#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:51:50 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179458 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/55/4335507.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4335507
loop_
_publ_author_name
'Anton O. Oliynyk'
'Stanislav S. Stoyko'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Quaternary Germanides RE4Mn2InGe4 (RE = La-Nd, Sm, Gd-Tm, Lu)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8264
_journal_page_last               8271
_journal_paper_doi               10.1021/ic401171v
_journal_volume                  52
_journal_year                    2013
_chemical_formula_structural     'La4 Mn2 In0.94 Ge4'
_chemical_formula_sum            'Ge4 In0.94 La4 Mn2'
_chemical_formula_weight         1064.38
_chemical_name_common
'lanthanum manganese indium germanide (4/2/1/4)'
_chemical_name_systematic
'lanthanum manganese indium germanide (4/2/1/4)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.893(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.646(2)
_cell_length_b                   4.4190(6)
_cell_length_c                   7.4834(10)
_cell_measurement_reflns_used    2807
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.68
_cell_measurement_theta_min      4.35
_cell_volume                     526.72(12)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0282
_diffrn_reflns_av_sigmaI/netI    0.0261
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            3733
_diffrn_reflns_theta_full        33.24
_diffrn_reflns_theta_max         33.24
_diffrn_reflns_theta_min         2.56
_exptl_absorpt_coefficient_mu    31.319
_exptl_absorpt_correction_T_max  0.4843
_exptl_absorpt_correction_T_min  0.1674
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    6.711
_exptl_crystal_description       irregular
_exptl_crystal_F_000             905
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.927
_refine_diff_density_min         -1.125
_refine_diff_density_rms         0.293
_refine_ls_extinction_coef       0.00191(9)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         1099
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.0234
_refine_ls_R_factor_gt           0.0195
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0184P)²+0.1024P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0406
_refine_ls_wR_factor_ref         0.0417
_reflns_number_gt                989
_reflns_number_total             1099
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic401171v_si_002_2.cif
_cod_data_source_block           La4Mn2InGe4
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               4335507
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
La1 La 0.348689(16) 0.0000 0.07052(4) 0.00745(8) Uani 1 2 d S
La2 La 0.582519(16) 0.0000 0.36528(4) 0.00731(8) Uani 1 2 d S
Mn Mn 0.21679(4) 0.0000 0.62018(10) 0.00832(14) Uani 1 2 d S
In In 0.0000 0.0000 0.0000 0.01069(15) Uani 0.945(2) 4 d SP
Ge1 Ge 0.06228(3) 0.0000 0.64873(7) 0.00788(11) Uani 1 2 d S
Ge2 Ge 0.20235(3) 0.0000 0.25755(8) 0.00888(11) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 La1 Ge1 90.479(18) 7_556 7_546
Ge1 La1 Ge2 88.742(15) 7_556 .
Ge1 La1 Ge2 88.742(15) 7_546 .
