#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:48:37 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179425 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/22/4332281.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4332281
loop_
_publ_author_name
'Yamamura, Masaki'
'Kano, Naokazu'
'Kawashima, Takayuki'
_publ_section_title
;
 Systematic Study on the Structures and Reactivity of Hydrazobenzenes and
 Azobenzenes Bearing a Chalcogenophosphoryl Group
;
_journal_issue                   16
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6497
_journal_page_last               6507
_journal_paper_doi               10.1021/ic0601790
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'C24 H19 N2 P Se'
_chemical_formula_sum            'C24 H19 N2 P Se'
_chemical_formula_weight         445.34
_chemical_melting_point          130.5(5)
_chemical_name_common            'phosphine selenide'
_chemical_name_systematic
; 
Diphenyl[2-(phenylazo)phenyl]phosphine selenide
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.7375(15)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   8.604(4)
_cell_length_b                   23.038(9)
_cell_length_c                   20.764(9)
_cell_measurement_reflns_used    11922
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.4835
_cell_measurement_theta_min      3.0312
_cell_volume                     4114(3)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_molecular_graphics
'ORTEP-3 for Windows ver 1.08 (Farrugia, 1997-2005)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 14.5666
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_details
;
scan:
    Number of images: 600
               Slice: -70.0000 - 110.0000
         Image width: 0.3000
            Exp time: 22.0000
       Rotation axis: Omega
               Omega: 0.0000
                 Chi: 45.0000
                 Phi: 0.0000
                 XTD: 44.9617
              2theta: 19.9611
scan:
    Number of images: 600
               Slice: -70.0000 - 110.0000
         Image width: 0.3000
            Exp time: 22.0000
       Rotation axis: Omega
               Omega: 0.0000
                 Chi: 45.0000
                 Phi: 90.0000
                 XTD: 44.9617
              2theta: 19.9611

;
_diffrn_measurement_device
;
Mercury CCD (2x2 bin mode)
;
_diffrn_measurement_device_details
;
AFC8: Eulerian 3-circle
;
_diffrn_measurement_method       dtintegrate.ref
_diffrn_orient_matrix_type       d*Trek
_diffrn_orient_matrix_UB_11      -0.1132
_diffrn_orient_matrix_UB_12      -0.0175
_diffrn_orient_matrix_UB_13      -0.0201
_diffrn_orient_matrix_UB_21      0.0084
_diffrn_orient_matrix_UB_22      -0.0056
_diffrn_orient_matrix_UB_23      -0.0422
_diffrn_orient_matrix_UB_31      0.0045
_diffrn_orient_matrix_UB_32      -0.0474
_diffrn_orient_matrix_UB_33      0.0072
_diffrn_radiation_detector       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0482
_diffrn_reflns_av_sigmaI/netI    0.0586
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            25529
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.07
_diffrn_source_current           40.0000
_diffrn_source_power             2.0000
_diffrn_source_voltage           50.0000
_exptl_absorpt_coefficient_mu    1.915
_exptl_absorpt_correction_T_max  0.7007
_exptl_absorpt_correction_T_min  0.7007
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Jacobson, R. (1998) Private communication
;
_exptl_crystal_colour            Orange
_exptl_crystal_density_diffrn    1.438
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1808
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.220
_refine_diff_density_min         -0.543
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.109
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     505
_refine_ls_number_reflns         7208
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.109
_refine_ls_R_factor_all          0.0632
_refine_ls_R_factor_gt           0.0533
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0836P)²+1.2501P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1421
_refine_ls_wR_factor_ref         0.1519
_reflns_number_gt                6252
_reflns_number_total             7208
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0601790sup1.cif
_cod_data_source_block           compoundE9
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value '130-131' was changed to '130.5(5)' -
the average value was taken and precision was
estimated.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4332281
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.69528(12) 0.30984(4) 0.22616(5) 0.0161(2) Uani 1 1 d . . .
