#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:24:02 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179448 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/45/4334508.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334508
loop_
_publ_author_name
'Vadapalli Chandrasekhar'
'Prasenjit Bag'
'Enrique Colacio'
_publ_section_title
;
 Octanuclear {Ln(III)8} (Ln = Gd, Tb, Dy, Ho) Macrocyclic Complexes in a
 Cyclooctadiene-like Conformation: Manifestation of Slow Relaxation of
 Magnetization in the Dy(III) Derivative
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4562
_journal_page_last               4570
_journal_paper_doi               10.1021/ic400091j
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'C116 H200 Dy8 N16 O48'
_chemical_formula_weight         3886.92
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           88
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-I 4ad'
_symmetry_space_group_name_H-M   'I 41/a :2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.228(3)
_cell_length_b                   18.228(3)
_cell_length_c                   44.831(9)
_cell_measurement_reflns_used    3837
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      22.10
_cell_measurement_theta_min      2.23
_cell_volume                     14896(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0907
_diffrn_reflns_av_sigmaI/netI    0.0601
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -54
_diffrn_reflns_number            40419
_diffrn_reflns_theta_full        25.49
_diffrn_reflns_theta_max         25.49
_diffrn_reflns_theta_min         1.21
_exptl_absorpt_coefficient_mu    4.041
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.735263
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.733
_exptl_crystal_description       block
_exptl_crystal_F_000             7680
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.085
_refine_diff_density_max         2.467
_refine_diff_density_min         -1.674
_refine_diff_density_rms         0.284
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           fullcycle
_refine_ls_number_parameters     445
_refine_ls_number_reflns         6918
_refine_ls_number_restraints     56
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0820
_refine_ls_R_factor_gt           0.0548
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0949P)²+95.1606P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1439
_refine_ls_wR_factor_ref         0.1685
_reflns_number_gt                5033
_reflns_number_total             6918
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic400091j_si_001_3.cif
_cod_data_source_block           Dy8
_cod_original_cell_volume        14896(4)
_cod_original_sg_symbol_H-M      'I 41/a'
_cod_database_code               4334508
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-y+3/4, x+1/4, z+1/4'
'y+3/4, -x+3/4, z+3/4'
'x+1/2, y+1/2, z+1/2'
'-x+1, -y+1/2, z+1'
'-y+5/4, x+3/4, z+3/4'
'y+5/4, -x+5/4, z+5/4'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'y-3/4, -x-1/4, -z-1/4'
'-y-3/4, x-3/4, -z-3/4'
'-x+1/2, -y+1/2, -z+1/2'
'x, y+1/2, -z'
'y-1/4, -x+1/4, -z+1/4'
'-y-1/4, x-1/4, -z-1/4'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.73167(2) 0.68261(2) 0.099618(9) 0.024 Uani 1 1 d .
Dy2 Dy 0.69020(2) 0.88901(2) 0.096128(9) 0.024 Uani 1 1 d .
O1 O 0.5962(4) 0.9502(4) 0.03270(15) 0.033 Uani 1 1 d .
H1 H 0.6198 0.9854 0.0388 0.050 Uiso 1 1 calc R
O2 O 0.6571(3) 0.7743(3) 0.07744(13) 0.025 Uani 1 1 d .
O3 O 0.6938(3) 0.5603(3) 0.10675(14) 0.027 Uani 1 1 d .
O4 O 0.7634(3) 0.7989(3) 0.11462(14) 0.027 Uani 1 1 d .
O5 O 0.7708(3) 0.8687(4) 0.05181(15) 0.028 Uani 1 1 d D
H5 H 0.7801(18) 0.8244(16) 0.056(2) 0.042 Uiso 1 1 d D
O6 O 0.6490(3) 0.6756(3) 0.13706(14) 0.024 Uani 1 1 d .
O7 O 0.8043(4) 0.7250(4) 0.05525(16) 0.037 Uani 1 1 d .
O8 O 0.8250(4) 0.6143(4) 0.07226(15) 0.033 Uani 1 1 d .
O9 O 0.8160(4) 0.6472(4) 0.13649(15) 0.035 Uani 1 1 d .
