#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:46:09 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179423 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/20/4332015.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4332015
loop_
_publ_author_name
'Silva, Rosalice M.'
'Smith, Mark D.'
'Gardinier, James R.'
_publ_section_title
;
 Anion- and Solvent-Directed Assembly in Silver Bis(thioimidazolyl)methane
 Chemistry and the Silver−Sulfur Interaction
;
_journal_issue                   5
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2132
_journal_page_last               2142
_journal_paper_doi               10.1021/ic052025a
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'C18 H24 Ag2 N8 S4, 2(C F3 O3 S)'
_chemical_formula_sum            'C20 H24 Ag2 F6 N8 O6 S6'
_chemical_formula_weight         994.57
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   12.8641(7)
_cell_length_b                   22.0250(12)
_cell_length_c                   23.7696(13)
_cell_measurement_reflns_used    9623
_cell_measurement_temperature    150(1)
_cell_measurement_theta_max      26.376
_cell_measurement_theta_min      2.333
_cell_volume                     6734.7(6)
_computing_cell_refinement       'SAINT+ NT V6.22 (Bruker, 2001)'
_computing_data_collection       'SMART NT V5.625 (Bruker, 1998)'
_computing_data_reduction        'SAINT+ NT V6.22'
_computing_molecular_graphics    'SHELXTL V6.1 (Sheldrick, 2000)'
_computing_publication_material  'SHELXTL V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(1)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0526
_diffrn_reflns_av_sigmaI/netI    0.0256
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            68052
_diffrn_reflns_theta_full        26.40
_diffrn_reflns_theta_max         26.40
_diffrn_reflns_theta_min         1.71
_diffrn_standards_decay_%        none
_exptl_absorpt_coefficient_mu    1.618
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.962
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3936
_exptl_crystal_size_max          0.46
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.389
_refine_diff_density_min         -0.710
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     437
_refine_ls_number_reflns         6898
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0444
_refine_ls_R_factor_gt           0.0391
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0548P)²+13.6907P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0973
_refine_ls_wR_factor_ref         0.1005
_reflns_number_gt                6199
_reflns_number_total             6898
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic052025asup1.cif
_cod_data_source_block           Ag2(L2)2(OTf)2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_database_code               4332015
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.10703(2) 0.575046(12) 0.218813(12) 0.02589(9) Uani 1 1 d .
Ag2 Ag 0.34186(2) 0.539405(13) 0.203738(12) 0.02654(9) Uani 1 1 d .
S1 S 0.18977(7) 0.73114(4) 0.23696(4) 0.0272(2) Uani 1 1 d .
S2 S 0.42086(8) 0.69028(4) 0.22935(4) 0.0280(2) Uani 1 1 d .
S3 S 0.15076(8) 0.58689(4) 0.37070(4) 0.0291(2) Uani 1 1 d .
S4 S 0.38524(8) 0.55883(4) 0.35348(4) 0.0275(2) Uani 1 1 d .
C1 C 0.1591(3) 0.70241(16) 0.17045(16) 0.0245(7) Uani 1 1 d .
C2 C 0.1157(3) 0.64101(18) 0.10381(17) 0.0306(8) Uani 1 1 d .
H2 H 0.0960 0.6052 0.0843 0.037 Uiso 1 1 calc R
C3 C 0.1303(3) 0.69642(19) 0.07996(18) 0.0356(9) Uani 1 1 d .
H3 H 0.1234 0.7063 0.0412 0.043 Uiso 1 1 calc R
C4 C 0.1721(4) 0.80095(18) 0.1166(2) 0.0398(10) Uani 1 1 d .
H4A H 0.1515 0.8213 0.1515 0.060 Uiso 1 1 calc R
H4B H 0.1295 0.8161 0.0854 0.060 Uiso 1 1 calc R
H4C H 0.2456 0.8093 0.1088 0.060 Uiso 1 1 calc R
C5 C 0.3262(3) 0.75143(17) 0.22934(16) 0.0254(8) Uani 1 1 d .
H5A H 0.3340 0.7742 0.1937 0.031 Uiso 1 1 calc R
H5B H 0.3443 0.7796 0.2603 0.031 Uiso 1 1 calc R
C6 C 0.4153(3) 0.66373(16) 0.16029(15) 0.0232(7) Uani 1 1 d .
C7 C 0.3931(3) 0.60482(19) 0.08898(17) 0.0317(9) Uani 1 1 d .