C1 C 0.6823(4) 0.24921(16) 0.17073(18) 0.0159(8) Uani 1 1 d . . .
C2 C 0.7344(4) 0.19422(16) 0.18853(19) 0.0178(8) Uani 1 1 d . . .
H1 H 0.7875 0.1887 0.2288 0.021 Uiso 1 1 calc R . .
C3 C 0.7086(5) 0.14720(18) 0.1472(2) 0.0221(9) Uani 1 1 d . .. .
H2 H 0.7424 0.1095 0.1599 0.027 Uiso 1 1 calc R . .
C4 C 0.6335(5) 0.15530(17) 0.0874(2) 0.0210(9) Uani 1 1 d . . .
H3 H 0.6169 0.1232 0.0593 0.025 Uiso 1 1 calc R . .
C5 C 0.5832(5) 0.20984(17) 0.06876(19) 0.0209(9) Uani 1 1 d . .. .
H4 H 0.5322 0.2152 0.0280 0.025 Uiso 1 1 calc R . .
C6 C 0.6074(4) 0.25707(16) 0.10999(18) 0.0167(8) Uani 1 1 d . . .
N1 N 0.5536(4) 0.31417(14) 0.09825(15) 0.0182(7) Uani 1 1 d . . .
N2 N 0.4918(4) 0.32275(14) 0.04391(16) 0.0199(7) Uani 1 1 d . . .
C7 C 0.4313(5) 0.38022(17) 0.03527(19) 0.0196(8) Uani 1 1 d . . .
C8 C 0.3780(5) 0.39460(18) -0.0256(2) 0.0233(9) Uani 1 1 d . . .
H5 H 0.3849 0.3673 -0.0598 0.028 Uiso 1 1 calc R .. .
C9 C 0.3135(5) 0.44958(19) -0.0373(2) 0.0283(10) Uani 1 1 d . . .
H6 H 0.2775 0.4599 -0.0795 0.034 Uiso 1 1 calc R . .
C10 C 0.3025(5) 0.48863(18) 0.0127(2) 0.0242(9) Uani 1 1 d . . .
H7 H 0.2578 0.5258 0.0051 0.029 Uiso 1 1 calc R . ..
C11 C 0.3562(5) 0.47369(18) 0.0734(2) 0.0253(9) Uani 1 1 d . . .
H8 H 0.3487 0.5010 0.1074 0.030 Uiso 1 1 calc R . .
C12 C 0.4209(5) 0.41990(17) 0.0861(2) 0.0216(9) Uani 1 1 d . . .
H9 H 0.4574 0.4100 0.1283 0.026 Uiso 1 1 calc R . ..
Se1 Se 0.47795(5) 0.334353(18) 0.26126(2) 0.02075(15) Uani 1 1 d . . .
C13 C 0.7991(4) 0.36753(16) 0.18652(18) 0.0164(8) Uani 1 1 d . . .
C14 C 0.9031(5) 0.35578(18) 0.1390(2) 0.0237(9) Uani 1 1 d . . .
H10 H 0.9176 0.3170 0.1247 0.028 Uiso 1 1 calc R . .
C15 C 0.9866(5) 0.4009(2) 0.1122(2) 0.0288(10) Uani 1 1 d . . .
H11 H 1.0587 0.3928 0.0797 0.035 Uiso 1 1 calc R . .
C16 C 0.9662(5) 0.45684(19) 0.1323(2) 0.0275(10) Uani 1 1 d . . .
H12 H 1.0245 0.4873 0.1139 0.033 Uiso 1 1 calc R . .
C17 C 0.8608(5) 0.46916(18) 0.1794(2) 0.0257(10) Uani 1 1 d . . .
H13 H 0.8458 0.5080 0.1931 0.031 Uiso 1 1 calc R .. .
C18 C 0.7774(5) 0.42457(17) 0.2062(2) 0.0207(9) Uani 1 1 d . . .
H14 H 0.7045 0.4329 0.2385 0.025 Uiso 1 1 calc R . .
