#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:34:16 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179413 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/10/4331023.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4331023
loop_
_publ_author_name
'Philip A. Smith'
'Carlos Crawford'
'Nuquie Beedoe'
'Zerihun Assefa'
'Richard E. Sykora'
_publ_contact_author_address
;University of South Alabama
Department of Chemistry
Chemistry Building, Room 223
Mobile  AL  36688-0002
;
_publ_contact_author_email       rsykora@southalabama.edu
_publ_contact_author_fax         1(251)4607359
_publ_contact_author_name        'Richard E. Sykora'
_publ_contact_author_phone       1(251)4607422
_publ_section_title
;
 Synthesis, Crystal Structures, and Dual Donor Luminescence Sensitization
 in Novel Terbium Tetracyanoplatinates
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              12230
_journal_page_last               12241
_journal_paper_doi               10.1021/ic3013975
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety
;
2(C19 H21 N3 O6 Tb), C4 N4 Pt, 4(H2 O)
;
_chemical_formula_sum            'C42 H50 N10 O16 Pt Tb2'
_chemical_formula_weight         1463.85
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.848(2)
_cell_angle_beta                 92.169(2)
_cell_angle_gamma                118.076(2)
_cell_formula_units_Z            2
_cell_length_a                   12.0947(2)
_cell_length_b                   12.7430(3)
_cell_length_c                   18.6790(3)
_cell_measurement_reflns_used    31479
_cell_measurement_temperature    290(2)
_cell_measurement_theta_max      25.6245
_cell_measurement_theta_min      3.1962
_cell_volume                     2530.82(10)
_computing_cell_refinement
'CrysAlisPro Oxford Diffraction, (2010)'
_computing_data_collection
'CrysAlisPro Oxford Diffraction, (2010)'
_computing_data_reduction
'CrysAlisPro Oxford Diffraction, (2010)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2008)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      290(2)
_diffrn_detector_area_resol_mean 16.0514
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Oxford Excalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0241
_diffrn_reflns_av_sigmaI/netI    0.0207
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            48688
_diffrn_reflns_theta_full        25.68
_diffrn_reflns_theta_max         25.68
_diffrn_reflns_theta_min         3.20
_exptl_absorpt_coefficient_mu    5.597
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.56600
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrysAlisPro
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.921
_exptl_crystal_description       prism
_exptl_crystal_F_000             1416
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.709
_refine_diff_density_min         -0.664
_refine_diff_density_rms         0.065
_refine_ls_extinction_coef       0.00030(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.994
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     654
_refine_ls_number_reflns         9604
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.994
_refine_ls_R_factor_all          0.0218
_refine_ls_R_factor_gt           0.0165
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0223P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0381
_refine_ls_wR_factor_ref         0.0387
_reflns_number_gt                8243
_reflns_number_total             9604
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            ic3013975_si_001_5.cif
_cod_data_source_block           3
_cod_database_code               4331023
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Tb1 Tb 0.881125(10) 0.741736(10) 0.399078(6) 0.02284(4) Uani 1 1 d .
Tb2 Tb 0.146637(11) 0.392709(12) 0.094719(7) 0.02903(4) Uani 1 1 d .
Pt1 Pt 0.519441(9) 0.042891(9) 0.260955(6) 0.03314(4) Uani 1 1 d .
O1 O 1.02565(17) 0.67406(17) 0.36173(11) 0.0405(5) Uani 1 1 d .
O2 O 0.98081(17) 0.76990(17) 0.28121(10) 0.0386(5) Uani 1 1 d .
O3 O 0.68526(17) 0.69412(17) 0.44805(11) 0.0419(5) Uani 1 1 d .
O4 O 0.83393(15) 0.87062(16) 0.48790(10) 0.0324(4) Uani 1 1 d .
O5 O 0.82119(19) 0.86845(18) 0.33573(10) 0.0428(5) Uani 1 1 d .
H5A H 0.8286 0.8621 0.2909 0.064 Uiso 1 1 d .
H5B H 0.7862 0.9080 0.3521 0.064 Uiso 1 1 d .
O6 O 1.07660(15) 0.91711(15) 0.42285(10) 0.0322(4) Uani 1 1 d .
H6A H 1.1361 0.9071 0.4068 0.048 Uiso 1 1 d .
