#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:58:01 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179433 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/30/4333044.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4333044
loop_
_publ_author_name
'Du, Zi-Yi'
'Xu, Hai-Bing'
'Mao, Jiang-Gao'
_publ_section_title
;
 Rational Design of 0D, 1D, and 3D Open Frameworks Based on Tetranuclear
 Lanthanide(III) Sulfonate−Phosphonate Clusters
;
_journal_issue                   24
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9780
_journal_page_last               9788
_journal_paper_doi               10.1021/ic0613255
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C36 H40 Eu2 N4 O20 P2 S2'
_chemical_formula_weight         1278.70
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.52(1)
_cell_angle_beta                 108.2770(10)
_cell_angle_gamma                98.2940(10)
_cell_formula_units_Z            2
_cell_length_a                   12.2312(2)
_cell_length_b                   14.3800(3)
_cell_length_c                   15.4760(2)
_cell_measurement_temperature    293(2)
_cell_volume                     2276.6(2)
_computing_cell_refinement       'Siemens Smart CCD'
_computing_data_collection       'Siemens Smart CCD'
_computing_data_reduction        'Siemens Smart CCD'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'Siemens Smart CCD'
_diffrn_measurement_method       'narrow frame method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0257
_diffrn_reflns_av_sigmaI/netI    0.0406
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            12392
_diffrn_reflns_theta_full        25.68
_diffrn_reflns_theta_max         25.68
_diffrn_reflns_theta_min         1.87
_diffrn_standards_decay_%        <1.0%
_exptl_absorpt_coefficient_mu    2.974
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.887
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.865
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       brick
_exptl_crystal_F_000             1264
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.842
_refine_diff_density_min         -1.462
_refine_diff_density_rms         0.175
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.087
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     596
_refine_ls_number_reflns         8446
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.090
_refine_ls_R_factor_all          0.0605
_refine_ls_R_factor_gt           0.0490
_refine_ls_shift/su_max          0.388
_refine_ls_shift/su_mean         0.004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0219P)²+26.3370P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1017
_refine_ls_wR_factor_ref         0.1089
_reflns_number_gt                7385
_reflns_number_total             8446
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0613255sup3.cif
_cod_data_source_block           1
_cod_original_cell_volume        2276.53(7)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4333044
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.85355(3) 0.41077(3) 0.48323(3) 0.01750(9) Uani 1 1 d . . .
Eu2 Eu 0.77727(3) 0.30053(3) 0.09131(3) 0.02342(10) Uani 1 1 d . . .
P1 P 0.99065(16) 0.67347(14) 0.68088(13) 0.0193(4) Uani 1 1 d . . .
P2 P 0.81096(16) 0.51125(14) 0.33369(13) 0.0186(4) Uani 1 1 d . . .
S1 S 0.6657(2) 0.8820(2) 0.7738(3) 0.0786(11) Uani 1 1 d D . .
S2 S 0.67063(18) 0.80170(16) 0.20334(15) 0.0313(4) Uani 1 1 d . . .
N1 N 0.8517(5) 0.2692(5) 0.5458(5) 0.0267(13) Uani 1 1 d . . .
N2 N 0.7003(5) 0.3901(5) 0.5617(5) 0.0283(14) Uani 1 1 d . . .
N3 N 0.7620(6) 0.4116(5) -0.0090(5) 0.0353(16) Uani 1 1 d . . .
N4 N 0.9264(6) 0.3032(5) 0.0047(5) 0.0376(16) Uani 1 1 d . . .
C1 C 0.9421(6) 0.7912(5) 0.7122(5) 0.0210(14) Uani 1 1 d . A .
C2 C 0.8329(7) 0.7900(6) 0.7244(6) 0.0271(16) Uani 1 1 d . . .
H2A H 0.7818 0.7274 0.7118 0.033 Uiso 1 1 calc R A .
C3 C 0.8018(7) 0.8825(6) 0.7553(6) 0.0312(17) Uani 1 1 d . A .