C19 C 0.8281(4) 0.28609(16) 0.29154(18) 0.0169(8) Uani 1 1 d . . .
C20 C 0.7696(5) 0.27187(17) 0.3513(2) 0.0218(9) Uani 1 1 d . . .
H15 H 0.6610 0.2738 0.3580 0.026 Uiso 1 1 calc R . .
C21 C 0.8707(5) 0.25494(18) 0.4008(2) 0.0244(9) Uani 1 1 d . . .
H16 H 0.8311 0.2458 0.4418 0.029 Uiso 1 1 calc R . ..
C22 C 1.0273(5) 0.25122(18) 0.3914(2) 0.0253(10) Uani 1 1 d . . .
H17 H 1.0955 0.2395 0.4258 0.030 Uiso 1 1 calc R . .
C23 C 1.0865(5) 0.26456(19) 0.3318(2) 0.0283(10) Uani 1 1 d . . .
H18 H 1.1951 0.2619 0.3253 0.034 Uiso 1 1 calc R .. .
C24 C 0.9858(5) 0.28196(18) 0.2814(2) 0.0222(9) Uani 1 1 d . . .
H19 H 1.0255 0.2909 0.2403 0.027 Uiso 1 1 calc R . .
P2 P 0.32343(12) 0.58840(4) 0.25673(5) 0.0165(2) Uani 1 1 d . . .
Se2 Se 0.54674(5) 0.567976(18) 0.22510(2) 0.02207(15) Uani 1 1 d . . .
C25 C 0.3209(4) 0.64407(17) 0.31925(18) 0.0173(8) Uani 1 1 d . . .
C26 C 0.2556(4) 0.69835(17) 0.3082(2) 0.0193(9) Uani 1 1 d . .. .
H20 H 0.2037 0.7063 0.2681 0.023 Uiso 1 1 calc R . .
C27 C 0.2655(5) 0.74129(18) 0.3555(2) 0.0223(9) Uani 1 1 d . . .
H21 H 0.2199 0.7783 0.3478 0.027 Uiso 1 1 calc R . .
C28 C 0.3423(5) 0.72973(18) 0.4139(2) 0.0229(9) Uani 1 1 d .. . .
H22 H 0.3501 0.7592 0.4458 0.027 Uiso 1 1 calc R . .
C29 C 0.4070(5) 0.67616(17) 0.42606(19) 0.0202(9) Uani 1 1 d . . .
H23 H 0.4582 0.6684 0.4663 0.024 Uiso 1 1 calc R . .
C30 C 0.3970(4) 0.63332(16) 0.37885(19) 0.0177(8) Uani 1 1 d . . .
N3 N 0.4608(4) 0.57652(14) 0.38661(16) 0.0191(7) Uani 1 1 d . . .
N4 N 0.5567(4) 0.57188(14) 0.43326(16) 0.0194(7) Uani 1 1 d . . .
C31 C 0.6228(4) 0.51553(16) 0.44016(19) 0.0188(9) Uani 1 1 d . . .
C32 C 0.7298(5) 0.50826(18) 0.49087(19) 0.0213(9) Uani 1 1 d . . .
H24 H 0.7514 0.5396 0.5196 0.026 Uiso 1 1 calc R . .
C33 C 0.8052(5) 0.45585(19) 0.4999(2) 0.0258(9) Uani 1 1 d . . .
H25 H 0.8794 0.4513 0.5343 0.031 Uiso 1 1 calc R . .
C34 C 0.7721(5) 0.40965(19) 0.4584(2) 0.0262(10) Uani 1 1 d . . .
H26 H 0.8237 0.3735 0.4644 0.031 Uiso 1 1 calc R . .
C35 C 0.6638(5) 0.41679(18) 0.4087(2) 0.0260(10) Uani 1 1 d . . .
H27 H 0.6401 0.3850 0.3810 0.031 Uiso 1 1 calc R . .
