#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:19:19 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179407 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/04/4330465.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4330465
loop_
_publ_author_name
'W. Adam Phelan'
'Michael J. Kangas'
'Gregory T. McCandless'
'Brenton L. Drake'
'Neel Haldolaarachchige'
'Liang L. Zhao'
'Jiakui K. Wang'
'Xiaoping P. Wang'
'David P. Young'
'Emilia Morosan'
'Christina Hoffmann'
'Julia Y. Chan'
_publ_section_title
;
 Synthesis, Structure, and Physical Properties of Ln(Cu,Al,Ga)13-x (Ln =
 La-Pr, and Eu) and Eu(Cu,Al)13-x
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              10193
_journal_page_last               10202
_journal_paper_doi               10.1021/ic301024t
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'Al4.42 Cu5.87 Eu Ga2.48'
_chemical_formula_sum            'Al4.42 Cu5.87 Eu Ga2.48'
_chemical_formula_weight         816.89
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           226
_symmetry_cell_setting           cubic
_symmetry_space_group_name_Hall  '-F 4a 2 3'
_symmetry_space_group_name_H-M   'F m -3 c'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   11.932(5)
_cell_length_b                   11.932(5)
_cell_length_c                   11.932(5)
_cell_measurement_reflns_used    227
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      30.034
_cell_measurement_theta_min      0.998
_cell_volume                     1698.8(12)
_computing_cell_refinement       'Denzo and Scalepack (otwinski & Minor 1999)'
_computing_data_collection       'Collect (Nonius 1999)'
_computing_data_reduction        'Denzo and Scalepack (otwinski & Minor 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR 97'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0383
_diffrn_reflns_av_sigmaI/netI    0.0490
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            349
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         29.89
_diffrn_reflns_theta_min         3.41
_exptl_absorpt_coefficient_mu    29.748
_exptl_absorpt_correction_T_max  0.7074
_exptl_absorpt_correction_T_min  0.1805
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'HKL scalepack(Otwinski & Minor, 1997)'
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    6.388
_exptl_crystal_description       cube
_exptl_crystal_F_000             2940
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.01
_refine_diff_density_max         1.271
