#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:29:25 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179450 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/47/4334776.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334776
loop_
_publ_author_name
'Kazuhiro Uemura'
'Masahiro Ebihara'
_publ_section_title
;
 Paramagnetic One-Dimensional Chains Comprised of Trinuclear Pt-Cu-Pt and
 Paddlewheel Dirhodium Complexes with Metal-Metal Bonds
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5535
_journal_page_last               5550
_journal_paper_doi               10.1021/ic400470g
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'C46 H100 Cu F12 N8 O18 P2 Pt2 Rh2'
_chemical_formula_weight         2002.82
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.288(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.251(3)
_cell_length_b                   20.825(4)
_cell_length_c                   14.476(3)
_cell_measurement_reflns_used    11895
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      30.8980
_cell_measurement_theta_min      1.5097
_cell_volume                     3722.1(13)
_computing_cell_refinement       CRYSTALCLEAR
_computing_data_collection       CRYSTALCLEAR
_computing_data_reduction        CRYSTALCLEAR
_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_detector_area_resol_mean 14.6199
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0298
_diffrn_reflns_av_sigmaI/netI    0.0375
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            29529
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         3.03
_exptl_absorpt_coefficient_mu    4.596
_exptl_absorpt_correction_T_max  0.5655
_exptl_absorpt_correction_T_min  0.1659
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.787
_exptl_crystal_description       plate
_exptl_crystal_F_000             1978
_exptl_crystal_size_max          0.61
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.542
_refine_diff_density_min         -2.013
_refine_diff_density_rms         0.137
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.117
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     428
_refine_ls_number_reflns         8500
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.117
_refine_ls_R_factor_all          0.0395
_refine_ls_R_factor_gt           0.0337
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0346P)²+5.3495P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0785
_refine_ls_wR_factor_ref         0.0831
_reflns_number_gt                7593
_reflns_number_total             8500
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic400470g_si_002_5.cif
_cod_data_source_block           6
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4334776
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.198493(9) 0.010489(7) -0.002741(10) 0.01243(6) Uani 1 1 d .
Rh1 Rh 0.40864(2) -0.000139(14) -0.00311(2) 0.01338(7) Uani 1 1 d .
Cu1 Cu 0.0000 0.0000 0.0000 0.01114(13) Uani 1 2 d S
P1 P 0.74230(8) 0.24417(5) 0.46088(8) 0.0225(2) Uani 1 1 d .
O6 O 0.45108(19) -0.06878(13) 0.1049(2) 0.0190(6) Uani 1 1 d .
N2 N 0.1535(2) 0.06764(16) -0.1271(2) 0.0160(6) Uani 1 1 d .
H24 H 0.1593 0.0449 -0.1787 0.024 Uiso 1 1 calc R
H25 H 0.1976 0.1026 -0.1151 0.024 Uiso 1 1 calc R
H26 H 0.0837 0.0806 -0.1426 0.024 Uiso 1 1 calc R
N3 N 0.1540(2) -0.06728(15) -0.0896(2) 0.0155(6) Uani 1 1 d .
H10 H 0.1972 -0.0805 -0.1196 0.019 Uiso 1 1 calc R
N4 N 0.2347(2) -0.04564(16) 0.1180(2) 0.0155(6) Uani 1 1 d .
H20 H 0.3012 -0.0606 0.1442 0.019 Uiso 1 1 calc R
N1 N 0.2371(2) 0.08928(15) 0.0890(2) 0.0164(6) Uani 1 1 d .
H21 H 0.2811 0.0771 0.1509 0.025 Uiso 1 1 calc R
H22 H 0.1754 0.1069 0.0918 0.025 Uiso 1 1 calc R
H23 H 0.2719 0.1188 0.0649 0.025 Uiso 1 1 calc R
O3 O 0.4533(2) 0.06944(14) 0.1014(2) 0.0209(6) Uani 1 1 d .
O4 O 0.37593(19) 0.06710(14) -0.1121(2) 0.0203(6) Uani 1 1 d .
O5 O 0.37415(19) -0.07096(14) -0.1076(2) 0.0207(6) Uani 1 1 d .
