#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:37:02 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179415 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/12/4331258.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4331258
loop_
_publ_author_name
'Tommy Kenny'
'Simon Lamare'
'Shawkat M. Aly'
'Daniel Fortin'
'Gessie Brisard'
'Pierre D. Harvey'
_publ_section_title
;
 Reduced and Oxidized Forms of the Pt-Organometallic Version of
 Polyaniline
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              13081
_journal_page_last               13095
_journal_paper_doi               10.1021/ic300775n
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C70 H118 Cl2 F4 N2 P4 Pt2'
_chemical_formula_weight         1648.68
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2010-08-03T11:48:27-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 114.10(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   12.307(4)
_cell_length_b                   23.926(4)
_cell_length_c                   14.694(5)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      35
_cell_measurement_theta_min      30
_cell_volume                     3950(2)
_computing_cell_refinement       Difrac
_computing_data_collection       Difrac
_computing_data_reduction        NRCVAX
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  CAD4
_diffrn_measurement_method       Omega
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54176
_diffrn_reflns_av_R_equivalents  0
_diffrn_reflns_av_unetI/netI     0.0818
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            7310
_diffrn_reflns_theta_full        69.77
_diffrn_reflns_theta_max         69.77
_diffrn_reflns_theta_min         3.69
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 100
_diffrn_standards_number         1
_exptl_absorpt_coefficient_mu    8.279
_exptl_absorpt_correction_T_max  0.4915
_exptl_absorpt_correction_T_min  0.1902
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   empirical
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.386
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1676
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.949
_refine_diff_density_min         -1.112
_refine_diff_density_rms         0.121
_refine_ls_extinction_coef       0.00143(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.989
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     260
_refine_ls_number_reflns         7310
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      0.989
_refine_ls_R_factor_all          0.1709
_refine_ls_R_factor_gt           0.085
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1231P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.211
_refine_ls_wR_factor_ref         0.2465
_reflns_number_gt                3465
_reflns_number_total             7310
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300775n_si_002_17.cif
_cod_data_source_block           9b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Psi-Scan' changed to
'psi-scan' according to the built-in table from CIF Core dictionary
named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        3949.8(18)
_cod_database_code               4331258
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.1946(13) 0.1961(5) 0.1484(11) 0.092(4) Uani 1 1 d .
C2 C 0.2044(13) 0.2453(7) 0.1300(12) 0.102(4) Uani 1 1 d .
C3 C 0.2281(14) 0.3040(6) 0.1112(11) 0.097(4) Uani 1 1 d .
C4 C 0.2988(14) 0.3142(6) 0.0566(11) 0.103(5) Uani 1 1 d .
H4 H 0.3238 0.2835 0.029 0.124 Uiso 1 1 calc R
C5 C 0.3316(15) 0.3673(6) 0.0426(11) 0.103(5) Uani 1 1 d .
H5 H 0.3752 0.373 0.0029 0.124 Uiso 1 1 calc R
C6 C 0.3019(13) 0.4120(6) 0.0857(10) 0.087(4) Uani 1 1 d .
C7 C 0.2302(16) 0.4021(7) 0.1397(12) 0.106(5) Uani 1 1 d .
H7 H 0.2045 0.4328 0.1669 0.127 Uiso 1 1 calc R
C8 C 0.1982(12) 0.3487(6) 0.1529(11) 0.095(4) Uani 1 1 d .
H8 H 0.154 0.343 0.1921 0.114 Uiso 1 1 calc R
C9 C 0.4153(14) 0.4827(6) 0.0412(11) 0.089(4) Uani 1 1 d .
C10 C 0.4003(14) 0.4741(6) -0.0562(11) 0.097(4) Uani 1 1 d .
C11 C 0.5205(14) 0.5105(6) 0.0946(11) 0.094(4) Uani 1 1 d .
C12 C -0.0233(18) 0.1488(10) -0.0564(15) 0.1517(18) Uani 1 1 d .
H12A H -0.1083 0.1468 -0.1029 0.182 Uiso 1 1 calc R
H12B H -0.0006 0.1888 -0.0493 0.182 Uiso 1 1 calc R
C13 C 0.044(2) 0.1214(8) -0.1031(17) 0.1517(18) Uani 1 1 d .
