#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:49:57 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179426 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/23/4332394.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4332394
loop_
_publ_author_name
'Croizat, Pierre'
'Auvray, Nicolas'
'Braunstein, Pierre'
'Welter, Richard'
_publ_section_title
;
 Comparative Bonding Behavior of Functional Cyclopentadienyl Ligands and
 Boron-Containing Analogues in Heterometallic Complexes and
 Clusters†
;
_journal_issue                   15
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5852
_journal_page_last               5866
_journal_paper_doi               10.1021/ic060318d
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'C32 H50 Mo2 N2 O6 P2 Pt2'
_chemical_formula_sum            'C32 H50 Mo2 N2 O6 P2 Pt2'
_chemical_formula_weight         1202.74
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.28(5)
_cell_angle_beta                 97.83(5)
_cell_angle_gamma                101.97(5)
_cell_formula_units_Z            1
_cell_length_a                   8.9590(10)
_cell_length_b                   10.1280(10)
_cell_length_c                   11.0770(10)
_cell_measurement_reflns_used    28319
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.034
_cell_measurement_theta_min      0.998
_cell_volume                     911.4(5)
_computing_cell_refinement       'Denzo (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo (Nonius B.V., 1998)'
_computing_molecular_graphics    'PLATON 98 (Spek, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'π scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.1260
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            5287
_diffrn_reflns_theta_full        30.18
_diffrn_reflns_theta_max         30.18
_diffrn_reflns_theta_min         3.26
_exptl_absorpt_coefficient_mu    8.454
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            violet
_exptl_crystal_density_diffrn    2.191
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             574
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.07
_refine_diff_density_max         2.228
_refine_diff_density_min         -2.855
_refine_diff_density_rms         0.329
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     208
_refine_ls_number_reflns         5286
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0815
_refine_ls_R_factor_gt           0.0623
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0142P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1370
_refine_ls_wR_factor_ref         0.1465
_reflns_number_gt                4338
_reflns_number_total             5286
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic060318dsup6.cif
_cod_data_source_block           croizat
_cod_original_cell_volume        911.43(46)
_cod_database_code               4332394
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
Pt Pt 0.41608(4) 0.39245(4) 0.89350(3) 0.02485(12) Uani 1 1 d
Mo Mo 0.41046(9) 0.35311(8) 1.12981(7) 0.02452(17) Uani 1 1 d
P P 0.2729(3) 0.1886(3) 0.7271(2) 0.0286(5) Uani 1 1 d