H7 H 0.3748 0.5705 0.0668 0.038 Uiso 1 1 calc R
C8 C 0.4362(3) 0.65664(18) 0.06867(17) 0.0314(9) Uani 1 1 d .
H8 H 0.4529 0.6655 0.0306 0.038 Uiso 1 1 calc R
C9 C 0.5044(3) 0.75236(18) 0.11386(18) 0.0361(9) Uani 1 1 d .
H9A H 0.4531 0.7851 0.1110 0.054 Uiso 1 1 calc R
H9B H 0.5515 0.7540 0.0815 0.054 Uiso 1 1 calc R
H9C H 0.5443 0.7571 0.1487 0.054 Uiso 1 1 calc R
C10 C 0.1081(3) 0.51974(17) 0.33871(16) 0.0254(8) Uani 1 1 d .
C11 C 0.0592(3) 0.45164(18) 0.27879(18) 0.0297(8) Uani 1 1 d .
H11 H 0.0430 0.4320 0.2443 0.036 Uiso 1 1 calc R
C12 C 0.0543(3) 0.42572(17) 0.33003(18) 0.0319(9) Uani 1 1 d .
H12 H 0.0332 0.3854 0.3382 0.038 Uiso 1 1 calc R
C13 C 0.0882(5) 0.4602(2) 0.42864(19) 0.0490(12) Uani 1 1 d .
H13A H 0.1362 0.4896 0.4455 0.074 Uiso 1 1 calc R
H13B H 0.1117 0.4189 0.4373 0.074 Uiso 1 1 calc R
H13C H 0.0183 0.4664 0.4440 0.074 Uiso 1 1 calc R
C14 C 0.2710(3) 0.60144(15) 0.33338(15) 0.0228(7) Uani 1 1 d .
H14A H 0.2583 0.5940 0.2929 0.027 Uiso 1 1 calc R
H14B H 0.2874 0.6451 0.3375 0.027 Uiso 1 1 calc R
C15 C 0.3565(3) 0.48763(16) 0.32466(16) 0.0232(7) Uani 1 1 d .
C16 C 0.3192(3) 0.41481(17) 0.26756(18) 0.0286(8) Uani 1 1 d .
H16 H 0.3012 0.3934 0.2343 0.034 Uiso 1 1 calc R
C17 C 0.3348(3) 0.38938(17) 0.31844(18) 0.0304(9) Uani 1 1 d .
H17 H 0.3306 0.3474 0.3273 0.036 Uiso 1 1 calc R
C18 C 0.3824(4) 0.4292(2) 0.41471(18) 0.0395(10) Uani 1 1 d .
H18A H 0.3950 0.4694 0.4311 0.059 Uiso 1 1 calc R
H18B H 0.4446 0.4040 0.4190 0.059 Uiso 1 1 calc R
H18C H 0.3238 0.4099 0.4340 0.059 Uiso 1 1 calc R
N1 N 0.1338(2) 0.64488(14) 0.16046(13) 0.0245(6) Uani 1 1 d .
N2 N 0.1568(3) 0.73514(14) 0.12244(14) 0.0286(7) Uani 1 1 d .
N3 N 0.3799(2) 0.60912(14) 0.14594(13) 0.0259(7) Uani 1 1 d .
N4 N 0.4505(2) 0.69351(14) 0.11450(13) 0.0266(7) Uani 1 1 d .
N5 N 0.0912(2) 0.51123(14) 0.28426(13) 0.0246(6) Uani 1 1 d .
N6 N 0.0858(3) 0.46869(15) 0.36806(14) 0.0305(7) Uani 1 1 d .
N7 N 0.3333(2) 0.47667(14) 0.27133(14) 0.0250(7) Uani 1 1 d .
N8 N 0.3579(3) 0.43580(14) 0.35497(14) 0.0276(7) Uani 1 1 d .
S5 S 0.17170(8) 0.44555(4) 0.11912(4) 0.0276(2) Uani 1 1 d .
O1 O 0.1039(2) 0.49514(13) 0.13373(12) 0.0375(7) Uani 1 1 d .
O2 O 0.2773(3) 0.45149(13) 0.13803(13) 0.0409(7) Uani 1 1 d .
O3 O 0.1268(3) 0.38627(12) 0.12659(13) 0.0392(7) Uani 1 1 d .
C19 C 0.1858(4) 0.4533(2) 0.04332(18) 0.0366(10) Uani 1 1 d .
F1 F 0.2530(3) 0.41352(14) 0.02299(12) 0.0583(8) Uani 1 1 d .
