#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:51:50 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179458 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/55/4335510.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4335510
loop_
_publ_author_name
'Anton O. Oliynyk'
'Stanislav S. Stoyko'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Quaternary Germanides RE4Mn2InGe4 (RE = La-Nd, Sm, Gd-Tm, Lu)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8264
_journal_page_last               8271
_journal_paper_doi               10.1021/ic401171v
_journal_volume                  52
_journal_year                    2013
_chemical_formula_structural     'Nd4 Mn2 In0.88 Ge4'
_chemical_formula_sum            'Ge4 In0.88 Mn2 Nd4'
_chemical_formula_weight         1078.24
_chemical_name_common
'neodymium manganese indium germanide (4/2/1/4)'
_chemical_name_systematic
'neodymium manganese indium germanide (4/2/1/4)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.813(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.249(3)
_cell_length_b                   4.3313(7)
_cell_length_c                   7.3185(12)
_cell_measurement_reflns_used    2461
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      33.05
_cell_measurement_theta_min      4.44
_cell_volume                     493.05(15)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.975
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0288
_diffrn_reflns_av_sigmaI/netI    0.0260
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3462
_diffrn_reflns_theta_full        33.20
_diffrn_reflns_theta_max         33.20
_diffrn_reflns_theta_min         2.62
_exptl_absorpt_coefficient_mu    37.041
_exptl_absorpt_correction_T_max  0.4536
_exptl_absorpt_correction_T_min  0.1228
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.263
_exptl_crystal_description       irregular
_exptl_crystal_F_000             922
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         3.965
_refine_diff_density_min         -1.399
_refine_diff_density_rms         0.494
_refine_ls_extinction_coef       0.00031(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         1029
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0314
_refine_ls_R_factor_gt           0.0264
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0384P)²+1.5747P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0632
_refine_ls_wR_factor_ref         0.0656
_reflns_number_gt                912
_reflns_number_total             1029
