#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/34/4333488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4333488
loop_
_publ_author_name
'Stork, Jay R.'
'Thoi, Van S.'
'Cohen, Seth M.'
_publ_section_title
;
 Rare Examples of Transition-Metal−Main-Group Metal Heterometallic
 Metal−Organic Frameworks from Gallium and Indium Dipyrrinato
 Complexes and Silver Salts:  Synthesis and Framework Variability
;
_journal_issue                   26
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11213
_journal_page_last               11223
_journal_paper_doi               10.1021/ic7016159
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C43.85 H30 Ag F6 Ga N9.7 Sb'
_chemical_formula_weight         1106.12
_chemical_name_common            MOF-Ga/AgSbF₆-1
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.941(4)
_cell_angle_beta                 98.464(4)
_cell_angle_gamma                111.852(4)
_cell_formula_units_Z            2
_cell_length_a                   13.339(3)
_cell_length_b                   16.060(4)
_cell_length_c                   16.380(4)
_cell_measurement_reflns_used    971
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.1
_cell_measurement_theta_min      2.54
_cell_volume                     2933.5(12)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART 5.632 (Bruker, 2005)'
_computing_data_reduction        'SAINT 6.45A (Bruker, 2003)'
_computing_molecular_graphics    'SHELXTL 5.1 (Sheldrick, 1994)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.3
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker APEX'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0292
_diffrn_reflns_av_sigmaI/netI    0.0475
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            27016
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.38
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.296
_exptl_absorpt_correction_T_max  0.91206
_exptl_absorpt_correction_T_min  0.74319
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2.10 (Sheldrick, 2004)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.252
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1088
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.09
_platon_squeeze_details
;
;
_refine_diff_density_max         1.295
_refine_diff_density_min         -0.696
_refine_diff_density_rms         0.109
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     689
_refine_ls_number_reflns         11865
_refine_ls_number_restraints     5
_refine_ls_restrained_S_all      1.072
_refine_ls_R_factor_all          0.0854
_refine_ls_R_factor_gt           0.0642
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1075P)²+1.9032P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1795
_refine_ls_wR_factor_ref         0.1905
_reflns_number_gt                8483
_reflns_number_total             11865
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic7016159sup1.cif
_cod_data_source_block           jrs155-sqz1
_cod_original_formula_sum        'C43.85 H30 Ag F6 Ga N9.70 Sb'
_cod_database_code               4333488
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.71259(5) 0.22804(3) 0.03961(3) 0.05762(17) Uani 1 1 d . . .
Ga1 Ga 0.68225(4) 0.83929(4) 0.41983(4) 0.03395(15) Uani 1 1 d . . .
C1 C 0.5044(5) 0.7220(5) 0.2331(4) 0.0543(15) Uani 1 1 d . . .
H1 H 0.4762 0.6644 0.2442 0.065 Uiso 1 1 calc R . .
C2 C 0.4620(5) 0.7268(6) 0.1524(4) 0.073(2) Uani 1 1 d . . .
H2 H 0.3996 0.6755 0.1018 0.088 Uiso 1 1 calc R . .
C3 C 0.5266(6) 0.8183(6) 0.1600(4) 0.0653(19) Uani 1 1 d . . .
H3 H 0.5195 0.8424 0.1147 0.078 Uiso 1 1 calc R . .
C4 C 0.6070(5) 0.8720(4) 0.2481(3) 0.0456(13) Uani 1 1 d . . .
C5 C 0.6875(4) 0.9717(4) 0.2871(3) 0.0422(12) Uani 1 1 d . . .
C6 C 0.7603(4) 1.0247(4) 0.3760(3) 0.0386(11) Uani 1 1 d . . .
C7 C 0.8401(5) 1.1256(4) 0.4160(4) 0.0448(12) Uani 1 1 d . . .
H7 H 0.8549 1.1698 0.3874 0.054 Uiso 1 1 calc R . .
C8 C 0.8918(5) 1.1470(4) 0.5044(4) 0.0497(13) Uani 1 1 d . . .
H8 H 0.9480 1.2093 0.5491 0.060 Uiso 1 1 calc R . .
C9 C 0.8453(4) 1.0586(4) 0.5155(3) 0.0390(11) Uani 1 1 d . . .
H9 H 0.8673 1.0522 0.5701 0.047 Uiso 1 1 calc R . .
C10 C 0.6952(5) 1.0253(5) 0.2280(4) 0.0537(15) Uani 1 1 d . . .
C11 C 0.6689(9) 1.1094(8) 0.2532(7) 0.052(3) Uani 0.632(13) 1 d P . 1
H11 H 0.6454 1.1273 0.3055 0.062 Uiso 0.632(13) 1 calc PR . 1
C12 C 0.6783(9) 1.1637(9) 0.1999(7) 0.058(3) Uani 0.632(13) 1 d P . 1
H12 H 0.6549 1.2145 0.2128 0.070 Uiso 0.632(13) 1 calc PR . 1
C13 C 0.5952(13) 1.0368(13) 0.1953(11) 0.044(4) Uani 0.368(13) 1 d P . 2
H13 H 0.5269 1.0101 0.2094 0.053 Uiso 0.368(13) 1 calc PR . 2
C14 C 0.6075(13) 1.0890(13) 0.1427(11) 0.043(4) Uani 0.368(13) 1 d P . 2
H14 H 0.5523 1.1115 0.1328 0.051 Uiso 0.368(13) 1 calc PR . 2
C15 C 0.7629(5) 1.0787(5) 0.1200(4) 0.0524(15) Uani 1 1 d . . .
H15 H 0.7997 1.0700 0.0746 0.063 Uiso 1 1 calc R . 1
C16 C 0.7560(5) 1.0245(5) 0.1705(4) 0.0530(15) Uani 1 1 d . . .
H16 H 0.7956 0.9855 0.1642 0.064 Uiso 1 1 calc R . .
C17 C 0.8844(4) 0.8718(4) 0.3468(3) 0.0378(11) Uani 1 1 d . . .
H17 H 0.9120 0.9413 0.3747 0.045 Uiso 1 1 calc R . .
