#------------------------------------------------------------------------------
#$Date: 2019-11-25 00:17:03 +0200 (Mon, 25 Nov 2019) $
#$Revision: 239749 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/35/01/4350120.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4350120
loop_
_publ_author_name
'Dennett, James N. L.'
'Bierenstiel, Matthias'
'Ferguson, Michael J.'
'McDonald, Robert'
'Cowie, Martin'
_publ_section_title
;
 Various coordination modes of the
 bis(di(o-N,N-dimethylanilinyl)phosphino)methane ligand in mononuclear and
 binuclear complexes of group 8 and group 9 metals.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3705
_journal_page_last               3717
_journal_paper_doi               10.1021/ic051639c
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'C34 H42 Cl N4 O P2 Rh'
_chemical_formula_sum            'C34 H42 Cl N4 O P2 Rh'
_chemical_formula_weight         723.02
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'manual editing of SHELXL template'
_cell_angle_alpha                90.00
_cell_angle_beta                 104.966(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.6672(16)
_cell_length_b                   14.4312(15)
_cell_length_c                   15.6577(16)
_cell_measurement_reflns_used    7288
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      26.36
_cell_measurement_theta_min      2.56
_cell_volume                     3420.1(6)
_computing_cell_refinement       'Bruker SAINT (Bruker, 1997)'
_computing_data_collection       'Bruker SMART (Bruker, 1997)'
_computing_data_reduction        'Bruker SAINT (Bruker, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL (Bruker, 1997)'
_computing_publication_material  'Bruker SHELXTL (Bruker, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 8.192
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type
'Bruker PLATFORM diffractometer/SMART 1000 CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0301
_diffrn_reflns_av_sigmaI/netI    0.0265
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            25535
_diffrn_reflns_theta_full        26.39
_diffrn_reflns_theta_max         26.39
_diffrn_reflns_theta_min         1.95
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.704
_exptl_absorpt_correction_T_max  0.8010
_exptl_absorpt_correction_T_min  0.6982
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.404
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             1496
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.49
_exptl_crystal_size_min          0.33
_refine_diff_density_max         1.456
_refine_diff_density_min         -0.490
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     396
_refine_ls_number_reflns         6971
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.110
_refine_ls_R_factor_all          0.0413
_refine_ls_R_factor_gt           0.0357
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0459P)²+3.5716P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0958
_refine_ls_wR_factor_ref         0.1002
_reflns_number_gt                6182
_reflns_number_total             6971
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic051639csi20060223_121259.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4350120
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh Rh 0.300537(13) -0.145669(15) 0.226741(13) 0.03216(8) Uani 1 1 d .
Cl Cl 0.39891(6) -0.26692(7) 0.21101(7) 0.0703(3) Uani 1 1 d .
P1 P 0.21729(4) -0.02972(4) 0.24649(4) 0.02477(14) Uani 1 1 d .
P2 P 0.22498(4) 0.03319(5) 0.06601(4) 0.02727(14) Uani 1 1 d .
O1 O 0.14916(15) -0.26585(15) 0.14591(14) 0.0475(5) Uani 1 1 d .
N1 N 0.41126(15) -0.05252(19) 0.28825(16) 0.0402(6) Uani 1 1 d .
N2 N 0.26048(16) -0.08960(16) 0.43593(14) 0.0360(5) Uani 1 1 d .
N3 N 0.2596(3) 0.2317(2) 0.11955(18) 0.0725(11) Uani 1 1 d .
N4 N 0.29266(17) -0.02038(18) -0.08063(17) 0.0421(6) Uani 1 1 d .
C1 C 0.20730(19) -0.21801(19) 0.17704(17) 0.0335(6) Uani 1 1 d .
C10 C 0.15605(17) 0.03138(18) 0.14693(16) 0.0288(5) Uani 1 1 d .
H10A H 0.1429 0.0955 0.1620 0.035 Uiso 1 1 calc R
H10B H 0.0994 -0.0006 0.1209 0.035 Uiso 1 1 calc R
C11 C 0.29509(17) 0.05716(19) 0.30299(16) 0.0303(5) Uani 1 1 d .
C12 C 0.38413(17) 0.0378(2) 0.31732(17) 0.0347(6) Uani 1 1 d .
