#------------------------------------------------------------------------------
#$Date: 2018-08-11 08:38:50 +0300 (Sat, 11 Aug 2018) $
#$Revision: 209563 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/00/05/7000566.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000566
loop_
_publ_author_name
'Welch, Gregory C.'
'Prieto, Roberto'
'Dureen, Meghan A.'
'Lough, Alan J.'
'Labeodan, Oijsamola A.'
'Höltrichter-Rössmann, Thorsten'
'Stephan, Douglas W.'
_publ_section_title
;
 Reactions of phosphines with electron deficient boranes
;
_journal_coden_ASTM              DTARAF
_journal_issue                   9
_journal_name_full               'Dalton Transactions'
_journal_page_first              1559
_journal_page_last               1570
_journal_paper_doi               10.1039/b814486a
_journal_year                    2009
_chemical_formula_sum            'C30 H11 B F15 P'
_chemical_formula_weight         698.17
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.364(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.064(2)
_cell_length_b                   8.3163(11)
_cell_length_c                   21.102(3)
_cell_measurement_reflns_used    6400
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      24.63
_cell_measurement_theta_min      2.59
_cell_volume                     2753.7(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0311
_diffrn_reflns_av_sigmaI/netI    0.0230
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            25561
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.98
_exptl_absorpt_coefficient_mu    0.224
_exptl_absorpt_correction_T_max  0.978
_exptl_absorpt_correction_T_min  0.948
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.684
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1384
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.292
_refine_diff_density_min         -0.157
_refine_diff_density_rms         0.038
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     428
_refine_ls_number_reflns         4837
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0552
_refine_ls_R_factor_gt           0.0378
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0475P)²+0.5727P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0892
_refine_ls_wR_factor_ref         0.0997
_reflns_number_gt                3586
_reflns_number_total             4837
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            B814486a.txt
_cod_data_source_block           Ph2PH(B(C6F5)3)
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        2753.8(6)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7000566
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.22343(3) 0.63473(7) 0.41143(3) 0.04842(16) Uani 1 1 d . . .
B1 B 0.21582(15) 0.3855(3) 0.42449(11) 0.0463(5) Uani 1 1 d . . .
F1 F 0.19309(8) 0.05594(16) 0.38427(8) 0.0761(4) Uani 1 1 d . . .
F2 F 0.05461(10) -0.08456(19) 0.31762(8) 0.0882(5) Uani 1 1 d . . .
F3 F -0.09051(9) 0.0878(2) 0.27456(8) 0.0911(5) Uani 1 1 d . . .
F4 F -0.09428(8) 0.4021(2) 0.30723(9) 0.0920(5) Uani 1 1 d . . .
F5 F 0.04230(8) 0.54433(18) 0.37634(9) 0.0903(5) Uani 1 1 d . . .
F6 F 0.23749(8) 0.43608(17) 0.29562(6) 0.0626(3) Uani 1 1 d . . .
F7 F 0.37200(9) 0.3635(2) 0.24584(7) 0.0807(4) Uani 1 1 d . . .
F8 F 0.50615(9) 0.2001(2) 0.31870(8) 0.0934(5) Uani 1 1 d . . .
F9 F 0.50044(8) 0.10908(19) 0.44086(7) 0.0824(5) Uani 1 1 d . . .
F10 F 0.36685(8) 0.17586(16) 0.49055(6) 0.0628(4) Uani 1 1 d . . .
F11 F 0.35495(8) 0.48510(15) 0.52806(6) 0.0595(3) Uani 1 1 d . . .
F12 F 0.36311(10) 0.4767(2) 0.65455(6) 0.0853(5) Uani 1 1 d . . .
F13 F 0.22990(10) 0.3580(2) 0.70175(6) 0.0933(5) Uani 1 1 d . . .
F14 F 0.09195(10) 0.2388(2) 0.61750(8) 0.0882(5) Uani 1 1 d . . .
F15 F 0.08164(9) 0.2467(2) 0.49235(7) 0.0828(5) Uani 1 1 d . . .
