#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/05/7000590.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000590
loop_
_publ_author_name
'Garon, Christian N.'
'McIsaac, Daniel I.'
'Vogels, Christopher M.'
'Decken, Andreas'
'Williams, Ian D.'
'Kleeberg, Christian'
'Marder, Todd B.'
'Westcott, Stephen A.'
_publ_section_title
;
 Synthesis and structure of indenyl rhodium(I) complexes containing
 unsaturated phosphines: catalyst precursors for alkene hydroboration
;
_journal_issue                   9
_journal_name_full               'Dalton Transactions'
_journal_page_first              1624
_journal_page_last               1631
_journal_paper_doi               10.1039/b812259h
_journal_year                    2009
_chemical_formula_moiety         'C45 H45 P2 Rh'
_chemical_formula_sum            'C45 H45 P2 Rh'
_chemical_formula_weight         750.66
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.854(1)
_cell_angle_beta                 92.464(1)
_cell_angle_gamma                112.489(1)
_cell_formula_units_Z            2
_cell_length_a                   11.0600(6)
_cell_length_b                   11.8418(7)
_cell_length_c                   17.1608(10)
_cell_measurement_reflns_used    8366
_cell_measurement_temperature    198(1)
_cell_measurement_theta_max      28.2725
_cell_measurement_theta_min      2.3365
_cell_volume                     1929.21(19)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'Bruker SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      198(1)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.948
_diffrn_measurement_device_type  'Bruker AXS SMART1000/P4'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0174
_diffrn_reflns_av_sigmaI/netI    0.0278
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            13395
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.94
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_type              K760
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.555
_exptl_absorpt_correction_T_max  0.8971
_exptl_absorpt_correction_T_min  0.8084
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2004)'
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.292
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Parallelepiped
_exptl_crystal_F_000             780
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.473
_refine_diff_density_min         -0.463
_refine_diff_density_rms         0.081
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     439
_refine_ls_number_reflns         8406
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.091
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0332
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0590P)²+0.2619P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0877
_refine_ls_wR_factor_ref         0.0922
_reflns_number_gt                7406
_reflns_number_total             8406
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            b812259h.txt
_cod_data_source_block           sw050640
_cod_original_sg_symbol_Hall     '-P 1 '
_cod_database_code               7000590
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh Rh 0.363449(14) 0.485095(13) 0.263143(9) 0.02624(6) Uani 1 1 d . . .
P1 P 0.19817(5) 0.31726(5) 0.16836(3) 0.02518(11) Uani 1 1 d . . .
P2 P 0.24132(5) 0.50656(5) 0.36075(3) 0.02800(11) Uani 1 1 d . . .
C1 C 0.5230(2) 0.4971(2) 0.18730(15) 0.0361(5) Uani 1 1 d . . .
H1 H 0.5173 0.4276 0.1334 0.043 Uiso 1 1 calc R . .
C2 C 0.5770(2) 0.5119(2) 0.26877(15) 0.0383(5) Uani 1 1 d . . .
H2 H 0.6138 0.4534 0.2816 0.046 Uiso 1 1 calc R . .
C3 C 0.5750(2) 0.6265(2) 0.32818(16) 0.0394(5) Uani 1 1 d . . .
H3 H 0.6098 0.6620 0.3899 0.047 Uiso 1 1 calc R . .
C3A C 0.5401(2) 0.6966(2) 0.28198(16) 0.0380(5) Uani 1 1 d . . .
C4 C 0.5346(2) 0.8203(2) 0.30804(19) 0.0478(6) Uani 1 1 d . . .
H4 H 0.5566 0.8747 0.3658 0.057 Uiso 1 1 calc R . .
C5 C 0.4968(3) 0.8603(2) 0.2483(2) 0.0562(7) Uani 1 1 d . . .
H5 H 0.4959 0.9446 0.2649 0.067 Uiso 1 1 calc R . .
C6 C 0.4597(3) 0.7798(3) 0.1634(2) 0.0544(7) Uani 1 1 d . . .
