#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:51:50 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179458 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/55/4335508.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4335508
loop_
_publ_author_name
'Anton O. Oliynyk'
'Stanislav S. Stoyko'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Quaternary Germanides RE4Mn2InGe4 (RE = La-Nd, Sm, Gd-Tm, Lu)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8264
_journal_page_last               8271
_journal_paper_doi               10.1021/ic401171v
_journal_volume                  52
_journal_year                    2013
_chemical_formula_structural     'Ce4 Mn2 In0.92 Ge4'
_chemical_formula_sum            'Ce4 Ge4 In0.92 Mn2'
_chemical_formula_weight         1066.93
_chemical_name_common            'cerium manganese indium germanide (4/2/1/4)'
_chemical_name_systematic        'cerium manganese indium germanide (4/2/1/4)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.6390(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.4357(6)
_cell_length_b                   4.3652(2)
_cell_length_c                   7.3742(3)
_cell_measurement_reflns_used    5074
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      33.02
_cell_measurement_theta_min      2.59
_cell_volume                     506.91(4)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0182
_diffrn_reflns_av_sigmaI/netI    0.0169
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            3628
_diffrn_reflns_theta_full        33.18
_diffrn_reflns_theta_max         33.18
_diffrn_reflns_theta_min         2.59
_exptl_absorpt_coefficient_mu    33.603
_exptl_absorpt_correction_T_max  0.3092
_exptl_absorpt_correction_T_min  0.0670
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    6.990
_exptl_crystal_description       irregular
_exptl_crystal_F_000             911
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.684
_refine_diff_density_min         -1.253
_refine_diff_density_rms         0.269
_refine_ls_extinction_coef       0.00246(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.164
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         1063
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.164
_refine_ls_R_factor_all          0.0176
_refine_ls_R_factor_gt           0.0166
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0181P)²+1.4038P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0379
_refine_ls_wR_factor_ref         0.0383
_reflns_number_gt                1028
_reflns_number_total             1063