C1 C 0.12792(13) 0.3120(3) 0.37984(10) 0.0481(5) Uani 1 1 d . . .
C2 C 0.12449(13) 0.1503(3) 0.36344(10) 0.0518(5) Uani 1 1 d . . .
C3 C 0.05317(15) 0.0742(3) 0.32941(11) 0.0589(6) Uani 1 1 d . . .
C4 C -0.02011(14) 0.1591(3) 0.30860(11) 0.0631(6) Uani 1 1 d . . .
C5 C -0.02173(14) 0.3177(3) 0.32417(12) 0.0624(6) Uani 1 1 d . . .
C6 C 0.05111(14) 0.3891(3) 0.35944(11) 0.0572(6) Uani 1 1 d . . .
C7 C 0.29735(12) 0.3203(2) 0.39707(10) 0.0460(5) Uani 1 1 d . . .
C8 C 0.30253(13) 0.3555(3) 0.33371(10) 0.0510(5) Uani 1 1 d . . .
C9 C 0.37057(15) 0.3189(3) 0.30687(11) 0.0586(6) Uani 1 1 d . . .
C10 C 0.43831(15) 0.2376(3) 0.34319(13) 0.0639(6) Uani 1 1 d . . .
C11 C 0.43542(14) 0.1916(3) 0.40525(12) 0.0591(6) Uani 1 1 d . . .
C12 C 0.36582(13) 0.2318(3) 0.43039(10) 0.0504(5) Uani 1 1 d . . .
C13 C 0.21882(13) 0.3657(3) 0.50211(10) 0.0488(5) Uani 1 1 d . . .
C14 C 0.28736(13) 0.4215(3) 0.54820(10) 0.0510(5) Uani 1 1 d . . .
C15 C 0.29313(16) 0.4191(3) 0.61405(11) 0.0610(6) Uani 1 1 d . . .
C16 C 0.22697(17) 0.3593(3) 0.63792(11) 0.0667(7) Uani 1 1 d . . .
C17 C 0.15695(16) 0.3016(3) 0.59518(12) 0.0632(6) Uani 1 1 d . . .
C18 C 0.15407(14) 0.3061(3) 0.52947(11) 0.0573(6) Uani 1 1 d . . .
C19 C 0.21465(14) 0.7503(3) 0.48242(11) 0.0516(5) Uani 1 1 d . . .
C20 C 0.28457(16) 0.8248(3) 0.52089(13) 0.0672(7) Uani 1 1 d . . .
H20A H 0.3367 0.8243 0.5083 0.081 Uiso 1 1 calc R . .
C21 C 0.27741(19) 0.8996(3) 0.57756(14) 0.0799(8) Uani 1 1 d . . .
H21A H 0.3250 0.9475 0.6036 0.096 Uiso 1 1 calc R . .
C22 C 0.2010(2) 0.9042(4) 0.59597(14) 0.0833(8) Uani 1 1 d . . .
H22A H 0.1967 0.9532 0.6348 0.100 Uiso 1 1 calc R . .
C23 C 0.1309(2) 0.8364(4) 0.55693(16) 0.0921(10) Uani 1 1 d . . .
H23A H 0.0783 0.8427 0.5686 0.110 Uiso 1 1 calc R . .
C24 C 0.13739(17) 0.7587(3) 0.50044(13) 0.0741(7) Uani 1 1 d . . .
H24A H 0.0894 0.7118 0.4745 0.089 Uiso 1 1 calc R . .
C25 C 0.31432(14) 0.7054(3) 0.38135(10) 0.0506(5) Uani 1 1 d . . .
C26 C 0.29828(17) 0.7872(3) 0.32298(12) 0.0687(7) Uani 1 1 d . . .
H26A H 0.2425 0.8094 0.3019 0.082 Uiso 1 1 calc R . .
C27 C 0.3650(2) 0.8357(4) 0.29598(14) 0.0887(9) Uani 1 1 d . . .
H27A H 0.3540 0.8904 0.2566 0.106 Uiso 1 1 calc R . .