H13A H 0.0035 0.0856 -0.1308 0.182 Uiso 1 1 calc R
H13B H 0.1229 0.1122 -0.0507 0.182 Uiso 1 1 calc R
C16 C -0.0897(19) 0.1789(9) 0.0958(14) 0.1517(18) Uani 1 1 d .
H16A H -0.0499 0.2151 0.0975 0.182 Uiso 1 1 calc R
H16B H -0.1717 0.1816 0.0436 0.182 Uiso 1 1 calc R
C17 C -0.0964(18) 0.1702(8) 0.1956(14) 0.1517(18) Uani 1 1 d D
H17A H -0.0169 0.1587 0.2453 0.182 Uiso 1 1 calc R
H17B H -0.1525 0.1393 0.1893 0.182 Uiso 1 1 calc R
C20 C -0.1015(18) 0.0622(8) 0.0460(15) 0.1517(18) Uani 1 1 d .
H20A H -0.0706 0.033 0.0152 0.182 Uiso 1 1 calc R
H20B H -0.0893 0.0488 0.1133 0.182 Uiso 1 1 calc R
C21 C -0.2368(18) 0.0679(9) -0.0166(15) 0.1517(18) Uani 1 1 d .
H21A H -0.2686 0.0994 0.0088 0.182 Uiso 1 1 calc R
H21B H -0.252 0.0758 -0.0869 0.182 Uiso 1 1 calc R
C22 C -0.2997(18) 0.0135(9) -0.0107(15) 0.1517(18) Uani 1 1 d .
H22A H -0.3802 0.0134 -0.0655 0.182 Uiso 1 1 calc R
H22B H -0.2552 -0.0183 -0.022 0.182 Uiso 1 1 calc R
C23 C -0.3116(18) 0.0041(9) 0.0832(14) 0.1517(18) Uani 1 1 d .
H23A H -0.3517 -0.0317 0.0802 0.228 Uiso 1 1 calc R
H23B H -0.3586 0.0344 0.094 0.228 Uiso 1 1 calc R
H23C H -0.2325 0.0033 0.1383 0.228 Uiso 1 1 calc R
C24 C 0.4777(18) 0.1603(9) 0.2420(15) 0.1517(18) Uani 1 1 d .
H24A H 0.4689 0.2014 0.2409 0.182 Uiso 1 1 calc R
H24B H 0.5608 0.1511 0.2875 0.182 Uiso 1 1 calc R
C25 C 0.4549(19) 0.1404(9) 0.1401(16) 0.1517(18) Uani 1 1 d .
H25A H 0.3691 0.1444 0.0969 0.182 Uiso 1 1 calc R
H25B H 0.4754 0.1002 0.1429 0.182 Uiso 1 1 calc R
C27 C 0.5047(17) 0.1637(9) -0.0108(14) 0.1517(18) Uani 1 1 d .
H27A H 0.5528 0.1879 -0.0336 0.228 Uiso 1 1 calc R
H27B H 0.42 0.171 -0.0508 0.228 Uiso 1 1 calc R
H27C H 0.5224 0.1245 -0.0183 0.228 Uiso 1 1 calc R
C28 C 0.4566(19) 0.0651(9) 0.3565(15) 0.1517(18) Uani 1 1 d .
H28A H 0.5291 0.077 0.4142 0.182 Uiso 1 1 calc R
H28B H 0.4059 0.0444 0.3827 0.182 Uiso 1 1 calc R
C29 C 0.4931(18) 0.0253(9) 0.2923(15) 0.1517(18) Uani 1 1 d .
H29A H 0.5511 0.0438 0.2713 0.182 Uiso 1 1 calc R
H29B H 0.4226 0.0145 0.2319 0.182 Uiso 1 1 calc R
C30 C 0.5508(19) -0.0278(9) 0.3569(15) 0.1517(18) Uani 1 1 d .
H30A H 0.497 -0.0437 0.3852 0.182 Uiso 1 1 calc R
H30B H 0.6274 -0.018 0.4123 0.182 Uiso 1 1 calc R
C31 C 0.571(2) -0.0717(11) 0.2826(16) 0.211(12) Uani 1 1 d .