H6B H 1.1022 0.9798 0.4509 0.048 Uiso 1 1 d .
O7 O -0.00500(17) 0.47516(18) 0.08903(10) 0.0398(5) Uani 1 1 d .
O8 O 0.01848(18) 0.4002(2) 0.18754(10) 0.0439(5) Uani 1 1 d .
O9 O 0.35015(19) 0.4272(2) 0.06355(12) 0.0571(6) Uani 1 1 d .
O10 O 0.19629(19) 0.2489(2) 0.03245(11) 0.0499(6) Uani 1 1 d .
O11 O 0.09739(19) 0.3895(2) -0.03036(10) 0.0483(5) Uani 1 1 d .
H11A H 0.0909 0.3262 -0.0517 0.072 Uiso 1 1 d .
H11B H 0.0517 0.4199 -0.0443 0.072 Uiso 1 1 d .
O12 O -0.05139(17) 0.21090(19) 0.07522(11) 0.0480(5) Uani 1 1 d .
H12B H -0.0557 0.1665 0.0386 0.072 Uiso 1 1 d .
H12C H -0.1107 0.1819 0.1032 0.072 Uiso 1 1 d .
O13 O 0.0506(3) 0.2011(3) 0.86724(14) 0.0984(10) Uani 1 1 d .
H13A H -0.0267 0.1806 0.8708 0.148 Uiso 1 1 d .
H13B H 0.0483 0.2245 0.8257 0.148 Uiso 1 1 d .
O14 O 0.7919(2) 0.9021(2) 0.19229(13) 0.0761(8) Uani 1 1 d .
H14A H 0.7789 0.9510 0.1686 0.114 Uiso 1 1 d .
H14B H 0.8400 0.8844 0.1684 0.114 Uiso 1 1 d .
O15 O 0.1413(3) 0.9743(4) 0.04268(18) 0.1381(16) Uani 1 1 d .
H15A H 0.1620 0.9237 0.0577 0.207 Uiso 1 1 d .
H15B H 0.1991 1.0288 0.0706 0.207 Uiso 1 1 d .
O16 O 0.1080(9) 1.0693(8) -0.0535(5) 0.178(4) Uani 0.50 1 d P
H16A H 0.1447 1.0315 -0.0377 0.267 Uiso 0.50 1 d P
H16B H 0.0408 1.0347 -0.0807 0.267 Uiso 0.50 1 d P
O17 O 0.4654(6) 0.4822(7) 0.4685(4) 0.155(4) Uani 0.50 1 d P
H17D H 0.5077 0.4453 0.4743 0.233 Uiso 0.50 1 d P
H17E H 0.4407 0.5048 0.5053 0.233 Uiso 0.50 1 d P
N1 N 0.94975(19) 0.71130(19) 0.52342(12) 0.0316(5) Uani 1 1 d .
N2 N 0.79312(18) 0.52481(18) 0.43241(12) 0.0294(5) Uani 1 1 d .
N3 N 0.72097(19) 0.5800(2) 0.30701(12) 0.0326(5) Uani 1 1 d .
N4 N 0.2705(2) 0.6178(2) 0.08233(14) 0.0478(7) Uani 1 1 d .
N5 N 0.29766(18) 0.51754(19) 0.20067(11) 0.0292(5) Uani 1 1 d .
N6 N 0.1740(2) 0.2784(2) 0.19462(12) 0.0338(5) Uani 1 1 d .
N7 N 0.7485(3) 0.1218(3) 0.16566(16) 0.0636(8) Uani 1 1 d .
N8 N 0.3649(3) 0.0840(3) 0.13755(19) 0.0856(11) Uani 1 1 d .
N9 N 0.2909(2) -0.0470(3) 0.35668(17) 0.0650(9) Uani 1 1 d .
N10 N 0.6629(2) -0.0331(3) 0.37267(15) 0.0544(7) Uani 1 1 d .
C1 C 1.0206(3) 0.8052(3) 0.56939(15) 0.0404(7) Uani 1 1 d .
H1 H 1.0423 0.8809 0.5551 0.048 Uiso 1 1 calc R
C2 C 1.0635(3) 0.7957(3) 0.63688(16) 0.0453(8) Uani 1 1 d .
