#------------------------------------------------------------------------------
#$Date: 2019-11-25 00:34:17 +0200 (Mon, 25 Nov 2019) $
#$Revision: 239771 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/35/01/4350185.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4350185
loop_
_publ_author_name
'Dong, Yu-Bin'
'Xu, Hong-Xia'
'Ma, Jian-Ping'
'Huang, Ru-Qi'
_publ_section_title
;
 Silver(I) coordination polymers based on a nano-sized bent
 bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole ligand: the role of
 ligand isomerism and the templating effect of polyatomic anions and
 solvent intermediates.
;
_journal_issue                   8
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3325
_journal_page_last               3343
_journal_paper_doi               10.1021/ic052158w
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C40 H22 Ag2 F6 N4 O7 S2'
_chemical_formula_weight         1064.48
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.202(3)
_cell_angle_beta                 97.789(3)
_cell_angle_gamma                110.376(3)
_cell_formula_units_Z            2
_cell_length_a                   10.181(2)
_cell_length_b                   12.826(3)
_cell_length_c                   17.657(4)
_cell_measurement_temperature    298(2)
_cell_volume                     2123.4(8)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0269
_diffrn_reflns_av_sigmaI/netI    0.0680
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            11769
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.71
_exptl_absorpt_coefficient_mu    1.100
_exptl_absorpt_correction_T_max  0.8101
_exptl_absorpt_correction_T_min  0.4060
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.665
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       bar
_exptl_crystal_F_000             1052
_exptl_crystal_size_max          1.00
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.644
_refine_diff_density_min         -0.435
_refine_diff_density_rms         '0.095 End ===='
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     520
_refine_ls_number_reflns         8092
_refine_ls_number_restraints     19
_refine_ls_restrained_S_all      1.004
_refine_ls_R_factor_all          0.1091
_refine_ls_R_factor_gt           0.0570
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0700P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1332
_refine_ls_wR_factor_ref         0.1480
_reflns_number_gt                4486
_reflns_number_total             8092
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic052158wsi20051219_053724.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        2123.2(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4350185
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.87220(6) 0.70925(4) 0.14269(3) 0.0730(2) Uani 1 1 d .
Ag2 Ag 1.13858(6) 0.60905(4) 0.22287(3) 0.0771(2) Uani 1 1 d .
N1 N 0.8727(4) 0.5475(3) 0.0825(2) 0.0452(10) Uani 1 1 d .
N2 N 0.9691(4) 0.5039(3) 0.1217(2) 0.0460(10) Uani 1 1 d .
N3 N 1.7026(6) 0.3838(5) 0.6817(3) 0.0887(18) Uani 1 1 d .
N4 N 0.2026(6) 1.1554(5) -0.1354(3) 0.0831(17) Uani 1 1 d .
C1 C 1.3526(8) 0.3394(8) 0.4589(5) 0.112(3) Uani 1 1 d .
H1 H 1.2631 0.3448 0.4515 0.135 Uiso 1 1 calc R
C2 C 1.4276(9) 0.3551(8) 0.5354(4) 0.115(3) Uani 1 1 d .
H2 H 1.3859 0.3671 0.5773 0.138 Uiso 1 1 calc R
C3 C 1.5570(7) 0.3525(6) 0.5460(4) 0.0737(18) Uani 1 1 d .
C4 C 1.6371(7) 0.3695(6) 0.6217(4) 0.0791(19) Uani 1 1 d .
C5 C 1.6142(10) 0.3326(10) 0.4854(5) 0.141(4) Uani 1 1 d .
H5 H 1.7044 0.3286 0.4935 0.170 Uiso 1 1 calc R
C6 C 1.5403(9) 0.3175(10) 0.4093(5) 0.144(4) Uani 1 1 d .
H6 H 1.5838 0.3078 0.3676 0.173 Uiso 1 1 calc R
C7 C 1.4064(7) 0.3172(5) 0.3973(3) 0.0673(17) Uani 1 1 d .