C28 C 0.44749(19) 0.8037(4) 0.32691(15) 0.0836(8) Uani 1 1 d . . .
H28A H 0.4922 0.8359 0.3083 0.100 Uiso 1 1 calc R . .
C29 C 0.46403(16) 0.7250(3) 0.38470(13) 0.0721(7) Uani 1 1 d . . .
H29A H 0.5201 0.7050 0.4058 0.087 Uiso 1 1 calc R . .
C30 C 0.39775(14) 0.6748(3) 0.41199(12) 0.0610(6) Uani 1 1 d . . .
H30A H 0.4093 0.6200 0.4513 0.073 Uiso 1 1 calc R . .
H1 H 0.1603(13) 0.684(2) 0.3674(10) 0.056(6) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C25 P1 C19 109.23(10) . . ?
C25 P1 B1 116.16(10) . . ?
C19 P1 B1 113.51(10) . . ?
C25 P1 H1 102.4(9) . . ?
C19 P1 H1 103.9(9) . . ?
B1 P1 H1 110.4(9) . . ?
C7 B1 C13 117.83(17) . . ?
C7 B1 C1 109.26(17) . . ?
C13 B1 C1 112.02(17) . . ?
C7 B1 P1 101.99(14) . . ?
C13 B1 P1 103.94(14) . . ?
C1 B1 P1 111.13(14) . . ?
C6 C1 C2 112.90(19) . . ?
C6 C1 B1 127.6(2) . . ?
C2 C1 B1 119.26(18) . . ?
F1 C2 C3 115.8(2) . . ?
F1 C2 C1 119.83(19) . . ?
C3 C2 C1 124.3(2) . . ?
F2 C3 C4 119.8(2) . . ?
F2 C3 C2 120.3(2) . . ?
C4 C3 C2 119.9(2) . . ?
F3 C4 C5 120.0(2) . . ?
F3 C4 C3 121.0(2) . . ?
C5 C4 C3 119.0(2) . . ?
F4 C5 C4 120.2(2) . . ?
F4 C5 C6 120.5(2) . . ?
C4 C5 C6 119.3(2) . . ?
F5 C6 C1 120.0(2) . . ?
F5 C6 C5 115.3(2) . . ?
C1 C6 C5 124.7(2) . . ?
C12 C7 C8 113.35(18) . . ?
C12 C7 B1 127.37(19) . . ?
C8 C7 B1 119.27(18) . . ?
F6 C8 C9 116.63(19) . . ?
F6 C8 C7 118.62(18) . . ?
C9 C8 C7 124.7(2) . . ?
F7 C9 C10 119.9(2) . . ?
F7 C9 C8 120.9(2) . . ?
C10 C9 C8 119.2(2) . . ?
F8 C10 C9 121.0(2) . . ?
F8 C10 C11 119.9(2) . . ?
C9 C10 C11 119.1(2) . . ?
F9 C11 C10 119.8(2) . . ?
F9 C11 C12 120.6(2) . . ?
C10 C11 C12 119.7(2) . . ?
F10 C12 C11 115.57(19) . . ?
F10 C12 C7 120.65(18) . . ?
C11 C12 C7 123.8(2) . . ?
C14 C13 C18 112.5(2) . . ?
C14 C13 B1 121.21(19) . . ?
C18 C13 B1 126.12(19) . . ?
F11 C14 C15 116.0(2) . . ?
F11 C14 C13 118.74(18) . . ?
C15 C14 C13 125.3(2) . . ?
F12 C15 C16 120.4(2) . . ?
F12 C15 C14 120.2(2) . . ?
C16 C15 C14 119.4(2) . . ?
F13 C16 C15 120.8(2) . . ?
F13 C16 C17 120.5(2) . . ?
C15 C16 C17 118.7(2) . . ?
F14 C17 C16 119.8(2) . . ?
F14 C17 C18 120.2(2) . . ?
C16 C17 C18 120.0(2) . . ?
F15 C18 C17 114.4(2) . . ?