H2 H 1.1122 0.8633 0.6676 0.054 Uiso 1 1 calc R
C3 C 1.0321(3) 0.6838(3) 0.65756(17) 0.0521(9) Uani 1 1 d .
H3 H 1.0602 0.6745 0.7026 0.062 Uiso 1 1 calc R
C4 C 0.9596(3) 0.5866(3) 0.61167(17) 0.0476(8) Uani 1 1 d .
H4 H 0.9382 0.5105 0.6252 0.057 Uiso 1 1 calc R
C5 C 0.9175(2) 0.6015(2) 0.54446(15) 0.0326(6) Uani 1 1 d .
C6 C 0.8356(2) 0.4994(2) 0.49333(15) 0.0328(6) Uani 1 1 d .
C7 C 0.8025(3) 0.3821(3) 0.50832(18) 0.0467(8) Uani 1 1 d .
H7 H 0.8326 0.3664 0.5508 0.056 Uiso 1 1 calc R
C8 C 0.7252(3) 0.2912(3) 0.4594(2) 0.0548(9) Uani 1 1 d .
H8 H 0.7041 0.2129 0.4678 0.066 Uiso 1 1 calc R
C9 C 0.6791(3) 0.3149(3) 0.39831(19) 0.0479(8) Uani 1 1 d .
H9 H 0.6249 0.2530 0.3654 0.057 Uiso 1 1 calc R
C10 C 0.7137(2) 0.4329(2) 0.38541(16) 0.0347(7) Uani 1 1 d .
C11 C 0.6663(2) 0.4639(2) 0.31979(15) 0.0328(6) Uani 1 1 d .
C12 C 0.5734(3) 0.3774(3) 0.27286(18) 0.0483(8) Uani 1 1 d .
H12 H 0.5358 0.2980 0.2835 0.058 Uiso 1 1 calc R
C13 C 0.5368(3) 0.4086(3) 0.21075(19) 0.0547(9) Uani 1 1 d .
H13 H 0.4745 0.3509 0.1788 0.066 Uiso 1 1 calc R
C14 C 0.5938(3) 0.5268(3) 0.19635(17) 0.0499(8) Uani 1 1 d .
H14 H 0.5723 0.5507 0.1542 0.060 Uiso 1 1 calc R
C15 C 0.6835(3) 0.6082(3) 0.24609(16) 0.0425(7) Uani 1 1 d .
H15 H 0.7205 0.6883 0.2368 0.051 Uiso 1 1 calc R
C16 C 1.0408(3) 0.7163(3) 0.30105(17) 0.0379(7) Uani 1 1 d .
C17 C 1.1318(3) 0.7033(3) 0.25348(19) 0.0621(10) Uani 1 1 d .
H17A H 1.1144 0.7157 0.2049 0.093 Uiso 1 1 calc R
H17B H 1.1230 0.6246 0.2553 0.093 Uiso 1 1 calc R
H17C H 1.2160 0.7613 0.2698 0.093 Uiso 1 1 calc R
C18 C 0.7203(2) 0.7925(3) 0.48432(14) 0.0322(6) Uani 1 1 d .
C19 C 0.6240(3) 0.8138(3) 0.52084(17) 0.0469(8) Uani 1 1 d .
H19A H 0.6242 0.7962 0.5702 0.070 Uiso 1 1 calc R
H19B H 0.5425 0.7630 0.4973 0.070 Uiso 1 1 calc R
H19C H 0.6434 0.8957 0.5184 0.070 Uiso 1 1 calc R
C20 C 0.2586(3) 0.6659(4) 0.0225(2) 0.0766(13) Uani 1 1 d .
H20 H 0.1956 0.6173 -0.0123 0.092 Uiso 1 1 calc R
C21 C 0.3339(3) 0.7827(4) 0.0093(2) 0.0724(12) Uani 1 1 d .
H21 H 0.3208 0.8127 -0.0327 0.087 Uiso 1 1 calc R
C22 C 0.4268(4) 0.8523(3) 0.0585(2) 0.0707(11) Uani 1 1 d .
H22 H 0.4809 0.9313 0.0506 0.085 Uiso 1 1 calc R
C23 C 0.4410(3) 0.8056(3) 0.12037(19) 0.0613(10) Uani 1 1 d .
