#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:18:00 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179446 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/43/4334355.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334355
loop_
_publ_author_name
'Shih-Pu Liu'
'Meng-Ling Chen'
'Bor-Chen Chang'
'Kwang-Hwa Lii'
_publ_section_title
;
 Flux Synthesis, Crystal Structure, and Photoluminescence of a
 Heterometallic Uranyl-Europium Germanate with U=O-Eu Linkage:
 K4[(UO2)Eu2(Ge2O7)2]
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3990
_journal_page_last               3994
_journal_paper_doi               10.1021/ic302826u
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'Eu2 Ge4 K4 O16 U'
_chemical_formula_weight         1244.71
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   none
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.695(2)
_cell_angle_beta                 98.659(2)
_cell_angle_gamma                110.512(2)
_cell_formula_units_Z            1
_cell_length_a                   6.9491(4)
_cell_length_b                   6.9502(4)
_cell_length_c                   9.9102(5)
_cell_measurement_temperature    296(2)
_cell_volume                     438.48(4)
_computing_molecular_graphics    Diamond
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0225
_diffrn_reflns_av_sigmaI/netI    0.0206
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            8041
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         2.10
_exptl_absorpt_coefficient_mu    24.024
_exptl_absorpt_correction_T_max  0.746
_exptl_absorpt_correction_T_min  0.490
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS program'
_exptl_crystal_colour            light-yellow
_exptl_crystal_density_diffrn    4.714
_exptl_crystal_description       block
_exptl_crystal_F_000             550
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.881
_refine_diff_density_min         -0.721
_refine_diff_density_rms         0.157
_refine_ls_extinction_coef       0.0117(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.100
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     125
_refine_ls_number_reflns         2174
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.100
_refine_ls_R_factor_all          0.0155
_refine_ls_R_factor_gt           0.0148
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0115P)²+0.7214P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0331
_refine_ls_wR_factor_ref         0.0334
_reflns_number_gt                2098
_reflns_number_total             2174
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic302826u_si_002.cif
_cod_data_source_block           keuugeo
_cod_original_cell_volume        438.47(4)
_cod_database_code               4334355
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
K1 K 0.04000(12) 0.75681(12) 0.60206(8) 0.01393(16) Uani 1 1 d .
K2 K 0.16237(15) 0.80846(15) -0.04019(9) 0.0262(2) Uani 1 1 d .
U1 U 0.5000 0.5000 0.0000 0.00694(6) Uani 1 2 d S
Eu1 Eu 0.48001(2) 0.72809(2) 0.403701(16) 0.00652(5) Uani 1 1 d .
Ge1 Ge 0.03491(5) 0.24084(5) -0.26310(3) 0.00716(8) Uani 1 1 d .
Ge2 Ge 0.62402(5) 0.83080(5) 0.73611(3) 0.00649(8) Uani 1 1 d .
O1 O 0.1683(4) 0.3896(4) -0.1027(2) 0.0127(5) Uani 1 1 d .
O2 O 0.1906(4) 0.1862(4) -0.3680(2) 0.0124(5) Uani 1 1 d .
O3 O -0.1280(4) 0.3479(4) -0.3501(2) 0.0121(5) Uani 1 1 d .
O4 O -0.1093(4) -0.0006(4) -0.2076(3) 0.0125(5) Uani 1 1 d .
O5 O 0.6190(4) 0.6278(4) 0.6202(2) 0.0101(5) Uani 1 1 d .
O6 O 0.4750(4) 0.9327(4) 0.6289(2) 0.0113(5) Uani 1 1 d .
O7 O 0.5417(4) 0.7770(4) 0.8905(2) 0.0132(5) Uani 1 1 d .
O8 O 0.4305(4) 0.6394(4) 0.1408(2) 0.0125(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 K1 O3 61.86(7) 2_565 2_565
O2 K1 O2 79.86(8) 2_565 1_566
O3 K1 O2 102.48(7) 2_565 1_566
O2 K1 O3 110.14(7) 2_565 1_556
O3 K1 O3 94.14(7) 2_565 1_556
O2 K1 O3 163.28(8) 1_566 1_556
O2 K1 O5 69.64(7) 2_565 1_455
O3 K1 O5 116.53(7) 2_565 1_455
O2 K1 O5 106.73(7) 1_566 1_455
O3 K1 O5 66.48(7) 1_556 1_455
O2 K1 O6 115.95(7) 2_565 .