O1 O 0.7074(9) 0.5249(8) 1.3393(7) 0.0375(16) Uani 1 1 d
O2 O 0.6044(8) 0.1927(8) 0.9502(7) 0.0372(15) Uani 1 1 d
O3 O 0.1892(9) 0.5319(9) 1.0498(8) 0.0425(17) Uani 1 1 d
N N 0.0754(10) 0.3510(11) 1.2569(9) 0.041(2) Uani 1 1 d
C1 C 0.6085(11) 0.4920(10) 1.2478(8) 0.0297(19) Uani 1 1 d
C3 C 0.2840(12) 0.4743(11) 1.0691(10) 0.035(2) Uani 1 1 d
C2 C 0.5293(11) 0.2651(11) 1.0045(9) 0.032(2) Uani 1 1 d
C4 C 0.3471(12) 0.3343(11) 1.3214(10) 0.034(2) Uani 1 1 d
H4 H 0.3853 0.4176 1.3982 0.041 Uiso 1 1 calc
C5 C 0.4314(14) 0.2335(13) 1.2725(10) 0.043(3) Uani 1 1 d
H5 H 0.5320 0.2334 1.3127 0.052 Uiso 1 1 calc
C6 C 0.3380(16) 0.1325(13) 1.1519(13) 0.051(3) Uani 1 1 d
H6 H 0.3648 0.0519 1.0972 0.061 Uiso 1 1 calc
C7 C 0.1979(12) 0.1725(11) 1.1274(9) 0.037(2) Uani 1 1 d
H7 H 0.1180 0.1276 1.0503 0.044 Uiso 1 1 calc
C8 C 0.1965(11) 0.2931(11) 1.2390(9) 0.032(2) Uani 1 1 d
C9 C 0.1041(15) 0.4909(15) 1.3532(11) 0.052(3) Uani 1 1 d
H9A H 0.1668 0.4947 1.4346 0.078 Uiso 1 1 calc
H9B H 0.0043 0.5105 1.3684 0.078 Uiso 1 1 calc
H9C H 0.1608 0.5635 1.3228 0.078 Uiso 1 1 calc
C10 C -0.0557(13) 0.3119(15) 1.1502(12) 0.049(3) Uani 1 1 d
H10A H -0.0211 0.3432 1.0810 0.074 Uiso 1 1 calc
H10B H -0.1357 0.3588 1.1805 0.074 Uiso 1 1 calc
H10C H -0.0994 0.2070 1.1163 0.074 Uiso 1 1 calc
C11 C 0.3460(13) 0.1631(11) 0.5783(10) 0.038(2) Uani 1 1 d
H11A H 0.2906 0.0659 0.5145 0.045 Uiso 1 1 calc
H11B H 0.3220 0.2347 0.5404 0.045 Uiso 1 1 calc
C12 C 0.5204(15) 0.1784(16) 0.5996(13) 0.060(3) Uani 1 1 d
H12A H 0.5768 0.2790 0.6507 0.090 Uiso 1 1 calc
H12B H 0.5503 0.1500 0.5152 0.090 Uiso 1 1 calc
H12C H 0.5469 0.1162 0.6467 0.090 Uiso 1 1 calc
C13 C 0.2688(13) 0.0202(11) 0.7568(10) 0.040(2) Uani 1 1 d
H13A H 0.3776 0.0127 0.7733 0.048 Uiso 1 1 calc
H13B H 0.2302 0.0269 0.8376 0.048 Uiso 1 1 calc
C14 C 0.1712(13) -0.1176(12) 0.6508(11) 0.044(3) Uani 1 1 d
H14A H 0.0601 -0.1231 0.6475 0.066 Uiso 1 1 calc
H14B H 0.1948 -0.2004 0.6694 0.066 Uiso 1 1 calc
H14C H 0.1952 -0.1189 0.5669 0.066 Uiso 1 1 calc
C15 C 0.0689(13) 0.1793(12) 0.6760(10) 0.040(2) Uani 1 1 d
H15A H 0.0626 0.2631 0.6495 0.048 Uiso 1 1 calc
H15B H 0.0210 0.0909 0.5986 0.048 Uiso 1 1 calc
C16 C -0.0270(15) 0.1782(16) 0.7814(13) 0.057(3) Uani 1 1 d
H16A H -0.0396 0.0861 0.7957 0.086 Uiso 1 1 calc
H16B H -0.1301 0.1903 0.7527 0.086 Uiso 1 1 calc
H16C H 0.0277 0.2574 0.8629 0.086 Uiso 1 1 calc
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt P 86.6(3) 2_667 .
C1 Pt C2 156.9(4) 2_667 .
P Pt C2 93.2(3) . .
C1 Pt C3 111.4(3) 2_667 .
P Pt C3 114.4(3) . .
C2 Pt C3 89.7(3) . .
C1 Pt Pt 101.1(3) 2_667 2_667
P Pt Pt 172.28(6) . 2_667
C2 Pt Pt 79.7(2) . 2_667
C3 Pt Pt 62.9(3) . 2_667
C1 Pt Mo 155.2(2) 2_667 .
P Pt Mo 109.96(7) . .
C2 Pt Mo 44.3(3) . .
C3 Pt Mo 45.4(2) . .
Pt Pt Mo 62.76(4) 2_667 .
C1 Pt Mo 44.8(3) 2_667 2_667
P Pt Mo 126.46(7) . 2_667
C2 Pt Mo 122.3(2) . 2_667
C3 Pt Mo 105.2(2) . 2_667
Pt Pt Mo 60.76(4) 2_667 2_667
Mo Pt Mo 123.52(6) . 2_667
C2 Mo C1 90.5(4) . .
C2 Mo C3 113.9(4) . .
C1 Mo C3 106.1(4) . .
C2 Mo C5 101.4(4) . .
C1 Mo C5 84.1(4) . .
C3 Mo C5 142.8(4) . .
