#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:11:17 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179680 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/02/7000280.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000280
loop_
_publ_author_name
'Jean-Baptiste dit Dominique, François'
'Gornitzka, Heinz'
'Sournia-Saquet, Alix'
'Hemmert, Catherine'
_publ_section_title
;
 Dinuclear gold(i) and gold(iii) complexes of bridging functionalized
 bis(N-heterocyclic carbene) ligands: synthesis, structural,
 spectroscopic and electrochemical characterizations
;
_journal_issue                   2
_journal_name_full               'Dalton Transactions'
_journal_page_first              340
_journal_page_last               352
_journal_paper_doi               10.1039/b809943j
_journal_year                    2009
_chemical_formula_sum            'C35 H62 Au2 F12 N8 O6 P2'
_chemical_formula_weight         1374.80
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.366(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.814(3)
_cell_length_b                   12.286(2)
_cell_length_c                   28.357(5)
_cell_measurement_reflns_used    4404
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.79
_cell_measurement_theta_min      2.21
_cell_volume                     5419.6(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.953
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0399
_diffrn_reflns_av_sigmaI/netI    0.0842
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            16612
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         5.11
_exptl_absorpt_coefficient_mu    5.553
_exptl_absorpt_correction_T_max  0.6067
_exptl_absorpt_correction_T_min  0.1678
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            clear
_exptl_crystal_density_diffrn    1.685
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2688
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.10
_refine_diff_density_max         3.155
_refine_diff_density_min         -6.708
_refine_diff_density_rms         0.274
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     681
_refine_ls_number_reflns         10577
_refine_ls_number_restraints     192
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.1090
_refine_ls_R_factor_gt           0.0736
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0861P)²+145.4051P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1890
_refine_ls_wR_factor_ref         0.2099
_reflns_number_gt                7222
_reflns_number_total             10577
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b809943j.txt
_cod_data_source_block           15.MeOH.H2O
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        5419.3(16)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7000280
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.77544(3) 0.35367(4) 0.179384(18) 0.02075(16) Uani 1 1 d . . .
Au2 Au 1.17630(3) 0.34828(4) 0.179127(19) 0.02368(17) Uani 1 1 d . . .
N1 N 1.2326(7) 0.5808(10) 0.1648(5) 0.031(3) Uani 1 1 d . . .
N2 N 1.1420(7) 0.5768(9) 0.2125(4) 0.026(3) Uani 1 1 d . . .
N3 N 0.8343(7) 0.5751(9) 0.2183(4) 0.023(2) Uani 1 1 d . . .
N4 N 0.7121(7) 0.5882(9) 0.1705(4) 0.022(2) Uani 1 1 d . . .
O1 O 1.1789(10) 0.4712(17) 0.0715(6) 0.086(6) Uani 1 1 d . . .
H1 H 1.1789 0.4409 0.0450 0.129 Uiso 1 1 calc R . .
O2 O 0.7120(7) 0.4780(11) 0.0774(4) 0.049(3) Uani 1 1 d . . .
H2 H 0.7619 0.5013 0.0771 0.073 Uiso 1 1 calc R . .
C1 C 1.1824(9) 0.5088(11) 0.1851(6) 0.030(3) Uani 1 1 d U . .
C2 C 1.2263(10) 0.6871(12) 0.1820(7) 0.038(4) Uani 1 1 d . . .
H2 H 1.2555 0.7497 0.1736 0.046 Uiso 1 1 calc R . .
C3 C 1.1697(10) 0.6832(12) 0.2135(6) 0.036(4) Uani 1 1 d . . .
H3 H 1.1532 0.7414 0.2320 0.043 Uiso 1 1 calc R . .
C4 C 1.2865(8) 0.5528(12) 0.1304(5) 0.026(3) Uani 1 1 d . . .
H4A H 1.3096 0.4787 0.1379 0.031 Uiso 1 1 calc R . .
H4B H 1.3359 0.6036 0.1348 0.031 Uiso 1 1 calc R . .
C5 C 1.2441(10) 0.5556(16) 0.0789(7) 0.046(4) Uani 1 1 d . . .