F1 F 0.8516(2) 0.21418(16) 0.5352(2) 0.0467(8) Uani 1 1 d .
F2 F 0.8027(2) 0.31212(13) 0.4678(2) 0.0407(7) Uani 1 1 d .
F5 F 0.7770(2) 0.22496(14) 0.3700(2) 0.0417(7) Uani 1 1 d .
C1 C 0.0653(3) -0.09953(18) -0.1045(3) 0.0152(7) Uani 1 1 d .
C6 C 0.1665(3) -0.06137(18) 0.1599(3) 0.0165(7) Uani 1 1 d .
C13 C 0.5484(3) -0.08809(19) 0.1380(3) 0.0182(8) Uani 1 1 d .
F4 F 0.6821(2) 0.17698(14) 0.4542(2) 0.0436(7) Uani 1 1 d .
F6 F 0.7096(2) 0.26410(14) 0.5528(2) 0.0453(7) Uani 1 1 d .
C11 C 0.5498(3) 0.09063(19) 0.1345(3) 0.0195(8) Uani 1 1 d .
C7 C 0.2005(3) -0.1039(2) 0.2523(3) 0.0210(8) Uani 1 1 d .
C14 C 0.5782(3) -0.1401(2) 0.2150(3) 0.0281(9) Uani 1 1 d .
H30 H 0.6195 -0.1735 0.1966 0.042 Uiso 1 1 calc R
H31 H 0.5122 -0.1588 0.2191 0.042 Uiso 1 1 calc R
H32 H 0.6224 -0.1219 0.2794 0.042 Uiso 1 1 calc R
C2 C 0.0411(3) -0.1620(2) -0.1638(3) 0.0278(10) Uani 1 1 d .
C12 C 0.5737(3) 0.1424(2) 0.2107(3) 0.0310(10) Uani 1 1 d .
H27 H 0.5256 0.1790 0.1836 0.047 Uiso 1 1 calc R
H28 H 0.6492 0.1562 0.2290 0.047 Uiso 1 1 calc R
H29 H 0.5621 0.1261 0.2696 0.047 Uiso 1 1 calc R
C3 C 0.1259(3) -0.1771(2) -0.2100(4) 0.0299(10) Uani 1 1 d .
H1 H 0.1965 -0.1842 -0.1573 0.045 Uiso 1 1 calc R
H2 H 0.1311 -0.1409 -0.2514 0.045 Uiso 1 1 calc R
H3 H 0.1044 -0.2158 -0.2510 0.045 Uiso 1 1 calc R
C10 C 0.1835(4) -0.0660(2) 0.3355(3) 0.0395(12) Uani 1 1 d .
H17 H 0.2293 -0.0275 0.3499 0.059 Uiso 1 1 calc R
H18 H 0.2030 -0.0928 0.3951 0.059 Uiso 1 1 calc R
H19 H 0.1073 -0.0532 0.3151 0.059 Uiso 1 1 calc R
C9 C 0.1284(4) -0.1638(2) 0.2269(4) 0.0396(12) Uani 1 1 d .
H14 H 0.0530 -0.1513 0.2128 0.059 Uiso 1 1 calc R
H15 H 0.1519 -0.1936 0.2832 0.059 Uiso 1 1 calc R
H16 H 0.1343 -0.1849 0.1685 0.059 Uiso 1 1 calc R
C8 C 0.3187(3) -0.1252(3) 0.2856(4) 0.0459(15) Uani 1 1 d .
H11 H 0.3296 -0.1503 0.2327 0.069 Uiso 1 1 calc R
H12 H 0.3367 -0.1516 0.3454 0.069 Uiso 1 1 calc R
H13 H 0.3657 -0.0873 0.2999 0.069 Uiso 1 1 calc R
C5 C 0.0404(5) -0.2161(2) -0.0926(5) 0.0599(18) Uani 1 1 d .
H7 H 0.1130 -0.2209 -0.0421 0.090 Uiso 1 1 calc R
H8 H 0.0188 -0.2563 -0.1297 0.090 Uiso 1 1 calc R
H9 H -0.0112 -0.2058 -0.0605 0.090 Uiso 1 1 calc R
C4 C -0.0689(4) -0.1549(4) -0.2466(4) 0.067(2) Uani 1 1 d .
