#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:51:50 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179458 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/55/4335506.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4335506
loop_
_publ_author_name
'Anton O. Oliynyk'
'Stanislav S. Stoyko'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Quaternary Germanides RE4Mn2InGe4 (RE = La-Nd, Sm, Gd-Tm, Lu)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8264
_journal_page_last               8271
_journal_paper_doi               10.1021/ic401171v
_journal_volume                  52
_journal_year                    2013
_chemical_formula_structural     'Gd4 Mn2 In0.87 Ge4'
_chemical_formula_sum            'Gd4 Ge4 In0.87 Mn2'
_chemical_formula_weight         1128.56
_chemical_name_common
'gadolinium manganese indium germanide (4/2/1/4)'
_chemical_name_systematic
'gadolinium manganese indium germanide (4/2/1/4)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.3040(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   15.9808(9)
_cell_length_b                   4.2363(2)
_cell_length_c                   7.1590(4)
_cell_measurement_reflns_used    2934
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.94
_cell_measurement_theta_min      3.38
_cell_volume                     465.17(4)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0255
_diffrn_reflns_av_sigmaI/netI    0.0219
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3319
_diffrn_reflns_theta_full        33.23
_diffrn_reflns_theta_max         33.23
_diffrn_reflns_theta_min         2.66
_exptl_absorpt_coefficient_mu    45.416
_exptl_absorpt_correction_T_max  0.4384
_exptl_absorpt_correction_T_min  0.0884
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    8.057
_exptl_crystal_description       irregular
_exptl_crystal_F_000             953
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.825
_refine_diff_density_min         -1.109
_refine_diff_density_rms         0.306
_refine_ls_extinction_coef       0.00060(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         978
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.095
_refine_ls_R_factor_all          0.0221
_refine_ls_R_factor_gt           0.0179
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0167P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0362
_refine_ls_wR_factor_ref         0.0371
_reflns_number_gt                887
_reflns_number_total             978
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic401171v_si_002_1.cif
_cod_data_source_block           Gd4Mn2InGe4
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               4335506
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Gd1 Gd 0.346425(16) 0.0000 0.07408(4) 0.00637(7) Uani 1 2 d S
Gd2 Gd 0.580569(16) 0.0000 0.36699(4) 0.00636(7) Uani 1 2 d S
Mn Mn 0.22018(5) 0.0000 0.61883(12) 0.00693(15) Uani 1 2 d S
In In 0.0000 0.0000 0.0000 0.00924(18) Uani 0.866(3) 4 d SP
Ge1 Ge 0.06384(4) 0.0000 0.65464(8) 0.00683(11) Uani 1 2 d S
Ge2 Ge 0.19381(4) 0.0000 0.24366(8) 0.00743(11) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Gd1 Ge1 91.453(17) 7_556 7_546
Ge1 Gd1 Ge2 91.922(15) 7_556 .
Ge1 Gd1 Ge2 91.922(15) 7_546 .