O3 K1 O6 73.57(7) 2_565 .
O2 K1 O6 67.11(7) 1_566 .
O3 K1 O6 116.94(7) 1_556 .
O5 K1 O6 169.61(8) 1_455 .
O2 K1 O4 94.22(7) 2_565 1_566
O3 K1 O4 153.35(7) 2_565 1_566
O2 K1 O4 59.03(7) 1_566 1_566
O3 K1 O4 105.87(7) 1_556 1_566
O5 K1 O4 59.05(7) 1_455 1_566
O6 K1 O4 110.93(7) . 1_566
O2 K1 Ge1 31.12(5) 2_565 2_565
O3 K1 Ge1 31.26(5) 2_565 2_565
O2 K1 Ge1 87.39(5) 1_566 2_565
O3 K1 Ge1 108.15(6) 1_556 2_565
O5 K1 Ge1 95.92(5) 1_455 2_565
O6 K1 Ge1 92.20(5) . 2_565
O4 K1 Ge1 123.07(5) 1_566 2_565
O2 K1 K2 149.56(6) 2_565 1_556
O3 K1 K2 148.45(6) 2_565 1_556
O2 K1 K2 86.90(6) 1_566 1_556
O3 K1 K2 77.85(6) 1_556 1_556
O5 K1 K2 88.49(5) 1_455 1_556
O6 K1 K2 82.92(5) . 1_556
O4 K1 K2 55.69(5) 1_566 1_556
Ge1 K1 K2 173.60(3) 2_565 1_556
O2 K1 Ge1 83.57(6) 2_565 1_566
O3 K1 Ge1 127.32(6) 2_565 1_566
O2 K1 Ge1 28.55(5) 1_566 1_566
O3 K1 Ge1 136.57(6) 1_556 1_566
O5 K1 Ge1 81.79(5) 1_455 1_566
O6 K1 Ge1 90.01(5) . 1_566
O4 K1 Ge1 30.73(5) 1_566 1_566
Ge1 K1 Ge1 103.77(2) 2_565 1_566
K2 K1 Ge1 72.22(2) 1_556 1_566
O2 K1 Ge2 79.26(5) 2_565 1_455
O3 K1 Ge2 138.80(5) 2_565 1_455
O2 K1 Ge2 82.24(5) 1_566 1_455
O3 K1 Ge2 86.47(5) 1_556 1_455
O5 K1 Ge2 28.85(5) 1_455 1_455
O6 K1 Ge2 141.20(6) . 1_455
O4 K1 Ge2 30.28(5) 1_566 1_455
Ge1 K1 Ge2 110.23(2) 2_565 1_455
K2 K1 Ge2 71.82(2) 1_556 1_455
Ge1 K1 Ge2 54.796(14) 1_566 1_455
O2 K1 K1 84.77(6) 2_565 2_566
O3 K1 K1 47.30(5) 2_565 2_566
O2 K1 K1 149.74(6) 1_566 2_566
O3 K1 K1 46.84(5) 1_556 2_566
O5 K1 K1 91.87(6) 1_455 2_566
O6 K1 K1 97.30(6) . 2_566
O4 K1 K1 148.77(6) 1_566 2_566
Ge1 K1 K1 66.70(2) 2_565 2_566
K2 K1 K1 117.91(3) 1_556 2_566
Ge1 K1 K1 168.08(4) 1_566 2_566
Ge2 K1 K1 120.33(3) 1_455 2_566
O4 K2 O1 57.01(7) 2_565 2_565
O4 K2 O7 128.46(8) 2_565 1_554
O1 K2 O7 141.16(8) 2_565 1_554
O4 K2 O1 128.72(7) 2_565 .
O1 K2 O1 84.88(8) 2_565 .
O7 K2 O1 62.48(7) 1_554 .
O4 K2 O8 86.09(7) 2_565 .
O1 K2 O8 87.40(7) 2_565 .
O7 K2 O8 57.86(7) 1_554 .
O1 K2 O8 56.68(7) . .