H6 H 0.4319 0.8097 0.1238 0.065 Uiso 1 1 calc R . .
C7 C 0.4623(2) 0.6579(2) 0.13580(17) 0.0427(5) Uani 1 1 d . . .
H7 H 0.4352 0.6033 0.0780 0.051 Uiso 1 1 calc R . .
C7A C 0.5062(2) 0.6162(2) 0.19529(15) 0.0362(5) Uani 1 1 d . . .
C8 C 0.19527(19) 0.3331(2) 0.06536(12) 0.0294(4) Uani 1 1 d . . .
C9 C 0.1450(2) 0.4186(2) 0.05198(14) 0.0365(5) Uani 1 1 d . . .
H9 H 0.1103 0.4639 0.0948 0.044 Uiso 1 1 calc R . .
C10 C 0.1457(3) 0.4375(3) -0.02376(16) 0.0466(6) Uani 1 1 d . . .
H10 H 0.1106 0.4950 -0.0326 0.056 Uiso 1 1 calc R . .
C11 C 0.1969(2) 0.3734(3) -0.08613(16) 0.0502(6) Uani 1 1 d . . .
H11 H 0.1981 0.3876 -0.1376 0.060 Uiso 1 1 calc R . .
C12 C 0.2464(2) 0.2884(3) -0.07354(15) 0.0466(6) Uani 1 1 d . . .
H12 H 0.2805 0.2431 -0.1168 0.056 Uiso 1 1 calc R . .
C13 C 0.2465(2) 0.2688(2) 0.00228(14) 0.0374(5) Uani 1 1 d . . .
H13 H 0.2819 0.2113 0.0108 0.045 Uiso 1 1 calc R . .
C14 C 0.20168(19) 0.15587(18) 0.14606(12) 0.0268(4) Uani 1 1 d . . .
C15 C 0.3181(2) 0.1516(2) 0.17560(14) 0.0354(5) Uani 1 1 d . . .
H15 H 0.3941 0.2310 0.2060 0.043 Uiso 1 1 calc R . .
C16 C 0.3234(2) 0.0308(2) 0.16060(15) 0.0415(5) Uani 1 1 d . . .
H16 H 0.4034 0.0281 0.1806 0.050 Uiso 1 1 calc R . .
C17 C 0.2137(2) -0.0846(2) 0.11705(14) 0.0372(5) Uani 1 1 d . . .
H17 H 0.2174 -0.1667 0.1080 0.045 Uiso 1 1 calc R . .
C18 C 0.0985(2) -0.0809(2) 0.08652(14) 0.0380(5) Uani 1 1 d . . .
H18 H 0.0233 -0.1606 0.0554 0.046 Uiso 1 1 calc R . .
C19 C 0.0920(2) 0.0390(2) 0.10109(13) 0.0336(4) Uani 1 1 d . . .
H19 H 0.0122 0.0409 0.0802 0.040 Uiso 1 1 calc R . .
C20 C 0.02781(19) 0.27648(19) 0.17317(12) 0.0286(4) Uani 1 1 d . . .
C21 C -0.0892(2) 0.24624(19) 0.16878(13) 0.0305(4) Uani 1 1 d . . .
C22 C -0.2347(2) 0.2060(2) 0.15933(14) 0.0327(4) Uani 1 1 d . . .
C23 C -0.3057(2) 0.0611(2) 0.10101(16) 0.0476(6) Uani 1 1 d . . .
H23A H -0.2775 0.0500 0.0467 0.071 Uiso 1 1 calc R . .
H23B H -0.4023 0.0339 0.0929 0.071 Uiso 1 1 calc R . .
H23C H -0.2826 0.0069 0.1262 0.071 Uiso 1 1 calc R . .
C24 C -0.2758(2) 0.2240(3) 0.24500(15) 0.0479(6) Uani 1 1 d . . .
H24A H -0.2592 0.1638 0.2674 0.072 Uiso 1 1 calc R . .
