#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:31:45 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179451 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/48/4334891.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334891
loop_
_publ_author_name
'Shin-ichiro Noro'
'Katsuo Fukuhara'
'Yuh Hijikata'
'Kazuya Kubo'
'Takayoshi Nakamura'
_publ_section_title
;
 Rational Synthesis of a Porous Copper(II) Coordination Polymer Bridged by
 Weak Lewis-Base Inorganic Monoanions Using an Anion-Mixing Method
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5630
_journal_page_last               5632
_journal_paper_doi               10.1021/ic400276c
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'C27 H28 Cu F9 N4 O3 P S'
_chemical_formula_sum            'C27 H28 Cu F9 N4 O3 P S'
_chemical_formula_weight         754.11
_space_group_IT_number           63
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      63
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   12.5414(11)
_cell_length_b                   18.4210(18)
_cell_length_c                   15.6352(12)
_cell_measurement_reflns_used    9748
_cell_measurement_temperature    173
_cell_measurement_theta_max      27.41
_cell_measurement_theta_min      3.25
_cell_volume                     3612.1(5)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.0'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0852
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            17214
_diffrn_reflns_theta_full        27.41
_diffrn_reflns_theta_max         27.42
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.785
_exptl_absorpt_correction_T_max  0.925
_exptl_absorpt_correction_T_min  0.554
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.387
_exptl_crystal_description       block
_exptl_crystal_F_000             1532.00
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.050
_refine_diff_density_max         0.560
_refine_diff_density_min         -0.750
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     132
_refine_ls_number_reflns         2224
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0618
_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0974P)²+3.0374P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1796
_reflns_number_gt                1579
_reflns_number_total             2224
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            ic400276c_si_004.cif
_cod_data_source_block           110204-(1+2)H2O-Actn-dry
_cod_original_cell_volume        3612.1(6)
_cod_database_code               4334891
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 -X,+Y,+Z
3 +X,-Y,1/2+Z
4 -X,-Y,1/2+Z
5 -X,-Y,-Z
6 +X,-Y,-Z
7 -X,+Y,1/2-Z
8 +X,+Y,1/2-Z
9 1/2+X,1/2+Y,+Z
10 1/2-X,1/2+Y,+Z
11 1/2+X,1/2-Y,1/2+Z
12 1/2-X,1/2-Y,1/2+Z
13 1/2-X,1/2-Y,-Z
14 1/2+X,1/2-Y,-Z
15 1/2-X,1/2+Y,1/2-Z
16 1/2+X,1/2+Y,1/2-Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.0000 0.0000 0.5000 0.0361(3) Uani 1.0 4 d .
S1 S -0.03212(16) 0.04137(13) 0.7500 0.0351(6) Uani 0.5000 8 d .
P1 P 0.0000 0.27041(14) 0.2500 0.0566(6) Uani 1.0 4 d .
F1 F -0.1137(7) 0.1416(5) 0.7500 0.077(3) Uani 0.5000 8 d .
F2 F 0.0000 0.1685(3) 0.8209(4) 0.147(3) Uani 1.0 8 d .
F3 F 0.0000 0.2737(4) 0.3469(3) 0.147(3) Uani 1.0 8 d .
F4 F 0.0000 0.3549(7) 0.2500 0.256(8) Uani 1.0 4 d .
F5 F 0.1263(4) 0.2739(4) 0.2500 0.130(3) Uani 1.0 8 d .
F6 F 0.0000 0.1865(4) 0.2500 0.113(3) Uani 1.0 4 d .
O1 O 0.0000 0.0142(2) 0.6712(2) 0.0548(11) Uani 1.0 8 d .
O2 O -0.1461(5) 0.0442(5) 0.7500 0.058(3) Uani 0.5000 8 d .
N1 N 0.1182(2) 0.07453(16) 0.48606(16) 0.0345(6) Uani 1.0 16 d .
C1 C 0.1392(3) 0.10911(19) 0.41205(19) 0.0374(8) Uani 1.0 16 d .
C2 C 0.2281(3) 0.15249(19) 0.4009(2) 0.0383(8) Uani 1.0 16 d .