C2 Mo C6 86.6(4) . .
C1 Mo C6 117.2(4) . .
C3 Mo C6 132.0(4) . .
C5 Mo C6 36.1(5) . .
C2 Mo C4 137.1(4) . .
C1 Mo C4 84.3(4) . .
C3 Mo C4 108.5(4) . .
C5 Mo C4 35.7(4) . .
C6 Mo C4 59.1(4) . .
C2 Mo C7 108.6(4) . .
C1 Mo C7 141.1(3) . .
C3 Mo C7 96.8(4) . .
C5 Mo C7 59.5(4) . .
C6 Mo C7 35.5(4) . .
C4 Mo C7 58.5(3) . .
C2 Mo C8 142.5(4) . .
C1 Mo C8 115.4(3) . .
C3 Mo C8 85.7(4) . .
C5 Mo C8 58.2(4) . .
C6 Mo C8 58.1(4) . .
C4 Mo C8 34.3(3) . .
C7 Mo C8 34.7(4) . .
C2 Mo Pt 55.6(3) . .
C1 Mo Pt 103.7(3) . .
C3 Mo Pt 58.3(3) . .
C5 Mo Pt 155.2(3) . .
C6 Mo Pt 124.3(3) . .
C4 Mo Pt 165.8(2) . .
C7 Mo Pt 115.1(2) . .
C8 Mo Pt 133.0(2) . .
C2 Mo Pt 81.6(3) . 2_667
C1 Mo Pt 52.0(3) . 2_667
C3 Mo Pt 63.9(3) . 2_667
C5 Mo Pt 136.1(3) . 2_667
C6 Mo Pt 163.6(3) . 2_667
C4 Mo Pt 124.9(3) . 2_667
C7 Mo Pt 160.7(3) . 2_667
C8 Mo Pt 135.5(2) . 2_667
Pt Mo Pt 56.48(6) . 2_667
C15 P C11 103.7(5) . .
C15 P C13 104.3(5) . .
C11 P C13 103.7(5) . .
C15 P Pt 115.8(4) . .
C11 P Pt 112.8(3) . .
C13 P Pt 115.1(3) . .
C8 N C9 118.6(10) . .
C8 N C10 119.7(10) . .
C9 N C10 115.6(10) . .
O1 C1 Mo 149.3(8) . .
O1 C1 Pt 127.4(8) . 2_667
Mo C1 Pt 83.2(3) . 2_667
O3 C3 Mo 164.7(8) . .
O3 C3 Pt 116.4(7) . .
Mo C3 Pt 76.3(3) . .
O2 C2 Mo 162.9(8) . .
O2 C2 Pt 116.7(7) . .
Mo C2 Pt 80.0(3) . .
C5 C4 C8 110.0(10) . .
C5 C4 Mo 70.6(5) . .
C8 C4 Mo 78.6(5) . .
C5 C4 H4 125.0 . .
C8 C4 H4 125.0 . .
Mo C4 H4 117.5 . .
C4 C5 C6 107.2(10) . .
C4 C5 Mo 73.7(5) . .
C6 C5 Mo 72.3(5) . .
C4 C5 H5 126.4 . .
C6 C5 H5 126.4 . .
Mo C5 H5 119.5 . .
C7 C6 C5 108.2(10) . .
C7 C6 Mo 74.1(6) . .
C5 C6 Mo 71.5(6) . .
C7 C6 H6 125.9 . .
C5 C6 H6 125.9 . .
Mo C6 H6 120.2 . .
C6 C7 C8 108.6(9) . .
C6 C7 Mo 70.4(6) . .
C8 C7 Mo 77.6(6) . .
C6 C7 H7 125.7 . .
C8 C7 H7 125.7 . .
Mo C7 H7 118.1 . .
N C8 C4 129.0(10) . .
N C8 C7 125.6(9) . .
C4 C8 C7 105.4(9) . .
N C8 Mo 129.3(7) . .
C4 C8 Mo 67.1(5) . .
C7 C8 Mo 67.7(5) . .
N C9 H9A 109.5 . .
N C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
N C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
N C10 H10A 109.5 . .
N C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
N C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C12 C11 P 113.2(8) . .