H24B H -0.3708 0.2049 0.2389 0.072 Uiso 1 1 calc R . .
H24C H -0.2236 0.3148 0.2836 0.072 Uiso 1 1 calc R . .
C25 C -0.2710(3) 0.2908(3) 0.1201(2) 0.0577(7) Uani 1 1 d . . .
H25A H -0.2224 0.3837 0.1562 0.087 Uiso 1 1 calc R . .
H25B H -0.3671 0.2663 0.1145 0.087 Uiso 1 1 calc R . .
H25C H -0.2467 0.2767 0.0647 0.087 Uiso 1 1 calc R . .
C26 C 0.1170(2) 0.56836(19) 0.34571(12) 0.0296(4) Uani 1 1 d . . .
C27 C 0.0076(2) 0.5480(2) 0.38502(13) 0.0362(5) Uani 1 1 d . . .
H27 H -0.0058 0.4985 0.4203 0.043 Uiso 1 1 calc R . .
C28 C -0.0823(2) 0.5996(2) 0.37302(15) 0.0415(5) Uani 1 1 d . . .
H28 H -0.1571 0.5851 0.3999 0.050 Uiso 1 1 calc R . .
C29 C -0.0628(2) 0.6718(2) 0.32201(16) 0.0431(5) Uani 1 1 d . . .
H29 H -0.1250 0.7060 0.3133 0.052 Uiso 1 1 calc R . .
C30 C 0.0465(3) 0.6945(2) 0.28348(16) 0.0449(5) Uani 1 1 d . . .
H30 H 0.0609 0.7463 0.2497 0.054 Uiso 1 1 calc R . .
C31 C 0.1357(2) 0.6411(2) 0.29427(14) 0.0381(5) Uani 1 1 d . . .
H31 H 0.2094 0.6545 0.2664 0.046 Uiso 1 1 calc R . .
C32 C 0.3420(2) 0.6248(2) 0.46355(13) 0.0328(4) Uani 1 1 d . . .
C33 C 0.3792(3) 0.7582(2) 0.48230(15) 0.0463(6) Uani 1 1 d . . .
H33 H 0.3400 0.7865 0.4463 0.056 Uiso 1 1 calc R . .
C34 C 0.4732(3) 0.8502(3) 0.55336(16) 0.0541(7) Uani 1 1 d . . .
H34 H 0.4984 0.9413 0.5658 0.065 Uiso 1 1 calc R . .
C35 C 0.5306(3) 0.8097(3) 0.60637(15) 0.0513(6) Uani 1 1 d . . .
H35 H 0.5957 0.8730 0.6548 0.062 Uiso 1 1 calc R . .
C36 C 0.4932(3) 0.6778(3) 0.58867(15) 0.0486(6) Uani 1 1 d . . .
H36 H 0.5322 0.6499 0.6250 0.058 Uiso 1 1 calc R . .
C37 C 0.3989(2) 0.5857(2) 0.51811(14) 0.0408(5) Uani 1 1 d . . .
H37 H 0.3726 0.4947 0.5067 0.049 Uiso 1 1 calc R . .
C38 C 0.1483(2) 0.3641(2) 0.38153(13) 0.0358(5) Uani 1 1 d . . .
C39 C 0.0880(2) 0.2586(2) 0.38523(14) 0.0381(5) Uani 1 1 d . . .
C40 C 0.0152(3) 0.1249(2) 0.38610(15) 0.0441(6) Uani 1 1 d . . .
C41 C -0.0230(4) 0.0271(3) 0.29541(18) 0.0778(11) Uani 1 1 d . . .
H41A H -0.0752 0.0506 0.2610 0.117 Uiso 1 1 calc R . .
H41B H -0.0762 -0.0617 0.2938 0.117 Uiso 1 1 calc R . .
H41C H 0.0581 0.0299 0.2735 0.117 Uiso 1 1 calc R . .
C42 C -0.1096(3) 0.1152(3) 0.42296(17) 0.0533(6) Uani 1 1 d . . .