O10 O 0.6719(4) 1.0105(4) 0.07900(14) 0.031 Uani 1 1 d .
O11 O 0.9287(17) 0.4918(15) 0.0948(7) 0.227 Uani 1 1 d DU
H11 H 0.9442 0.5309 0.1013 0.341 Uiso 1 1 calc R
O12 O 0.979(3) 0.434(3) 0.0700(12) 0.446 Uani 1 1 d DU
H12 H 1.0213 0.4186 0.0716 0.669 Uiso 1 1 calc R
N1 N 0.6176(4) 0.8874(4) 0.04796(16) 0.027 Uani 1 1 d .
N2 N 0.6212(4) 0.6993(4) 0.03810(18) 0.029 Uani 1 1 d .
N3 N 0.6552(4) 0.6443(4) 0.05573(17) 0.026 Uani 1 1 d .
N4 N 0.8215(5) 0.9381(4) 0.10166(18) 0.031 Uani 1 1 d .
C1 C 0.5601(5) 0.8232(5) 0.0056(2) 0.029 Uani 1 1 d .
H1A H 0.5094 0.8355 0.0086 0.044 Uiso 1 1 calc R
H1B H 0.5636 0.7742 -0.0021 0.044 Uiso 1 1 calc R
H1C H 0.5816 0.8569 -0.0083 0.044 Uiso 1 1 calc R
C2 C 0.5997(5) 0.8276(5) 0.03460(19) 0.024 Uani 1 1 d .
C3 C 0.6257(5) 0.7623(5) 0.0508(2) 0.025 Uani 1 1 d .
C4 C 0.6509(5) 0.5795(5) 0.0436(2) 0.028 Uani 1 1 d .
H4 H 0.6252 0.5748 0.0258 0.033 Uiso 1 1 calc R
C5 C 0.6841(5) 0.5144(5) 0.0565(2) 0.028 Uani 1 1 d .
C6 C 0.6953(5) 0.4567(5) 0.0363(2) 0.028 Uani 1 1 d .
H6 H 0.6805 0.4626 0.0166 0.034 Uiso 1 1 calc R
C7 C 0.7282(5) 0.3905(5) 0.0448(2) 0.029 Uani 1 1 d .
C8 C 0.7447(7) 0.3312(6) 0.0232(2) 0.040 Uani 1 1 d .
H8A H 0.7010 0.3032 0.0195 0.060 Uiso 1 1 calc R
H8B H 0.7819 0.2997 0.0313 0.060 Uiso 1 1 calc R
H8C H 0.7618 0.3523 0.0049 0.060 Uiso 1 1 calc R
C9 C 0.7442(6) 0.3827(6) 0.0754(2) 0.032 Uani 1 1 d .
H9 H 0.7618 0.3379 0.0822 0.038 Uiso 1 1 calc R
C10 C 0.7347(6) 0.4392(5) 0.0957(2) 0.029 Uani 1 1 d .
C11 C 0.7040(5) 0.5063(5) 0.0868(2) 0.026 Uani 1 1 d .
C12 C 0.8237(6) 1.0027(6) 0.1220(2) 0.033 Uani 1 1 d .
H12A H 0.7868 1.0376 0.1156 0.040 Uiso 1 1 calc R
H12B H 0.8712 1.0262 0.1201 0.040 Uiso 1 1 calc R
C13 C 0.8704(5) 0.8787(6) 0.1120(2) 0.035 Uani 1 1 d .
H13A H 0.9088 0.8996 0.1243 0.042 Uiso 1 1 calc R
H13B H 0.8936 0.8561 0.0948 0.042 Uiso 1 1 calc R
C14 C 0.8296(5) 0.8196(5) 0.1298(2) 0.027 Uani 1 1 d .
H14A H 0.8609 0.7769 0.1322 0.033 Uiso 1 1 calc R
H14B H 0.8178 0.8382 0.1495 0.033 Uiso 1 1 calc R
C15 C 0.8432(6) 0.9665(6) 0.0716(2) 0.040 Uani 1 1 d .