C8 C 1.3267(7) 0.2993(5) 0.3200(4) 0.0689(17) Uani 1 1 d .
C9 C 1.2608(6) 0.2841(5) 0.2592(3) 0.0613(15) Uani 1 1 d .
C10 C 1.1714(6) 0.2678(4) 0.1852(3) 0.0501(13) Uani 1 1 d .
C11 C 1.1611(6) 0.1847(4) 0.1282(3) 0.0539(14) Uani 1 1 d .
H11 H 1.2116 0.1375 0.1373 0.065 Uiso 1 1 calc R
C12 C 1.0755(6) 0.1713(4) 0.0572(3) 0.0545(14) Uani 1 1 d .
H12 H 1.0674 0.1139 0.0194 0.065 Uiso 1 1 calc R
C13 C 1.0025(5) 0.2422(4) 0.0421(3) 0.0449(12) Uani 1 1 d .
H13 H 0.9456 0.2332 -0.0056 0.054 Uiso 1 1 calc R
C14 C 1.0155(5) 0.3271(4) 0.0993(3) 0.0400(11) Uani 1 1 d .
C15 C 0.9462(5) 0.4075(4) 0.0843(3) 0.0426(12) Uani 1 1 d .
C16 C 1.0971(5) 0.3381(4) 0.1712(3) 0.0471(13) Uani 1 1 d .
H16 H 1.1017 0.3930 0.2100 0.056 Uiso 1 1 calc R
C17 C 0.7999(5) 0.4734(4) 0.0239(3) 0.0383(11) Uani 1 1 d .
C18 C 0.6912(5) 0.4749(4) -0.0383(3) 0.0390(11) Uani 1 1 d .
C19 C 0.6343(5) 0.3867(4) -0.0967(3) 0.0519(14) Uani 1 1 d .
H19 H 0.6630 0.3254 -0.0955 0.062 Uiso 1 1 calc R
C20 C 0.5346(6) 0.3892(5) -0.1571(3) 0.0631(16) Uani 1 1 d .
H20 H 0.4978 0.3304 -0.1973 0.076 Uiso 1 1 calc R
C21 C 0.4899(6) 0.4779(5) -0.1580(3) 0.0580(15) Uani 1 1 d .
H21 H 0.4224 0.4790 -0.1988 0.070 Uiso 1 1 calc R
C22 C 0.5436(5) 0.5660(4) -0.0992(3) 0.0448(12) Uani 1 1 d .
C23 C 0.6441(5) 0.5643(4) -0.0390(3) 0.0408(11) Uani 1 1 d .
H23 H 0.6804 0.6231 0.0011 0.049 Uiso 1 1 calc R
C24 C 0.4919(6) 0.6573(5) -0.1021(3) 0.0544(14) Uani 1 1 d .
C25 C 0.4426(6) 0.7280(5) -0.1058(3) 0.0558(14) Uani 1 1 d .
C26 C 0.3833(6) 0.8139(5) -0.1132(3) 0.0528(14) Uani 1 1 d .
C27 C 0.3456(8) 0.8414(6) -0.1845(4) 0.084(2) Uani 1 1 d .
H27 H 0.3543 0.8015 -0.2285 0.101 Uiso 1 1 calc R
C28 C 0.2945(9) 0.9286(6) -0.1915(4) 0.090(2) Uani 1 1 d .
H28 H 0.2684 0.9465 -0.2399 0.108 Uiso 1 1 calc R
C29 C 0.2830(6) 0.9878(5) -0.1261(3) 0.0580(15) Uani 1 1 d .
C30 C 0.2361(7) 1.0796(5) -0.1328(4) 0.0688(17) Uani 1 1 d .
C31 C 0.3160(6) 0.9576(5) -0.0550(3) 0.0580(15) Uani 1 1 d .