C13 C 0.4464(2) 0.1033(2) 0.3591(2) 0.0465(7) Uani 1 1 d .
H13 H 0.5076 0.0914 0.3670 0.056 Uiso 1 1 calc R
C14 C 0.4193(2) 0.1851(2) 0.3889(2) 0.0493(8) Uani 1 1 d .
H14 H 0.4620 0.2291 0.4182 0.059 Uiso 1 1 calc R
C15 C 0.3305(2) 0.2039(2) 0.37657(19) 0.0451(7) Uani 1 1 d .
H15 H 0.3123 0.2600 0.3982 0.054 Uiso 1 1 calc R
C16 C 0.2683(2) 0.14058(19) 0.33261(18) 0.0358(6) Uani 1 1 d .
H16 H 0.2071 0.1540 0.3226 0.043 Uiso 1 1 calc R
C17 C 0.4657(2) -0.1023(3) 0.3682(3) 0.0582(9) Uani 1 1 d .
H17A H 0.5208 -0.0683 0.3922 0.070 Uiso 1 1 calc R
H17B H 0.4793 -0.1649 0.3515 0.070 Uiso 1 1 calc R
H17C H 0.4325 -0.1061 0.4132 0.070 Uiso 1 1 calc R
C18 C 0.4655(2) -0.0371(3) 0.2240(3) 0.0630(10) Uani 1 1 d .
H18A H 0.5179 -0.0005 0.2522 0.076 Uiso 1 1 calc R
H18B H 0.4303 -0.0036 0.1724 0.076 Uiso 1 1 calc R
H18C H 0.4838 -0.0970 0.2051 0.076 Uiso 1 1 calc R
C21 C 0.13789(16) -0.04191(16) 0.31280(15) 0.0257(5) Uani 1 1 d .
C22 C 0.16749(18) -0.07387(18) 0.40013(16) 0.0308(5) Uani 1 1 d .
C23 C 0.1064(2) -0.0880(2) 0.44965(19) 0.0440(7) Uani 1 1 d .
H23 H 0.1261 -0.1101 0.5086 0.053 Uiso 1 1 calc R
C24 C 0.0180(2) -0.0703(2) 0.4144(2) 0.0486(8) Uani 1 1 d .
H24 H -0.0227 -0.0809 0.4489 0.058 Uiso 1 1 calc R
C25 C -0.0117(2) -0.0374(2) 0.3293(2) 0.0433(7) Uani 1 1 d .
H25 H -0.0727 -0.0246 0.3053 0.052 Uiso 1 1 calc R
C26 C 0.04835(17) -0.02300(19) 0.27880(17) 0.0330(6) Uani 1 1 d .
H26 H 0.0279 0.0001 0.2202 0.040 Uiso 1 1 calc R
C27 C 0.2807(2) -0.1864(2) 0.4593(2) 0.0519(8) Uani 1 1 d .
H27A H 0.2613 -0.2251 0.4063 0.062 Uiso 1 1 calc R
H27B H 0.2498 -0.2057 0.5033 0.062 Uiso 1 1 calc R
H27C H 0.3445 -0.1936 0.4838 0.062 Uiso 1 1 calc R
C28 C 0.2982(3) -0.0282(3) 0.5106(2) 0.0570(9) Uani 1 1 d .
H28A H 0.2825 0.0361 0.4934 0.068 Uiso 1 1 calc R
H28B H 0.3626 -0.0348 0.5276 0.068 Uiso 1 1 calc R
H28C H 0.2746 -0.0449 0.5607 0.068 Uiso 1 1 calc R
C31 C 0.17237(18) 0.13571(18) 0.00174(17) 0.0304(5) Uani 1 1 d .
C32 C 0.1936(2) 0.2246(2) 0.03824(19) 0.0446(7) Uani 1 1 d .
C33 C 0.1473(3) 0.3010(2) -0.0048(2) 0.0529(9) Uani 1 1 d .
H33 H 0.1601 0.3607 0.0208 0.064 Uiso 1 1 calc R
C34 C 0.0838(2) 0.2923(2) -0.0832(2) 0.0508(8) Uani 1 1 d .
H34 H 0.0526 0.3452 -0.1110 0.061 Uiso 1 1 calc R
C35 C 0.0660(2) 0.2065(2) -0.1210(2) 0.0483(8) Uani 1 1 d .
