#------------------------------------------------------------------------------
#$Date: 2019-11-25 00:34:17 +0200 (Mon, 25 Nov 2019) $
#$Revision: 239771 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/35/01/4350191.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4350191
loop_
_publ_author_name
'Dong, Yu-Bin'
'Xu, Hong-Xia'
'Ma, Jian-Ping'
'Huang, Ru-Qi'
_publ_section_title
;
 Silver(I) coordination polymers based on a nano-sized bent
 bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole ligand: the role of
 ligand isomerism and the templating effect of polyatomic anions and
 solvent intermediates.
;
_journal_issue                   8
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3325
_journal_page_last               3343
_journal_paper_doi               10.1021/ic052158w
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C32 H16 Ag F6 N4 O Sb'
_chemical_formula_weight         816.11
_space_group_IT_number           43
_space_group_name_Hall           'F 2 -2d'
_space_group_name_H-M_alt        'F d d 2'
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'F d d 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   23.124(2)
_cell_length_b                   37.368(5)
_cell_length_c                   19.180(2)
_cell_measurement_reflns_used    3656
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      21.749
_cell_measurement_theta_min      2.387
_cell_volume                     16573(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0595
_diffrn_reflns_av_sigmaI/netI    0.0696
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       44
_diffrn_reflns_limit_k_min       -45
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21841
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.07
_exptl_absorpt_coefficient_mu    1.176
_exptl_absorpt_correction_T_max  0.8527
_exptl_absorpt_correction_T_min  0.7048
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.308
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             6336
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.049
_refine_diff_density_min         -0.824
_refine_diff_density_rms         '0.087 End ===='
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     407
_refine_ls_number_reflns         7238
_refine_ls_number_restraints     49
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0896
_refine_ls_R_factor_gt           0.0634
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0798P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1442
_refine_ls_wR_factor_ref         0.1549
_reflns_number_gt                4921
_reflns_number_total             7238
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic052158wsi20051219_053724.cif
_cod_data_source_block           7
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Orthorhombic' was changed
to 'orthorhombic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        16574(4)
_cod_original_sg_symbol_H-M      Fdd2
_cod_database_code               4350191
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'x+1/4, -y+1/4, z+1/4'
'-x+1/4, y+1/4, z+1/4'
'x, y+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'x+1/4, -y+3/4, z+3/4'
'-x+1/4, y+3/4, z+3/4'
'x+1/2, y, z+1/2'
'-x+1/2, -y, z+1/2'
'x+3/4, -y+1/4, z+3/4'
'-x+3/4, y+1/4, z+3/4'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z'
'x+3/4, -y+3/4, z+1/4'
'-x+3/4, y+3/4, z+1/4'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.22851(3) 0.701147(15) 0.12497(4) 0.0626(2) Uani 1 1 d .
N1 N 0.2401(3) 0.73208(16) 0.0240(3) 0.0470(16) Uani 1 1 d .
N2 N 0.2487(3) 0.73110(17) 0.2275(3) 0.0545(18) Uani 1 1 d .
N3 N 0.4030(4) 0.5854(2) -0.5893(4) 0.082(2) Uani 1 1 d .
N4 N 0.0369(4) 0.6009(3) 0.8440(5) 0.089(3) Uani 1 1 d .
C1 C 0.2489(4) 0.7215(2) 0.2893(5) 0.050(2) Uani 1 1 d .
C2 C 0.2462(3) 0.6861(2) 0.3209(4) 0.0419(18) Uani 1 1 d .
C3 C 0.2679(4) 0.6563(2) 0.2865(4) 0.060(2) Uani 1 1 d .
H3 H 0.2851 0.6593 0.2430 0.072 Uiso 1 1 calc R
C4 C 0.2651(4) 0.6235(3) 0.3133(5) 0.074(3) Uani 1 1 d .
H4 H 0.2801 0.6042 0.2884 0.089 Uiso 1 1 calc R
C5 C 0.2400(4) 0.6178(2) 0.3777(5) 0.071(2) Uani 1 1 d .