_reflns_threshold_expression     I>2σ(I)'
_cod_data_source_file            ic401171v_si_002_3.cif
_cod_data_source_block           Ce4Mn2InGe4
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               4335508
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ce1 Ce 0.348557(13) 0.0000 0.07032(3) 0.00654(7) Uani 1 2 d S
Ce2 Ce 0.582114(13) 0.0000 0.36473(3) 0.00655(7) Uani 1 2 d S
Mn Mn 0.21744(4) 0.0000 0.61982(8) 0.00707(11) Uani 1 2 d S
In In 0.0000 0.0000 0.0000 0.00922(13) Uani 0.927(2) 4 d SP
Ge1 Ge 0.06276(2) 0.0000 0.65019(6) 0.00674(9) Uani 1 2 d S
Ge2 Ge 0.20111(3) 0.0000 0.25494(6) 0.00825(9) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ce Ce -0.2486 2.6331 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Ce1 Ge1 90.681(12) 7_556 7_546
Ge1 Ce1 Ge2 89.183(11) 7_556 .
Ge1 Ce1 Ge2 89.183(11) 7_546 .
Ge1 Ce1 Ge2 165.287(14) 7_556 7_545
Ge1 Ce1 Ge2 89.333(9) 7_546 7_545
Ge2 Ce1 Ge2 105.528(10) . 7_545
Ge1 Ce1 Ge2 89.333(9) 7_556 7
Ge1 Ce1 Ge2 165.287(14) 7_546 7
Ge2 Ce1 Ge2 105.528(10) . 7
Ge2 Ce1 Ge2 86.956(12) 7_545 7
Ge1 Ce1 Mn 134.582(6) 7_556 1_554
Ge1 Ce1 Mn 134.582(6) 7_546 1_554
Ge2 Ce1 Mn 94.158(14) . 1_554
Ge2 Ce1 Mn 46.204(7) 7_545 1_554
Ge2 Ce1 Mn 46.204(7) 7 1_554
Ge1 Ce1 In 55.119(8) 7_556 3
Ge1 Ce1 In 109.006(9) 7_546 3
Ge2 Ce1 In 138.774(4) . 3
Ge2 Ce1 In 111.174(9) 7_545 3
Ge2 Ce1 In 59.533(8) 7 3
Mn Ce1 In 97.781(9) 1_554 3
Ge1 Ce1 In 109.006(9) 7_556 3_545
Ge1 Ce1 In 55.119(8) 7_546 3_545
Ge2 Ce1 In 138.774(4) . 3_545
Ge2 Ce1 In 59.533(8) 7_545 3_545
Ge2 Ce1 In 111.174(9) 7 3_545
Mn Ce1 In 97.781(9) 1_554 3_545
In Ce1 In 78.237(5) 3 3_545
Ge1 Ce1 Mn 45.867(11) 7_556 7_556
Ge1 Ce1 Mn 100.316(12) 7_546 7_556
Ge2 Ce1 Mn 45.217(9) . 7_556
Ge2 Ce1 Mn 148.274(14) 7_545 7_556
Ge2 Ce1 Mn 90.215(10) 7 7_556
Mn Ce1 Mn 113.821(11) 1_554 7_556
In Ce1 Mn 94.255(8) 3 7_556
In Ce1 Mn 148.287(11) 3_545 7_556
Ge1 Ce1 Mn 100.316(12) 7_556 7_546
Ge1 Ce1 Mn 45.867(11) 7_546 7_546
Ge2 Ce1 Mn 45.217(9) . 7_546
Ge2 Ce1 Mn 90.215(10) 7_545 7_546
Ge2 Ce1 Mn 148.274(14) 7 7_546
Mn Ce1 Mn 113.821(11) 1_554 7_546
In Ce1 Mn 148.287(11) 3 7_546
In Ce1 Mn 94.255(8) 3_545 7_546
Mn Ce1 Mn 75.955(13) 7_556 7_546
Ge1 Ce1 Ce2 112.177(9) 7_556 5_655
Ge1 Ce1 Ce2 112.177(9) 7_546 5_655
Ge2 Ce1 Ce2 148.680(10) . 5_655
Ge2 Ce1 Ce2 54.599(8) 7_545 5_655
Ge2 Ce1 Ce2 54.599(8) 7 5_655
Mn Ce1 Ce2 54.522(11) 1_554 5_655
In Ce1 Ce2 57.076(4) 3 5_655
In Ce1 Ce2 57.076(4) 3_545 5_655
Mn Ce1 Ce2 141.781(6) 7_556 5_655
Mn Ce1 Ce2 141.781(6) 7_546 5_655
Ge1 Ce1 Ce1 142.801(12) 7_556 7_545
Ge1 Ce1 Ce1 88.775(7) 7_546 7_545