Ge1 Gd1 Ge2 162.039(18) 7_556 7_545
Ge1 Gd1 Ge2 87.369(12) 7_546 7_545
Ge2 Gd1 Ge2 106.027(13) . 7_545
Ge1 Gd1 Ge2 87.369(12) 7_556 7
Ge1 Gd1 Ge2 162.039(18) 7_546 7
Ge2 Gd1 Ge2 106.027(13) . 7
Ge2 Gd1 Ge2 88.268(16) 7_545 7
Ge1 Gd1 Mn 133.960(9) 7_556 1_554
Ge1 Gd1 Mn 133.960(9) 7_546 1_554
Ge2 Gd1 Mn 93.326(19) . 1_554
Ge2 Gd1 Mn 47.360(10) 7_545 1_554
Ge2 Gd1 Mn 47.360(10) 7 1_554
Ge1 Gd1 In 54.355(11) 7_556 3
Ge1 Gd1 In 108.111(12) 7_546 3
Ge2 Gd1 In 139.928(5) . 3
Ge2 Gd1 In 109.150(12) 7_545 3
Ge2 Gd1 In 57.248(11) 7 3
Mn Gd1 In 96.518(12) 1_554 3
Ge1 Gd1 In 108.111(12) 7_556 3_545
Ge1 Gd1 In 54.355(11) 7_546 3_545
Ge2 Gd1 In 139.928(5) . 3_545
Ge2 Gd1 In 57.248(11) 7_545 3_545
Ge2 Gd1 In 109.150(12) 7 3_545
Mn Gd1 In 96.518(12) 1_554 3_545
In Gd1 In 77.219(6) 3 3_545
Ge1 Gd1 Mn 46.966(17) 7_556 7_556
Ge1 Gd1 Mn 101.645(16) 7_546 7_556
Ge2 Gd1 Mn 46.378(13) . 7_556
Ge2 Gd1 Mn 150.546(19) 7_545 7_556
Ge2 Gd1 Mn 90.617(13) 7 7_556
Mn Gd1 Mn 114.657(15) 1_554 7_556
In Gd1 Mn 94.753(11) 3 7_556
In Gd1 Mn 148.595(16) 3_545 7_556
Ge1 Gd1 Mn 101.645(16) 7_556 7_546
Ge1 Gd1 Mn 46.966(17) 7_546 7_546
Ge2 Gd1 Mn 46.378(13) . 7_546
Ge2 Gd1 Mn 90.617(13) 7_545 7_546
Ge2 Gd1 Mn 150.546(19) 7 7_546
Mn Gd1 Mn 114.657(15) 1_554 7_546
In Gd1 Mn 148.595(16) 3 7_546
In Gd1 Mn 94.753(11) 3_545 7_546
Mn Gd1 Mn 76.267(17) 7_556 7_546
Ge1 Gd1 Gd1 145.280(15) 7_556 7_545
Ge1 Gd1 Gd1 89.394(10) 7_546 7_545
Ge2 Gd1 Gd1 53.364(10) . 7_545
Ge2 Gd1 Gd1 52.663(11) 7_545 7_545
Ge2 Gd1 Gd1 101.721(14) 7 7_545
Mn Gd1 Gd1 58.831(12) 1_554 7_545
In Gd1 Gd1 155.081(11) 3 7_545
In Gd1 Gd1 100.448(6) 3_545 7_545
Mn Gd1 Gd1 98.990(15) 7_556 7_545
Mn Gd1 Gd1 55.826(15) 7_546 7_545
Ge1 Gd1 Gd1 89.394(10) 7_556 7
Ge1 Gd1 Gd1 145.280(15) 7_546 7
Ge2 Gd1 Gd1 53.364(10) . 7
Ge2 Gd1 Gd1 101.721(14) 7_545 7
Ge2 Gd1 Gd1 52.663(11) 7 7
Mn Gd1 Gd1 58.831(12) 1_554 7
In Gd1 Gd1 100.448(5) 3 7
In Gd1 Gd1 155.081(11) 3_545 7
Mn Gd1 Gd1 55.826(15) 7_556 7
Mn Gd1 Gd1 98.990(15) 7_546 7
Gd1 Gd1 Gd1 71.093(10) 7_545 7
Ge1 Gd2 Ge1 89.152(16) 3 3_545
Ge1 Gd2 Ge2 83.362(12) 3 3
Ge1 Gd2 Ge2 148.450(17) 3_545 3
Ge1 Gd2 Ge2 148.450(18) 3 3_545