C36 C 0.5889(5) 0.46936(18) 0.3984(2) 0.0245(9) Uani 1 1 d . . .
H28 H 0.5158 0.4739 0.3636 0.029 Uiso 1 1 calc R . ..
C37 C 0.2172(4) 0.52737(16) 0.28771(19) 0.0175(8) Uani 1 1 d . . .
C38 C 0.0952(4) 0.53656(17) 0.32930(18) 0.0193(8) Uani 1 1 d . . .
H29 H 0.0718 0.5748 0.3433 0.023 Uiso 1 1 calc R . .
C39 C 0.0089(5) 0.49030(18) 0.3501(2) 0.0235(9) Uani 1 1 d . . .
H30 H -0.0742 0.4965 0.3784 0.028 Uiso 1 1 calc R . .
C40 C 0.0434(5) 0.43457(18) 0.3295(2) 0.0255(10) Uani 1 1 d . . .
H31 H -0.0162 0.4027 0.3440 0.031 Uiso 1 1 calc R . .
C41 C 0.1620(5) 0.42529(18) 0.2888(2) 0.0242(9) Uani 1 1 d . . .
H32 H 0.1844 0.3870 0.2749 0.029 Uiso 1 1 calc R . .
C42 C 0.2503(5) 0.47148(17) 0.2677(2) 0.0201(9) Uani 1 1 d . . .
H33 H 0.3335 0.4648 0.2396 0.024 Uiso 1 1 calc R . ..
C43 C 0.1966(5) 0.61451(16) 0.19057(19) 0.0186(8) Uani 1 1 d . . .
C44 C 0.2570(5) 0.62456(17) 0.13056(19) 0.0221(9) Uani 1 1 d . . .
H34 H 0.3652 0.6197 0.1245 0.026 Uiso 1 1 calc R . .
C45 C 0.1596(5) 0.64190(19) 0.0787(2) 0.0294(10) Uani 1 1 d . . .
H35 H 0.2016 0.6488 0.0376 0.035 Uiso 1 1 calc R . .
C46 C 0.0041(5) 0.64886(19) 0.0876(2) 0.0300(10) Uani 1 1 d . . .
H36 H -0.0626 0.6601 0.0525 0.036 Uiso 1 1 calc R .. .
C47 C -0.0565(5) 0.63961(19) 0.1477(2) 0.0292(10) Uani 1 1 d . . .
H37 H -0.1644 0.6452 0.1539 0.035 Uiso 1 1 calc R . .
C48 C 0.0385(5) 0.62245(18) 0.1985(2) 0.0233(9) Uani 1 1 d .. . .
H38 H -0.0044 0.6159 0.2394 0.028 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 P1 C13 107.38(18) . .
C1 P1 C19 105.40(18) . ..
C13 P1 C19 104.50(18) . .
C1 P1 Se1 112.87(13) . .
C13 P1 Se1 114.58(13) . .
C19 P1 Se1 111.37(13) . .
C2 C1 C6 119.3(3) . .
C2 C1 P1 121.4(3) . .
C6 C1 P1 119.1(3) . .
C1 C2 C3 120.0(4) . ..
C1 C2 H1 120.0 . .
C3 C2 H1 120.0 . .
C2 C3 C4 120.3(4) . .
C2 C3 H2 119.9 . .
C4 C3 H2 119.9 . .
C5 C4 C3 120.2(4) . .
C5 C4 H3 119.9 . ..
C3 C4 H3 119.9 . .
C4 C5 C6 119.9(4) . .
C4 C5 H4 120.1 . .
C6 C5 H4 120.1 . .
C5 C6 C1 120.3(4) . .
C5 C6 N1 125.3(4) . .
C1 C6 N1 114.3(3) . .
N2 N1 C6 115.6(3) . .
N1 N2 C7 113.8(3) . .
C8 C7 C12 120.6(4) . ..
C8 C7 N2 116.6(3) . .
C12 C7 N2 122.7(4) . .