C12 C11 H11A 108.9 . .
P C11 H11A 108.9 . .
C12 C11 H11B 108.9 . .
P C11 H11B 108.9 . .
H11A C11 H11B 107.8 . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C14 C13 P 117.1(7) . .
C14 C13 H13A 108.0 . .
P C13 H13A 108.0 . .
C14 C13 H13B 108.0 . .
P C13 H13B 108.0 . .
H13A C13 H13B 107.3 . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 P 114.2(8) . .
C16 C15 H15A 108.7 . .
P C15 H15A 108.7 . .
C16 C15 H15B 108.7 . .
P C15 H15B 108.7 . .
H15A C15 H15B 107.6 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt C1 2.243(9) 2_667
Pt P 2.275(3) .
Pt C2 2.324(9) .
Pt C3 2.428(11) .
Pt Pt 2.650(2) 2_667
Pt Mo 2.7739(8) .
Pt Mo 2.8263(15) 2_667
Mo C2 1.969(11) .
Mo C1 2.004(10) .
Mo C3 2.032(9) .
Mo C5 2.283(9) .
Mo C6 2.293(11) .
Mo C4 2.324(9) .
Mo C7 2.342(10) .
Mo C8 2.473(9) .
Mo Pt 2.8263(15) 2_667
P C15 1.812(11) .
P C11 1.820(11) .
P C13 1.829(10) .
O1 C1 1.159(11) .
O2 C2 1.179(12) .
O3 C3 1.158(12) .
N C8 1.345(13) .
N C9 1.428(17) .
N C10 1.439(14) .
C1 Pt 2.243(9) 2_667
C4 C5 1.411(15) .
C4 C8 1.421(14) .
C4 H4 0.9500 .
C5 C6 1.419(18) .
C5 H5 0.9500 .
C6 C7 1.414(16) .
C6 H6 0.9500 .
C7 C8 1.443(15) .
C7 H7 0.9500 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 C12 1.515(17) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 C14 1.509(15) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 C16 1.542(17) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Pt Mo C2 -157.2(7) 2_667 .
P Pt Mo C2 73.3(3) . .
C3 Pt Mo C2 178.3(5) . .
Pt Pt Mo C2 -103.9(3) 2_667 .
Mo Pt Mo C2 -103.9(3) 2_667 .
C1 Pt Mo C1 -76.2(7) 2_667 .
P Pt Mo C1 154.4(3) . .
C2 Pt Mo C1 81.1(4) . .
C3 Pt Mo C1 -100.6(4) . .
Pt Pt Mo C1 -22.8(3) 2_667 .
Mo Pt Mo C1 -22.8(3) 2_667 .
C1 Pt Mo C3 24.4(7) 2_667 .
P Pt Mo C3 -105.0(4) . .
C2 Pt Mo C3 -178.3(5) . .
Pt Pt Mo C3 77.8(4) 2_667 .
Mo Pt Mo C3 77.8(4) 2_667 .
C1 Pt Mo C5 177.8(9) 2_667 .
P Pt Mo C5 48.4(7) . .
C2 Pt Mo C5 -24.9(8) . .
C3 Pt Mo C5 153.4(8) . .
Pt Pt Mo C5 -128.8(7) 2_667 .
Mo Pt Mo C5 -128.8(7) 2_667 .
C1 Pt Mo C6 146.5(7) 2_667 .
P Pt Mo C6 17.0(4) . .
C2 Pt Mo C6 -56.3(5) . .
C3 Pt Mo C6 122.0(5) . .
Pt Pt Mo C6 -160.2(4) 2_667 .
Mo Pt Mo C6 -160.2(4) 2_667 .
C1 Pt Mo C4 47.0(13) 2_667 .
P Pt Mo C4 -82.5(11) . .
C2 Pt Mo C4 -155.8(12) . .
C3 Pt Mo C4 22.5(12) . .
Pt Pt Mo C4 100.3(11) 2_667 .
Mo Pt Mo C4 100.3(11) 2_667 .
C1 Pt Mo C7 106.7(7) 2_667 .
P Pt Mo C7 -22.8(3) . .
C2 Pt Mo C7 -96.1(5) . .
C3 Pt Mo C7 82.2(5) . .
