#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:15:54 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179683 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/05/7000504.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000504
loop_
_publ_author_name
'Bomparola, Roberta'
'Davies, Robert P.'
'Hornauer, Stefan'
'White, Andrew J. P.'
_publ_section_title
;
 The influence of tetrahydrofuran on the structures and reactivities of
 lithium organo-amidocuprates
;
_journal_issue                   7
_journal_name_full               'Dalton Transactions'
_journal_page_first              1104
_journal_page_last               1106
_journal_paper_doi               10.1039/b821206f
_journal_year                    2009
_chemical_formula_moiety         'C30 H47 Cu Li N O3'
_chemical_formula_sum            'C30 H47 Cu Li N O3'
_chemical_formula_weight         540.17
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 92.4171(17)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.63755(17)
_cell_length_b                   18.1879(3)
_cell_length_c                   19.0128(3)
_cell_measurement_reflns_used    20211
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.6216
_cell_measurement_theta_min      3.8336
_cell_volume                     2984.23(9)
_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd'
_computing_data_collection       'CrysAlis CCD, Oxford Diffraction Ltd'
_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 15.9863
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.920
_diffrn_measurement_device_type  'OD Xcalibur 3'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0231
_diffrn_reflns_av_sigmaI/netI    0.0177
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            28212
_diffrn_reflns_theta_full        31.00
_diffrn_reflns_theta_max         32.68
_diffrn_reflns_theta_min         3.84
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.760
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.90203
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May 8 2007,13:10:02)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.202
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blocks
_exptl_crystal_F_000             1160
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.552
_refine_diff_density_min         -0.536
_refine_diff_density_rms         0.109
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.144
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     328
_refine_ls_number_reflns         10080
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.144
_refine_ls_R_factor_all          0.0973
_refine_ls_R_factor_gt           0.0865
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0125P)²+17.1386P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2125
_refine_ls_wR_factor_ref         0.2157
_reflns_number_gt                8565
_reflns_number_total             10080
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b821206f.txt
_cod_data_source_block           Complex_1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7000504
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu Cu 0.46138(6) 0.75203(3) 0.10740(3) 0.02897(12) Uani 1 1 d . . .
Li Li 0.7224(8) 0.7583(4) 0.2295(4) 0.0333(14) Uani 1 1 d . . .
N1 N 0.6258(4) 0.6952(2) 0.15047(18) 0.0301(7) Uani 1 1 d . . .
C2 C 0.7517(5) 0.6814(3) 0.1020(2) 0.0387(10) Uani 1 1 d . . .
H2A H 0.8301 0.6493 0.1260 0.046 Uiso 1 1 calc R . .
H2B H 0.8026 0.7287 0.0918 0.046 Uiso 1 1 calc R . .
C3 C 0.6996(5) 0.6455(3) 0.0324(2) 0.0345(8) Uani 1 1 d . . .
C4 C 0.6249(5) 0.6861(3) -0.0209(2) 0.0372(9) Uani 1 1 d . . .
H4A H 0.6141 0.7377 -0.0150 0.045 Uiso 1 1 calc R . .
C5 C 0.5658(6) 0.6543(3) -0.0822(2) 0.0440(11) Uani 1 1 d . . .
H5A H 0.5159 0.6839 -0.1175 0.053 Uiso 1 1 calc R . .
C6 C 0.5791(7) 0.5801(3) -0.0922(3) 0.0544(14) Uani 1 1 d . . .
H6A H 0.5355 0.5577 -0.1336 0.065 Uiso 1 1 calc R . .
C7 C 0.6560(9) 0.5385(3) -0.0418(3) 0.0652(17) Uani 1 1 d . . .
H7A H 0.6692 0.4872 -0.0491 0.078 Uiso 1 1 calc R . .
C8 C 0.7147(7) 0.5708(3) 0.0199(3) 0.0538(14) Uani 1 1 d . . .
H8A H 0.7666 0.5409 0.0545 0.065 Uiso 1 1 calc R . .
C9 C 0.5685(6) 0.6253(2) 0.1769(2) 0.0374(9) Uani 1 1 d . . .
