#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/55/4335511.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4335511
loop_
_publ_author_name
'Anton O. Oliynyk'
'Stanislav S. Stoyko'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Quaternary Germanides RE4Mn2InGe4 (RE = La-Nd, Sm, Gd-Tm, Lu)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8264
_journal_page_last               8271
_journal_paper_doi               10.1021/ic401171v
_journal_volume                  52
_journal_year                    2013
_chemical_formula_structural     'Sm4 Mn2 In0.90 Ge4'
_chemical_formula_sum            'Ge4 In0.9 Mn2 Sm4'
_chemical_formula_weight         1104.98
_chemical_name_common
'samarium manganese indium germanide (4/2/1/4)'
_chemical_name_systematic
'samarium manganese indium germanide (4/2/1/4)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.458(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.093(2)
_cell_length_b                   4.2718(6)
_cell_length_c                   7.2124(10)
_cell_measurement_reflns_used    2926
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.65
_cell_measurement_theta_min      4.48
_cell_volume                     475.51(11)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0334
_diffrn_reflns_av_sigmaI/netI    0.0317
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3390
_diffrn_reflns_theta_full        33.15
_diffrn_reflns_theta_max         33.15
_diffrn_reflns_theta_min         2.64
_exptl_absorpt_coefficient_mu    41.314
_exptl_absorpt_correction_T_max  0.3786
_exptl_absorpt_correction_T_min  0.1748
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.717
_exptl_crystal_description       irregular
_exptl_crystal_F_000             940
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_refine_diff_density_max         3.342
_refine_diff_density_min         -1.404
_refine_diff_density_rms         0.411
_refine_ls_extinction_coef       0.00121(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_matrix_type           full
_refine_ls_number_parameters     37
_refine_ls_number_reflns         994
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0252
_refine_ls_R_factor_gt           0.0223
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0259P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0516
_refine_ls_wR_factor_ref         0.0525
_reflns_number_gt                896
_reflns_number_total             994
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic401171v_si_002_6.cif
_cod_data_source_block           Sm4Mn2InGe4
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_original_formula_sum        'Ge4 In0.90 Mn2 Sm4'
_cod_database_code               4335511
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sm1 Sm 0.346969(19) 0.0000 0.07277(4) 0.00610(9) Uani 1 2 d S
Sm2 Sm 0.58089(2) 0.0000 0.36627(4) 0.00616(9) Uani 1 2 d S
Mn Mn 0.21956(6) 0.0000 0.61928(13) 0.00666(17) Uani 1 2 d S
In In 0.0000 0.0000 0.0000 0.00871(19) Uani 0.904(3) 4 d SP
Ge1 Ge 0.06377(4) 0.0000 0.65308(9) 0.00637(13) Uani 1 2 d S
Ge2 Ge 0.19588(4) 0.0000 0.24653(9) 0.00732(14) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge1 Sm1 Ge1 91.27(2) 7_556 7_546
Ge1 Sm1 Ge2 91.028(18) 7_556 .
Ge1 Sm1 Ge2 91.028(18) 7_546 .
