#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:51:50 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179458 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/55/4335509.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4335509
loop_
_publ_author_name
'Anton O. Oliynyk'
'Stanislav S. Stoyko'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Quaternary Germanides RE4Mn2InGe4 (RE = La-Nd, Sm, Gd-Tm, Lu)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8264
_journal_page_last               8271
_journal_paper_doi               10.1021/ic401171v
_journal_volume                  52
_journal_year                    2013
_chemical_formula_structural     'Pr4 Mn2 In0.92 Ge4'
_chemical_formula_sum            'Ge4 In0.92 Mn2 Pr4'
_chemical_formula_weight         1068.94
_chemical_name_common
'praseodymium manganese indium germanide (4/2/1/4)'
_chemical_name_systematic
'praseodymium manganese indium germanide (4/2/1/4)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.7210(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.3401(11)
_cell_length_b                   4.3470(3)
_cell_length_c                   7.3425(5)
_cell_measurement_reflns_used    3363
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.73
_cell_measurement_theta_min      4.42
_cell_volume                     499.49(6)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0247
_diffrn_reflns_av_sigmaI/netI    0.0224
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            3612
_diffrn_reflns_theta_full        33.20
_diffrn_reflns_theta_max         33.20
_diffrn_reflns_theta_min         2.60
_exptl_absorpt_coefficient_mu    35.361
_exptl_absorpt_correction_T_max  0.5800
_exptl_absorpt_correction_T_min  0.1791
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.107
_exptl_crystal_description       irregular
_exptl_crystal_F_000             918
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.616
_refine_diff_density_min         -1.086
_refine_diff_density_rms         0.364
_refine_ls_extinction_coef       0.00051(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         1052
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0247
_refine_ls_R_factor_gt           0.0203
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0256P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0453
_refine_ls_wR_factor_ref         0.0468
_reflns_number_gt                942
_reflns_number_total             1052
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic401171v_si_002_4.cif