C18 C 0.9303(5) 0.8238(4) 0.2866(3) 0.0476(13) Uani 1 1 d . . .
H18 H 0.9919 0.8540 0.2667 0.057 Uiso 1 1 calc R . .
C19 C 0.8696(4) 0.7258(4) 0.2625(4) 0.0458(13) Uani 1 1 d . . .
H19 H 0.8808 0.6744 0.2225 0.055 Uiso 1 1 calc R . .
C20 C 0.7869(4) 0.7144(4) 0.3080(3) 0.0352(10) Uani 1 1 d . . .
C21 C 0.7041(4) 0.6268(4) 0.3036(3) 0.0398(11) Uani 1 1 d . A .
C22 C 0.6206(5) 0.6166(4) 0.3467(4) 0.0488(13) Uani 1 1 d . . .
C23 C 0.5490(8) 0.5300(5) 0.3571(8) 0.057(3) Uani 0.84(2) 1 d P A 1
H23 H 0.5447 0.4662 0.3301 0.069 Uiso 0.84(2) 1 calc PR A 1
C24 C 0.4877(10) 0.5562(7) 0.4136(10) 0.077(4) Uani 0.84(2) 1 d P A 1
H24 H 0.4315 0.5142 0.4306 0.093 Uiso 0.84(2) 1 calc PR A 1
C25 C 0.5257(8) 0.6570(7) 0.4399(8) 0.058(3) Uani 0.84(2) 1 d P A 1
H25 H 0.5014 0.6957 0.4818 0.070 Uiso 0.84(2) 1 calc PR A 1
C26 C 0.515(5) 0.525(3) 0.308(5) 0.057(3) Uani 0.16(2) 1 d P A 2
H26 H 0.4941 0.4651 0.2568 0.069 Uiso 0.16(2) 1 calc PR A 2
C27 C 0.449(6) 0.552(5) 0.372(6) 0.077(4) Uani 0.16(2) 1 d P A 2
H27 H 0.3906 0.5114 0.3890 0.093 Uiso 0.16(2) 1 calc PR A 2
C28 C 0.500(5) 0.651(4) 0.399(4) 0.058(3) Uani 0.16(2) 1 d P A 2
H28 H 0.4602 0.6880 0.4177 0.070 Uiso 0.16(2) 1 calc PR A 2
C29 C 0.7047(4) 0.5332(4) 0.2430(4) 0.0424(12) Uani 1 1 d . . .
C30 C 0.7933(5) 0.5120(5) 0.2623(4) 0.0571(16) Uani 1 1 d . A .
H30 H 0.8561 0.5555 0.3155 0.069 Uiso 1 1 calc R . .
C31 C 0.7901(5) 0.4257(5) 0.2029(4) 0.0591(16) Uani 1 1 d . . .
H31 H 0.8521 0.4119 0.2173 0.071 Uiso 1 1 calc R A .
C32 C 0.6204(6) 0.3844(5) 0.1105(4) 0.0615(17) Uani 1 1 d . . .
H32 H 0.5591 0.3402 0.0565 0.074 Uiso 1 1 calc R A .
C33 C 0.6161(5) 0.4679(4) 0.1665(4) 0.0588(16) Uani 1 1 d . A .
H33 H 0.5524 0.4795 0.1518 0.071 Uiso 1 1 calc R . .
C34 C 0.8685(4) 0.8626(4) 0.5657(4) 0.0436(12) Uani 1 1 d . . .
H34 H 0.8965 0.8314 0.5213 0.052 Uiso 1 1 calc R . .
C35 C 0.9222(4) 0.9042(4) 0.6613(4) 0.0484(13) Uani 1 1 d . . .
H35 H 0.9895 0.9048 0.6910 0.058 Uiso 1 1 calc R . .
C36 C 0.8563(4) 0.9431(4) 0.7017(4) 0.0464(13) Uani 1 1 d . . .
H36 H 0.8697 0.9767 0.7648 0.056 Uiso 1 1 calc R . .
C37 C 0.7632(4) 0.9226(4) 0.6289(3) 0.0387(11) Uani 1 1 d . . .
C38 C 0.6728(4) 0.9463(4) 0.6366(3) 0.0392(11) Uani 1 1 d . . .
C39 C 0.5787(4) 0.9192(4) 0.5662(3) 0.0388(11) Uani 1 1 d . . .
C40 C 0.4806(4) 0.9319(4) 0.5742(4) 0.0455(12) Uani 1 1 d . . .
H40 H 0.4695 0.9662 0.6286 0.055 Uiso 1 1 calc R . .
C41 C 0.4052(4) 0.8859(4) 0.4896(4) 0.0452(13) Uani 1 1 d . . .
H41 H 0.3304 0.8794 0.4739 0.054 Uiso 1 1 calc R . .
C42 C 0.4600(4) 0.8495(4) 0.4297(4) 0.0409(11) Uani 1 1 d . . .
H42 H 0.4276 0.8161 0.3657 0.049 Uiso 1 1 calc R . .
C43 C 0.6810(4) 1.0081(4) 0.7290(3) 0.0408(12) Uani 1 1 d . . .
C44 C 0.7227(7) 1.1082(5) 0.7574(5) 0.067(2) Uani 1 1 d . . .
H44 H 0.7467 1.1381 0.7179 0.081 Uiso 1 1 calc R . .
C45 C 0.7295(6) 1.1641(5) 0.8422(5) 0.0646(18) Uani 1 1 d . . .
H45 H 0.7603 1.2333 0.8598 0.077 Uiso 1 1 calc R . .
C46 C 0.6323(16) 1.0405(10) 0.8734(9) 0.036(3) Uani 0.48(3) 1 d P . 1
H46 H 0.5917 1.0168 0.9105 0.043 Uiso 0.48(3) 1 calc PR . 1
C47 C 0.6201(15) 0.9747(9) 0.7871(7) 0.033(4) Uani 0.48(3) 1 d P . 1
H47 H 0.5706 0.9066 0.7665 0.040 Uiso 0.48(3) 1 calc PR . 1
C48 C 0.688(2) 1.0352(9) 0.8786(8) 0.051(6) Uani 0.52(3) 1 d P . 2
H48 H 0.6867 1.0123 0.9253 0.061 Uiso 0.52(3) 1 calc PR . 2
C49 C 0.679(2) 0.9720(9) 0.7953(9) 0.052(5) Uani 0.52(3) 1 d P . 2
H49 H 0.6732 0.9081 0.7838 0.062 Uiso 0.52(3) 1 calc PR . 2
N1 N 0.5899(3) 0.8089(3) 0.2930(3) 0.0421(10) Uani 1 1 d . . .
