#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:12:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179681 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/03/7000381.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000381
loop_
_publ_author_name
'Schenk, Christian'
'Drost, Christian'
'Schnepf, Andreas'
_publ_section_title
;
 [(OtBu)2C6H3]3Ge+ a free germyl cation with aryl ligands
;
_journal_issue                   5
_journal_name_full               'Dalton Transactions'
_journal_page_first              773
_journal_page_last               776
_journal_paper_doi               10.1039/b818931e
_journal_year                    2009
_chemical_formula_sum            'C42 H64 Ge O7'
_chemical_formula_weight         753.52
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.70(3)
_cell_angle_beta                 95.43(3)
_cell_angle_gamma                90.95(3)
_cell_formula_units_Z            2
_cell_length_a                   11.869(2)
_cell_length_b                   12.774(3)
_cell_length_c                   13.757(3)
_cell_measurement_reflns_used    25423
_cell_measurement_temperature    149(2)
_cell_measurement_theta_max      25.94
_cell_measurement_theta_min      1.44
_cell_volume                     2075.9(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      149(2)
_diffrn_measured_fraction_theta_full 0.898
_diffrn_measured_fraction_theta_max 0.898
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0667
_diffrn_reflns_av_sigmaI/netI    0.0836
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            14158
_diffrn_reflns_theta_full        26.05
_diffrn_reflns_theta_max         26.05
_diffrn_reflns_theta_min         1.49
_exptl_absorpt_coefficient_mu    0.783
_exptl_absorpt_correction_T_max  0.8745
_exptl_absorpt_correction_T_min  0.7874
_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.205
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             808
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.487
_refine_diff_density_min         -0.674
_refine_diff_density_rms         0.063
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.947
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     498
_refine_ls_number_reflns         7372
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.947
_refine_ls_R_factor_all          0.0725
_refine_ls_R_factor_gt           0.0475
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0596P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1076
_refine_ls_wR_factor_ref         0.1179
_reflns_number_gt                5339
_reflns_number_total             7372
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b818931e.txt
_cod_data_source_block           cs70p-1
_cod_original_cell_volume        2075.9(7)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7000381
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.28617(3) 0.79509(3) 0.28317(3) 0.03019(12) Uani 0.9479(14) 1 d P A 1
O100 O 0.32367(19) 0.88158(18) 0.38487(17) 0.0358(6) Uani 0.9479(14) 1 d P A 1
Ge1A Ge 0.2725(6) 0.7296(6) 0.2187(6) 0.047(3) Uiso 0.0521(14) 1 d P A 2
O101 O 0.237(4) 0.631(4) 0.125(4) 0.049(11) Uiso 0.0521(14) 1 d P A 2
O1 O 0.4143(2) 0.58681(16) 0.24485(18) 0.0446(6) Uani 1 1 d . . .
O2 O 0.1377(2) 0.72723(16) 0.42663(17) 0.0422(6) Uani 1 1 d . . .
O10 O 0.06642(19) 0.67457(16) 0.20781(19) 0.0464(6) Uani 1 1 d . . .
O11 O 0.21584(19) 1.01525(17) 0.25067(18) 0.0456(6) Uani 1 1 d . . .
O20 O 0.53142(19) 0.78364(17) 0.33296(17) 0.0415(6) Uani 1 1 d . . .
O21 O 0.2776(2) 0.85110(17) 0.05381(17) 0.0426(6) Uani 1 1 d . . .
C1 C 0.2825(3) 0.6572(2) 0.3422(3) 0.0369(8) Uani 1 1 d . . .
C2 C 0.2075(3) 0.6451(2) 0.4144(3) 0.0443(9) Uani 1 1 d . A .
C3 C 0.1992(3) 0.5507(3) 0.4639(3) 0.0546(10) Uani 1 1 d . . .
H3A H 0.1485 0.5433 0.5130 0.066 Uiso 1 1 calc R A .
