#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/78/4507884.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4507884
loop_
_publ_author_name
'Lee, Sumi'
'Oh, Seungwhan'
'Lee, Joosub'
'Malpani, Yashwardhan'
'Jung, Young-Sik'
'Kang, Baotao'
'Lee, Jin Yong'
'Ozasa, Kazunari'
'Isoshima, Takashi'
'Lee, Sang Yun'
'Hara, Masahiko'
'Hashizume, Daisuke'
'Kim, Jong-Man'
_publ_section_title
;
 Stimulus-responsive azobenzene supramolecules: fibers, gels, and hollow
 spheres.
;
_journal_issue                   19
_journal_name_full
'Langmuir : the ACS journal of surfaces and colloids'
_journal_page_first              5869
_journal_page_last               5877
_journal_paper_doi               10.1021/la400159m
_journal_volume                  29
_journal_year                    2013
_chemical_formula_moiety         'C30 H22 N6 O2'
_chemical_formula_sum            'C30 H22 N6 O2'
_chemical_formula_weight         498.54
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 103.160(4)
_cell_angle_gamma                90
_cell_formula_units_Z            12
_cell_length_a                   59.367(7)
_cell_length_b                   4.7106(5)
_cell_length_c                   39.948(4)
_cell_measurement_reflns_used    38216
_cell_measurement_temperature    90
_cell_measurement_theta_max      25.34
_cell_measurement_theta_min      1.39
_cell_volume                     10878(2)
_computing_cell_refinement       HKL2000
_computing_data_collection       CrystalClear
_computing_data_reduction        HKL2000
_computing_molecular_graphics    'ORTEP-3 for Windows'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  SHELXL-97
_computing_structure_solution    SIR2002
_diffrn_ambient_temperature      90
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.961
_diffrn_measured_fraction_theta_max 0.961
_diffrn_measurement_device_type  'Rigaku AFC-8 with Saturn70 CCD'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1299
_diffrn_reflns_av_sigmaI/netI    0.3447
_diffrn_reflns_limit_h_max       70
_diffrn_reflns_limit_h_min       -70
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       44
_diffrn_reflns_limit_l_min       -48
_diffrn_reflns_number            35007
_diffrn_reflns_theta_full        25.34
_diffrn_reflns_theta_max         25.34
_diffrn_reflns_theta_min         1.39
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.060
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    0.913
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3120
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.04
_platon_squeeze_details
;
;
_refine_diff_density_max         0.292
_refine_diff_density_min         -0.323
_refine_diff_density_rms         0.081
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.793
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     534
_refine_ls_number_reflns         9588
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      0.793
_refine_ls_R_factor_all          0.2300
_refine_ls_R_factor_gt           0.1050
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1226P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2511
_refine_ls_wR_factor_ref         0.2858
_reflns_number_gt                2479
_reflns_number_total             9588
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            la400159m_si_002.cif
_cod_data_source_block           shelxl
_cod_original_cell_volume        10878.4(19)
_cod_original_sg_symbol_Hall     '-C 2cy'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4507884
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.59431(6) 0.2685(8) 0.53728(10) 0.0348(11) Uani 1 1 d . . .
O2 O 0.57684(6) 1.1086(8) 0.41469(11) 0.0361(11) Uani 1 1 d . . .
O3 O 0.67372(7) 0.4902(9) 0.46151(12) 0.0451(12) Uani 1 1 d . . .
N2 N 0.56754(8) 1.1758(10) 0.46737(14) 0.0392(14) Uani 1 1 d . . .
H2 H 0.5709 1.1137 0.4887 0.047 Uiso 1 1 calc R . .
N5 N 0.63270(9) 0.2795(11) 0.55995(14) 0.0398(14) Uani 1 1 d . . .
H5 H 0.6459 0.3454 0.5568 0.048 Uiso 1 1 calc R . .
N7 N 0.66059(8) 0.8545(10) 0.42514(12) 0.0351(14) Uani 1 1 d D . .
H7 H 0.6495 0.9820 0.4211 0.042 Uiso 1 1 calc R A 1
N11 N 0.65846(10) -0.3594(11) 0.70098(16) 0.0465(16) Uani 1 1 d . . .
N14 N 0.73143(9) 1.2015(14) 0.33820(16) 0.0551(17) Uani 1 1 d . B .