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic401171v_si_002_5.cif
_cod_data_source_block           Nd4Mn2InGe4
_cod_original_cell_volume        493.05(14)
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               4335510
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Nd1 Nd 0.34837(2) 0.0000 0.07190(5) 0.00707(11) Uani 1 2 d S
Nd2 Nd 0.58085(2) 0.0000 0.36504(5) 0.00670(11) Uani 1 2 d S
Mn Mn 0.21888(7) 0.0000 0.61892(15) 0.0069(2) Uani 1 2 d S
In In 0.0000 0.0000 0.0000 0.0103(2) Uani 0.881(4) 4 d SP
Ge1 Ge 0.06336(5) 0.0000 0.65175(10) 0.00681(16) Uani 1 2 d S
Ge2 Ge 0.19749(5) 0.0000 0.24909(11) 0.00750(16) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nd Nd -0.1943 3.0179 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Nd1 Ge1 91.38(2) 7_556 7_546
Ge1 Nd1 Ge2 89.98(2) 7_556 .
Ge1 Nd1 Ge2 89.98(2) 7_546 .
Ge1 Nd1 Ge2 164.33(2) 7_556 7_545
Ge1 Nd1 Ge2 88.299(19) 7_546 7_545
Ge2 Nd1 Ge2 105.682(19) . 7_545
Ge1 Nd1 Ge2 88.299(19) 7_556 7
Ge1 Nd1 Ge2 164.33(2) 7_546 7
Ge2 Nd1 Ge2 105.682(19) . 7
Ge2 Nd1 Ge2 87.82(3) 7_545 7
Ge1 Nd1 Mn 134.184(13) 7_556 1_554
Ge1 Nd1 Mn 134.184(13) 7_546 1_554
Ge2 Nd1 Mn 93.87(3) . 1_554
Ge2 Nd1 Mn 46.802(14) 7_545 1_554
Ge2 Nd1 Mn 46.802(14) 7 1_554
Ge1 Nd1 In 55.156(16) 7_556 3
Ge1 Nd1 In 109.353(19) 7_546 3
Ge2 Nd1 In 139.170(9) . 3
Ge2 Nd1 In 110.354(18) 7_545 3
Ge2 Nd1 In 58.191(15) 7 3
Mn Nd1 In 96.927(18) 1_554 3
Ge1 Nd1 In 109.353(19) 7_556 3_545
Ge1 Nd1 In 55.156(16) 7_546 3_545
Ge2 Nd1 In 139.170(9) . 3_545
Ge2 Nd1 In 58.191(15) 7_545 3_545
Ge2 Nd1 In 110.354(18) 7 3_545
Mn Nd1 In 96.927(18) 1_554 3_545
In Nd1 In 78.215(15) 3 3_545
Ge1 Nd1 Mn 46.10(2) 7_556 7_556
Ge1 Nd1 Mn 100.69(2) 7_546 7_556
Ge2 Nd1 Mn 45.521(16) . 7_556
Ge2 Nd1 Mn 149.08(2) 7_545 7_556
Ge2 Nd1 Mn 90.34(2) 7 7_556
Mn Nd1 Mn 114.18(2) 1_554 7_556
In Nd1 Mn 94.604(16) 3 7_556
In Nd1 Mn 148.77(2) 3_545 7_556
Ge1 Nd1 Mn 100.69(2) 7_556 7_546
Ge1 Nd1 Mn 46.10(2) 7_546 7_546
Ge2 Nd1 Mn 45.521(16) . 7_546
Ge2 Nd1 Mn 90.34(2) 7_545 7_546
Ge2 Nd1 Mn 149.08(2) 7 7_546
Mn Nd1 Mn 114.18(2) 1_554 7_546
In Nd1 Mn 148.77(2) 3 7_546
In Nd1 Mn 94.604(16) 3_545 7_546
Mn Nd1 Mn 75.78(2) 7_556 7_546
Ge1 Nd1 Nd2 111.839(18) 7_556 5_655
Ge1 Nd1 Nd2 111.839(18) 7_546 5_655
Ge2 Nd1 Nd2 147.844(18) . 5_655
Ge2 Nd1 Nd2 54.249(15) 7_545 5_655
Ge2 Nd1 Nd2 54.249(15) 7 5_655
Mn Nd1 Nd2 53.98(2) 1_554 5_655
In Nd1 Nd2 56.700(7) 3 5_655
In Nd1 Nd2 56.700(8) 3_545 5_655
Mn Nd1 Nd2 141.857(13) 7_556 5_655
Mn Nd1 Nd2 141.857(13) 7_546 5_655
Ge1 Nd1 Nd1 143.26(2) 7_556 7_545
Ge1 Nd1 Nd1 88.570(16) 7_546 7_545