N2 N 0.7662(3) 0.9848(3) 0.4397(3) 0.0341(9) Uani 1 1 d . . .
N3 N 0.7200(14) 1.1434(12) 0.1320(9) 0.044(3) Uani 0.632(13) 1 d P . 1
N4 N 0.689(2) 1.111(2) 0.1040(14) 0.046(6) Uani 0.368(13) 1 d P . 2
N5 N 0.7973(3) 0.8078(3) 0.3597(3) 0.0353(9) Uani 1 1 d . . .
N6 N 0.6024(4) 0.6941(3) 0.3981(3) 0.0459(11) Uani 1 1 d . A .
N7 N 0.7069(4) 0.3626(3) 0.1286(3) 0.0523(12) Uani 1 1 d . A .
N8 N 0.7756(3) 0.8730(3) 0.5466(3) 0.0396(9) Uani 1 1 d . . .
N9 N 0.5639(3) 0.8682(3) 0.4749(3) 0.0362(9) Uani 1 1 d . . .
N10 N 0.6975(4) 1.1313(3) 0.9015(3) 0.0469(11) Uani 1 1 d . . .
Sb1 Sb 0.12529(10) 0.59140(10) 0.23994(10) 0.0580(3) Uani 0.37 1 d P B 1
F1 F 0.0580(9) 0.5711(10) 0.3272(8) 0.085(4) Uani 0.37 1 d P B 1
F2 F 0.0443(14) 0.4572(9) 0.1641(10) 0.107(4) Uani 0.37 1 d P B 1
F3 F 0.0134(11) 0.6123(9) 0.1859(8) 0.087(3) Uani 0.37 1 d P B 1
F4 F 0.1985(13) 0.7222(9) 0.3115(9) 0.094(4) Uani 0.37 1 d P B 1
F5 F 0.2362(13) 0.5672(12) 0.2862(11) 0.113(5) Uani 0.37 1 d P B 1
F6 F 0.1938(10) 0.6097(9) 0.1511(10) 0.093(4) Uani 0.37 1 d P B 1
Sb2 Sb 0.0000 0.0000 0.0000 0.0816(3) Uani 1 2 d S . .
F7 F -0.0594(7) -0.0264(7) 0.0890(5) 0.175(3) Uani 1 1 d . C .
F8 F 0.1522(10) 0.0575(13) 0.0612(10) 0.126(6) Uani 0.50 1 d P C 1
F9 F 0.0103(19) 0.1272(12) 0.0426(15) 0.177(9) Uani 0.50 1 d P C 1
F10 F 0.0585(12) 0.1146(12) 0.0899(9) 0.142(6) Uani 0.50 1 d P C 2
F11 F 0.1173(10) -0.0203(13) 0.0559(7) 0.112(5) Uani 0.50 1 d P C 2
Sb3 Sb 0.0253(4) 0.4257(3) 0.4663(2) 0.0800(12) Uani 0.13 1 d PGD . 1
F13 F 0.0549(18) 0.3481(12) 0.4777(17) 0.22(3) Uiso 0.13 1 d PGD . 1
F14 F -0.073(2) 0.3251(16) 0.3578(13) 0.17(3) Uiso 0.13 1 d PGD . 1
F15 F -0.0537(18) 0.4803(19) 0.4207(18) 0.164(10) Uiso 0.26 1 d PGD . 1
F16 F -0.1051(17) 0.372(3) 0.498(2) 0.151(13) Uiso 0.13 1 d PG . 1
F17 F 0.1342(12) 0.477(2) 0.447(2) 0.151(13) Uiso 0.13 1 d PGD . 1
N11 N 0.9379(12) 0.3220(11) 0.0871(10) 0.088(4) Uiso 0.50 1 d P . .
C50 C -0.029(3) 0.353(2) 0.3666(16) 0.123(8) Uiso 0.55 1 d P D 2
C51 C 0.0611(17) 0.3927(15) 0.4350(14) 0.097(6) Uiso 0.55 1 d P D 2
C52 C 0.1571(13) 0.3856(11) 0.4778(10) 0.086(4) Uiso 0.55 1 d P D 2
N12 N 0.116(4) 0.676(3) 0.274(3) 0.097(11) Uiso 0.20 1 d P E 2
C53 C 0.156(2) 0.631(2) 0.295(2) 0.040(6) Uiso 0.20 1 d P E 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N7 Ag1 N10 148.27(17) . 1_544
N7 Ag1 N3 104.2(4) . 1_545
N10 Ag1 N3 107.1(4) 1_544 1_545
N7 Ag1 N4 113.1(7) . 1_545
N10 Ag1 N4 97.0(6) 1_544 1_545
N3 Ag1 N4 12.8(5) 1_545 1_545
N8 Ga1 N6 90.07(18) . .
N8 Ga1 N1 178.67(17) . .
N6 Ga1 N1 91.25(19) . .
N8 Ga1 N9 88.55(16) . .
N6 Ga1 N9 91.58(17) . .
N1 Ga1 N9 91.25(16) . .
N8 Ga1 N2 90.12(16) . .
N6 Ga1 N2 178.22(17) . .
N1 Ga1 N2 88.56(17) . .
N9 Ga1 N2 90.20(16) . .
N8 Ga1 N5 93.52(16) . .
N6 Ga1 N5 88.00(16) . .
N1 Ga1 N5 86.69(16) . .
N9 Ga1 N5 177.89(15) . .
N2 Ga1 N5 90.22(16) . .
N1 C1 C2 111.8(6) . .
N1 C1 H1 124.1 . .
C2 C1 H1 124.1 . .
C3 C2 C1 107.0(6) . .
C3 C2 H2 126.5 . .
C1 C2 H2 126.5 . .