N15 N 0.73571(10) 1.0262(14) 0.36275(18) 0.0641(19) Uani 1 1 d D . .
N16 N 0.63910(12) -0.3627(12) 0.67934(16) 0.0546(17) Uani 1 1 d . . .
N17 N 0.49016(9) 2.0872(10) 0.40853(15) 0.0391(14) Uani 1 1 d . . .
N18 N 0.49477(9) 1.9799(12) 0.43855(16) 0.0470(15) Uani 1 1 d . . .
C1 C 0.61733(9) 0.5329(12) 0.50719(15) 0.0256(15) Uani 1 1 d . . .
C2 C 0.59909(10) 0.7060(13) 0.49354(16) 0.0336(16) Uani 1 1 d . . .
H2A H 0.5861 0.7123 0.5036 0.040 Uiso 1 1 calc R . .
C3 C 0.59945(11) 0.8729(14) 0.46501(18) 0.0429(18) Uani 1 1 d . . .
C4 C 0.61857(9) 0.8627(12) 0.44965(16) 0.0314(16) Uani 1 1 d . B .
H4 H 0.6187 0.9699 0.4295 0.038 Uiso 1 1 calc R . .
C5 C 0.63718(10) 0.6932(12) 0.46448(18) 0.0372(17) Uani 1 1 d . . .
C6 C 0.63683(10) 0.5243(12) 0.49306(16) 0.0338(16) Uani 1 1 d . B .
H6 H 0.6496 0.4056 0.5027 0.041 Uiso 1 1 calc R . .
C7 C 0.61443(11) 0.3552(13) 0.53573(17) 0.0336(16) Uani 1 1 d . . .
C8 C 0.63486(14) 0.1084(14) 0.5906(2) 0.053(2) Uani 1 1 d . . .
C9 C 0.65393(12) 0.1313(15) 0.61661(19) 0.051(2) Uani 1 1 d . . .
H9 H 0.6660 0.2556 0.6141 0.061 Uiso 1 1 calc R . .
C10 C 0.65617(12) -0.0209(16) 0.64652(19) 0.056(2) Uani 1 1 d . . .
H10 H 0.6698 -0.0055 0.6643 0.067 Uiso 1 1 calc R . .
C11 C 0.63824(11) -0.1970(14) 0.65016(18) 0.0391(17) Uani 1 1 d . . .
C12 C 0.61807(11) -0.2245(14) 0.62378(17) 0.0398(17) Uani 1 1 d . . .
H12 H 0.6059 -0.3463 0.6265 0.048 Uiso 1 1 calc R . .
C13 C 0.61647(10) -0.0702(11) 0.59388(16) 0.0263(15) Uani 1 1 d . . .
H13 H 0.6031 -0.0847 0.5757 0.032 Uiso 1 1 calc R . .
C14 C 0.65910(12) -0.5365(15) 0.73111(19) 0.0454(19) Uani 1 1 d . . .
C15 C 0.67756(13) -0.4942(15) 0.75772(19) 0.0509(19) Uani 1 1 d . . .
H15 H 0.6889 -0.3559 0.7561 0.061 Uiso 1 1 calc R . .
C16 C 0.67964(18) -0.655(2) 0.7873(3) 0.094(3) Uani 1 1 d . . .
H16 H 0.6925 -0.6271 0.8061 0.113 Uiso 1 1 calc R . .
C17 C 0.6626(2) -0.8619(18) 0.7895(3) 0.076(3) Uani 1 1 d . . .
H17 H 0.6642 -0.9773 0.8094 0.092 Uiso 1 1 calc R . .
C18 C 0.6430(2) -0.894(2) 0.7613(3) 0.105(4) Uani 1 1 d . . .
H18 H 0.6311 -1.0257 0.7623 0.126 Uiso 1 1 calc R . .
C19 C 0.64209(13) -0.7277(14) 0.73282(19) 0.0477(19) Uani 1 1 d . . .
H19 H 0.6293 -0.7461 0.7138 0.057 Uiso 1 1 calc R . .
C20 C 0.58025(9) 1.0671(12) 0.44744(18) 0.0316(16) Uani 1 1 d . . .
C21 C 0.54913(11) 1.3784(13) 0.4599(2) 0.0417(18) Uani 1 1 d . . .