_refine_diff_density_min         -0.690
_refine_diff_density_rms         0.206
_refine_ls_extinction_coef       0.00096(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.125
_refine_ls_matrix_type           full
_refine_ls_number_parameters     14
_refine_ls_number_reflns         124
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.105
_refine_ls_R_factor_all          0.0314
_refine_ls_R_factor_gt           0.0253
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0077P)²+10.1258P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0470
_refine_ls_wR_factor_ref         0.0481
_reflns_number_gt                108
_reflns_number_total             124
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic301024t_si_002_08.cif
_cod_data_source_block           shelxl
_cod_database_code               4330465
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, z+1/2, y'
'y, -z, x'
'y, x, -z+1/2'
'x, -z, y+1/2'
'-z, y, x+1/2'
'z, x, -y'
'y, z, -x'
'z+1/2, y, -x'
'-z, x, -y'
'x, z+1/2, -y'
'y, -z, -x'
'x, -z, -y+1/2'
'-z, y, -x+1/2'
'x, -y, z'
'y, -x, z+1/2'
'x, -y, -z'
'y, -x+1/2, -z'
'-y, -z, -x'
'-x, -y, z'
'-y, -x+1/2, -z'
'-z, -x, -y'
'-z+1/2, -y, -x'
'z, -x, -y'
'x, y+1/2, z+1/2'
'x, z+1, y+1/2'
'y, -z+1/2, x+1/2'
'y, x+1/2, -z+1'
'x, -z+1/2, y+1'
'-z, y+1/2, x+1'
'z, x+1/2, -y+1/2'
'y, z+1/2, -x+1/2'
'z+1/2, y+1/2, -x+1/2'
'-z, x+1/2, -y+1/2'
'x, z+1, -y+1/2'
'y, -z+1/2, -x+1/2'
'x, -z+1/2, -y+1'
'-z, y+1/2, -x+1'
'x, -y+1/2, z+1/2'
'y, -x+1/2, z+1'
'x, -y+1/2, -z+1/2'
'y, -x+1, -z+1/2'
'-y, -z+1/2, -x+1/2'
'-x, -y+1/2, z+1/2'
'-y, -x+1, -z+1/2'
'-z, -x+1/2, -y+1/2'
'-z+1/2, -y+1/2, -x+1/2'
'z, -x+1/2, -y+1/2'
'x+1/2, y, z+1/2'
'x+1/2, z+1/2, y+1/2'
'y+1/2, -z, x+1/2'
'y+1/2, x, -z+1'
'x+1/2, -z, y+1'
'-z+1/2, y, x+1'
'z+1/2, x, -y+1/2'
'y+1/2, z, -x+1/2'
'z+1, y, -x+1/2'
'-z+1/2, x, -y+1/2'
'x+1/2, z+1/2, -y+1/2'
'y+1/2, -z, -x+1/2'
'x+1/2, -z, -y+1'
'-z+1/2, y, -x+1'
'x+1/2, -y, z+1/2'
'y+1/2, -x, z+1'
'x+1/2, -y, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, -z, -x+1/2'
'-x+1/2, -y, z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-z+1/2, -x, -y+1/2'
'-z+1, -y, -x+1/2'
'z+1/2, -x, -y+1/2'
'x+1/2, y+1/2, z'
'x+1/2, z+1, y'
'y+1/2, -z+1/2, x'
'y+1/2, x+1/2, -z+1/2'
'x+1/2, -z+1/2, y+1/2'
'-z+1/2, y+1/2, x+1/2'
'z+1/2, x+1/2, -y'
'y+1/2, z+1/2, -x'
'z+1, y+1/2, -x'
'-z+1/2, x+1/2, -y'
'x+1/2, z+1, -y'
'y+1/2, -z+1/2, -x'
'x+1/2, -z+1/2, -y+1/2'
'-z+1/2, y+1/2, -x+1/2'
'x+1/2, -y+1/2, z'