H4 H -0.0887 -0.1955 -0.2831 0.101 Uiso 1 1 calc R
H5 H -0.0655 -0.1208 -0.2919 0.101 Uiso 1 1 calc R
H6 H -0.1235 -0.1440 -0.2182 0.101 Uiso 1 1 calc R
O1 O -0.00564(19) -0.08207(13) -0.0685(2) 0.0195(6) Uani 1 1 d .
O2 O 0.06758(19) -0.04293(14) 0.12733(19) 0.0191(6) Uani 1 1 d .
F3 F 0.6334(2) 0.27539(18) 0.3872(3) 0.0598(10) Uani 1 1 d .
O7 O 0.3626(3) 0.06407(18) 0.3087(3) 0.0453(9) Uani 1 1 d .
O8 O 0.8884(4) 0.00358(19) 0.3148(3) 0.0517(10) Uani 1 1 d .
O9 O 0.7866(3) -0.1608(2) 0.4680(3) 0.0594(11) Uani 1 1 d .
C18 C 0.8578(4) 0.0275(2) 0.3767(4) 0.0401(12) Uani 1 1 d .
C21 C 0.8500(4) -0.1932(3) 0.4448(4) 0.0385(12) Uani 1 1 d .
C22 C 0.8792(4) -0.1770(3) 0.3572(4) 0.0412(12) Uani 1 1 d .
H45 H 0.8426 -0.2068 0.3029 0.062 Uiso 1 1 calc R
H46 H 0.9578 -0.1806 0.3753 0.062 Uiso 1 1 calc R
H47 H 0.8564 -0.1329 0.3358 0.062 Uiso 1 1 calc R
C23 C 0.9029(4) -0.2514(3) 0.5026(4) 0.0452(13) Uani 1 1 d .
H48 H 0.9804 -0.2432 0.5366 0.068 Uiso 1 1 calc R
H49 H 0.8927 -0.2879 0.4575 0.068 Uiso 1 1 calc R
H50 H 0.8700 -0.2611 0.5517 0.068 Uiso 1 1 calc R
C15 C 0.3845(3) 0.1044(2) 0.3729(4) 0.0341(11) Uani 1 1 d .
C19 C 0.9288(4) 0.0720(3) 0.4534(4) 0.0405(12) Uani 1 1 d .
H39 H 1.0005 0.0736 0.4484 0.061 Uiso 1 1 calc R
H40 H 0.9357 0.0565 0.5194 0.061 Uiso 1 1 calc R
H41 H 0.8968 0.1150 0.4430 0.061 Uiso 1 1 calc R
C16 C 0.3746(4) 0.1746(3) 0.3502(4) 0.0449(13) Uani 1 1 d .
H33 H 0.3446 0.1809 0.2782 0.067 Uiso 1 1 calc R
H34 H 0.4463 0.1947 0.3776 0.067 Uiso 1 1 calc R
H35 H 0.3265 0.1944 0.3798 0.067 Uiso 1 1 calc R
C20 C 0.7492(5) 0.0126(3) 0.3797(5) 0.0593(17) Uani 1 1 d .
H42 H 0.7012 -0.0025 0.3143 0.089 Uiso 1 1 calc R
H43 H 0.7185 0.0513 0.3976 0.089 Uiso 1 1 calc R
H44 H 0.7562 -0.0210 0.4291 0.089 Uiso 1 1 calc R
C17 C 0.4239(5) 0.0864(4) 0.4803(4) 0.0629(18) Uani 1 1 d .
H36 H 0.4216 0.0396 0.4865 0.094 Uiso 1 1 calc R
H37 H 0.3774 0.1064 0.5115 0.094 Uiso 1 1 calc R
H38 H 0.4985 0.1015 0.5131 0.094 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Pt1 N4 89.90(13) . .
N3 Pt1 N1 176.78(11) . .
N4 Pt1 N1 88.72(13) . .
N3 Pt1 N2 89.59(13) . .
N4 Pt1 N2 177.17(10) . .
N1 Pt1 N2 91.64(13) . .
N3 Pt1 Cu1 82.82(8) . .