H31A H 0.6067 -0.106 0.3191 0.317 Uiso 1 1 calc R
H31B H 0.625 -0.0554 0.2556 0.317 Uiso 1 1 calc R
H31C H 0.4948 -0.0805 0.2278 0.317 Uiso 1 1 calc R
C32 C 0.386(3) 0.1726(9) 0.3903(16) 0.177(10) Uani 1 1 d .
H32A H 0.4703 0.1793 0.4345 0.212 Uiso 1 1 calc R
H32B H 0.3477 0.209 0.3642 0.212 Uiso 1 1 calc R
C33 C 0.326(3) 0.1457(18) 0.446(3) 0.272(13) Uani 1 1 d D
H33A H 0.384 0.1441 0.5164 0.327 Uiso 1 1 calc R
H33B H 0.3101 0.1066 0.422 0.327 Uiso 1 1 calc R
C34 C 0.214(3) 0.1682(17) 0.445(3) 0.272(13) Uani 1 1 d D
H34A H 0.1519 0.1637 0.3767 0.327 Uiso 1 1 calc R
H34B H 0.2252 0.2089 0.4575 0.327 Uiso 1 1 calc R
C35 C 0.162(4) 0.1465(16) 0.514(2) 0.272(13) Uani 1 1 d .
H35A H 0.0822 0.1625 0.496 0.408 Uiso 1 1 calc R
H35B H 0.2131 0.157 0.5829 0.408 Uiso 1 1 calc R
H35C H 0.1556 0.1057 0.509 0.408 Uiso 1 1 calc R
Cl1 Cl 0.1674(4) 0.02553(16) 0.2106(3) 0.1059(11) Uani 1 1 d .
F1 F 0.5464(8) 0.5217(3) 0.1934(6) 0.117(3) Uani 1 1 d .
F2 F 0.2956(8) 0.4486(4) -0.1209(6) 0.117(3) Uani 1 1 d .
N1 N 0.3367(10) 0.4677(4) 0.0822(8) 0.091(3) Uani 1 1 d .
H1 H 0.3072 0.494 0.1072 0.109 Uiso 1 1 calc R
P1 P -0.0119(4) 0.12520(16) 0.0607(3) 0.0970(11) Uani 1 1 d .
P2 P 0.3750(4) 0.12832(18) 0.2907(3) 0.1107(14) Uani 1 1 d .
Pt1 Pt 0.18184(6) 0.11987(2) 0.17527(4) 0.0879(3) Uani 1 1 d .
C14 C 0.0630(19) 0.1528(9) -0.1872(15) 0.1517(18) Uani 1 1 d .
H14A H -0.0165 0.161 -0.2402 0.182 Uiso 1 1 calc R
H14B H 0.1004 0.1892 -0.1598 0.182 Uiso 1 1 calc R
C15 C 0.1315(19) 0.1275(8) -0.2332(16) 0.1517(18) Uani 1 1 d .
H15A H 0.1403 0.1537 -0.2811 0.228 Uiso 1 1 calc R
H15B H 0.0914 0.0936 -0.268 0.228 Uiso 1 1 calc R
H15C H 0.2102 0.1179 -0.1822 0.228 Uiso 1 1 calc R
C26 C 0.5319(18) 0.1751(9) 0.0918(14) 0.1517(18) Uani 1 1 d .
H26A H 0.5198 0.2155 0.0987 0.182 Uiso 1 1 calc R
H26B H 0.6173 0.167 0.1311 0.182 Uiso 1 1 calc R
C18 C -0.1377(18) 0.2237(8) 0.2350(15) 0.1517(18) Uani 1 1 d D
H18A H -0.0757 0.253 0.2508 0.182 Uiso 1 1 calc R
H18B H -0.2116 0.2383 0.1818 0.182 Uiso 1 1 calc R
C19 C -0.1594(17) 0.2120(9) 0.3243(13) 0.1517(18) Uani 1 1 d .