H42A H -0.0841 0.1758 0.4816 0.080 Uiso 1 1 calc R . .
H42B H -0.1596 0.0251 0.4202 0.080 Uiso 1 1 calc R . .
H42C H -0.1655 0.1384 0.3908 0.080 Uiso 1 1 calc R . .
C43 C 0.1084(3) 0.0980(3) 0.4399(2) 0.0611(8) Uani 1 1 d . . .
H43A H 0.1920 0.1126 0.4190 0.092 Uiso 1 1 calc R . .
H43B H 0.0652 0.0068 0.4365 0.092 Uiso 1 1 calc R . .
H43C H 0.1272 0.1576 0.4983 0.092 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh P2 94.30(2) . . ?
P1 Rh C1 98.13(6) . . ?
P2 Rh C1 167.49(6) . . ?
P1 Rh C2 122.92(6) . . ?
P2 Rh C2 132.44(6) . . ?
C1 Rh C2 37.11(9) . . ?
P1 Rh C3 159.00(7) . . ?
P2 Rh C3 105.46(7) . . ?
C1 Rh C3 62.03(9) . . ?
C2 Rh C3 36.68(8) . . ?
P1 Rh C7A 108.98(6) . . ?
P2 Rh C7A 138.72(6) . . ?
C1 Rh C7A 36.56(7) . . ?
C2 Rh C7A 59.93(8) . . ?
C3 Rh C7A 59.89(8) . . ?
P1 Rh C3A 141.36(6) . . ?
P2 Rh C3A 110.35(6) . . ?
C1 Rh C3A 59.84(8) . . ?
C2 Rh C3A 59.28(8) . . ?
C3 Rh C3A 35.92(8) . . ?
C7A Rh C3A 34.37(8) . . ?
C20 P1 C8 98.32(9) . . ?
C20 P1 C14 100.47(9) . . ?
C8 P1 C14 103.27(9) . . ?
C20 P1 Rh 124.04(7) . . ?
C8 P1 Rh 111.69(7) . . ?
C14 P1 Rh 115.93(6) . . ?
C38 P2 C26 102.99(10) . . ?
C38 P2 C32 103.36(10) . . ?
C26 P2 C32 102.40(9) . . ?
C38 P2 Rh 116.87(7) . . ?
C26 P2 Rh 116.93(7) . . ?
C32 P2 Rh 112.40(7) . . ?
C2 C1 C7A 107.4(2) . . ?
C2 C1 Rh 72.47(13) . . ?
C7A C1 Rh 77.86(12) . . ?
C2 C1 H1 125.7 . . ?
C7A C1 H1 125.7 . . ?
Rh C1 H1 125.7 . . ?
C3 C2 C1 108.61(19) . . ?
C3 C2 Rh 71.83(12) . . ?
C1 C2 Rh 70.42(12) . . ?
C3 C2 H2 125.7 . . ?
C1 C2 H2 125.7 . . ?
Rh C2 H2 125.7 . . ?
C2 C3 C3A 107.6(2) . . ?
C2 C3 Rh 71.50(12) . . ?
C3A C3 Rh 78.30(12) . . ?
C2 C3 H3 125.6 . . ?
C3A C3 H3 125.6 . . ?
Rh C3 H3 125.6 . . ?
C4 C3A C7A 119.9(2) . . ?
C4 C3A C3 132.3(2) . . ?
C7A C3A C3 107.78(19) . . ?
C4 C3A Rh 127.94(16) . . ?
C7A C3A Rh 71.52(12) . . ?
C3 C3A Rh 65.78(11) . . ?
C5 C4 C3A 118.6(3) . . ?
C5 C4 H4 120.7 . . ?
C3A C4 H4 120.7 . . ?
C4 C5 C6 121.5(2) . . ?
C4 C5 H5 119.3 . . ?
C6 C5 H5 119.3 . . ?
C7 C6 C5 121.5(2) . . ?
C7 C6 H6 119.3 . . ?