O4 K2 O7 56.17(7) 2_565 2_676
O1 K2 O7 113.06(7) 2_565 2_676
O7 K2 O7 82.84(8) 1_554 2_676
O1 K2 O7 137.39(7) . 2_676
O8 K2 O7 84.72(7) . 2_676
O4 K2 O4 90.21(7) 2_565 1_565
O1 K2 O4 91.26(7) 2_565 1_565
O7 K2 O4 124.48(7) 1_554 1_565
O1 K2 O4 126.73(7) . 1_565
O8 K2 O4 176.22(8) . 1_565
O7 K2 O4 92.56(7) 2_676 1_565
O4 K2 K1 143.72(6) 2_565 1_554
O1 K2 K1 117.89(6) 2_565 1_554
O7 K2 K1 79.85(5) 1_554 1_554
O1 K2 K1 82.00(5) . 1_554
O8 K2 K1 130.13(6) . 1_554
O7 K2 K1 117.21(5) 2_676 1_554
O4 K2 K1 53.54(5) 1_565 1_554
O4 K2 Ge1 31.14(5) 2_565 2_565
O1 K2 Ge1 30.13(5) 2_565 2_565
O7 K2 Ge1 131.60(5) 1_554 2_565
O1 K2 Ge1 99.91(5) . 2_565
O8 K2 Ge1 74.58(5) . 2_565
O7 K2 Ge1 84.53(5) 2_676 2_565
O4 K2 Ge1 102.57(5) 1_565 2_565
K1 K2 Ge1 145.73(3) 1_554 2_565
O4 K2 Ge2 30.22(5) 2_565 2_676
O1 K2 Ge2 84.80(5) 2_565 2_676
O7 K2 Ge2 99.92(6) 1_554 2_676
O1 K2 Ge2 130.06(5) . 2_676
O8 K2 Ge2 74.14(5) . 2_676
O7 K2 Ge2 29.54(5) 2_676 2_676
O4 K2 Ge2 102.23(5) 1_565 2_676
K1 K2 Ge2 144.16(3) 1_554 2_676
Ge1 K2 Ge2 55.336(16) 2_565 2_676
O4 K2 U1 115.96(5) 2_565 .
O1 K2 U1 103.84(6) 2_565 .
O7 K2 U1 37.32(5) 1_554 .
O1 K2 U1 36.66(5) . .
O8 K2 U1 29.87(5) . .
O7 K2 U1 100.76(5) 2_676 .
O4 K2 U1 153.79(6) 1_565 .
K1 K2 U1 100.26(3) 1_554 .
Ge1 K2 U1 101.09(2) 2_565 .
Ge2 K2 U1 100.39(2) 2_676 .
O4 K2 K2 47.14(5) 2_565 2_575
O1 K2 K2 69.16(6) 2_565 2_575
O7 K2 K2 147.11(7) 1_554 2_575
O1 K2 K2 149.95(6) . 2_575
O8 K2 K2 133.23(6) . 2_575
O7 K2 K2 69.67(6) 2_676 2_575
O4 K2 K2 43.07(5) 1_565 2_575
K1 K2 K2 96.60(3) 1_554 2_575
Ge1 K2 K2 64.85(2) 2_565 2_575
Ge2 K2 K2 64.22(2) 2_676 2_575
U1 K2 K2 163.06(4) . 2_575
O8 U1 O8 180.00(10) . 2_665
O8 U1 O1 92.53(10) . 2_665
O8 U1 O1 87.47(10) 2_665 2_665
O8 U1 O1 87.47(10) . .
O8 U1 O1 92.53(10) 2_665 .
O1 U1 O1 180.0 2_665 .
O8 U1 O7 92.28(10) . 2_666
O8 U1 O7 87.72(10) 2_665 2_666
O1 U1 O7 85.91(9) 2_665 2_666
O1 U1 O7 94.09(9) . 2_666
O8 U1 O7 87.72(10) . 1_554
O8 U1 O7 92.28(10) 2_665 1_554
O1 U1 O7 94.09(9) 2_665 1_554
O1 U1 O7 85.91(9) . 1_554
O7 U1 O7 180.000(1) 2_666 1_554
O8 U1 K2 126.47(7) . 2_665
O8 U1 K2 53.53(7) 2_665 2_665
O1 U1 K2 52.81(7) 2_665 2_665
O1 U1 K2 127.19(7) . 2_665
O7 U1 K2 51.64(7) 2_666 2_665
O7 U1 K2 128.36(7) 1_554 2_665
O8 U1 K2 53.53(7) . .