Ge1 Sm1 Ge2 163.08(2) 7_556 7_545
Ge1 Sm1 Ge2 87.868(16) 7_546 7_545
Ge2 Sm1 Ge2 105.877(16) . 7_545
Ge1 Sm1 Ge2 87.868(16) 7_556 7
Ge1 Sm1 Ge2 163.08(2) 7_546 7
Ge2 Sm1 Ge2 105.878(16) . 7
Ge2 Sm1 Ge2 88.08(2) 7_545 7
Ge1 Sm1 Mn 134.142(11) 7_556 1_554
Ge1 Sm1 Mn 134.142(11) 7_546 1_554
Ge2 Sm1 Mn 93.62(2) . 1_554
Ge2 Sm1 Mn 47.098(13) 7_545 1_554
Ge2 Sm1 Mn 47.098(13) 7 1_554
Ge1 Sm1 In 54.652(14) 7_556 3
Ge1 Sm1 In 108.469(16) 7_546 3
Ge2 Sm1 In 139.591(7) . 3
Ge2 Sm1 In 109.782(15) 7_545 3
Ge2 Sm1 In 57.852(14) 7 3
Mn Sm1 In 96.849(16) 1_554 3
Ge1 Sm1 In 108.469(16) 7_556 3_545
Ge1 Sm1 In 54.652(14) 7_546 3_545
Ge2 Sm1 In 139.591(7) . 3_545
Ge2 Sm1 In 57.852(14) 7_545 3_545
Ge2 Sm1 In 109.782(15) 7 3_545
Mn Sm1 In 96.849(16) 1_554 3_545
In Sm1 In 77.537(12) 3 3_545
Ge1 Sm1 Mn 46.57(2) 7_556 7_556
Ge1 Sm1 Mn 101.22(2) 7_546 7_556
Ge2 Sm1 Mn 46.016(15) . 7_556
Ge2 Sm1 Mn 149.89(2) 7_545 7_556
Ge2 Sm1 Mn 90.427(18) 7 7_556
Mn Sm1 Mn 114.429(18) 1_554 7_556
In Sm1 Mn 94.612(14) 3 7_556
In Sm1 Mn 148.531(18) 3_545 7_556
Ge1 Sm1 Mn 101.22(2) 7_556 7_546
Ge1 Sm1 Mn 46.57(2) 7_546 7_546
Ge2 Sm1 Mn 46.016(15) . 7_546
Ge2 Sm1 Mn 90.427(18) 7_545 7_546
Ge2 Sm1 Mn 149.89(2) 7 7_546
Mn Sm1 Mn 114.429(18) 1_554 7_546
In Sm1 Mn 148.531(18) 3 7_546
In Sm1 Mn 94.612(14) 3_545 7_546
Mn Sm1 Mn 76.17(2) 7_556 7_546
Ge1 Sm1 Sm2 111.155(15) 7_556 5_655
Ge1 Sm1 Sm2 111.155(15) 7_546 5_655
Ge2 Sm1 Sm2 147.456(17) . 5_655
Ge2 Sm1 Sm2 53.967(13) 7_545 5_655
Ge2 Sm1 Sm2 53.967(13) 7 5_655
Mn Sm1 Sm2 53.834(19) 1_554 5_655
In Sm1 Sm2 56.519(6) 3 5_655
In Sm1 Sm2 56.519(6) 3_545 5_655
Mn Sm1 Sm2 141.691(10) 7_556 5_655
Mn Sm1 Sm2 141.691(11) 7_546 5_655
Ge1 Sm1 Sm1 144.434(18) 7_556 7_545
Ge1 Sm1 Sm1 89.068(14) 7_546 7_545
Ge2 Sm1 Sm1 53.410(13) . 7_545
Ge2 Sm1 Sm1 52.467(14) 7_545 7_545
Ge2 Sm1 Sm1 101.391(17) 7 7_545
Mn Sm1 Sm1 58.923(14) 1_554 7_545
In Sm1 Sm1 155.545(14) 3 7_545
In Sm1 Sm1 100.579(12) 3_545 7_545
Mn Sm1 Sm1 98.602(19) 7_556 7_545
Mn Sm1 Sm1 55.506(17) 7_546 7_545
Sm2 Sm1 Sm1 101.767(12) 5_655 7_545
Ge1 Sm2 Ge1 89.28(2) 3 3_545
Ge1 Sm2 Ge2 83.221(16) 3 3
Ge1 Sm2 Ge2 148.09(2) 3_545 3