F2 F 0.0960(2) 0.44541(14) 0.01623(11) 0.0528(7) Uani 1 1 d .
F3 F 0.2200(3) 0.50883(12) 0.02989(11) 0.0548(8) Uani 1 1 d .
S6 S 0.33528(11) 0.77737(5) 0.41268(5) 0.0455(3) Uani 1 1 d .
O4 O 0.3118(5) 0.75443(19) 0.36144(17) 0.128(3) Uani 1 1 d D
O5 O 0.2536(4) 0.81849(18) 0.4353(2) 0.0874(15) Uani 1 1 d D
O6 O 0.4347(3) 0.80048(18) 0.42597(18) 0.0703(11) Uani 1 1 d D
C20 C 0.3207(4) 0.71371(18) 0.46013(18) 0.0370(10) Uani 1 1 d .
F4 F 0.3346(3) 0.72691(16) 0.51228(13) 0.0834(13) Uani 1 1 d .
F5 F 0.3769(3) 0.66705(13) 0.44423(16) 0.0720(10) Uani 1 1 d .
F6 F 0.2232(3) 0.69135(15) 0.45783(15) 0.0710(10) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N1 Ag1 N5 173.01(12) .
N1 Ag1 O1 89.14(11) .
N5 Ag1 O1 96.76(11) .
N1 Ag1 Ag2 87.15(9) .
N5 Ag1 Ag2 90.58(9) .
O1 Ag1 Ag2 76.38(7) .
N1 Ag1 Ag2 126.45(9) 6_556
N5 Ag1 Ag2 55.99(9) 6_556
O1 Ag1 Ag2 101.99(7) 6_556
Ag2 Ag1 Ag2 146.391(11) 6_556
N3 Ag2 N7 167.24(12) .
N3 Ag2 O2 102.84(11) .
N7 Ag2 O2 87.35(11) .
N3 Ag2 Ag1 96.60(9) .
N7 Ag2 Ag1 91.53(8) .
O2 Ag2 Ag1 87.02(7) .
N3 Ag2 Ag1 87.64(9) 6_656
N7 Ag2 Ag1 79.71(9) 6_656
O2 Ag2 Ag1 134.18(7) 6_656
Ag1 Ag2 Ag1 136.607(10) 6_656
C1 S1 C5 102.50(17) .
C6 S2 C5 102.77(17) .
C10 S3 C14 101.79(17) .
C15 S4 C14 100.96(17) .
N1 C1 N2 110.6(3) .
N1 C1 S1 124.2(3) .
N2 C1 S1 125.2(3) .
C3 C2 N1 109.3(4) .
C3 C2 H2 125.3 .
N1 C2 H2 125.3 .
C2 C3 N2 106.7(4) .
C2 C3 H3 126.7 .
N2 C3 H3 126.7 .
N2 C4 H4A 109.5 .
N2 C4 H4B 109.5 .
H4A C4 H4B 109.5 .
N2 C4 H4C 109.5 .
H4A C4 H4C 109.5 .
H4B C4 H4C 109.5 .
S2 C5 S1 117.7(2) .
S2 C5 H5A 107.9 .
S1 C5 H5A 107.9 .
S2 C5 H5B 107.9 .
S1 C5 H5B 107.9 .
H5A C5 H5B 107.2 .
N3 C6 N4 110.3(3) .
N3 C6 S2 123.9(3) .
N4 C6 S2 125.6(3) .
C8 C7 N3 110.2(4) .
C8 C7 H7 124.9 .
N3 C7 H7 124.9 .
C7 C8 N4 105.7(3) .
C7 C8 H8 127.2 .
N4 C8 H8 127.2 .
N4 C9 H9A 109.5 .
N4 C9 H9B 109.5 .
H9A C9 H9B 109.5 .
N4 C9 H9C 109.5 .
H9A C9 H9C 109.5 .
H9B C9 H9C 109.5 .
N5 C10 N6 110.5(3) .
N5 C10 S3 126.5(3) .
N6 C10 S3 123.0(3) .
C12 C11 N5 109.4(4) .
C12 C11 H11 125.3 .
N5 C11 H11 125.3 .
C11 C12 N6 106.9(3) .
C11 C12 H12 126.6 .
N6 C12 H12 126.6 .
N6 C13 H13A 109.5 .
N6 C13 H13B 109.5 .
H13A C13 H13B 109.5 .
N6 C13 H13C 109.5 .
H13A C13 H13C 109.5 .
H13B C13 H13C 109.5 .
S4 C14 S3 118.22(19) .
S4 C14 H14A 107.8 .