C6 C 1.3102(14) 0.535(2) 0.0485(7) 0.065(6) Uani 1 1 d . . .
H6A H 1.3425 0.4688 0.0597 0.097 Uiso 1 1 calc R . .
H6B H 1.3496 0.5968 0.0507 0.097 Uiso 1 1 calc R . .
H6C H 1.2817 0.5250 0.0151 0.097 Uiso 1 1 calc R . .
C7 C 1.205(2) 0.672(2) 0.0662(9) 0.103(11) Uani 1 1 d . . .
H7A H 1.1419 0.6668 0.0598 0.155 Uiso 1 1 calc R . .
H7B H 1.2246 0.6995 0.0377 0.155 Uiso 1 1 calc R . .
H7C H 1.2233 0.7211 0.0932 0.155 Uiso 1 1 calc R . .
C8 C 1.0776(8) 0.5372(13) 0.2405(5) 0.030(3) Uani 1 1 d . . .
H8A H 1.0872 0.5719 0.2725 0.036 Uiso 1 1 calc R . .
H8B H 1.0828 0.4574 0.2449 0.036 Uiso 1 1 calc R . .
C9 C 0.9881(8) 0.5662(13) 0.2130(5) 0.030(3) Uani 1 1 d . . .
H9A H 0.9774 0.5271 0.1819 0.036 Uiso 1 1 calc R . .
H9B H 0.9851 0.6453 0.2062 0.036 Uiso 1 1 calc R . .
C10 C 0.9172(8) 0.5345(11) 0.2428(5) 0.024(3) Uani 1 1 d . . .
H10A H 0.9149 0.4544 0.2461 0.029 Uiso 1 1 calc R . .
H10B H 0.9313 0.5666 0.2753 0.029 Uiso 1 1 calc R . .
C11 C 0.7740(10) 0.5119(11) 0.1897(5) 0.030(3) Uani 1 1 d . . .
C12 C 0.7332(10) 0.6901(12) 0.1889(6) 0.030(3) Uani 1 1 d . . .
H12 H 0.6997 0.7541 0.1814 0.036 Uiso 1 1 calc R . .
C13 C 0.8096(9) 0.6846(10) 0.2194(5) 0.024(3) Uani 1 1 d . . .
H13 H 0.8397 0.7421 0.2376 0.029 Uiso 1 1 calc R . .
C14 C 0.6375(8) 0.5649(11) 0.1341(5) 0.022(3) Uani 1 1 d . . .
H14A H 0.5922 0.6191 0.1365 0.026 Uiso 1 1 calc R . .
H14B H 0.6149 0.4922 0.1403 0.026 Uiso 1 1 calc R . .
C15 C 0.6571(9) 0.5671(14) 0.0838(6) 0.035(4) Uani 1 1 d . . .
C16 C 0.6979(14) 0.6740(16) 0.0713(8) 0.060(6) Uani 1 1 d . . .
H16A H 0.7554 0.6813 0.0909 0.091 Uiso 1 1 calc R . .
H16B H 0.6620 0.7353 0.0778 0.091 Uiso 1 1 calc R . .
H16C H 0.7024 0.6737 0.0373 0.091 Uiso 1 1 calc R . .
C17 C 0.5691(11) 0.544(2) 0.0498(7) 0.059(6) Uani 1 1 d . . .
H17A H 0.5797 0.5238 0.0179 0.089 Uiso 1 1 calc R . .
H17B H 0.5331 0.6093 0.0473 0.089 Uiso 1 1 calc R . .
H17C H 0.5395 0.4840 0.0629 0.089 Uiso 1 1 calc R . .
N5 N 1.2300(7) 0.1152(9) 0.1605(5) 0.027(3) Uani 1 1 d . . .
N6 N 1.1382(9) 0.1195(11) 0.2065(5) 0.039(3) Uani 1 1 d . . .
N7 N 0.8240(7) 0.1172(9) 0.2001(5) 0.028(3) Uani 1 1 d . . .
N8 N 0.7062(8) 0.1262(9) 0.1500(5) 0.029(3) Uani 1 1 d . . .