Ge1 Sm2 Ge2 148.09(2) 3 3_545
Ge1 Sm2 Ge2 83.221(16) 3_545 3_545
Ge2 Sm2 Ge2 86.95(2) 3 3_545
Ge1 Sm2 Ge1 107.448(13) 3 7_546
Ge1 Sm2 Ge1 48.84(2) 3_545 7_546
Ge2 Sm2 Ge1 161.91(2) 3 7_546
Ge2 Sm2 Ge1 90.719(16) 3_545 7_546
Ge1 Sm2 Ge1 48.84(2) 3 7_556
Ge1 Sm2 Ge1 107.448(13) 3_545 7_556
Ge2 Sm2 Ge1 90.719(17) 3 7_556
Ge2 Sm2 Ge1 161.91(2) 3_545 7_556
Ge1 Sm2 Ge1 85.95(2) 7_546 7_556
Ge1 Sm2 Mn 105.236(18) 3 5_656
Ge1 Sm2 Mn 105.236(18) 3_545 5_656
Ge2 Sm2 Mn 48.228(13) 3 5_656
Ge2 Sm2 Mn 48.228(13) 3_545 5_656
Ge1 Sm2 Mn 137.003(10) 7_546 5_656
Ge1 Sm2 Mn 137.003(10) 7_556 5_656
Ge1 Sm2 Mn 48.42(2) 3 3
Ge1 Sm2 Mn 105.06(2) 3_545 3
Ge2 Sm2 Mn 48.36(2) 3 3
Ge2 Sm2 Mn 103.87(2) 3_545 3
Ge1 Sm2 Mn 148.90(2) 7_546 3
Ge1 Sm2 Mn 87.729(19) 7_556 3
Mn Sm2 Mn 57.03(2) 5_656 3
Ge1 Sm2 Mn 105.06(2) 3 3_545
Ge1 Sm2 Mn 48.42(2) 3_545 3_545
Ge2 Sm2 Mn 103.87(2) 3 3_545
Ge2 Sm2 Mn 48.36(2) 3_545 3_545
Ge1 Sm2 Mn 87.729(19) 7_546 3_545
Ge1 Sm2 Mn 148.90(2) 7_556 3_545
Mn Sm2 Mn 57.03(2) 5_656 3_545
Mn Sm2 Mn 82.16(3) 3 3_545
Ge1 Sm2 In 153.150(17) 3 3_545
Ge1 Sm2 In 89.927(14) 3_545 3_545
Ge2 Sm2 In 110.328(15) 3 3_545
Ge2 Sm2 In 58.168(14) 3_545 3_545
Ge1 Sm2 In 54.133(12) 7_546 3_545
Ge1 Sm2 In 106.312(15) 7_556 3_545
Mn Sm2 In 100.855(14) 5_656 3_545
Mn Sm2 In 155.601(19) 3 3_545
Mn Sm2 In 94.309(15) 3_545 3_545
Ge1 Sm2 In 89.927(14) 3 3
Ge1 Sm2 In 153.150(17) 3_545 3
Ge2 Sm2 In 58.168(14) 3 3
Ge2 Sm2 In 110.328(15) 3_545 3
Ge1 Sm2 In 106.312(15) 7_546 3
Ge1 Sm2 In 54.133(12) 7_556 3
Mn Sm2 In 100.855(14) 5_656 3
Mn Sm2 In 94.309(15) 3 3
Mn Sm2 In 155.601(19) 3_545 3
In Sm2 In 78.954(13) 3_545 3
Ge1 Sm2 Sm2 54.908(12) 3 5_656
Ge1 Sm2 Sm2 54.908(12) 3_545 5_656
Ge2 Sm2 Sm2 135.811(10) 3 5_656
Ge2 Sm2 Sm2 135.811(10) 3_545 5_656
Ge1 Sm2 Sm2 52.540(12) 7_546 5_656
Ge1 Sm2 Sm2 52.540(12) 7_556 5_656
Mn Sm2 Sm2 147.78(2) 5_656 5_656
Mn Sm2 Sm2 100.50(2) 3 5_656
Mn Sm2 Sm2 100.50(2) 3_545 5_656
In Sm2 Sm2 103.877(12) 3_545 5_656
In Sm2 Sm2 103.877(12) 3 5_656
Ge2 Mn Ge2 112.43(4) 7_556 7_546
Ge2 Mn Ge1 112.86(3) 7_556 .
Ge2 Mn Ge1 112.86(3) 7_546 .
Ge2 Mn Ge2 107.19(3) 7_556 .
Ge2 Mn Ge2 107.19(3) 7_546 .