C2 C3 C4 107.6(6) . .
C2 C3 H3 126.2 . .
C4 C3 H3 126.2 . .
C5 C4 N1 124.5(4) . .
C5 C4 C3 127.3(6) . .
N1 C4 C3 108.1(6) . .
C6 C5 C4 126.3(5) . .
C6 C5 C10 117.2(5) . .
C4 C5 C10 116.5(5) . .
C5 C6 N2 124.5(5) . .
C5 C6 C7 126.4(5) . .
N2 C6 C7 109.1(4) . .
C8 C7 C6 106.7(5) . .
C8 C7 H7 126.7 . .
C6 C7 H7 126.7 . .
C7 C8 C9 106.5(5) . .
C7 C8 H8 126.7 . .
C9 C8 H8 126.7 . .
N2 C9 C8 111.7(5) . .
N2 C9 H9 124.2 . .
C8 C9 H9 124.2 . .
C16 C10 C13 111.4(7) . .
C16 C10 C11 113.7(6) . .
C13 C10 C11 47.3(7) . .
C16 C10 C5 124.4(5) . .
C13 C10 C5 117.1(8) . .
C11 C10 C5 118.6(5) . .
C12 C11 C10 120.2(7) . .
C12 C11 H11 119.9 . .
C10 C11 H11 119.9 . .
N3 C12 C11 119.2(11) . .
N3 C12 H12 120.4 . .
C11 C12 H12 120.4 . .
C14 C13 C10 114.8(12) . .
C14 C13 H13 122.6 . .
C10 C13 H13 122.6 . .
N4 C14 C13 126.6(18) . .
N4 C14 H14 116.7 . .
C13 C14 H14 116.7 . .
N4 C15 C16 123.1(15) . .
N3 C15 C16 122.6(9) . .
N4 C15 H15 112.9 . .
N3 C15 H15 118.7 . .
C16 C15 H15 118.7 . .
C10 C16 C15 121.5(5) . .
C10 C16 H16 119.2 . .
C15 C16 H16 119.2 . .
N5 C17 C18 111.6(5) . .
N5 C17 H17 124.2 . .
C18 C17 H17 124.2 . .
C19 C18 C17 106.7(5) . .
C19 C18 H18 126.7 . .
C17 C18 H18 126.7 . .
C18 C19 C20 107.3(5) . .
C18 C19 H19 126.4 . .
C20 C19 H19 126.4 . .
C21 C20 N5 123.2(4) . .
C21 C20 C19 128.0(5) . .
N5 C20 C19 108.8(4) . .
C22 C21 C20 127.3(5) . .
C22 C21 C29 117.1(5) . .
C20 C21 C29 115.6(5) . .
N6 C22 C21 124.2(5) . .
N6 C22 C23 107.6(5) . .
C21 C22 C23 127.7(5) . .
N6 C22 C26 110.4(18) . .
C21 C22 C26 119(2) . .
C24 C23 C22 108.1(7) . .
C24 C23 H23 126.0 . .
C22 C23 H23 126.0 . .
C23 C24 C25 105.5(8) . .
C23 C24 H24 127.2 . .
C25 C24 H24 127.2 . .
N6 C25 C24 112.2(8) . .
N6 C25 H25 123.9 . .
C24 C25 H25 123.9 . .
C22 C26 C27 100(4) . .
C22 C26 H26 129.9 . .
C27 C26 H26 129.9 . .
C28 C27 C26 98(5) . .
C28 C27 H27 130.8 . .
C26 C27 H27 130.8 . .
N6 C28 C27 120(5) . .
N6 C28 H28 120.1 . .
C27 C28 H28 120.1 . .
C33 C29 C30 118.3(5) . .
C33 C29 C21 120.1(5) . .
C30 C29 C21 121.6(5) . .
C29 C30 C31 119.0(5) . .
C29 C30 H30 120.5 . .
C31 C30 H30 120.5 . .
N7 C31 C30 123.9(5) . .
N7 C31 H31 118.0 . .
C30 C31 H31 118.0 . .
N7 C32 C33 123.4(6) . .
N7 C32 H32 118.3 . .
C33 C32 H32 118.3 . .
C29 C33 C32 119.0(6) . .
C29 C33 H33 120.5 . .
C32 C33 H33 120.5 . .
N8 C34 C35 111.9(5) . .
N8 C34 H34 124.1 . .
C35 C34 H34 124.1 . .
C36 C35 C34 106.0(4) . .
C36 C35 H35 127.0 . .
C34 C35 H35 127.0 . .
C35 C36 C37 106.2(5) . .
C35 C36 H36 126.9 . .
C37 C36 H36 126.9 . .
N8 C37 C38 124.0(4) . .
N8 C37 C36 108.8(4) . .
C38 C37 C36 127.2(5) . .
C39 C38 C37 126.6(5) . .
C39 C38 C43 117.5(4) . .
C37 C38 C43 115.9(4) . .
C38 C39 N9 124.1(4) . .
C38 C39 C40 126.9(5) . .
N9 C39 C40 108.9(4) . .
C41 C40 C39 107.4(5) . .
C41 C40 H40 126.3 . .
C39 C40 H40 126.3 . .
C40 C41 C42 106.4(4) . .
C40 C41 H41 126.8 . .
C42 C41 H41 126.8 . .
N9 C42 C41 111.2(5) . .
N9 C42 H42 124.4 . .
C41 C42 H42 124.4 . .
C44 C43 C49 117.2(7) . .
C44 C43 C47 111.0(7) . .
C44 C43 C38 120.2(5) . .
C49 C43 C38 119.9(7) . .
C47 C43 C38 126.3(6) . .
C45 C44 C43 119.7(6) . .
C45 C44 H44 120.1 . .
C43 C44 H44 120.1 . .
N10 C45 C44 125.6(6) . .
N10 C45 H45 117.2 . .
C44 C45 H45 117.2 . .
N10 C46 C47 119.9(11) . .
N10 C46 H46 120.0 . .
C47 C46 H46 120.0 . .
C46 C47 C43 121.5(10) . .
C46 C47 H47 119.2 . .
C43 C47 H47 119.2 . .
C49 C48 N10 126.1(10) . .