O3 O 1.1764(14) 0.2285(19) 0.0689(7) 0.112(8) Uani 1 1 d . . .
H3A H 1.1310 0.2060 0.0515 0.168 Uiso 1 1 calc R . .
O4 O 0.7204(9) 0.2456(13) 0.0628(5) 0.065(4) Uani 1 1 d . . .
H4 H 0.7053 0.3100 0.0668 0.097 Uiso 1 1 calc R . .
C18 C 1.1800(8) 0.1834(12) 0.1811(5) 0.027(3) Uani 1 1 d . . .
C19 C 1.2217(9) 0.0061(17) 0.1750(7) 0.051(5) Uani 1 1 d . . .
H19 H 1.2508 -0.0563 0.1662 0.061 Uiso 1 1 calc R . .
C20 C 1.1633(10) 0.0107(12) 0.2038(6) 0.037(4) Uani 1 1 d . . .
H20 H 1.1426 -0.0491 0.2197 0.044 Uiso 1 1 calc R . .
C21 C 1.2865(10) 0.1480(14) 0.1276(6) 0.037(4) Uani 1 1 d . . .
H21A H 1.3381 0.1008 0.1324 0.044 Uiso 1 1 calc R . .
H21B H 1.3056 0.2240 0.1345 0.044 Uiso 1 1 calc R . .
C22 C 1.2409(12) 0.1396(17) 0.0761(8) 0.055(5) Uani 1 1 d . . .
C23 C 1.2106(17) 0.027(2) 0.0633(7) 0.082(9) Uani 1 1 d . . .
H23A H 1.1715 0.0034 0.0845 0.123 Uiso 1 1 calc R . .
H23B H 1.2601 -0.0225 0.0670 0.123 Uiso 1 1 calc R . .
H23C H 1.1804 0.0253 0.0299 0.123 Uiso 1 1 calc R . .
C24 C 1.3135(19) 0.1718(19) 0.0459(9) 0.083(8) Uani 1 1 d . . .
H24A H 1.3551 0.1122 0.0474 0.124 Uiso 1 1 calc R . .
H24B H 1.3430 0.2379 0.0594 0.124 Uiso 1 1 calc R . .
H24C H 1.2868 0.1849 0.0124 0.124 Uiso 1 1 calc R . .
C25 C 1.0697(10) 0.1561(13) 0.2324(6) 0.041(4) Uani 1 1 d . . .
H25A H 1.0736 0.2358 0.2373 0.049 Uiso 1 1 calc R . .
H25B H 1.0773 0.1205 0.2642 0.049 Uiso 1 1 calc R . .
C26 C 0.9810(9) 0.1264(13) 0.2028(7) 0.038(4) Uani 1 1 d . . .
H26A H 0.9710 0.1694 0.1728 0.046 Uiso 1 1 calc R . .
H26B H 0.9807 0.0484 0.1940 0.046 Uiso 1 1 calc R . .
C27 C 0.9079(8) 0.1483(13) 0.2308(5) 0.029(3) Uani 1 1 d . . .
H27A H 0.9171 0.1051 0.2607 0.035 Uiso 1 1 calc R . .
H27B H 0.9071 0.2263 0.2393 0.035 Uiso 1 1 calc R . .
C28 C 0.7719(8) 0.1864(11) 0.1754(5) 0.021(3) Uani 1 1 d . . .
C29 C 0.7226(10) 0.0167(15) 0.1621(6) 0.044(4) Uani 1 1 d . . .
H29 H 0.6870 -0.0431 0.1503 0.053 Uiso 1 1 calc R . .
C30 C 0.7955(9) 0.0107(11) 0.1926(6) 0.031(3) Uani 1 1 d . . .
H30 H 0.8229 -0.0533 0.2066 0.037 Uiso 1 1 calc R . .
C31 C 0.6325(9) 0.1694(12) 0.1157(6) 0.032(3) Uani 1 1 d . . .
H31A H 0.6187 0.2435 0.1258 0.039 Uiso 1 1 calc R . .
H31B H 0.5816 0.1227 0.1163 0.039 Uiso 1 1 calc R . .