C7 C8 C9 119.8(4) . .
C7 C8 H5 120.1 . .
C9 C8 H5 120.1 . .
C10 C9 C8 119.7(4) . .
C10 C9 H6 120.2 . .
C8 C9 H6 120.2 . .
C11 C10 C9 119.9(4) . .
C11 C10 H7 120.0 . .
C9 C10 H7 120.0 . .
C10 C11 C12 121.5(4) . .
C10 C11 H8 119.2 . .
C12 C11 H8 119.2 . .
C11 C12 C7 118.4(4) . ..
C11 C12 H9 120.8 . .
C7 C12 H9 120.8 . .
C14 C13 C18 119.5(4) . .
C14 C13 P1 121.4(3) . .
C18 C13 P1 119.1(3) .. .
C13 C14 C15 119.6(4) . .
C13 C14 H10 120.2 . .
C15 C14 H10 120.2 . .
C16 C15 C14 120.7(4) . .
C16 C15 H11 119.7 . .
C14 C15 H11 119.7 . .
C15 C16 C17 120.1(4) . .
C15 C16 H12 119.9 .. .
C17 C16 H12 119.9 . .
C18 C17 C16 119.5(4) . .
C18 C17 H13 120.2 . .
C16 C17 H13 120.2 . .
C17 C18 C13 120.5(4) . .
C17 C18 H14 119.7 . .
C13 C18 H14 119.7 . .
C24 C19 C20 120.2(4) .. .
C24 C19 P1 120.0(3) . .
C20 C19 P1 119.8(3) . .
C21 C20 C19 119.5(4) . ..
C21 C20 H15 120.3 . .
C19 C20 H15 120.3 . .
C22 C21 C20 120.8(4) . .
C22 C21 H16 119.6 . .
C20 C21 H16 119.6 . .
C21 C22 C23 120.1(4) . .
C21 C22 H17 119.9 . .
C23 C22 H17 119.9 . ..
C22 C23 C24 119.8(4) . .
C22 C23 H18 120.1 . .
C24 C23 H18 120.1 . .
C19 C24 C23 119.6(4) . .
C19 C24 H19 120.2 . .
C23 C24 H19 120.2 . .
C37 P2 C25 106.05(18) . .
C37 P2 C43 103.09(18) . .
C25 P2 C43 106.45(18) . .
C37 P2 Se2 114.47(13) . .
C25 P2 Se2 114.22(13) . .
C43 P2 Se2 111.64(14) . .
C26 C25 C30 118.7(4) . .
C26 C25 P2 121.9(3) . .
C30 C25 P2 119.2(3) . .
C25 C26 C27 120.5(4) . .
C25 C26 H20 119.8 .. .
C27 C26 H20 119.8 . .
C28 C27 C26 119.7(4) . .
C28 C27 H21 120.1 . .
C26 C27 H21 120.1 . .
C29 C28 C27 120.8(4) . .
C29 C28 H22 119.6 . .
C27 C28 H22 119.6 . .
C28 C29 C30 119.4(4) .. .
C28 C29 H23 120.3 . .
C30 C29 H23 120.3 . .
C29 C30 C25 120.9(4) . .
C29 C30 N3 123.7(4) . .
C25 C30 N3 115.4(3) . .
N4 N3 C30 114.0(3) . .
N3 N4 C31 114.0(3) . .
C32 C31 C36 120.0(4) .. .
C32 C31 N4 116.1(3) . .
C36 C31 N4 123.9(4) . .
C33 C32 C31 120.5(4) . ..
C33 C32 H24 119.8 . .
C31 C32 H24 119.8 . .
C32 C33 C34 119.9(4) . .
C32 C33 H25 120.1 . .
C34 C33 H25 120.1 . .
C35 C34 C33 119.5(4) . .
C35 C34 H26 120.2 . .
C33 C34 H26 120.2 . ..
C34 C35 C36 121.3(4) . .