Ge2 Ce1 Ce1 53.618(8) . 7_545
Ge2 Ce1 Ce1 51.910(9) 7_545 7_545
Ge2 Ce1 Ce1 100.039(10) 7 7_545
Mn Ce1 Ce1 58.731(9) 1_554 7_545
In Ce1 Ce1 156.375(9) 3 7_545
In Ce1 Ce1 100.993(4) 3_545 7_545
Mn Ce1 Ce1 97.776(11) 7_556 7_545
Mn Ce1 Ce1 55.090(10) 7_546 7_545
Ce2 Ce1 Ce1 102.344(7) 5_655 7_545
Ge1 Ce2 Ge1 89.099(12) 3 3_545
Ge1 Ce2 Ge2 83.135(9) 3 3
Ge1 Ce2 Ge2 147.312(13) 3_545 3
Ge1 Ce2 Ge2 147.312(13) 3 3_545
Ge1 Ce2 Ge2 83.135(9) 3_545 3_545
Ge2 Ce2 Ge2 86.478(12) 3 3_545
Ge1 Ce2 Ge1 106.365(8) 3 7_546
Ge1 Ce2 Ge1 47.729(13) 3_545 7_546
Ge2 Ce2 Ge1 163.899(13) 3 7_546
Ge2 Ce2 Ge1 91.651(9) 3_545 7_546
Ge1 Ce2 Ge1 47.729(13) 3 7_556
Ge1 Ce2 Ge1 106.365(8) 3_545 7_556
Ge2 Ce2 Ge1 91.651(9) 3 7_556
Ge2 Ce2 Ge1 163.899(13) 3_545 7_556
Ge1 Ce2 Ge1 85.722(11) 7_546 7_556
Ge1 Ce2 Mn 105.910(11) 3 5_656
Ge1 Ce2 Mn 105.911(11) 3_545 5_656
Ge2 Ce2 Mn 47.305(8) 3 5_656
Ge2 Ce2 Mn 47.305(8) 3_545 5_656
Ge1 Ce2 Mn 137.135(6) 7_546 5_656
Ge1 Ce2 Mn 137.135(6) 7_556 5_656
Ge1 Ce2 Mn 48.086(12) 3 3
Ge1 Ce2 Mn 105.160(12) 3_545 3
Ge2 Ce2 Mn 47.783(12) 3 3
Ge2 Ce2 Mn 103.637(13) 3_545 3
Ge1 Ce2 Mn 147.487(14) 7_546 3
Ge1 Ce2 Mn 86.673(10) 7_556 3
Mn Ce2 Mn 58.020(14) 5_656 3
Ge1 Ce2 Mn 105.160(12) 3 3_545
Ge1 Ce2 Mn 48.086(12) 3_545 3_545
Ge2 Ce2 Mn 103.637(12) 3 3_545
Ge2 Ce2 Mn 47.783(12) 3_545 3_545
Ge1 Ce2 Mn 86.673(10) 7_546 3_545
Ge1 Ce2 Mn 147.487(14) 7_556 3_545
Mn Ce2 Mn 58.020(14) 5_656 3_545
Mn Ce2 Mn 82.984(14) 3 3_545
Ge1 Ce2 In 152.174(10) 3 3_545
Ge1 Ce2 In 89.464(7) 3_545 3_545
Ge2 Ce2 In 111.678(9) 3 3_545
Ge2 Ce2 In 59.778(8) 3_545 3_545
Ge1 Ce2 In 54.420(7) 7_546 3_545
Ge1 Ce2 In 106.544(8) 7_556 3_545
Mn Ce2 In 101.196(9) 5_656 3_545
Mn Ce2 In 156.928(12) 3 3_545
Mn Ce2 In 94.357(8) 3_545 3_545
Ge1 Ce2 In 89.464(7) 3 3
Ge1 Ce2 In 152.174(10) 3_545 3
Ge2 Ce2 In 59.778(8) 3 3
Ge2 Ce2 In 111.678(9) 3_545 3
Ge1 Ce2 In 106.544(8) 7_546 3
Ge1 Ce2 In 54.420(7) 7_556 3
Mn Ce2 In 101.196(9) 5_656 3
Mn Ce2 In 94.357(8) 3 3
Mn Ce2 In 156.928(12) 3_545 3
In Ce2 In 79.136(5) 3_545 3
Ge1 Ce2 Ce1 134.696(6) 3 5_655
Ge1 Ce2 Ce1 134.696(6) 3_545 5_655
Ge2 Ce2 Ce1 54.246(7) 3 5_655
Ge2 Ce2 Ce1 54.246(7) 3_545 5_655
Ge1 Ce2 Ce1 112.341(9) 7_546 5_655
Ge1 Ce2 Ce1 112.341(9) 7_556 5_655
Mn Ce2 Ce1 58.112(11) 5_656 5_655
Mn Ce2 Ce1 99.786(11) 3 5_655
Mn Ce2 Ce1 99.786(11) 3_545 5_655
In Ce2 Ce1 57.937(4) 3_545 5_655
In Ce2 Ce1 57.937(4) 3 5_655
Ge2 Mn Ge2 114.95(3) 7_556 7_546
Ge2 Mn Ge1 112.679(17) 7_556 .
Ge2 Mn Ge1 112.679(17) 7_546 .
Ge2 Mn Ge2 104.843(18) 7_556 .
Ge2 Mn Ge2 104.843(18) 7_546 .
Ge1 Mn Ge2 105.73(2) . .