C3 C 0.2995(3) 0.16279(18) 0.4674(2) 0.0341(7) Uani 1.0 16 d .
C4 C 0.2758(3) 0.1284(2) 0.5444(2) 0.0399(8) Uani 1.0 16 d .
C5 C 0.1866(3) 0.08502(19) 0.55113(19) 0.0380(8) Uani 1.0 16 d .
C6 C 0.3990(3) 0.20725(19) 0.4575(3) 0.0409(8) Uani 1.0 16 d .
C7 C 0.5000 0.1606(2) 0.4595(3) 0.0351(10) Uani 1.0 8 d .
C8 C 0.0000 0.1346(5) 0.7500 0.067(3) Uani 1.0 4 d .
H1 H 0.0911 0.1035 0.3656 0.0449 Uiso 1.0 16 calc R
H2 H 0.2403 0.1754 0.3473 0.0459 Uiso 1.0 16 calc R
H4 H 0.3211 0.1348 0.5924 0.0479 Uiso 1.0 16 calc R
H5 H 0.1729 0.0615 0.6041 0.0456 Uiso 1.0 16 calc R
H6A H 0.4023 0.2435 0.5042 0.0491 Uiso 1.0 16 calc R
H6B H 0.3959 0.2339 0.4026 0.0491 Uiso 1.0 16 calc R
H7A H 0.5000 0.1275 0.4096 0.0421 Uiso 1.0 8 calc R
H7B H 0.5000 0.1306 0.5120 0.0421 Uiso 1.0 8 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
Cu Cu 0.3201 1.2651
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
S S 0.1246 0.1234
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.0106 0.0060
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cu1 O1 180.00(11) yes . 5_556
O1 Cu1 N1 92.35(9) yes . .
O1 Cu1 N1 92.35(9) yes . 2_555
O1 Cu1 N1 87.65(9) yes . 5_556
O1 Cu1 N1 87.65(9) yes . 6_556
O1 Cu1 N1 87.65(9) yes 5_556 .
O1 Cu1 N1 87.65(9) yes 5_556 2_555
O1 Cu1 N1 92.35(9) yes 5_556 5_556
O1 Cu1 N1 92.35(9) yes 5_556 6_556
N1 Cu1 N1 93.68(11) yes . 2_555
N1 Cu1 N1 180.00(15) yes . 5_556
N1 Cu1 N1 86.32(11) yes . 6_556
N1 Cu1 N1 86.32(11) yes 2_555 5_556
N1 Cu1 N1 180.00(15) yes 2_555 6_556
N1 Cu1 N1 93.68(11) yes 5_556 6_556
F1 S1 O1 117.10(17) yes . .
F1 S1 O1 117.10(17) yes . 7_556
F1 S1 O2 58.9(5) yes . .
F1 S1 C8 42.2(3) yes . .
O1 S1 O1 124.9(3) yes . 7_556
O1 S1 O2 107.63(17) yes . .
O1 S1 C8 106.53(18) yes . .
O1 S1 O2 107.63(17) yes 7_556 .
O1 S1 C8 106.53(18) yes 7_556 .
O2 S1 C8 101.1(4) yes . .
F3 P1 F3 175.4(5) yes . 7_555
F3 P1 F4 87.7(3) yes . .
F3 P1 F5 89.907(18) yes . .
F3 P1 F5 89.907(18) yes . 2_555
F3 P1 F6 92.3(3) yes . .
F3 P1 F4 87.7(3) yes 7_555 .
F3 P1 F5 89.907(18) yes 7_555 .
F3 P1 F5 89.907(18) yes 7_555 2_555
F3 P1 F6 92.3(3) yes 7_555 .
F4 P1 F5 87.7(3) yes . .
F4 P1 F5 87.7(3) yes . 2_555
F4 P1 F6 180.000(2) yes . .
F5 P1 F5 175.4(5) yes . 2_555
F5 P1 F6 92.3(3) yes . .
F5 P1 F6 92.3(3) yes 2_555 .