H23 H 0.5053 0.8528 0.1548 0.074 Uiso 1 1 calc R
C24 C 0.3601(2) 0.6886(3) 0.13170(16) 0.0369(7) Uani 1 1 d .
C25 C 0.3676(2) 0.6365(2) 0.19924(15) 0.0343(6) Uani 1 1 d .
C26 C 0.4418(3) 0.7070(3) 0.25930(18) 0.0514(9) Uani 1 1 d .
H26 H 0.4905 0.7889 0.2571 0.062 Uiso 1 1 calc R
C27 C 0.4427(3) 0.6559(3) 0.32069(19) 0.0613(10) Uani 1 1 d .
H27 H 0.4907 0.7024 0.3614 0.074 Uiso 1 1 calc R
C28 C 0.3724(3) 0.5347(3) 0.32259(17) 0.0515(9) Uani 1 1 d .
H28 H 0.3718 0.4983 0.3647 0.062 Uiso 1 1 calc R
C29 C 0.3023(2) 0.4669(3) 0.26120(15) 0.0338(6) Uani 1 1 d .
C30 C 0.2344(2) 0.3348(3) 0.25750(14) 0.0326(6) Uani 1 1 d .
C31 C 0.2369(3) 0.2724(3) 0.31489(18) 0.0553(9) Uani 1 1 d .
H31 H 0.2786 0.3131 0.3584 0.066 Uiso 1 1 calc R
C32 C 0.1786(4) 0.1514(3) 0.3082(2) 0.0665(11) Uani 1 1 d .
H32 H 0.1798 0.1091 0.3471 0.080 Uiso 1 1 calc R
C33 C 0.1183(3) 0.0921(3) 0.2442(2) 0.0582(9) Uani 1 1 d .
H33 H 0.0789 0.0093 0.2380 0.070 Uiso 1 1 calc R
C34 C 0.1180(3) 0.1597(3) 0.18886(18) 0.0484(8) Uani 1 1 d .
H34 H 0.0763 0.1202 0.1451 0.058 Uiso 1 1 calc R
C35 C -0.0395(3) 0.4407(3) 0.15083(15) 0.0363(7) Uani 1 1 d .
C36 C -0.1506(3) 0.4460(3) 0.17971(18) 0.0556(9) Uani 1 1 d .
H36A H -0.1598 0.5095 0.1595 0.083 Uiso 1 1 calc R
H36B H -0.1384 0.4602 0.2311 0.083 Uiso 1 1 calc R
H36C H -0.2250 0.3716 0.1671 0.083 Uiso 1 1 calc R
C37 C 0.3109(3) 0.3248(4) 0.03245(17) 0.0502(9) Uani 1 1 d .
C38 C 0.4010(3) 0.2926(4) -0.0029(2) 0.0820(13) Uani 1 1 d .
H38A H 0.4299 0.2537 0.0300 0.123 Uiso 1 1 calc R
H38B H 0.4714 0.3636 -0.0164 0.123 Uiso 1 1 calc R
H38C H 0.3596 0.2397 -0.0450 0.123 Uiso 1 1 calc R
C39 C 0.6650(3) 0.0960(3) 0.20049(17) 0.0430(8) Uani 1 1 d .
C40 C 0.4223(3) 0.0728(3) 0.1840(2) 0.0544(9) Uani 1 1 d .
C41 C 0.3748(3) -0.0135(3) 0.32208(18) 0.0451(8) Uani 1 1 d .
C42 C 0.6119(3) -0.0003(3) 0.33449(17) 0.0385(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
O6 Tb1 O3 128.41(6) .
O6 Tb1 O1 78.37(6) .
O3 Tb1 O1 147.63(7) .
O6 Tb1 O5 84.47(7) .
O3 Tb1 O5 79.34(7) .
O1 Tb1 O5 126.17(7) .
O6 Tb1 O2 76.20(6) .
O3 Tb1 O2 141.22(7) .
O1 Tb1 O2 52.94(6) .
O5 Tb1 O2 73.53(6) .
O6 Tb1 O4 75.88(6) .
O3 Tb1 O4 52.54(6) .
O1 Tb1 O4 147.80(6) .
O5 Tb1 O4 70.06(6) .
O2 Tb1 O4 135.63(6) .
O6 Tb1 N1 78.40(6) .
O3 Tb1 N1 85.60(7) .