_cod_data_source_block           Pr4Mn2InGe4
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               4335509
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pr1 Pr 0.347789(17) 0.0000 0.07133(4) 0.00667(8) Uani 1 2 d S
Pr2 Pr 0.581688(17) 0.0000 0.36612(4) 0.00664(8) Uani 1 2 d S
Mn Mn 0.21840(5) 0.0000 0.61982(11) 0.00744(15) Uani 1 2 d S
In In 0.0000 0.0000 0.0000 0.00989(17) Uani 0.921(2) 4 d SP
Ge1 Ge 0.06309(3) 0.0000 0.65145(8) 0.00688(12) Uani 1 2 d S
Ge2 Ge 0.19878(4) 0.0000 0.25157(8) 0.00802(12) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -0.2180 2.8214 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Pr1 Ge1 91.023(16) 7_556 7_546
Ge1 Pr1 Ge2 89.882(15) 7_556 .
Ge1 Pr1 Ge2 89.882(14) 7_546 .
Ge1 Pr1 Ge2 164.233(18) 7_556 7_545
Ge1 Pr1 Ge2 88.630(12) 7_546 7_545
Ge2 Pr1 Ge2 105.879(13) . 7_545
Ge1 Pr1 Ge2 88.630(12) 7_556 7
Ge1 Pr1 Ge2 164.233(18) 7_546 7
Ge2 Pr1 Ge2 105.879(13) . 7
Ge2 Pr1 Ge2 87.460(17) 7_545 7
Ge1 Pr1 Mn 134.352(8) 7_556 1_554
Ge1 Pr1 Mn 134.352(8) 7_546 1_554
Ge2 Pr1 Mn 94.159(19) . 1_554
Ge2 Pr1 Mn 46.616(10) 7_545 1_554
Ge2 Pr1 Mn 46.616(10) 7 1_554
Ge1 Pr1 In 54.960(11) 7_556 3
Ge1 Pr1 In 108.877(12) 7_546 3
Ge2 Pr1 In 139.103(6) . 3
Ge2 Pr1 In 110.437(13) 7_545 3
Ge2 Pr1 In 58.623(11) 7 3
Mn Pr1 In 97.223(12) 1_554 3
Ge1 Pr1 In 108.877(12) 7_556 3_545
Ge1 Pr1 In 54.960(11) 7_546 3_545
Ge2 Pr1 In 139.103(5) . 3_545
Ge2 Pr1 In 58.623(11) 7_545 3_545
Ge2 Pr1 In 110.437(13) 7 3_545
Mn Pr1 In 97.223(12) 1_554 3_545
In Pr1 In 77.978(8) 3 3_545
Ge1 Pr1 Mn 46.139(15) 7_556 7_556
Ge1 Pr1 Mn 100.723(16) 7_546 7_556
Ge2 Pr1 Mn 45.506(12) . 7_556
Ge2 Pr1 Mn 149.104(18) 7_545 7_556
Ge2 Pr1 Mn 90.366(14) 7 7_556
Mn Pr1 Mn 114.171(15) 1_554 7_556
In Pr1 Mn 94.420(10) 3 7_556
In Pr1 Mn 148.459(15) 3_545 7_556
Ge1 Pr1 Mn 100.723(16) 7_556 7_546
Ge1 Pr1 Mn 46.139(15) 7_546 7_546
Ge2 Pr1 Mn 45.506(12) . 7_546
Ge2 Pr1 Mn 90.366(14) 7_545 7_546
Ge2 Pr1 Mn 149.104(18) 7 7_546
Mn Pr1 Mn 114.171(15) 1_554 7_546
In Pr1 Mn 148.459(15) 3 7_546
In Pr1 Mn 94.420(10) 3_545 7_546
Mn Pr1 Mn 76.057(17) 7_556 7_546
Ge1 Pr1 Pr2 111.743(12) 7_556 5_655
Ge1 Pr1 Pr2 111.743(12) 7_546 5_655
Ge2 Pr1 Pr2 148.255(14) . 5_655
Ge2 Pr1 Pr2 54.228(11) 7_545 5_655
Ge2 Pr1 Pr2 54.228(10) 7 5_655
Mn Pr1 Pr2 54.096(15) 1_554 5_655
In Pr1 Pr2 56.800(5) 3 5_655
In Pr1 Pr2 56.800(5) 3_545 5_655
Mn Pr1 Pr2 141.738(9) 7_556 5_655
Mn Pr1 Pr2 141.738(9) 7_546 5_655
Ge1 Pr1 Pr1 143.508(16) 7_556 7_545
Ge1 Pr1 Pr1 88.756(10) 7_546 7_545
Ge2 Pr1 Pr1 53.628(10) . 7_545