Ge1 Gd2 Ge2 83.362(12) 3_545 3_545
Ge2 Gd2 Ge2 87.172(16) 3 3_545
Ge1 Gd2 Ge1 107.814(10) 3 7_546
Ge1 Gd2 Ge1 49.313(19) 3_545 7_546
Ge2 Gd2 Ge1 161.048(17) 3 7_546
Ge2 Gd2 Ge1 90.279(12) 3_545 7_546
Ge1 Gd2 Ge1 49.313(19) 3 7_556
Ge1 Gd2 Ge1 107.814(10) 3_545 7_556
Ge2 Gd2 Ge1 90.279(12) 3 7_556
Ge2 Gd2 Ge1 161.048(17) 3_545 7_556
Ge1 Gd2 Ge1 86.059(16) 7_546 7_556
Ge1 Gd2 Mn 105.060(16) 3 5_656
Ge1 Gd2 Mn 105.060(16) 3_545 5_656
Ge2 Gd2 Mn 48.629(11) 3 5_656
Ge2 Gd2 Mn 48.629(11) 3_545 5_656
Ge1 Gd2 Mn 136.933(8) 7_546 5_656
Ge1 Gd2 Mn 136.933(8) 7_556 5_656
Ge1 Gd2 Mn 48.642(17) 3 3
Ge1 Gd2 Mn 104.995(17) 3_545 3
Ge2 Gd2 Mn 48.603(17) 3 3
Ge2 Gd2 Mn 104.002(17) 3_545 3
Ge1 Gd2 Mn 149.510(19) 7_546 3
Ge1 Gd2 Mn 88.151(14) 7_556 3
Mn Gd2 Mn 56.654(19) 5_656 3
Ge1 Gd2 Mn 104.995(17) 3 3_545
Ge1 Gd2 Mn 48.642(17) 3_545 3_545
Ge2 Gd2 Mn 104.002(17) 3 3_545
Ge2 Gd2 Mn 48.603(17) 3_545 3_545
Ge1 Gd2 Mn 88.151(14) 7_546 3_545
Ge1 Gd2 Mn 149.510(19) 7_556 3_545
Mn Gd2 Mn 56.654(18) 5_656 3_545
Mn Gd2 Mn 81.85(2) 3 3_545
Ge1 Gd2 In 153.345(14) 3 3_545
Ge1 Gd2 In 90.184(9) 3_545 3_545
Ge2 Gd2 In 109.839(12) 3 3_545
Ge2 Gd2 In 57.630(11) 3_545 3_545
Ge1 Gd2 In 53.898(10) 7_546 3_545
Ge1 Gd2 In 106.056(12) 7_556 3_545
Mn Gd2 In 100.833(13) 5_656 3_545
Mn Gd2 In 155.174(17) 3 3_545
Mn Gd2 In 94.385(11) 3_545 3_545
Ge1 Gd2 In 90.184(9) 3 3
Ge1 Gd2 In 153.345(14) 3_545 3
Ge2 Gd2 In 57.630(11) 3 3
Ge2 Gd2 In 109.839(12) 3_545 3
Ge1 Gd2 In 106.056(12) 7_546 3
Ge1 Gd2 In 53.898(10) 7_556 3
Mn Gd2 In 100.833(13) 5_656 3
Mn Gd2 In 94.385(11) 3 3
Mn Gd2 In 155.174(16) 3_545 3
In Gd2 In 78.751(7) 3_545 3
Ge1 Gd2 Gd2 55.013(10) 3 5_656
Ge1 Gd2 Gd2 55.013(10) 3_545 5_656
Ge2 Gd2 Gd2 135.822(8) 3 5_656
Ge2 Gd2 Gd2 135.822(8) 3_545 5_656
Ge1 Gd2 Gd2 52.801(10) 7_546 5_656
Ge1 Gd2 Gd2 52.801(10) 7_556 5_656
Mn Gd2 Gd2 147.785(19) 5_656 5_656
Mn Gd2 Gd2 100.877(16) 3 5_656
Mn Gd2 Gd2 100.877(16) 3_545 5_656
In Gd2 Gd2 103.928(9) 3_545 5_656
In Gd2 Gd2 103.928(9) 3 5_656
Ge2 Mn Ge2 111.26(4) 7_556 7_546
Ge2 Mn Ge1 113.01(2) 7_556 .
Ge2 Mn Ge1 113.01(2) 7_546 .
Ge2 Mn Ge2 108.09(2) 7_556 .
Ge2 Mn Ge2 108.09(2) 7_546 .
Ge1 Mn Ge2 102.82(3) . .