C32 C 0.6503(11) 0.1739(14) 0.0652(6) 0.041(4) Uani 1 1 d . . .
C33 C 0.6735(14) 0.0628(19) 0.0470(8) 0.062(6) Uani 1 1 d . . .
H33A H 0.6742 0.0673 0.0126 0.094 Uiso 1 1 calc R . .
H33B H 0.6307 0.0089 0.0527 0.094 Uiso 1 1 calc R . .
H33C H 0.7304 0.0408 0.0641 0.094 Uiso 1 1 calc R . .
C34 C 0.5675(15) 0.2183(19) 0.0340(7) 0.066(6) Uani 1 1 d . . .
H34A H 0.5587 0.2940 0.0428 0.100 Uiso 1 1 calc R . .
H34B H 0.5183 0.1742 0.0392 0.100 Uiso 1 1 calc R . .
H34C H 0.5728 0.2148 0.0001 0.100 Uiso 1 1 calc R . .
O5 O 0.8895(13) 0.5047(18) 0.0905(8) 0.048(6) Uani 0.57(2) 1 d PDU A 1
H5 H 0.9237 0.5549 0.0865 0.073 Uiso 0.57(2) 1 calc PR A 1
C35 C 0.937(2) 0.401(3) 0.0991(15) 0.067(11) Uani 0.57(2) 1 d PDU A 1
H35A H 0.9989 0.4143 0.1003 0.100 Uiso 0.57(2) 1 calc PR A 1
H35B H 0.9165 0.3496 0.0731 0.100 Uiso 0.57(2) 1 calc PR A 1
H35C H 0.9287 0.3696 0.1297 0.100 Uiso 0.57(2) 1 calc PR A 1
O5' O 0.9387(13) 0.576(2) 0.0077(9) 0.032(7) Uani 0.43(2) 1 d PDU A 2
H5' H 0.9172 0.6190 -0.0140 0.048 Uiso 0.43(2) 1 calc PR A 2
C35' C 0.873(4) 0.547(6) 0.038(2) 0.102(18) Uani 0.43(2) 1 d PDU A 2
H35D H 0.8967 0.5603 0.0715 0.153 Uiso 0.43(2) 1 calc PR A 2
H35E H 0.8573 0.4701 0.0331 0.153 Uiso 0.43(2) 1 calc PR A 2
H35F H 0.8216 0.5922 0.0280 0.153 Uiso 0.43(2) 1 calc PR A 2
O6 O 0.9753(16) 0.791(2) -0.0108(12) 0.063(8) Uani 0.50 1 d P . .
O7 O 1.108(2) 0.843(4) -0.060(2) 0.16(2) Uani 0.50 1 d P . .
P1 P 0.0169(2) 0.8551(3) 0.30195(13) 0.0253(7) Uani 1 1 d D . .
F1 F 0.1170(6) 0.8550(10) 0.3007(4) 0.068(3) Uani 1 1 d D . .
F2 F 0.0144(8) 0.7245(7) 0.3013(4) 0.069(3) Uani 1 1 d D . .
F3 F 0.0385(7) 0.8530(8) 0.3579(3) 0.054(3) Uani 1 1 d D . .
F4 F -0.0820(6) 0.8558(10) 0.3033(4) 0.069(4) Uani 1 1 d D . .
F5 F 0.0184(7) 0.9836(7) 0.3052(4) 0.062(3) Uani 1 1 d D . .
F6 F -0.0038(6) 0.8582(10) 0.2452(3) 0.055(3) Uani 1 1 d D . .
P2 P 0.0363(2) 0.3553(3) 0.36691(15) 0.0301(8) Uani 1 1 d DU . .