C49 C48 H48 117.0 . .
N10 C48 H48 117.0 . .
C48 C49 C43 115.2(10) . .
C48 C49 H49 122.4 . .
C43 C49 H49 122.4 . .
C1 N1 C4 105.4(5) . .
C1 N1 Ga1 126.9(4) . .
C4 N1 Ga1 127.6(3) . .
C9 N2 C6 106.0(4) . .
C9 N2 Ga1 126.0(3) . .
C6 N2 Ga1 127.8(3) . .
C12 N3 C15 119.8(15) . .
C12 N3 Ag1 115.3(12) . 1_565
C15 N3 Ag1 124.8(10) . 1_565
C15 N4 C14 114(2) . .
C15 N4 Ag1 125(2) . 1_565
C14 N4 Ag1 120(2) . 1_565
C17 N5 C20 105.6(4) . .
C17 N5 Ga1 125.8(3) . .
C20 N5 Ga1 127.3(3) . .
C28 N6 C22 103(3) . .
C25 N6 C22 106.5(5) . .
C28 N6 Ga1 124(3) . .
C25 N6 Ga1 125.0(5) . .
C22 N6 Ga1 128.3(4) . .
C31 N7 C32 116.4(5) . .
C31 N7 Ag1 120.3(4) . .
C32 N7 Ag1 123.3(4) . .
C34 N8 C37 107.1(4) . .
C34 N8 Ga1 125.2(4) . .
C37 N8 Ga1 127.2(3) . .
C42 N9 C39 106.0(4) . .
C42 N9 Ga1 126.9(3) . .
C39 N9 Ga1 126.9(3) . .
C46 N10 C45 117.8(7) . .
C45 N10 C48 110.8(7) . .
C46 N10 Ag1 116.8(6) . 1_566
C45 N10 Ag1 123.4(4) . 1_566
C48 N10 Ag1 122.9(5) . 1_566
F5 Sb1 F4 94.1(7) . .
F5 Sb1 F3 176.4(7) . .
F4 Sb1 F3 88.0(6) . .
F5 Sb1 F1 90.3(6) . .
F4 Sb1 F1 89.4(6) . .
F3 Sb1 F1 92.7(5) . .
F5 Sb1 F2 88.4(7) . .
F4 Sb1 F2 177.5(7) . .
F3 Sb1 F2 89.5(6) . .
F1 Sb1 F2 90.4(6) . .
F5 Sb1 F6 88.9(6) . .
F4 Sb1 F6 91.4(6) . .
F3 Sb1 F6 88.1(6) . .
F1 Sb1 F6 178.9(5) . .
F2 Sb1 F6 88.8(6) . .
F10 Sb2 F10 180.0(10) . 2
F10 Sb2 F8 61.8(7) . .
F10 Sb2 F8 118.2(7) 2 .
F10 Sb2 F8 118.2(7) . 2
F10 Sb2 F8 61.8(7) 2 2
F8 Sb2 F8 179.999(1) . 2
F10 Sb2 F7 103.5(7) . 2
F10 Sb2 F7 76.5(7) 2 2
F8 Sb2 F7 80.5(5) . 2
F8 Sb2 F7 99.5(5) 2 2
F10 Sb2 F7 76.5(7) . .
F10 Sb2 F7 103.5(7) 2 .
F8 Sb2 F7 99.5(5) . .
F8 Sb2 F7 80.5(5) 2 .
F7 Sb2 F7 179.998(1) 2 .
F10 Sb2 F9 33.6(7) . .
F10 Sb2 F9 146.4(7) 2 .
F8 Sb2 F9 87.1(9) . .
F8 Sb2 F9 92.9(9) 2 .
F7 Sb2 F9 87.5(5) 2 .
F7 Sb2 F9 92.5(5) . .
F10 Sb2 F9 146.4(7) . 2
F10 Sb2 F9 33.6(7) 2 2
F8 Sb2 F9 92.9(9) . 2
F8 Sb2 F9 87.1(9) 2 2
F7 Sb2 F9 92.5(5) 2 2
F7 Sb2 F9 87.5(5) . 2
F9 Sb2 F9 179.999(1) . 2
F10 Sb2 F11 92.8(6) . 2
F10 Sb2 F11 87.2(6) 2 2
F8 Sb2 F11 144.8(5) . 2
F8 Sb2 F11 35.2(5) 2 2
F7 Sb2 F11 82.8(4) 2 2
F7 Sb2 F11 97.2(4) . 2
F9 Sb2 F11 61.3(9) . 2
F9 Sb2 F11 118.7(9) 2 2
F10 Sb2 F11 87.2(6) . .
F10 Sb2 F11 92.8(6) 2 .
F8 Sb2 F11 35.2(5) . .
F8 Sb2 F11 144.8(5) 2 .
F7 Sb2 F11 97.2(4) 2 .
F7 Sb2 F11 82.8(4) . .
F9 Sb2 F11 118.7(9) . .
F9 Sb2 F11 61.3(9) 2 .
F11 Sb2 F11 179.999(1) 2 .
F13 Sb3 F17 93.9 . .
F13 Sb3 F15 159.3 . .
F17 Sb3 F15 96.7 . .
F13 Sb3 F14 83.4 . .
F17 Sb3 F14 105.7 . .
F15 Sb3 F14 76.6 . .
F13 Sb3 F15 109(2) . 2_566
F17 Sb3 F15 99(3) . 2_566
F15 Sb3 F15 87.0(19) . 2_566
F14 Sb3 F15 151(2) . 2_566
F13 Sb3 F16 88.3 . .
F17 Sb3 F16 175.7 . .
F15 Sb3 F16 82.3 . .
F14 Sb3 F16 78.3 . .
F15 Sb3 F16 76(3) 2_566 .
F13 Sb3 Sb3 149.9(10) . 2_566
F17 Sb3 Sb3 101.1(11) . 2_566
F15 Sb3 Sb3 43.8(9) . 2_566
F14 Sb3 Sb3 116.7(9) . 2_566
F15 Sb3 Sb3 43.2(10) 2_566 2_566
F16 Sb3 Sb3 75.3(11) . 2_566
Sb3 F15 Sb3 93.0(10) . 2_566
C50 C51 C52 148(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N7 2.216(5) .