H9A H 0.6562 0.5973 0.1988 0.045 Uiso 1 1 calc R . .
H9B H 0.5245 0.5960 0.1370 0.045 Uiso 1 1 calc R . .
C10 C 0.4459(6) 0.6360(3) 0.2305(3) 0.0432(10) Uani 1 1 d . . .
H10A H 0.4109 0.5879 0.2469 0.065 Uiso 1 1 calc R . .
H10B H 0.3578 0.6628 0.2088 0.065 Uiso 1 1 calc R . .
H10C H 0.4895 0.6642 0.2706 0.065 Uiso 1 1 calc R . .
C11 C 0.2871(4) 0.7960(2) 0.0589(2) 0.0275(7) Uani 1 1 d . . .
C12 C 0.2646(5) 0.8712(2) 0.0423(2) 0.0294(7) Uani 1 1 d . . .
C13 C 0.1341(5) 0.8966(2) 0.0038(2) 0.0316(8) Uani 1 1 d . . .
H13A H 0.1237 0.9477 -0.0056 0.038 Uiso 1 1 calc R . .
C14 C 0.0198(5) 0.8489(2) -0.0210(2) 0.0318(8) Uani 1 1 d . . .
C15 C 0.0387(5) 0.7743(2) -0.0064(2) 0.0314(8) Uani 1 1 d . . .
H15A H -0.0381 0.7405 -0.0231 0.038 Uiso 1 1 calc R . .
C16 C 0.1677(5) 0.7484(2) 0.0324(2) 0.0306(7) Uani 1 1 d . . .
C17 C 0.3877(5) 0.9267(2) 0.0668(3) 0.0391(10) Uani 1 1 d . . .
H17A H 0.3597 0.9755 0.0486 0.059 Uiso 1 1 calc R . .
H17B H 0.4882 0.9121 0.0491 0.059 Uiso 1 1 calc R . .
H17C H 0.3945 0.9281 0.1183 0.059 Uiso 1 1 calc R . .
C18 C -0.1217(5) 0.8762(3) -0.0623(3) 0.0435(11) Uani 1 1 d . . .
H18A H -0.1607 0.8373 -0.0941 0.065 Uiso 1 1 calc R . .
H18B H -0.0942 0.9194 -0.0900 0.065 Uiso 1 1 calc R . .
H18C H -0.2021 0.8896 -0.0298 0.065 Uiso 1 1 calc R . .
C19 C 0.1804(6) 0.6661(3) 0.0461(3) 0.0419(10) Uani 1 1 d . . .
H19A H 0.0902 0.6411 0.0242 0.063 Uiso 1 1 calc R . .
H19B H 0.1843 0.6570 0.0969 0.063 Uiso 1 1 calc R . .
H19C H 0.2751 0.6472 0.0259 0.063 Uiso 1 1 calc R . .
O20 O 0.8715(3) 0.70776(18) 0.29609(16) 0.0366(7) Uani 1 1 d . . .
C21 C 0.8202(5) 0.6688(3) 0.3576(2) 0.0395(10) Uani 1 1 d . . .
H21A H 0.7190 0.6448 0.3470 0.047 Uiso 1 1 calc R . .
H21B H 0.8087 0.7033 0.3973 0.047 Uiso 1 1 calc R . .
C22 C 0.9415(6) 0.6120(3) 0.3764(3) 0.0450(11) Uani 1 1 d . . .
H22A H 0.8943 0.5661 0.3933 0.054 Uiso 1 1 calc R . .
H22B H 1.0172 0.6306 0.4127 0.054 Uiso 1 1 calc R . .
C23 C 1.0172(6) 0.6002(3) 0.3059(3) 0.0517(13) Uani 1 1 d . . .
H23A H 1.1245 0.5816 0.3129 0.062 Uiso 1 1 calc R . .
H23B H 0.9566 0.5653 0.2757 0.062 Uiso 1 1 calc R . .
C24 C 1.0152(6) 0.6758(3) 0.2749(3) 0.0438(11) Uani 1 1 d . . .
H24A H 1.1049 0.7049 0.2934 0.053 Uiso 1 1 calc R . .