C4 C 0.8769(7) 0.9767(6) 0.7763(6) 0.0345(18) Uani 1 1 d . . .
H4A H 0.8558 1.0385 0.7990 0.041 Uiso 1 1 calc R A .
C5 C 0.9839(8) 0.9789(6) 0.7632(7) 0.0375(19) Uani 1 1 d . A .
H5A H 1.0353 1.0418 0.7769 0.045 Uiso 1 1 calc R . .
C6 C 1.0132(7) 0.8853(6) 0.7293(6) 0.0312(17) Uani 1 1 d . . .
H6A H 1.0834 0.8862 0.7178 0.037 Uiso 1 1 calc R A .
C7 C 0.7781(6) 0.6357(5) 0.3565(5) 0.0210(14) Uani 1 1 d . . .
C8 C 0.7880(7) 0.7022(6) 0.4546(6) 0.0309(17) Uani 1 1 d . . .
H8A H 0.8084 0.6811 0.5059 0.037 Uiso 1 1 calc R . .
C9 C 0.7674(8) 0.7980(7) 0.4748(6) 0.039(2) Uani 1 1 d . . .
H9A H 0.7758 0.8420 0.5404 0.047 Uiso 1 1 calc R . .
C10 C 0.7345(7) 0.8304(6) 0.3999(6) 0.0348(18) Uani 1 1 d . . .
H10A H 0.7213 0.8958 0.4145 0.042 Uiso 1 1 calc R . .
C11 C 0.7215(6) 0.7638(6) 0.3024(5) 0.0232(15) Uani 1 1 d . . .
C12 C 0.7441(6) 0.6676(6) 0.2800(6) 0.0245(15) Uani 1 1 d . . .
H12A H 0.7367 0.6245 0.2144 0.029 Uiso 1 1 calc R . .
C13 C 0.8396(10) 0.1087(8) 0.6050(8) 0.055(3) Uani 1 1 d . . .
H13A H 0.8372 0.0558 0.6256 0.066 Uiso 1 1 calc R . .
C14 C 0.7582(9) 0.1683(7) 0.6127(7) 0.046(2) Uani 1 1 d . . .
C15 C 0.6695(11) 0.1527(9) 0.6525(9) 0.067(3) Uani 1 1 d . . .
H15A H 0.6638 0.1005 0.6737 0.081 Uiso 1 1 calc R . .
C16 C 0.5949(9) 0.2122(9) 0.6596(8) 0.060(3) Uani 1 1 d . . .
H16A H 0.5379 0.2001 0.6852 0.072 Uiso 1 1 calc R . .
C17 C 0.6013(8) 0.2941(7) 0.6284(7) 0.042(2) Uani 1 1 d . . .
C18 C 0.5278(9) 0.3609(9) 0.6370(7) 0.053(3) Uani 1 1 d . . .
H18A H 0.4703 0.3518 0.6630 0.064 Uiso 1 1 calc R . .
C19 C 0.5393(8) 0.4387(8) 0.6079(7) 0.051(2) Uani 1 1 d . . .
H19A H 0.4900 0.4824 0.6127 0.061 Uiso 1 1 calc R . .
C20 C 0.6283(8) 0.4503(7) 0.5705(7) 0.041(2) Uani 1 1 d . . .
H20A H 0.6372 0.5034 0.5508 0.049 Uiso 1 1 calc R . .
C21 C 0.6855(7) 0.3113(6) 0.5888(6) 0.0298(17) Uani 1 1 d . . .
C22 C 0.7680(7) 0.2491(6) 0.5825(6) 0.0297(17) Uani 1 1 d . . .
C23 C 0.9250(8) 0.2090(6) 0.5372(7) 0.041(2) Uani 1 1 d . . .
H23A H 0.9807 0.2206 0.5102 0.049 Uiso 1 1 calc R . .
C24 C 0.9210(10) 0.1286(7) 0.5676(8) 0.055(3) Uani 1 1 d . . .