Pt Pt Mo C7 160.0(3) 2_667 .
Mo Pt Mo C7 160.0(3) 2_667 .
C1 Pt Mo C8 70.2(7) 2_667 .
P Pt Mo C8 -59.3(4) . .
C2 Pt Mo C8 -132.6(5) . .
C3 Pt Mo C8 45.8(5) . .
Pt Pt Mo C8 123.5(3) 2_667 .
Mo Pt Mo C8 123.5(3) 2_667 .
C1 Pt Mo Pt -53.3(6) 2_667 2_667
P Pt Mo Pt 177.20(7) . 2_667
C2 Pt Mo Pt 103.9(3) . 2_667
C3 Pt Mo Pt -77.8(3) . 2_667
Mo Pt Mo Pt 0.0 2_667 2_667
C1 Pt P C15 -69.7(5) 2_667 .
C2 Pt P C15 133.5(5) . .
C3 Pt P C15 42.4(5) . .
Pt Pt P C15 110.3(6) 2_667 .
Mo Pt P C15 91.4(4) . .
Mo Pt P C15 -91.5(4) 2_667 .
C1 Pt P C11 49.5(4) 2_667 .
C2 Pt P C11 -107.3(4) . .
C3 Pt P C11 161.5(4) . .
Pt Pt P C11 -130.6(6) 2_667 .
Mo Pt P C11 -149.4(4) . .
Mo Pt P C11 27.7(4) 2_667 .
C1 Pt P C13 168.3(5) 2_667 .
C2 Pt P C13 11.4(5) . .
C3 Pt P C13 -79.7(5) . .
Pt Pt P C13 -11.8(7) 2_667 .
Mo Pt P C13 -30.7(4) . .
Mo Pt P C13 146.4(4) 2_667 .
C2 Mo C1 O1 -100.1(15) . .
C3 Mo C1 O1 144.9(15) . .
C5 Mo C1 O1 1.4(15) . .
C6 Mo C1 O1 -13.6(17) . .
C4 Mo C1 O1 37.2(15) . .
C7 Mo C1 O1 21.2(19) . .
C8 Mo C1 O1 52.0(16) . .
Pt Mo C1 O1 -154.7(15) . .
Pt Mo C1 O1 -178.9(17) 2_667 .
C2 Mo C1 Pt 78.8(3) . 2_667
C3 Mo C1 Pt -36.2(4) . 2_667
C5 Mo C1 Pt -179.7(4) . 2_667
C6 Mo C1 Pt 165.3(4) . 2_667
C4 Mo C1 Pt -143.9(3) . 2_667
C7 Mo C1 Pt -159.9(5) . 2_667
C8 Mo C1 Pt -129.1(3) . 2_667
Pt Mo C1 Pt 24.2(3) . 2_667
C2 Mo C3 O3 146(3) . .
C1 Mo C3 O3 -116(4) . .
C5 Mo C3 O3 -14(4) . .
C6 Mo C3 O3 38(4) . .
C4 Mo C3 O3 -26(4) . .
C7 Mo C3 O3 33(4) . .
C8 Mo C3 O3 0(4) . .
Pt Mo C3 O3 148(4) . .
Pt Mo C3 O3 -147(4) 2_667 .
C2 Mo C3 Pt -1.5(4) . .
C1 Mo C3 Pt 96.4(3) . .
C5 Mo C3 Pt -161.9(6) . .
C6 Mo C3 Pt -109.6(5) . .
C4 Mo C3 Pt -174.3(3) . .
C7 Mo C3 Pt -115.3(3) . .
C8 Mo C3 Pt -148.3(3) . .
Pt Mo C3 Pt 65.18(18) 2_667 .
C1 Pt C3 O3 19.8(10) 2_667 .
P Pt C3 O3 -76.5(9) . .
C2 Pt C3 O3 -169.8(9) . .
Pt Pt C3 O3 111.6(9) 2_667 .
Mo Pt C3 O3 -171.0(11) . .
Mo Pt C3 O3 66.6(9) 2_667 .
C1 Pt C3 Mo -169.3(3) 2_667 .
P Pt C3 Mo 94.5(3) . .
C2 Pt C3 Mo 1.2(3) . .