H31 H 0.3025 0.9948 -0.0112 0.070 Uiso 1 1 calc R
C32 C 0.3683(6) 0.8740(5) -0.0478(3) 0.0583(15) Uani 1 1 d .
H32 H 0.3942 0.8567 0.0009 0.070 Uiso 1 1 calc R
C33 C 0.9568(19) 0.636(2) 0.4099(8) 0.191(7) Uani 1 1 d .
C34 C 1.2707(14) 0.9425(9) 0.2610(5) 0.120(3) Uani 1 1 d .
C35 C 0.0179(15) 0.8958(18) 0.6439(7) 0.242(7) Uiso 1 1 d D
H35 H -0.0657 0.8809 0.6639 0.290 Uiso 1 1 calc R
C36 C 0.068(2) 0.8094(14) 0.6305(8) 0.287(9) Uiso 1 1 d D
H36 H 0.0197 0.7373 0.6411 0.345 Uiso 1 1 calc R
C37 C 0.192(2) 0.8361(17) 0.6008(8) 0.280(9) Uiso 1 1 d D
H37 H 0.2298 0.7810 0.5910 0.336 Uiso 1 1 calc R
C38 C 0.2604(17) 0.942(2) 0.5856(9) 0.317(11) Uiso 1 1 d D
H38 H 0.3437 0.9572 0.5652 0.381 Uiso 1 1 calc R
C39 C 0.212(2) 1.0281(16) 0.5990(10) 0.47(2) Uiso 1 1 d D
H39 H 0.2607 1.1002 0.5885 0.566 Uiso 1 1 calc R
C40 C 0.088(2) 1.0023(16) 0.6285(9) 0.291(10) Uiso 1 1 d D
H40 H 0.0509 1.0579 0.6382 0.349 Uiso 1 1 calc R
O1 O 0.8414(3) 0.3828(3) 0.02118(17) 0.0409(8) Uani 1 1 d .
O2 O 1.1441(5) 0.7694(4) 0.1580(2) 0.0817(13) Uani 1 1 d .
O3 O 1.3899(6) 0.8670(5) 0.1643(5) 0.148(3) Uani 1 1 d .
O4 O 1.2314(9) 0.9518(4) 0.1171(3) 0.149(3) Uani 1 1 d .
O5 O 0.9248(7) 0.6483(6) 0.2663(3) 0.123(2) Uani 1 1 d .
O6 O 0.7131(13) 0.5369(18) 0.3216(8) 0.105(8) Uiso 0.41(3) 1 d PD
O7 O 0.752(4) 0.468(2) 0.310(2) 0.21(2) Uiso 0.26(3) 1 d PD
O6' O 0.7356(16) 0.617(2) 0.3203(8) 0.173(8) Uiso 0.59(3) 1 d PD
O7' O 0.907(2) 0.4766(13) 0.3059(9) 0.243(10) Uiso 0.74(3) 1 d PD
F1 F 1.2841(10) 0.8809(6) 0.3126(3) 0.205(4) Uani 1 1 d .
F2 F 1.3665(8) 1.0412(5) 0.2771(3) 0.167(3) Uani 1 1 d .
F3 F 1.1505(10) 0.9602(7) 0.2660(4) 0.206(4) Uani 1 1 d .
F4 F 0.9250(13) 0.7284(14) 0.4288(6) 0.276(6) Uani 1 1 d .
F5 F 1.0800(10) 0.6595(12) 0.4171(4) 0.289(7) Uani 1 1 d .
F6 F 0.9025(11) 0.5734(11) 0.4626(5) 0.279(6) Uani 1 1 d .
S1 S 1.2541(2) 0.87728(14) 0.16566(10) 0.0751(5) Uani 1 1 d .
S2 S 0.8618(3) 0.5799(4) 0.31641(15) 0.1608(15) Uani 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N4 Ag1 N1 146.42(18) 2_675 .