H24A H 0.9745 0.0891 0.5619 0.066 Uiso 1 1 calc R . .
C25 C 0.7323(12) 0.5151(8) -0.1316(8) 0.067(4) Uani 1 1 d . . .
H25A H 0.7211 0.5486 -0.1732 0.081 Uiso 1 1 calc R . .
C26 C 0.8190(10) 0.4613(7) -0.1260(7) 0.053(3) Uani 1 1 d . . .
C27 C 0.8962(14) 0.4549(10) -0.1817(8) 0.082(5) Uani 1 1 d . . .
H27A H 0.8907 0.4896 -0.2220 0.098 Uiso 1 1 calc R . .
C28 C 0.9746(12) 0.4001(10) -0.1754(8) 0.071(4) Uani 1 1 d . . .
H28A H 1.0229 0.3977 -0.2117 0.086 Uiso 1 1 calc R . .
C29 C 0.9876(9) 0.3446(8) -0.1148(6) 0.049(2) Uani 1 1 d . . .
C30 C 1.0693(10) 0.2881(9) -0.1061(8) 0.064(3) Uani 1 1 d . . .
H30A H 1.1162 0.2808 -0.1440 0.077 Uiso 1 1 calc R . .
C31 C 1.0811(9) 0.2436(8) -0.0423(9) 0.064(3) Uani 1 1 d . . .
H31A H 1.1369 0.2065 -0.0353 0.077 Uiso 1 1 calc R . .
C32 C 1.0085(8) 0.2536(7) 0.0132(8) 0.048(2) Uani 1 1 d . . .
H32A H 1.0188 0.2240 0.0580 0.058 Uiso 1 1 calc R . .
C33 C 0.9153(8) 0.3498(7) -0.0582(6) 0.038(2) Uani 1 1 d . . .
C34 C 0.8295(8) 0.4079(7) -0.0654(6) 0.0369(19) Uani 1 1 d . . .
C35 C 0.6825(9) 0.4664(7) -0.0151(7) 0.048(2) Uani 1 1 d . . .
H35A H 0.6366 0.4703 0.0233 0.058 Uiso 1 1 calc R . .
C36 C 0.6650(12) 0.5184(8) -0.0769(8) 0.067(3) Uani 1 1 d . . .
H36A H 0.6078 0.5546 -0.0799 0.080 Uiso 1 1 calc R . .
O1W O 0.6732(4) 0.2475(4) 0.3569(4) 0.0293(11) Uani 1 1 d . . .
O2W O 0.8141(6) 0.1201(5) 0.0415(5) 0.0478(16) Uani 1 1 d . . .
O3W O 0.6536(6) 0.1744(5) -0.0918(4) 0.0471(16) Uani 1 1 d . . .
O4W O 0.5679(5) 0.3064(6) 0.0489(5) 0.0490(16) Uani 1 1 d . . .
O5W O 0.6920(6) 0.2115(5) 0.1698(5) 0.0455(15) Uani 1 1 d . . .
O6W O 0.5041(18) 0.0441(16) 0.0695(17) 0.107(7) Uani 0.50 1 d P . .
O7W O 0.6830(15) -0.0296(16) 0.0844(16) 0.097(7) Uani 0.50 1 d P . .
O8W O 0.6339(19) 0.0542(16) 0.3427(16) 0.070(6) Uiso 0.50 1 d P . .
O8W' O 0.6090(16) 0.0578(13) 0.3627(13) 0.053(5) Uiso 0.50 1 d P . .
O9W O 0.4932(5) 0.3572(5) 0.2033(5) 0.0472(16) Uani 1 1 d . . .
O11 O 1.0827(4) 0.6905(4) 0.6365(4) 0.0238(10) Uani 1 1 d . . .
O12 O 0.8800(4) 0.5784(4) 0.6049(4) 0.0233(10) Uani 1 1 d . . .
O13 O 1.0465(4) 0.6723(4) 0.7836(4) 0.0271(11) Uani 1 1 d . . .
