#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:18:11 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179684 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/06/7000657.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000657
loop_
_publ_author_name
'Wong, Elizabeth'
'Li, John'
'Seward, Corey'
'Wang, Suning'
_publ_section_title
;
 Cu(i) and Ag(i) complexes of 7-azaindolyl and
 2,2′-dipyridylamino substituted 1,3,5-triazine and benzene: the
 central core impact on structure, solution dynamics and fluorescence
 of the complexes
;
_journal_issue                   10
_journal_name_full               'Dalton Transactions'
_journal_page_first              1776
_journal_page_last               1785
_journal_paper_doi               10.1039/b814393e
_journal_year                    2009
_chemical_formula_sum            'C48 H30 Ag4 N22 O12'
_chemical_formula_weight         1538.42
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.933(8)
_cell_angle_beta                 94.262(8)
_cell_angle_gamma                115.538(7)
_cell_formula_units_Z            1
_cell_length_a                   10.365(5)
_cell_length_b                   10.660(5)
_cell_length_c                   12.142(6)
_cell_measurement_temperature    180(2)
_cell_volume                     1169.9(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0942
_diffrn_reflns_av_sigmaI/netI    0.2683
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7037
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.21
_exptl_absorpt_coefficient_mu    1.746
_exptl_absorpt_correction_T_max  0.8447
_exptl_absorpt_correction_T_min  0.7215
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    2.183
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             756
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.104
_refine_diff_density_min         -1.176
_refine_diff_density_rms         0.153
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.847
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     388
_refine_ls_number_reflns         4514
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.847
_refine_ls_R_factor_all          0.1821
_refine_ls_R_factor_gt           0.0729
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0410P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1180
_refine_ls_wR_factor_ref         0.1375
_reflns_number_gt                1796
_reflns_number_total             4514
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b814393e.txt
_cod_data_source_block           jli1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        1170.0(9)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7000657
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.31854(10) 1.03317(10) 0.39678(10) 0.0483(4) Uani 1 1 d . . .
Ag2 Ag 0.76686(10) 0.96726(10) 0.26600(9) 0.0421(3) Uani 1 1 d . . .
O1 O 0.9672(9) 1.1427(9) 0.6168(9) 0.056(3) Uani 1 1 d . . .
O2 O 0.8150(8) 1.0270(8) 0.4634(7) 0.045(2) Uani 1 1 d . . .
O3 O 1.0388(10) 1.1684(9) 0.4589(8) 0.056(3) Uani 1 1 d . . .
O4 O 1.5289(10) 0.9052(10) 0.3341(9) 0.091(4) Uani 1 1 d . . .
O5 O 1.2998(10) 0.7934(9) 0.2999(8) 0.064(3) Uani 1 1 d . . .
O6 O 1.4245(12) 0.7323(10) 0.1891(9) 0.079(4) Uani 1 1 d . . .
N1 N 1.2404(10) 1.1522(10) 0.2557(8) 0.038(3) Uani 1 1 d . . .
N2 N 1.0021(10) 1.1223(10) 0.1935(8) 0.029(3) Uani 1 1 d . . .
N3 N 1.1940(9) 1.3515(9) 0.2878(7) 0.025(2) Uani 1 1 d . . .
N4 N 1.4231(9) 1.3805(9) 0.3379(8) 0.031(2) Uani 1 1 d . . .
N5 N 1.5184(9) 1.2277(9) 0.3991(8) 0.037(3) Uani 1 1 d . . .
N6 N 1.0596(10) 0.9360(9) 0.1509(8) 0.030(2) Uani 1 1 d . . .
N7 N 0.7966(10) 0.8234(10) 0.1171(8) 0.036(3) Uani 1 1 d . . .
N8 N 0.9660(9) 1.3251(9) 0.2337(8) 0.026(2) Uani 1 1 d . . .
N9 N 0.7247(10) 1.1255(10) 0.1784(8) 0.034(3) Uani 1 1 d . . .
N10 N 0.9438(13) 1.1152(11) 0.5143(11) 0.037(3) Uani 1 1 d . . .