N4 Ag1 O5 120.6(2) 2_675 .
N1 Ag1 O5 89.58(18) . .
N4 Ag1 O2 113.94(19) 2_675 .
N1 Ag1 O2 83.86(14) . .
O5 Ag1 O2 79.54(18) . .
N3 Ag2 N2 148.2(2) 2_866 .
N3 Ag2 O2 123.0(2) 2_866 .
N2 Ag2 O2 86.47(14) . .
N3 Ag2 O5 112.5(2) 2_866 .
N2 Ag2 O5 82.41(17) . .
O2 Ag2 O5 79.28(18) . .
C17 N1 N2 106.4(4) . .
C17 N1 Ag1 138.5(3) . .
N2 N1 Ag1 114.7(3) . .
C15 N2 N1 106.8(4) . .
C15 N2 Ag2 132.0(3) . .
N1 N2 Ag2 120.9(3) . .
C4 N3 Ag2 163.6(6) . 2_866
C30 N4 Ag1 176.7(6) . 2_675
C7 C1 C2 122.2(7) . .
C7 C1 H1 118.9 . .
C2 C1 H1 118.9 . .
C3 C2 C1 119.0(8) . .
C3 C2 H2 120.5 . .
C1 C2 H2 120.5 . .
C2 C3 C5 119.9(7) . .
C2 C3 C4 121.0(7) . .
C5 C3 C4 119.1(6) . .
N3 C4 C3 179.1(9) . .
C3 C5 C6 121.3(7) . .
C3 C5 H5 119.4 . .
C6 C5 H5 119.4 . .
C7 C6 C5 119.7(8) . .
C7 C6 H6 120.2 . .
C5 C6 H6 120.2 . .
C1 C7 C6 117.8(6) . .
C1 C7 C8 121.1(6) . .
C6 C7 C8 121.0(7) . .
C9 C8 C7 178.6(8) . .
C8 C9 C10 176.0(6) . .
C11 C10 C16 119.7(4) . .
C11 C10 C9 121.0(5) . .
C16 C10 C9 119.2(5) . .
C10 C11 C12 120.1(5) . .
C10 C11 H11 120.0 . .
C12 C11 H11 120.0 . .
C13 C12 C11 120.8(5) . .
C13 C12 H12 119.6 . .
C11 C12 H12 119.6 . .
C12 C13 C14 118.8(4) . .
C12 C13 H13 120.6 . .
C14 C13 H13 120.6 . .
C16 C14 C13 120.4(4) . .
C16 C14 C15 119.1(4) . .
C13 C14 C15 120.5(4) . .
N2 C15 O1 111.5(4) . .
N2 C15 C14 129.8(4) . .
O1 C15 C14 118.8(4) . .
C10 C16 C14 120.2(4) . .
C10 C16 H16 119.9 . .
C14 C16 H16 119.9 . .
N1 C17 O1 111.3(4) . .
N1 C17 C18 130.9(4) . .
O1 C17 C18 117.7(4) . .
C19 C18 C23 119.7(4) . .
C19 C18 C17 119.6(4) . .
C23 C18 C17 120.7(4) . .
C18 C19 C20 120.0(5) . .
C18 C19 H19 120.0 . .
C20 C19 H19 120.0 . .
C21 C20 C19 120.1(5) . .
C21 C20 H20 120.0 . .
C19 C20 H20 120.0 . .
C20 C21 C22 120.8(5) . .
C20 C21 H21 119.6 . .
C22 C21 H21 119.6 . .
C21 C22 C23 119.4(4) . .
C21 C22 C24 118.8(4) . .
C23 C22 C24 121.8(5) . .
C22 C23 C18 120.1(4) . .
C22 C23 H23 119.9 . .
C18 C23 H23 119.9 . .
C25 C24 C22 176.5(6) . .
C24 C25 C26 177.9(6) . .
C27 C26 C32 118.9(5) . .