H19A H -0.1849 0.2463 0.3462 0.228 Uiso 1 1 calc R
H19B H -0.086 0.1982 0.3775 0.228 Uiso 1 1 calc R
H19C H -0.2218 0.1836 0.3085 0.228 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.018 0.009 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.364 0.702 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.073 0.053 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.031 0.018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.296 0.433 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.593 6.926 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C2 C1 Pt1 178.6(15) .
C1 C2 C3 174.8(17) .
C8 C3 C4 117.3(14) .
C8 C3 C2 123.6(15) .
C4 C3 C2 118.7(15) .
C5 C4 C3 121.9(15) .
C6 C5 C4 120.2(14) .
C5 C6 N1 125.5(14) .
C5 C6 C7 118.2(13) .
N1 C6 C7 116.3(13) .
C8 C7 C6 120.7(15) .
C3 C8 C7 121.6(14) .
C11 C9 N1 122.6(14) .
C11 C9 C10 111.1(13) .
N1 C9 C10 126.3(14) .
C11 C10 C9 124.9(15) 3_665
C11 C10 F2 117.2(14) 3_665
C9 C10 F2 117.9(15) .
C10 C11 F1 119.1(14) 3_665
C10 C11 C9 124.0(14) 3_665
F1 C11 C9 116.9(13) .
C13 C12 P1 119.4(16) .
C12 C13 C14 118.0(19) .
C17 C16 P1 115.1(14) .
C16 C17 C18 113.3(17) .
C21 C20 P1 116.8(14) .
C22 C21 C20 109.7(17) .
C23 C22 C21 115.5(18) .
C25 C24 P2 112.3(15) .
C24 C25 C26 111.9(18) .
C29 C28 P2 114.8(14) .
C28 C29 C30 107.7(17) .
C29 C30 C31 106.0(16) .
C33 C32 P2 108(2) .
C32 C33 C34 121(4) .
C33 C34 C35 122(4) .
C9 N1 C6 122.8(12) .
C12 P1 C16 102.2(10) .
C12 P1 C20 110.2(10) .
C16 P1 C20 104.9(11) .
C12 P1 Pt1 112.3(7) .
C16 P1 Pt1 110.2(7) .
C20 P1 Pt1 116.0(6) .
C32 P2 C24 104.0(12) .
C32 P2 C28 102.5(11) .
C24 P2 C28 103.2(10) .
C32 P2 Pt1 111.7(9) .
C24 P2 Pt1 114.5(7) .
C28 P2 Pt1 119.3(7) .
C1 Pt1 P1 86.7(4) .
C1 Pt1 P2 85.4(4) .
P1 Pt1 P2 171.74(15) .
C1 Pt1 Cl1 179.3(5) .
P1 Pt1 Cl1 93.79(14) .
P2 Pt1 Cl1 94.05(15) .
C15 C14 C13 119.4(19) .
C27 C26 C25 115.8(18) .
C19 C18 C17 112.1(17) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.225(18) .
C1 Pt1 1.887(13) .
C2 C3 1.48(2) .
C3 C8 1.357(19) .
C3 C4 1.42(2) .
C4 C5 1.374(18) .
C5 C6 1.366(19) .
C6 N1 1.407(16) .
C6 C7 1.43(2) .
C7 C8 1.37(2) .
C9 C11 1.379(19) .
C9 N1 1.380(17) .
C9 C10 1.383(19) .
C10 C11 1.363(19) 3_665
C10 F2 1.391(16) .
C11 C10 1.363(19) 3_665
C11 F1 1.378(15) .
C12 C13 1.43(3) .
C12 P1 1.76(2) .
C13 C14 1.55(3) .
C16 C17 1.52(2) .
C16 P1 1.80(2) .
C17 C18 1.573(16) .
C20 C21 1.54(3) .
C20 P1 1.83(2) .
C21 C22 1.54(2) .
C22 C23 1.46(2) .
C24 C25 1.48(3) .
C24 P2 1.85(2) .
C25 C26 1.63(3) .
C27 C26 1.43(2) .
C28 C29 1.53(2) .
C28 P2 1.85(2) .
C29 C30 1.57(2) .
C30 C31 1.61(3) .
C32 C33 1.45(4) .
C32 P2 1.77(2) .
C33 C34 1.482(19) .
C34 C35 1.49(4) .
Cl1 Pt1 2.339(4) .