C5 C6 H6 119.3 . . ?
C6 C7 C7A 118.4(3) . . ?
C6 C7 H7 120.8 . . ?
C7A C7 H7 120.8 . . ?
C7 C7A C3A 119.9(2) . . ?
C7 C7A C1 132.3(2) . . ?
C3A C7A C1 107.7(2) . . ?
C7 C7A Rh 124.77(15) . . ?
C3A C7A Rh 74.11(12) . . ?
C1 C7A Rh 65.58(11) . . ?
C13 C8 C9 119.03(19) . . ?
C13 C8 P1 122.66(16) . . ?
C9 C8 P1 118.24(16) . . ?
C10 C9 C8 120.2(2) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C11 C10 C9 120.5(2) . . ?
C11 C10 H10 119.7 . . ?
C9 C10 H10 119.7 . . ?
C10 C11 C12 119.7(2) . . ?
C10 C11 H11 120.1 . . ?
C12 C11 H11 120.1 . . ?
C11 C12 C13 120.3(2) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 H12 119.8 . . ?
C8 C13 C12 120.2(2) . . ?
C8 C13 H13 119.9 . . ?
C12 C13 H13 119.9 . . ?
C19 C14 C15 119.25(18) . . ?
C19 C14 P1 122.20(15) . . ?
C15 C14 P1 118.56(15) . . ?
C14 C15 C16 119.9(2) . . ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 . . ?
C17 C16 C15 120.5(2) . . ?
C17 C16 H16 119.8 . . ?
C15 C16 H16 119.8 . . ?
C16 C17 C18 119.8(2) . . ?
C16 C17 H17 120.1 . . ?
C18 C17 H17 120.1 . . ?
C17 C18 C19 120.2(2) . . ?
C17 C18 H18 119.9 . . ?
C19 C18 H18 119.9 . . ?
C14 C19 C18 120.3(2) . . ?
C14 C19 H19 119.8 . . ?
C18 C19 H19 119.8 . . ?
C21 C20 P1 174.09(18) . . ?
C20 C21 C22 177.5(2) . . ?
C21 C22 C24 110.05(18) . . ?
C21 C22 C25 108.55(18) . . ?
C24 C22 C25 110.1(2) . . ?
C21 C22 C23 108.65(18) . . ?
C24 C22 C23 109.96(19) . . ?
C25 C22 C23 109.5(2) . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C22 C25 H25A 109.5 . . ?
C22 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C22 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C27 C26 C31 119.3(2) . . ?
C27 C26 P2 122.61(16) . . ?
C31 C26 P2 118.12(16) . . ?
C26 C27 C28 120.4(2) . . ?
C26 C27 H27 119.8 . . ?
C28 C27 H27 119.8 . . ?
C29 C28 C27 119.9(2) . . ?
C29 C28 H28 120.0 . . ?
C27 C28 H28 120.0 . . ?
C28 C29 C30 120.3(2) . . ?
C28 C29 H29 119.8 . . ?
C30 C29 H29 119.8 . . ?
C29 C30 C31 119.9(2) . . ?
C29 C30 H30 120.1 . . ?
C31 C30 H30 120.1 . . ?
C26 C31 C30 120.2(2) . . ?
C26 C31 H31 119.9 . . ?
C30 C31 H31 119.9 . . ?
C33 C32 C37 118.9(2) . . ?
C33 C32 P2 119.47(16) . . ?
C37 C32 P2 120.92(17) . . ?
C34 C33 C32 120.2(2) . . ?
C34 C33 H33 119.9 . . ?
C32 C33 H33 119.9 . . ?
C33 C34 C35 120.2(2) . . ?
C33 C34 H34 119.9 . . ?
C35 C34 H34 119.9 . . ?
C36 C35 C34 119.8(2) . . ?
C36 C35 H35 120.1 . . ?
C34 C35 H35 120.1 . . ?
C35 C36 C37 120.1(2) . . ?
C35 C36 H36 119.9 . . ?