C27 C26 C25 120.6(5) . .
C32 C26 C25 120.4(5) . .
C26 C27 C28 120.6(6) . .
C26 C27 H27 119.7 . .
C28 C27 H27 119.7 . .
C29 C28 C27 119.4(6) . .
C29 C28 H28 120.3 . .
C27 C28 H28 120.3 . .
C31 C29 C28 119.9(5) . .
C31 C29 C30 120.5(5) . .
C28 C29 C30 119.6(5) . .
N4 C30 C29 177.0(7) . .
C32 C31 C29 120.8(5) . .
C32 C31 H31 119.6 . .
C29 C31 H31 119.6 . .
C31 C32 C26 120.3(5) . .
C31 C32 H32 119.9 . .
C26 C32 H32 119.9 . .
F5 C33 F6 111.5(15) . .
F5 C33 F4 111(2) . .
F6 C33 F4 100.2(14) . .
F5 C33 S2 115.4(12) . .
F6 C33 S2 112.1(15) . .
F4 C33 S2 105.7(11) . .
F1 C34 F2 111.3(10) . .
F1 C34 F3 106.3(11) . .
F2 C34 F3 103.4(9) . .
F1 C34 S1 113.2(7) . .
F2 C34 S1 114.3(8) . .
F3 C34 S1 107.5(8) . .
C40 C35 C36 122.2(11) . .
C40 C35 H35 118.9 . .
C36 C35 H35 118.9 . .
C37 C36 C35 116.5(11) . .
C37 C36 H36 121.7 . .
C35 C36 H36 121.7 . .
C38 C37 C36 120.7(12) . .
C38 C37 H37 119.6 . .
C36 C37 H37 119.6 . .
C37 C38 C39 123.0(12) . .
C37 C38 H38 118.5 . .
C39 C38 H38 118.5 . .
C38 C39 C40 116.7(12) . .
C38 C39 H39 121.6 . .
C40 C39 H39 121.6 . .
C35 C40 C39 120.8(12) . .
C35 C40 H40 119.6 . .
C39 C40 H40 119.6 . .
C15 O1 C17 104.0(3) . .
S1 O2 Ag2 129.5(2) . .
S1 O2 Ag1 131.7(3) . .
Ag2 O2 Ag1 91.04(15) . .
S2 O5 Ag1 141.6(4) . .
S2 O5 Ag2 113.9(4) . .
Ag1 O5 Ag2 90.16(18) . .
O4 S1 O2 117.0(4) . .
O4 S1 O3 111.8(5) . .
O2 S1 O3 110.9(3) . .
O4 S1 C34 105.6(5) . .
O2 S1 C34 106.6(4) . .
O3 S1 C34 103.8(5) . .
O5 S2 O6 127.3(8) . .
O5 S2 O7 136.0(17) . .
O6 S2 O7 45(2) . .
O5 S2 O6' 98.7(9) . .
O6 S2 O6' 38.3(7) . .
O7 S2 O6' 83(2) . .
O5 S2 O7' 105.3(7) . .
O6 S2 O7' 106.4(11) . .
O7 S2 O7' 62(2) . .
O6' S2 O7' 144.4(11) . .
O5 S2 C33 108.3(8) . .
O6 S2 C33 107.4(8) . .
O7 S2 C33 115.0(17) . .
O6' S2 C33 98.6(9) . .
O7' S2 C33 98.4(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N4 2.130(5) 2_675
Ag1 N1 2.263(4) .
Ag1 O5 2.427(5) .
Ag1 O2 2.571(5) .
Ag2 N3 2.144(5) 2_866
Ag2 N2 2.276(4) .
Ag2 O2 2.414(4) .
Ag2 O5 2.596(6) .
N1 C17 1.296(6) .
N1 N2 1.417(5) .
N2 C15 1.287(6) .
N3 C4 1.139(7) .