C34 C35 H27 119.3 . .
C36 C35 H27 119.3 . .
C35 C36 C31 118.9(4) . .
C35 C36 H28 120.6 . .
C31 C36 H28 120.6 . .
C42 C37 C38 119.5(4) . .
C42 C37 P2 120.4(3) .. .
C38 C37 P2 120.0(3) . .
C39 C38 C37 120.0(4) . .
C39 C38 H29 120.0 . .
C37 C38 H29 120.0 . .
C38 C39 C40 119.9(4) . .
C38 C39 H30 120.1 . .
C40 C39 H30 120.1 . .
C41 C40 C39 120.5(4) .. .
C41 C40 H31 119.8 . .
C39 C40 H31 119.8 . .
C40 C41 C42 120.3(4) . .
C40 C41 H32 119.9 . .
C42 C41 H32 119.9 . .
C37 C42 C41 120.0(4) . .
C37 C42 H33 120.0 . .
C41 C42 H33 120.0 . ..
C44 C43 C48 118.7(4) . .
C44 C43 P2 119.9(3) . .
C48 C43 P2 121.3(3) . .
C43 C44 C45 120.4(4) . .
C43 C44 H34 119.8 . .
C45 C44 H34 119.8 . .
C46 C45 C44 119.6(4) . .
C46 C45 H35 120.2 .. .
C44 C45 H35 120.2 . .
C45 C46 C47 120.1(4) . .
C45 C46 H36 119.9 . .
C47 C46 H36 119.9 . .
C48 C47 C46 120.3(4) . .
C48 C47 H37 119.8 . .
C46 C47 H37 119.8 . .
C47 C48 C43 120.7(4) .. .
C47 C48 H38 119.6 . .
C43 C48 H38 119.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
P1 C1 1.811(4)
P1 C13 1.813(4)
P1 C19 1.832(4)
P1 Se1 2.1045(13)
C1 C2 1.390(5)
C1 C6 1.410(5)
C2 C3 1.395(6)
C2 H1 0.9500
C3 C4 1.396(6)
C3 H2 0.9500
C4 C5 1.380(6)
C4 H3 0.9500
C5 C6 1.396(5)
C5 H4 0.9500
C6 N1 1.413(5)
N1 N2 1.248(5)
N2 C7 1.432(5)
C7 C8 1.373(5)
C7 C12 1.401(6)
C8 C9 1.401(6)
C8 H5 0.9500
C9 C10 1.379(6)
C9 H6 0.9500
C10 C11 1.374(6)
C10 H7 0.9500
C11 C12 1.380(6)
C11 H8 0.9500
C12 H9 0.9500
C13 C14 1.378(6)
C13 C18 1.391(5)
C14 C15 1.389(6)
C14 H10 0.9500
C15 C16 1.369(6)
C15 H11 0.9500
C16 C17 1.382(6)
C16 H12 0.9500
C17 C18 1.380(6)
C17 H13 0.9500
C18 H14 0.9500
C19 C24 1.383(6)
C19 C20 1.392(6)
C20 C21 1.382(6)
C20 H15 0.9500
C21 C22 1.370(6)
C21 H16 0.9500
C22 C23 1.388(6)
C22 H17 0.9500
C23 C24 1.397(6)
C23 H18 0.9500
C24 H19 0.9500
P2 C37 1.806(4)
P2 C25 1.826(4)
P2 C43 1.830(4)
P2 Se2 2.1025(13)
C25 C26 1.387(6)
C25 C30 1.404(5)
C26 C27 1.395(6)
C26 H20 0.9500
C27 C28 1.390(6)
C27 H21 0.9500
C28 C29 1.374(6)
C28 H22 0.9500
C29 C30 1.392(5)
C29 H23 0.9500
C30 N3 1.426(5)
N3 N4 1.258(5)
N4 C31 1.422(5)
C31 C32 1.388(6)
C31 C36 1.397(6)
C32 C33 1.381(6)
C32 H24 0.9500
C33 C34 1.393(6)
C33 H25 0.9500
C34 C35 1.379(6)
C34 H26 0.9500
C35 C36 1.385(6)
C35 H27 0.9500
C36 H28 0.9500
C37 C42 1.385(5)
C37 C38 1.395(5)
C38 C39 1.376(6)
C38 H29 0.9500
C39 C40 1.388(6)
C39 H30 0.9500
C40 C41 1.362(6)
C40 H31 0.9500
C41 C42 1.386(6)
C41 H32 0.9500
C42 H33 0.9500
C43 C44 1.384(6)
C43 C48 1.387(6)
C44 C45 1.403(6)
C44 H34 0.9500
C45 C46 1.366(6)
C45 H35 0.9500
C46 C47 1.383(6)
C46 H36 0.9500
C47 C48 1.373(6)
C47 H37 0.9500
C48 H38 0.9500
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C13 P1 C1 C2 125.6(3) . . . .