O21 O 0.7242(4) 0.4478(4) 0.3587(4) 0.0262(11) Uani 1 1 d . . .
O22 O 0.9386(4) 0.5346(4) 0.4126(4) 0.0231(10) Uani 1 1 d . . .
O23 O 0.7951(5) 0.4589(4) 0.2230(4) 0.0268(11) Uani 1 1 d . . .
O31 O 0.7047(14) 0.9064(12) 0.8878(11) 0.066(4) Uiso 0.50 1 d PD A 1
O32 O 0.6341(11) 0.9729(9) 0.7674(10) 0.042(3) Uiso 0.50 1 d PD A 1
O31' O 0.6612(14) 0.9707(12) 0.8295(12) 0.063(4) Uiso 0.50 1 d P A 2
O32' O 0.607(3) 0.912(3) 0.682(3) 0.223(16) Uiso 0.50 1 d PD A 2
O33 O 0.5824(7) 0.7833(6) 0.7107(6) 0.0612(19) Uiso 1 1 d D A .
O41 O 0.7657(8) 0.8870(8) 0.2258(8) 0.107(4) Uani 1 1 d . . .
O42 O 0.6412(9) 0.7115(7) 0.1087(5) 0.080(3) Uani 1 1 d . . .
O43 O 0.5670(7) 0.8340(7) 0.2105(6) 0.070(2) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Eu1 O12 146.47(17) 2_766 .
O11 Eu1 O22 81.14(17) 2_766 2_766
O12 Eu1 O22 78.29(16) . 2_766
O11 Eu1 O21 89.76(17) 2_766 .
O12 Eu1 O21 87.97(17) . .
O22 Eu1 O21 137.76(17) 2_766 .
O11 Eu1 O1W 74.60(17) 2_766 .
O12 Eu1 O1W 135.04(16) . .
O22 Eu1 O1W 142.75(16) 2_766 .
O21 Eu1 O1W 70.62(17) . .
O11 Eu1 N1 87.83(18) 2_766 .
O12 Eu1 N1 114.84(18) . .
O22 Eu1 N1 81.86(18) 2_766 .
O21 Eu1 N1 139.26(18) . .
O1W Eu1 N1 69.55(18) . .
O11 Eu1 N2 140.13(18) 2_766 .
O12 Eu1 N2 73.39(18) . .
O22 Eu1 N2 118.82(18) 2_766 .
O21 Eu1 N2 94.26(19) . .
O1W Eu1 N2 69.54(18) . .
N1 Eu1 N2 63.9(2) . .
O11 Eu1 O22 73.15(15) 2_766 .
O12 Eu1 O22 77.40(16) . .
O22 Eu1 O22 80.05(16) 2_766 .
O21 Eu1 O22 57.91(15) . .
O1W Eu1 O22 117.99(15) . .
N1 Eu1 O22 155.47(17) . .
N2 Eu1 O22 140.16(17) . .
O11 Eu1 P2 77.96(12) 2_766 .
O12 Eu1 P2 84.38(12) . .
O22 Eu1 P2 109.66(12) 2_766 .
O21 Eu1 P2 28.51(12) . .
O1W Eu1 P2 92.57(12) . .
N1 Eu1 P2 159.75(14) . .
N2 Eu1 P2 119.81(15) . .
O22 Eu1 P2 29.61(10) . .
O11 Eu1 P1 130.61(12) 2_766 .
O12 Eu1 P1 18.24(12) . .
O22 Eu1 P1 61.03(12) 2_766 .
O21 Eu1 P1 97.58(12) . .
O1W Eu1 P1 153.26(12) . .
N1 Eu1 P1 114.46(14) . .
N2 Eu1 P1 88.16(14) . .
O22 Eu1 P1 70.18(11) . .
P2 Eu1 P1 85.78(4) . .