C4 C 0.2654(4) 0.4687(3) 0.4404(3) 0.0604(11) Uani 1 1 d . A .
H4A H 0.2608 0.4047 0.4743 0.073 Uiso 1 1 calc R . .
C6 C 0.3384(3) 0.4772(3) 0.3687(3) 0.0514(10) Uani 1 1 d . . .
H6A H 0.3826 0.4191 0.3530 0.062 Uiso 1 1 calc R A .
C5 C 0.3473(3) 0.5716(2) 0.3189(3) 0.0413(8) Uani 1 1 d . A .
C7C C 0.4364(4) 0.4176(3) 0.1654(4) 0.0758(14) Uani 1 1 d . . .
H7CA H 0.375(3) 0.4408(7) 0.117(2) 0.114 Uiso 1 1 calc R . .
H7CB H 0.404(3) 0.3739(19) 0.2151(14) 0.114 Uiso 1 1 calc R . .
H7CC H 0.4912(17) 0.3761(19) 0.132(2) 0.114 Uiso 1 1 calc R . .
C7 C 0.4967(3) 0.5130(3) 0.2149(3) 0.0485(9) Uani 1 1 d . . .
C7B C 0.5569(3) 0.5731(3) 0.1410(3) 0.0598(11) Uani 1 1 d . . .
H7BA H 0.5006(14) 0.598(2) 0.0890(16) 0.090 Uiso 1 1 calc R . .
H7BB H 0.611(2) 0.5267(13) 0.1116(17) 0.090 Uiso 1 1 calc R . .
H7BC H 0.598(2) 0.6338(19) 0.1736(9) 0.090 Uiso 1 1 calc R . .
C7A C 0.5827(4) 0.4863(4) 0.3012(4) 0.0831(17) Uani 1 1 d . . .
H7AA H 0.618(3) 0.5527(19) 0.331(2) 0.125 Uiso 1 1 calc R . .
H7AB H 0.643(2) 0.441(3) 0.2774(9) 0.125 Uiso 1 1 calc R . .
H7AC H 0.5431(13) 0.447(3) 0.3515(19) 0.125 Uiso 1 1 calc R . .
C8 C 0.1139(3) 0.7684(3) 0.5214(3) 0.0494(9) Uani 1 1 d . . .
C8C C 0.0740(4) 0.8782(3) 0.4984(3) 0.0561(10) Uani 1 1 d . . .
H8CA H 0.010(2) 0.8748(3) 0.4467(19) 0.084 Uiso 1 1 calc R . .
H8CB H 0.1371(16) 0.9202(12) 0.475(2) 0.084 Uiso 1 1 calc R . .
H8CC H 0.049(2) 0.9115(11) 0.5582(15) 0.084 Uiso 1 1 calc R . .
C8B C 0.0180(4) 0.7054(3) 0.5609(4) 0.0700(13) Uani 1 1 d . . .
H8BA H -0.050(2) 0.696(2) 0.5059(15) 0.105 Uiso 1 1 calc R . .
H8BB H -0.0100(19) 0.7453(15) 0.622(2) 0.105 Uiso 1 1 calc R . .
H8BC H 0.0476(11) 0.631(2) 0.583(2) 0.105 Uiso 1 1 calc R . .
C8A C 0.2201(4) 0.7716(3) 0.5923(3) 0.0671(13) Uani 1 1 d . . .
H8AA H 0.2825(18) 0.807(2) 0.5613(12) 0.101 Uiso 1 1 calc R . .
H8AB H 0.2425(18) 0.6988(19) 0.6094(19) 0.101 Uiso 1 1 calc R . .
H8AC H 0.2049(9) 0.811(2) 0.6526(18) 0.101 Uiso 1 1 calc R . .
C10 C 0.1364(3) 0.8450(2) 0.2327(2) 0.0337(7) Uani 1 1 d . . .
C11 C 0.1197(3) 0.9524(2) 0.2299(2) 0.0378(8) Uani 1 1 d . A .