H5 H 0.2393 0.5949 0.3968 0.085 Uiso 1 1 calc R
C6 C 0.2156(4) 0.6465(3) 0.4144(4) 0.061(3) Uani 1 1 d .
C7 C 0.2202(3) 0.6807(2) 0.3855(5) 0.057(2) Uani 1 1 d .
H7 H 0.2056 0.7002 0.4099 0.068 Uiso 1 1 calc R
C8 C 0.1885(4) 0.6410(2) 0.4796(4) 0.059(2) Uani 1 1 d .
C9 C 0.1667(4) 0.6359(3) 0.5349(5) 0.068(3) Uani 1 1 d .
C10 C 0.1381(4) 0.6300(3) 0.6013(4) 0.061(2) Uani 1 1 d .
C11 C 0.1468(4) 0.5973(2) 0.6335(4) 0.064(2) Uani 1 1 d .
H11 H 0.1687 0.5794 0.6123 0.077 Uiso 1 1 calc R
C12 C 0.1221(4) 0.5920(3) 0.6977(4) 0.063(2) Uani 1 1 d .
H12 H 0.1301 0.5709 0.7217 0.076 Uiso 1 1 calc R
C13 C 0.0869(4) 0.6159(2) 0.7270(4) 0.053(2) Uani 1 1 d .
C14 C 0.0585(4) 0.6086(2) 0.7924(4) 0.057(2) Uani 1 1 d .
C15 C 0.0760(4) 0.6480(3) 0.6935(5) 0.072(3) Uani 1 1 d .
H15 H 0.0509 0.6647 0.7129 0.086 Uiso 1 1 calc R
C16 C 0.1030(4) 0.6548(2) 0.6311(5) 0.075(3) Uani 1 1 d .
H16 H 0.0972 0.6767 0.6090 0.090 Uiso 1 1 calc R
C17 C 0.2346(3) 0.7229(2) -0.0413(4) 0.0376(18) Uani 1 1 d .
C18 C 0.2169(4) 0.6887(2) -0.0695(4) 0.0440(19) Uani 1 1 d .
C19 C 0.1798(4) 0.6663(2) -0.0369(4) 0.059(2) Uani 1 1 d .
H19 H 0.1632 0.6729 0.0053 0.070 Uiso 1 1 calc R
C20 C 0.1664(4) 0.6331(2) -0.0665(4) 0.066(3) Uani 1 1 d .
H20 H 0.1425 0.6170 -0.0433 0.079 Uiso 1 1 calc R
C21 C 0.1893(4) 0.6246(2) -0.1308(5) 0.062(2) Uani 1 1 d .
H21 H 0.1789 0.6032 -0.1520 0.074 Uiso 1 1 calc R
C22 C 0.2270(3) 0.6470(2) -0.1642(5) 0.052(2) Uani 1 1 d .
C23 C 0.2394(3) 0.6794(2) -0.1362(4) 0.049(2) Uani 1 1 d .
H23 H 0.2626 0.6955 -0.1604 0.059 Uiso 1 1 calc R
C24 C 0.2502(4) 0.6376(3) -0.2314(5) 0.065(3) Uani 1 1 d .
C25 C 0.2731(4) 0.6294(3) -0.2838(4) 0.065(2) Uani 1 1 d .
C26 C 0.2992(4) 0.6196(3) -0.3498(5) 0.071(3) Uani 1 1 d .
C27 C 0.3219(5) 0.6457(3) -0.3886(6) 0.098(4) Uani 1 1 d .
H27 H 0.3207 0.6693 -0.3728 0.118 Uiso 1 1 calc R
C28 C 0.3480(5) 0.6377(3) -0.4546(5) 0.085(3) Uani 1 1 d .
H28 H 0.3633 0.6559 -0.4822 0.102 Uiso 1 1 calc R
C29 C 0.3501(4) 0.6026(3) -0.4763(4) 0.059(2) Uani 1 1 d .
C30 C 0.3786(4) 0.5928(3) -0.5390(5) 0.072(3) Uani 1 1 d .
C31 C 0.3255(5) 0.5759(3) -0.4350(6) 0.085(3) Uani 1 1 d .