C22 C 0.53815(10) 1.4667(13) 0.48426(18) 0.0392(17) Uani 1 1 d . . .
H22 H 0.5431 1.3951 0.5070 0.047 Uiso 1 1 calc R . .
C23 C 0.51984(10) 1.6587(13) 0.47719(17) 0.0342(17) Uani 1 1 d . . .
H23 H 0.5123 1.7146 0.4947 0.041 Uiso 1 1 calc R . .
C24 C 0.51282(11) 1.7666(13) 0.44437(18) 0.0387(17) Uani 1 1 d . . .
C25 C 0.52340(11) 1.6757(14) 0.4175(2) 0.054(2) Uani 1 1 d . . .
H25 H 0.5182 1.7443 0.3947 0.065 Uiso 1 1 calc R . .
C26 C 0.54149(10) 1.4849(13) 0.42566(17) 0.0386(17) Uani 1 1 d . . .
H26 H 0.5490 1.4235 0.4083 0.046 Uiso 1 1 calc R . .
C27 C 0.47202(10) 2.2846(12) 0.40222(16) 0.0271(15) Uani 1 1 d . . .
C28 C 0.45684(10) 2.3436(13) 0.42288(17) 0.0397(17) Uani 1 1 d . . .
H28 H 0.4585 2.2460 0.4441 0.048 Uiso 1 1 calc R . .
C29 C 0.43938(11) 2.5397(14) 0.41351(19) 0.0461(19) Uani 1 1 d . . .
H29 H 0.4288 2.5709 0.4277 0.055 Uiso 1 1 calc R . .
C30 C 0.43725(11) 2.6938(14) 0.38280(19) 0.0436(18) Uani 1 1 d . . .
H30 H 0.4256 2.8348 0.3766 0.052 Uiso 1 1 calc R . .
C31 C 0.45190(13) 2.6402(17) 0.3620(2) 0.065(2) Uani 1 1 d . . .
H31 H 0.4502 2.7388 0.3408 0.078 Uiso 1 1 calc R . .
C32 C 0.46972(13) 2.4381(16) 0.3718(2) 0.063(2) Uani 1 1 d . . .
H32 H 0.4803 2.4064 0.3576 0.075 Uiso 1 1 calc R . .
C33 C 0.65971(10) 0.6594(15) 0.44984(17) 0.0315(16) Uani 1 1 d . B .
C34A C 0.67754(13) 0.876(2) 0.4050(2) 0.026(2) Uani 0.520(8) 1 d PGDU B 1
C35A C 0.67901(15) 1.130(2) 0.3878(3) 0.085(3) Uani 0.520(8) 1 d PG B 1
H35A H 0.6668 1.2645 0.3851 0.102 Uiso 0.520(8) 1 calc PR B 1
C36A C 0.6983(2) 1.186(2) 0.3748(3) 0.075(3) Uani 0.520(8) 1 d PG B 1
H36A H 0.6993 1.3598 0.3630 0.090 Uiso 0.520(8) 1 calc PR B 1
C37A C 0.71617(14) 0.989(3) 0.3788(3) 0.048(2) Uani 0.520(8) 1 d PGD B 1
C38A C 0.71470(14) 0.736(2) 0.3959(3) 0.075(3) Uani 0.520(8) 1 d PG B 1
H38A H 0.7269 0.6009 0.3987 0.090 Uiso 0.520(8) 1 calc PR B 1
C39A C 0.69539(18) 0.6790(18) 0.4090(3) 0.085(3) Uani 0.520(8) 1 d PG B 1
H39A H 0.6944 0.5056 0.4208 0.102 Uiso 0.520(8) 1 calc PR B 1
C34B C 0.68158(14) 0.904(2) 0.4143(3) 0.026(2) Uani 0.480(8) 1 d PGDU B 2
C35B C 0.67742(14) 1.024(3) 0.3817(3) 0.085(3) Uani 0.480(8) 1 d PG B 2
H35B H 0.6623 1.0843 0.3707 0.102 Uiso 0.480(8) 1 calc PR B 2
C36B C 0.6954(2) 1.055(3) 0.3650(2) 0.075(3) Uani 0.480(8) 1 d PG B 2
H36B H 0.6926 1.1363 0.3427 0.090 Uiso 0.480(8) 1 calc PR B 2
C37B C 0.71761(17) 0.966(3) 0.3810(3) 0.048(2) Uani 0.480(8) 1 d PGD B 2
C38B C 0.72177(12) 0.847(3) 0.4137(3) 0.075(3) Uani 0.480(8) 1 d PG B 2
H38B H 0.7369 0.7862 0.4246 0.090 Uiso 0.480(8) 1 calc PR B 2
C39B C 0.70375(19) 0.816(3) 0.4303(2) 0.085(3) Uani 0.480(8) 1 d PG B 2
H39B H 0.7066 0.7343 0.4526 0.102 Uiso 0.480(8) 1 calc PR B 2
C40 C 0.75209(13) 1.2376(18) 0.32316(19) 0.055(2) Uani 1 1 d . . .