O11 Eu1 P1 16.58(12) 2_766 2_766
O12 Eu1 P1 129.90(12) . 2_766
O22 Eu1 P1 72.09(12) 2_766 2_766
O21 Eu1 P1 87.80(12) . 2_766
O1W Eu1 P1 89.47(12) . 2_766
N1 Eu1 P1 100.04(14) . 2_766
N2 Eu1 P1 156.71(14) . 2_766
O22 Eu1 P1 58.55(10) . 2_766
P2 Eu1 P1 69.38(4) . 2_766
P1 Eu1 P1 114.60(3) . 2_766
O11 Eu1 Eu1 72.85(12) 2_766 2_766
O12 Eu1 Eu1 74.03(12) . 2_766
O22 Eu1 Eu1 42.98(12) 2_766 2_766
O21 Eu1 Eu1 94.90(12) . 2_766
O1W Eu1 Eu1 144.30(12) . 2_766
N1 Eu1 Eu1 122.88(14) . 2_766
N2 Eu1 Eu1 145.73(14) . 2_766
O22 Eu1 Eu1 37.08(10) . 2_766
P2 Eu1 Eu1 66.69(3) . 2_766
P1 Eu1 Eu1 57.92(3) . 2_766
P1 Eu1 Eu1 56.68(3) 2_766 2_766
O13 Eu2 O23 78.14(17) 2_766 .
O13 Eu2 O5W 83.3(2) 2_766 .
O23 Eu2 O5W 87.6(2) . .
O13 Eu2 O4W 145.99(19) 2_766 .
O23 Eu2 O4W 76.6(2) . .
O5W Eu2 O4W 73.3(2) . .
O13 Eu2 O3W 138.39(18) 2_766 .
O23 Eu2 O3W 143.17(18) . .
O5W Eu2 O3W 99.5(2) . .
O4W Eu2 O3W 71.1(2) . .
O13 Eu2 O2W 74.63(19) 2_766 .
O23 Eu2 O2W 146.85(18) . .
O5W Eu2 O2W 70.9(2) . .
O4W Eu2 O2W 118.3(2) . .
O3W Eu2 O2W 67.5(2) . .
O13 Eu2 N4 78.1(2) 2_766 .
O23 Eu2 N4 117.6(2) . .
O5W Eu2 N4 144.1(2) . .
O4W Eu2 N4 134.4(2) . .
O3W Eu2 N4 76.0(2) . .
O2W Eu2 N4 74.7(2) . .
O13 Eu2 N3 121.3(2) 2_766 .
O23 Eu2 N3 82.63(19) . .
O5W Eu2 N3 150.6(2) . .
O4W Eu2 N3 77.5(2) . .
O3W Eu2 N3 73.5(2) . .
O2W Eu2 N3 128.0(2) . .
N4 Eu2 N3 63.2(2) . .
O12 P1 O11 112.9(3) . .
O12 P1 O13 112.4(3) . .
O11 P1 O13 113.1(3) . .
O12 P1 C1 108.2(3) . .
O11 P1 C1 105.5(3) . .
O13 P1 C1 103.9(3) . .
O12 P1 Eu1 28.46(18) . .
O11 P1 Eu1 90.30(19) . .
O13 P1 Eu1 109.5(2) . .
C1 P1 Eu1 133.5(2) . .
O12 P1 Eu1 90.50(19) . 2_766
O11 P1 Eu1 25.55(18) . 2_766
O13 P1 Eu1 114.5(2) . 2_766
C1 P1 Eu1 126.5(2) . 2_766
Eu1 P1 Eu1 65.40(3) . 2_766
O23 P2 O21 114.0(3) . .
O23 P2 O22 114.9(3) . .
O21 P2 O22 105.6(3) . .
O23 P2 C7 106.5(3) . .
O21 P2 C7 107.2(3) . .
O22 P2 C7 108.3(3) . .
O23 P2 Eu1 126.6(2) . .
O21 P2 Eu1 47.45(18) . .
O22 P2 Eu1 58.68(19) . .
C7 P2 Eu1 126.3(2) . .
O31' S1 O33 134.4(8) . .