O1 Tb1 N1 82.69(7) .
O5 Tb1 N1 142.51(7) .
O2 Tb1 N1 132.20(7) .
O4 Tb1 N1 73.50(7) .
O6 Tb1 N3 148.50(7) .
O3 Tb1 N3 77.07(7) .
O1 Tb1 N3 86.10(7) .
O5 Tb1 N3 82.89(7) .
O2 Tb1 N3 72.58(7) .
O4 Tb1 N3 125.55(6) .
N1 Tb1 N3 126.87(7) .
O6 Tb1 N2 134.39(6) .
O3 Tb1 N2 74.68(7) .
O1 Tb1 N2 73.08(6) .
O5 Tb1 N2 141.14(7) .
O2 Tb1 N2 111.14(7) .
O4 Tb1 N2 113.08(6) .
N1 Tb1 N2 63.46(7) .
N3 Tb1 N2 63.57(7) .
O6 Tb1 C16 75.32(7) .
O3 Tb1 C16 155.60(7) .
O1 Tb1 C16 26.34(7) .
O5 Tb1 C16 99.95(8) .
O2 Tb1 C16 26.61(7) .
O4 Tb1 C16 150.29(7) .
N1 Tb1 C16 107.42(8) .
N3 Tb1 C16 78.63(7) .
N2 Tb1 C16 92.44(8) .
O6 Tb1 C18 102.18(7) .
O3 Tb1 C18 26.27(7) .
O1 Tb1 C18 161.77(7) .
O5 Tb1 C18 71.72(7) .
O2 Tb1 C18 145.20(7) .
O4 Tb1 C18 26.32(6) .
N1 Tb1 C18 79.61(7) .
N3 Tb1 C18 101.02(7) .
N2 Tb1 C18 94.90(7) .
C16 Tb1 C18 171.59(8) .
O11 Tb2 O9 86.97(7) .
O11 Tb2 O8 124.29(7) .
O9 Tb2 O8 147.03(7) .
O11 Tb2 O12 78.14(7) .
O9 Tb2 O12 128.49(8) .
O8 Tb2 O12 73.85(7) .
O11 Tb2 O10 72.54(7) .
O9 Tb2 O10 53.78(8) .
O8 Tb2 O10 139.29(7) .
O12 Tb2 O10 74.73(7) .
O11 Tb2 O7 75.31(6) .
O9 Tb2 O7 143.67(7) .
O8 Tb2 O7 52.83(6) .
O12 Tb2 O7 79.05(7) .
O10 Tb2 O7 141.84(7) .
O11 Tb2 N6 146.00(7) .
O9 Tb2 N6 85.66(7) .
O8 Tb2 N6 73.60(7) .
O12 Tb2 N6 80.74(7) .
O10 Tb2 N6 76.37(7) .
O7 Tb2 N6 126.05(6) .
O11 Tb2 N5 144.00(7) .
O9 Tb2 N5 73.93(8) .
O8 Tb2 N5 73.99(7) .
O12 Tb2 N5 137.45(7) .
O10 Tb2 N5 115.68(7) .
O7 Tb2 N5 102.40(7) .
N6 Tb2 N5 63.91(7) .
O11 Tb2 N4 82.24(8) .
O9 Tb2 N4 74.92(9) .
O8 Tb2 N4 97.32(8) .
O12 Tb2 N4 147.88(7) .
O10 Tb2 N4 122.83(8) .
O7 Tb2 N4 71.48(7) .
N6 Tb2 N4 127.22(7) .
N5 Tb2 N4 63.64(7) .
O11 Tb2 C37 77.72(8) .
O9 Tb2 C37 26.82(9) .
O8 Tb2 C37 154.48(8) .
O12 Tb2 C37 101.71(10) .
O10 Tb2 C37 26.99(9) .
O7 Tb2 C37 152.25(7) .
N6 Tb2 C37 80.89(8) .
N5 Tb2 C37 95.55(9) .
N4 Tb2 C37 98.61(10) .
O11 Tb2 C35 99.48(8) .
O9 Tb2 C35 158.75(9) .
O8 Tb2 C35 26.20(7) .
O12 Tb2 C35 72.75(8) .
O10 Tb2 C35 147.46(8) .
O7 Tb2 C35 26.78(7) .