Ge2 Pr1 Pr1 52.251(11) 7_545 7_545
Ge2 Pr1 Pr1 100.826(14) 7 7_545
Mn Pr1 Pr1 58.976(12) 1_554 7_545
In Pr1 Pr1 156.022(12) 3 7_545
In Pr1 Pr1 100.692(6) 3_545 7_545
Mn Pr1 Pr1 98.175(15) 7_556 7_545
Mn Pr1 Pr1 55.195(14) 7_546 7_545
Pr2 Pr1 Pr1 102.107(10) 5_655 7_545
Ge1 Pr2 Ge1 89.259(17) 3 3_545
Ge1 Pr2 Ge2 83.233(12) 3 3
Ge1 Pr2 Ge2 147.890(17) 3_545 3
Ge1 Pr2 Ge2 147.890(17) 3 3_545
Ge1 Pr2 Ge2 83.233(12) 3_545 3_545
Ge2 Pr2 Ge2 86.740(16) 3 3_545
Ge1 Pr2 Ge1 106.861(11) 3 7_546
Ge1 Pr2 Ge1 48.090(18) 3_545 7_546
Ge2 Pr2 Ge1 162.896(17) 3 7_546
Ge2 Pr2 Ge1 91.107(12) 3_545 7_546
Ge1 Pr2 Ge1 48.090(18) 3 7_556
Ge1 Pr2 Ge1 106.861(10) 3_545 7_556
Ge2 Pr2 Ge1 91.107(12) 3 7_556
Ge2 Pr2 Ge1 162.896(17) 3_545 7_556
Ge1 Pr2 Ge1 85.975(15) 7_546 7_556
Ge1 Pr2 Mn 105.850(15) 3 5_656
Ge1 Pr2 Mn 105.850(15) 3_545 5_656
Ge2 Pr2 Mn 47.713(11) 3 5_656
Ge2 Pr2 Mn 47.713(11) 3_545 5_656
Ge1 Pr2 Mn 136.997(8) 7_546 5_656
Ge1 Pr2 Mn 136.997(8) 7_556 5_656
Ge1 Pr2 Mn 48.273(16) 3 3
Ge1 Pr2 Mn 105.314(16) 3_545 3
Ge2 Pr2 Mn 48.076(17) 3 3
Ge2 Pr2 Mn 103.924(17) 3_545 3
Ge1 Pr2 Mn 148.188(19) 7_546 3
Ge1 Pr2 Mn 86.988(14) 7_556 3
Mn Pr2 Mn 57.775(18) 5_656 3
Ge1 Pr2 Mn 105.314(16) 3 3_545
Ge1 Pr2 Mn 48.273(16) 3_545 3_545
Ge2 Pr2 Mn 103.924(17) 3 3_545
Ge2 Pr2 Mn 48.076(17) 3_545 3_545
Ge1 Pr2 Mn 86.988(14) 7_546 3_545
Ge1 Pr2 Mn 148.188(19) 7_556 3_545
Mn Pr2 Mn 57.775(18) 5_656 3_545
Mn Pr2 Mn 82.86(2) 3 3_545
Ge1 Pr2 In 152.581(13) 3 3_545
Ge1 Pr2 In 89.634(9) 3_545 3_545
Ge2 Pr2 In 110.919(12) 3 3_545
Ge2 Pr2 In 58.877(11) 3_545 3_545
Ge1 Pr2 In 54.331(10) 7_546 3_545
Ge1 Pr2 In 106.536(12) 7_556 3_545
Mn Pr2 In 100.794(13) 5_656 3_545
Mn Pr2 In 156.256(17) 3 3_545
Mn Pr2 In 94.202(11) 3_545 3_545
Ge1 Pr2 In 89.634(9) 3 3
Ge1 Pr2 In 152.581(13) 3_545 3
Ge2 Pr2 In 58.878(11) 3 3
Ge2 Pr2 In 110.919(12) 3_545 3
Ge1 Pr2 In 106.536(12) 7_546 3
Ge1 Pr2 In 54.331(10) 7_556 3
Mn Pr2 In 100.794(13) 5_656 3
Mn Pr2 In 94.202(11) 3 3
Mn Pr2 In 156.256(17) 3_545 3
In Pr2 In 79.035(8) 3_545 3
Ge1 Pr2 Pr1 134.546(9) 3 5_655
Ge1 Pr2 Pr1 134.546(9) 3_545 5_655
Ge2 Pr2 Pr1 53.708(10) 3 5_655
Ge2 Pr2 Pr1 53.708(10) 3_545 5_655
Ge1 Pr2 Pr1 112.123(12) 7_546 5_655
Ge1 Pr2 Pr1 112.123(12) 7_556 5_655
Mn Pr2 Pr1 57.729(16) 5_656 5_655
Mn Pr2 Pr1 99.262(16) 3 5_655
Mn Pr2 Pr1 99.262(16) 3_545 5_655
In Pr2 Pr1 57.808(6) 3_545 5_655
In Pr2 Pr1 57.808(6) 3 5_655
Ge2 Mn Ge2 114.06(4) 7_556 7_546
Ge2 Mn Ge1 112.72(2) 7_556 .
Ge2 Mn Ge1 112.72(2) 7_546 .
Ge2 Mn Ge2 105.73(2) 7_556 .
Ge2 Mn Ge2 105.73(2) 7_546 .
Ge1 Mn Ge2 104.90(3) . .