N4 Pt1 Cu1 82.21(8) . .
N1 Pt1 Cu1 94.11(8) . .
N2 Pt1 Cu1 94.97(8) . .
N3 Pt1 Rh1 90.09(8) . .
N4 Pt1 Rh1 91.83(8) . .
N1 Pt1 Rh1 92.87(8) . .
N2 Pt1 Rh1 90.96(8) . .
Cu1 Pt1 Rh1 170.711(9) . .
O3 Rh1 O4 90.52(12) . .
O3 Rh1 O6 90.25(12) . .
O4 Rh1 O6 176.12(10) . .
O3 Rh1 O5 176.16(9) . .
O4 Rh1 O5 89.73(12) . .
O6 Rh1 O5 89.24(12) . .
O3 Rh1 Rh1 87.28(7) . 3_655
O4 Rh1 Rh1 87.43(7) . 3_655
O6 Rh1 Rh1 88.81(7) . 3_655
O5 Rh1 Rh1 88.91(7) . 3_655
O3 Rh1 Pt1 87.89(7) . .
O4 Rh1 Pt1 90.87(7) . .
O6 Rh1 Pt1 92.96(7) . .
O5 Rh1 Pt1 95.93(7) . .
Rh1 Rh1 Pt1 174.86(2) 3_655 .
O2 Cu1 O2 180.00(18) 3 .
O2 Cu1 O1 90.10(12) 3 .
O2 Cu1 O1 89.90(12) . .
O2 Cu1 O1 89.90(12) 3 3
O2 Cu1 O1 90.10(12) . 3
O1 Cu1 O1 180.00(8) . 3
O2 Cu1 Pt1 86.23(7) 3 3
O2 Cu1 Pt1 93.77(7) . 3
O1 Cu1 Pt1 94.57(7) . 3
O1 Cu1 Pt1 85.44(7) 3 3
O2 Cu1 Pt1 93.77(7) 3 .
O2 Cu1 Pt1 86.23(7) . .
O1 Cu1 Pt1 85.43(7) . .
O1 Cu1 Pt1 94.56(7) 3 .
Pt1 Cu1 Pt1 180.0 3 .
F1 P1 F3 179.0(2) . .
F1 P1 F5 89.71(16) . .
F3 P1 F5 90.70(18) . .
F1 P1 F4 90.53(17) . .
F3 P1 F4 90.35(18) . .
F5 P1 F4 91.01(16) . .
F1 P1 F6 89.71(17) . .
F3 P1 F6 89.86(18) . .
F5 P1 F6 178.98(17) . .
F4 P1 F6 89.84(16) . .
F1 P1 F2 89.59(17) . .
F3 P1 F2 89.53(18) . .
F5 P1 F2 89.21(15) . .
F4 P1 F2 179.76(17) . .
F6 P1 F2 89.95(16) . .
C13 O6 Rh1 118.1(2) . .
Pt1 N2 H24 109.5 . .
Pt1 N2 H25 109.5 . .
H24 N2 H25 109.5 . .
Pt1 N2 H26 109.5 . .
H24 N2 H26 109.5 . .
H25 N2 H26 109.5 . .
C1 N3 Pt1 124.3(2) . .
C1 N3 H10 117.8 . .
Pt1 N3 H10 117.8 . .
C6 N4 Pt1 124.4(2) . .
C6 N4 H20 117.8 . .
Pt1 N4 H20 117.8 . .
Pt1 N1 H21 109.5 . .
Pt1 N1 H22 109.5 . .
H21 N1 H22 109.5 . .
Pt1 N1 H23 109.5 . .
H21 N1 H23 109.5 . .
H22 N1 H23 109.5 . .
C11 O3 Rh1 120.8(2) . .
C13 O4 Rh1 119.8(2) 3_655 .
C11 O5 Rh1 118.0(2) 3_655 .
O1 C1 N3 122.5(3) . .
O1 C1 C2 115.8(3) . .
N3 C1 C2 121.7(3) . .
O2 C6 N4 123.0(3) . .
O2 C6 C7 115.6(3) . .
N4 C6 C7 121.4(3) . .