Ge1 La1 Ge2 165.476(16) 7_556 7_545
Ge1 La1 Ge2 89.767(14) 7_546 7_545
Ge2 La1 Ge2 105.782(13) . 7_545
Ge1 La1 Ge2 89.767(14) 7_556 7
Ge1 La1 Ge2 165.476(16) 7_546 7
Ge2 La1 Ge2 105.782(13) . 7
Ge2 La1 Ge2 86.396(18) 7_545 7
Ge1 La1 Mn 134.694(9) 7_556 1_554
Ge1 La1 Mn 134.694(9) 7_546 1_554
Ge2 La1 Mn 94.56(2) . 1_554
Ge2 La1 Mn 45.907(10) 7_545 1_554
Ge2 La1 Mn 45.907(10) 7 1_554
Ge1 La1 In 55.371(12) 7_556 3
Ge1 La1 In 109.103(14) 7_546 3
Ge2 La1 In 138.704(7) . 3
Ge2 La1 In 111.037(13) 7_545 3
Ge2 La1 In 59.713(11) 7 3
Mn La1 In 97.720(13) 1_554 3
Ge1 La1 In 109.103(14) 7_556 3_545
Ge1 La1 In 55.371(12) 7_546 3_545
Ge2 La1 In 138.704(7) . 3_545
Ge2 La1 In 59.713(11) 7_545 3_545
Ge2 La1 In 111.037(13) 7 3_545
Mn La1 In 97.720(13) 1_554 3_545
In La1 In 78.188(12) 3 3_545
Ge1 La1 Mn 45.739(16) 7_556 7_556
Ge1 La1 Mn 100.132(17) 7_546 7_556
Ge2 La1 Mn 45.017(11) . 7_556
Ge2 La1 Mn 148.144(17) 7_545 7_556
Ge2 La1 Mn 90.399(15) 7 7_556
Mn La1 Mn 113.820(16) 1_554 7_556
In La1 Mn 94.311(12) 3 7_556
In La1 Mn 148.346(14) 3_545 7_556
Ge1 La1 Mn 100.132(17) 7_556 7_546
Ge1 La1 Mn 45.739(16) 7_546 7_546
Ge2 La1 Mn 45.017(11) . 7_546
Ge2 La1 Mn 90.399(15) 7_545 7_546
Ge2 La1 Mn 148.144(17) 7 7_546
Mn La1 Mn 113.820(16) 1_554 7_546
In La1 Mn 148.346(14) 3 7_546
In La1 Mn 94.311(12) 3_545 7_546
Mn La1 Mn 75.953(18) 7_556 7_546
Ge1 La1 La2 112.367(13) 7_556 5_655
Ge1 La1 La2 112.367(13) 7_546 5_655
Ge2 La1 La2 149.074(14) . 5_655
Ge2 La1 La2 54.485(11) 7_545 5_655
Ge2 La1 La2 54.485(11) 7 5_655
Mn La1 La2 54.516(16) 1_554 5_655
In La1 La2 57.012(6) 3 5_655
In La1 La2 57.012(6) 3_545 5_655
Mn La1 La2 141.781(9) 7_556 5_655
Mn La1 La2 141.781(9) 7_546 5_655
Ge1 La1 La1 142.650(15) 7_556 7_545
Ge1 La1 La1 88.776(12) 7_546 7_545
Ge2 La1 La1 53.908(12) . 7_545
Ge2 La1 La1 51.874(11) 7_545 7_545
Ge2 La1 La1 99.762(15) 7 7_545
Mn La1 La1 58.712(12) 1_554 7_545
In La1 La1 156.293(13) 3 7_545
In La1 La1 100.991(11) 3_545 7_545
Mn La1 La1 97.781(16) 7_556 7_545
Mn La1 La1 55.108(14) 7_546 7_545
La2 La1 La1 102.324(11) 5_655 7_545
Ge1 La2 Ge1 89.153(18) 3 3_545
Ge1 La2 Ge2 83.277(13) 3 3
Ge1 La2 Ge2 147.412(16) 3_545 3
Ge1 La2 Ge2 147.412(16) 3 3_545