N6 Tb2 C35 99.30(8) .
N5 Tb2 C35 89.62(7) .
N4 Tb2 C35 85.84(8) .
C37 Tb2 C35 174.29(10) .
C41 Pt1 C39 178.55(13) .
C41 Pt1 C40 90.88(13) .
C39 Pt1 C40 90.19(13) .
C41 Pt1 C42 89.19(12) .
C39 Pt1 C42 89.66(11) .
C40 Pt1 C42 175.42(13) .
C16 O1 Tb1 96.27(17) .
C16 O2 Tb1 90.74(17) .
C18 O3 Tb1 97.28(15) .
C18 O4 Tb1 90.09(16) .
Tb1 O5 H5A 111.4 .
Tb1 O5 H5B 127.6 .
H5A O5 H5B 120.4 .
Tb1 O6 H6A 110.9 .
Tb1 O6 H6B 134.3 .
H6A O6 H6B 113.1 .
C35 O7 Tb2 90.42(16) .
C35 O8 Tb2 96.11(16) .
C37 O9 Tb2 94.30(19) .
C37 O10 Tb2 91.9(2) .
Tb2 O11 H11A 109.3 .
Tb2 O11 H11B 119.8 .
H11A O11 H11B 121.2 .
Tb2 O12 H12B 114.0 .
Tb2 O12 H12C 128.3 .
H12B O12 H12C 116.9 .
H13A O13 H13B 91.2 .
H14A O14 H14B 106.5 .
H15A O15 H15B 90.0 .
H16A O16 H16B 121.6 .
O17 O17 H17D 68.6 2_666
O17 O17 H17E 58.4 2_666
H17D O17 H17E 118.7 .
C1 N1 C5 118.2(2) .
C1 N1 Tb1 120.17(17) .
C5 N1 Tb1 121.60(18) .
C6 N2 C10 118.3(2) .
C6 N2 Tb1 120.59(17) .
C10 N2 Tb1 120.66(17) .
C15 N3 C11 117.1(2) .
C15 N3 Tb1 121.33(19) .
C11 N3 Tb1 121.45(18) .
C24 N4 C20 117.2(3) .
C24 N4 Tb2 120.69(18) .
C20 N4 Tb2 121.6(2) .
C29 N5 C25 118.7(2) .
C29 N5 Tb2 120.26(17) .
C25 N5 Tb2 120.91(17) .
C34 N6 C30 117.9(2) .
C34 N6 Tb2 121.0(2) .
C30 N6 Tb2 120.74(17) .
N1 C1 C2 123.4(3) .
N1 C1 H1 118.3 .
C2 C1 H1 118.3 .
C3 C2 C1 118.1(3) .
C3 C2 H2 120.9 .
C1 C2 H2 120.9 .
C4 C3 C2 119.6(3) .
C4 C3 H3 120.2 .
C2 C3 H3 120.2 .
C3 C4 C5 119.8(3) .
C3 C4 H4 120.1 .
C5 C4 H4 120.1 .
N1 C5 C4 120.9(3) .
N1 C5 C6 116.9(2) .
C4 C5 C6 122.2(3) .
N2 C6 C7 122.0(3) .
N2 C6 C5 116.7(2) .
C7 C6 C5 121.4(3) .
C8 C7 C6 118.7(3) .
C8 C7 H7 120.7 .
C6 C7 H7 120.7 .
C9 C8 C7 120.2(3) .
C9 C8 H8 119.9 .
C7 C8 H8 119.9 .
C8 C9 C10 119.5(3) .
C8 C9 H9 120.3 .
C10 C9 H9 120.3 .
N2 C10 C9 121.3(3) .
N2 C10 C11 116.9(2) .
C9 C10 C11 121.7(3) .
N3 C11 C12 121.7(3) .
N3 C11 C10 116.6(2) .
C12 C11 C10 121.7(3) .
C13 C12 C11 120.1(3) .
C13 C12 H12 120.0 .
C11 C12 H12 120.0 .
C12 C13 C14 118.8(3) .
C12 C13 H13 120.6 .
C14 C13 H13 120.6 .
C15 C14 C13 118.0(3) .
C15 C14 H14 121.0 .
C13 C14 H14 121.0 .
N3 C15 C14 124.3(3) .
N3 C15 H15 117.9 .