'y+1/2, -x+1/2, z+1/2'
'x+1/2, -y+1/2, -z'
'y+1/2, -x+1, -z'
'-y+1/2, -z+1/2, -x'
'-x+1/2, -y+1/2, z'
'-y+1/2, -x+1, -z'
'-z+1/2, -x+1/2, -y'
'-z+1, -y+1/2, -x'
'z+1/2, -x+1/2, -y'
'-x, -y, -z'
'-x, -z-1/2, -y'
'-y, z, -x'
'-y, -x, z-1/2'
'-x, z, -y-1/2'
'z, -y, -x-1/2'
'-z, -x, y'
'-y, -z, x'
'-z-1/2, -y, x'
'z, -x, y'
'-x, -z-1/2, y'
'-y, z, x'
'-x, z, y-1/2'
'z, -y, x-1/2'
'-x, y, -z'
'-y, x, -z-1/2'
'-x, y, z'
'-y, x-1/2, z'
'y, z, x'
'x, y, -z'
'y, x-1/2, z'
'z, x, y'
'z-1/2, y, x'
'-z, x, y'
'-x, -y+1/2, -z+1/2'
'-x, -z, -y+1/2'
'-y, z+1/2, -x+1/2'
'-y, -x+1/2, z'
'-x, z+1/2, -y'
'z, -y+1/2, -x'
'-z, -x+1/2, y+1/2'
'-y, -z+1/2, x+1/2'
'-z-1/2, -y+1/2, x+1/2'
'z, -x+1/2, y+1/2'
'-x, -z, y+1/2'
'-y, z+1/2, x+1/2'
'-x, z+1/2, y'
'z, -y+1/2, x'
'-x, y+1/2, -z+1/2'
'-y, x+1/2, -z'
'-x, y+1/2, z+1/2'
'-y, x, z+1/2'
'y, z+1/2, x+1/2'
'x, y+1/2, -z+1/2'
'y, x, z+1/2'
'z, x+1/2, y+1/2'
'z-1/2, y+1/2, x+1/2'
'-z, x+1/2, y+1/2'
'-x+1/2, -y, -z+1/2'
'-x+1/2, -z-1/2, -y+1/2'
'-y+1/2, z, -x+1/2'
'-y+1/2, -x, z'
'-x+1/2, z, -y'
'z+1/2, -y, -x'
'-z+1/2, -x, y+1/2'
'-y+1/2, -z, x+1/2'
'-z, -y, x+1/2'
'z+1/2, -x, y+1/2'
'-x+1/2, -z-1/2, y+1/2'
'-y+1/2, z, x+1/2'
'-x+1/2, z, y'
'z+1/2, -y, x'
'-x+1/2, y, -z+1/2'
'-y+1/2, x, -z'
'-x+1/2, y, z+1/2'
'-y+1/2, x-1/2, z+1/2'
'y+1/2, z, x+1/2'
'x+1/2, y, -z+1/2'
'y+1/2, x-1/2, z+1/2'
'z+1/2, x, y+1/2'
'z, y, x+1/2'
'-z+1/2, x, y+1/2'
'-x+1/2, -y+1/2, -z'
'-x+1/2, -z, -y'
'-y+1/2, z+1/2, -x'
'-y+1/2, -x+1/2, z-1/2'
'-x+1/2, z+1/2, -y-1/2'
'z+1/2, -y+1/2, -x-1/2'
'-z+1/2, -x+1/2, y'
'-y+1/2, -z+1/2, x'
'-z, -y+1/2, x'
'z+1/2, -x+1/2, y'
'-x+1/2, -z, y'
'-y+1/2, z+1/2, x'
'-x+1/2, z+1/2, y-1/2'
'z+1/2, -y+1/2, x-1/2'
'-x+1/2, y+1/2, -z'
'-y+1/2, x+1/2, -z-1/2'
'-x+1/2, y+1/2, z'
'-y+1/2, x, z'
'y+1/2, z+1/2, x'
'x+1/2, y+1/2, -z'
'y+1/2, x, z'
'z+1/2, x+1/2, y'
'z, y+1/2, x'
'-z+1/2, x+1/2, y'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.2500 0.2500 0.2500 0.0134(4) Uani 1 24 d S
Cu1 Cu 0.0000 0.0000 0.0000 0.0108(7) Uani 0.7675(1) 24 d SP
Cu2 Cu 0.11891(8) 0.17763(7) 0.0000 0.0183(4) Uani 0.4252(1) 2 d SP
Al2 Al 0.11891(8) 0.17763(7) 0.0000 0.0183(4) Uani 0.3681(1) 2 d SP
Ga2 Ga 0.11891(8) 0.17763(7) 0.0000 0.0183(4) Uani 0.2067(1) 2 d SP
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ga2 Eu1 Al2 0.00(3) 174_556 174_556
Ga2 Eu1 Cu2 0.00(3) 174_556 174_556
Al2 Eu1 Cu2 0.00(3) 174_556 174_556
Ga2 Eu1 Cu2 146.46(3) 174_556 .
Al2 Eu1 Cu2 146.46(3) 174_556 .
Cu2 Eu1 Cu2 146.46(3) 174_556 .