Ge2 Mn Mn 123.70(3) 7_556 7_546
Ge2 Mn Mn 52.963(13) 7_546 7_546
Ge1 Mn Mn 122.52(2) . 7_546
Ge2 Mn Mn 51.881(17) . 7_546
Ge2 Mn Mn 52.963(13) 7_556 7_556
Ge2 Mn Mn 123.70(3) 7_546 7_556
Ge1 Mn Mn 122.52(2) . 7_556
Ge2 Mn Mn 51.881(17) . 7_556
Mn Mn Mn 86.67(3) 7_546 7_556
Ge2 Mn Ce2 64.772(15) 7_556 5_656
Ge2 Mn Ce2 64.772(15) 7_546 5_656
Ge1 Mn Ce2 173.38(2) . 5_656
Ge2 Mn Ce2 80.897(18) . 5_656
Mn Mn Ce2 61.474(19) 7_546 5_656
Mn Mn Ce2 61.474(19) 7_556 5_656
Ge2 Mn Ce2 163.32(2) 7_556 3_445
Ge2 Mn Ce2 80.835(10) 7_546 3_445
Ge1 Mn Ce2 62.290(12) . 3_445
Ge2 Mn Ce2 63.946(13) . 3_445
Mn Mn Ce2 60.506(14) 7_546 3_445
Mn Mn Ce2 114.64(3) 7_556 3_445
Ce2 Mn Ce2 121.980(14) 5_656 3_445
Ge2 Mn Ce2 80.835(10) 7_556 3_455
Ge2 Mn Ce2 163.32(2) 7_546 3_455
Ge1 Mn Ce2 62.290(12) . 3_455
Ge2 Mn Ce2 63.946(13) . 3_455
Mn Mn Ce2 114.64(3) 7_546 3_455
Mn Mn Ce2 60.506(14) 7_556 3_455
Ce2 Mn Ce2 121.980(14) 5_656 3_455
Ce2 Mn Ce2 82.984(14) 3_445 3_455
Ge2 Mn Ce1 62.191(14) 7_556 1_556
Ge2 Mn Ce1 62.191(14) 7_546 1_556
Ge1 Mn Ce1 106.01(2) . 1_556
Ge2 Mn Ce1 148.26(2) . 1_556
Mn Mn Ce1 108.82(2) 7_546 1_556
Mn Mn Ce1 108.82(2) 7_556 1_556
Ce2 Mn Ce1 67.366(12) 5_656 1_556
Ce2 Mn Ce1 133.846(10) 3_445 1_556
Ce2 Mn Ce1 133.846(10) 3_455 1_556
Ge2 Mn Ce1 58.240(12) 7_556 7_556
Ge2 Mn Ce1 120.75(2) 7_546 7_556
Ge1 Mn Ce1 57.367(12) . 7_556
Ge2 Mn Ce1 134.392(13) . 7_556
Mn Mn Ce1 173.65(2) 7_546 7_556
Mn Mn Ce1 98.587(10) 7_556 7_556
Ce2 Mn Ce1 117.992(14) 5_656 7_556
Ce2 Mn Ce1 119.640(18) 3_445 7_556
Ce2 Mn Ce1 71.288(9) 3_455 7_556
Ce1 Mn Ce1 66.179(11) 1_556 7_556
Ge2 Mn Ce1 120.75(2) 7_556 7_546
Ge2 Mn Ce1 58.240(12) 7_546 7_546
Ge1 Mn Ce1 57.367(12) . 7_546
Ge2 Mn Ce1 134.392(13) . 7_546
Mn Mn Ce1 98.587(10) 7_546 7_546
Mn Mn Ce1 173.65(2) 7_556 7_546
Ce2 Mn Ce1 117.992(14) 5_656 7_546
Ce2 Mn Ce1 71.288(9) 3_445 7_546
Ce2 Mn Ce1 119.640(18) 3_455 7_546
Ce1 Mn Ce1 66.179(11) 1_556 7_546
Ce1 Mn Ce1 75.956(13) 7_556 7_546
Ge1 In Ge1 180.000(13) 5_556 1_554
Ge1 In Ce2 120.861(6) 5_556 7_545
Ge1 In Ce2 59.139(6) 1_554 7_545
Ge1 In Ce2 59.139(6) 5_556 3_455
Ge1 In Ce2 120.861(6) 1_554 3_455
Ce2 In Ce2 180.000(8) 7_545 3_455
Ge1 In Ce2 120.861(6) 5_556 7
Ge1 In Ce2 59.139(6) 1_554 7
Ce2 In Ce2 79.137(5) 7_545 7
Ce2 In Ce2 100.863(5) 3_455 7
Ge1 In Ce2 59.139(6) 5_556 3_445
Ge1 In Ce2 120.861(6) 1_554 3_445
Ce2 In Ce2 100.863(5) 7_545 3_445
Ce2 In Ce2 79.137(5) 3_455 3_445