H15A H 0.8934 0.9840 0.0725 0.048 Uiso 1 1 calc R
H15B H 0.8120 1.0077 0.0665 0.048 Uiso 1 1 calc R
C16 C 0.8369(6) 0.9078(6) 0.0474(2) 0.039 Uani 1 1 d D
H16A H 0.8369 0.9306 0.0278 0.047 Uiso 1 1 calc R
H16B H 0.8784 0.8745 0.0485 0.047 Uiso 1 1 calc R
C17 C 0.6171(6) 0.7416(6) 0.1495(2) 0.038 Uani 1 1 d .
H17A H 0.5696 0.7305 0.1575 0.057 Uiso 1 1 calc R
H17B H 0.6125 0.7780 0.1342 0.057 Uiso 1 1 calc R
H17C H 0.6482 0.7599 0.1651 0.057 Uiso 1 1 calc R
C18 C 0.8360(5) 0.6628(6) 0.0529(2) 0.031 Uani 1 1 d .
C19 C 0.8831(6) 0.6438(6) 0.0265(2) 0.036 Uani 1 1 d .
C20 C 0.8924(9) 0.7099(9) 0.0056(3) 0.080 Uani 1 1 d .
H20A H 0.8504 0.7137 -0.0073 0.120 Uiso 1 1 calc R
H20B H 0.9357 0.7035 -0.0063 0.120 Uiso 1 1 calc R
H20C H 0.8969 0.7540 0.0172 0.120 Uiso 1 1 calc R
C21 C 0.9615(8) 0.6294(10) 0.0381(4) 0.087 Uani 1 1 d .
H21A H 0.9757 0.6683 0.0514 0.130 Uiso 1 1 calc R
H21B H 0.9950 0.6275 0.0216 0.130 Uiso 1 1 calc R
H21C H 0.9627 0.5836 0.0486 0.130 Uiso 1 1 calc R
C22 C 0.8597(10) 0.5746(10) 0.0120(4) 0.096 Uani 1 1 d .
H22A H 0.8523 0.5376 0.0269 0.144 Uiso 1 1 calc R
H22B H 0.8969 0.5588 -0.0017 0.144 Uiso 1 1 calc R
H22C H 0.8146 0.5827 0.0014 0.144 Uiso 1 1 calc R
C23 C 0.8164(6) 0.6120(6) 0.1610(2) 0.033 Uani 1 1 d .
C24 C 0.8852(9) 0.6099(8) 0.1790(4) 0.100 Uani 1 1 d D
C26 C 0.9113(10) 0.5297(8) 0.1742(5) 0.100 Uani 1 1 d DU
H26A H 0.8787 0.4966 0.1843 0.150 Uiso 1 1 calc R
H26B H 0.9600 0.5240 0.1820 0.150 Uiso 1 1 calc R
H26C H 0.9115 0.5187 0.1532 0.150 Uiso 1 1 calc R
C27 C 0.9541(9) 0.6297(10) 0.1619(4) 0.090 Uani 1 1 d DU
H27A H 0.9608 0.5958 0.1458 0.136 Uiso 1 1 calc R
H27B H 0.9956 0.6274 0.1751 0.136 Uiso 1 1 calc R
H27C H 0.9495 0.6785 0.1541 0.136 Uiso 1 1 calc R
C28 C 0.954(3) 0.431(2) 0.1144(10) 0.328 Uani 1 1 d DU
H28A H 1.0050 0.4380 0.1192 0.492 Uiso 1 1 calc R
H28B H 0.9481 0.3851 0.1042 0.492 Uiso 1 1 calc R
H28C H 0.9257 0.4306 0.1324 0.492 Uiso 1 1 calc R
C29 C 0.9431(13) 0.3971(13) 0.0454(6) 0.140 Uani 1 1 d DU
H29A H 0.8918 0.4093 0.0454 0.211 Uiso 1 1 calc R
H29B H 0.9487 0.3450 0.0475 0.211 Uiso 1 1 calc R
H29C H 0.9646 0.4125 0.0269 0.211 Uiso 1 1 calc R
C25A C 0.8783(14) 0.5973(14) 0.2121(4) 0.096 Uani 0.69 1 d PDU
H25A H 0.8679 0.6430 0.2219 0.143 Uiso 0.69 1 calc PR
H25B H 0.9234 0.5775 0.2197 0.143 Uiso 0.69 1 calc PR
H25C H 0.8391 0.5633 0.2159 0.143 Uiso 0.69 1 calc PR
C25B C 0.8840(18) 0.6872(12) 0.1938(7) 0.035 Uani 0.31 1 d PDU
H25D H 0.8739 0.7237 0.1788 0.052 Uiso 0.31 1 calc PR
H25E H 0.9308 0.6970 0.2028 0.052 Uiso 0.31 1 calc PR
H25F H 0.8465 0.6887 0.2088 0.052 Uiso 0.31 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 Dy1 O4 90.1(2) . .
