 2_545 14_655
C2 W1 C1 N1 -77.6(5) 12_556 14_655
C2 W1 C1 N1 49.6(5) 14_655 14_655
C2 W1 C1 N1 -84.7(5) 8_556 14_655
C2 W1 C1 N1 -111.2(5) 11_656 14_655
C2 W1 C1 N1 128.9(5) . 14_655
C2 W1 C1 N1 127.5(5) 13 14_655
N2 N2 C2 C2 0.0 13 13
C2 N2 C2 N2 0.0 13 13
C1 W1 C2 C2 -88.97(19) 8_556 13
C1 W1 C2 C2 -16.24(9) 2_545 13
C1 W1 C2 C2 -112.39(18) 12_556 13
C1 W1 C2 C2 94.72(10) 7_546 13
C1 W1 C2 C2 -4.67(9) 13 13
C1 W1 C2 C2 -174.87(10) . 13
C1 W1 C2 C2 79.69(10) 11_656 13
C1 W1 C2 C2 -162.99(9) 14_655 13
C2 W1 C2 C2 138.61(4) 7_546 13
C2 W1 C2 C2 -79.47(11) 2_545 13
C2 W1 C2 C2 152.21(11) 12_556 13
C2 W1 C2 C2 -96.04(7) 14_655 13
C2 W1 C2 C2 36.60(4) 8_556 13
C2 W1 C2 C2 48.85(12) 11_656 13
C1 W1 C2 N2 -16.6(4) 2_545 13
C1 W1 C2 N2 -112.8(4) 12_556 13
C1 W1 C2 N2 94.3(4) 7_546 13
C1 W1 C2 N2 -5.1(4) 13 13
C1 W1 C2 N2 -175.3(4) . 13
C1 W1 C2 N2 79.3(4) 11_656 13
C1 W1 C2 N2 -163.4(4) 14_655 13
C2 W1 C2 N2 138.2(4) 7_546 13
C2 W1 C2 N2 -79.9(4) 2_545 13
C2 W1 C2 N2 151.8(4) 12_556 13
C2 W1 C2 N2 -96.4(4) 14_655 13
C2 W1 C2 N2 36.2(3) 8_556 13
C2 W1 C2 N2 48.4(3) 11_656 13
C2 W1 C2 N2 -0.4(4) 13 13