Ce2 In Ce2 180.000(7) 7 3_445
Ge1 In Ce1 55.895(6) 5_556 3_445
Ge1 In Ce1 124.105(6) 1_554 3_445
Ce2 In Ce1 64.987(5) 7_545 3_445
Ce2 In Ce1 115.013(5) 3_455 3_445
Ce2 In Ce1 112.393(5) 7 3_445
Ce2 In Ce1 67.607(5) 3_445 3_445
Ge1 In Ce1 124.105(6) 5_556 7
Ge1 In Ce1 55.895(6) 1_554 7
Ce2 In Ce1 115.013(5) 7_545 7
Ce2 In Ce1 64.987(5) 3_455 7
Ce2 In Ce1 67.607(5) 7 7
Ce2 In Ce1 112.393(5) 3_445 7
Ce1 In Ce1 180.000(5) 3_445 7
Ge1 In Ce1 124.105(6) 5_556 7_545
Ge1 In Ce1 55.895(6) 1_554 7_545
Ce2 In Ce1 67.607(5) 7_545 7_545
Ce2 In Ce1 112.393(5) 3_455 7_545
Ce2 In Ce1 115.013(5) 7 7_545
Ce2 In Ce1 64.987(5) 3_445 7_545
Ce1 In Ce1 101.764(5) 3_445 7_545
Ce1 In Ce1 78.236(5) 7 7_545
Ge1 In Ce1 55.895(6) 5_556 3_455
Ge1 In Ce1 124.105(6) 1_554 3_455
Ce2 In Ce1 112.393(5) 7_545 3_455
Ce2 In Ce1 67.607(5) 3_455 3_455
Ce2 In Ce1 64.987(5) 7 3_455
Ce2 In Ce1 115.013(5) 3_445 3_455
Ce1 In Ce1 78.236(5) 3_445 3_455
Ce1 In Ce1 101.764(5) 7 3_455
Ce1 In Ce1 180.000(5) 7_545 3_455
Ge1 Ge1 Mn 119.24(3) 5_556 .
Ge1 Ge1 In 110.44(2) 5_556 1_556
Mn Ge1 In 130.317(19) . 1_556
Ge1 Ge1 Ce1 133.765(7) 5_556 7_556
Mn Ge1 Ce1 76.766(13) . 7_556
In Ge1 Ce1 68.986(9) 1_556 7_556
Ge1 Ge1 Ce1 133.765(7) 5_556 7_546
Mn Ge1 Ce1 76.766(13) . 7_546
In Ge1 Ce1 68.986(9) 1_556 7_546
Ce1 Ge1 Ce1 90.681(12) 7_556 7_546
Ge1 Ge1 Ce2 68.131(13) 5_556 3_445
Mn Ge1 Ce2 69.625(12) . 3_445
In Ge1 Ce2 134.378(7) 1_556 3_445
Ce1 Ge1 Ce2 146.359(15) 7_556 3_445
Ce1 Ge1 Ce2 80.476(6) 7_546 3_445
Ge1 Ge1 Ce2 68.131(13) 5_556 3_455
Mn Ge1 Ce2 69.625(12) . 3_455
In Ge1 Ce2 134.378(7) 1_556 3_455
Ce1 Ge1 Ce2 80.476(7) 7_556 3_455
Ce1 Ge1 Ce2 146.359(15) 7_546 3_455
Ce2 Ge1 Ce2 89.098(12) 3_445 3_455
Ge1 Ge1 Ce2 64.139(12) 5_556 7_546
Mn Ge1 Ce2 136.645(6) . 7_546
In Ge1 Ce2 66.441(8) 1_556 7_546
Ce1 Ge1 Ce2 135.395(15) 7_556 7_546
Ce1 Ge1 Ce2 75.185(7) 7_546 7_546
Ce2 Ge1 Ce2 73.636(8) 3_445 7_546
Ce2 Ge1 Ce2 132.270(13) 3_455 7_546
Ge1 Ge1 Ce2 64.139(12) 5_556 7_556
Mn Ge1 Ce2 136.645(6) . 7_556
In Ge1 Ce2 66.441(8) 1_556 7_556
Ce1 Ge1 Ce2 75.185(7) 7_556 7_556
Ce1 Ge1 Ce2 135.395(15) 7_546 7_556
Ce2 Ge1 Ce2 132.270(13) 3_445 7_556
Ce2 Ge1 Ce2 73.636(8) 3_455 7_556
Ce2 Ge1 Ce2 85.721(11) 7_546 7_556
Mn Ge2 Mn 114.95(3) 7_556 7_546
Mn Ge2 Mn 75.157(18) 7_556 .
Mn Ge2 Mn 75.157(18) 7_546 .
Mn Ge2 Ce1 76.541(16) 7_556 .
Mn Ge2 Ce1 76.541(16) 7_546 .
Mn Ge2 Ce1 125.90(2) . .