C37 C36 H36 119.9 . . ?
C36 C37 C32 120.7(2) . . ?
C36 C37 H37 119.7 . . ?
C32 C37 H37 119.7 . . ?
C39 C38 P2 171.1(2) . . ?
C38 C39 C40 177.3(2) . . ?
C39 C40 C42 110.2(2) . . ?
C39 C40 C41 107.8(2) . . ?
C42 C40 C41 110.0(3) . . ?
C39 C40 C43 108.4(2) . . ?
C42 C40 C43 109.9(2) . . ?
C41 C40 C43 110.5(3) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C40 C42 H42A 109.5 . . ?
C40 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C40 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C40 C43 H43A 109.5 . . ?
C40 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C40 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh P1 2.1938(5) . ?
Rh P2 2.2083(5) . ?
Rh C1 2.226(2) . ?
Rh C2 2.253(2) . ?
Rh C3 2.257(2) . ?
Rh C7A 2.390(2) . ?
Rh C3A 2.423(2) . ?
P1 C20 1.770(2) . ?
P1 C8 1.837(2) . ?
P1 C14 1.8401(19) . ?
P2 C38 1.768(2) . ?
P2 C26 1.831(2) . ?
P2 C32 1.832(2) . ?
C1 C2 1.425(3) . ?
C1 C7A 1.456(3) . ?
C1 H1 1.0000 . ?
C2 C3 1.419(3) . ?
C2 H2 1.0000 . ?
C3 C3A 1.452(3) . ?
C3 H3 1.0000 . ?
C3A C4 1.414(3) . ?
C3A C7A 1.423(3) . ?
C4 C5 1.371(4) . ?
C4 H4 0.9500 . ?
C5 C6 1.396(4) . ?
C5 H5 0.9500 . ?
C6 C7 1.379(4) . ?
C6 H6 0.9500 . ?
C7 C7A 1.410(3) . ?
C7 H7 0.9500 . ?
C8 C13 1.387(3) . ?
C8 C9 1.399(3) . ?
C9 C10 1.388(3) . ?
C9 H9 0.9500 . ?
C10 C11 1.377(4) . ?
C10 H10 0.9500 . ?
C11 C12 1.383(4) . ?
C11 H11 0.9500 . ?
C12 C13 1.393(3) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 C19 1.388(3) . ?
C14 C15 1.389(3) . ?
C15 C16 1.395(3) . ?
C15 H15 0.9500 . ?
C16 C17 1.375(3) . ?
C16 H16 0.9500 . ?
C17 C18 1.379(3) . ?
C17 H17 0.9500 . ?
C18 C19 1.391(3) . ?
C18 H18 0.9500 . ?
C19 H19 0.9500 . ?
C20 C21 1.195(3) . ?
C21 C22 1.478(3) . ?
C22 C24 1.530(3) . ?
C22 C25 1.531(3) . ?
C22 C23 1.534(3) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 C27 1.389(3) . ?
C26 C31 1.391(3) . ?
C27 C28 1.391(3) . ?
C27 H27 0.9500 . ?
C28 C29 1.379(4) . ?
C28 H28 0.9500 . ?
C29 C30 1.381(4) . ?
C29 H29 0.9500 . ?
C30 C31 1.394(3) . ?
C30 H30 0.9500 . ?
C31 H31 0.9500 . ?
C32 C33 1.390(3) . ?
C32 C37 1.393(3) . ?
C33 C34 1.386(4) . ?
C33 H33 0.9500 . ?
C34 C35 1.388(4) . ?
C34 H34 0.9500 . ?
C35 C36 1.376(4) . ?
C35 H35 0.9500 . ?
C36 C37 1.382(3) . ?
C36 H36 0.9500 . ?
C37 H37 0.9500 . ?
C38 C39 1.195(3) . ?
C39 C40 1.481(3) . ?
C40 C42 1.524(4) . ?
C40 C41 1.532(4) . ?
C40 C43 1.541(4) . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