H24B H 1.0183 0.6736 0.2229 0.053 Uiso 1 1 calc R . .
O25 O 0.8550(4) 0.8371(2) 0.19536(18) 0.0426(8) Uani 1 1 d . . .
C26 C 1.0173(5) 0.8520(3) 0.2004(3) 0.0375(9) Uani 1 1 d . . .
H26A H 1.0715 0.8256 0.1631 0.045 Uiso 1 1 calc R . .
H26B H 1.0623 0.8366 0.2468 0.045 Uiso 1 1 calc R . .
C27 C 1.0315(6) 0.9347(3) 0.1910(3) 0.0474(12) Uani 1 1 d . . .
H27A H 1.0555 0.9591 0.2367 0.057 Uiso 1 1 calc R . .
H27B H 1.1140 0.9467 0.1583 0.057 Uiso 1 1 calc R . .
C28 C 0.8778(8) 0.9581(4) 0.1614(5) 0.079(2) Uani 1 1 d . . .
H28A H 0.8270 0.9915 0.1945 0.094 Uiso 1 1 calc R . .
H28B H 0.8889 0.9843 0.1163 0.094 Uiso 1 1 calc R . .
C29 C 0.7866(7) 0.8918(4) 0.1505(4) 0.072(2) Uani 1 1 d . . .
H29A H 0.6778 0.9006 0.1626 0.087 Uiso 1 1 calc R . .
H29B H 0.7882 0.8761 0.1007 0.087 Uiso 1 1 calc R . .
O30 O 0.5857(4) 0.8117(2) 0.29252(17) 0.0401(7) Uani 1 1 d . . .
C31 C 0.6538(6) 0.8603(3) 0.3444(3) 0.0502(12) Uani 1 1 d . . .
H31A H 0.7532 0.8801 0.3284 0.060 Uiso 1 1 calc R . .
H31B H 0.6737 0.8340 0.3894 0.060 Uiso 1 1 calc R . .
C32 C 0.5388(9) 0.9220(4) 0.3536(4) 0.079(2) Uani 1 1 d . . .
H32A H 0.4912 0.9186 0.4000 0.094 Uiso 1 1 calc R . .
H32B H 0.5898 0.9705 0.3499 0.094 Uiso 1 1 calc R . .
C33 C 0.4188(7) 0.9113(3) 0.2947(3) 0.0541(14) Uani 1 1 d . . .
H33A H 0.3148 0.9268 0.3089 0.065 Uiso 1 1 calc R . .
H33B H 0.4459 0.9391 0.2521 0.065 Uiso 1 1 calc R . .
C34 C 0.4250(5) 0.8299(3) 0.2822(3) 0.0440(11) Uani 1 1 d . . .
H34A H 0.3616 0.8032 0.3161 0.053 Uiso 1 1 calc R . .
H34B H 0.3870 0.8177 0.2338 0.053 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Cu N1 171.98(16) . . ?
O25 Li O30 102.4(4) . . ?
O25 Li O20 100.2(3) . . ?
O30 Li O20 103.2(4) . . ?
O25 Li N1 113.1(4) . . ?
O30 Li N1 119.2(4) . . ?
O20 Li N1 116.2(4) . . ?
C9 N1 C2 109.6(4) . . ?
C9 N1 Cu 111.2(3) . . ?
C2 N1 Cu 112.2(3) . . ?
C9 N1 Li 111.7(3) . . ?
C2 N1 Li 105.5(3) . . ?
Cu N1 Li 106.5(3) . . ?
N1 C2 C3 114.6(3) . . ?
C8 C3 C4 116.1(4) . . ?
C8 C3 C2 122.8(4) . . ?
C4 C3 C2 121.1(4) . . ?
C5 C4 C3 122.4(5) . . ?
C6 C5 C4 120.1(5) . . ?
C5 C6 C7 119.3(5) . . ?
C6 C7 C8 120.3(5) . . ?
C3 C8 C7 121.7(5) . . ?
N1 C9 C10 112.1(4) . . ?
C12 C11 C16 114.7(3) . . ?
C12 C11 Cu 127.7(3) . . ?
C16 C11 Cu 117.5(3) . . ?