O8 U1 K2 126.47(7) 2_665 .
O1 U1 K2 127.19(7) 2_665 .
O1 U1 K2 52.81(7) . .
O7 U1 K2 128.36(7) 2_666 .
O7 U1 K2 51.64(7) 1_554 .
K2 U1 K2 180.0 2_665 .
O8 U1 Eu1 20.48(7) . .
O8 U1 Eu1 159.52(7) 2_665 .
O1 U1 Eu1 77.75(6) 2_665 .
O1 U1 Eu1 102.25(6) . .
O7 U1 Eu1 77.26(6) 2_666 .
O7 U1 Eu1 102.74(6) 1_554 .
K2 U1 Eu1 105.982(14) 2_665 .
K2 U1 Eu1 74.018(14) . .
O8 U1 Eu1 159.52(7) . 2_665
O8 U1 Eu1 20.48(7) 2_665 2_665
O1 U1 Eu1 102.25(6) 2_665 2_665
O1 U1 Eu1 77.75(6) . 2_665
O7 U1 Eu1 102.74(6) 2_666 2_665
O7 U1 Eu1 77.26(6) 1_554 2_665
K2 U1 Eu1 74.018(14) 2_665 2_665
K2 U1 Eu1 105.982(14) . 2_665
Eu1 U1 Eu1 180.0 . 2_665
O8 U1 K2 112.23(8) . 1_655
O8 U1 K2 67.77(8) 2_665 1_655
O1 U1 K2 33.58(6) 2_665 1_655
O1 U1 K2 146.42(6) . 1_655
O7 U1 K2 111.18(6) 2_666 1_655
O7 U1 K2 68.82(6) 1_554 1_655
K2 U1 K2 62.93(2) 2_665 1_655
K2 U1 K2 117.07(2) . 1_655
Eu1 U1 K2 104.576(12) . 1_655
Eu1 U1 K2 75.424(12) 2_665 1_655
O8 U1 K2 67.77(8) . 2_565
O8 U1 K2 112.23(8) 2_665 2_565
O1 U1 K2 146.42(6) 2_665 2_565
O1 U1 K2 33.58(6) . 2_565
O7 U1 K2 68.82(6) 2_666 2_565
O7 U1 K2 111.18(6) 1_554 2_565
K2 U1 K2 117.07(2) 2_665 2_565
K2 U1 K2 62.93(2) . 2_565
Eu1 U1 K2 75.424(12) . 2_565
Eu1 U1 K2 104.576(12) 2_665 2_565
K2 U1 K2 180.000(13) 1_655 2_565
O2 Eu1 O3 157.40(8) 2_665 2_565
O2 Eu1 O5 99.48(9) 2_665 2_666
O3 Eu1 O5 83.36(9) 2_565 2_666
O2 Eu1 O6 84.61(9) 2_665 2_676
O3 Eu1 O6 87.45(8) 2_565 2_676
O5 Eu1 O6 165.04(8) 2_666 2_676
O2 Eu1 O5 83.99(8) 2_665 .
O3 Eu1 O5 117.72(8) 2_565 .
O5 Eu1 O5 70.54(9) 2_666 .
O6 Eu1 O5 124.36(8) 2_676 .
O2 Eu1 O6 110.31(8) 2_665 .
O3 Eu1 O6 86.68(8) 2_565 .
O5 Eu1 O6 120.59(8) 2_666 .
O6 Eu1 O6 70.41(9) 2_676 .
O5 Eu1 O6 63.33(8) . .
O2 Eu1 O8 76.77(8) 2_665 .
O3 Eu1 O8 81.83(8) 2_565 .
O5 Eu1 O8 79.20(8) 2_666 .
O6 Eu1 O8 87.83(8) 2_676 .
O5 Eu1 O8 140.71(8) . .
O6 Eu1 O8 155.83(8) . .
O2 Eu1 Ge2 93.57(6) 2_665 .
O3 Eu1 Ge2 108.24(6) 2_565 .
O5 Eu1 Ge2 98.76(6) 2_666 .
O6 Eu1 Ge2 95.32(6) 2_676 .