C41 C 0.74920(15) 1.447(2) 0.2976(2) 0.083(3) Uani 1 1 d . B .
H41 H 0.7353 1.5543 0.2920 0.099 Uiso 1 1 calc R . .
C42 C 0.76687(13) 1.4968(17) 0.2807(2) 0.067(2) Uani 1 1 d . . .
H42 H 0.7653 1.6399 0.2635 0.080 Uiso 1 1 calc R B .
C43 C 0.78713(12) 1.3324(16) 0.2893(2) 0.051(2) Uani 1 1 d . B .
H43 H 0.7995 1.3657 0.2783 0.061 Uiso 1 1 calc R . .
C44 C 0.78886(17) 1.128(2) 0.3131(3) 0.091(3) Uani 1 1 d . . .
H44 H 0.8024 1.0131 0.3179 0.110 Uiso 1 1 calc R B .
C45 C 0.77199(15) 1.0771(18) 0.3308(2) 0.079(3) Uani 1 1 d . B .
H45 H 0.7740 0.9342 0.3480 0.095 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C20 N2 C21 130.4(6)
C7 N5 C8 131.8(6)
C33 N7 C34B 120.8(6)
C33 N7 C34A 127.3(6)
C34B N7 C34A 16.8(7)
N16 N11 C14 113.8(6)
N15 N14 C40 110.4(6)
N14 N15 C37B 118.3(8)
N14 N15 C37A 112.3(8)
C37B N15 C37A 6.0(10)
N11 N16 C11 114.7(6)
N18 N17 C27 115.1(5)
N17 N18 C24 114.8(5)
C2 C1 C6 120.6(6)
C2 C1 C7 115.5(5)
C6 C1 C7 123.8(6)
C1 C2 C3 120.4(6)
C2 C3 C4 120.2(6)
C2 C3 C20 125.1(6)
C4 C3 C20 114.7(6)
C5 C4 C3 118.5(6)
C4 C5 C6 121.4(5)
C4 C5 C33 124.0(6)
C6 C5 C33 114.6(5)
C5 C6 C1 118.8(6)
O1 C7 N5 119.8(6)
O1 C7 C1 120.1(6)
N5 C7 C1 120.1(6)
C9 C8 C13 120.4(7)
C9 C8 N5 120.1(6)
C13 C8 N5 119.4(7)
C8 C9 C10 121.6(7)
C9 C10 C11 118.7(7)
C10 C11 N16 122.8(7)
C10 C11 C12 121.3(7)
N16 C11 C12 115.9(6)
C13 C12 C11 118.5(6)
C12 C13 C8 119.5(6)
C15 C14 C19 122.1(7)
C15 C14 N11 115.3(7)
C19 C14 N11 122.6(7)
C14 C15 C16 119.2(8)
C15 C16 C17 120.1(10)
C16 C17 C18 119.0(10)
C19 C18 C17 117.7(11)
C14 C19 C18 121.8(9)
O2 C20 N2 125.0(5)
O2 C20 C3 119.4(5)
N2 C20 C3 115.5(6)
C22 C21 N2 121.7(7)
C22 C21 C26 118.7(6)
N2 C21 C26 119.6(6)
C21 C22 C23 122.4(7)
C24 C23 C22 119.0(6)
C23 C24 C25 121.0(6)
C23 C24 N18 117.4(6)
C25 C24 N18 121.6(6)
C26 C25 C24 118.0(7)
C25 C26 C21 120.9(6)
C28 C27 C32 117.9(6)
C28 C27 N17 127.2(6)
C32 C27 N17 114.8(6)
C29 C28 C27 121.7(6)
C28 C29 C30 119.8(6)
C31 C30 C29 119.7(7)
C30 C31 C32 120.0(8)
C27 C32 C31 120.8(7)
O3 C33 N7 127.5(5)
O3 C33 C5 120.3(6)
N7 C33 C5 112.0(5)
C35A C34A C39A 120.0
C35A C34A N7 118.0(8)
C39A C34A N7 120.2(8)