C19 P1 C1 C2 14.6(4) . . . .
Se1 P1 C1 C2 -107.2(3) .. . . .
C13 P1 C1 C6 -59.1(3) . . . .
C19 P1 C1 C6 -170.1(3) . . . .
Se1 P1 C1 C6 68.1(3) . . . .
C6 C1 C2 C3 -1.8(6) . . . .
P1 C1 C2 C3 173.5(3) . . .. .
C1 C2 C3 C4 1.3(6) . . . .
C2 C3 C4 C5 -0.4(6) . . . .
C3 C4 C5 C6 -0.1(6) . . . .
C4 C5 C6 C1 -0.4(6) . .. . .
C4 C5 C6 N1 -176.0(4) . . . .
C2 C1 C6 C5 1.3(6) . . . .
P1 C1 C6 C5 -174.1(3) . . . .
C2 C1 C6 N1 177.4(3) . . . .
P1 C1 C6 N1 2.0(5) . . .. .
C5 C6 N1 N2 -6.5(6) . . . .
C1 C6 N1 N2 177.6(3) . . . .
C6 N1 N2 C7 176.7(3) . . . .
N1 N2 C7 C8 172.7(4) .. . . .
N1 N2 C7 C12 -9.4(6) . . . .
C12 C7 C8 C9 0.4(6) . . . .
N2 C7 C8 C9 178.4(4) . . . .
C7 C8 C9 C10 -0.7(7) . . . .
C8 C9 C10 C11 0.7(7) . . .. .
C9 C10 C11 C12 -0.4(7) . . . .
C10 C11 C12 C7 0.2(6) . . . .
C8 C7 C12 C11 -0.2(6) . . . .
N2 C7 C12 C11 -178.0(4) . . . .
C1 P1 C13 C14 -26.0(4) . .. . .
C19 P1 C13 C14 85.7(4) . . . .
Se1 P1 C13 C14 -152.2(3) . . . .
C1 P1 C13 C18 156.4(3) . . . .
C19 P1 C13 C18 -92.0(3) . . . .
Se1 P1 C13 C18 30.2(3) . . . .
C18 C13 C14 C15 1.1(6) . .. . .
P1 C13 C14 C15 -176.5(3) . . . .
C13 C14 C15 C16 -0.3(6) . . . .
C14 C15 C16 C17 -0.5(7) . . . .
C15 C16 C17 C18 0.5(6) . . . .
C16 C17 C18 C13 0.2(6) . . . .
C14 C13 C18 C17 -1.0(6) . .. . .
P1 C13 C18 C17 176.6(3) . . . .
C1 P1 C19 C24 73.2(4) . . . .
C13 P1 C19 C24 -39.8(4) . . . .
Se1 P1 C19 C24 -164.1(3) . . . .
C1 P1 C19 C20 -106.4(3) . . . .
C13 P1 C19 C20 140.6(3) .. . . .
Se1 P1 C19 C20 16.4(4) . . . .