F15 C18 C13 121.3(2) . . ?
C17 C18 C13 124.3(2) . . ?
C24 C19 C20 118.9(2) . . ?
C24 C19 P1 119.35(18) . . ?
C20 C19 P1 121.73(17) . . ?
C21 C20 C19 120.3(2) . . ?
C21 C20 H20A 119.9 . . ?
C19 C20 H20A 119.9 . . ?
C22 C21 C20 120.5(3) . . ?
C22 C21 H21A 119.7 . . ?
C20 C21 H21A 119.7 . . ?
C21 C22 C23 119.5(3) . . ?
C21 C22 H22A 120.3 . . ?
C23 C22 H22A 120.3 . . ?
C22 C23 C24 120.6(3) . . ?
C22 C23 H23A 119.7 . . ?
C24 C23 H23A 119.7 . . ?
C19 C24 C23 120.1(3) . . ?
C19 C24 H24A 119.9 . . ?
C23 C24 H24A 119.9 . . ?
C30 C25 C26 119.0(2) . . ?
C30 C25 P1 123.41(17) . . ?
C26 C25 P1 117.51(17) . . ?
C27 C26 C25 120.0(3) . . ?
C27 C26 H26A 120.0 . . ?
C25 C26 H26A 120.0 . . ?
C28 C27 C26 120.3(3) . . ?
C28 C27 H27A 119.9 . . ?
C26 C27 H27A 119.9 . . ?
C29 C28 C27 120.2(2) . . ?
C29 C28 H28A 119.9 . . ?
C27 C28 H28A 119.9 . . ?
C28 C29 C30 120.0(3) . . ?
C28 C29 H29A 120.0 . . ?
C30 C29 H29A 120.0 . . ?
C29 C30 C25 120.5(2) . . ?
C29 C30 H30A 119.8 . . ?
C25 C30 H30A 119.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 C25 1.810(2) . ?
P1 C19 1.811(2) . ?
P1 B1 2.098(3) . ?
P1 H1 1.29(2) . ?
B1 C7 1.634(3) . ?
B1 C13 1.637(3) . ?
B1 C1 1.639(3) . ?
F1 C2 1.348(2) . ?
F2 C3 1.345(3) . ?
F3 C4 1.341(3) . ?
F4 C5 1.341(3) . ?
F5 C6 1.355(3) . ?
F6 C8 1.352(2) . ?
F7 C9 1.345(3) . ?
F8 C10 1.339(3) . ?
F9 C11 1.338(3) . ?
F10 C12 1.349(2) . ?
F11 C14 1.355(2) . ?
F12 C15 1.346(3) . ?
F13 C16 1.338(3) . ?
F14 C17 1.340(3) . ?
F15 C18 1.350(3) . ?
C1 C6 1.375(3) . ?
C1 C2 1.386(3) . ?
C2 C3 1.370(3) . ?
C3 C4 1.362(3) . ?
C4 C5 1.361(4) . ?
C5 C6 1.379(3) . ?
C7 C12 1.384(3) . ?
C7 C8 1.389(3) . ?
C8 C9 1.369(3) . ?
C9 C10 1.368(3) . ?
C10 C11 1.375(3) . ?
C11 C12 1.377(3) . ?
C13 C14 1.384(3) . ?
C13 C18 1.385(3) . ?
C14 C15 1.373(3) . ?
C15 C16 1.364(4) . ?
C16 C17 1.369(4) . ?
C17 C18 1.378(3) . ?
C19 C24 1.375(3) . ?
C19 C20 1.383(3) . ?
C20 C21 1.375(4) . ?
C20 H20A 0.9300 . ?
C21 C22 1.365(4) . ?
C21 H21A 0.9300 . ?
C22 C23 1.367(4) . ?
C22 H22A 0.9300 . ?
C23 C24 1.380(4) . ?
C23 H23A 0.9300 . ?
C24 H24A 0.9300 . ?
C25 C30 1.381(3) . ?
C25 C26 1.382(3) . ?
C26 C27 1.377(4) . ?