F7 F -0.0403(15) 0.3668(19) 0.3962(9) 0.101(8) Uani 0.73(3) 1 d PDU B 1
F8 F 0.0230(13) 0.4786(10) 0.3500(8) 0.073(6) Uani 0.73(3) 1 d PDU B 1
F9 F -0.0347(13) 0.3218(16) 0.3236(7) 0.084(6) Uani 0.73(3) 1 d PDU B 1
F10 F 0.1078(14) 0.3447(18) 0.3355(9) 0.092(7) Uani 0.73(3) 1 d PDU B 1
F11 F 0.0481(14) 0.2317(10) 0.3810(10) 0.090(7) Uani 0.73(3) 1 d PDU B 1
F12 F 0.1026(17) 0.3886(19) 0.4126(7) 0.113(8) Uani 0.73(3) 1 d PDU B 1
F7' F -0.0652(10) 0.350(3) 0.361(2) 0.079(14) Uani 0.27(3) 1 d PDU B 2
F8' F 0.032(3) 0.475(2) 0.3445(19) 0.092(15) Uani 0.27(3) 1 d PDU B 2
F9' F 0.026(4) 0.311(4) 0.3142(9) 0.101(15) Uani 0.27(3) 1 d PDU B 2
F10' F 0.1366(11) 0.356(3) 0.370(2) 0.071(13) Uani 0.27(3) 1 d PDU B 2
F11' F 0.042(3) 0.2341(18) 0.3855(18) 0.072(14) Uani 0.27(3) 1 d PDU B 2
F12' F 0.043(4) 0.401(4) 0.4189(9) 0.097(15) Uani 0.27(3) 1 d PDU B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Au1 C28 173.8(5) . . ?
C1 Au2 C18 172.9(6) . . ?
C1 N1 C2 111.6(11) . . ?
C1 N1 C4 125.5(12) . . ?
C2 N1 C4 122.9(12) . . ?
C1 N2 C3 114.2(11) . . ?
C1 N2 C8 122.5(12) . . ?
C3 N2 C8 123.2(12) . . ?
C11 N3 C13 112.9(11) . . ?
C11 N3 C10 123.8(11) . . ?
C13 N3 C10 123.2(11) . . ?
C12 N4 C11 111.1(12) . . ?
C12 N4 C14 124.1(12) . . ?
C11 N4 C14 124.8(12) . . ?
N2 C1 N1 101.9(11) . . ?
N2 C1 Au2 129.3(11) . . ?
N1 C1 Au2 128.7(10) . . ?
C3 C2 N1 106.8(12) . . ?
C2 C3 N2 105.1(13) . . ?
N1 C4 C5 116.0(12) . . ?
O1 C5 C6 110.3(16) . . ?
O1 C5 C4 107.9(15) . . ?
C6 C5 C4 108.9(14) . . ?
O1 C5 C7 111.9(19) . . ?
C6 C5 C7 108.2(19) . . ?
C4 C5 C7 109.5(16) . . ?
N2 C8 C9 108.2(12) . . ?
C8 C9 C10 110.6(11) . . ?
N3 C10 C9 109.0(11) . . ?
N3 C11 N4 102.4(11) . . ?
N3 C11 Au1 128.4(11) . . ?
N4 C11 Au1 129.3(12) . . ?
C13 C12 N4 108.9(13) . . ?
C12 C13 N3 104.6(12) . . ?
N4 C14 C15 112.9(10) . . ?
O2 C15 C14 109.8(13) . . ?
O2 C15 C16 109.6(14) . . ?
C14 C15 C16 113.5(14) . . ?
O2 C15 C17 105.9(14) . . ?
C14 C15 C17 105.5(13) . . ?
C16 C15 C17 112.1(16) . . ?
C18 N5 C19 111.7(12) . . ?
C18 N5 C21 125.2(12) . . ?
C19 N5 C21 123.1(12) . . ?
C18 N6 C20 111.3(13) . . ?
C18 N6 C25 124.9(13) . . ?
C20 N6 C25 123.8(12) . . ?
C28 N7 C30 112.2(12) . . ?
C28 N7 C27 123.8(12) . . ?
C30 N7 C27 123.9(12) . . ?
C28 N8 C29 107.5(12) . . ?
C28 N8 C31 125.9(12) . . ?
C29 N8 C31 126.5(13) . . ?
N6 C18 N5 104.8(13) . . ?
N6 C18 Au2 126.4(10) . . ?
N5 C18 Au2 128.5(10) . . ?