O6 C13 O4 125.7(4) . 3_655
O6 C13 C14 117.8(3) . .
O4 C13 C14 116.4(3) 3_655 .
O3 C11 O5 124.9(4) . 3_655
O3 C11 C12 116.4(3) . .
O5 C11 C12 118.6(3) 3_655 .
C10 C7 C8 109.3(4) . .
C10 C7 C6 108.1(3) . .
C8 C7 C6 112.7(3) . .
C10 C7 C9 110.7(4) . .
C8 C7 C9 108.5(4) . .
C6 C7 C9 107.6(3) . .
C13 C14 H30 109.5 . .
C13 C14 H31 109.5 . .
H30 C14 H31 109.5 . .
C13 C14 H32 109.5 . .
H30 C14 H32 109.5 . .
H31 C14 H32 109.5 . .
C4 C2 C1 107.9(4) . .
C4 C2 C5 111.3(5) . .
C1 C2 C5 107.5(4) . .
C4 C2 C3 108.6(4) . .
C1 C2 C3 112.4(3) . .
C5 C2 C3 109.1(4) . .
C11 C12 H27 109.5 . .
C11 C12 H28 109.5 . .
H27 C12 H28 109.5 . .
C11 C12 H29 109.5 . .
H27 C12 H29 109.5 . .
H28 C12 H29 109.5 . .
C2 C3 H1 109.5 . .
C2 C3 H2 109.5 . .
H1 C3 H2 109.5 . .
C2 C3 H3 109.5 . .
H1 C3 H3 109.5 . .
H2 C3 H3 109.5 . .
C7 C10 H17 109.5 . .
C7 C10 H18 109.5 . .
H17 C10 H18 109.5 . .
C7 C10 H19 109.5 . .
H17 C10 H19 109.5 . .
H18 C10 H19 109.5 . .
C7 C9 H14 109.5 . .
C7 C9 H15 109.5 . .
H14 C9 H15 109.5 . .
C7 C9 H16 109.5 . .
H14 C9 H16 109.5 . .
H15 C9 H16 109.5 . .
C7 C8 H11 109.5 . .
C7 C8 H12 109.5 . .
H11 C8 H12 109.5 . .
C7 C8 H13 109.5 . .
H11 C8 H13 109.5 . .
H12 C8 H13 109.5 . .
C2 C5 H7 109.5 . .
C2 C5 H8 109.5 . .
H7 C5 H8 109.5 . .
C2 C5 H9 109.5 . .
H7 C5 H9 109.5 . .
H8 C5 H9 109.5 . .
C2 C4 H4 109.5 . .
C2 C4 H5 109.5 . .
H4 C4 H5 109.5 . .
C2 C4 H6 109.5 . .
H4 C4 H6 109.5 . .
H5 C4 H6 109.5 . .
C1 O1 Cu1 123.6(2) . .
C6 O2 Cu1 122.9(2) . .
O8 C18 C20 121.3(5) . .
O8 C18 C19 121.1(5) . .
C20 C18 C19 117.6(5) . .
O9 C21 C22 121.9(5) . .
O9 C21 C23 121.7(5) . .
C22 C21 C23 116.5(4) . .
C21 C22 H45 109.5 . .
C21 C22 H46 109.5 . .
H45 C22 H46 109.5 . .
C21 C22 H47 109.5 . .
H45 C22 H47 109.5 . .
H46 C22 H47 109.5 . .
C21 C23 H48 109.5 . .
C21 C23 H49 109.5 . .
H48 C23 H49 109.5 . .
C21 C23 H50 109.5 . .
H48 C23 H50 109.5 . .
H49 C23 H50 109.5 . .
O7 C15 C16 122.3(5) . .
O7 C15 C17 121.5(5) . .
C16 C15 C17 116.2(5) . .
C18 C19 H39 109.5 . .
C18 C19 H40 109.5 . .
H39 C19 H40 109.5 . .
C18 C19 H41 109.5 . .
H39 C19 H41 109.5 . .
H40 C19 H41 109.5 . .
C15 C16 H33 109.5 . .
C15 C16 H34 109.5 . .
H33 C16 H34 109.5 . .
C15 C16 H35 109.5 . .