O31' S1 O32 39.4(7) . .
O33 S1 O32 119.0(7) . .
O31' S1 O31 66.4(9) . .
O33 S1 O31 110.7(7) . .
O32 S1 O31 105.8(8) . .
O31' S1 C3 115.3(8) . .
O33 S1 C3 109.6(4) . .
O32 S1 C3 107.2(6) . .
O31 S1 C3 103.4(7) . .
O31' S1 O32' 83.6(16) . .
O33 S1 O32' 86.5(15) . .
O32 S1 O32' 44.3(14) . .
O31 S1 O32' 149.7(16) . .
C3 S1 O32' 93.3(15) . .
O41 S2 O42 113.5(7) . .
O41 S2 O43 111.4(6) . .
O42 S2 O43 112.3(5) . .
O41 S2 C11 106.3(4) . .
O42 S2 C11 107.4(4) . .
O43 S2 C11 105.4(4) . .
C23 N1 C22 118.2(7) . .
C23 N1 Eu1 122.1(5) . .
C22 N1 Eu1 119.5(5) . .
C20 N2 C21 117.9(7) . .
C20 N2 Eu1 121.7(6) . .
C21 N2 Eu1 120.3(5) . .
C35 N3 C34 117.4(8) . .
C35 N3 Eu2 122.6(6) . .
C34 N3 Eu2 119.8(5) . .
C32 N4 C33 118.0(8) . .
C32 N4 Eu2 121.7(6) . .
C33 N4 Eu2 120.1(5) . .
C6 C1 C2 118.0(6) . .
C6 C1 P1 121.3(5) . .
C2 C1 P1 120.6(5) . .
C3 C2 C1 119.6(7) . .
C4 C3 C2 121.3(7) . .
C4 C3 S1 118.9(6) . .
C2 C3 S1 119.7(6) . .
C3 C4 C5 119.7(7) . .
C4 C5 C6 118.8(8) . .
C1 C6 C5 122.5(7) . .
C12 C7 C8 119.1(6) . .
C12 C7 P2 122.2(5) . .
C8 C7 P2 118.8(5) . .
C9 C8 C7 120.0(7) . .
C8 C9 C10 121.3(7) . .
C9 C10 C11 118.7(7) . .
C12 C11 C10 121.4(7) . .
C12 C11 S2 119.5(6) . .
C10 C11 S2 119.0(5) . .
C11 C12 C7 119.4(7) . .
C24 C13 C14 119.6(8) . .
C13 C14 C22 117.6(8) . .
C13 C14 C15 123.2(9) . .
C22 C14 C15 119.2(10) . .
C16 C15 C14 121.1(9) . .
C15 C16 C17 121.3(9) . .
C21 C17 C18 116.9(8) . .
C21 C17 C16 119.4(9) . .
C18 C17 C16 123.7(9) . .
C19 C18 C17 121.2(8) . .
C18 C19 C20 117.4(9) . .
N2 C20 C19 123.8(9) . .
N2 C21 C17 122.9(8) . .
N2 C21 C22 117.1(6) . .
C17 C21 C22 119.9(7) . .
N1 C22 C14 122.1(8) . .
N1 C22 C21 118.8(7) . .
C14 C22 C21 119.1(7) . .
N1 C23 C24 122.3(9) . .
C13 C24 C23 120.1(9) . .
C36 C25 C26 120.0(9) . .
C34 C26 C25 118.2(10) . .
C34 C26 C27 118.3(11) . .
C25 C26 C27 123.5(11) . .
C28 C27 C26 120.7(11) . .
C27 C28 C29 122.5(11) . .
C30 C29 C33 117.7(10) . .
C30 C29 C28 123.6(10) . .
C33 C29 C28 118.6(11) . .
C31 C30 C29 119.9(10) . .
C30 C31 C32 119.5(11) . .
N4 C32 C31 122.8(11) . .
N4 C33 C29 122.0(9) . .
N4 C33 C34 118.8(7) . .