S1 F1 C8 55.8(5) yes . .
Cu1 O1 S1 156.57(18) yes . .
Cu1 O1 S1 156.57(18) yes . 2_555
S1 O1 S1 33.71(14) yes . 2_555
Cu1 N1 C1 123.7(2) yes . .
Cu1 N1 C5 118.8(3) yes . .
C1 N1 C5 117.2(3) yes . .
N1 C1 C2 122.7(3) yes . .
C1 C2 C3 120.4(3) yes . .
C2 C3 C4 116.6(3) yes . .
C2 C3 C6 122.4(3) yes . .
C4 C3 C6 121.0(3) yes . .
C3 C4 C5 120.2(3) yes . .
N1 C5 C4 122.9(3) yes . .
C3 C6 C7 112.3(3) yes . .
C6 C7 C6 111.7(3) yes . 2_655
S1 C8 S1 26.40(17) yes . 2_555
S1 C8 F1 82.0(5) yes . .
S1 C8 F1 108.4(6) yes . 2_555
S1 C8 F2 118.5(5) yes . .
S1 C8 F2 118.5(5) yes . 7_556
S1 C8 F1 108.4(6) yes 2_555 .
S1 C8 F1 82.0(5) yes 2_555 2_555
S1 C8 F2 118.5(5) yes 2_555 .
S1 C8 F2 118.5(5) yes 2_555 7_556
F1 C8 F1 169.7(9) yes . 2_555
F1 C8 F2 87.5(3) yes . .
F1 C8 F2 87.5(3) yes . 7_556
F1 C8 F2 87.5(3) yes 2_555 .
F1 C8 F2 87.5(3) yes 2_555 7_556
F2 C8 F2 121.2(8) yes . 7_556
N1 C1 H1 118.672 no . .
C2 C1 H1 118.663 no . .
C1 C2 H2 119.808 no . .
C3 C2 H2 119.814 no . .
C3 C4 H4 119.886 no . .
C5 C4 H4 119.885 no . .
N1 C5 H5 118.562 no . .
C4 C5 H5 118.552 no . .
C3 C6 H6A 109.136 no . .
C3 C6 H6B 109.140 no . .
C7 C6 H6A 109.129 no . .
C7 C6 H6B 109.163 no . .
H6A C6 H6B 107.865 no . .
C6 C7 H7A 109.260 no . .
C6 C7 H7B 109.310 no . .
C6 C7 H7A 109.260 no 2_655 .
C6 C7 H7B 109.310 no 2_655 .
H7A C7 H7B 107.938 no . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_2
Cu1 O1 2.689(4) yes .
Cu1 O1 2.689(4) yes 5_556
Cu1 N1 2.032(3) yes .
Cu1 N1 2.032(3) yes 2_555
Cu1 N1 2.032(3) yes 5_556
Cu1 N1 2.032(3) yes 6_556
S1 F1 2.111(10) yes .
S1 O1 1.390(4) yes .
S1 O1 1.390(4) yes 7_556
S1 O2 1.430(7) yes .
S1 C8 1.764(10) yes .
P1 F3 1.516(5) yes .
P1 F3 1.516(5) yes 7_555
P1 F4 1.556(14) yes .
P1 F5 1.585(5) yes .
P1 F5 1.585(5) yes 2_555
P1 F6 1.546(8) yes .
F1 C8 1.432(9) yes .
F2 C8 1.272(8) yes .
N1 C1 1.347(4) yes .
N1 C5 1.345(4) yes .
C1 C2 1.383(5) yes .
C2 C3 1.385(5) yes .
C3 C4 1.393(5) yes .
C3 C6 1.500(5) yes .
C4 C5 1.378(5) yes .
C6 C7 1.532(4) yes .
C1 H1 0.950 no .
C2 H2 0.950 no .
C4 H4 0.950 no .
C5 H5 0.950 no .
C6 H6A 0.990 no .
C6 H6B 0.990 no .
C7 H7A 0.990 no .
C7 H7B 0.990 no .