Ag1 N10 2.219(5) 1_544
Ag1 N3 2.354(19) 1_545
Ag1 N4 2.38(3) 1_545
Ga1 N8 2.040(4) .
Ga1 N6 2.049(4) .
Ga1 N1 2.051(4) .
Ga1 N9 2.053(4) .
Ga1 N2 2.066(4) .
Ga1 N5 2.069(4) .
C1 N1 1.344(7) .
C1 C2 1.396(9) .
C1 H1 0.9500 .
C2 C3 1.351(11) .
C2 H2 0.9500 .
C3 C4 1.423(7) .
C3 H3 0.9500 .
C4 C5 1.406(8) .
C4 N1 1.409(7) .
C5 C6 1.397(7) .
C5 C10 1.482(8) .
C6 N2 1.397(6) .
C6 C7 1.418(8) .
C7 C8 1.377(8) .
C7 H7 0.9500 .
C8 C9 1.406(8) .
C8 H8 0.9500 .
C9 N2 1.337(6) .
C9 H9 0.9500 .
C10 C16 1.331(7) .
C10 C13 1.461(14) .
C10 C11 1.467(10) .
C11 C12 1.408(14) .
C11 H11 0.9500 .
C12 N3 1.318(19) .
C12 H12 0.9500 .
C13 C14 1.37(2) .
C13 H13 0.9500 .
C14 N4 1.33(4) .
C14 H14 0.9500 .
C15 N4 1.31(3) .
C15 N3 1.337(19) .
C15 C16 1.371(8) .
C15 H15 0.9500 .
C16 H16 0.9500 .
C17 N5 1.332(6) .
C17 C18 1.407(7) .
C17 H17 0.9500 .
C18 C19 1.357(8) .
C18 H18 0.9500 .
C19 C20 1.409(7) .
C19 H19 0.9500 .
C20 C21 1.400(7) .
C20 N5 1.404(6) .
C21 C22 1.393(8) .
C21 C29 1.512(7) .
C22 N6 1.385(7) .
C22 C23 1.445(9) .
C22 C26 1.46(5) .
C23 C24 1.389(13) .
C23 H23 0.9500 .
C24 C25 1.390(13) .
C24 H24 0.9500 .
C25 N6 1.374(10) .
C25 H25 0.9500 .
C26 C27 1.53(8) .
C26 H26 0.9500 .
C27 C28 1.36(9) .
C27 H27 0.9500 .
C28 N6 1.28(6) .
C28 H28 0.9500 .
C29 C33 1.361(8) .
C29 C30 1.368(7) .
C30 C31 1.392(8) .
C30 H30 0.9500 .
C31 N7 1.305(7) .
C31 H31 0.9500 .
C32 N7 1.345(8) .
C32 C33 1.385(9) .
C32 H32 0.9500 .
C33 H33 0.9500 .
C34 N8 1.317(6) .
C34 C35 1.431(8) .
C34 H34 0.9500 .
C35 C36 1.384(8) .
C35 H35 0.9500 .
C36 C37 1.441(7) .
C36 H36 0.9500 .
C37 N8 1.395(7) .
C37 C38 1.403(7) .
C38 C39 1.392(7) .
C38 C43 1.478(7) .
C39 N9 1.394(6) .
C39 C40 1.415(7) .
C40 C41 1.360(7) .
C40 H40 0.9500 .
C41 C42 1.413(7) .
C41 H41 0.9500 .
C42 N9 1.342(6) .
C42 H42 0.9500 .
C43 C44 1.372(8) .
C43 C49 1.386(14) .
C43 C47 1.445(13) .
C44 C45 1.355(9) .
C44 H44 0.9500 .
C45 N10 1.301(7) .
C45 H45 0.9500 .
C46 N10 1.263(14) .
C46 C47 1.406(16) .
C46 H46 0.9500 .
C47 H47 0.9500 .
C48 C49 1.371(18) .
C48 N10 1.413(18) .
C48 H48 0.9500 .
C49 H49 0.9500 .
N3 Ag1 2.354(19) 1_565
N4 Ag1 2.38(3) 1_565
N10 Ag1 2.219(5) 1_566
Sb1 F5 1.790(12) .
Sb1 F4 1.810(13) .
Sb1 F3 1.817(11) .
Sb1 F1 1.848(11) .
Sb1 F2 1.868(12) .
Sb1 F6 1.873(12) .
Sb2 F10 1.731(13) .
Sb2 F10 1.732(13) 2
Sb2 F8 1.839(11) .
Sb2 F8 1.839(11) 2
Sb2 F7 1.850(6) 2
Sb2 F7 1.850(6) .
Sb2 F9 1.875(11) .
Sb2 F9 1.875(11) 2
Sb2 F11 1.882(10) 2
Sb2 F11 1.882(10) .
Sb3 F13 1.4966 .
Sb3 F17 1.5193 .
Sb3 F15 1.8227 .
Sb3 F14 1.8318 .
Sb3 F15 1.845(9) 2_566
Sb3 F16 1.8635 .
Sb3 Sb3 2.661(11) 2_566
F15 Sb3 1.84(3) 2_566
C50 C51 1.29(3) .
C51 C52 1.43(2) .
N12 C53 1.14(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 3.1(7) . .
C1 C2 C3 C4 -2.4(7) . .
C2 C3 C4 C5 -176.5(5) . .
C2 C3 C4 N1 1.0(6) . .
N1 C4 C5 C6 -2.0(8) . .
C3 C4 C5 C6 175.2(5) . .
N1 C4 C5 C10 178.2(4) . .
C3 C4 C5 C10 -4.7(8) . .
C4 C5 C6 N2 2.0(8) . .
C10 C5 C6 N2 -178.1(4) . .
C4 C5 C6 C7 -178.8(5) . .
C10 C5 C6 C7 1.0(7) . .
C5 C6 C7 C8 179.2(5) . .
N2 C6 C7 C8 -1.5(6) . .
C6 C7 C8 C9 1.7(6) . .
C7 C8 C9 N2 -1.4(6) . .
C6 C5 C10 C16 95.9(7) . .