O6 Dy1 O9 84.1(2) . .
O4 Dy1 O9 83.3(2) . .
O6 Dy1 O3 69.5(2) . .
O4 Dy1 O3 155.1(2) . .
O9 Dy1 O3 80.6(2) . .
O6 Dy1 O2 88.2(2) . .
O4 Dy1 O2 67.5(2) . .
O9 Dy1 O2 149.7(2) . .
O3 Dy1 O2 123.7(2) . .
O6 Dy1 O8 144.1(2) . .
O4 Dy1 O8 116.3(2) . .
O9 Dy1 O8 75.9(2) . .
O3 Dy1 O8 77.9(2) . .
O2 Dy1 O8 123.3(2) . .
O6 Dy1 N3 101.3(2) . .
O4 Dy1 N3 128.7(2) . .
O9 Dy1 N3 147.0(3) . .
O3 Dy1 N3 71.4(2) . .
O2 Dy1 N3 63.2(2) . .
O8 Dy1 N3 81.5(2) . .
O6 Dy1 O7 163.2(2) . .
O4 Dy1 O7 79.4(2) . .
O9 Dy1 O7 107.3(2) . .
O3 Dy1 O7 123.6(2) . .
O2 Dy1 O7 75.7(2) . .
O8 Dy1 O7 52.5(2) . .
N3 Dy1 O7 76.0(2) . .
O6 Dy1 C18 169.5(3) . .
O4 Dy1 C18 99.4(3) . .
O9 Dy1 C18 92.6(3) . .
O3 Dy1 C18 100.1(3) . .
O2 Dy1 C18 99.4(3) . .
O8 Dy1 C18 26.0(3) . .
N3 Dy1 C18 76.1(2) . .
O7 Dy1 C18 26.6(3) . .
O6 Dy1 Dy2 34.47(15) . 15_565
O4 Dy1 Dy2 118.62(16) . 15_565
O9 Dy1 Dy2 70.79(17) . 15_565
O3 Dy1 Dy2 37.53(15) . 15_565
O2 Dy1 Dy2 116.02(15) . 15_565
O8 Dy1 Dy2 109.81(16) . 15_565
N3 Dy1 Dy2 95.34(17) . 15_565
O7 Dy1 Dy2 160.80(16) . 15_565
C18 Dy1 Dy2 135.1(2) . 15_565
O6 Dy1 Dy2 87.39(15) . .
O4 Dy1 Dy2 32.63(16) . .
O9 Dy1 Dy2 115.26(18) . .
O3 Dy1 Dy2 151.03(15) . .
O2 Dy1 Dy2 34.94(15) . .
O8 Dy1 Dy2 128.09(16) . .
N3 Dy1 Dy2 97.54(18) . .
O7 Dy1 Dy2 76.71(16) . .
C18 Dy1 Dy2 103.0(2) . .
Dy2 Dy1 Dy2 121.864(16) 15_565 .
O6 Dy2 O4 119.2(2) 12_766 .
O6 Dy2 O2 87.2(2) 12_766 .
O4 Dy2 O2 68.6(2) . .
O6 Dy2 O3 70.0(2) 12_766 12_766
O4 Dy2 O3 88.9(2) . 12_766
O2 Dy2 O3 135.0(2) . 12_766
O6 Dy2 O10 84.3(2) 12_766 .
O4 Dy2 O10 151.3(2) . .
O2 Dy2 O10 133.3(2) . .
O3 Dy2 O10 83.9(2) 12_766 .
O6 Dy2 O5 146.1(2) 12_766 .
O4 Dy2 O5 80.7(2) . .