Ge2 Mn Mn 124.15(4) 7_556 7_546
Ge2 Mn Mn 53.429(17) 7_546 7_546
Ge1 Mn Mn 122.14(3) . 7_546
Ge2 Mn Mn 52.30(2) . 7_546
Ge2 Mn Mn 53.429(17) 7_556 7_556
Ge2 Mn Mn 124.15(4) 7_546 7_556
Ge1 Mn Mn 122.14(3) . 7_556
Ge2 Mn Mn 52.30(2) . 7_556
Mn Mn Mn 87.21(4) 7_546 7_556
Ge2 Mn Pr2 64.660(19) 7_556 5_656
Ge2 Mn Pr2 64.660(19) 7_546 5_656
Ge1 Mn Pr2 173.37(3) . 5_656
Ge2 Mn Pr2 81.73(2) . 5_656
Mn Mn Pr2 61.85(2) 7_546 5_656
Mn Mn Pr2 61.85(2) 7_556 5_656
Ge2 Mn Pr2 163.85(3) 7_556 3_445
Ge2 Mn Pr2 81.390(13) 7_546 3_445
Ge1 Mn Pr2 62.042(17) . 3_445
Ge2 Mn Pr2 63.580(17) . 3_445
Mn Mn Pr2 60.374(19) 7_546 3_445
Mn Mn Pr2 114.73(4) 7_556 3_445
Pr2 Mn Pr2 122.225(18) 5_656 3_445
Ge2 Mn Pr2 81.390(13) 7_556 3_455
Ge2 Mn Pr2 163.85(3) 7_546 3_455
Ge1 Mn Pr2 62.042(17) . 3_455
Ge2 Mn Pr2 63.581(17) . 3_455
Mn Mn Pr2 114.73(4) 7_546 3_455
Mn Mn Pr2 60.37(2) 7_556 3_455
Pr2 Mn Pr2 122.225(18) 5_656 3_455
Pr2 Mn Pr2 82.86(2) 3_445 3_455
Ge2 Mn Pr1 61.888(19) 7_556 1_556
Ge2 Mn Pr1 61.888(19) 7_546 1_556
Ge1 Mn Pr1 105.19(3) . 1_556
Ge2 Mn Pr1 149.91(3) . 1_556
Mn Mn Pr1 109.55(3) 7_546 1_556
Mn Mn Pr1 109.55(3) 7_556 1_556
Pr2 Mn Pr1 68.175(17) 5_656 1_556
Pr2 Mn Pr1 133.437(14) 3_445 1_556
Pr2 Mn Pr1 133.437(14) 3_455 1_556
Ge2 Mn Pr1 58.229(16) 7_556 7_556
Ge2 Mn Pr1 120.47(3) 7_546 7_556
Ge1 Mn Pr1 57.177(16) . 7_556
Ge2 Mn Pr1 133.763(18) . 7_556
Mn Mn Pr1 173.73(3) 7_546 7_556
Mn Mn Pr1 98.295(13) 7_556 7_556
Pr2 Mn Pr1 118.192(19) 5_656 7_556
Pr2 Mn Pr1 119.21(2) 3_445 7_556
Pr2 Mn Pr1 70.893(12) 3_455 7_556
Pr1 Mn Pr1 65.827(15) 1_556 7_556
Ge2 Mn Pr1 120.47(3) 7_556 7_546
Ge2 Mn Pr1 58.229(16) 7_546 7_546
Ge1 Mn Pr1 57.177(16) . 7_546
Ge2 Mn Pr1 133.763(18) . 7_546
Mn Mn Pr1 98.295(13) 7_546 7_546
Mn Mn Pr1 173.73(3) 7_556 7_546
Pr2 Mn Pr1 118.192(19) 5_656 7_546
Pr2 Mn Pr1 70.893(12) 3_445 7_546
Pr2 Mn Pr1 119.21(2) 3_455 7_546
Pr1 Mn Pr1 65.828(15) 1_556 7_546
Pr1 Mn Pr1 76.058(17) 7_556 7_546
Ge1 In Ge1 180.000(17) 5_556 1_554
Ge1 In Pr2 121.016(9) 5_556 7_545
Ge1 In Pr2 58.984(9) 1_554 7_545
Ge1 In Pr2 58.984(9) 5_556 3_455
Ge1 In Pr2 121.016(9) 1_554 3_455
Pr2 In Pr2 180.000(7) 7_545 3_455
Ge1 In Pr2 121.016(9) 5_556 7
Ge1 In Pr2 58.984(9) 1_554 7
Pr2 In Pr2 79.034(8) 7_545 7
Pr2 In Pr2 100.966(8) 3_455 7
Ge1 In Pr2 58.984(9) 5_556 3_445
Ge1 In Pr2 121.016(9) 1_554 3_445
Pr2 In Pr2 100.966(8) 7_545 3_445
Pr2 In Pr2 79.034(8) 3_455 3_445