Ge1 La2 Ge2 83.277(13) 3_545 3_545
Ge2 La2 Ge2 86.257(17) 3 3_545
Ge1 La2 Ge1 105.986(12) 3 7_546
Ge1 La2 Ge1 47.217(17) 3_545 7_546
Ge2 La2 Ge1 164.311(17) 3 7_546
Ge2 La2 Ge1 91.886(14) 3_545 7_546
Ge1 La2 Ge1 47.217(17) 3 7_556
Ge1 La2 Ge1 105.986(12) 3_545 7_556
Ge2 La2 Ge1 91.886(14) 3 7_556
Ge2 La2 Ge1 164.311(17) 3_545 7_556
Ge1 La2 Ge1 85.698(17) 7_546 7_556
Ge1 La2 Mn 106.403(15) 3 5_656
Ge1 La2 Mn 106.403(14) 3_545 5_656
Ge2 La2 Mn 47.012(11) 3 5_656
Ge2 La2 Mn 47.012(11) 3_545 5_656
Ge1 La2 Mn 137.147(9) 7_546 5_656
Ge1 La2 Mn 137.147(9) 7_556 5_656
Ge1 La2 Mn 48.104(16) 3 3
Ge1 La2 Mn 105.412(17) 3_545 3
Ge2 La2 Mn 47.746(17) 3 3
Ge2 La2 Mn 103.703(18) 3_545 3
Ge1 La2 Mn 147.118(18) 7_546 3
Ge1 La2 Mn 86.287(15) 7_556 3
Mn La2 Mn 58.473(17) 5_656 3
Ge1 La2 Mn 105.412(17) 3 3_545
Ge1 La2 Mn 48.104(16) 3_545 3_545
Ge2 La2 Mn 103.703(18) 3 3_545
Ge2 La2 Mn 47.746(17) 3_545 3_545
Ge1 La2 Mn 86.287(16) 7_546 3_545
Ge1 La2 Mn 147.118(18) 7_556 3_545
Mn La2 Mn 58.473(17) 5_656 3_545
Mn La2 Mn 83.37(2) 3 3_545
Ge1 La2 In 151.846(13) 3 3_545
Ge1 La2 In 89.343(13) 3_545 3_545
Ge2 La2 In 111.731(14) 3 3_545
Ge2 La2 In 60.019(12) 3_545 3_545
Ge1 La2 In 54.678(11) 7_546 3_545
Ge1 La2 In 106.693(13) 7_556 3_545
Mn La2 In 100.978(12) 5_656 3_545
Mn La2 In 157.122(15) 3 3_545
Mn La2 In 94.303(13) 3_545 3_545
Ge1 La2 In 89.343(13) 3 3
Ge1 La2 In 151.846(14) 3_545 3
Ge2 La2 In 60.019(12) 3 3
Ge2 La2 In 111.731(14) 3_545 3
Ge1 La2 In 106.693(13) 7_546 3
Ge1 La2 In 54.678(11) 7_556 3
Mn La2 In 100.978(12) 5_656 3
Mn La2 In 94.303(13) 3 3
Mn La2 In 157.122(15) 3_545 3
In La2 In 79.029(12) 3_545 3
Ge1 La2 La1 134.760(9) 3 5_655
Ge1 La2 La1 134.760(9) 3_545 5_655
Ge2 La2 La1 54.381(10) 3 5_655
Ge2 La2 La1 54.381(10) 3_545 5_655
Ge1 La2 La1 112.479(12) 7_546 5_655
Ge1 La2 La1 112.479(12) 7_556 5_655
Mn La2 La1 57.954(15) 5_656 5_655
Mn La2 La1 100.049(16) 3 5_655
Mn La2 La1 100.049(16) 3_545 5_655
In La2 La1 57.816(9) 3_545 5_655
In La2 La1 57.816(9) 3 5_655
Ge2 Mn Ge2 115.64(3) 7_556 7_546
Ge2 Mn Ge1 112.74(2) 7_556 .
Ge2 Mn Ge1 112.74(2) 7_546 .
Ge2 Mn Ge2 104.04(2) 7_556 .
Ge2 Mn Ge2 104.04(2) 7_546 .
Ge1 Mn Ge2 106.36(3) . .