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_publ_flag
_geom_contact_site_symmetry_2
Cu1 C1 2.997(4) no 2_555
Cu1 C1 2.997(4) no 5_556
Cu1 C1 2.997(4) no 6_556
Cu1 C5 2.927(4) no 2_555
Cu1 C5 2.927(4) no 5_556
Cu1 C5 2.927(4) no 6_556
S1 O2 2.236(7) no 2_555
F1 C5 3.405(5) no 2_555
F1 C5 3.405(5) no 7_556
F2 O1 2.845(7) no 7_556
F2 O2 3.135(9) no .
F2 O2 3.135(9) no 2_555
F2 C5 3.442(6) no 7_556
O1 C1 3.147(5) no 5_556
O1 C1 3.147(5) no 6_556
O1 C5 3.272(4) no .
O1 C5 3.272(4) no 2_555
O2 C5 3.239(4) no 2_555
O2 C5 3.239(4) no 7_556
N1 C1 3.488(4) no 2_555
N1 C3 2.811(4) no .
N1 C5 3.117(5) no 6_556
C1 C1 3.493(5) no 2_555
C1 C4 2.709(5) no .
C2 C5 2.708(5) no .
C2 C7 3.534(4) no .
C4 C7 3.166(4) no .
C5 C5 3.517(5) no 6_556
F2 C5 3.442(6) no 8_556
F2 C6 3.377(7) no 11_455
F2 C6 3.377(7) no 12_555
F3 C6 3.329(6) no 13_556
F3 C6 3.329(6) no 14_456
F3 C7 3.260(7) no 13_556
F5 C2 3.493(6) no .
F5 C2 3.493(6) no 8_555
F6 C1 3.391(5) no .
F6 C1 3.391(5) no 2_555
F6 C1 3.391(5) no 7_555
F6 C1 3.391(5) no 8_555
C1 F6 3.391(5) no .
C2 F5 3.493(6) no .
C3 C3 3.593(5) no 13_556
C6 F2 3.377(7) no 11_554
C6 F3 3.329(6) no 13_556
C7 F3 3.260(7) no 13_556
Cu1 H1 3.0578 no .
Cu1 H1 3.0578 no 2_555
Cu1 H1 3.0578 no 5_556
Cu1 H1 3.0578 no 6_556
Cu1 H5 2.9382 no .
Cu1 H5 2.9382 no 2_555
Cu1 H5 2.9382 no 5_556
Cu1 H5 2.9382 no 6_556
S1 H1 3.3067 no 5_556
S1 H1 3.5741 no 6_556
S1 H5 3.4575 no .
S1 H5 2.9087 no 2_555
S1 H5 2.9087 no 7_556
F1 H4 3.5855 no 2_555
F1 H4 3.5855 no 7_556
F1 H5 2.8167 no 2_555
F1 H5 2.8167 no 7_556
F2 H5 3.1563 no 7_556
O1 H1 2.5168 no 5_556
O1 H1 2.5168 no 6_556
O1 H5 2.5618 no .
O1 H5 2.5618 no 2_555
O2 H1 3.3384 no 5_556
O2 H5 2.3282 no 2_555
O2 H5 2.3282 no 7_556
N1 H1 3.2735 no 2_555
N1 H2 3.2406 no .
N1 H4 3.2370 no .
N1 H5 2.9558 no 6_556
C1 H1 2.9799 no 2_555
C1 H5 3.1560 no .
C1 H5 3.1812 no 6_556
C2 H4 3.2301 no .
C2 H6A 3.1925 no .
C2 H6B 2.5842 no .
C2 H7A 3.4434 no .
C3 H1 3.2493 no .
C3 H5 3.2514 no .
C3 H7A 2.7497 no .
C3 H7B 2.6761 no .
C4 H2 3.2312 no .
C4 H6A 2.7220 no .
C4 H6B 3.3113 no .
C4 H7A 3.5142 no .
C4 H7B 2.8580 no .
C5 H1 3.1563 no .
C6 H2 2.6968 no .
C6 H4 2.6796 no .
C6 H6A 2.6814 no 2_655
C6 H6B 2.7566 no 2_655
C7 H4 3.0943 no .