Ge1 Mn Ge2 103.58(4) . .
Ge2 Mn Mn 124.75(5) 7_556 7_546
Ge2 Mn Mn 54.14(2) 7_546 7_546
Ge1 Mn Mn 121.61(4) . 7_546
Ge2 Mn Mn 53.05(3) . 7_546
Ge2 Mn Mn 54.14(2) 7_556 7_556
Ge2 Mn Mn 124.75(5) 7_546 7_556
Ge1 Mn Mn 121.61(4) . 7_556
Ge2 Mn Mn 53.05(3) . 7_556
Mn Mn Mn 88.10(5) 7_546 7_556
Ge2 Mn Sm2 64.28(2) 7_556 5_656
Ge2 Mn Sm2 64.28(2) 7_546 5_656
Ge1 Mn Sm2 173.02(4) . 5_656
Ge2 Mn Sm2 83.40(3) . 5_656
Mn Mn Sm2 62.58(3) 7_546 5_656
Mn Mn Sm2 62.58(3) 7_556 5_656
Ge2 Mn Sm2 164.51(3) 7_556 3_445
Ge2 Mn Sm2 82.609(17) 7_546 3_445
Ge1 Mn Sm2 61.53(2) . 3_445
Ge2 Mn Sm2 62.89(2) . 3_445
Mn Mn Sm2 60.38(3) 7_546 3_445
Mn Mn Sm2 114.81(4) 7_556 3_445
Sm2 Mn Sm2 122.97(2) 5_656 3_445
Ge2 Mn Sm2 82.609(17) 7_556 3_455
Ge2 Mn Sm2 164.51(3) 7_546 3_455
Ge1 Mn Sm2 61.53(2) . 3_455
Ge2 Mn Sm2 62.89(2) . 3_455
Mn Mn Sm2 114.81(4) 7_546 3_455
Mn Mn Sm2 60.38(3) 7_556 3_455
Sm2 Mn Sm2 122.97(2) 5_656 3_455
Sm2 Mn Sm2 82.16(3) 3_445 3_455
Ge2 Mn Sm1 61.14(2) 7_556 1_556
Ge2 Mn Sm1 61.14(2) 7_546 1_556
Ge1 Mn Sm1 104.52(3) . 1_556
Ge2 Mn Sm1 151.90(4) . 1_556
Mn Mn Sm1 110.16(4) 7_546 1_556
Mn Mn Sm1 110.16(4) 7_556 1_556
Sm2 Mn Sm1 68.49(2) 5_656 1_556
Sm2 Mn Sm1 133.218(17) 3_445 1_556
Sm2 Mn Sm1 133.218(17) 3_455 1_556
Ge2 Mn Sm1 58.18(2) 7_556 7_556
Ge2 Mn Sm1 119.87(3) 7_546 7_556
Ge1 Mn Sm1 57.006(18) . 7_556
Ge2 Mn Sm1 132.86(2) . 7_556
Mn Mn Sm1 173.61(3) 7_546 7_556
Mn Mn Sm1 97.816(18) 7_556 7_556
Sm2 Mn Sm1 118.13(2) 5_656 7_556
Sm2 Mn Sm1 118.53(3) 3_445 7_556
Sm2 Mn Sm1 70.540(16) 3_455 7_556
Sm1 Mn Sm1 65.572(18) 1_556 7_556
Ge2 Mn Sm1 119.87(3) 7_556 7_546
Ge2 Mn Sm1 58.18(2) 7_546 7_546
Ge1 Mn Sm1 57.006(18) . 7_546
Ge2 Mn Sm1 132.86(2) . 7_546
Mn Mn Sm1 97.816(18) 7_546 7_546
Mn Mn Sm1 173.61(3) 7_556 7_546
Sm2 Mn Sm1 118.13(2) 5_656 7_546
Sm2 Mn Sm1 70.540(16) 3_445 7_546
Sm2 Mn Sm1 118.53(3) 3_455 7_546
Sm1 Mn Sm1 65.572(18) 1_556 7_546
Sm1 Mn Sm1 76.18(2) 7_556 7_546
Ge1 In Ge1 180.00(2) 5_556 1_554
Ge1 In Ge2 86.904(19) 5_556 5
Ge1 In Ge2 93.096(19) 1_554 5
Ge1 In Ge2 93.097(19) 5_556 .