Ge2 Mn Mn 123.19(4) 7_556 7_546
Ge2 Mn Mn 52.625(17) 7_546 7_546
Ge1 Mn Mn 122.84(3) . 7_546
Ge2 Mn Mn 51.42(2) . 7_546
Ge2 Mn Mn 52.625(17) 7_556 7_556
Ge2 Mn Mn 123.19(4) 7_546 7_556
Ge1 Mn Mn 122.84(3) . 7_556
Ge2 Mn Mn 51.42(2) . 7_556
Mn Mn Mn 86.00(4) 7_546 7_556
Ge2 Mn La2 64.907(18) 7_556 5_656
Ge2 Mn La2 64.907(18) 7_546 5_656
Ge1 Mn La2 173.76(3) . 5_656
Ge2 Mn La2 79.88(2) . 5_656
Mn Mn La2 60.94(2) 7_546 5_656
Mn Mn La2 60.94(2) 7_556 5_656
Ge2 Mn La2 163.02(3) 7_556 3_445
Ge2 Mn La2 80.252(15) 7_546 3_445
Ge1 Mn La2 62.494(17) . 3_445
Ge2 Mn La2 64.341(17) . 3_445
Mn Mn La2 60.586(19) 7_546 3_445
Mn Mn La2 114.58(3) 7_556 3_445
La2 Mn La2 121.527(17) 5_656 3_445
Ge2 Mn La2 80.252(15) 7_556 3_455
Ge2 Mn La2 163.02(3) 7_546 3_455
Ge1 Mn La2 62.494(17) . 3_455
Ge2 Mn La2 64.341(17) . 3_455
Mn Mn La2 114.58(3) 7_546 3_455
Mn Mn La2 60.586(19) 7_556 3_455
La2 Mn La2 121.527(17) 5_656 3_455
La2 Mn La2 83.37(2) 3_445 3_455
Ge2 Mn La1 62.624(19) 7_556 1_556
Ge2 Mn La1 62.625(19) 7_546 1_556
Ge1 Mn La1 106.23(3) . 1_556
Ge2 Mn La1 147.41(3) . 1_556
Mn Mn La1 108.64(3) 7_546 1_556
Mn Mn La1 108.64(3) 7_556 1_556
La2 Mn La1 67.532(17) 5_656 1_556
La2 Mn La1 133.833(14) 3_445 1_556
La2 Mn La1 133.833(13) 3_455 1_556
Ge2 Mn La1 58.360(16) 7_556 7_556
Ge2 Mn La1 121.13(3) 7_546 7_556
Ge1 Mn La1 57.514(15) . 7_556
Ge2 Mn La1 134.821(17) . 7_556
Mn Mn La1 173.75(3) 7_546 7_556
Mn Mn La1 98.901(15) 7_556 7_556
La2 Mn La1 118.112(18) 5_656 7_556
La2 Mn La1 119.99(2) 3_445 7_556
La2 Mn La1 71.417(14) 3_455 7_556
La1 Mn La1 66.179(16) 1_556 7_556
Ge2 Mn La1 121.13(3) 7_556 7_546
Ge2 Mn La1 58.360(16) 7_546 7_546
Ge1 Mn La1 57.514(15) . 7_546
Ge2 Mn La1 134.821(17) . 7_546
Mn Mn La1 98.901(15) 7_546 7_546
Mn Mn La1 173.75(3) 7_556 7_546
La2 Mn La1 118.112(18) 5_656 7_546
La2 Mn La1 71.417(14) 3_445 7_546
La2 Mn La1 119.99(2) 3_455 7_546
La1 Mn La1 66.179(16) 1_556 7_546
La1 Mn La1 75.953(18) 7_556 7_546
Ge1 In Ge1 180.000(15) 5_556 1_554
Ge1 In La2 121.021(10) 5_556 7_545
Ge1 In La2 58.979(10) 1_554 7_545
Ge1 In La2 58.979(10) 5_556 3_455
Ge1 In La2 121.021(10) 1_554 3_455
La2 In La2 180.000(7) 7_545 3_455
Ge1 In La2 121.021(10) 5_556 7
Ge1 In La2 58.979(10) 1_554 7
La2 In La2 79.029(12) 7_545 7
La2 In La2 100.971(12) 3_455 7
Ge1 In La2 58.979(10) 5_556 3_445
Ge1 In La2 121.021(10) 1_554 3_445
La2 In La2 100.971(12) 7_545 3_445
La2 In La2 79.029(12) 3_455 3_445