S3 C14 H14A 107.8 .
S4 C14 H14B 107.8 .
S3 C14 H14B 107.8 .
H14A C14 H14B 107.1 .
N7 C15 N8 111.1(3) .
N7 C15 S4 125.8(3) .
N8 C15 S4 123.1(3) .
C17 C16 N7 109.5(4) .
C17 C16 H16 125.3 .
N7 C16 H16 125.3 .
C16 C17 N8 106.9(3) .
C16 C17 H17 126.6 .
N8 C17 H17 126.6 .
N8 C18 H18A 109.5 .
N8 C18 H18B 109.5 .
H18A C18 H18B 109.5 .
N8 C18 H18C 109.5 .
H18A C18 H18C 109.5 .
H18B C18 H18C 109.5 .
C1 N1 C2 106.1(3) .
C1 N1 Ag1 128.3(3) .
C2 N1 Ag1 125.2(3) .
C1 N2 C3 107.3(3) .
C1 N2 C4 127.1(3) .
C3 N2 C4 125.4(3) .
C6 N3 C7 105.9(3) .
C6 N3 Ag2 124.6(3) .
C7 N3 Ag2 128.4(3) .
C6 N4 C8 107.9(3) .
C6 N4 C9 126.5(3) .
C8 N4 C9 125.3(3) .
C10 N5 C11 106.0(3) .
C10 N5 Ag1 127.7(3) .
C11 N5 Ag1 126.4(3) .
C10 N6 C12 107.2(3) .
C10 N6 C13 127.8(4) .
C12 N6 C13 124.8(4) .
C15 N7 C16 105.8(3) .
C15 N7 Ag2 126.5(2) .
C16 N7 Ag2 127.0(3) .
C15 N8 C17 106.8(3) .
C15 N8 C18 127.2(3) .
C17 N8 C18 125.9(3) .
O2 S5 O3 115.07(19) .
O2 S5 O1 115.34(18) .
O3 S5 O1 114.52(19) .
O2 S5 C19 102.0(2) .
O3 S5 C19 104.32(19) .
O1 S5 C19 103.2(2) .
S5 O1 Ag1 132.10(17) .
S5 O2 Ag2 123.57(17) .
F1 C19 F2 107.7(3) .
F1 C19 F3 107.6(4) .
F2 C19 F3 106.8(4) .
F1 C19 S5 111.4(3) .
F2 C19 S5 112.3(3) .
F3 C19 S5 110.8(3) .
O4 S6 O6 122.5(3) .
O4 S6 O5 113.3(3) .
O6 S6 O5 109.8(2) .
O4 S6 C20 104.4(2) .
O6 S6 C20 103.5(2) .
O5 S6 C20 100.0(3) .
F4 C20 F5 112.3(4) .
F4 C20 F6 104.5(4) .
F5 C20 F6 102.4(4) .
F4 C20 S6 114.3(3) .
F5 C20 S6 111.7(3) .
F6 C20 S6 110.7(3) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.100(3) .
Ag1 N5 2.106(3) .
Ag1 O1 2.681(3) .
Ag1 Ag2 3.1418(4) .
Ag1 Ag2 3.9549(4) 6_556
Ag2 N3 2.118(3) .
Ag2 N7 2.122(3) .
Ag2 O2 2.623(3) .
Ag2 Ag1 3.9549(4) 6_656
S1 C1 1.748(4) .
S1 C5 1.820(4) .
S2 C6 1.744(4) .
S2 C5 1.816(4) .
S3 C10 1.751(4) .
S3 C14 1.812(4) .
S4 C15 1.751(4) .
S4 C14 1.808(4) .
C1 N1 1.330(5) .
C1 N2 1.350(5) .
C2 C3 1.359(6) .
C2 N1 1.369(5) .
C2 H2 0.9500 .
C3 N2 1.365(5) .
C3 H3 0.9500 .
C4 N2 1.470(5) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C6 N3 1.331(5) .
C6 N4 1.349(5) .
C7 C8 1.358(6) .
C7 N3 1.368(5) .
C7 H7 0.9500 .
C8 N4 1.371(5) .
C8 H8 0.9500 .
C9 N4 1.470(5) .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 N5 1.326(5) .
C10 N6 1.354(5) .
C11 C12 1.346(6) .
C11 N5 1.382(5) .
C11 H11 0.9500 .
C12 N6 1.370(5) .
C12 H12 0.9500 .
C13 N6 1.452(6) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 N7 1.324(5) .
C15 N8 1.350(5) .