H35 H 0.0235 0.2000 -0.1762 0.058 Uiso 1 1 calc R
C36 C 0.10979(19) 0.1293(2) -0.0787(2) 0.0372(6) Uani 1 1 d .
H36 H 0.0966 0.0702 -0.1056 0.045 Uiso 1 1 calc R
C37 C 0.2519(6) 0.3146(3) 0.1717(3) 0.145(3) Uani 1 1 d .
H37A H 0.1925 0.3173 0.1811 0.174 Uiso 1 1 calc R
H37B H 0.2622 0.3701 0.1397 0.174 Uiso 1 1 calc R
H37C H 0.2958 0.3116 0.2289 0.174 Uiso 1 1 calc R
C38 C 0.3487(3) 0.2189(4) 0.1112(3) 0.104(2) Uani 1 1 d .
H38A H 0.3509 0.1637 0.0753 0.125 Uiso 1 1 calc R
H38B H 0.3890 0.2109 0.1700 0.125 Uiso 1 1 calc R
H38C H 0.3664 0.2734 0.0826 0.125 Uiso 1 1 calc R
C41 C 0.17365(17) -0.05723(17) -0.01381(16) 0.0276(5) Uani 1 1 d .
C42 C 0.21239(19) -0.06903(18) -0.08486(17) 0.0333(6) Uani 1 1 d .
C43 C 0.1705(2) -0.1239(2) -0.1562(2) 0.0463(7) Uani 1 1 d .
H43 H 0.1948 -0.1292 -0.2057 0.056 Uiso 1 1 calc R
C44 C 0.0937(2) -0.1708(2) -0.1559(2) 0.0525(8) Uani 1 1 d .
H44 H 0.0654 -0.2079 -0.2052 0.063 Uiso 1 1 calc R
C45 C 0.0579(2) -0.1643(2) -0.0845(2) 0.0453(7) Uani 1 1 d .
H45 H 0.0067 -0.1990 -0.0830 0.054 Uiso 1 1 calc R
C46 C 0.09763(18) -0.10631(19) -0.01439(19) 0.0354(6) Uani 1 1 d .
H46 H 0.0720 -0.1003 0.0341 0.042 Uiso 1 1 calc R
C47 C 0.3048(3) 0.0106(3) -0.1655(3) 0.0774(13) Uani 1 1 d .
H47A H 0.2518 0.0438 -0.1982 0.093 Uiso 1 1 calc R
H47B H 0.3146 -0.0432 -0.1999 0.093 Uiso 1 1 calc R
H47C H 0.3560 0.0520 -0.1554 0.093 Uiso 1 1 calc R
C48 C 0.3697(2) -0.0705(3) -0.0306(3) 0.0601(9) Uani 1 1 d .
H48A H 0.3584 -0.0943 0.0240 0.072 Uiso 1 1 calc R
H48B H 0.4207 -0.0286 -0.0160 0.072 Uiso 1 1 calc R
H48C H 0.3821 -0.1223 -0.0660 0.072 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C1 Rh P1 93.31(9)
C1 Rh N1 177.73(10)
P1 Rh N1 84.42(7)
C1 Rh Cl 90.21(9)
P1 Rh Cl 176.41(3)
N1 Rh Cl 92.05(7)
C11 P1 C21 105.11(11)
C11 P1 C10 102.76(12)
C21 P1 C10 104.28(11)
C11 P1 Rh 104.32(9)
C21 P1 Rh 121.67(8)
C10 P1 Rh 116.57(8)
C41 P2 C31 98.14(11)
C41 P2 C10 102.89(12)
C31 P2 C10 97.20(11)
C12 N1 C18 109.6(3)
C12 N1 C17 108.1(2)
C18 N1 C17 109.5(3)
C12 N1 Rh 114.51(16)
C18 N1 Rh 108.5(2)
C17 N1 Rh 106.6(2)
C22 N2 C27 112.4(2)
C22 N2 C28 112.0(2)
C27 N2 C28 111.3(2)
C32 N3 C38 113.9(3)
C32 N3 C37 114.3(4)
C38 N3 C37 111.9(5)