Pt Pt C3 Mo -77.4(2) 2_667 .
Mo Pt C3 Mo -122.4(2) 2_667 .
C1 Mo C2 O2 85(3) . .
C3 Mo C2 O2 -167(3) . .
C5 Mo C2 O2 1(3) . .
C6 Mo C2 O2 -32(3) . .
C4 Mo C2 O2 3(3) . .
C7 Mo C2 O2 -61(3) . .
C8 Mo C2 O2 -51(3) . .
Pt Mo C2 O2 -169(3) . .
Pt Mo C2 O2 136(3) 2_667 .
C1 Mo C2 Pt -106.3(3) . .
C3 Mo C2 Pt 1.6(4) . .
C5 Mo C2 Pt 169.6(3) . .
C6 Mo C2 Pt 136.5(4) . .
C4 Mo C2 Pt 171.5(4) . .
C7 Mo C2 Pt 108.2(3) . .
C8 Mo C2 Pt 117.8(5) . .
Pt Mo C2 Pt -54.90(18) 2_667 .
C1 Pt C2 O2 -28.1(14) 2_667 .
P Pt C2 O2 60.7(8) . .
C3 Pt C2 O2 175.1(8) . .
Pt Pt C2 O2 -122.4(8) 2_667 .
Mo Pt C2 O2 176.3(10) . .
Mo Pt C2 O2 -77.0(8) 2_667 .
C1 Pt C2 Mo 155.6(7) 2_667 .
P Pt C2 Mo -115.6(2) . .
C3 Pt C2 Mo -1.2(3) . .
Pt Pt C2 Mo 61.3(2) 2_667 .
Mo Pt C2 Mo 106.7(3) 2_667 .
C2 Mo C4 C5 -3.2(10) . .
C1 Mo C4 C5 -87.9(7) . .
C3 Mo C4 C5 167.1(7) . .
C6 Mo C4 C5 38.6(7) . .
C7 Mo C4 C5 80.4(8) . .
C8 Mo C4 C5 116.2(10) . .
Pt Mo C4 C5 147.0(9) . .
Pt Mo C4 C5 -122.4(6) 2_667 .
C2 Mo C4 C8 -119.4(7) . .
C1 Mo C4 C8 156.0(7) . .
C3 Mo C4 C8 50.9(7) . .
C5 Mo C4 C8 -116.2(10) . .
C6 Mo C4 C8 -77.6(7) . .
C7 Mo C4 C8 -35.8(6) . .
Pt Mo C4 C8 30.8(15) . .
Pt Mo C4 C8 121.4(5) 2_667 .
C8 C4 C5 C6 4.4(11) . .
Mo C4 C5 C6 -65.1(7) . .
C8 C4 C5 Mo 69.5(7) . .
C2 Mo C5 C4 177.7(7) . .
C1 Mo C5 C4 88.4(7) . .
C3 Mo C5 C4 -20.5(11) . .
C6 Mo C5 C4 -114.6(10) . .
C7 Mo C5 C4 -77.3(7) . .
C8 Mo C5 C4 -36.5(6) . .
Pt Mo C5 C4 -161.5(5) . .
Pt Mo C5 C4 88.1(7) 2_667 .
C2 Mo C5 C6 -67.6(7) . .
C1 Mo C5 C6 -157.0(7) . .
C3 Mo C5 C6 94.1(9) . .
C4 Mo C5 C6 114.6(10) . .
C7 Mo C5 C6 37.3(7) . .
C8 Mo C5 C6 78.2(7) . .
Pt Mo C5 C6 -46.8(11) . .
Pt Mo C5 C6 -157.3(6) 2_667 .
C4 C5 C6 C7 0.4(11) . .
Mo C5 C6 C7 -65.6(7) . .
C4 C5 C6 Mo 66.0(7) . .
C2 Mo C6 C7 -129.3(7) . .
C1 Mo C6 C7 141.8(6) . .
C3 Mo C6 C7 -9.9(10) . .
C5 Mo C6 C7 115.9(10) . .
C4 Mo C6 C7 77.8(7) . .
C8 Mo C6 C7 37.4(6) . .
Pt Mo C6 C7 -85.9(7) . .