Ge2 Mn Mn 124.95(4) 7_556 7_546
Ge2 Mn Mn 54.548(19) 7_546 7_546
Ge1 Mn Mn 121.39(3) . 7_546
Ge2 Mn Mn 53.54(3) . 7_546
Ge2 Mn Mn 54.548(19) 7_556 7_556
Ge2 Mn Mn 124.95(4) 7_546 7_556
Ge1 Mn Mn 121.39(3) . 7_556
Ge2 Mn Mn 53.54(3) . 7_556
Mn Mn Mn 88.58(4) 7_546 7_556
Ge2 Mn Gd2 63.96(2) 7_556 5_656
Ge2 Mn Gd2 63.96(2) 7_546 5_656
Ge1 Mn Gd2 172.76(4) . 5_656
Ge2 Mn Gd2 84.42(2) . 5_656
Mn Mn Gd2 62.94(3) 7_546 5_656
Mn Mn Gd2 62.94(3) 7_556 5_656
Ge2 Mn Gd2 165.01(3) 7_556 3_445
Ge2 Mn Gd2 83.375(13) 7_546 3_445
Ge1 Mn Gd2 61.313(18) . 3_445
Ge2 Mn Gd2 62.455(18) . 3_445
Mn Mn Gd2 60.40(2) 7_546 3_445
Mn Mn Gd2 114.90(4) 7_556 3_445
Gd2 Mn Gd2 123.347(19) 5_656 3_445
Ge2 Mn Gd2 83.375(13) 7_556 3_455
Ge2 Mn Gd2 165.01(3) 7_546 3_455
Ge1 Mn Gd2 61.313(18) . 3_455
Ge2 Mn Gd2 62.455(18) . 3_455
Mn Mn Gd2 114.90(4) 7_546 3_455
Mn Mn Gd2 60.40(2) 7_556 3_455
Gd2 Mn Gd2 123.347(18) 5_656 3_455
Gd2 Mn Gd2 81.84(2) 3_445 3_455
Ge2 Mn Gd1 60.69(2) 7_556 1_556
Ge2 Mn Gd1 60.69(2) 7_546 1_556
Ge1 Mn Gd1 103.95(3) . 1_556
Ge2 Mn Gd1 153.23(3) . 1_556
Mn Mn Gd1 110.54(3) 7_546 1_556
Mn Mn Gd1 110.54(3) 7_556 1_556
Gd2 Mn Gd1 68.814(18) 5_656 1_556
Gd2 Mn Gd1 133.003(15) 3_445 1_556
Gd2 Mn Gd1 133.003(15) 3_455 1_556
Ge2 Mn Gd1 58.235(17) 7_556 7_556
Ge2 Mn Gd1 119.53(3) 7_546 7_556
Ge1 Mn Gd1 56.865(16) . 7_556
Ge2 Mn Gd1 132.29(2) . 7_556
Mn Mn Gd1 173.52(3) 7_546 7_556
Mn Mn Gd1 97.539(14) 7_556 7_556
Gd2 Mn Gd1 118.10(2) 5_656 7_556
Gd2 Mn Gd1 118.17(2) 3_445 7_556
Gd2 Mn Gd1 70.317(12) 3_455 7_556
Gd1 Mn Gd1 65.344(15) 1_556 7_556
Ge2 Mn Gd1 119.53(3) 7_556 7_546
Ge2 Mn Gd1 58.235(17) 7_546 7_546
Ge1 Mn Gd1 56.865(16) . 7_546
Ge2 Mn Gd1 132.29(2) . 7_546
Mn Mn Gd1 97.539(14) 7_546 7_546
Mn Mn Gd1 173.52(3) 7_556 7_546
Gd2 Mn Gd1 118.10(2) 5_656 7_546
Gd2 Mn Gd1 70.317(12) 3_445 7_546
Gd2 Mn Gd1 118.17(2) 3_455 7_546
Gd1 Mn Gd1 65.344(15) 1_556 7_546
Gd1 Mn Gd1 76.266(17) 7_556 7_546
Ge1 In Ge1 180.000(18) 5_556 1_554
Ge1 In Ge2 93.142(15) 5_556 .