C24 C19 C20 C21 1.5(6) . . . .
P1 C19 C20 C21 -178.9(3) . . . .
C19 C20 C21 C22 -0.9(6) . . . .
C20 C21 C22 C23 0.1(6) .. . . .
C21 C22 C23 C24 0.2(6) . . . .
C20 C19 C24 C23 -1.3(6) . . . .
P1 C19 C24 C23 179.1(3) . . . .
C22 C23 C24 C19 0.4(6) . . . .
C37 P2 C25 C26 -120.0(3) . . . .
C43 P2 C25 C26 -10.7(4) .. . . .
Se2 P2 C25 C26 113.0(3) . . . ..
C37 P2 C25 C30 64.7(4) . . . .
C43 P2 C25 C30 174.0(3) . . . .
Se2 P2 C25 C30 -62.3(3) . . . .
C30 C25 C26 C27 0.0(6) . . . .
P2 C25 C26 C27 -175.4(3) . .. . .
C25 C26 C27 C28 0.5(6) . . . .
C26 C27 C28 C29 -0.8(6) . . . .
C27 C28 C29 C30 0.8(6) . . . .
C28 C29 C30 C25 -0.4(6) . . . .
C28 C29 C30 N3 179.7(4) . . . .
C26 C25 C30 C29 0.0(6) . .. . .
P2 C25 C30 C29 175.4(3) . . . .
C26 C25 C30 N3 179.9(3) . . . .
P2 C25 C30 N3 -4.7(5) . . . .
C29 C30 N3 N4 -15.2(6) . . . .
C25 C30 N3 N4 164.9(3) . .. . .
C30 N3 N4 C31 -178.8(3) . . . .
N3 N4 C31 C32 179.8(3) . . . .
N3 N4 C31 C36 1.6(6) . . . .
C36 C31 C32 C33 1.0(6) . . . .
N4 C31 C32 C33 -177.3(4) . . . .
C31 C32 C33 C34 -0.9(6) .. . . .
C32 C33 C34 C35 -0.1(6) . . . ..
C33 C34 C35 C36 1.1(7) . . . .
C34 C35 C36 C31 -1.0(7) . . . .
C32 C31 C36 C35 0.0(6) . . . .
N4 C31 C36 C35 178.1(4) . . . .
C25 P2 C37 C42 -152.2(3) .. . . .
C43 P2 C37 C42 96.1(3) . . . .
Se2 P2 C37 C42 -25.3(4) . . . .
C25 P2 C37 C38 31.3(4) . . . .
C43 P2 C37 C38 -80.3(3) . . . .
Se2 P2 C37 C38 158.2(3) . . . .
C42 C37 C38 C39 -0.1(6) . .. . .
P2 C37 C38 C39 176.4(3) . . . .
C37 C38 C39 C40 0.0(6) . . . .
C38 C39 C40 C41 -0.1(7) . . . .
C39 C40 C41 C42 0.4(7) . . . .
C38 C37 C42 C41 0.3(6) .. . . .
P2 C37 C42 C41 -176.2(3) . . . ..
C40 C41 C42 C37 -0.5(6) . . . .
C37 P2 C43 C44 -130.3(3) . . . .
C25 P2 C43 C44 118.3(3) . . . .
Se2 P2 C43 C44 -6.9(4) . . . .
C37 P2 C43 C48 47.2(4) . .. . .
C25 P2 C43 C48 -64.2(4) . . . .
Se2 P2 C43 C48 170.5(3) . . . .
C48 C43 C44 C45 -0.6(6) . . . .
P2 C43 C44 C45 176.9(3) . . . .
C43 C44 C45 C46 0.0(6) . . . .
C44 C45 C46 C47 0.9(7) . .. . .
C45 C46 C47 C48 -1.1(7) . . . .
C46 C47 C48 C43 0.5(7) . . . .
C44 C43 C48 C47 0.4(6) . . . .
P2 C43 C48 C47 -177.1(3) . . . .