C20 C19 N5 104.2(14) . . ?
C19 C20 N6 107.9(14) . . ?
N5 C21 C22 111.0(13) . . ?
O3 C22 C23 118(2) . . ?
O3 C22 C21 106.3(16) . . ?
C23 C22 C21 112.1(18) . . ?
O3 C22 C24 106.6(19) . . ?
C23 C22 C24 109.2(17) . . ?
C21 C22 C24 103.7(16) . . ?
N6 C25 C26 109.5(14) . . ?
C27 C26 C25 111.9(14) . . ?
N7 C27 C26 109.0(12) . . ?
N7 C28 N8 106.1(12) . . ?
N7 C28 Au1 128.0(10) . . ?
N8 C28 Au1 125.4(10) . . ?
C30 C29 N8 108.5(14) . . ?
C29 C30 N7 105.7(14) . . ?
N8 C31 C32 112.2(12) . . ?
O4 C32 C31 110.3(14) . . ?
O4 C32 C33 107.5(15) . . ?
C31 C32 C33 112.6(15) . . ?
O4 C32 C34 109.9(16) . . ?
C31 C32 C34 105.8(15) . . ?
C33 C32 C34 110.6(16) . . ?
F3 P1 F4 90.6(6) . . ?
F3 P1 F5 87.6(6) . . ?
F4 P1 F5 89.8(6) . . ?
F3 P1 F6 179.2(6) . . ?
F4 P1 F6 90.0(6) . . ?
F5 P1 F6 91.9(6) . . ?
F3 P1 F1 89.3(6) . . ?
F4 P1 F1 179.7(7) . . ?
F5 P1 F1 89.9(6) . . ?
F6 P1 F1 90.1(6) . . ?
F3 P1 F2 89.8(6) . . ?
F4 P1 F2 89.0(7) . . ?
F5 P1 F2 177.1(7) . . ?
F6 P1 F2 90.7(6) . . ?
F1 P1 F2 91.3(7) . . ?
F12' P2 F9 139(2) . . ?
F12' P2 F10 129(2) . . ?
F9 P2 F10 91.2(11) . . ?
F12' P2 F12 37.1(16) . . ?
F9 P2 F12 176.1(12) . . ?
F10 P2 F12 92.7(12) . . ?
F12' P2 F9' 178(2) . . ?
F9 P2 F9' 38.9(17) . . ?
F10 P2 F9' 52.8(19) . . ?
F12 P2 F9' 145(2) . . ?
F12' P2 F10' 92.2(17) . . ?
F9 P2 F10' 129(2) . . ?
F10 P2 F10' 38.0(17) . . ?
F12 P2 F10' 55.2(19) . . ?
F9' P2 F10' 89.8(17) . . ?
F12' P2 F11 97(3) . . ?
F9 P2 F11 89.0(11) . . ?
F10 P2 F11 90.0(10) . . ?
F12 P2 F11 90.6(11) . . ?
F9' P2 F11 84(3) . . ?
F10' P2 F11 85(2) . . ?
F12' P2 F11' 91.9(16) . . ?
F9 P2 F11' 90(2) . . ?
F10 P2 F11' 96(2) . . ?
F12 P2 F11' 89(2) . . ?
F9' P2 F11' 89.0(16) . . ?
F10' P2 F11' 89.2(14) . . ?
F11 P2 F11' 6(2) . . ?
F12' P2 F7' 91.3(17) . . ?
F9 P2 F7' 47.9(19) . . ?
F10 P2 F7' 139(2) . . ?
F12 P2 F7' 128(2) . . ?
F9' P2 F7' 86.7(17) . . ?
F10' P2 F7' 176.4(19) . . ?
F11 P2 F7' 93(2) . . ?
F11' P2 F7' 89.9(15) . . ?
F12' P2 F8 86(2) . . ?
F9 P2 F8 88.6(9) . . ?
F10 P2 F8 88.7(10) . . ?
F12 P2 F8 91.9(10) . . ?
F9' P2 F8 93(2) . . ?
F10' P2 F8 95(2) . . ?