Ge1 In Ge2 86.903(19) 1_554 .
Ge2 In Ge2 180.0 5 .
Ge1 In Sm2 120.968(12) 5_556 7_545
Ge1 In Sm2 59.032(12) 1_554 7_545
Ge2 In Sm2 56.857(9) 5 7_545
Ge2 In Sm2 123.142(9) . 7_545
Ge1 In Sm2 59.032(12) 5_556 3_455
Ge1 In Sm2 120.968(12) 1_554 3_455
Ge2 In Sm2 123.143(9) 5 3_455
Ge2 In Sm2 56.858(9) . 3_455
Sm2 In Sm2 180.000(8) 7_545 3_455
Ge1 In Sm2 120.968(12) 5_556 7
Ge1 In Sm2 59.032(12) 1_554 7
Ge2 In Sm2 56.857(9) 5 7
Ge2 In Sm2 123.142(9) . 7
Sm2 In Sm2 78.953(12) 7_545 7
Sm2 In Sm2 101.047(13) 3_455 7
Ge1 In Sm2 59.032(12) 5_556 3_445
Ge1 In Sm2 120.968(12) 1_554 3_445
Ge2 In Sm2 123.143(9) 5 3_445
Ge2 In Sm2 56.858(9) . 3_445
Sm2 In Sm2 101.047(13) 7_545 3_445
Sm2 In Sm2 78.953(12) 3_455 3_445
Sm2 In Sm2 180.0 7 3_445
Ge1 In Sm1 55.376(10) 5_556 3_445
Ge1 In Sm1 124.624(10) 1_554 3_445
Ge2 In Sm1 55.680(11) 5 3_445
Ge2 In Sm1 124.321(11) . 3_445
Sm2 In Sm1 65.611(10) 7_545 3_445
Sm2 In Sm1 114.389(9) 3_455 3_445
Sm2 In Sm1 112.537(10) 7 3_445
Sm2 In Sm1 67.463(10) 3_445 3_445
Ge1 In Sm1 124.624(10) 5_556 7
Ge1 In Sm1 55.376(10) 1_554 7
Ge2 In Sm1 124.320(11) 5 7
Ge2 In Sm1 55.679(11) . 7
Sm2 In Sm1 114.389(9) 7_545 7
Sm2 In Sm1 65.611(10) 3_455 7
Sm2 In Sm1 67.463(10) 7 7
Sm2 In Sm1 112.537(10) 3_445 7
Sm1 In Sm1 180.000(7) 3_445 7
Ge1 In Sm1 55.376(10) 5_556 3_455
Ge1 In Sm1 124.624(10) 1_554 3_455
Ge2 In Sm1 55.680(11) 5 3_455
Ge2 In Sm1 124.321(11) . 3_455
Sm2 In Sm1 112.537(10) 7_545 3_455
Sm2 In Sm1 67.463(10) 3_455 3_455
Sm2 In Sm1 65.611(10) 7 3_455
Sm2 In Sm1 114.389(10) 3_445 3_455
Sm1 In Sm1 77.537(12) 3_445 3_455
Sm1 In Sm1 102.463(12) 7 3_455
Ge1 In Sm1 124.624(10) 5_556 7_545
Ge1 In Sm1 55.376(10) 1_554 7_545
Ge2 In Sm1 124.320(11) 5 7_545
Ge2 In Sm1 55.679(11) . 7_545
Sm2 In Sm1 67.463(10) 7_545 7_545
Sm2 In Sm1 112.537(10) 3_455 7_545
Sm2 In Sm1 114.389(10) 7 7_545
Sm2 In Sm1 65.611(10) 3_445 7_545
Sm1 In Sm1 102.463(12) 3_445 7_545
Sm1 In Sm1 77.537(12) 7 7_545
Sm1 In Sm1 180.000(10) 3_455 7_545
Ge1 Ge1 Mn 118.79(4) 5_556 .