C14 C15 H15 117.9 .
O1 C16 O2 120.0(3) .
O1 C16 C17 119.2(3) .
O2 C16 C17 120.8(3) .
O1 C16 Tb1 57.40(14) .
O2 C16 Tb1 62.64(14) .
C17 C16 Tb1 175.9(2) .
C16 C17 H17A 109.5 .
C16 C17 H17B 109.5 .
H17A C17 H17B 109.5 .
C16 C17 H17C 109.5 .
H17A C17 H17C 109.5 .
H17B C17 H17C 109.5 .
O4 C18 O3 119.8(2) .
O4 C18 C19 121.5(3) .
O3 C18 C19 118.7(2) .
O4 C18 Tb1 63.59(14) .
O3 C18 Tb1 56.44(13) .
C19 C18 Tb1 172.6(2) .
C18 C19 H19A 109.5 .
C18 C19 H19B 109.5 .
H19A C19 H19B 109.5 .
C18 C19 H19C 109.5 .
H19A C19 H19C 109.5 .
H19B C19 H19C 109.5 .
N4 C20 C21 123.9(4) .
N4 C20 H20 118.0 .
C21 C20 H20 118.0 .
C22 C21 C20 118.3(3) .
C22 C21 H21 120.8 .
C20 C21 H21 120.8 .
C21 C22 C23 119.1(3) .
C21 C22 H22 120.5 .
C23 C22 H22 120.5 .
C22 C23 C24 120.0(3) .
C22 C23 H23 120.0 .
C24 C23 H23 120.0 .
N4 C24 C23 121.3(3) .
N4 C24 C25 116.8(2) .
C23 C24 C25 121.9(3) .
N5 C25 C26 121.3(3) .
N5 C25 C24 117.0(3) .
C26 C25 C24 121.7(3) .
C27 C26 C25 119.6(3) .
C27 C26 H26 120.2 .
C25 C26 H26 120.2 .
C26 C27 C28 119.5(3) .
C26 C27 H27 120.3 .
C28 C27 H27 120.3 .
C27 C28 C29 119.3(3) .
C27 C28 H28 120.4 .
C29 C28 H28 120.4 .
N5 C29 C28 121.5(3) .
N5 C29 C30 116.4(2) .
C28 C29 C30 122.0(3) .
N6 C30 C31 121.2(3) .
N6 C30 C29 116.9(2) .
C31 C30 C29 121.9(3) .
C32 C31 C30 120.1(3) .
C32 C31 H31 120.0 .
C30 C31 H31 120.0 .
C31 C32 C33 119.7(3) .
C31 C32 H32 120.1 .
C33 C32 H32 120.1 .
C32 C33 C34 117.4(3) .
C32 C33 H33 121.3 .
C34 C33 H33 121.3 .
N6 C34 C33 123.6(3) .
N6 C34 H34 118.2 .
C33 C34 H34 118.2 .
O8 C35 O7 120.0(3) .
O8 C35 C36 119.6(3) .
O7 C35 C36 120.5(3) .
O8 C35 Tb2 57.70(14) .
O7 C35 Tb2 62.80(14) .
C36 C35 Tb2 171.3(2) .
C35 C36 H36A 109.5 .
C35 C36 H36B 109.5 .
H36A C36 H36B 109.5 .
C35 C36 H36C 109.5 .
H36A C36 H36C 109.5 .
H36B C36 H36C 109.5 .
O9 C37 O10 119.9(3) .
O9 C37 C38 119.8(3) .
O10 C37 C38 120.2(4) .
O9 C37 Tb2 58.88(16) .
O10 C37 Tb2 61.16(16) .
C38 C37 Tb2 177.7(3) .
C37 C38 H38A 109.5 .
C37 C38 H38B 109.5 .
H38A C38 H38B 109.5 .
C37 C38 H38C 109.5 .
H38A C38 H38C 109.5 .
H38B C38 H38C 109.5 .
N7 C39 Pt1 177.0(3) .
N8 C40 Pt1 176.0(3) .
N9 C41 Pt1 179.3(3) .
N10 C42 Pt1 174.2(3) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb1 O6 2.3727(17) .
Tb1 O3 2.3839(18) .
Tb1 O1 2.3953(19) .
Tb1 O5 2.3999(18) .