O5 Eu1 Ge2 31.87(5) . .
O6 Eu1 Ge2 32.18(5) . .
O8 Eu1 Ge2 169.54(5) . .
O2 Eu1 Ge2 97.24(6) 2_665 2_676
O3 Eu1 Ge2 70.08(6) 2_565 2_676
O5 Eu1 Ge2 145.31(6) 2_666 2_676
O6 Eu1 Ge2 20.35(6) 2_676 2_676
O5 Eu1 Ge2 141.69(5) . 2_676
O6 Eu1 Ge2 80.75(5) . 2_676
O8 Eu1 Ge2 75.36(6) . 2_676
Ge2 Eu1 Ge2 110.303(8) . 2_676
O2 Eu1 Eu1 91.77(6) 2_665 2_666
O3 Eu1 Eu1 103.09(6) 2_565 2_666
O5 Eu1 Eu1 36.69(6) 2_666 2_666
O6 Eu1 Eu1 158.18(6) 2_676 2_666
O5 Eu1 Eu1 33.84(5) . 2_666
O6 Eu1 Eu1 90.92(5) . 2_666
O8 Eu1 Eu1 112.33(6) . 2_666
Ge2 Eu1 Eu1 63.369(8) . 2_666
Ge2 Eu1 Eu1 169.407(9) 2_676 2_666
O2 Eu1 K1 155.53(6) 2_665 .
O3 Eu1 K1 43.41(6) 2_565 .
O5 Eu1 K1 96.09(6) 2_666 .
O6 Eu1 K1 85.17(6) 2_676 .
O5 Eu1 K1 83.56(6) . .
O6 Eu1 K1 45.23(6) . .
O8 Eu1 K1 124.96(5) . .
Ge2 Eu1 K1 65.348(13) . .
Ge2 Eu1 K1 79.972(13) 2_676 .
Eu1 Eu1 K1 89.518(13) 2_666 .
O2 Eu1 K1 42.78(7) 2_665 2_676
O3 Eu1 K1 131.10(6) 2_565 2_676
O5 Eu1 K1 142.25(6) 2_666 2_676
O6 Eu1 K1 43.93(6) 2_676 2_676
O5 Eu1 K1 98.78(6) . 2_676
O6 Eu1 K1 81.71(6) . 2_676
O8 Eu1 K1 89.93(6) . 2_676
Ge2 Eu1 K1 85.489(13) . 2_676
Ge2 Eu1 K1 61.218(13) 2_676 2_676
Eu1 Eu1 K1 124.318(13) 2_666 2_676
K1 Eu1 K1 119.191(12) . 2_676
O2 Ge1 O3 110.59(12) . .
O2 Ge1 O1 115.28(11) . .
O3 Ge1 O1 111.64(12) . .
O2 Ge1 O4 106.62(12) . .
O3 Ge1 O4 112.24(11) . .
O1 Ge1 O4 99.96(11) . .
O2 Ge1 K1 55.83(8) . 2_565
O3 Ge1 K1 56.03(8) . 2_565
O1 Ge1 K1 144.60(8) . 2_565
O4 Ge1 K1 115.44(8) . 2_565
O2 Ge1 K2 149.76(8) . 2_565
O3 Ge1 K2 99.06(8) . 2_565
O1 Ge1 K2 55.44(8) . 2_565
O4 Ge1 K2 54.27(8) . 2_565
K1 Ge1 K2 149.84(2) 2_565 2_565
O2 Ge1 K1 50.28(8) . 1_544
O3 Ge1 K1 120.72(8) . 1_544
O1 Ge1 K1 127.43(8) . 1_544
O4 Ge1 K1 56.94(8) . 1_544
K1 Ge1 K1 76.23(2) 2_565 1_544
K2 Ge1 K1 109.12(2) 2_565 1_544
O2 Ge1 K1 96.83(8) . 1_554
O3 Ge1 K1 38.36(8) . 1_554
O1 Ge1 K1 87.81(8) . 1_554
O4 Ge1 K1 148.86(8) . 1_554
K1 Ge1 K1 62.15(2) 2_565 1_554
K2 Ge1 K1 110.51(2) 2_565 1_554
K1 Ge1 K1 137.75(2) 1_544 1_554
O5 Ge2 O6 99.31(11) . .