Ge1 Ge1 In 110.15(4) 5_556 1_556
Mn Ge1 In 131.06(3) . 1_556
Ge1 Ge1 Sm1 133.650(12) 5_556 7_556
Mn Ge1 Sm1 76.42(2) . 7_556
In Ge1 Sm1 69.973(15) 1_556 7_556
Ge1 Ge1 Sm1 133.650(12) 5_556 7_546
Mn Ge1 Sm1 76.42(2) . 7_546
In Ge1 Sm1 69.973(15) 1_556 7_546
Sm1 Ge1 Sm1 91.27(2) 7_556 7_546
Ge1 Ge1 Sm2 67.49(2) 5_556 3_445
Mn Ge1 Sm2 70.046(19) . 3_445
In Ge1 Sm2 134.022(11) 1_556 3_445
Sm1 Ge1 Sm2 146.45(2) 7_556 3_445
Sm1 Ge1 Sm2 80.139(14) 7_546 3_445
Ge1 Ge1 Sm2 67.49(2) 5_556 3_455
Mn Ge1 Sm2 70.046(19) . 3_455
In Ge1 Sm2 134.022(11) 1_556 3_455
Sm1 Ge1 Sm2 80.139(14) 7_556 3_455
Sm1 Ge1 Sm2 146.45(2) 7_546 3_455
Sm2 Ge1 Sm2 89.28(2) 3_445 3_455
Ge1 Ge1 Sm2 63.67(2) 5_556 7_546
Mn Ge1 Sm2 136.349(12) . 7_546
In Ge1 Sm2 66.836(14) 1_556 7_546
Sm1 Ge1 Sm2 136.78(2) 7_556 7_546
Sm1 Ge1 Sm2 75.759(13) 7_546 7_546
Sm2 Ge1 Sm2 72.552(13) 3_445 7_546
Sm2 Ge1 Sm2 131.16(2) 3_455 7_546
Ge1 Ge1 Sm2 63.67(2) 5_556 7_556
Mn Ge1 Sm2 136.349(11) . 7_556
In Ge1 Sm2 66.836(14) 1_556 7_556
Sm1 Ge1 Sm2 75.759(13) 7_556 7_556
Sm1 Ge1 Sm2 136.78(2) 7_546 7_556
Sm2 Ge1 Sm2 131.16(2) 3_445 7_556
Sm2 Ge1 Sm2 72.552(13) 3_455 7_556
Sm2 Ge1 Sm2 85.95(2) 7_546 7_556
Mn Ge2 Mn 112.43(4) 7_556 7_546
Mn Ge2 Mn 72.81(3) 7_556 .
Mn Ge2 Mn 72.81(3) 7_546 .
Mn Ge2 Sm1 75.81(3) 7_556 .
Mn Ge2 Sm1 75.81(3) 7_546 .
Mn Ge2 Sm1 121.73(3) . .
Mn Ge2 Sm1 147.40(3) 7_556 7_545
Mn Ge2 Sm1 71.76(2) 7_546 7_545
Mn Ge2 Sm1 135.179(12) . 7_545
Sm1 Ge2 Sm1 74.124(16) . 7_545
Mn Ge2 Sm1 71.76(2) 7_556 7
Mn Ge2 Sm1 147.40(3) 7_546 7
Mn Ge2 Sm1 135.179(12) . 7
Sm1 Ge2 Sm1 74.124(16) . 7
Sm1 Ge2 Sm1 88.08(2) 7_545 7
Mn Ge2 Sm2 139.53(3) 7_556 3_445
Mn Ge2 Sm2 67.49(2) 7_546 3_445
Mn Ge2 Sm2 68.75(2) . 3_445
Sm1 Ge2 Sm2 136.499(10) . 3_445
Sm1 Ge2 Sm2 72.864(13) 7_545 3_445
Sm1 Ge2 Sm2 131.44(2) 7 3_445
Mn Ge2 Sm2 67.49(2) 7_556 3_455
Mn Ge2 Sm2 139.53(3) 7_546 3_455
Mn Ge2 Sm2 68.75(2) . 3_455
Sm1 Ge2 Sm2 136.499(10) . 3_455
Sm1 Ge2 Sm2 131.44(2) 7_545 3_455
Sm1 Ge2 Sm2 72.864(13) 7 3_455
Sm2 Ge2 Sm2 86.94(2) 3_445 3_455
Mn Ge2 In 123.44(2) 7_556 .