H31 H 0.3261 0.5522 -0.4497 0.102 Uiso 1 1 calc R
C32 C 0.2996(4) 0.5852(2) -0.3705(6) 0.069(2) Uani 1 1 d .
H32 H 0.2830 0.5676 -0.3426 0.083 Uiso 1 1 calc R
O1 O 0.2500 0.7500 -0.0834(3) 0.0482(19) Uani 1 2 d S
O2 O 0.2500 0.7500 0.3350(4) 0.0543(19) Uani 1 2 d S
F1 F 0.0381(7) 0.7790(3) 0.0146(8) 0.369(10) Uani 1 1 d DU
F2 F 0.0808(10) 0.7183(3) 0.0366(7) 0.341(9) Uani 1 1 d DU
F3 F 0.0524(7) 0.7240(3) 0.1597(7) 0.331(9) Uani 1 1 d DU
F4 F 0.0187(8) 0.7857(3) 0.1419(9) 0.358(10) Uani 1 1 d DU
F5 F -0.0201(7) 0.7340(7) 0.0709(10) 0.387(9) Uani 1 1 d DU
F6 F 0.1192(6) 0.7674(6) 0.0924(9) 0.384(10) Uani 1 1 d DU
Sb1 Sb 0.05046(8) 0.75290(3) 0.08945(11) 0.2458(12) Uani 1 1 d DU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N2 117.06(18) . .
N1 Ag1 N3 129.8(3) . 11_465
N2 Ag1 N3 100.7(3) . 11_465
N1 Ag1 N4 97.6(3) . 3_564
N2 Ag1 N4 118.8(3) . 3_564
N3 Ag1 N4 91.1(3) 11_465 3_564
C17 N1 N1 106.3(4) . 14_565
C17 N1 Ag1 132.2(5) . .
N1 N1 Ag1 121.33(16) 14_565 .
C1 N2 N2 106.8(5) . 14_565
C1 N2 Ag1 132.5(6) . .
N2 N2 Ag1 119.5(2) 14_565 .
C30 N3 Ag1 139.3(8) . 3_564
C14 N4 Ag1 130.5(8) . 11_465
N2 C1 O2 112.6(7) . .
N2 C1 C2 131.4(8) . .
O2 C1 C2 116.0(7) . .
C3 C2 C7 117.7(8) . .
C3 C2 C1 121.0(7) . .
C7 C2 C1 121.3(8) . .
C4 C3 C2 122.4(8) . .
C3 C4 C5 120.5(9) . .
C4 C5 C6 120.0(8) . .
C7 C6 C5 118.1(8) . .
C7 C6 C8 121.2(9) . .
C5 C6 C8 120.6(8) . .
C2 C7 C6 121.1(8) . .
C9 C8 C6 178.6(11) . .
C8 C9 C10 177.9(11) . .
C16 C10 C11 120.2(8) . .
C16 C10 C9 122.4(8) . .
C11 C10 C9 117.4(9) . .
C12 C11 C10 117.8(9) . .
C13 C12 C11 122.5(8) . .
C12 C13 C15 119.7(7) . .
C12 C13 C14 121.2(8) . .
C15 C13 C14 119.1(8) . .
N4 C14 C13 176.5(11) . .
C16 C15 C13 118.9(9) . .
C10 C16 C15 120.7(9) . .
N1 C17 O1 110.5(7) . .
N1 C17 C18 128.3(7) . .
O1 C17 C18 121.1(7) . .
C19 C18 C23 119.8(7) . .
C19 C18 C17 123.5(7) . .
C23 C18 C17 116.6(7) . .
C18 C19 C20 120.0(8) . .
C21 C20 C19 118.8(8) . .
C22 C21 C20 121.7(7) . .
C23 C22 C21 119.6(8) . .
C23 C22 C24 119.8(8) . .
C21 C22 C24 120.5(8) . .
C22 C23 C18 119.9(8) . .
C25 C24 C22 175.0(10) . .
C24 C25 C26 177.9(10) . .
C27 C26 C32 122.1(9) . .
C27 C26 C25 117.8(9) . .
C32 C26 C25 120.1(10) . .
C26 C27 C28 120.3(9) . .