C12 C 0.0124(3) 0.9943(3) 0.2149(3) 0.0478(9) Uani 1 1 d . . .
H12A H 0.0025 1.0679 0.2169 0.057 Uiso 1 1 calc R A .
C13 C -0.0796(3) 0.9268(3) 0.1971(3) 0.0495(10) Uani 1 1 d . A .
H13A H -0.1535 0.9546 0.1866 0.059 Uiso 1 1 calc R . .
C14 C -0.0661(3) 0.8200(3) 0.1942(3) 0.0464(9) Uani 1 1 d . . .
H14A H -0.1301 0.7748 0.1799 0.056 Uiso 1 1 calc R A .
C15 C 0.0408(3) 0.7786(2) 0.2122(2) 0.0375(8) Uani 1 1 d . A .
C17 C -0.0165(3) 0.5882(3) 0.1955(3) 0.0541(10) Uani 1 1 d . . .
C17C C 0.0602(4) 0.4933(3) 0.2006(4) 0.0632(12) Uani 1 1 d . . .
H17A H 0.101(2) 0.4909(14) 0.2638(18) 0.095 Uiso 1 1 calc R . .
H17B H 0.112(2) 0.4987(12) 0.1519(19) 0.095 Uiso 1 1 calc R . .
H17C H 0.0151(12) 0.4308(16) 0.189(2) 0.095 Uiso 1 1 calc R . .
C17B C -0.0825(4) 0.5930(3) 0.0944(4) 0.0747(15) Uani 1 1 d . . .
H17D H -0.140(2) 0.649(2) 0.0944(8) 0.112 Uiso 1 1 calc R . .
H17E H -0.121(3) 0.525(2) 0.0786(12) 0.112 Uiso 1 1 calc R . .
H17F H -0.0293(15) 0.609(3) 0.0447(14) 0.112 Uiso 1 1 calc R . .
C17A C -0.0911(4) 0.5874(3) 0.2789(4) 0.0699(13) Uani 1 1 d . . .
H17G H -0.137(2) 0.649(2) 0.2761(13) 0.105 Uiso 1 1 calc R . .
H17H H -0.0443(12) 0.587(2) 0.3401(16) 0.105 Uiso 1 1 calc R . .
H17I H -0.139(2) 0.526(2) 0.2735(13) 0.105 Uiso 1 1 calc R . .
C18 C 0.2378(3) 1.1101(2) 0.1961(3) 0.0436(9) Uani 1 1 d . . .
C18C C 0.1895(3) 1.1002(3) 0.0895(3) 0.0506(10) Uani 1 1 d . . .
H18A H 0.1072(19) 1.098(2) 0.0859(3) 0.076 Uiso 1 1 calc R . .
H18B H 0.2158(18) 1.0358(18) 0.0613(9) 0.076 Uiso 1 1 calc R . .
H18C H 0.2147(18) 1.1598(17) 0.0534(10) 0.076 Uiso 1 1 calc R . .
C18B C 0.3670(3) 1.1148(3) 0.2033(3) 0.0495(9) Uani 1 1 d . . .
H18D H 0.3969 1.1209 0.2720 0.074 Uiso 1 1 calc R . .
H18E H 0.3919 1.1757 0.1678 0.074 Uiso 1 1 calc R . .
H18F H 0.3951 1.0508 0.1747 0.074 Uiso 1 1 calc R . .
C18A C 0.1913(3) 1.2048(3) 0.2459(3) 0.0552(10) Uani 1 1 d . . .
H18G H 0.2176(19) 1.2040(11) 0.3198(17) 0.083 Uiso 1 1 calc R . .
H18H H 0.104(2) 1.2023(11) 0.2361(16) 0.083 Uiso 1 1 calc R . .
H18I H 0.2209(19) 1.2725(16) 0.2158(15) 0.083 Uiso 1 1 calc R . .