Mn Ge2 In 123.44(2) 7_546 .
Mn Ge2 In 114.38(3) . .
Sm1 Ge2 In 123.90(2) . .
Sm1 Ge2 In 66.468(14) 7_545 .
Sm1 Ge2 In 66.468(14) 7 .
Sm2 Ge2 In 64.974(15) 3_445 .
Sm2 Ge2 In 64.974(15) 3_455 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sm1 Ge1 2.9876(5) 7_556
Sm1 Ge1 2.9876(5) 7_546
Sm1 Ge2 3.0346(8) .
Sm1 Ge2 3.0727(6) 7_545
Sm1 Ge2 3.0727(6) 7
Sm1 Mn 3.3320(11) 1_554
Sm1 In 3.4110(4) 3
Sm1 In 3.4110(4) 3_545
Sm1 Mn 3.4625(8) 7_556
Sm1 Mn 3.4625(8) 7_546
Sm1 Sm2 3.6685(6) 5_655
Sm1 Sm1 3.6809(6) 7_545
Sm2 Ge1 3.0397(6) 3
Sm2 Ge1 3.0397(6) 3_545
Sm2 Ge2 3.1044(6) 3
Sm2 Ge2 3.1044(6) 3_545
Sm2 Ge1 3.1333(6) 7_546
Sm2 Ge1 3.1333(6) 7_556
Sm2 Mn 3.1833(11) 5_656
Sm2 Mn 3.2504(8) 3
Sm2 Mn 3.2504(8) 3_545
Sm2 In 3.3596(4) 3_545
Sm2 In 3.3596(4) 3
Sm2 Sm2 3.6532(7) 5_656
Mn Ge2 2.5699(7) 7_556
Mn Ge2 2.5699(7) 7_546
Mn Ge1 2.5868(12) .
Mn Ge2 2.6062(11) .
Mn Mn 3.0720(13) 7_546
Mn Mn 3.0720(13) 7_556
Mn Sm2 3.1833(11) 5_656
Mn Sm2 3.2503(8) 3_445
Mn Sm2 3.2503(8) 3_455
Mn Sm1 3.3320(11) 1_556
Mn Sm1 3.4625(8) 7_556
Mn Sm1 3.4625(8) 7_546
In Ge1 2.9613(7) 5_556
In Ge1 2.9613(7) 1_554
In Ge2 3.1500(8) 5
In Ge2 3.1500(8) .
In Sm2 3.3596(4) 7_545
In Sm2 3.3596(4) 3_455
In Sm2 3.3596(4) 7
In Sm2 3.3596(4) 3_445
In Sm1 3.4110(4) 3_445
In Sm1 3.4110(4) 7
In Sm1 3.4110(4) 3_455
In Sm1 3.4110(4) 7_545
Ge1 Ge1 2.5536(13) 5_556
Ge1 In 2.9612(7) 1_556
Ge1 Sm1 2.9876(5) 7_556
Ge1 Sm1 2.9876(5) 7_546
Ge1 Sm2 3.0397(6) 3_445
Ge1 Sm2 3.0397(6) 3_455
Ge1 Sm2 3.1333(6) 7_546
Ge1 Sm2 3.1333(6) 7_556
Ge2 Mn 2.5699(7) 7_556
Ge2 Mn 2.5699(7) 7_546
Ge2 Sm1 3.0727(6) 7_545
Ge2 Sm1 3.0727(6) 7
Ge2 Sm2 3.1045(6) 3_445
Ge2 Sm2 3.1045(6) 3_455