Pt Mo C6 C7 -173.0(8) 2_667 .
C2 Mo C6 C5 114.8(7) . .
C1 Mo C6 C5 25.9(8) . .
C3 Mo C6 C5 -125.8(7) . .
C4 Mo C6 C5 -38.1(6) . .
C7 Mo C6 C5 -115.9(10) . .
C8 Mo C6 C5 -78.5(7) . .
Pt Mo C6 C5 158.2(6) . .
Pt Mo C6 C5 71.1(14) 2_667 .
C5 C6 C7 C8 -5.0(11) . .
Mo C6 C7 C8 -68.9(7) . .
C5 C6 C7 Mo 63.9(7) . .
C2 Mo C7 C6 54.6(8) . .
C1 Mo C7 C6 -61.1(10) . .
C3 Mo C7 C6 172.6(7) . .
C5 Mo C7 C6 -38.0(7) . .
C4 Mo C7 C6 -79.9(7) . .
C8 Mo C7 C6 -115.2(9) . .
Pt Mo C7 C6 114.5(7) . .
Pt Mo C7 C6 174.0(7) 2_667 .
C2 Mo C7 C8 169.7(5) . .
C1 Mo C7 C8 54.1(9) . .
C3 Mo C7 C8 -72.2(6) . .
C5 Mo C7 C8 77.2(6) . .
C6 Mo C7 C8 115.2(9) . .
C4 Mo C7 C8 35.3(5) . .
Pt Mo C7 C8 -130.3(5) . .
Pt Mo C7 C8 -70.8(9) 2_667 .
C9 N C8 C4 16.2(15) . .
C10 N C8 C4 167.5(10) . .
C9 N C8 C7 -163.6(10) . .
C10 N C8 C7 -12.3(15) . .
C9 N C8 Mo -74.7(12) . .
C10 N C8 Mo 76.7(13) . .
C5 C4 C8 N 172.9(9) . .
Mo C4 C8 N -122.8(10) . .
C5 C4 C8 C7 -7.3(10) . .
Mo C4 C8 C7 57.0(6) . .
C5 C4 C8 Mo -64.3(6) . .
C6 C7 C8 N -172.7(9) . .
Mo C7 C8 N 123.2(9) . .
C6 C7 C8 C4 7.4(10) . .
Mo C7 C8 C4 -56.7(6) . .
C6 C7 C8 Mo 64.1(7) . .
C2 Mo C8 N -134.7(9) . .
C1 Mo C8 N 95.8(10) . .
C3 Mo C8 N -10.0(10) . .
C5 Mo C8 N 160.4(11) . .
C6 Mo C8 N -156.8(11) . .
C4 Mo C8 N 122.5(12) . .
C7 Mo C8 N -118.5(11) . .
Pt Mo C8 N -47.6(11) . .
Pt Mo C8 N 35.0(11) 2_667 .
C2 Mo C8 C4 102.9(8) . .
C1 Mo C8 C4 -26.7(7) . .
C3 Mo C8 C4 -132.4(7) . .
C5 Mo C8 C4 38.0(6) . .
C6 Mo C8 C4 80.8(7) . .
C7 Mo C8 C4 119.0(9) . .
Pt Mo C8 C4 -170.1(5) . .
Pt Mo C8 C4 -87.4(6) 2_667 .
C2 Mo C8 C7 -16.2(8) . .
C1 Mo C8 C7 -145.7(6) . .
C3 Mo C8 C7 108.5(6) . .
C5 Mo C8 C7 -81.1(7) . .
C6 Mo C8 C7 -38.3(6) . .
C4 Mo C8 C7 -119.0(9) . .
Pt Mo C8 C7 70.9(6) . .
Pt Mo C8 C7 153.5(5) 2_667 .
C15 P C11 C12 175.5(9) . .
C13 P C11 C12 -75.7(9) . .
Pt P C11 C12 49.5(9) . .
C15 P C13 C14 50.1(10) . .
C11 P C13 C14 -58.2(10) . .
Pt P C13 C14 178.2(8) . .
C11 P C15 C16 172.4(9) . .
C13 P C15 C16 64.1(9) . .
Pt P C15 C16 -63.5(9) . .