C16 C17 1.348(6) .
C16 N7 1.377(5) .
C16 H16 0.9500 .
C17 N8 1.374(5) .
C17 H17 0.9500 .
C18 N8 1.462(5) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
S5 O2 1.437(3) .
S5 O3 1.439(3) .
S5 O1 1.440(3) .
S5 C19 1.819(4) .
C19 F1 1.322(5) .
C19 F2 1.333(5) .
C19 F3 1.339(5) .
S6 O4 1.353(4) .
S6 O6 1.412(4) .
S6 O5 1.488(4) .
S6 C20 1.809(4) .
C20 F4 1.286(5) .
C20 F5 1.312(5) .
C20 F6 1.349(6) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Ag1 Ag2 N3 1.21(12) . .
N5 Ag1 Ag2 N3 -172.17(12) . .
O1 Ag1 Ag2 N3 91.02(11) . .
Ag2 Ag1 Ag2 N3 -177.74(9) 6_556 .
N1 Ag1 Ag2 N7 171.36(12) . .
N5 Ag1 Ag2 N7 -2.02(12) . .
O1 Ag1 Ag2 N7 -98.83(11) . .
Ag2 Ag1 Ag2 N7 -7.59(9) 6_556 .
N1 Ag1 Ag2 O2 -101.37(11) . .
N5 Ag1 Ag2 O2 85.24(11) . .
O1 Ag1 Ag2 O2 -11.57(9) . .
Ag2 Ag1 Ag2 O2 79.68(7) 6_556 .
N1 Ag1 Ag2 Ag1 94.77(9) . 6_656
N5 Ag1 Ag2 Ag1 -78.61(9) . 6_656
O1 Ag1 Ag2 Ag1 -175.43(7) . 6_656
Ag2 Ag1 Ag2 Ag1 -84.18(3) 6_556 6_656
C5 S1 C1 N1 114.2(3) . .
C5 S1 C1 N2 -66.5(4) . .
N1 C2 C3 N2 -0.6(5) . .
C6 S2 C5 S1 81.3(2) . .
C1 S1 C5 S2 -75.4(2) . .
C5 S2 C6 N3 -113.1(3) . .
C5 S2 C6 N4 70.5(3) . .
N3 C7 C8 N4 0.5(4) . .
C14 S3 C10 N5 -56.5(4) . .
C14 S3 C10 N6 124.8(3) . .
N5 C11 C12 N6 -1.4(5) . .
C15 S4 C14 S3 74.1(2) . .
C10 S3 C14 S4 -78.9(2) . .
C14 S4 C15 N7 55.4(4) . .
C14 S4 C15 N8 -126.3(3) . .
N7 C16 C17 N8 0.7(4) . .
N2 C1 N1 C2 0.6(4) . .
S1 C1 N1 C2 180.0(3) . .
N2 C1 N1 Ag1 -172.2(2) . .
S1 C1 N1 Ag1 7.1(5) . .
C3 C2 N1 C1 0.0(5) . .
C3 C2 N1 Ag1 173.1(3) . .
O1 Ag1 N1 C1 -170.3(3) . .
Ag2 Ag1 N1 C1 -93.9(3) . .
Ag2 Ag1 N1 C1 85.4(3) 6_556 .
O1 Ag1 N1 C2 18.1(3) . .
Ag2 Ag1 N1 C2 94.5(3) . .
Ag2 Ag1 N1 C2 -86.2(3) 6_556 .
N1 C1 N2 C3 -1.0(4) . .
S1 C1 N2 C3 179.7(3) . .
N1 C1 N2 C4 175.0(4) . .
S1 C1 N2 C4 -4.4(6) . .
C2 C3 N2 C1 0.9(5) . .
C2 C3 N2 C4 -175.1(4) . .
N4 C6 N3 C7 -0.3(4) . .
S2 C6 N3 C7 -177.1(3) . .
N4 C6 N3 Ag2 168.5(2) . .
S2 C6 N3 Ag2 -8.4(4) . .
C8 C7 N3 C6 -0.1(4) . .
C8 C7 N3 Ag2 -168.3(3) . .
N7 Ag2 N3 C6 -38.6(7) . .
O2 Ag2 N3 C6 179.0(3) . .
Ag1 Ag2 N3 C6 90.6(3) . .
Ag1 Ag2 N3 C6 -46.1(3) 6_656 .
N7 Ag2 N3 C7 127.5(5) . .
O2 Ag2 N3 C7 -14.8(3) . .