C29 C28 C27 118.7(9) . .
C28 C29 C31 119.7(8) . .
C28 C29 C30 121.1(10) . .
C31 C29 C30 119.2(9) . .
N3 C30 C29 178.3(12) . .
C29 C31 C32 119.5(9) . .
C26 C32 C31 119.6(10) . .
C17 O1 C17 106.3(8) 14_565 .
C1 O2 C1 101.2(8) 14_565 .
F6 Sb1 F3 98.7(7) . .
F6 Sb1 F4 98.8(10) . .
F3 Sb1 F4 90.0(6) . .
F6 Sb1 F1 90.2(6) . .
F3 Sb1 F1 170.9(7) . .
F4 Sb1 F1 90.7(5) . .
F6 Sb1 F2 83.1(10) . .
F3 Sb1 F2 88.8(5) . .
F4 Sb1 F2 177.9(9) . .
F1 Sb1 F2 90.2(6) . .
F6 Sb1 F5 169.5(10) . .
F3 Sb1 F5 86.1(6) . .
F4 Sb1 F5 90.5(11) . .
F1 Sb1 F5 84.8(7) . .
F2 Sb1 F5 87.7(12) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.271(6) .
Ag1 N2 2.310(7) .
Ag1 N3 2.319(9) 11_465
Ag1 N4 2.442(9) 3_564
N1 C17 1.307(9) .
N1 N1 1.415(12) 14_565
N2 C1 1.240(10) .
N2 N2 1.414(13) 14_565
N3 C30 1.152(11) .
N3 Ag1 2.319(9) 3_564
N4 C14 1.144(10) .
N4 Ag1 2.442(9) 11_465
C1 O2 1.379(9) .
C1 C2 1.457(11) .
C2 C3 1.388(11) .
C2 C7 1.392(12) .
C3 C4 1.330(12) .
C4 C5 1.382(13) .
C5 C6 1.401(13) .
C6 C7 1.396(12) .
C6 C8 1.414(12) .
C8 C9 1.190(11) .
C9 C10 1.452(12) .
C10 C16 1.359(12) .
C10 C11 1.384(12) .
C11 C12 1.372(12) .
C12 C13 1.332(12) .
C13 C15 1.384(12) .
C13 C14 1.443(12) .
C15 C16 1.374(12) .
C17 O1 1.344(8) .
C17 C18 1.446(11) .
C18 C19 1.352(11) .
C18 C23 1.423(11) .
C19 C20 1.400(11) .
C20 C21 1.378(12) .
C21 C22 1.368(12) .
C22 C23 1.354(11) .
C22 C24 1.439(13) .
C24 C25 1.176(12) .
C25 C26 1.450(12) .
C26 C27 1.335(14) .
C26 C32 1.346(12) .
C27 C28 1.433(13) .
C28 C29 1.379(13) .
C29 C31 1.393(14) .
C29 C30 1.420(12) .
C31 C32 1.418(14) .
O1 C17 1.344(8) 14_565
O2 C1 1.379(9) 14_565
F1 Sb1 1.760(12) .
F2 Sb1 1.786(10) .
F3 Sb1 1.729(12) .
F4 Sb1 1.747(10) .
F5 Sb1 1.813(13) .
F6 Sb1 1.681(12) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Ag1 N1 C17 177.2(7) . .
N3 Ag1 N1 C17 -48.6(8) 11_465 .
N4 Ag1 N1 C17 49.3(8) 3_564 .
N2 Ag1 N1 N1 1.1(8) . 14_565
N3 Ag1 N1 N1 135.3(7) 11_465 14_565
N4 Ag1 N1 N1 -126.8(8) 3_564 14_565
N1 Ag1 N2 C1 -176.6(8) . .
N3 Ag1 N2 C1 37.4(9) 11_465 .
N4 Ag1 N2 C1 -59.8(9) 3_564 .
N1 Ag1 N2 N2 17.8(8) . 14_565
N3 Ag1 N2 N2 -128.2(8) 11_465 14_565
N4 Ag1 N2 N2 134.6(8) 3_564 14_565
N2 N2 C1 O2 1.6(11) 14_565 .