C13 C12 C11 122.4(4) . . ?
C13 C12 C17 118.6(4) . . ?
C11 C12 C17 119.0(4) . . ?
C14 C13 C12 121.4(4) . . ?
C13 C14 C15 117.9(4) . . ?
C13 C14 C18 121.5(4) . . ?
C15 C14 C18 120.6(4) . . ?
C16 C15 C14 121.3(4) . . ?
C15 C16 C11 122.3(4) . . ?
C15 C16 C19 118.3(4) . . ?
C11 C16 C19 119.4(4) . . ?
C24 O20 C21 108.9(3) . . ?
C24 O20 Li 123.3(3) . . ?
C21 O20 Li 121.7(3) . . ?
O20 C21 C22 107.0(4) . . ?
C21 C22 C23 102.0(4) . . ?
C24 C23 C22 102.5(4) . . ?
O20 C24 C23 104.8(4) . . ?
C29 O25 C26 106.8(4) . . ?
C29 O25 Li 118.5(4) . . ?
C26 O25 Li 134.6(3) . . ?
O25 C26 C27 105.3(4) . . ?
C28 C27 C26 104.6(4) . . ?
C29 C28 C27 106.7(5) . . ?
O25 C29 C28 106.7(5) . . ?
C31 O30 C34 108.6(4) . . ?
C31 O30 Li 118.9(4) . . ?
C34 O30 Li 129.2(3) . . ?
O30 C31 C32 106.6(4) . . ?
C33 C32 C31 104.6(5) . . ?
C34 C33 C32 102.5(5) . . ?
O30 C34 C33 104.3(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu C11 1.907(4) . ?
Cu N1 1.912(3) . ?
Li O25 1.962(8) . ?
Li O30 1.972(8) . ?
Li O20 1.992(8) . ?
Li N1 2.041(8) . ?
N1 C9 1.462(5) . ?
N1 C2 1.477(5) . ?
C2 C3 1.525(6) . ?
C3 C8 1.387(7) . ?
C3 C4 1.392(6) . ?
C4 C5 1.380(7) . ?
C5 C6 1.367(8) . ?
C6 C7 1.371(9) . ?
C7 C8 1.390(8) . ?
C9 C10 1.513(7) . ?
C11 C12 1.415(6) . ?
C11 C16 1.422(5) . ?
C12 C13 1.397(6) . ?
C12 C17 1.524(6) . ?
C13 C14 1.382(6) . ?
C14 C15 1.393(6) . ?
C14 C18 1.509(6) . ?
C15 C16 1.392(6) . ?
C16 C19 1.523(6) . ?
O20 C24 1.444(5) . ?
O20 C21 1.453(5) . ?
C21 C22 1.503(6) . ?
C22 C23 1.531(8) . ?
C23 C24 1.496(7) . ?
O25 C29 1.423(6) . ?
O25 C26 1.427(5) . ?
C26 C27 1.521(7) . ?
C27 C28 1.483(8) . ?
C28 C29 1.450(9) . ?
O30 C31 1.432(6) . ?
O30 C34 1.433(5) . ?
C31 C32 1.514(8) . ?
C32 C33 1.507(8) . ?
C33 C34 1.500(8) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O25 Li N1 C9 162.5(4) . . . . ?
O30 Li N1 C9 -77.1(5) . . . . ?
O20 Li N1 C9 47.4(5) . . . . ?
O25 Li N1 C2 43.5(5) . . . . ?
O30 Li N1 C2 163.9(4) . . . . ?
O20 Li N1 C2 -71.6(5) . . . . ?
O25 Li N1 Cu -75.9(4) . . . . ?
O30 Li N1 Cu 44.4(5) . . . . ?
O20 Li N1 Cu 169.0(3) . . . . ?
C9 N1 C2 C3 69.1(5) . . . . ?
Cu N1 C2 C3 -54.9(5) . . . . ?
Li N1 C2 C3 -170.5(4) . . . . ?
N1 C2 C3 C8 -99.5(6) . . . . ?
N1 C2 C3 C4 76.6(6) . . . . ?
C8 C3 C4 C5 1.4(7) . . . . ?