Ga2 Eu1 Ga2 163.62(3) 174_556 118
Al2 Eu1 Ga2 163.62(3) 174_556 118
Cu2 Eu1 Ga2 163.62(3) 174_556 118
Cu2 Eu1 Ga2 44.71(2) . 118
Ga2 Eu1 Cu2 128.94(3) 174_556 3
Al2 Eu1 Cu2 128.94(3) 174_556 3
Cu2 Eu1 Cu2 128.94(3) 174_556 3
Cu2 Eu1 Cu2 44.71(2) . 3
Ga2 Eu1 Cu2 44.71(2) 118 3
Ga2 Eu1 Ga2 44.71(2) 174_556 172_556
Al2 Eu1 Ga2 44.71(2) 174_556 172_556
Cu2 Eu1 Ga2 44.71(2) 174_556 172_556
Cu2 Eu1 Ga2 163.62(3) . 172_556
Ga2 Eu1 Ga2 128.94(3) 118 172_556
Cu2 Eu1 Ga2 146.46(3) 3 172_556
Ga2 Eu1 Ga2 128.94(3) 174_556 3
Al2 Eu1 Ga2 128.94(3) 174_556 3
Cu2 Eu1 Ga2 128.94(3) 174_556 3
Cu2 Eu1 Ga2 44.71(2) . 3
Ga2 Eu1 Ga2 44.71(2) 118 3
Cu2 Eu1 Ga2 0.00(4) 3 3
Ga2 Eu1 Ga2 146.46(3) 172_556 3
Ga2 Eu1 Cu2 44.71(2) 174_556 172_556
Al2 Eu1 Cu2 44.71(2) 174_556 172_556
Cu2 Eu1 Cu2 44.71(2) 174_556 172_556
Cu2 Eu1 Cu2 163.62(3) . 172_556
Ga2 Eu1 Cu2 128.94(3) 118 172_556
Cu2 Eu1 Cu2 146.46(3) 3 172_556
Ga2 Eu1 Cu2 0.0 172_556 172_556
Ga2 Eu1 Cu2 146.46(3) 3 172_556
Ga2 Eu1 Ga2 44.71(2) 174_556 146_565
Al2 Eu1 Ga2 44.71(2) 174_556 146_565
Cu2 Eu1 Ga2 44.71(2) 174_556 146_565
Cu2 Eu1 Ga2 128.94(3) . 146_565
Ga2 Eu1 Ga2 146.46(3) 118 146_565
Cu2 Eu1 Ga2 163.62(3) 3 146_565
Ga2 Eu1 Ga2 44.71(2) 172_556 146_565
Ga2 Eu1 Ga2 163.62(3) 3 146_565
Cu2 Eu1 Ga2 44.71(2) 172_556 146_565
Ga2 Cu1 Ga2 62.466(9) 22 99
Ga2 Cu1 Ga2 62.466(9) 22 97
Ga2 Cu1 Ga2 62.466(9) 99 97
Ga2 Cu1 Al2 0.00(4) 22 22
Ga2 Cu1 Al2 62.466(9) 99 22
Ga2 Cu1 Al2 62.466(9) 97 22
Ga2 Cu1 Cu2 62.466(9) 22 97
Ga2 Cu1 Cu2 62.466(9) 99 97
Ga2 Cu1 Cu2 0.00(4) 97 97
Al2 Cu1 Cu2 62.466(9) 22 97
Ga2 Cu1 Al2 62.466(9) 22 99
Ga2 Cu1 Al2 0.00(4) 99 99
Ga2 Cu1 Al2 62.466(9) 97 99
Al2 Cu1 Al2 62.466(9) 22 99
Cu2 Cu1 Al2 62.466(9) 97 99
Ga2 Cu1 Cu2 62.466(9) 22 99
Ga2 Cu1 Cu2 0.00(4) 99 99
Ga2 Cu1 Cu2 62.466(9) 97 99
Al2 Cu1 Cu2 62.466(9) 22 99
Cu2 Cu1 Cu2 62.466(9) 97 99
Al2 Cu1 Cu2 0.00(4) 99 99