N3 Ag2 2.144(5) 2_866
N4 C30 1.139(7) .
N4 Ag1 2.130(5) 2_675
C1 C7 1.339(10) .
C1 C2 1.421(9) .
C1 H1 0.9300 .
C2 C3 1.318(10) .
C2 H2 0.9300 .
C3 C5 1.335(10) .
C3 C4 1.426(8) .
C5 C6 1.413(10) .
C5 H5 0.9300 .
C6 C7 1.349(10) .
C6 H6 0.9300 .
C7 C8 1.448(8) .
C8 C9 1.152(7) .
C9 C10 1.444(7) .
C10 C11 1.377(7) .
C10 C16 1.379(6) .
C11 C12 1.388(7) .
C11 H11 0.9300 .
C12 C13 1.380(7) .
C12 H12 0.9300 .
C13 C14 1.389(7) .
C13 H13 0.9300 .
C14 C16 1.388(6) .
C14 C15 1.459(6) .
C15 O1 1.368(5) .
C16 H16 0.9300 .
C17 O1 1.368(5) .
C17 C18 1.456(6) .
C18 C19 1.375(7) .
C18 C23 1.388(6) .
C19 C20 1.379(7) .
C19 H19 0.9300 .
C20 C21 1.365(7) .
C20 H20 0.9300 .
C21 C22 1.378(7) .
C21 H21 0.9300 .
C22 C23 1.378(6) .
C22 C24 1.442(7) .
C23 H23 0.9300 .
C24 C25 1.182(7) .
C25 C26 1.435(7) .
C26 C27 1.372(8) .
C26 C32 1.397(8) .
C27 C28 1.394(8) .
C27 H27 0.9300 .
C28 C29 1.376(8) .
C28 H28 0.9300 .
C29 C31 1.374(7) .
C29 C30 1.423(7) .
C31 C32 1.360(7) .
C31 H31 0.9300 .
C32 H32 0.9300 .
C33 F5 1.169(15) .
C33 F6 1.326(18) .
C33 F4 1.36(2) .
C33 S2 1.758(16) .
C34 F1 1.272(11) .
C34 F2 1.284(11) .
C34 F3 1.333(12) .
C34 S1 1.784(9) .
C35 C40 1.370(9) .
C35 C36 1.387(9) .
C35 H35 0.9300 .
C36 C37 1.379(9) .
C36 H36 0.9300 .
C37 C38 1.361(9) .
C37 H37 0.9300 .
C38 C39 1.373(9) .
C38 H38 0.9300 .
C39 C40 1.375(9) .
C39 H39 0.9300 .
C40 H40 0.9300 .
O2 S1 1.428(5) .
O3 S1 1.437(6) .
O4 S1 1.387(6) .
O5 S2 1.356(6) .
O6 S2 1.439(12) .
O7 S2 1.467(19) .
O6' S2 1.527(13) .
O7' S2 1.550(14) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N4 Ag1 N1 C17 -16.5(7) 2_675
O5 Ag1 N1 C17 138.8(5) .
O2 Ag1 N1 C17 -141.7(5) .
N4 Ag1 N1 N2 171.8(4) 2_675
O5 Ag1 N1 N2 -32.9(3) .
O2 Ag1 N1 N2 46.6(3) .
C17 N1 N2 C15 -0.5(5) .
Ag1 N1 N2 C15 173.8(3) .
C17 N1 N2 Ag2 173.8(3) .
Ag1 N1 N2 Ag2 -12.0(4) .
N3 Ag2 N2 C15 -18.9(7) 2_866
O2 Ag2 N2 C15 140.3(5) .
O5 Ag2 N2 C15 -140.1(5) .
N3 Ag2 N2 N1 168.4(4) 2_866
O2 Ag2 N2 N1 -32.4(4) .
O5 Ag2 N2 N1 47.2(4) .
C7 C1 C2 C3 3.0(14) .