Ge1 In Ge2 86.858(15) 1_554 .
Ge1 In Ge2 86.857(15) 5_556 5
Ge1 In Ge2 93.143(15) 1_554 5
Ge2 In Ge2 180.0 . 5
Ge1 In Gd2 121.048(9) 5_556 7_545
Ge1 In Gd2 58.952(9) 1_554 7_545
Ge2 In Gd2 123.137(8) . 7_545
Ge2 In Gd2 56.864(8) 5 7_545
Ge1 In Gd2 58.952(9) 5_556 3_455
Ge1 In Gd2 121.048(9) 1_554 3_455
Ge2 In Gd2 56.863(8) . 3_455
Ge2 In Gd2 123.136(8) 5 3_455
Gd2 In Gd2 180.000(9) 7_545 3_455
Ge1 In Gd2 121.048(9) 5_556 7
Ge1 In Gd2 58.952(9) 1_554 7
Ge2 In Gd2 123.137(8) . 7
Ge2 In Gd2 56.864(8) 5 7
Gd2 In Gd2 78.752(7) 7_545 7
Gd2 In Gd2 101.248(7) 3_455 7
Ge1 In Gd2 58.952(9) 5_556 3_445
Ge1 In Gd2 121.048(9) 1_554 3_445
Ge2 In Gd2 56.863(8) . 3_445
Ge2 In Gd2 123.136(8) 5 3_445
Gd2 In Gd2 101.248(7) 7_545 3_445
Gd2 In Gd2 78.752(7) 3_455 3_445
Gd2 In Gd2 180.0 7 3_445
Ge1 In Gd1 55.206(8) 5_556 3_445
Ge1 In Gd1 124.794(8) 1_554 3_445
Ge2 In Gd1 124.354(8) . 3_445
Ge2 In Gd1 55.645(8) 5 3_445
Gd2 In Gd1 65.862(6) 7_545 3_445
Gd2 In Gd1 114.138(6) 3_455 3_445
Gd2 In Gd1 112.509(6) 7 3_445
Gd2 In Gd1 67.491(6) 3_445 3_445
Ge1 In Gd1 124.794(8) 5_556 7
Ge1 In Gd1 55.206(8) 1_554 7
Ge2 In Gd1 55.646(8) . 7
Ge2 In Gd1 124.355(8) 5 7
Gd2 In Gd1 114.138(6) 7_545 7
Gd2 In Gd1 65.862(6) 3_455 7
Gd2 In Gd1 67.491(6) 7 7
Gd2 In Gd1 112.509(6) 3_445 7
Gd1 In Gd1 180.000(6) 3_445 7
Ge1 In Gd1 124.794(8) 5_556 7_545
Ge1 In Gd1 55.206(8) 1_554 7_545
Ge2 In Gd1 55.646(8) . 7_545
Ge2 In Gd1 124.355(8) 5 7_545
Gd2 In Gd1 67.491(6) 7_545 7_545
Gd2 In Gd1 112.509(6) 3_455 7_545
Gd2 In Gd1 114.138(6) 7 7_545
Gd2 In Gd1 65.862(6) 3_445 7_545
Gd1 In Gd1 102.780(7) 3_445 7_545
Gd1 In Gd1 77.220(6) 7 7_545
Ge1 In Gd1 55.206(8) 5_556 3_455
Ge1 In Gd1 124.794(8) 1_554 3_455
Ge2 In Gd1 124.354(8) . 3_455
Ge2 In Gd1 55.645(8) 5 3_455
Gd2 In Gd1 112.509(6) 7_545 3_455
Gd2 In Gd1 67.491(6) 3_455 3_455
Gd2 In Gd1 65.862(6) 7 3_455
Gd2 In Gd1 114.138(6) 3_445 3_455
Gd1 In Gd1 77.220(6) 3_445 3_455
Gd1 In Gd1 102.780(7) 7 3_455
Gd1 In Gd1 180.000(6) 7_545 3_455
Ge1 Ge1 Mn 118.26(4) 5_556 .