Ag1 N2 C1 O2 -165.4(5) . .
N2 N2 C1 C2 179.2(9) 14_565 .
Ag1 N2 C1 C2 12.3(15) . .
N2 C1 C2 C3 29.0(14) . .
O2 C1 C2 C3 -153.4(7) . .
N2 C1 C2 C7 -148.8(10) . .
O2 C1 C2 C7 28.8(11) . .
C7 C2 C3 C4 -0.7(13) . .
C1 C2 C3 C4 -178.6(9) . .
C2 C3 C4 C5 -0.1(15) . .
C3 C4 C5 C6 2.1(15) . .
C4 C5 C6 C7 -3.2(14) . .
C4 C5 C6 C8 178.4(9) . .
C3 C2 C7 C6 -0.5(12) . .
C1 C2 C7 C6 177.3(8) . .
C5 C6 C7 C2 2.5(13) . .
C8 C6 C7 C2 -179.2(8) . .
C7 C6 C8 C9 -129(47) . .
C5 C6 C8 C9 49(47) . .
C6 C8 C9 C10 -157(36) . .
C8 C9 C10 C16 -57(30) . .
C8 C9 C10 C11 122(30) . .
C16 C10 C11 C12 -4.1(13) . .
C9 C10 C11 C12 177.1(8) . .
C10 C11 C12 C13 5.3(13) . .
C11 C12 C13 C15 -2.5(14) . .
C11 C12 C13 C14 175.8(8) . .
Ag1 N4 C14 C13 -43(16) 11_465 .
C12 C13 C14 N4 -11(16) . .
C15 C13 C14 N4 167(16) . .
C12 C13 C15 C16 -1.4(14) . .
C14 C13 C15 C16 -179.8(8) . .
C11 C10 C16 C15 0.4(14) . .
C9 C10 C16 C15 179.1(9) . .
C13 C15 C16 C10 2.4(14) . .
N1 N1 C17 O1 0.8(9) 14_565 .
Ag1 N1 C17 O1 -175.7(4) . .
N1 N1 C17 C18 178.5(8) 14_565 .
Ag1 N1 C17 C18 2.0(12) . .
N1 C17 C18 C19 30.9(13) . .
O1 C17 C18 C19 -151.7(7) . .
N1 C17 C18 C23 -150.8(8) . .
O1 C17 C18 C23 26.7(10) . .
C23 C18 C19 C20 3.9(13) . .
C17 C18 C19 C20 -177.8(8) . .
C18 C19 C20 C21 -3.3(13) . .
C19 C20 C21 C22 3.6(14) . .
C20 C21 C22 C23 -4.6(14) . .
C20 C21 C22 C24 -179.9(9) . .
C21 C22 C23 C18 5.1(13) . .
C24 C22 C23 C18 -179.5(8) . .
C19 C18 C23 C22 -4.9(13) . .
C17 C18 C23 C22 176.7(8) . .
C23 C22 C24 C25 76(13) . .
C21 C22 C24 C25 -109(12) . .
C22 C24 C25 C26 -178(100) . .
C24 C25 C26 C27 86(31) . .
C24 C25 C26 C32 -93(31) . .
C32 C26 C27 C28 -0.3(18) . .
C25 C26 C27 C28 -179.6(10) . .
C26 C27 C28 C29 -1.1(17) . .
C27 C28 C29 C31 1.8(15) . .
C27 C28 C29 C30 -176.0(10) . .
Ag1 N3 C30 C29 73(43) 3_564 .
C28 C29 C30 N3 50(43) . .
C31 C29 C30 N3 -128(43) . .
C28 C29 C31 C32 -1.2(15) . .
C30 C29 C31 C32 176.6(9) . .
C27 C26 C32 C31 0.9(16) . .
C25 C26 C32 C31 -179.8(9) . .
C29 C31 C32 C26 -0.2(15) . .
N1 C17 O1 C17 -0.3(4) . 14_565
C18 C17 O1 C17 -178.2(8) . 14_565
N2 C1 O2 C1 -0.7(5) . 14_565
C2 C1 O2 C1 -178.7(9) . 14_565