C42 N4 C48 112.4(2)
C42 N4 C47 115.4(3)
C48 N4 C47 111.0(3)
O1 C1 Rh 178.4(3)
P1 C10 P2 108.48(13)
C12 C11 C16 119.9(3)
C12 C11 P1 117.6(2)
C16 C11 P1 122.5(2)
C11 C12 C13 119.6(3)
C11 C12 N1 119.1(2)
C13 C12 N1 121.3(3)
C14 C13 C12 120.0(3)
C13 C14 C15 120.6(3)
C14 C15 C16 119.7(3)
C15 C16 C11 120.1(3)
C26 C21 C22 118.9(2)
C26 C21 P1 122.10(18)
C22 C21 P1 118.95(19)
C23 C22 C21 119.3(3)
C23 C22 N2 122.2(2)
C21 C22 N2 118.6(2)
C24 C23 C22 120.9(3)
C23 C24 C25 120.4(3)
C24 C25 C26 119.4(3)
C25 C26 C21 121.0(3)
C36 C31 C32 117.9(3)
C36 C31 P2 123.4(2)
C32 C31 P2 118.7(2)
C33 C32 C31 119.0(3)
C33 C32 N3 122.9(3)
C31 C32 N3 118.1(3)
C34 C33 C32 121.8(3)
C35 C34 C33 119.2(3)
C34 C35 C36 120.1(3)
C35 C36 C31 121.8(3)
C46 C41 C42 118.6(2)
C46 C41 P2 126.3(2)
C42 C41 P2 114.83(19)
C43 C42 C41 119.6(3)
C43 C42 N4 123.1(3)
C41 C42 N4 117.3(2)
C44 C43 C42 120.5(3)
C45 C44 C43 120.5(3)
C44 C45 C46 119.2(3)
C41 C46 C45 121.5(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Rh C1 1.801(3)
Rh P1 2.1921(7)
Rh N1 2.209(2)
Rh Cl 2.3862(8)
P1 C11 1.812(3)
P1 C21 1.823(2)
P1 C10 1.832(2)
P2 C41 1.842(3)
P2 C31 1.858(3)
P2 C10 1.865(3)
O1 C1 1.147(3)
N1 C12 1.479(4)
N1 C18 1.492(4)
N1 C17 1.504(4)
N2 C22 1.438(4)
N2 C27 1.458(4)
N2 C28 1.464(4)
N3 C32 1.422(4)
N3 C38 1.447(7)
N3 C37 1.470(6)
N4 C42 1.427(4)
N4 C48 1.451(4)
N4 C47 1.460(4)
C11 C12 1.383(4)
C11 C16 1.393(4)
C12 C13 1.394(4)
C13 C14 1.377(5)
C14 C15 1.380(5)
C15 C16 1.383(4)
C21 C26 1.393(4)
C21 C22 1.404(3)
C22 C23 1.393(4)
C23 C24 1.376(5)
C24 C25 1.377(5)
C25 C26 1.393(4)
C31 C36 1.385(4)
C31 C32 1.408(4)
C32 C33 1.394(5)
C33 C34 1.372(5)
C34 C35 1.369(5)
C35 C36 1.385(4)
C41 C46 1.384(4)
C41 C42 1.408(4)
C42 C43 1.389(4)
C43 C44 1.382(5)
C44 C45 1.378(5)
C45 C46 1.393(4)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 Rh P1 C11 177.33(12)
N1 Rh P1 C11 -2.71(11)
Cl Rh P1 C11 8.7(6)
C1 Rh P1 C21 59.06(12)
N1 Rh P1 C21 -120.98(11)
Cl Rh P1 C21 -109.6(6)
C1 Rh P1 C10 -70.19(13)
N1 Rh P1 C10 109.78(12)
Cl Rh P1 C10 121.1(6)
C1 Rh N1 C12 3(3)
P1 Rh N1 C12 2.48(18)
Cl Rh N1 C12 -176.82(18)
C1 Rh N1 C18 -119(3)
P1 Rh N1 C18 -120.2(2)
Cl Rh N1 C18 60.5(2)
C1 Rh N1 C17 123(3)