C20 C 0.4058(3) 0.8185(2) 0.1953(2) 0.0333(7) Uani 1 1 d . . .
C21 C 0.5171(3) 0.8216(2) 0.2390(2) 0.0379(8) Uani 1 1 d . A .
C22 C 0.6062(3) 0.8529(3) 0.1884(3) 0.0461(9) Uani 1 1 d . . .
H22A H 0.6810 0.8551 0.2197 0.055 Uiso 1 1 calc R A .
C23 C 0.5859(3) 0.8812(3) 0.0919(3) 0.0489(9) Uani 1 1 d . A .
H23A H 0.6472 0.9036 0.0571 0.059 Uiso 1 1 calc R . .
C24 C 0.4779(3) 0.8771(3) 0.0457(3) 0.0463(9) Uani 1 1 d . . .
H24A H 0.4646 0.8961 -0.0209 0.056 Uiso 1 1 calc R A .
C25 C 0.3883(3) 0.8451(2) 0.0971(2) 0.0379(8) Uani 1 1 d . A .
C27 C 0.6055(3) 0.8361(3) 0.4110(3) 0.0462(9) Uani 1 1 d . . .
C27C C 0.5996(3) 0.9536(3) 0.4046(3) 0.0569(11) Uani 1 1 d . . .
H27A H 0.517(2) 0.9756(6) 0.400(2) 0.085 Uiso 1 1 calc R . .
H27B H 0.635(2) 0.9779(7) 0.3438(18) 0.085 Uiso 1 1 calc R . .
H27C H 0.643(2) 0.9870(9) 0.4655(17) 0.085 Uiso 1 1 calc R . .
C27B C 0.5567(3) 0.7967(3) 0.5014(3) 0.0584(11) Uani 1 1 d . . .
H27D H 0.478(2) 0.8196(19) 0.5015(10) 0.088 Uiso 1 1 calc R . .
H27E H 0.6017(17) 0.8247(18) 0.5596(14) 0.088 Uiso 1 1 calc R . .
H27F H 0.558(2) 0.7200(18) 0.5018(10) 0.088 Uiso 1 1 calc R . .
C27A C 0.7280(3) 0.7991(3) 0.4088(3) 0.0614(12) Uani 1 1 d . . .
H27G H 0.7640(12) 0.8358(18) 0.3555(18) 0.092 Uiso 1 1 calc R . .
H27H H 0.7277(3) 0.7218(19) 0.396(2) 0.092 Uiso 1 1 calc R . .
H27I H 0.7718(13) 0.816(2) 0.4730(17) 0.092 Uiso 1 1 calc R . .
C28C C 0.2521(4) 0.6640(3) 0.0233(4) 0.0704(14) Uani 1 1 d . . .
H28A H 0.336(2) 0.6529(11) 0.045(2) 0.106 Uiso 1 1 calc R . .
H28B H 0.224(3) 0.6086(15) -0.0276(15) 0.106 Uiso 1 1 calc R . .
H28C H 0.207(2) 0.6580(9) 0.082(2) 0.106 Uiso 1 1 calc R . .
C28B C 0.1130(3) 0.7987(4) -0.0389(3) 0.0633(12) Uani 1 1 d . . .
H28D H 0.1053(4) 0.8768(19) -0.064(2) 0.095 Uiso 1 1 calc R . .
H28E H 0.0737(11) 0.791(2) 0.0269(16) 0.095 Uiso 1 1 calc R . .
H28F H 0.0729(12) 0.7465(19) -0.0926(19) 0.095 Uiso 1 1 calc R . .
C28 C 0.2371(3) 0.7724(3) -0.0205(3) 0.0513(10) Uani 1 1 d . . .
C28A C 0.2951(4) 0.7844(4) -0.1127(3) 0.0759(14) Uani 1 1 d . . .
H28G H 0.289(2) 0.861(2) -0.1358(15) 0.114 Uiso 1 1 calc R . .