Ge2 Nd1 Nd1 53.274(15) . 7_545
Ge2 Nd1 Nd1 52.409(16) 7_545 7_545
Ge2 Nd1 Nd1 101.00(2) 7 7_545
Mn Nd1 Nd1 59.047(17) 1_554 7_545
In Nd1 Nd1 155.825(17) 3 7_545
In Nd1 Nd1 100.599(14) 3_545 7_545
Mn Nd1 Nd1 97.90(2) 7_556 7_545
Mn Nd1 Nd1 55.13(2) 7_546 7_545
Nd2 Nd1 Nd1 102.145(15) 5_655 7_545
Ge1 Nd2 Ge1 89.17(2) 3 3_545
Ge1 Nd2 Ge2 83.202(18) 3 3
Ge1 Nd2 Ge2 147.81(2) 3_545 3
Ge1 Nd2 Ge2 147.81(2) 3 3_545
Ge1 Nd2 Ge2 83.202(18) 3_545 3_545
Ge2 Nd2 Ge2 86.81(2) 3 3_545
Ge1 Nd2 Ge1 107.083(16) 3 7_546
Ge1 Nd2 Ge1 48.22(2) 3_545 7_546
Ge2 Nd2 Ge1 162.80(2) 3 7_546
Ge2 Nd2 Ge1 90.888(19) 3_545 7_546
Ge1 Nd2 Ge1 48.22(2) 3 7_556
Ge1 Nd2 Ge1 107.083(16) 3_545 7_556
Ge2 Nd2 Ge1 90.888(19) 3 7_556
Ge2 Nd2 Ge1 162.80(2) 3_545 7_556
Ge1 Nd2 Ge1 86.29(2) 7_546 7_556
Ge1 Nd2 Mn 105.42(2) 3 5_656
Ge1 Nd2 Mn 105.42(2) 3_545 5_656
Ge2 Nd2 Mn 47.943(15) 3 5_656
Ge2 Nd2 Mn 47.943(15) 3_545 5_656
Ge1 Nd2 Mn 136.847(12) 7_546 5_656
Ge1 Nd2 Mn 136.847(12) 7_556 5_656
Ge1 Nd2 Mn 48.22(2) 3 3
Ge1 Nd2 Mn 105.10(2) 3_545 3
Ge2 Nd2 Mn 48.16(2) 3 3
Ge2 Nd2 Mn 103.90(2) 3_545 3
Ge1 Nd2 Mn 148.25(3) 7_546 3
Ge1 Nd2 Mn 86.99(2) 7_556 3
Mn Nd2 Mn 57.42(3) 5_656 3
Ge1 Nd2 Mn 105.10(2) 3 3_545
Ge1 Nd2 Mn 48.22(2) 3_545 3_545
Ge2 Nd2 Mn 103.90(2) 3 3_545
Ge2 Nd2 Mn 48.16(2) 3_545 3_545
Ge1 Nd2 Mn 86.99(2) 7_546 3_545
Ge1 Nd2 Mn 148.25(3) 7_556 3_545
Mn Nd2 Mn 57.42(3) 5_656 3_545
Mn Nd2 Mn 82.62(3) 3 3_545
Ge1 Nd2 In 153.164(18) 3 3_545
Ge1 Nd2 In 89.807(17) 3_545 3_545
Ge2 Nd2 In 110.638(18) 3 3_545
Ge2 Nd2 In 58.378(16) 3_545 3_545
Ge1 Nd2 In 54.523(15) 7_546 3_545
Ge1 Nd2 In 106.990(18) 7_556 3_545
Mn Nd2 In 100.693(18) 5_656 3_545
Mn Nd2 In 155.85(2) 3 3_545
Mn Nd2 In 94.021(17) 3_545 3_545
Ge1 Nd2 In 89.807(17) 3 3
Ge1 Nd2 In 153.164(18) 3_545 3
Ge2 Nd2 In 58.378(16) 3 3
Ge2 Nd2 In 110.638(18) 3_545 3
Ge1 Nd2 In 106.990(18) 7_546 3
Ge1 Nd2 In 54.523(15) 7_556 3
Mn Nd2 In 100.693(18) 5_656 3
Mn Nd2 In 94.021(17) 3 3
Mn Nd2 In 155.85(2) 3_545 3
In Nd2 In 79.284(15) 3_545 3
Ge1 Nd2 Nd1 134.503(13) 3 5_655
Ge1 Nd2 Nd1 134.503(13) 3_545 5_655
Ge2 Nd2 Nd1 53.524(13) 3 5_655
Ge2 Nd2 Nd1 53.524(13) 3_545 5_655
Ge1 Nd2 Nd1 112.220(17) 7_546 5_655
Ge1 Nd2 Nd1 112.220(17) 7_556 5_655
Mn Nd2 Nd1 57.87(2) 5_656 5_655
Mn Nd2 Nd1 99.03(2) 3 5_655
Mn Nd2 Nd1 99.03(2) 3_545 5_655
In Nd2 Nd1 57.712(11) 3_545 5_655
In Nd2 Nd1 57.712(11) 3 5_655
Ge2 Mn Ge2 113.45(5) 7_556 7_546
Ge2 Mn Ge1 112.55(3) 7_556 .
Ge2 Mn Ge1 112.55(3) 7_546 .
Ge2 Mn Ge2 106.44(3) 7_556 .
Ge2 Mn Ge2 106.44(3) 7_546 .
Ge1 Mn Ge2 104.60(4) . .