P1 Rh N1 C17 122.0(2)
Cl Rh N1 C17 -57.3(2)
P1 Rh C1 O1 -158(9)
N1 Rh C1 O1 -158(7)
Cl Rh C1 O1 22(9)
C11 P1 C10 P2 78.61(15)
C21 P1 C10 P2 -171.91(12)
Rh P1 C10 P2 -34.76(16)
C41 P2 C10 P1 102.92(14)
C31 P2 C10 P1 -156.98(14)
C21 P1 C11 C12 132.3(2)
C10 P1 C11 C12 -118.9(2)
Rh P1 C11 C12 3.2(2)
C21 P1 C11 C16 -47.0(2)
C10 P1 C11 C16 61.8(2)
Rh P1 C11 C16 -176.1(2)
C16 C11 C12 C13 -1.9(4)
P1 C11 C12 C13 178.8(2)
C16 C11 C12 N1 177.8(2)
P1 C11 C12 N1 -1.5(3)
C18 N1 C12 C11 121.0(3)
C17 N1 C12 C11 -119.7(3)
Rh N1 C12 C11 -1.1(3)
C18 N1 C12 C13 -59.4(3)
C17 N1 C12 C13 59.9(4)
Rh N1 C12 C13 178.6(2)
C11 C12 C13 C14 2.5(4)
N1 C12 C13 C14 -177.2(3)
C12 C13 C14 C15 -1.0(5)
C13 C14 C15 C16 -1.1(5)
C14 C15 C16 C11 1.7(4)
C12 C11 C16 C15 -0.2(4)
P1 C11 C16 C15 179.0(2)
C11 P1 C21 C26 119.0(2)
C10 P1 C21 C26 11.3(2)
Rh P1 C21 C26 -123.1(2)
C11 P1 C21 C22 -62.8(2)
C10 P1 C21 C22 -170.6(2)
Rh P1 C21 C22 55.1(2)
C26 C21 C22 C23 1.6(4)
P1 C21 C22 C23 -176.7(2)
C26 C21 C22 N2 -177.5(2)
P1 C21 C22 N2 4.3(3)
C27 N2 C22 C23 63.7(3)
C28 N2 C22 C23 -62.5(4)
C27 N2 C22 C21 -117.3(3)
C28 N2 C22 C21 116.5(3)
C21 C22 C23 C24 -0.6(4)
N2 C22 C23 C24 178.5(3)
C22 C23 C24 C25 -0.6(5)
C23 C24 C25 C26 0.7(5)
C24 C25 C26 C21 0.4(5)
C22 C21 C26 C25 -1.5(4)
P1 C21 C26 C25 176.7(2)
C41 P2 C31 C36 3.8(3)
C10 P2 C31 C36 -100.4(2)
C41 P2 C31 C32 -179.5(2)
C10 P2 C31 C32 76.3(2)
C36 C31 C32 C33 3.9(4)
P2 C31 C32 C33 -173.0(2)
C36 C31 C32 N3 -178.2(3)
P2 C31 C32 N3 4.9(4)
C38 N3 C32 C33 -107.5(4)
C37 N3 C32 C33 23.0(6)
C38 N3 C32 C31 74.8(4)
C37 N3 C32 C31 -154.8(4)
C31 C32 C33 C34 -2.2(5)
N3 C32 C33 C34 -180.0(3)
C32 C33 C34 C35 -0.8(5)
C33 C34 C35 C36 2.0(5)
C34 C35 C36 C31 -0.2(5)
C32 C31 C36 C35 -2.8(4)
P2 C31 C36 C35 174.0(2)
C31 P2 C41 C46 -94.3(2)
C10 P2 C41 C46 5.1(3)
C31 P2 C41 C42 79.1(2)
C10 P2 C41 C42 178.48(19)
C46 C41 C42 C43 4.6(4)
P2 C41 C42 C43 -169.4(2)
C46 C41 C42 N4 -177.5(2)
P2 C41 C42 N4 8.5(3)
C48 N4 C42 C43 -97.2(3)
C47 N4 C42 C43 31.4(4)
C48 N4 C42 C41 84.9(3)
C47 N4 C42 C41 -146.4(3)
C41 C42 C43 C44 -3.5(4)
N4 C42 C43 C44 178.7(3)
C42 C43 C44 C45 -0.4(5)
C43 C44 C45 C46 3.1(5)
C42 C41 C46 C45 -1.9(4)
P2 C41 C46 C45 171.3(2)
C44 C45 C46 C41 -1.9(4)