H28H H 0.256(2) 0.735(2) -0.1667(16) 0.114 Uiso 1 1 calc R . .
H28I H 0.380(2) 0.765(2) -0.0992(7) 0.114 Uiso 1 1 calc R . .
H100 H 0.300(3) 0.936(3) 0.370(2) 0.031(9) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O100 Ge1 C1 103.67(13) . . ?
O100 Ge1 C10 102.61(12) . . ?
C1 Ge1 C10 113.81(13) . . ?
O100 Ge1 C20 104.50(12) . . ?
C1 Ge1 C20 115.76(14) . . ?
C10 Ge1 C20 114.37(13) . . ?
O101 Ge1A C1 106.2(16) . . ?
O101 Ge1A C20 114.0(17) . . ?
C1 Ge1A C20 115.6(4) . . ?
O101 Ge1A C10 113.5(15) . . ?
C1 Ge1A C10 103.8(4) . . ?
C20 Ge1A C10 103.4(3) . . ?
C5 O1 C7 125.0(3) . . ?
C2 O2 C8 123.9(3) . . ?
C15 O10 C17 125.2(3) . . ?
C11 O11 C18 122.9(2) . . ?
C21 O20 C27 122.4(2) . . ?
C25 O21 C28 118.7(3) . . ?
C5 C1 C2 118.5(3) . . ?
C5 C1 Ge1A 100.0(4) . . ?
C2 C1 Ge1A 133.0(3) . . ?
C5 C1 Ge1 125.8(3) . . ?
C2 C1 Ge1 115.7(2) . . ?
Ge1A C1 Ge1 36.2(2) . . ?
O2 C2 C3 122.8(4) . . ?
O2 C2 C1 115.9(3) . . ?
C3 C2 C1 121.2(3) . . ?
C4 C3 C2 118.9(4) . . ?
C3 C4 C6 121.6(3) . . ?
C4 C6 C5 119.9(4) . . ?
O1 C5 C1 115.6(3) . . ?
O1 C5 C6 124.3(3) . . ?
C1 C5 C6 120.1(4) . . ?
O1 C7 C7B 103.3(3) . . ?
O1 C7 C7C 110.1(3) . . ?
C7B C7 C7C 109.4(4) . . ?
O1 C7 C7A 110.8(3) . . ?
C7B C7 C7A 108.8(3) . . ?
C7C C7 C7A 113.9(3) . . ?
O2 C8 C8C 103.1(3) . . ?
O2 C8 C8A 111.0(3) . . ?
C8C C8 C8A 110.7(3) . . ?
O2 C8 C8B 110.5(3) . . ?
C8C C8 C8B 109.3(3) . . ?
C8A C8 C8B 112.0(4) . . ?
C11 C10 C15 117.6(3) . . ?
C11 C10 Ge1 118.1(2) . . ?
C15 C10 Ge1 123.6(2) . . ?
C11 C10 Ge1A 140.1(3) . . ?
C15 C10 Ge1A 99.5(3) . . ?
Ge1 C10 Ge1A 32.8(2) . . ?
C12 C11 O11 121.8(3) . . ?
C12 C11 C10 122.0(3) . . ?
O11 C11 C10 116.0(3) . . ?
C13 C12 C11 118.6(3) . . ?
C14 C13 C12 121.1(3) . . ?
C13 C14 C15 119.9(3) . . ?
O10 C15 C14 125.7(3) . . ?
O10 C15 C10 113.6(3) . . ?
C14 C15 C10 120.6(3) . . ?
O10 C17 C17A 110.6(3) . . ?
O10 C17 C17C 101.5(3) . . ?
C17A C17 C17C 110.4(4) . . ?
O10 C17 C17B 109.9(3) . . ?
C17A C17 C17B 113.8(4) . . ?
C17C C17 C17B 109.9(4) . . ?
O11 C18 C18A 109.9(3) . . ?
O11 C18 C18C 111.7(3) . . ?
C18A C18 C18C 111.5(3) . . ?