O2 Dy2 O5 74.5(2) . .
O3 Dy2 O5 141.7(2) 12_766 .
O10 Dy2 O5 87.9(2) . .
O6 Dy2 N1 78.2(2) 12_766 .
O4 Dy2 N1 127.6(2) . .
O2 Dy2 N1 63.2(2) . .
O3 Dy2 N1 140.7(2) 12_766 .
O10 Dy2 N1 70.1(2) . .
O5 Dy2 N1 68.1(2) . .
O6 Dy2 N4 144.5(2) 12_766 .
O4 Dy2 N4 70.7(2) . .
O2 Dy2 N4 126.0(2) . .
O3 Dy2 N4 76.5(2) 12_766 .
O10 Dy2 N4 80.6(3) . .
O5 Dy2 N4 65.2(2) . .
N1 Dy2 N4 125.0(2) . .
O6 Dy2 Dy1 34.65(15) 12_766 12_766
O4 Dy2 Dy1 116.35(16) . 12_766
O2 Dy2 Dy1 119.16(15) . 12_766
O3 Dy2 Dy1 37.90(16) 12_766 12_766
O10 Dy2 Dy1 72.65(16) . 12_766
O5 Dy2 Dy1 160.56(15) . 12_766
N1 Dy2 Dy1 104.39(18) . 12_766
N4 Dy2 Dy1 109.91(18) . 12_766
O6 Dy2 Dy1 104.52(16) 12_766 .
O4 Dy2 Dy1 33.04(16) . .
O2 Dy2 Dy1 35.62(15) . .
O3 Dy2 Dy1 112.48(16) 12_766 .
O10 Dy2 Dy1 163.19(16) . .
O5 Dy2 Dy1 76.79(15) . .
N1 Dy2 Dy1 97.27(18) . .
N4 Dy2 Dy1 98.85(19) . .
Dy1 Dy2 Dy1 122.528(16) 12_766 .
C3 O2 Dy2 125.2(5) . .
C3 O2 Dy1 120.2(6) . .
Dy2 O2 Dy1 109.4(2) . .
C11 O3 Dy2 131.2(6) . 15_565
C11 O3 Dy1 124.3(6) . .
Dy2 O3 Dy1 104.6(2) 15_565 .
C14 O4 Dy2 118.5(5) . .
C14 O4 Dy1 126.3(5) . .
Dy2 O4 Dy1 114.3(3) . .
C16 O5 Dy2 122.6(6) . .
C17 O6 Dy2 128.1(6) . 15_565
C17 O6 Dy1 120.5(6) . .
Dy2 O6 Dy1 110.9(2) 15_565 .
C18 O7 Dy1 91.8(6) . .
C18 O8 Dy1 95.7(6) . .
C23 O9 Dy1 138.5(6) . .
C23 O10 Dy2 134.6(6) 12_766 .
C2 N1 O1 113.5(7) . .
C2 N1 Dy2 122.6(6) . .
O1 N1 Dy2 123.9(5) . .
C3 N2 N3 110.9(8) . .
C4 N3 N2 112.4(8) . .
C4 N3 Dy1 127.8(6) . .
N2 N3 Dy1 118.8(5) . .
C13 N4 C12 111.8(8) . .
C13 N4 C15 112.1(8) . .
C12 N4 C15 105.7(8) . .
C13 N4 Dy2 109.8(6) . .
C12 N4 Dy2 111.1(6) . .
C15 N4 Dy2 106.2(6) . .
N1 C2 C3 111.9(8) . .
N1 C2 C1 125.1(8) . .
C3 C2 C1 122.9(8) . .
N2 C3 O2 124.6(9) . .
N2 C3 C2 118.8(8) . .
O2 C3 C2 116.4(8) . .
N3 C4 C5 123.3(9) . .
C6 C5 C11 120.3(9) . .
C6 C5 C4 114.7(9) . .
C11 C5 C4 125.0(9) . .
C7 C6 C5 122.1(9) . .
C6 C7 C9 116.2(9) . .
C6 C7 C8 122.4(9) . .
C9 C7 C8 121.4(9) . .
C10 C9 C7 122.7(9) . .