C7 H4 3.0943 no 2_655
C7 H6A 2.0784 no 2_655
C7 H6B 2.0787 no 2_655
C8 H5 3.4235 no .
C8 H5 3.4235 no 2_555
C8 H5 3.4235 no 7_556
H1 H1 2.2840 no 2_555
H1 H2 2.3106 no .
H1 H5 3.2425 no 6_556
H2 H6A 3.4238 no .
H2 H6B 2.3914 no .
H2 H7A 3.5122 no .
H4 H5 2.3054 no .
H4 H6A 2.6349 no .
H4 H7B 2.5728 no .
H6A H6A 2.4498 no 2_655
H6A H6B 2.9932 no 2_655
H6A H7A 2.8732 no .
H6A H7B 2.4170 no .
H6B H6B 2.6114 no 2_655
H6B H7A 2.3587 no .
H6B H7B 2.8733 no .
S1 H1 3.5741 no 3_555
S1 H1 3.3067 no 4_555
S1 H5 3.4575 no 8_556
F1 H6B 3.3112 no 11_455
F1 H6B 3.3113 no 14_456
F2 H5 3.1563 no 8_556
F2 H6A 3.5136 no 11_455
F2 H6A 3.5136 no 12_555
F2 H6B 2.5626 no 11_455
F2 H6B 2.5626 no 12_555
F3 H1 3.3501 no .
F3 H1 3.3501 no 2_555
F3 H2 3.5163 no .
F3 H2 3.5163 no 2_555
F3 H4 2.9615 no 13_556
F3 H4 2.9615 no 14_456
F3 H6A 2.6493 no 13_556
F3 H6A 2.6493 no 14_456
F3 H7B 2.8249 no 13_556
F4 H4 3.3374 no 11_454
F4 H4 3.3374 no 12_554
F4 H4 3.3374 no 13_556
F4 H4 3.3374 no 14_456
F5 H2 2.7666 no .
F5 H2 2.7666 no 8_555
F5 H4 3.0549 no 12_554
F5 H4 3.0549 no 13_556
F6 H1 2.6292 no .
F6 H1 2.6292 no 2_555
F6 H1 2.6292 no 7_555
F6 H1 2.6292 no 8_555
F6 H2 3.3822 no .
F6 H2 3.3822 no 2_555
F6 H2 3.3822 no 7_555
F6 H2 3.3822 no 8_555
O2 H1 3.3384 no 4_555
N1 H6A 3.3659 no 13_556
C1 H6A 3.0595 no 13_556
C2 H6A 2.9242 no 13_556
C3 H6A 3.0963 no 13_556
C4 H6A 3.3374 no 13_556
C4 H6B 3.4284 no 13_556
C5 H6A 3.4605 no 13_556
C5 H6B 3.5661 no 13_556
C8 H5 3.4235 no 8_556
H1 S1 3.5741 no 3_554
H1 S1 3.3067 no 4_554
H1 F3 3.3501 no .
H1 F6 2.6292 no .
H1 O2 3.3384 no 4_554
H1 H6A 3.4781 no 13_556
H2 F3 3.5163 no .
H2 F5 2.7666 no .
H2 F6 3.3822 no .
H2 H2 3.0429 no 8_555
H2 H6A 3.2900 no 13_556
H4 F3 2.9615 no 13_556
H4 F4 3.3374 no 11_555
H4 F5 3.0549 no 12_555
H6A F2 3.5136 no 11_554
H6A F3 2.6493 no 13_556
H6A N1 3.3659 no 13_556
H6A C1 3.0595 no 13_556
H6A C2 2.9242 no 13_556
H6A C3 3.0963 no 13_556
H6A C4 3.3374 no 13_556
H6A C5 3.4605 no 13_556
H6A H1 3.4781 no 13_556
H6A H2 3.2900 no 13_556
H6B F1 3.3113 no 11_554
H6B F2 2.5626 no 11_554
H6B C4 3.4284 no 13_556
H6B C5 3.5661 no 13_556
H7B F3 2.8249 no 13_556