C26 H26A 0.9300 . ?
C27 C28 1.373(4) . ?
C27 H27A 0.9300 . ?
C28 C29 1.359(4) . ?
C28 H28A 0.9300 . ?
C29 C30 1.379(3) . ?
C29 H29A 0.9300 . ?
C30 H30A 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C25 P1 B1 C7 -3.84(17) . . . . ?
C19 P1 B1 C7 -131.71(13) . . . . ?
C25 P1 B1 C13 119.15(14) . . . . ?
C19 P1 B1 C13 -8.72(17) . . . . ?
C25 P1 B1 C1 -120.18(15) . . . . ?
C19 P1 B1 C1 111.96(15) . . . . ?
C7 B1 C1 C6 -140.4(2) . . . . ?
C13 B1 C1 C6 87.2(3) . . . . ?
P1 B1 C1 C6 -28.6(3) . . . . ?
C7 B1 C1 C2 45.3(3) . . . . ?
C13 B1 C1 C2 -87.2(2) . . . . ?
P1 B1 C1 C2 157.05(16) . . . . ?
C6 C1 C2 F1 -175.12(19) . . . . ?
B1 C1 C2 F1 0.0(3) . . . . ?
C6 C1 C2 C3 1.2(3) . . . . ?
B1 C1 C2 C3 176.4(2) . . . . ?
F1 C2 C3 F2 -1.1(3) . . . . ?
C1 C2 C3 F2 -177.6(2) . . . . ?
F1 C2 C3 C4 177.5(2) . . . . ?
C1 C2 C3 C4 1.0(4) . . . . ?
F2 C3 C4 F3 -2.2(4) . . . . ?
C2 C3 C4 F3 179.2(2) . . . . ?
F2 C3 C4 C5 176.3(2) . . . . ?
C2 C3 C4 C5 -2.3(4) . . . . ?
F3 C4 C5 F4 2.0(4) . . . . ?
C3 C4 C5 F4 -176.5(2) . . . . ?
F3 C4 C5 C6 179.7(2) . . . . ?
C3 C4 C5 C6 1.2(4) . . . . ?
C2 C1 C6 F5 174.6(2) . . . . ?
B1 C1 C6 F5 0.0(3) . . . . ?
C2 C1 C6 C5 -2.4(3) . . . . ?
B1 C1 C6 C5 -177.0(2) . . . . ?
F4 C5 C6 F5 1.8(3) . . . . ?
C4 C5 C6 F5 -175.9(2) . . . . ?
F4 C5 C6 C1 179.0(2) . . . . ?
C4 C5 C6 C1 1.2(4) . . . . ?
C13 B1 C7 C12 8.3(3) . . . . ?
C1 B1 C7 C12 -121.0(2) . . . . ?
P1 B1 C7 C12 121.3(2) . . . . ?
C13 B1 C7 C8 -170.88(19) . . . . ?
C1 B1 C7 C8 59.8(2) . . . . ?
P1 B1 C7 C8 -57.9(2) . . . . ?
C12 C7 C8 F6 177.40(18) . . . . ?
B1 C7 C8 F6 -3.3(3) . . . . ?
C12 C7 C8 C9 -4.7(3) . . . . ?
B1 C7 C8 C9 174.6(2) . . . . ?
F6 C8 C9 F7 0.8(3) . . . . ?
C7 C8 C9 F7 -177.1(2) . . . . ?
F6 C8 C9 C10 179.9(2) . . . . ?
C7 C8 C9 C10 2.0(4) . . . . ?
F7 C9 C10 F8 -0.7(4) . . . . ?
C8 C9 C10 F8 -179.8(2) . . . . ?
F7 C9 C10 C11 -179.4(2) . . . . ?
C8 C9 C10 C11 1.5(4) . . . . ?
F8 C10 C11 F9 -0.2(4) . . . . ?
C9 C10 C11 F9 178.6(2) . . . . ?
F8 C10 C11 C12 179.4(2) . . . . ?
C9 C10 C11 C12 -1.8(4) . . . . ?