Ge1 Ge1 In 110.43(3) 5_556 1_556
Mn Ge1 In 131.31(3) . 1_556
Ge1 Ge1 Gd1 133.700(10) 5_556 7_556
Mn Ge1 Gd1 76.169(18) . 7_556
In Ge1 Gd1 70.439(12) 1_556 7_556
Ge1 Ge1 Gd1 133.700(9) 5_556 7_546
Mn Ge1 Gd1 76.169(18) . 7_546
In Ge1 Gd1 70.439(12) 1_556 7_546
Gd1 Ge1 Gd1 91.455(17) 7_556 7_546
Ge1 Ge1 Gd2 67.099(17) 5_556 3_445
Mn Ge1 Gd2 70.044(17) . 3_445
In Ge1 Gd2 134.022(9) 1_556 3_445
Gd1 Ge1 Gd2 146.20(2) 7_556 3_445
Gd1 Ge1 Gd2 79.976(9) 7_546 3_445
Ge1 Ge1 Gd2 67.099(17) 5_556 3_455
Mn Ge1 Gd2 70.044(17) . 3_455
In Ge1 Gd2 134.022(9) 1_556 3_455
Gd1 Ge1 Gd2 79.976(9) 7_556 3_455
Gd1 Ge1 Gd2 146.20(2) 7_546 3_455
Gd2 Ge1 Gd2 89.152(16) 3_445 3_455
Ge1 Ge1 Gd2 63.588(17) 5_556 7_546
Mn Ge1 Gd2 136.182(9) . 7_546
In Ge1 Gd2 67.150(11) 1_556 7_546
Gd1 Ge1 Gd2 137.56(2) 7_556 7_546
Gd1 Ge1 Gd2 76.157(9) 7_546 7_546
Gd2 Ge1 Gd2 72.185(10) 3_445 7_546
Gd2 Ge1 Gd2 130.686(19) 3_455 7_546
Ge1 Ge1 Gd2 63.588(17) 5_556 7_556
Mn Ge1 Gd2 136.182(9) . 7_556
In Ge1 Gd2 67.150(11) 1_556 7_556
Gd1 Ge1 Gd2 76.157(9) 7_556 7_556
Gd1 Ge1 Gd2 137.56(2) 7_546 7_556
Gd2 Ge1 Gd2 130.686(19) 3_445 7_556
Gd2 Ge1 Gd2 72.185(10) 3_455 7_556
Gd2 Ge1 Gd2 86.060(16) 7_546 7_556
Mn Ge2 Mn 111.26(4) 7_556 7_546
Mn Ge2 Mn 71.92(2) 7_556 .
Mn Ge2 Mn 71.92(2) 7_546 .
Mn Ge2 Gd1 75.39(2) 7_556 .
Mn Ge2 Gd1 75.39(2) 7_546 .
Mn Ge2 Gd1 120.10(3) . .
Mn Ge2 Gd1 147.10(3) 7_556 7_545
Mn Ge2 Gd1 71.950(18) 7_546 7_545
Mn Ge2 Gd1 135.367(9) . 7_545
Gd1 Ge2 Gd1 73.973(13) . 7_545
Mn Ge2 Gd1 71.950(18) 7_556 7
Mn Ge2 Gd1 147.10(3) 7_546 7
Mn Ge2 Gd1 135.367(9) . 7
Gd1 Ge2 Gd1 73.973(13) . 7
Gd1 Ge2 Gd1 88.267(16) 7_545 7
Mn Ge2 Gd2 138.95(3) 7_556 3_445
Mn Ge2 Gd2 67.416(18) 7_546 3_445
Mn Ge2 Gd2 68.943(17) . 3_445
Gd1 Ge2 Gd2 136.413(8) . 3_445
Gd1 Ge2 Gd2 73.554(9) 7_545 3_445
Gd1 Ge2 Gd2 132.61(2) 7 3_445
Mn Ge2 Gd2 67.416(18) 7_556 3_455
Mn Ge2 Gd2 138.95(3) 7_546 3_455
Mn Ge2 Gd2 68.943(17) . 3_455
Gd1 Ge2 Gd2 136.413(8) . 3_455
Gd1 Ge2 Gd2 132.61(2) 7_545 3_455
Gd1 Ge2 Gd2 73.554(9) 7 3_455
Gd2 Ge2 Gd2 87.173(16) 3_445 3_455
Mn Ge2 In 123.989(19) 7_556 .