Pr2 In Pr2 180.000(9) 7 3_445
Ge1 In Pr1 55.642(8) 5_556 3_445
Ge1 In Pr1 124.358(8) 1_554 3_445
Pr2 In Pr1 65.393(7) 7_545 3_445
Pr2 In Pr1 114.607(7) 3_455 3_445
Pr2 In Pr1 112.600(7) 7 3_445
Pr2 In Pr1 67.400(7) 3_445 3_445
Ge1 In Pr1 124.358(8) 5_556 7
Ge1 In Pr1 55.642(8) 1_554 7
Pr2 In Pr1 114.607(7) 7_545 7
Pr2 In Pr1 65.393(7) 3_455 7
Pr2 In Pr1 67.400(7) 7 7
Pr2 In Pr1 112.600(7) 3_445 7
Pr1 In Pr1 180.000(6) 3_445 7
Ge1 In Pr1 124.358(8) 5_556 7_545
Ge1 In Pr1 55.642(8) 1_554 7_545
Pr2 In Pr1 67.400(7) 7_545 7_545
Pr2 In Pr1 112.600(7) 3_455 7_545
Pr2 In Pr1 114.607(7) 7 7_545
Pr2 In Pr1 65.393(7) 3_445 7_545
Pr1 In Pr1 102.023(7) 3_445 7_545
Pr1 In Pr1 77.977(7) 7 7_545
Ge1 In Pr1 55.642(8) 5_556 3_455
Ge1 In Pr1 124.358(8) 1_554 3_455
Pr2 In Pr1 112.600(7) 7_545 3_455
Pr2 In Pr1 67.400(7) 3_455 3_455
Pr2 In Pr1 65.393(7) 7 3_455
Pr2 In Pr1 114.607(7) 3_445 3_455
Pr1 In Pr1 77.977(7) 3_445 3_455
Pr1 In Pr1 102.023(7) 7 3_455
Pr1 In Pr1 180.000(6) 7_545 3_455
Ge1 Ge1 Mn 118.84(4) 5_556 .
Ge1 Ge1 In 110.48(3) 5_556 1_556
Mn Ge1 In 130.67(3) . 1_556
Ge1 Ge1 Pr1 133.697(9) 5_556 7_556
Mn Ge1 Pr1 76.684(17) . 7_556
In Ge1 Pr1 69.398(12) 1_556 7_556
Ge1 Ge1 Pr1 133.697(9) 5_556 7_546
Mn Ge1 Pr1 76.684(17) . 7_546
In Ge1 Pr1 69.398(12) 1_556 7_546
Pr1 Ge1 Pr1 91.023(16) 7_556 7_546
Ge1 Ge1 Pr2 67.872(17) 5_556 3_445
Mn Ge1 Pr2 69.685(17) . 3_445
In Ge1 Pr2 134.223(9) 1_556 3_445
Pr1 Ge1 Pr2 146.34(2) 7_556 3_445
Pr1 Ge1 Pr2 80.213(9) 7_546 3_445
Ge1 Ge1 Pr2 67.872(17) 5_556 3_455
Mn Ge1 Pr2 69.685(17) . 3_455
In Ge1 Pr2 134.223(9) 1_556 3_455
Pr1 Ge1 Pr2 80.213(9) 7_556 3_455
Pr1 Ge1 Pr2 146.34(2) 7_546 3_455
Pr2 Ge1 Pr2 89.259(16) 3_445 3_455
Ge1 Ge1 Pr2 64.037(16) 5_556 7_546
Mn Ge1 Pr2 136.429(9) . 7_546
In Ge1 Pr2 66.686(11) 1_556 7_546
Pr1 Ge1 Pr2 136.05(2) 7_556 7_546
Pr1 Ge1 Pr2 75.353(9) 7_546 7_546
Pr2 Ge1 Pr2 73.139(10) 3_445 7_546
Pr2 Ge1 Pr2 131.910(18) 3_455 7_546
Ge1 Ge1 Pr2 64.037(16) 5_556 7_556
Mn Ge1 Pr2 136.429(9) . 7_556
In Ge1 Pr2 66.686(11) 1_556 7_556
Pr1 Ge1 Pr2 75.353(9) 7_556 7_556
Pr1 Ge1 Pr2 136.05(2) 7_546 7_556
Pr2 Ge1 Pr2 131.910(18) 3_445 7_556
Pr2 Ge1 Pr2 73.139(11) 3_455 7_556
Pr2 Ge1 Pr2 85.976(15) 7_546 7_556
Mn Ge2 Mn 114.06(4) 7_556 7_546
Mn Ge2 Mn 74.27(2) 7_556 .
Mn Ge2 Mn 74.27(2) 7_546 .
Mn Ge2 Pr1 76.27(2) 7_556 .
Mn Ge2 Pr1 76.27(2) 7_546 .
Mn Ge2 Pr1 124.25(3) . .