Mn Ge2 Ce1 147.64(2) 7_556 7_545
Mn Ge2 Ce1 71.604(13) 7_546 7_545
Mn Ge2 Ce1 134.695(8) . 7_545
Ce1 Ge2 Ce1 74.471(10) . 7_545
Mn Ge2 Ce1 71.604(13) 7_556 7
Mn Ge2 Ce1 147.64(2) 7_546 7
Mn Ge2 Ce1 134.695(8) . 7
Ce1 Ge2 Ce1 74.471(10) . 7
Ce1 Ge2 Ce1 86.956(12) 7_545 7
Mn Ge2 Ce2 141.20(2) 7_556 3_445
Mn Ge2 Ce2 67.922(13) 7_546 3_445
Mn Ge2 Ce2 68.271(12) . 3_445
Ce1 Ge2 Ce2 136.495(6) . 3_445
Ce1 Ge2 Ce2 71.155(7) 7_545 3_445
Ce1 Ge2 Ce2 128.297(15) 7 3_445
Mn Ge2 Ce2 67.922(13) 7_556 3_455
Mn Ge2 Ce2 141.20(2) 7_546 3_455
Mn Ge2 Ce2 68.271(12) . 3_455
Ce1 Ge2 Ce2 136.495(6) . 3_455
Ce1 Ge2 Ce2 128.297(15) 7_545 3_455
Ce1 Ge2 Ce2 71.155(7) 7 3_455
Ce2 Ge2 Ce2 86.480(12) 3_445 3_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ce1 Ge1 3.0685(3) 7_556
Ce1 Ge1 3.0685(3) 7_546
Ce1 Ge2 3.1010(5) .
Ce1 Ge2 3.1720(3) 7_545
Ce1 Ge2 3.1720(3) 7
Ce1 Mn 3.4030(6) 1_554
Ce1 In 3.45937(19) 3
Ce1 In 3.45937(19) 3_545
Ce1 Mn 3.5469(5) 7_556
Ce1 Mn 3.5469(5) 7_546
Ce1 Ce2 3.6991(3) 5_655
Ce1 Ce1 3.7962(3) 7_545
Ce2 Ge1 3.1112(3) 3
Ce2 Ge1 3.1112(3) 3_545
Ce2 Ge2 3.1861(4) 3
Ce2 Ge2 3.1861(4) 3_545
Ce2 Ge1 3.2087(3) 7_546
Ce2 Ge1 3.2087(3) 7_556
Ce2 Mn 3.2637(6) 5_656
Ce2 Mn 3.2944(5) 3
Ce2 Mn 3.2944(5) 3_545
Ce2 In 3.42639(19) 3_545
Ce2 In 3.42639(19) 3
Ce2 Ce1 3.6992(3) 5_655
Mn Ge2 2.5886(4) 7_556
Mn Ge2 2.5886(4) 7_546
Mn Ge1 2.6151(7) .
Mn Ge2 2.6265(7) .
Mn Mn 3.1806(9) 7_546
Mn Mn 3.1806(9) 7_556
Mn Ce2 3.2637(6) 5_656
Mn Ce2 3.2944(5) 3_445
Mn Ce2 3.2944(5) 3_455
Mn Ce1 3.4030(6) 1_556
Mn Ce1 3.5469(5) 7_556
Mn Ce1 3.5469(5) 7_546
In Ge1 3.0401(4) 5_556
In Ge1 3.0401(4) 1_554
In Ce2 3.42638(19) 7_545
In Ce2 3.42638(19) 3_455
In Ce2 3.42638(19) 7
In Ce2 3.42638(19) 3_445
In Ce1 3.45938(19) 3_445
In Ce1 3.45938(19) 7
In Ce1 3.45938(19) 7_545
In Ce1 3.45938(19) 3_455
Ge1 Ge1 2.5585(8) 5_556
Ge1 In 3.0401(4) 1_556
Ge1 Ce1 3.0685(3) 7_556
Ge1 Ce1 3.0685(3) 7_546
Ge1 Ce2 3.1112(3) 3_445
Ge1 Ce2 3.1112(3) 3_455
Ge1 Ce2 3.2087(3) 7_546
Ge1 Ce2 3.2087(3) 7_556
Ge2 Mn 2.5886(4) 7_556
Ge2 Mn 2.5886(4) 7_546
Ge2 Ce1 3.1720(3) 7_545
Ge2 Ce1 3.1720(3) 7
Ge2 Ce2 3.1860(4) 3_445
Ge2 Ce2 3.1860(4) 3_455