Ge2 Mn Mn 124.60(6) 7_556 7_546
Ge2 Mn Mn 53.76(2) 7_546 7_546
Ge1 Mn Mn 122.01(4) . 7_546
Ge2 Mn Mn 52.68(3) . 7_546
Ge2 Mn Mn 53.76(3) 7_556 7_556
Ge2 Mn Mn 124.60(6) 7_546 7_556
Ge1 Mn Mn 122.01(4) . 7_556
Ge2 Mn Mn 52.68(3) . 7_556
Mn Mn Mn 87.77(5) 7_546 7_556
Ge2 Mn Nd2 64.60(3) 7_556 5_656
Ge2 Mn Nd2 64.60(3) 7_546 5_656
Ge1 Mn Nd2 172.94(5) . 5_656
Ge2 Mn Nd2 82.46(3) . 5_656
Mn Mn Nd2 62.23(3) 7_546 5_656
Mn Mn Nd2 62.23(3) 7_556 5_656
Ge2 Mn Nd2 164.17(4) 7_556 3_445
Ge2 Mn Nd2 81.85(2) 7_546 3_445
Ge1 Mn Nd2 61.96(2) . 3_445
Ge2 Mn Nd2 63.35(2) . 3_445
Mn Mn Nd2 60.35(3) 7_546 3_445
Mn Mn Nd2 114.87(5) 7_556 3_445
Nd2 Mn Nd2 122.58(3) 5_656 3_445
Ge2 Mn Nd2 81.85(2) 7_556 3_455
Ge2 Mn Nd2 164.17(4) 7_546 3_455
Ge1 Mn Nd2 61.96(2) . 3_455
Ge2 Mn Nd2 63.35(2) . 3_455
Mn Mn Nd2 114.87(5) 7_546 3_455
Mn Mn Nd2 60.35(3) 7_556 3_455
Nd2 Mn Nd2 122.58(3) 5_656 3_455
Nd2 Mn Nd2 82.62(3) 3_445 3_455
Ge2 Mn Nd1 61.50(3) 7_556 1_556
Ge2 Mn Nd1 61.50(3) 7_546 1_556
Ge1 Mn Nd1 104.78(4) . 1_556
Ge2 Mn Nd1 150.62(4) . 1_556
Mn Mn Nd1 109.70(4) 7_546 1_556
Mn Mn Nd1 109.70(4) 7_556 1_556
Nd2 Mn Nd1 68.16(2) 5_656 1_556
Nd2 Mn Nd1 133.35(2) 3_445 1_556
Nd2 Mn Nd1 133.35(2) 3_455 1_556
Ge2 Mn Nd1 58.25(2) 7_556 7_556
Ge2 Mn Nd1 120.04(4) 7_546 7_556
Ge1 Mn Nd1 56.79(2) . 7_556
Ge2 Mn Nd1 133.46(3) . 7_556
Mn Mn Nd1 173.49(4) 7_546 7_556
Mn Mn Nd1 98.17(2) 7_556 7_556
Nd2 Mn Nd1 118.28(3) 5_656 7_556
Nd2 Mn Nd1 118.74(3) 3_445 7_556
Nd2 Mn Nd1 70.732(18) 3_455 7_556
Nd1 Mn Nd1 65.82(2) 1_556 7_556
Ge2 Mn Nd1 120.04(4) 7_556 7_546
Ge2 Mn Nd1 58.25(2) 7_546 7_546
Ge1 Mn Nd1 56.79(2) . 7_546
Ge2 Mn Nd1 133.46(3) . 7_546
Mn Mn Nd1 98.17(2) 7_546 7_546
Mn Mn Nd1 173.49(4) 7_556 7_546
Nd2 Mn Nd1 118.28(3) 5_656 7_546
Nd2 Mn Nd1 70.732(18) 3_445 7_546
Nd2 Mn Nd1 118.74(3) 3_455 7_546
Nd1 Mn Nd1 65.82(2) 1_556 7_546
Nd1 Mn Nd1 75.78(2) 7_556 7_546
Ge1 In Ge1 180.00(2) 5_556 1_554
Ge1 In Nd2 121.114(14) 5_556 7_545
Ge1 In Nd2 58.886(14) 1_554 7_545
Ge1 In Nd2 58.886(14) 5_556 3_455
Ge1 In Nd2 121.114(14) 1_554 3_455
Nd2 In Nd2 180.000(13) 7_545 3_455
Ge1 In Nd2 121.114(14) 5_556 7
Ge1 In Nd2 58.886(13) 1_554 7
Nd2 In Nd2 79.285(15) 7_545 7
Nd2 In Nd2 100.715(15) 3_455 7
Ge1 In Nd2 58.886(13) 5_556 3_445
Ge1 In Nd2 121.114(14) 1_554 3_445
Nd2 In Nd2 100.715(15) 7_545 3_445
Nd2 In Nd2 79.285(15) 3_455 3_445
Nd2 In Nd2 180.000(13) 7 3_445