C1 C2 C3 C5 -1.6(14) .
C1 C2 C3 C4 179.0(8) .
Ag2 N3 C4 C3 -48(48) 2_866
C2 C3 C4 N3 -147(47) .
C5 C3 C4 N3 33(47) .
C2 C3 C5 C6 2.0(16) .
C4 C3 C5 C6 -178.7(9) .
C3 C5 C6 C7 -3.5(17) .
C2 C1 C7 C6 -4.5(14) .
C2 C1 C7 C8 178.8(8) .
C5 C6 C7 C1 4.7(15) .
C5 C6 C7 C8 -178.6(9) .
C1 C7 C8 C9 -36(27) .
C6 C7 C8 C9 148(27) .
C7 C8 C9 C10 47(32) .
C8 C9 C10 C11 -150(9) .
C8 C9 C10 C16 31(10) .
C16 C10 C11 C12 -0.5(8) .
C9 C10 C11 C12 -179.4(5) .
C10 C11 C12 C13 1.5(9) .
C11 C12 C13 C14 -0.3(8) .
C12 C13 C14 C16 -2.0(8) .
C12 C13 C14 C15 176.7(5) .
N1 N2 C15 O1 0.9(6) .
Ag2 N2 C15 O1 -172.5(3) .
N1 N2 C15 C14 179.9(5) .
Ag2 N2 C15 C14 6.4(9) .
C16 C14 C15 N2 15.8(8) .
C13 C14 C15 N2 -162.9(5) .
C16 C14 C15 O1 -165.3(4) .
C13 C14 C15 O1 16.0(7) .
C11 C10 C16 C14 -1.8(8) .
C9 C10 C16 C14 177.1(5) .
C13 C14 C16 C10 3.0(8) .
C15 C14 C16 C10 -175.7(5) .
N2 N1 C17 O1 0.0(5) .
Ag1 N1 C17 O1 -172.2(3) .
N2 N1 C17 C18 -176.7(5) .
Ag1 N1 C17 C18 11.1(9) .
N1 C17 C18 C19 176.6(5) .
O1 C17 C18 C19 0.1(7) .
N1 C17 C18 C23 -3.5(8) .
O1 C17 C18 C23 179.9(4) .
C23 C18 C19 C20 2.3(8) .
C17 C18 C19 C20 -177.9(5) .
C18 C19 C20 C21 -1.5(9) .
C19 C20 C21 C22 0.2(9) .
C20 C21 C22 C23 0.3(9) .
C20 C21 C22 C24 -179.2(5) .
C21 C22 C23 C18 0.4(8) .
C24 C22 C23 C18 180.0(5) .
C19 C18 C23 C22 -1.7(7) .
C17 C18 C23 C22 178.4(5) .
C21 C22 C24 C25 40(10) .
C23 C22 C24 C25 -139(10) .
C22 C24 C25 C26 -86(21) .
C24 C25 C26 C27 11(18) .
C24 C25 C26 C32 -166(17) .
C32 C26 C27 C28 0.6(10) .
C25 C26 C27 C28 -176.8(7) .
C26 C27 C28 C29 0.5(12) .
C27 C28 C29 C31 -2.8(11) .
C27 C28 C29 C30 177.6(7) .
Ag1 N4 C30 C29 -145(10) 2_675
C31 C29 C30 N4 37(15) .
C28 C29 C30 N4 -143(14) .
C28 C29 C31 C32 4.0(9) .
C30 C29 C31 C32 -176.4(6) .
C29 C31 C32 C26 -2.9(9) .
C27 C26 C32 C31 0.6(9) .
C25 C26 C32 C31 178.0(5) .
C40 C35 C36 C37 0.0(3) .
C35 C36 C37 C38 -0.1(3) .
C36 C37 C38 C39 0.4(7) .
C37 C38 C39 C40 -0.5(9) .
C36 C35 C40 C39 -0.1(7) .