F11 P2 F8 177.2(12) . . ?
F11' P2 F8 175(2) . . ?
F7' P2 F8 86.0(19) . . ?
F12' P2 F7 53.8(19) . . ?
F9 P2 F7 85.8(11) . . ?
F10 P2 F7 176.8(12) . . ?
F12 P2 F7 90.3(12) . . ?
F9' P2 F7 124(2) . . ?
F10' P2 F7 145(2) . . ?
F11 P2 F7 91.1(10) . . ?
F11' P2 F7 85(2) . . ?
F7' P2 F7 38.1(17) . . ?
F8 P2 F7 90.1(10) . . ?
F12' P2 F8' 92.1(16) . . ?
F9 P2 F8' 87(2) . . ?
F10 P2 F8' 80(2) . . ?
F12 P2 F8' 94(2) . . ?
F9' P2 F8' 87.0(16) . . ?
F10' P2 F8' 89.3(15) . . ?
F11 P2 F8' 170(2) . . ?
F11' P2 F8' 175.7(18) . . ?
F7' P2 F8' 91.4(15) . . ?
F8 P2 F8' 8(2) . . ?
F7 P2 F8' 98(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C11 1.966(14) . ?
Au1 C28 2.059(13) . ?
Au2 C1 1.980(14) . ?
Au2 C18 2.027(14) . ?
N1 C1 1.380(19) . ?
N1 C2 1.405(19) . ?
N1 C4 1.447(16) . ?
N2 C1 1.375(18) . ?
N2 C3 1.377(18) . ?
N2 C8 1.481(16) . ?
N3 C11 1.375(19) . ?
N3 C13 1.403(16) . ?
N3 C10 1.457(16) . ?
N4 C12 1.374(18) . ?
N4 C11 1.394(18) . ?
N4 C14 1.448(17) . ?
O1 C5 1.45(2) . ?
O2 C15 1.430(18) . ?
C2 C3 1.37(2) . ?
C4 C5 1.49(2) . ?
C5 C6 1.49(2) . ?
C5 C7 1.57(3) . ?
C8 C9 1.531(19) . ?
C9 C10 1.570(17) . ?
C12 C13 1.36(2) . ?
C14 C15 1.513(19) . ?
C15 C16 1.53(2) . ?
C15 C17 1.57(2) . ?
N5 C18 1.354(16) . ?
N5 C19 1.41(2) . ?
N5 C21 1.461(18) . ?
N6 C18 1.321(18) . ?
N6 C20 1.400(19) . ?
N6 C25 1.481(18) . ?
N7 C28 1.297(18) . ?
N7 C30 1.389(17) . ?
N7 C27 1.498(18) . ?
N8 C28 1.369(18) . ?
N8 C29 1.40(2) . ?
N8 C31 1.48(2) . ?
O3 C22 1.48(2) . ?
O4 C32 1.426(19) . ?
C19 C20 1.34(2) . ?
C21 C22 1.51(3) . ?
C22 C23 1.49(3) . ?
C22 C24 1.60(3) . ?
C25 C26 1.54(2) . ?
C26 C27 1.539(18) . ?
C29 C30 1.31(2) . ?
C31 C32 1.51(2) . ?
C32 C33 1.53(3) . ?
C32 C34 1.54(3) . ?
O5 C35 1.48(3) . ?
O5' C35' 1.50(3) . ?
P1 F3 1.562(9) . ?
P1 F4 1.572(9) . ?
P1 F5 1.581(9) . ?
P1 F6 1.583(9) . ?
P1 F1 1.590(9) . ?
P1 F2 1.604(9) . ?
P2 F12' 1.562(17) . ?
P2 F9 1.562(13) . ?
P2 F10 1.565(11) . ?
P2 F12 1.567(13) . ?
P2 F9' 1.571(17) . ?
P2 F10' 1.572(15) . ?
P2 F11 1.573(11) . ?
P2 F11' 1.577(15) . ?
P2 F7' 1.584(15) . ?
P2 F8 1.591(11) . ?
P2 F7 1.592(12) . ?
P2 F8' 1.595(15) . ?