C2 C3 C4 C5 -174.9(4) . . . . ?
C3 C4 C5 C6 0.2(8) . . . . ?
C4 C5 C6 C7 -2.2(9) . . . . ?
C5 C6 C7 C8 2.4(10) . . . . ?
C4 C3 C8 C7 -1.1(9) . . . . ?
C2 C3 C8 C7 175.1(6) . . . . ?
C6 C7 C8 C3 -0.8(11) . . . . ?
C2 N1 C9 C10 176.4(4) . . . . ?
Cu N1 C9 C10 -58.9(4) . . . . ?
Li N1 C9 C10 59.9(5) . . . . ?
C16 C11 C12 C13 0.9(6) . . . . ?
Cu C11 C12 C13 177.3(3) . . . . ?
C16 C11 C12 C17 -178.6(4) . . . . ?
Cu C11 C12 C17 -2.2(6) . . . . ?
C11 C12 C13 C14 -0.7(6) . . . . ?
C17 C12 C13 C14 178.8(4) . . . . ?
C12 C13 C14 C15 0.0(6) . . . . ?
C12 C13 C14 C18 179.7(4) . . . . ?
C13 C14 C15 C16 0.4(6) . . . . ?
C18 C14 C15 C16 -179.3(4) . . . . ?
C14 C15 C16 C11 -0.2(6) . . . . ?
C14 C15 C16 C19 -179.8(4) . . . . ?
C12 C11 C16 C15 -0.4(6) . . . . ?
Cu C11 C16 C15 -177.2(3) . . . . ?
C12 C11 C16 C19 179.1(4) . . . . ?
Cu C11 C16 C19 2.4(5) . . . . ?
O25 Li O20 C24 -59.6(5) . . . . ?
O30 Li O20 C24 -165.0(4) . . . . ?
N1 Li O20 C24 62.6(6) . . . . ?
O25 Li O20 C21 151.0(4) . . . . ?
O30 Li O20 C21 45.6(5) . . . . ?
N1 Li O20 C21 -86.8(5) . . . . ?
C24 O20 C21 C22 2.0(5) . . . . ?
Li O20 C21 C22 155.3(4) . . . . ?
O20 C21 C22 C23 -24.2(5) . . . . ?
C21 C22 C23 C24 36.6(5) . . . . ?
C21 O20 C24 C23 21.8(5) . . . . ?
Li O20 C24 C23 -131.0(4) . . . . ?
C22 C23 C24 O20 -36.3(5) . . . . ?
O30 Li O25 C29 -67.6(6) . . . . ?
O20 Li O25 C29 -173.7(5) . . . . ?
N1 Li O25 C29 61.9(6) . . . . ?
O30 Li O25 C26 118.1(5) . . . . ?
O20 Li O25 C26 11.9(7) . . . . ?
N1 Li O25 C26 -112.4(5) . . . . ?
C29 O25 C26 C27 29.3(6) . . . . ?
Li O25 C26 C27 -155.9(5) . . . . ?
O25 C26 C27 C28 -15.5(6) . . . . ?
C26 C27 C28 C29 -3.5(8) . . . . ?
C26 O25 C29 C28 -32.2(8) . . . . ?
Li O25 C29 C28 152.0(6) . . . . ?
C27 C28 C29 O25 21.5(9) . . . . ?
O25 Li O30 C31 -49.5(5) . . . . ?
O20 Li O30 C31 54.2(5) . . . . ?
N1 Li O30 C31 -175.2(4) . . . . ?
O25 Li O30 C34 107.4(5) . . . . ?
O20 Li O30 C34 -148.9(4) . . . . ?
N1 Li O30 C34 -18.3(7) . . . . ?
C34 O30 C31 C32 -13.5(7) . . . . ?
Li O30 C31 C32 147.8(5) . . . . ?
O30 C31 C32 C33 -10.0(8) . . . . ?
C31 C32 C33 C34 28.2(8) . . . . ?
C31 O30 C34 C33 31.8(6) . . . . ?
Li O30 C34 C33 -127.0(5) . . . . ?
C32 C33 C34 O30 -36.8(6) . . . . ?