Ga2 Cu1 Al2 62.466(9) 22 97
Ga2 Cu1 Al2 62.466(9) 99 97
Ga2 Cu1 Al2 0.00(4) 97 97
Al2 Cu1 Al2 62.466(9) 22 97
Cu2 Cu1 Al2 0.00(4) 97 97
Al2 Cu1 Al2 62.466(9) 99 97
Cu2 Cu1 Al2 62.466(9) 99 97
Ga2 Cu1 Cu2 0.00(4) 22 22
Ga2 Cu1 Cu2 62.466(9) 99 22
Ga2 Cu1 Cu2 62.466(9) 97 22
Al2 Cu1 Cu2 0.00(4) 22 22
Cu2 Cu1 Cu2 62.466(9) 97 22
Al2 Cu1 Cu2 62.466(9) 99 22
Cu2 Cu1 Cu2 62.466(9) 99 22
Al2 Cu1 Cu2 62.466(9) 97 22
Ga2 Cu1 Ga2 180.0 22 118
Ga2 Cu1 Ga2 117.534(9) 99 118
Ga2 Cu1 Ga2 117.534(9) 97 118
Al2 Cu1 Ga2 180.0 22 118
Cu2 Cu1 Ga2 117.534(9) 97 118
Al2 Cu1 Ga2 117.534(9) 99 118
Cu2 Cu1 Ga2 117.534(9) 99 118
Al2 Cu1 Ga2 117.534(9) 97 118
Cu2 Cu1 Ga2 180.0 22 118
Ga2 Cu1 Ga2 117.534(9) 22 3
Ga2 Cu1 Ga2 180.00(3) 99 3
Ga2 Cu1 Ga2 117.534(9) 97 3
Al2 Cu1 Ga2 117.534(9) 22 3
Cu2 Cu1 Ga2 117.534(9) 97 3
Al2 Cu1 Ga2 180.00(3) 99 3
Cu2 Cu1 Ga2 180.00(3) 99 3
Al2 Cu1 Ga2 117.534(9) 97 3
Cu2 Cu1 Ga2 117.534(9) 22 3
Ga2 Cu1 Ga2 62.466(9) 118 3
Ga2 Cu1 Al2 180.0 22 118
Ga2 Cu1 Al2 117.534(9) 99 118
Ga2 Cu1 Al2 117.534(9) 97 118
Al2 Cu1 Al2 180.0 22 118
Cu2 Cu1 Al2 117.534(9) 97 118
Al2 Cu1 Al2 117.534(9) 99 118
Cu2 Cu1 Al2 117.534(9) 99 118
Al2 Cu1 Al2 117.534(9) 97 118
Cu2 Cu1 Al2 180.0 22 118
Ga2 Cu1 Al2 0.00(4) 118 118
Ga2 Cu1 Al2 62.466(9) 3 118
Ga2 Cu2 Al2 0.000(11) 40_554 40_554
Ga2 Cu2 Cu2 0.000(11) 40_554 40_554
Al2 Cu2 Cu2 0.000(11) 40_554 40_554
Ga2 Cu2 Ga2 90.0 40_554 160
Al2 Cu2 Ga2 90.0 40_554 160
Cu2 Cu2 Ga2 90.0 40_554 160
Ga2 Cu2 Al2 90.0 40_554 160
Al2 Cu2 Al2 90.0 40_554 160
Cu2 Cu2 Al2 90.0 40_554 160
Ga2 Cu2 Al2 0.00(4) 160 160
Ga2 Cu2 Cu2 90.0 40_554 160
Al2 Cu2 Cu2 90.0 40_554 160
Cu2 Cu2 Cu2 90.0 40_554 160
Ga2 Cu2 Cu2 0.00(4) 160 160
Al2 Cu2 Cu2 0.00(4) 160 160
Ga2 Cu2 Cu1 162.30(5) 40_554 .
Al2 Cu2 Cu1 162.30(5) 40_554 .
Cu2 Cu2 Cu1 162.30(5) 40_554 .
Ga2 Cu2 Cu1 107.70(5) 160 .
Al2 Cu2 Cu1 107.70(5) 160 .
Cu2 Cu2 Cu1 107.70(5) 160 .