C4 C5 C10 C16 -84.2(8) . .
C6 C5 C10 C13 -116.2(9) . .
C4 C5 C10 C13 63.7(10) . .
C6 C5 C10 C11 -62.3(8) . .
C4 C5 C10 C11 117.6(7) . .
C16 C10 C11 C12 17.8(13) . .
C13 C10 C11 C12 -80.1(12) . .
C5 C10 C11 C12 178.2(8) . .
C10 C11 C12 N3 -5.7(17) . .
C16 C10 C13 C14 -29.7(16) . .
C11 C10 C13 C14 73.4(14) . .
C5 C10 C13 C14 178.4(11) . .
C10 C13 C14 N4 15(3) . .
C13 C10 C16 C15 33.0(12) . .
C11 C10 C16 C15 -18.4(10) . .
C5 C10 C16 C15 -177.5(6) . .
N4 C15 C16 C10 -20.0(15) . .
N3 C15 C16 C10 7.4(12) . .
N5 C17 C18 C19 -0.9(6) . .
C17 C18 C19 C20 0.0(6) . .
C18 C19 C20 C21 179.4(5) . .
C18 C19 C20 N5 0.8(6) . .
N5 C20 C21 C22 0.6(8) . .
C19 C20 C21 C22 -177.7(5) . .
N5 C20 C21 C29 178.8(4) . .
C19 C20 C21 C29 0.5(7) . .
C20 C21 C22 N6 3.9(9) . .
C29 C21 C22 N6 -174.3(5) . .
C20 C21 C22 C23 -167.1(8) . .
C29 C21 C22 C23 14.7(10) . .
C20 C21 C22 C26 154(3) . .
C29 C21 C22 C26 -24(3) . .
N6 C22 C23 C24 0.8(9) . .
C21 C22 C23 C24 173.1(8) . .
C26 C22 C23 C24 -100(4) . .
C22 C23 C24 C25 -2.8(11) . .
C23 C24 C25 N6 4.0(12) . .
N6 C22 C26 C27 -21(4) . .
C21 C22 C26 C27 -176(3) . .
C23 C22 C26 C27 70(4) . .
C22 C26 C27 C28 26(5) . .
C26 C27 C28 N6 -27(7) . .
C22 C21 C29 C33 64.8(7) . .
C20 C21 C29 C33 -113.6(6) . .
C22 C21 C29 C30 -115.8(6) . .
C20 C21 C29 C30 65.8(7) . .
C33 C29 C30 C31 0.8(9) . .
C21 C29 C30 C31 -178.6(6) . .
C29 C30 C31 N7 0.1(11) . .
C30 C29 C33 C32 -1.6(10) . .
C21 C29 C33 C32 177.8(6) . .
N7 C32 C33 C29 1.6(11) . .
N8 C34 C35 C36 -0.7(6) . .
C34 C35 C36 C37 0.8(6) . .
C35 C36 C37 N8 -0.7(6) . .
C35 C36 C37 C38 178.7(5) . .
N8 C37 C38 C39 4.8(8) . .
C36 C37 C38 C39 -174.5(5) . .
N8 C37 C38 C43 -173.8(5) . .
C36 C37 C38 C43 6.9(8) . .
C37 C38 C39 N9 -4.1(9) . .
C43 C38 C39 N9 174.4(5) . .
C37 C38 C39 C40 171.3(5) . .
C43 C38 C39 C40 -10.1(8) . .
C38 C39 C40 C41 -173.6(5) . .
N9 C39 C40 C41 2.5(6) . .
C39 C40 C41 C42 -2.9(6) . .
C40 C41 C42 N9 2.4(7) . .
C39 C38 C43 C44 -82.2(7) . .
C37 C38 C43 C44 96.5(7) . .
C39 C38 C43 C49 116.9(15) . .
C37 C38 C43 C49 -64.4(15) . .
C39 C38 C43 C47 78.2(12) . .
C37 C38 C43 C47 -103.1(12) . .
C49 C43 C44 C45 -18.8(16) . .
C47 C43 C44 C45 16.6(12) . .
C38 C43 C44 C45 179.8(6) . .
C43 C44 C45 N10 -1.3(12) . .
N10 C46 C47 C43 0.3(17) . .
C44 C43 C47 C46 -16.5(15) . .
C49 C43 C47 C46 91.5(17) . .
C38 C43 C47 C46 -178.4(9) . .
N10 C48 C49 C43 0(2) . .
C44 C43 C49 C48 19(2) . .
C47 C43 C49 C48 -68.4(15) . .
C38 C43 C49 C48 179.9(11) . .
C2 C1 N1 C4 -2.4(6) . .
C2 C1 N1 Ga1 -178.7(4) . .
C5 C4 N1 C1 178.4(5) . .
C3 C4 N1 C1 0.8(6) . .
C5 C4 N1 Ga1 -5.3(7) . .
C3 C4 N1 Ga1 177.1(4) . .
N6 Ga1 N1 C1 5.8(4) . .
N9 Ga1 N1 C1 -85.8(4) . .
N2 Ga1 N1 C1 -176.0(4) . .
N5 Ga1 N1 C1 93.7(4) . .
N6 Ga1 N1 C4 -169.8(4) . .
N9 Ga1 N1 C4 98.6(4) . .
N2 Ga1 N1 C4 8.5(4) . .
N5 Ga1 N1 C4 -81.8(4) . .
C8 C9 N2 C6 0.4(6) . .
C8 C9 N2 Ga1 175.4(3) . .
C5 C6 N2 C9 180.0(5) . .
C7 C6 N2 C9 0.7(5) . .
C5 C6 N2 Ga1 5.2(7) . .
C7 C6 N2 Ga1 -174.1(3) . .
N8 Ga1 N2 C9 -2.1(4) . .
N1 Ga1 N2 C9 177.7(4) . .
N9 Ga1 N2 C9 86.4(4) . .
N5 Ga1 N2 C9 -95.7(4) . .
N8 Ga1 N2 C6 171.7(4) . .
N1 Ga1 N2 C6 -8.5(4) . .
N9 Ga1 N2 C6 -99.7(4) . .
N5 Ga1 N2 C6 78.2(4) . .