O5 Ge2 O7 118.77(11) . .
O6 Ge2 O7 114.84(12) . .
O5 Ge2 O4 107.54(12) . 1_666
O6 Ge2 O4 114.11(11) . 1_666
O7 Ge2 O4 102.62(12) . 1_666
O5 Ge2 Eu1 48.92(7) . .
O6 Ge2 Eu1 51.77(8) . .
O7 Ge2 Eu1 143.84(8) . .
O4 Ge2 Eu1 113.50(8) 1_666 .
O5 Ge2 K2 153.02(8) . 2_676
O6 Ge2 K2 105.90(8) . 2_676
O7 Ge2 K2 58.23(8) . 2_676
O4 Ge2 K2 53.14(8) 1_666 2_676
Eu1 Ge2 K2 150.440(19) . 2_676
O5 Ge2 K1 50.81(8) . 1_655
O6 Ge2 K1 114.73(8) . 1_655
O7 Ge2 K1 130.42(8) . 1_655
O4 Ge2 K1 56.89(8) 1_666 1_655
Eu1 Ge2 K1 72.647(14) . 1_655
K2 Ge2 K1 108.24(2) 2_676 1_655
O5 Ge2 Eu1 118.13(7) . 2_676
O6 Ge2 Eu1 27.77(8) . 2_676
O7 Ge2 Eu1 114.86(8) . 2_676
O4 Ge2 Eu1 88.03(8) 1_666 2_676
Eu1 Ge2 Eu1 69.697(8) . 2_676
K2 Ge2 Eu1 82.770(17) 2_676 2_676
K1 Ge2 Eu1 109.271(15) 1_655 2_676
O5 Ge2 K1 94.48(8) . .
O6 Ge2 K1 39.35(8) . .
O7 Ge2 K1 84.15(8) . .
O4 Ge2 K1 149.38(8) 1_666 .
Eu1 Ge2 K1 65.861(13) . .
K2 Ge2 K1 111.06(2) 2_676 .
K1 Ge2 K1 137.95(2) 1_655 .
Eu1 Ge2 K1 62.481(13) 2_676 .
Ge1 O1 U1 131.98(13) . .
Ge1 O1 K2 94.43(10) . 2_565
U1 O1 K2 121.32(10) . 2_565
Ge1 O1 K2 119.23(11) . .
U1 O1 K2 90.53(8) . .
K2 O1 K2 95.12(8) 2_565 .
Ge1 O2 Eu1 144.72(13) . 2_665
Ge1 O2 K1 93.05(10) . 2_565
Eu1 O2 K1 106.52(9) 2_665 2_565
Ge1 O2 K1 101.17(10) . 1_544
Eu1 O2 K1 103.80(9) 2_665 1_544
K1 O2 K1 100.14(8) 2_565 1_544
Ge1 O3 Eu1 136.37(13) . 2_565
Ge1 O3 K1 92.71(10) . 2_565
Eu1 O3 K1 101.98(9) 2_565 2_565
Ge1 O3 K1 118.97(11) . 1_554
Eu1 O3 K1 103.05(9) 2_565 1_554
K1 O3 K1 85.86(7) 2_565 1_554
Ge2 O4 Ge1 129.83(14) 1_444 .
Ge2 O4 K2 96.65(10) 1_444 2_565
Ge1 O4 K2 94.59(10) . 2_565
Ge2 O4 K1 92.83(10) 1_444 1_544
Ge1 O4 K1 92.32(10) . 1_544
K2 O4 K1 160.51(9) 2_565 1_544
Ge2 O4 K2 114.34(10) 1_444 1_545
Ge1 O4 K2 114.44(10) . 1_545
K2 O4 K2 89.79(7) 2_565 1_545
K1 O4 K2 70.77(6) 1_544 1_545
Ge2 O5 Eu1 139.51(12) . 2_666
Ge2 O5 Eu1 99.21(10) . .
Eu1 O5 Eu1 109.46(9) 2_666 .
Ge2 O5 K1 100.34(10) . 1_655
Eu1 O5 K1 102.33(9) 2_666 1_655
Eu1 O5 K1 99.54(8) . 1_655
Ge2 O6 Eu1 131.88(12) . 2_676
Ge2 O6 Eu1 96.05(10) . .