La2 In La2 180.000(9) 7 3_445
Ge1 In La1 55.869(8) 5_556 3_445
Ge1 In La1 124.131(8) 1_554 3_445
La2 In La1 65.172(9) 7_545 3_445
La2 In La1 114.828(9) 3_455 3_445
La2 In La1 112.492(9) 7 3_445
La2 In La1 67.508(9) 3_445 3_445
Ge1 In La1 124.131(8) 5_556 7
Ge1 In La1 55.869(8) 1_554 7
La2 In La1 114.828(9) 7_545 7
La2 In La1 65.172(9) 3_455 7
La2 In La1 67.508(9) 7 7
La2 In La1 112.492(9) 3_445 7
La1 In La1 180.000(6) 3_445 7
Ge1 In La1 124.131(8) 5_556 7_545
Ge1 In La1 55.869(8) 1_554 7_545
La2 In La1 67.508(9) 7_545 7_545
La2 In La1 112.492(9) 3_455 7_545
La2 In La1 114.828(9) 7 7_545
La2 In La1 65.172(9) 3_445 7_545
La1 In La1 101.813(12) 3_445 7_545
La1 In La1 78.187(12) 7 7_545
Ge1 In La1 55.869(8) 5_556 3_455
Ge1 In La1 124.131(8) 1_554 3_455
La2 In La1 112.492(9) 7_545 3_455
La2 In La1 67.508(9) 3_455 3_455
La2 In La1 65.172(9) 7 3_455
La2 In La1 114.828(9) 3_445 3_455
La1 In La1 78.187(12) 3_445 3_455
La1 In La1 101.813(12) 7 3_455
La1 In La1 180.000(9) 7_545 3_455
Ge1 Ge1 Mn 119.37(4) 5_556 .
Ge1 Ge1 In 110.59(3) 5_556 1_556
Mn Ge1 In 130.03(3) . 1_556
Ge1 Ge1 La1 133.840(10) 5_556 7_556
Mn Ge1 La1 76.745(17) . 7_556
In Ge1 La1 68.760(13) 1_556 7_556
Ge1 Ge1 La1 133.840(10) 5_556 7_546
Mn Ge1 La1 76.745(17) . 7_546
In Ge1 La1 68.760(13) 1_556 7_546
La1 Ge1 La1 90.479(17) 7_556 7_546
Ge1 Ge1 La2 68.458(18) 5_556 3_445
Mn Ge1 La2 69.401(16) . 3_445
In Ge1 La2 134.469(9) 1_556 3_445
La1 Ge1 La2 146.104(19) 7_556 3_445
La1 Ge1 La2 80.406(13) 7_546 3_445
Ge1 Ge1 La2 68.458(18) 5_556 3_455
Mn Ge1 La2 69.401(16) . 3_455
In Ge1 La2 134.469(9) 1_556 3_455
La1 Ge1 La2 80.406(13) 7_556 3_455
La1 Ge1 La2 146.104(19) 7_546 3_455
La2 Ge1 La2 89.153(18) 3_445 3_455
Ge1 Ge1 La2 64.325(16) 5_556 7_546
Mn Ge1 La2 136.711(9) . 7_546
In Ge1 La2 66.343(11) 1_556 7_546
La1 Ge1 La2 135.074(19) 7_556 7_546
La1 Ge1 La2 75.063(12) 7_546 7_546
La2 Ge1 La2 74.014(12) 3_445 7_546
La2 Ge1 La2 132.783(17) 3_455 7_546
Ge1 Ge1 La2 64.325(16) 5_556 7_556
Mn Ge1 La2 136.711(9) . 7_556
In Ge1 La2 66.343(11) 1_556 7_556
La1 Ge1 La2 75.063(12) 7_556 7_556
La1 Ge1 La2 135.074(19) 7_546 7_556
La2 Ge1 La2 132.783(17) 3_445 7_556
La2 Ge1 La2 74.014(12) 3_455 7_556
La2 Ge1 La2 85.699(17) 7_546 7_556
Mn Ge2 Mn 115.63(3) 7_556 7_546
Mn Ge2 Mn 75.96(2) 7_556 .
Mn Ge2 Mn 75.96(2) 7_546 .
Mn Ge2 La1 76.62(2) 7_556 .
Mn Ge2 La1 76.62(2) 7_546 .
Mn Ge2 La1 127.15(3) . .