C29 C33 C34 119.2(8) . .
N3 C34 C26 122.0(9) . .
N3 C34 C33 117.4(7) . .
C26 C34 C33 120.7(9) . .
N3 C35 C36 123.3(10) . .
C25 C36 C35 119.1(11) . .
P1 O11 Eu1 137.9(3) . 2_766
P1 O12 Eu1 133.3(3) . .
P1 O13 Eu2 144.0(3) . 2_766
P2 O21 Eu1 104.0(2) . .
P2 O22 Eu1 168.3(3) . 2_766
P2 O22 Eu1 91.7(2) . .
Eu1 O22 Eu1 99.95(16) 2_766 .
P2 O23 Eu2 143.5(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O11 2.308(5) 2_766
Eu1 O12 2.319(5) .
Eu1 O22 2.359(5) 2_766
Eu1 O21 2.370(5) .
Eu1 O1W 2.547(5) .
Eu1 N1 2.567(6) .
Eu1 N2 2.572(6) .
Eu1 O22 2.667(5) .
Eu1 P2 3.1205(17) .
Eu1 P1 3.5414(18) .
Eu1 P1 3.5909(17) 2_766
Eu1 Eu1 3.8536(7) 2_766
Eu2 O13 2.260(5) 2_766
Eu2 O23 2.326(5) .
Eu2 O5W 2.410(6) .
Eu2 O4W 2.459(6) .
Eu2 O3W 2.488(6) .
Eu2 O2W 2.560(6) .
Eu2 N4 2.584(7) .
Eu2 N3 2.607(7) .
P1 O12 1.523(5) .
P1 O11 1.528(5) .
P1 O13 1.529(5) .
P1 C1 1.816(7) .
P1 Eu1 3.5909(17) 2_766
P2 O23 1.516(5) .
P2 O21 1.536(5) .
P2 O22 1.543(5) .
P2 C7 1.818(7) .
S1 O31' 1.257(15) .
S1 O33 1.380(8) .
S1 O32 1.445(12) .
S1 O31 1.553(14) .
S1 C3 1.774(8) .
S1 O32' 1.63(2) .
S2 O41 1.409(8) .
S2 O42 1.428(7) .
S2 O43 1.433(7) .
S2 C11 1.782(7) .
N1 C23 1.335(10) .
N1 C22 1.364(10) .
N2 C20 1.323(10) .
N2 C21 1.359(10) .
N3 C35 1.340(11) .
N3 C34 1.370(11) .
N4 C32 1.315(11) .
N4 C33 1.364(11) .
C1 C6 1.378(10) .
C1 C2 1.405(10) .
C2 C3 1.385(10) .
C3 C4 1.379(11) .
C4 C5 1.382(12) .
C5 C6 1.389(11) .
C7 C12 1.395(9) .
C7 C8 1.406(10) .
C8 C9 1.371(11) .
C9 C10 1.378(11) .
C10 C11 1.385(11) .
C11 C12 1.384(10) .
C13 C24 1.347(15) .
C13 C14 1.408(14) .
C14 C22 1.413(11) .
C14 C15 1.435(14) .
C15 C16 1.338(16) .
C16 C17 1.435(13) .
C17 C21 1.391(11) .
C17 C18 1.404(14) .
C18 C19 1.362(15) .
C19 C20 1.401(12) .
C21 C22 1.444(11) .
C23 C24 1.405(12) .
C25 C36 1.346(17) .
C25 C26 1.401(16) .
C26 C34 1.410(12) .
C26 C27 1.456(17) .
C27 C28 1.330(19) .
C28 C29 1.435(16) .
C29 C30 1.382(16) .
C29 C33 1.417(12) .
C30 C31 1.351(17) .
C31 C32 1.403(14) .
C33 C34 1.435(13) .
C35 C36 1.409(14) .
O11 Eu1 2.308(5) 2_766
O13 Eu2 2.260(5) 2_766
O22 Eu1 2.359(5) 2_766