P1 Pt1 2.292(4) .
P2 Pt1 2.297(5) .
C14 C15 1.41(3) .
C18 C19 1.47(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
Pt1 C1 C2 C3 -4E1(8) .
C1 C2 C3 C8 -121(19) .
C1 C2 C3 C4 5E1(2) .
C8 C3 C4 C5 -3(2) .
C2 C3 C4 C5 -175.1(14) .
C3 C4 C5 C6 3(2) .
C4 C5 C6 N1 175.7(14) .
C4 C5 C6 C7 -4(2) .
C5 C6 C7 C8 4(2) .
N1 C6 C7 C8 -175.8(13) .
C4 C3 C8 C7 3(2) .
C2 C3 C8 C7 174.7(14) .
C6 C7 C8 C3 -3(2) .
C11 C9 C10 C11 1(2) 3_665
N1 C9 C10 C11 179.9(14) 3_665
C11 C9 C10 F2 -177.4(12) .
N1 C9 C10 F2 1(2) .
N1 C9 C11 C10 -179.9(14) 3_665
C10 C9 C11 C10 -1(2) 3_665
N1 C9 C11 F1 2(2) .
C10 C9 C11 F1 -179.9(12) .
P1 C12 C13 C14 -161.6(16) .
P1 C16 C17 C18 166.6(14) .
P1 C20 C21 C22 -173.2(15) .
C20 C21 C22 C23 75(2) .
P2 C24 C25 C26 171.7(14) .
P2 C28 C29 C30 -175.2(14) .
C28 C29 C30 C31 172.5(17) .
P2 C32 C33 C34 -111(4) .
C32 C33 C34 C35 -170(3) .
C11 C9 N1 C6 -121.7(15) .
C10 C9 N1 C6 60(2) .
C5 C6 N1 C9 -6(2) .
C7 C6 N1 C9 173.5(13) .
C13 C12 P1 C16 170.6(19) .
C13 C12 P1 C20 -78(2) .
C13 C12 P1 Pt1 53(2) .
C17 C16 P1 C12 179.5(16) .
C17 C16 P1 C20 64.5(18) .
C17 C16 P1 Pt1 -60.9(17) .
C21 C20 P1 C12 -61.3(19) .
C21 C20 P1 C16 48.0(18) .
C21 C20 P1 Pt1 169.8(13) .
C33 C32 P2 C24 -169(2) .
C33 C32 P2 C28 -62(2) .
C33 C32 P2 Pt1 67(2) .
C25 C24 P2 C32 -162.3(16) .
C25 C24 P2 C28 91.1(17) .
C25 C24 P2 Pt1 -40.2(18) .
C29 C28 P2 C32 -163.7(18) .
C29 C28 P2 C24 -55.9(17) .
C29 C28 P2 Pt1 72.4(17) .
C2 C1 Pt1 P1 -11E1(7) .
C2 C1 Pt1 P2 7E1(7) .
C2 C1 Pt1 Cl1 11E1(7) .
C12 P1 Pt1 C1 56.3(10) .
C16 P1 Pt1 C1 -56.9(9) .
C20 P1 Pt1 C1 -175.8(9) .
C12 P1 Pt1 P2 74.1(14) .
C16 P1 Pt1 P2 -39.1(14) .
C20 P1 Pt1 P2 -158.0(13) .
C12 P1 Pt1 Cl1 -124.1(9) .
C16 P1 Pt1 Cl1 122.6(7) .
C20 P1 Pt1 Cl1 3.8(8) .
C32 P2 Pt1 C1 67.1(10) .
C24 P2 Pt1 C1 -50.7(9) .
C28 P2 Pt1 C1 -173.6(9) .
C32 P2 Pt1 P1 49.2(15) .
C24 P2 Pt1 P1 -68.6(15) .
C28 P2 Pt1 P1 168.5(12) .
C32 P2 Pt1 Cl1 -112.5(9) .
C24 P2 Pt1 Cl1 129.7(8) .
C28 P2 Pt1 Cl1 6.8(8) .
C12 C13 C14 C15 178(2) .
C24 C25 C26 C27 -172.4(18) .
C16 C17 C18 C19 172.0(17) .