H33 C16 H35 109.5 . .
H34 C16 H35 109.5 . .
C18 C20 H42 109.5 . .
C18 C20 H43 109.5 . .
H42 C20 H43 109.5 . .
C18 C20 H44 109.5 . .
H42 C20 H44 109.5 . .
H43 C20 H44 109.5 . .
C15 C17 H36 109.5 . .
C15 C17 H37 109.5 . .
H36 C17 H37 109.5 . .
C15 C17 H38 109.5 . .
H36 C17 H38 109.5 . .
H37 C17 H38 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 N3 2.003(3) .
Pt1 N4 2.010(3) .
Pt1 N1 2.055(3) .
Pt1 N2 2.057(3) .
Pt1 Cu1 2.6540(5) .
Pt1 Rh1 2.7954(6) .
Rh1 O3 2.022(3) .
Rh1 O4 2.035(3) .
Rh1 O6 2.041(3) .
Rh1 O5 2.042(3) .
Rh1 Rh1 2.3901(7) 3_655
Cu1 O2 1.949(3) 3
Cu1 O2 1.949(3) .
Cu1 O1 1.963(3) .
Cu1 O1 1.964(3) 3
Cu1 Pt1 2.6539(5) 3
P1 F1 1.585(3) .
P1 F3 1.589(3) .
P1 F5 1.594(3) .
P1 F4 1.596(3) .
P1 F6 1.597(3) .
P1 F2 1.611(3) .
O6 C13 1.268(4) .
N2 H24 0.9100 .
N2 H25 0.9100 .
N2 H26 0.9100 .
N3 C1 1.301(4) .
N3 H10 0.8800 .
N4 C6 1.301(4) .
N4 H20 0.8800 .
N1 H21 0.9100 .
N1 H22 0.9100 .
N1 H23 0.9100 .
O3 C11 1.270(4) .
O4 C13 1.268(4) 3_655
O5 C11 1.274(4) 3_655
C1 O1 1.282(4) .
C1 C2 1.527(5) .
C6 O2 1.280(4) .
C6 C7 1.529(5) .
C13 O4 1.268(4) 3_655
C13 C14 1.500(5) .
C11 O5 1.274(4) 3_655
C11 C12 1.493(6) .
C7 C10 1.524(6) .
C7 C8 1.529(5) .
C7 C9 1.533(6) .
C14 H30 0.9800 .
C14 H31 0.9800 .
C14 H32 0.9800 .
C2 C4 1.522(7) .
C2 C5 1.529(7) .
C2 C3 1.536(5) .
C12 H27 0.9800 .
C12 H28 0.9800 .
C12 H29 0.9800 .
C3 H1 0.9800 .
C3 H2 0.9800 .
C3 H3 0.9800 .
C10 H17 0.9800 .
C10 H18 0.9800 .
C10 H19 0.9800 .
C9 H14 0.9800 .
C9 H15 0.9800 .
C9 H16 0.9800 .
C8 H11 0.9800 .
C8 H12 0.9800 .
C8 H13 0.9800 .
C5 H7 0.9800 .
C5 H8 0.9800 .
C5 H9 0.9800 .
C4 H4 0.9800 .
C4 H5 0.9800 .
C4 H6 0.9800 .
O7 C15 1.207(6) .
O8 C18 1.215(6) .
O9 C21 1.215(6) .
C18 C20 1.489(8) .
C18 C19 1.489(7) .
C21 C22 1.493(7) .
C21 C23 1.495(7) .
C22 H45 0.9800 .
C22 H46 0.9800 .
C22 H47 0.9800 .
C23 H48 0.9800 .
C23 H49 0.9800 .
C23 H50 0.9800 .
C15 C16 1.495(7) .
C15 C17 1.497(7) .
C19 H39 0.9800 .
C19 H40 0.9800 .
C19 H41 0.9800 .
C16 H33 0.9800 .
C16 H34 0.9800 .
C16 H35 0.9800 .
C20 H42 0.9800 .
C20 H43 0.9800 .
C20 H44 0.9800 .
C17 H36 0.9800 .
C17 H37 0.9800 .
C17 H38 0.9800 .