Mn Ge2 Pr1 147.40(3) 7_556 7_545
Mn Ge2 Pr1 71.495(18) 7_546 7_545
Mn Ge2 Pr1 134.976(10) . 7_545
Pr1 Ge2 Pr1 74.121(13) . 7_545
Mn Ge2 Pr1 71.495(18) 7_556 7
Mn Ge2 Pr1 147.40(3) 7_546 7
Mn Ge2 Pr1 134.976(10) . 7
Pr1 Ge2 Pr1 74.121(13) . 7
Pr1 Ge2 Pr1 87.460(17) 7_545 7
Mn Ge2 Pr2 140.49(3) 7_556 3_445
Mn Ge2 Pr2 67.626(17) 7_546 3_445
Mn Ge2 Pr2 68.344(16) . 3_445
Pr1 Ge2 Pr2 136.501(8) . 3_445
Pr1 Ge2 Pr2 72.064(10) 7_545 3_445
Pr1 Ge2 Pr2 129.90(2) 7 3_445
Mn Ge2 Pr2 67.626(17) 7_556 3_455
Mn Ge2 Pr2 140.49(3) 7_546 3_455
Mn Ge2 Pr2 68.343(16) . 3_455
Pr1 Ge2 Pr2 136.501(8) . 3_455
Pr1 Ge2 Pr2 129.90(2) 7_545 3_455
Pr1 Ge2 Pr2 72.064(10) 7 3_455
Pr2 Ge2 Pr2 86.739(16) 3_445 3_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pr1 Ge1 3.0467(4) 7_556
Pr1 Ge1 3.0467(4) 7_546
Pr1 Ge2 3.0877(6) .
Pr1 Ge2 3.1442(5) 7_545
Pr1 Ge2 3.1442(5) 7
Pr1 Mn 3.3805(9) 1_554
Pr1 In 3.4546(3) 3
Pr1 In 3.4546(3) 3_545
Pr1 Mn 3.5281(7) 7_556
Pr1 Mn 3.5281(7) 7_546
Pr1 Pr2 3.7114(5) 5_655
Pr1 Pr1 3.7560(5) 7_545
Pr2 Ge1 3.0939(5) 3
Pr2 Ge1 3.0939(4) 3_545
Pr2 Ge2 3.1651(5) 3
Pr2 Ge2 3.1651(5) 3_545
Pr2 Ge1 3.1877(5) 7_546
Pr2 Ge1 3.1877(5) 7_556
Pr2 Mn 3.2384(8) 5_656
Pr2 Mn 3.2848(6) 3
Pr2 Mn 3.2848(6) 3_545
Pr2 In 3.4158(3) 3_545
Pr2 In 3.4158(3) 3
Pr2 Pr1 3.7114(4) 5_655
Mn Ge2 2.5908(5) 7_556
Mn Ge2 2.5908(5) 7_546
Mn Ge1 2.6141(9) .
Mn Ge2 2.6296(10) .
Mn Mn 3.1516(11) 7_546
Mn Mn 3.1516(11) 7_556
Mn Pr2 3.2384(8) 5_656
Mn Pr2 3.2848(6) 3_445
Mn Pr2 3.2848(6) 3_455
Mn Pr1 3.3805(9) 1_556
Mn Pr1 3.5281(7) 7_556
Mn Pr1 3.5281(7) 7_546
In Ge1 3.0217(6) 5_556
In Ge1 3.0217(6) 1_554
In Pr2 3.4158(3) 7_545
In Pr2 3.4158(3) 3_455
In Pr2 3.4158(3) 7
In Pr2 3.4158(3) 3_445
In Pr1 3.4546(3) 3_445
In Pr1 3.4546(3) 7
In Pr1 3.4546(3) 7_545
In Pr1 3.4546(3) 3_455
Ge1 Ge1 2.5609(10) 5_556
Ge1 In 3.0217(6) 1_556
Ge1 Pr1 3.0467(4) 7_556
Ge1 Pr1 3.0467(4) 7_546
Ge1 Pr2 3.0939(5) 3_445
Ge1 Pr2 3.0939(4) 3_455
Ge1 Pr2 3.1877(5) 7_546
Ge1 Pr2 3.1877(5) 7_556
Ge2 Mn 2.5907(5) 7_556
Ge2 Mn 2.5907(5) 7_546
Ge2 Pr1 3.1443(5) 7_545
Ge2 Pr1 3.1443(5) 7
Ge2 Pr2 3.1651(5) 3_445
Ge2 Pr2 3.1651(5) 3_455