Ag1 Ag2 N3 C7 -103.3(3) . .
Ag1 Ag2 N3 C7 120.1(3) 6_656 .
N3 C6 N4 C8 0.6(4) . .
S2 C6 N4 C8 177.4(3) . .
N3 C6 N4 C9 -173.8(3) . .
S2 C6 N4 C9 3.0(5) . .
C7 C8 N4 C6 -0.7(4) . .
C7 C8 N4 C9 173.8(4) . .
N6 C10 N5 C11 -1.4(4) . .
S3 C10 N5 C11 179.7(3) . .
N6 C10 N5 Ag1 177.6(2) . .
S3 C10 N5 Ag1 -1.2(5) . .
C12 C11 N5 C10 1.7(4) . .
C12 C11 N5 Ag1 -177.3(3) . .
O1 Ag1 N5 C10 165.1(3) . .
Ag2 Ag1 N5 C10 88.8(3) . .
Ag2 Ag1 N5 C10 -94.9(3) 6_556 .
O1 Ag1 N5 C11 -16.0(3) . .
Ag2 Ag1 N5 C11 -92.4(3) . .
Ag2 Ag1 N5 C11 83.9(3) 6_556 .
N5 C10 N6 C12 0.6(4) . .
S3 C10 N6 C12 179.5(3) . .
N5 C10 N6 C13 -176.2(4) . .
S3 C10 N6 C13 2.7(6) . .
C11 C12 N6 C10 0.5(4) . .
C11 C12 N6 C13 177.4(4) . .
N8 C15 N7 C16 0.1(4) . .
S4 C15 N7 C16 178.6(3) . .
N8 C15 N7 Ag2 -170.6(2) . .
S4 C15 N7 Ag2 7.9(5) . .
C17 C16 N7 C15 -0.5(4) . .
C17 C16 N7 Ag2 170.1(3) . .
N3 Ag2 N7 C15 36.4(7) . .
O2 Ag2 N7 C15 179.8(3) . .
Ag1 Ag2 N7 C15 -93.3(3) . .
Ag1 Ag2 N7 C15 44.0(3) 6_656 .
N3 Ag2 N7 C16 -132.3(5) . .
O2 Ag2 N7 C16 11.1(3) . .
Ag1 Ag2 N7 C16 98.0(3) . .
Ag1 Ag2 N7 C16 -124.8(3) 6_656 .
N7 C15 N8 C17 0.3(4) . .
S4 C15 N8 C17 -178.2(3) . .
N7 C15 N8 C18 178.6(4) . .
S4 C15 N8 C18 0.0(6) . .
C16 C17 N8 C15 -0.6(4) . .
C16 C17 N8 C18 -178.9(4) . .
O2 S5 O1 Ag1 -27.1(3) . .
O3 S5 O1 Ag1 109.9(2) . .
C19 S5 O1 Ag1 -137.3(2) . .
N1 Ag1 O1 S5 114.5(3) . .
N5 Ag1 O1 S5 -61.8(3) . .
Ag2 Ag1 O1 S5 27.2(2) . .
Ag2 Ag1 O1 S5 -118.4(2) 6_556 .
O3 S5 O2 Ag2 -130.4(2) . .
O1 S5 O2 Ag2 6.4(3) . .
C19 S5 O2 Ag2 117.4(2) . .
N3 Ag2 O2 S5 -87.1(2) . .
N7 Ag2 O2 S5 100.7(2) . .
Ag1 Ag2 O2 S5 9.0(2) . .
Ag1 Ag2 O2 S5 173.57(14) 6_656 .
O2 S5 C19 F1 55.2(3) . .
O3 S5 C19 F1 -64.8(4) . .
O1 S5 C19 F1 175.2(3) . .
O2 S5 C19 F2 176.2(3) . .
O3 S5 C19 F2 56.1(4) . .
O1 S5 C19 F2 -63.9(3) . .
O2 S5 C19 F3 -64.6(4) . .
O3 S5 C19 F3 175.4(3) . .
O1 S5 C19 F3 55.4(4) . .
O4 S6 C20 F4 -176.5(5) . .
O6 S6 C20 F4 54.2(5) . .
O5 S6 C20 F4 -59.2(4) . .
O4 S6 C20 F5 54.6(5) . .
O6 S6 C20 F5 -74.7(4) . .
O5 S6 C20 F5 172.0(4) . .
O4 S6 C20 F6 -58.9(5) . .
O6 S6 C20 F6 171.9(3) . .
O5 S6 C20 F6 58.5(4) . .