C9 C10 C11 120.7(9) . .
C9 C10 C12 119.4(9) . 15_565
C11 C10 C12 119.7(8) . 15_565
O3 C11 C10 120.4(8) . .
O3 C11 C5 121.8(9) . .
C10 C11 C5 117.7(8) . .
N4 C12 C10 114.4(8) . 12_766
N4 C13 C14 112.7(8) . .
O4 C14 C13 110.1(8) . .
N4 C15 C16 112.2(9) . .
O5 C16 C15 108.4(8) . .
O8 C18 O7 119.8(9) . .
O8 C18 C19 118.2(9) . .
O7 C18 C19 121.9(10) . .
O8 C18 Dy1 58.4(5) . .
O7 C18 Dy1 61.7(5) . .
C19 C18 Dy1 171.3(7) . .
C22 C19 C18 112.2(10) . .
C22 C19 C20 115.5(12) . .
C18 C19 C20 111.3(10) . .
C22 C19 C21 105.7(13) . .
C18 C19 C21 107.5(10) . .
C20 C19 C21 103.7(11) . .
O9 C23 O10 123.1(9) . 15_565
O9 C23 C24 119.0(10) . .
O10 C23 C24 117.9(10) 15_565 .
C23 C24 C25A 117.9(15) . .
C23 C24 C27 114.6(14) . .
C25A C24 C27 127.1(18) . .
C23 C24 C26 101.9(13) . .
C25A C24 C26 91.2(15) . .
C27 C24 C26 84.2(12) . .
C23 C24 C25B 101.3(16) . .
C25A C24 C25B 73.7(17) . .
C27 C24 C25B 90.6(16) . .
C26 C24 C25B 156(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O6 2.259(6) .
Dy1 O4 2.298(6) .
Dy1 O9 2.348(7) .
Dy1 O3 2.356(6) .
Dy1 O2 2.372(6) .
Dy1 O8 2.439(7) .
Dy1 N3 2.511(8) .
Dy1 O7 2.511(7) .
Dy1 C18 2.851(10) .
Dy1 Dy2 3.7123(8) 15_565
Dy1 Dy2 3.8407(8) .
Dy2 O6 2.249(6) 12_766
Dy2 O4 2.273(6) .
Dy2 O2 2.333(6) .
Dy2 O3 2.336(6) 12_766
Dy2 O10 2.367(7) .
Dy2 O5 2.498(7) .
Dy2 N1 2.533(8) .
Dy2 N4 2.567(8) .
Dy2 Dy1 3.7121(8) 12_766
O1 N1 1.388(10) .
O2 C3 1.341(11) .
O3 C11 1.342(11) .
O3 Dy2 2.336(6) 15_565
O4 C14 1.437(11) .
O5 C16 1.414(11) .
O6 C17 1.448(12) .
O6 Dy2 2.249(6) 15_565
O7 C18 1.276(12) .
O8 C18 1.255(12) .
O9 C23 1.271(12) .
O10 C23 1.273(12) 12_766
O11 C28 1.487(10) .
O12 C29 1.451(10) .
N1 C2 1.287(11) .
N2 C3 1.285(12) .
N2 N3 1.419(11) .
N3 C4 1.303(12) .
N4 C13 1.476(13) .
N4 C12 1.490(12) .
N4 C15 1.495(13) .
C1 C2 1.488(12) .
C2 C3 1.474(13) .
C4 C5 1.453(13) .
C5 C6 1.402(13) .
C5 C11 1.417(13) .
C6 C7 1.401(13) .
C7 C9 1.406(14) .
C7 C8 1.483(13) .
C9 C10 1.386(13) .
C10 C11 1.403(13) .
C10 C12 1.502(13) 15_565
C12 C10 1.502(13) 12_766
C13 C14 1.536(14) .
C15 C16 1.531(14) .
C18 C19 1.504(14) .
C19 C22 1.481(18) .
C19 C20 1.538(17) .
C19 C21 1.545(17) .
C23 O10 1.273(12) 15_565
C23 C24 1.49(2) .
C24 C25A 1.506(10) .
C24 C27 1.516(9) .
C24 C26 1.554(9) .
C24 C25B 1.557(10) .