C36A C35A C34A 120.0
C35A C36A C37A 120.0
C36A C37A C38A 120.0
C36A C37A N15 122.1(9)
C38A C37A N15 117.7(9)
C39A C38A C37A 120.0
C38A C39A C34A 120.0
C35B C34B C39B 120.0
C35B C34B N7 111.7(9)
C39B C34B N7 127.7(9)
C34B C35B C36B 120.0
C37B C36B C35B 120.0
C36B C37B C38B 120.0
C36B C37B N15 116.1(10)
C38B C37B N15 123.7(10)
C39B C38B C37B 120.0
C38B C39B C34B 120.0
C45 C40 C41 120.4(7)
C45 C40 N14 126.1(8)
C41 C40 N14 113.4(8)
C42 C41 C40 119.4(8)
C41 C42 C43 119.1(8)
C44 C43 C42 119.4(7)
C43 C44 C45 123.0(9)
C44 C45 C40 118.6(9)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
O1 C7 1.277(7)
O2 C20 1.292(7)
O3 C33 1.169(7)
N2 C20 1.319(7)
N2 C21 1.430(7)
N5 C7 1.328(7)
N5 C8 1.447(8)
N7 C33 1.358(7)
N7 C34B 1.428(6)
N7 C34A 1.428(6)
N11 N16 1.271(7)
N11 C14 1.458(8)
N14 N15 1.263(7)
N14 C40 1.493(8)
N15 C37B 1.458(7)
N15 C37A 1.459(7)
N16 C11 1.394(8)
N17 N18 1.272(7)
N17 C27 1.402(7)
N18 C24 1.449(8)
C1 C2 1.366(7)
C1 C6 1.399(7)
C1 C7 1.456(8)
C2 C3 1.389(8)
C3 C4 1.408(8)
C3 C20 1.505(8)
C4 C5 1.382(8)
C5 C6 1.396(8)
C5 C33 1.585(7)
C8 C9 1.355(9)
C8 C13 1.408(8)
C9 C10 1.374(9)
C10 C11 1.383(9)
C11 C12 1.409(8)
C12 C13 1.383(8)
C14 C15 1.357(9)
C14 C19 1.367(9)
C15 C16 1.385(11)
C16 C17 1.421(12)
C17 C18 1.431(12)
C18 C19 1.372(11)
C21 C22 1.354(8)
C21 C26 1.431(9)
C22 C23 1.393(8)
C23 C24 1.379(8)
C24 C25 1.427(8)
C25 C26 1.381(8)
C27 C28 1.381(7)
C27 C32 1.392(9)
C28 C29 1.375(8)
C29 C30 1.406(9)
C30 C31 1.356(9)
C31 C32 1.411(10)
C34A C35A 1.3900
C34A C39A 1.3900
C35A C36A 1.3900
C36A C37A 1.3900
C37A C38A 1.3900
C38A C39A 1.3900
C34B C35B 1.3900
C34B C39B 1.3900
C35B C36B 1.3900
C36B C37B 1.3900
C37B C38B 1.3900
C38B C39B 1.3900
C40 C45 1.377(10)
C40 C41 1.401(10)
C41 C42 1.392(10)
C42 C43 1.406(10)
C43 C44 1.342(10)
C44 C45 1.373(10)
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.250 0.440 0.000 327 180 ' '
2 0.750 -0.052 0.000 327 180 ' '
3 0.500 0.416 0.250 676 270 ' '
4 1.000 0.916 0.250 676 270 ' '
5 0.250 -0.108 0.500 327 180 ' '
6 0.750 0.392 0.500 327 180 ' '
7 0.500 0.485 0.750 676 268 ' '
8 1.000 -0.015 0.750 676 268 ' '