F9 C11 C12 F10 -3.1(3) . . . . ?
C10 C11 C12 F10 177.3(2) . . . . ?
F9 C11 C12 C7 178.3(2) . . . . ?
C10 C11 C12 C7 -1.3(4) . . . . ?
C8 C7 C12 F10 -174.20(18) . . . . ?
B1 C7 C12 F10 6.6(3) . . . . ?
C8 C7 C12 C11 4.3(3) . . . . ?
B1 C7 C12 C11 -174.9(2) . . . . ?
C7 B1 C13 C14 52.6(3) . . . . ?
C1 B1 C13 C14 -179.36(19) . . . . ?
P1 B1 C13 C14 -59.3(2) . . . . ?
C7 B1 C13 C18 -132.7(2) . . . . ?
C1 B1 C13 C18 -4.7(3) . . . . ?
P1 B1 C13 C18 115.4(2) . . . . ?
C18 C13 C14 F11 -179.19(18) . . . . ?
B1 C13 C14 F11 -3.8(3) . . . . ?
C18 C13 C14 C15 0.4(3) . . . . ?
B1 C13 C14 C15 175.8(2) . . . . ?
F11 C14 C15 F12 -0.4(3) . . . . ?
C13 C14 C15 F12 179.9(2) . . . . ?
F11 C14 C15 C16 178.9(2) . . . . ?
C13 C14 C15 C16 -0.7(4) . . . . ?
F12 C15 C16 F13 0.6(4) . . . . ?
C14 C15 C16 F13 -178.7(2) . . . . ?
F12 C15 C16 C17 -179.9(2) . . . . ?
C14 C15 C16 C17 0.7(4) . . . . ?
F13 C16 C17 F14 -2.1(4) . . . . ?
C15 C16 C17 F14 178.5(2) . . . . ?
F13 C16 C17 C18 178.9(2) . . . . ?
C15 C16 C17 C18 -0.6(4) . . . . ?
F14 C17 C18 F15 1.3(3) . . . . ?
C16 C17 C18 F15 -179.7(2) . . . . ?
F14 C17 C18 C13 -178.7(2) . . . . ?
C16 C17 C18 C13 0.4(4) . . . . ?
C14 C13 C18 F15 179.8(2) . . . . ?
B1 C13 C18 F15 4.7(4) . . . . ?
C14 C13 C18 C17 -0.3(3) . . . . ?
B1 C13 C18 C17 -175.4(2) . . . . ?
C25 P1 C19 C24 157.88(19) . . . . ?
B1 P1 C19 C24 -70.7(2) . . . . ?
C25 P1 C19 C20 -25.1(2) . . . . ?
B1 P1 C19 C20 106.3(2) . . . . ?
C24 C19 C20 C21 2.8(4) . . . . ?
P1 C19 C20 C21 -174.2(2) . . . . ?
C19 C20 C21 C22 -1.3(4) . . . . ?
C20 C21 C22 C23 -1.2(5) . . . . ?
C21 C22 C23 C24 2.3(5) . . . . ?
C20 C19 C24 C23 -1.8(4) . . . . ?
P1 C19 C24 C23 175.3(2) . . . . ?
C22 C23 C24 C19 -0.8(5) . . . . ?
C19 P1 C25 C30 72.9(2) . . . . ?
B1 P1 C25 C30 -57.0(2) . . . . ?
C19 P1 C25 C26 -110.4(2) . . . . ?
B1 P1 C25 C26 119.71(19) . . . . ?
C30 C25 C26 C27 0.5(4) . . . . ?
P1 C25 C26 C27 -176.3(2) . . . . ?
C25 C26 C27 C28 -0.2(5) . . . . ?
C26 C27 C28 C29 -0.6(5) . . . . ?
C27 C28 C29 C30 1.0(5) . . . . ?
C28 C29 C30 C25 -0.7(4) . . . . ?
C26 C25 C30 C29 -0.1(4) . . . . ?
P1 C25 C30 C29 176.59(19) . . . . ?