Ge1 In Nd1 55.547(11) 5_556 3_445
Ge1 In Nd1 124.453(11) 1_554 3_445
Nd2 In Nd1 65.587(12) 7_545 3_445
Nd2 In Nd1 114.413(11) 3_455 3_445
Nd2 In Nd1 113.051(11) 7 3_445
Nd2 In Nd1 66.949(11) 3_445 3_445
Ge1 In Nd1 124.453(11) 5_556 7
Ge1 In Nd1 55.547(11) 1_554 7
Nd2 In Nd1 114.413(11) 7_545 7
Nd2 In Nd1 65.587(12) 3_455 7
Nd2 In Nd1 66.949(11) 7 7
Nd2 In Nd1 113.051(11) 3_445 7
Nd1 In Nd1 180.000(8) 3_445 7
Ge1 In Nd1 124.453(11) 5_556 7_545
Ge1 In Nd1 55.547(11) 1_554 7_545
Nd2 In Nd1 66.949(11) 7_545 7_545
Nd2 In Nd1 113.051(11) 3_455 7_545
Nd2 In Nd1 114.413(12) 7 7_545
Nd2 In Nd1 65.587(11) 3_445 7_545
Nd1 In Nd1 101.785(15) 3_445 7_545
Nd1 In Nd1 78.215(15) 7 7_545
Ge1 In Nd1 55.547(11) 5_556 3_455
Ge1 In Nd1 124.453(11) 1_554 3_455
Nd2 In Nd1 113.051(11) 7_545 3_455
Nd2 In Nd1 66.949(11) 3_455 3_455
Nd2 In Nd1 65.587(11) 7 3_455
Nd2 In Nd1 114.413(12) 3_445 3_455
Nd1 In Nd1 78.215(15) 3_445 3_455
Nd1 In Nd1 101.785(15) 7 3_455
Nd1 In Nd1 180.000(8) 7_545 3_455
Ge1 Ge1 Mn 118.61(5) 5_556 .
Ge1 Ge1 In 110.41(4) 5_556 1_556
Mn Ge1 In 130.97(4) . 1_556
Ge1 Ge1 Nd1 133.469(14) 5_556 7_556
Mn Ge1 Nd1 77.11(2) . 7_556
In Ge1 Nd1 69.297(18) 1_556 7_556
Ge1 Ge1 Nd1 133.469(14) 5_556 7_546
Mn Ge1 Nd1 77.11(2) . 7_546
In Ge1 Nd1 69.297(18) 1_556 7_546
Nd1 Ge1 Nd1 91.38(2) 7_556 7_546
Ge1 Ge1 Nd2 67.56(2) 5_556 3_445
Mn Ge1 Nd2 69.81(2) . 3_445
In Ge1 Nd2 134.162(13) 1_556 3_445
Nd1 Ge1 Nd2 146.90(3) 7_556 3_445
Nd1 Ge1 Nd2 80.395(16) 7_546 3_445
Ge1 Ge1 Nd2 67.56(2) 5_556 3_455
Mn Ge1 Nd2 69.81(2) . 3_455
In Ge1 Nd2 134.162(13) 1_556 3_455
Nd1 Ge1 Nd2 80.395(16) 7_556 3_455
Nd1 Ge1 Nd2 146.90(3) 7_546 3_455
Nd2 Ge1 Nd2 89.17(2) 3_445 3_455
Ge1 Ge1 Nd2 64.22(2) 5_556 7_546
Mn Ge1 Nd2 136.266(13) . 7_546
In Ge1 Nd2 66.590(16) 1_556 7_546
Nd1 Ge1 Nd2 135.86(3) 7_556 7_546
Nd1 Ge1 Nd2 74.864(15) 7_546 7_546
Nd2 Ge1 Nd2 72.916(16) 3_445 7_546
Nd2 Ge1 Nd2 131.78(2) 3_455 7_546
Ge1 Ge1 Nd2 64.22(2) 5_556 7_556
Mn Ge1 Nd2 136.266(13) . 7_556
In Ge1 Nd2 66.590(16) 1_556 7_556
Nd1 Ge1 Nd2 74.864(15) 7_556 7_556
Nd1 Ge1 Nd2 135.86(3) 7_546 7_556
Nd2 Ge1 Nd2 131.78(2) 3_445 7_556
Nd2 Ge1 Nd2 72.916(16) 3_455 7_556
Nd2 Ge1 Nd2 86.29(2) 7_546 7_556
Mn Ge2 Mn 113.44(5) 7_556 7_546
Mn Ge2 Mn 73.56(3) 7_556 .
Mn Ge2 Mn 73.56(3) 7_546 .
Mn Ge2 Nd1 76.23(3) 7_556 .
Mn Ge2 Nd1 76.23(3) 7_546 .
Mn Ge2 Nd1 123.25(4) . .