C11 C12 N3 C15 -6.6(18) . .
C11 C12 N3 Ag1 173.7(8) . 1_565
N4 C15 N3 C12 105(6) . .
C16 C15 N3 C12 6.4(17) . .
N4 C15 N3 Ag1 -75(5) . 1_565
C16 C15 N3 Ag1 -173.9(7) . 1_565
N3 C15 N4 C14 -95(5) . .
C16 C15 N4 C14 1(2) . .
N3 C15 N4 Ag1 72(5) . 1_565
C16 C15 N4 Ag1 168.8(8) . 1_565
C13 C14 N4 C15 0(3) . .
C13 C14 N4 Ag1 -168.3(14) . 1_565
C18 C17 N5 C20 1.4(5) . .
C18 C17 N5 Ga1 -166.6(3) . .
C21 C20 N5 C17 -180.0(4) . .
C19 C20 N5 C17 -1.4(5) . .
C21 C20 N5 Ga1 -12.3(6) . .
C19 C20 N5 Ga1 166.3(3) . .
N8 Ga1 N5 C17 -90.5(4) . .
N6 Ga1 N5 C17 179.5(4) . .
N1 Ga1 N5 C17 88.1(4) . .
N2 Ga1 N5 C17 -0.4(4) . .
N8 Ga1 N5 C20 104.1(4) . .
N6 Ga1 N5 C20 14.1(4) . .
N1 Ga1 N5 C20 -77.2(4) . .
N2 Ga1 N5 C20 -165.8(4) . .
C27 C28 N6 C25 -86(8) . .
C27 C28 N6 C22 14(6) . .
C27 C28 N6 Ga1 172(4) . .
C24 C25 N6 C28 83(6) . .
C24 C25 N6 C22 -3.5(10) . .
C24 C25 N6 Ga1 -178.5(6) . .
C21 C22 N6 C28 160(3) . .
C23 C22 N6 C28 -28(3) . .
C26 C22 N6 C28 7(3) . .
C21 C22 N6 C25 -171.0(7) . .
C23 C22 N6 C25 1.5(8) . .
C26 C22 N6 C25 36(3) . .
C21 C22 N6 Ga1 3.8(9) . .
C23 C22 N6 Ga1 176.3(6) . .
C26 C22 N6 Ga1 -149(3) . .
N8 Ga1 N6 C28 105(3) . .
N1 Ga1 N6 C28 -75(3) . .
N9 Ga1 N6 C28 17(3) . .
N5 Ga1 N6 C28 -161(3) . .
N8 Ga1 N6 C25 70.2(7) . .
N1 Ga1 N6 C25 -109.6(7) . .
N9 Ga1 N6 C25 -18.3(7) . .
N5 Ga1 N6 C25 163.8(7) . .
N8 Ga1 N6 C22 -103.6(5) . .
N1 Ga1 N6 C22 76.5(5) . .
N9 Ga1 N6 C22 167.8(5) . .
N5 Ga1 N6 C22 -10.1(5) . .
C30 C31 N7 C32 -0.2(10) . .
C30 C31 N7 Ag1 179.9(5) . .
C33 C32 N7 C31 -0.7(10) . .
C33 C32 N7 Ag1 179.3(5) . .
N10 Ag1 N7 C31 -129.0(5) 1_544 .
N3 Ag1 N7 C31 60.8(7) 1_545 .
N4 Ag1 N7 C31 70.6(9) 1_545 .
N10 Ag1 N7 C32 51.0(7) 1_544 .
N3 Ag1 N7 C32 -119.1(6) 1_545 .
N4 Ag1 N7 C32 -109.4(9) 1_545 .
C35 C34 N8 C37 0.3(6) . .
C35 C34 N8 Ga1 172.6(4) . .
C38 C37 N8 C34 -179.2(5) . .
C36 C37 N8 C34 0.2(6) . .
C38 C37 N8 Ga1 8.8(7) . .
C36 C37 N8 Ga1 -171.8(3) . .
N6 Ga1 N8 C34 82.2(4) . .
N9 Ga1 N8 C34 173.8(4) . .
N2 Ga1 N8 C34 -96.0(4) . .
N5 Ga1 N8 C34 -5.8(4) . .
N6 Ga1 N8 C37 -107.2(4) . .
N9 Ga1 N8 C37 -15.6(4) . .
N2 Ga1 N8 C37 74.6(4) . .
N5 Ga1 N8 C37 164.9(4) . .
C41 C42 N9 C39 -0.9(6) . .
C41 C42 N9 Ga1 -175.7(4) . .
C38 C39 N9 C42 175.2(5) . .
C40 C39 N9 C42 -0.9(6) . .
C38 C39 N9 Ga1 -9.9(7) . .
C40 C39 N9 Ga1 173.9(4) . .
N8 Ga1 N9 C42 -170.1(4) . .
N6 Ga1 N9 C42 -80.1(4) . .
N1 Ga1 N9 C42 11.2(4) . .
N2 Ga1 N9 C42 99.8(4) . .
N8 Ga1 N9 C39 16.2(4) . .
N6 Ga1 N9 C39 106.2(4) . .
N1 Ga1 N9 C39 -162.5(4) . .
N2 Ga1 N9 C39 -74.0(4) . .
C47 C46 N10 C45 16.4(16) . .
C47 C46 N10 C48 -69.1(15) . .
C47 C46 N10 Ag1 -179.0(8) . 1_566
C44 C45 N10 C46 -16.9(14) . .
C44 C45 N10 C48 18.4(15) . .
C44 C45 N10 Ag1 179.6(6) . 1_566
C49 C48 N10 C46 92(2) . .
C49 C48 N10 C45 -18(2) . .
C49 C48 N10 Ag1 -179.1(12) . 1_566
F13 Sb3 F15 Sb3 140.8(15) . 2_566
F17 Sb3 F15 Sb3 -99.0(15) . 2_566
F14 Sb3 F15 Sb3 156.4(15) . 2_566
F15 Sb3 F15 Sb3 0.0(14) 2_566 2_566
F16 Sb3 F15 Sb3 76.7(15) . 2_566
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.276 0.500 1.000 806.8 195.6