Mn Ge2 In 123.988(19) 7_546 .
Mn Ge2 In 115.35(3) . .
Gd1 Ge2 In 124.56(2) . .
Gd1 Ge2 In 67.107(12) 7_545 .
Gd1 Ge2 In 67.107(12) 7 .
Gd2 Ge2 In 65.508(12) 3_445 .
Gd2 Ge2 In 65.508(12) 3_455 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 Ge1 2.9582(4) 7_556
Gd1 Ge1 2.9582(4) 7_546
Gd1 Ge2 3.0140(6) .
Gd1 Ge2 3.0418(4) 7_545
Gd1 Ge2 3.0418(4) 7
Gd1 Mn 3.3167(9) 1_554
Gd1 In 3.3944(2) 3
Gd1 In 3.3944(2) 3_545
Gd1 Mn 3.4302(6) 7_556
Gd1 Mn 3.4302(6) 7_546
Gd1 Gd1 3.6434(4) 7_545
Gd1 Gd1 3.6434(4) 7
Gd2 Ge1 3.0179(4) 3
Gd2 Ge1 3.0179(4) 3_545
Gd2 Ge2 3.0723(4) 3
Gd2 Ge2 3.0723(4) 3_545
Gd2 Ge1 3.1041(5) 7_546
Gd2 Ge1 3.1041(5) 7_556
Gd2 Mn 3.1573(9) 5_656
Gd2 Mn 3.2336(7) 3
Gd2 Mn 3.2336(7) 3_545
Gd2 In 3.3388(2) 3_545
Gd2 In 3.3388(2) 3
Gd2 Gd2 3.6071(5) 5_656
Mn Ge2 2.5662(6) 7_556
Mn Ge2 2.5662(6) 7_546
Mn Ge1 2.5822(10) .
Mn Ge2 2.5992(10) .
Mn Mn 3.0332(11) 7_546
Mn Mn 3.0332(11) 7_556
Mn Gd2 3.1573(9) 5_656
Mn Gd2 3.2336(7) 3_445
Mn Gd2 3.2336(7) 3_455
Mn Gd1 3.3167(9) 1_556
Mn Gd1 3.4303(6) 7_556
Mn Gd1 3.4303(6) 7_546
In Ge1 2.9274(6) 5_556
In Ge1 2.9274(6) 1_554
In Ge2 3.0988(6) .
In Ge2 3.0988(6) 5
In Gd2 3.3388(2) 7_545
In Gd2 3.3388(2) 3_455
In Gd2 3.3388(2) 7
In Gd2 3.3388(2) 3_445
In Gd1 3.3944(2) 3_445
In Gd1 3.3944(2) 7
In Gd1 3.3944(2) 7_545
In Gd1 3.3944(2) 3_455
Ge1 Ge1 2.5552(11) 5_556
Ge1 In 2.9274(6) 1_556
Ge1 Gd1 2.9582(4) 7_556
Ge1 Gd1 2.9582(4) 7_546
Ge1 Gd2 3.0179(4) 3_445
Ge1 Gd2 3.0179(4) 3_455
Ge1 Gd2 3.1041(5) 7_546
Ge1 Gd2 3.1041(5) 7_556
Ge2 Mn 2.5662(6) 7_556
Ge2 Mn 2.5662(6) 7_546
Ge2 Gd1 3.0419(4) 7_545
Ge2 Gd1 3.0419(4) 7
Ge2 Gd2 3.0722(4) 3_445
Ge2 Gd2 3.0722(4) 3_455