Tb1 O2 2.5104(18) .
Tb1 O4 2.5414(18) .
Tb1 N1 2.546(2) .
Tb1 N3 2.568(2) .
Tb1 N2 2.572(2) .
Tb1 C16 2.826(3) .
Tb1 C18 2.838(3) .
Tb2 O11 2.3828(19) .
Tb2 O9 2.389(2) .
Tb2 O8 2.3967(19) .
Tb2 O12 2.4215(19) .
Tb2 O10 2.439(2) .
Tb2 O7 2.5078(19) .
Tb2 N6 2.528(2) .
Tb2 N5 2.542(2) .
Tb2 N4 2.564(2) .
Tb2 C37 2.783(3) .
Tb2 C35 2.819(3) .
Pt1 C41 1.983(3) .
Pt1 C39 1.984(3) .
Pt1 C40 1.986(4) .
Pt1 C42 1.994(3) .
O1 C16 1.261(3) .
O2 C16 1.266(3) .
O3 C18 1.266(3) .
O4 C18 1.258(3) .
O5 H5A 0.8501 .
O5 H5B 0.8499 .
O6 H6A 0.8503 .
O6 H6B 0.8498 .
O7 C35 1.270(3) .
O8 C35 1.252(3) .
O9 C37 1.259(4) .
O10 C37 1.263(4) .
O11 H11A 0.8505 .
O11 H11B 0.8501 .
O12 H12B 0.8505 .
O12 H12C 0.8497 .
O13 H13A 0.8501 .
O13 H13B 0.8499 .
O14 H14A 0.8505 .
O14 H14B 0.8501 .
O15 H15A 0.8500 .
O15 H15B 0.8500 .
O16 H16A 0.8501 .
O16 H16B 0.8498 .
O17 O17 1.344(12) 2_666
O17 H17D 0.8500 .
O17 H17E 0.8500 .
N1 C1 1.334(3) .
N1 C5 1.348(3) .
N2 C6 1.346(3) .
N2 C10 1.356(3) .
N3 C15 1.336(3) .
N3 C11 1.346(3) .
N4 C24 1.327(4) .
N4 C20 1.335(4) .
N5 C29 1.341(3) .
N5 C25 1.347(3) .
N6 C34 1.331(4) .
N6 C30 1.337(3) .
N7 C39 1.144(4) .
N8 C40 1.145(4) .
N9 C41 1.139(4) .
N10 C42 1.141(4) .
C1 C2 1.377(4) .
C1 H1 0.9300 .
C2 C3 1.372(4) .
C2 H2 0.9300 .
C3 C4 1.362(5) .
C3 H3 0.9300 .
C4 C5 1.392(4) .
C4 H4 0.9300 .
C5 C6 1.476(4) .
C6 C7 1.401(4) .
C7 C8 1.364(4) .
C7 H7 0.9300 .
C8 C9 1.359(4) .
C8 H8 0.9300 .
C9 C10 1.395(4) .
C9 H9 0.9300 .
C10 C11 1.481(4) .
C11 C12 1.381(4) .
C12 C13 1.368(5) .
C12 H12 0.9300 .
C13 C14 1.375(5) .
C13 H13 0.9300 .
C14 C15 1.373(4) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C17 1.502(4) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 C19 1.495(4) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 C21 1.372(5) .
C20 H20 0.9300 .
C21 C22 1.340(5) .
C21 H21 0.9300 .
C22 C23 1.368(5) .
C22 H22 0.9300 .
C23 C24 1.378(4) .
C23 H23 0.9300 .
C24 C25 1.474(4) .
C25 C26 1.391(4) .
C26 C27 1.349(4) .
C26 H26 0.9300 .
C27 C28 1.372(5) .
C27 H27 0.9300 .
C28 C29 1.385(4) .
C28 H28 0.9300 .
C29 C30 1.483(4) .
C30 C31 1.374(4) .
C31 C32 1.356(5) .
C31 H31 0.9300 .
C32 C33 1.363(5) .
C32 H32 0.9300 .
C33 C34 1.379(4) .
C33 H33 0.9300 .
C34 H34 0.9300 .
C35 C36 1.496(4) .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
C37 C38 1.497(4) .
C38 H38A 0.9600 .
C38 H38B 0.9600 .
C38 H38C 0.9600 .