Mn Ge2 La1 147.23(3) 7_556 7_545
Mn Ge2 La1 71.469(18) 7_546 7_545
Mn Ge2 La1 134.697(11) . 7_545
La1 Ge2 La1 74.216(13) . 7_545
Mn Ge2 La1 71.469(18) 7_556 7
Mn Ge2 La1 147.23(3) 7_546 7
Mn Ge2 La1 134.697(11) . 7
La1 Ge2 La1 74.216(13) . 7
La1 Ge2 La1 86.396(19) 7_545 7
Mn Ge2 La2 141.62(3) 7_556 3_445
Mn Ge2 La2 68.082(18) 7_546 3_445
Mn Ge2 La2 67.913(15) . 3_445
La1 Ge2 La2 136.521(9) . 3_445
La1 Ge2 La2 71.134(12) 7_545 3_445
La1 Ge2 La2 127.777(19) 7 3_445
Mn Ge2 La2 68.082(18) 7_556 3_455
Mn Ge2 La2 141.62(3) 7_546 3_455
Mn Ge2 La2 67.913(15) . 3_455
La1 Ge2 La2 136.521(9) . 3_455
La1 Ge2 La2 127.777(19) 7_545 3_455
La1 Ge2 La2 71.134(12) 7 3_455
La2 Ge2 La2 86.259(17) 3_445 3_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
La1 Ge1 3.1117(5) 7_556
La1 Ge1 3.1117(5) 7_546
La1 Ge2 3.1423(7) .
La1 Ge2 3.2278(5) 7_545
La1 Ge2 3.2278(5) 7
La1 Mn 3.4465(9) 1_554
La1 In 3.5038(4) 3
La1 In 3.5038(4) 3_545
La1 Mn 3.5907(7) 7_556
La1 Mn 3.5907(7) 7_546
La1 La2 3.7573(6) 5_655
La1 La1 3.8438(6) 7_545
La2 Ge1 3.1481(5) 3
La2 Ge1 3.1481(5) 3_545
La2 Ge2 3.2320(5) 3
La2 Ge2 3.2320(5) 3_545
La2 Ge1 3.2489(5) 7_546
La2 Ge1 3.2489(5) 7_556
La2 Mn 3.3109(9) 5_656
La2 Mn 3.3223(6) 3
La2 Mn 3.3223(6) 3_545
La2 In 3.4726(4) 3_545
La2 In 3.4726(4) 3
La2 La1 3.7574(6) 5_655
Mn Ge2 2.6106(6) 7_556
Mn Ge2 2.6106(6) 7_546
Mn Ge1 2.6420(9) .
Mn Ge2 2.6539(10) .
Mn Mn 3.2398(11) 7_546
Mn Mn 3.2398(11) 7_556
Mn La2 3.3108(9) 5_656
Mn La2 3.3224(6) 3_445
Mn La2 3.3224(6) 3_455
Mn La1 3.4464(9) 1_556
Mn La1 3.5907(7) 7_556
Mn La1 3.5907(7) 7_546
In Ge1 3.0933(6) 5_556
In Ge1 3.0933(6) 1_554
In La2 3.4726(4) 7_545
In La2 3.4726(4) 3_455
In La2 3.4726(4) 7
In La2 3.4726(4) 3_445
In La1 3.5039(4) 3_445
In La1 3.5039(4) 7
In La1 3.5039(4) 7_545
In La1 3.5039(4) 3_455
Ge1 Ge1 2.5636(10) 5_556
Ge1 In 3.0933(6) 1_556
Ge1 La1 3.1117(5) 7_556
Ge1 La1 3.1117(5) 7_546
Ge1 La2 3.1481(5) 3_445
Ge1 La2 3.1481(5) 3_455
Ge1 La2 3.2489(5) 7_546
Ge1 La2 3.2489(5) 7_556
Ge2 Mn 2.6106(6) 7_556
Ge2 Mn 2.6106(6) 7_546
Ge2 La1 3.2278(5) 7_545
Ge2 La1 3.2278(5) 7
Ge2 La2 3.2319(5) 3_445
Ge2 La2 3.2319(5) 3_455