C38 C39 C40 C35 0.3(8) .
N2 C15 O1 C17 -0.9(5) .
C14 C15 O1 C17 -180.0(4) .
N1 C17 O1 C15 0.5(5) .
C18 C17 O1 C15 177.7(4) .
N3 Ag2 O2 S1 9.5(5) 2_866
N2 Ag2 O2 S1 -157.5(4) .
O5 Ag2 O2 S1 119.5(4) .
N3 Ag2 O2 Ag1 -141.9(2) 2_866
N2 Ag2 O2 Ag1 51.06(14) .
O5 Ag2 O2 Ag1 -31.88(16) .
N4 Ag1 O2 S1 3.0(4) 2_675
N1 Ag1 O2 S1 153.3(4) .
O5 Ag1 O2 S1 -116.0(4) .
N4 Ag1 O2 Ag2 153.30(18) 2_675
N1 Ag1 O2 Ag2 -56.35(14) .
O5 Ag1 O2 Ag2 34.35(18) .
N4 Ag1 O5 S2 85.7(7) 2_675
N1 Ag1 O5 S2 -78.7(7) .
O2 Ag1 O5 S2 -162.6(7) .
N4 Ag1 O5 Ag2 -143.4(2) 2_675
N1 Ag1 O5 Ag2 52.18(18) .
O2 Ag1 O5 Ag2 -31.65(16) .
N3 Ag2 O5 S2 -55.4(5) 2_866
N2 Ag2 O5 S2 95.3(4) .
O2 Ag2 O5 S2 -176.9(4) .
N3 Ag2 O5 Ag1 155.4(2) 2_866
N2 Ag2 O5 Ag1 -53.82(18) .
O2 Ag2 O5 Ag1 34.01(17) .
Ag2 O2 S1 O4 176.1(4) .
Ag1 O2 S1 O4 -43.9(5) .
Ag2 O2 S1 O3 46.2(5) .
Ag1 O2 S1 O3 -173.7(4) .
Ag2 O2 S1 C34 -66.1(5) .
Ag1 O2 S1 C34 74.0(5) .
F1 C34 S1 O4 176.2(9) .
F2 C34 S1 O4 -55.0(10) .
F3 C34 S1 O4 59.2(9) .
F1 C34 S1 O2 51.1(11) .
F2 C34 S1 O2 180.0(8) .
F3 C34 S1 O2 -65.9(9) .
F1 C34 S1 O3 -66.0(11) .
F2 C34 S1 O3 62.8(10) .
F3 C34 S1 O3 177.0(8) .
Ag1 O5 S2 O6 -21.1(14) .
Ag2 O5 S2 O6 -145.3(10) .
Ag1 O5 S2 O7 39(3) .
Ag2 O5 S2 O7 -85(3) .
Ag1 O5 S2 O6' -49.2(10) .
Ag2 O5 S2 O6' -173.5(7) .
Ag1 O5 S2 O7' 104.1(9) .
Ag2 O5 S2 O7' -20.2(8) .
Ag1 O5 S2 C33 -151.4(8) .
Ag2 O5 S2 C33 84.3(8) .
F5 C33 S2 O5 -50(2) .
F6 C33 S2 O5 -179.4(13) .
F4 C33 S2 O5 72.3(14) .
F5 C33 S2 O6 169.1(19) .
F6 C33 S2 O6 40.0(19) .
F4 C33 S2 O6 -68.2(18) .
F5 C33 S2 O7 122(3) .
F6 C33 S2 O7 -8(3) .
F4 C33 S2 O7 -116(3) .
F5 C33 S2 O6' -153(2) .
F6 C33 S2 O6' 78.4(17) .
F4 C33 S2 O6' -29.9(17) .
F5 C33 S2 O7' 59(2) .
F6 C33 S2 O7' -70.2(16) .
F4 C33 S2 O7' -178.4(14) .