Mn Ge2 Nd1 147.74(4) 7_556 7_545
Mn Ge2 Nd1 71.70(3) 7_546 7_545
Mn Ge2 Nd1 134.967(15) . 7_545
Nd1 Ge2 Nd1 74.317(19) . 7_545
Mn Ge2 Nd1 71.70(3) 7_556 7
Mn Ge2 Nd1 147.74(4) 7_546 7
Mn Ge2 Nd1 134.967(15) . 7
Nd1 Ge2 Nd1 74.317(19) . 7
Nd1 Ge2 Nd1 87.82(3) 7_545 7
Mn Ge2 Nd2 139.95(4) 7_556 3_445
Mn Ge2 Nd2 67.46(3) 7_546 3_445
Mn Ge2 Nd2 68.49(2) . 3_445
Nd1 Ge2 Nd2 136.516(12) . 3_445
Nd1 Ge2 Nd2 72.228(15) 7_545 3_445
Nd1 Ge2 Nd2 130.38(3) 7 3_445
Mn Ge2 Nd2 67.46(3) 7_556 3_455
Mn Ge2 Nd2 139.95(4) 7_546 3_455
Mn Ge2 Nd2 68.49(2) . 3_455
Nd1 Ge2 Nd2 136.516(12) . 3_455
Nd1 Ge2 Nd2 130.38(3) 7_545 3_455
Nd1 Ge2 Nd2 72.228(15) 7 3_455
Nd2 Ge2 Nd2 86.81(2) 3_445 3_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Nd1 Ge1 3.0265(6) 7_556
Nd1 Ge1 3.0265(6) 7_546
Nd1 Ge2 3.0872(9) .
Nd1 Ge2 3.1227(7) 7_545
Nd1 Ge2 3.1227(7) 7
Nd1 Mn 3.3738(12) 1_554
Nd1 In 3.4333(5) 3
Nd1 In 3.4333(5) 3_545
Nd1 Mn 3.5262(9) 7_556
Nd1 Mn 3.5262(9) 7_546
Nd1 Nd2 3.6982(7) 5_655
Nd1 Nd1 3.7510(7) 7_545
Nd2 Ge1 3.0852(7) 3
Nd2 Ge1 3.0852(7) 3_545
Nd2 Ge2 3.1517(7) 3
Nd2 Ge2 3.1517(7) 3_545
Nd2 Ge1 3.1669(7) 7_546
Nd2 Ge1 3.1669(7) 7_556
Nd2 Mn 3.2222(12) 5_656
Nd2 Mn 3.2805(9) 3
Nd2 Mn 3.2805(9) 3_545
Nd2 In 3.3945(5) 3_545
Nd2 In 3.3945(5) 3
Nd2 Nd1 3.6981(7) 5_655
Mn Ge2 2.5904(8) 7_556
Mn Ge2 2.5904(8) 7_546
Mn Ge1 2.6067(13) .
Mn Ge2 2.6272(14) .
Mn Mn 3.1242(16) 7_546
Mn Mn 3.1242(16) 7_556
Mn Nd2 3.2223(12) 5_656
Mn Nd2 3.2806(9) 3_445
Mn Nd2 3.2806(9) 3_455
Mn Nd1 3.3737(12) 1_556
Mn Nd1 3.5263(9) 7_556
Mn Nd1 3.5263(9) 7_546
In Ge1 3.0123(8) 5_556
In Ge1 3.0123(8) 1_554
In Nd2 3.3945(5) 7_545
In Nd2 3.3945(5) 3_455
In Nd2 3.3945(5) 7
In Nd2 3.3945(5) 3_445
In Nd1 3.4333(5) 3_445
In Nd1 3.4333(5) 7
In Nd1 3.4333(5) 7_545
In Nd1 3.4333(5) 3_455
Ge1 Ge1 2.5549(15) 5_556
Ge1 In 3.0123(8) 1_556
Ge1 Nd1 3.0265(6) 7_556
Ge1 Nd1 3.0265(6) 7_546
Ge1 Nd2 3.0852(7) 3_445
Ge1 Nd2 3.0852(7) 3_455
Ge1 Nd2 3.1668(7) 7_546
Ge1 Nd2 3.1668(7) 7_556
Ge2 Mn 2.5904(8) 7_556
Ge2 Mn 2.5904(8) 7_546
Ge2 Nd1 3.1227(7) 7_545
Ge2 Nd1 3.1227(7) 7
Ge2 Nd2 3.1517(7) 3_445
Ge2 Nd2 3.1517(7) 3_455