O11 C18 C18B 102.2(3) . . ?
C18A C18 C18B 111.0(3) . . ?
C18C C18 C18B 110.3(3) . . ?
C25 C20 C21 117.5(3) . . ?
C25 C20 Ge1 125.7(2) . . ?
C21 C20 Ge1 116.3(2) . . ?
C25 C20 Ge1A 104.7(3) . . ?
C21 C20 Ge1A 132.0(3) . . ?
Ge1 C20 Ge1A 35.6(2) . . ?
C22 C21 O20 122.9(3) . . ?
C22 C21 C20 121.6(3) . . ?
O20 C21 C20 115.2(3) . . ?
C21 C22 C23 119.5(3) . . ?
C24 C23 C22 120.6(4) . . ?
C23 C24 C25 119.6(3) . . ?
C24 C25 O21 119.7(3) . . ?
C24 C25 C20 121.1(3) . . ?
O21 C25 C20 118.7(3) . . ?
O20 C27 C27C 111.8(3) . . ?
O20 C27 C27B 101.8(3) . . ?
C27C C27 C27B 111.4(3) . . ?
O20 C27 C27A 110.2(3) . . ?
C27C C27 C27A 111.1(3) . . ?
C27B C27 C27A 110.2(3) . . ?
O21 C28 C28A 111.8(3) . . ?
O21 C28 C28B 101.8(3) . . ?
C28A C28 C28B 110.4(3) . . ?
O21 C28 C28C 108.7(3) . . ?
C28A C28 C28C 112.5(4) . . ?
C28B C28 C28C 111.2(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 O100 1.790(2) . ?
Ge1 C1 1.950(3) . ?
Ge1 C10 1.965(3) . ?
Ge1 C20 1.971(3) . ?
Ge1A O101 1.81(5) . ?
Ge1A C1 1.939(8) . ?
Ge1A C20 1.985(8) . ?
Ge1A C10 2.225(8) . ?
O1 C5 1.364(4) . ?
O1 C7 1.454(4) . ?
O2 C2 1.366(4) . ?
O2 C8 1.453(5) . ?
O10 C15 1.370(4) . ?
O10 C17 1.464(4) . ?
O11 C11 1.389(4) . ?
O11 C18 1.466(4) . ?
O20 C21 1.383(4) . ?
O20 C27 1.470(4) . ?
O21 C25 1.394(4) . ?
O21 C28 1.467(4) . ?
C1 C5 1.399(5) . ?
C1 C2 1.403(5) . ?
C2 C3 1.400(4) . ?
C3 C4 1.373(6) . ?
C4 C6 1.377(6) . ?
C6 C5 1.402(4) . ?
C7C C7 1.522(5) . ?
C7 C7B 1.508(5) . ?
C7 C7A 1.535(6) . ?
C8 C8C 1.515(5) . ?
C8 C8A 1.518(6) . ?
C8 C8B 1.529(5) . ?
C10 C11 1.390(4) . ?
C10 C15 1.410(4) . ?
C11 C12 1.389(5) . ?
C12 C13 1.382(5) . ?
C13 C14 1.377(5) . ?
C14 C15 1.385(5) . ?
C17 C17A 1.513(6) . ?
C17 C17C 1.527(5) . ?
C17 C17B 1.532(6) . ?
C18 C18A 1.521(5) . ?
C18 C18C 1.525(5) . ?
C18 C18B 1.527(5) . ?
C20 C25 1.395(5) . ?
C20 C21 1.398(4) . ?
C21 C22 1.376(5) . ?
C22 C23 1.380(5) . ?
C23 C24 1.376(5) . ?
C24 C25 1.390(5) . ?
C27 C27C 1.507(5) . ?
C27 C27B 1.510(5) . ?
C27 C27A 1.538(5) . ?
C28C C28 1.523(5) . ?
C28B C28 1.516(5) . ?
C28 C28A 1.508(6) . ?