Ga2 Cu2 Ga2 113.78(3) 40_554 7
Al2 Cu2 Ga2 113.78(3) 40_554 7
Cu2 Cu2 Ga2 113.78(3) 40_554 7
Ga2 Cu2 Ga2 116.23(4) 160 7
Al2 Cu2 Ga2 116.23(4) 160 7
Cu2 Cu2 Ga2 116.23(4) 160 7
Cu1 Cu2 Ga2 58.767(4) . 7
Ga2 Cu2 Al2 113.78(3) 40_554 7
Al2 Cu2 Al2 113.78(3) 40_554 7
Cu2 Cu2 Al2 113.78(3) 40_554 7
Ga2 Cu2 Al2 116.23(4) 160 7
Al2 Cu2 Al2 116.23(4) 160 7
Cu2 Cu2 Al2 116.23(4) 160 7
Cu1 Cu2 Al2 58.767(4) . 7
Ga2 Cu2 Al2 0.00(2) 7 7
Ga2 Cu2 Cu2 113.78(3) 40_554 7
Al2 Cu2 Cu2 113.78(3) 40_554 7
Cu2 Cu2 Cu2 113.78(3) 40_554 7
Ga2 Cu2 Cu2 116.23(4) 160 7
Al2 Cu2 Cu2 116.23(4) 160 7
Cu2 Cu2 Cu2 116.23(4) 160 7
Cu1 Cu2 Cu2 58.767(4) . 7
Ga2 Cu2 Cu2 0.00(2) 7 7
Al2 Cu2 Cu2 0.00(2) 7 7
Ga2 Cu2 Ga2 134.14(2) 40_554 8
Al2 Cu2 Ga2 134.14(2) 40_554 8
Cu2 Cu2 Ga2 134.14(2) 40_554 8
Ga2 Cu2 Ga2 61.53(5) 160 8
Al2 Cu2 Ga2 61.53(5) 160 8
Cu2 Cu2 Ga2 61.53(5) 160 8
Cu1 Cu2 Ga2 58.767(4) . 8
Ga2 Cu2 Ga2 60.0 7 8
Al2 Cu2 Ga2 60.0 7 8
Cu2 Cu2 Ga2 60.0 7 8
Ga2 Cu2 Cu2 134.14(2) 40_554 8
Al2 Cu2 Cu2 134.14(2) 40_554 8
Cu2 Cu2 Cu2 134.14(2) 40_554 8
Ga2 Cu2 Cu2 61.53(5) 160 8
Al2 Cu2 Cu2 61.53(5) 160 8
Cu2 Cu2 Cu2 61.53(5) 160 8
Cu1 Cu2 Cu2 58.767(4) . 8
Ga2 Cu2 Cu2 60.0 7 8
Al2 Cu2 Cu2 60.0 7 8
Cu2 Cu2 Cu2 60.0 7 8
Ga2 Cu2 Cu2 0.00(5) 8 8
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Ga2 3.4772(15) 174_556
Eu1 Al2 3.4772(15) 174_556
Eu1 Cu2 3.4772(15) 174_556
Eu1 Cu2 3.4772(15) .
Eu1 Ga2 3.4772(15) 118
Eu1 Cu2 3.4772(15) 3
Eu1 Ga2 3.4772(15) 172_556
Eu1 Ga2 3.4772(15) 3
Eu1 Cu2 3.4772(15) 172_556
Eu1 Ga2 3.4772(15) 146_565
Cu1 Ga2 2.5505(14) 22
Cu1 Ga2 2.5505(14) 99
Cu1 Ga2 2.5505(14) 97
Cu1 Al2 2.5505(14) 22
Cu1 Cu2 2.5505(14) 97
Cu1 Al2 2.5505(14) 99
Cu1 Cu2 2.5505(14) 99
Cu1 Al2 2.5505(14) 97
Cu1 Cu2 2.5505(14) 22
Cu1 Ga2 2.5505(14) 118
Cu1 Ga2 2.5505(14) 3
Cu1 Al2 2.5505(14) 118
Cu2 Ga2 2.5268(16) 40_554
Cu2 Al2 2.5268(16) 40_554
Cu2 Cu2 2.5268(16) 40_554
Cu2 Ga2 2.5268(17) 160
Cu2 Al2 2.5268(17) 160
Cu2 Cu2 2.5268(17) 160
Cu2 Ga2 2.6450(15) 7
Cu2 Al2 2.6450(15) 7
Cu2 Cu2 2.6450(15) 7
Cu2 Ga2 2.6450(15) 8
Cu2 Cu2 2.6450(15) 8