Eu1 O6 Eu1 109.59(9) 2_676 .
Ge2 O6 K1 117.49(11) . .
Eu1 O6 K1 100.86(8) 2_676 .
Eu1 O6 K1 94.27(8) . .
Ge2 O7 U1 131.10(13) . 1_556
Ge2 O7 K2 124.33(12) . 1_556
U1 O7 K2 91.04(8) 1_556 1_556
Ge2 O7 K2 92.23(10) . 2_676
U1 O7 K2 117.98(9) 1_556 2_676
K2 O7 K2 97.16(8) 1_556 2_676
U1 O8 Eu1 144.91(12) . .
U1 O8 K2 96.59(9) . .
Eu1 O8 K2 118.50(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
K1 O2 2.753(2) 2_565
K1 O3 2.759(3) 2_565
K1 O2 2.768(3) 1_566
K1 O3 2.780(3) 1_556
K1 O5 2.782(3) 1_455
K1 O6 2.796(3) .
K1 O4 2.962(3) 1_566
K1 Ge1 3.3232(8) 2_565
K1 K2 3.4773(12) 1_556
K1 Ge1 3.5307(9) 1_566
K1 Ge2 3.5315(9) 1_455
K1 K1 3.7727(16) 2_566
K2 O4 2.834(3) 2_565
K2 O1 2.875(3) 2_565
K2 O7 2.897(3) 1_554
K2 O1 2.943(3) .
K2 O8 2.990(2) .
K2 O7 2.993(3) 2_676
K2 O4 3.042(3) 1_565
K2 K1 3.4773(12) 1_554
K2 Ge1 3.4800(10) 2_565
K2 Ge2 3.5183(10) 2_676
K2 U1 3.6937(9) .
K2 K2 4.1497(19) 2_575
U1 O8 1.852(2) .
U1 O8 1.852(2) 2_665
U1 O1 2.205(2) 2_665
U1 O1 2.205(2) .
U1 O7 2.240(2) 2_666
U1 O7 2.240(2) 1_554
U1 K2 3.6937(9) 2_665
U1 Eu1 4.2216(3) .
U1 Eu1 4.2216(3) 2_665
U1 K2 4.4404(10) 1_655
U1 K2 4.4404(10) 2_565
Eu1 O2 2.245(2) 2_665
Eu1 O3 2.281(2) 2_565
Eu1 O5 2.304(2) 2_666
Eu1 O6 2.324(2) 2_676
Eu1 O5 2.473(2) .
Eu1 O6 2.558(2) .
Eu1 O8 2.570(2) .
Eu1 Ge2 3.2381(4) .
Eu1 Ge2 3.7133(4) 2_676
Eu1 Eu1 3.9014(3) 2_666
Eu1 K1 3.9582(8) 2_676
Ge1 O2 1.720(2) .
Ge1 O3 1.726(2) .
Ge1 O1 1.752(2) .
Ge1 O4 1.806(2) .
Ge1 K1 3.3232(8) 2_565
Ge1 K2 3.4800(10) 2_565
Ge1 K1 3.5307(9) 1_544
Ge1 K1 3.9188(8) 1_554
Ge2 O5 1.732(2) .
Ge2 O6 1.734(2) .
Ge2 O7 1.736(2) .
Ge2 O4 1.783(2) 1_666
Ge2 K2 3.5183(10) 2_676
Ge2 K1 3.5315(9) 1_655
Ge2 Eu1 3.7133(4) 2_676
O1 K2 2.875(3) 2_565
O2 Eu1 2.245(2) 2_665
O2 K1 2.753(2) 2_565
O2 K1 2.768(3) 1_544
O3 Eu1 2.281(2) 2_565
O3 K1 2.759(3) 2_565
O3 K1 2.780(2) 1_554
O4 Ge2 1.783(2) 1_444
O4 K2 2.834(3) 2_565
O4 K1 2.962(3) 1_544
O4 K2 3.042(3) 1_545
O5 Eu1 2.304(2) 2_666
O5 K1 2.782(2) 1_655
O6 Eu1 2.324(2) 2_676
O7 U1 2.240(2) 1_556
O7 K2 2.897(3) 1_556
O7 K2 2.993(3) 2_676