C1 C 1.2781(12) 1.2900(13) 0.2922(10) 0.034(3) Uani 1 1 d . . .
C2 C 1.1002(12) 1.0751(11) 0.2070(10) 0.031(3) Uani 1 1 d . . .
C3 C 1.0574(13) 1.2660(13) 0.2412(9) 0.032(3) Uani 1 1 d . . .
C4 C 1.4840(12) 1.5277(12) 0.3418(11) 0.040(3) Uani 1 1 d . . .
H4A H 1.4330 1.5758 0.3169 0.048 Uiso 1 1 calc R . .
C5 C 1.6229(14) 1.5878(13) 0.3855(11) 0.049(4) Uani 1 1 d . . .
H5A H 1.6887 1.6864 0.3964 0.059 Uiso 1 1 calc R . .
C6 C 1.6587(11) 1.4842(12) 0.4133(11) 0.039(4) Uani 1 1 d . . .
C7 C 1.7808(13) 1.4822(13) 0.4618(10) 0.043(4) Uani 1 1 d . . .
H7A H 1.8697 1.5678 0.4868 0.052 Uiso 1 1 calc R . .
C8 C 1.7716(12) 1.3518(13) 0.4735(10) 0.038(3) Uani 1 1 d . . .
H8A H 1.8567 1.3463 0.5012 0.046 Uiso 1 1 calc R . .
C9 C 1.6424(14) 1.2326(13) 0.4456(10) 0.047(4) Uani 1 1 d . . .
H9A H 1.6392 1.1468 0.4599 0.056 Uiso 1 1 calc R . .
C10 C 1.5323(12) 1.3546(12) 0.3832(10) 0.036(3) Uani 1 1 d . . .
C11 C 1.1551(13) 0.8835(14) 0.1232(11) 0.042(4) Uani 1 1 d . . .
H11A H 1.2567 0.9350 0.1510 0.050 Uiso 1 1 calc R . .
C12 C 1.0923(13) 0.7544(13) 0.0543(11) 0.041(3) Uani 1 1 d . . .
H12A H 1.1390 0.6998 0.0231 0.050 Uiso 1 1 calc R . .
C13 C 0.9404(14) 0.7124(13) 0.0355(10) 0.038(3) Uani 1 1 d . . .
C14 C 0.8173(15) 0.5928(12) -0.0278(10) 0.048(4) Uani 1 1 d . . .
H14A H 0.8226 0.5130 -0.0737 0.058 Uiso 1 1 calc R . .
C15 C 0.6862(13) 0.5965(12) -0.0202(10) 0.040(3) Uani 1 1 d . . .
H15A H 0.5988 0.5212 -0.0660 0.048 Uiso 1 1 calc R . .
C16 C 0.6829(13) 0.7089(14) 0.0535(11) 0.046(4) Uani 1 1 d . . .
H16A H 0.5901 0.7041 0.0594 0.055 Uiso 1 1 calc R . .
C17 C 0.9200(13) 0.8263(12) 0.0994(10) 0.035(3) Uani 1 1 d . . .
C18 C 1.0197(13) 1.4744(11) 0.2526(10) 0.036(3) Uani 1 1 d . . .
H18A H 1.1178 1.5434 0.2817 0.043 Uiso 1 1 calc R . .
C19 C 0.9096(12) 1.5040(12) 0.2227(10) 0.041(3) Uani 1 1 d . . .
H19A H 0.9172 1.5969 0.2268 0.049 Uiso 1 1 calc R . .
C20 C 0.7805(13) 1.3724(12) 0.1840(9) 0.034(3) Uani 1 1 d . . .
C21 C 0.6377(11) 1.3351(12) 0.1409(11) 0.039(3) Uani 1 1 d . . .
H21A H 0.6079 1.4046 0.1282 0.047 Uiso 1 1 calc R . .
C22 C 0.5426(12) 1.1932(13) 0.1179(10) 0.039(3) Uani 1 1 d . . .
H22A H 0.4433 1.1622 0.0888 0.047 Uiso 1 1 calc R . .
C23 C 0.5889(13) 1.0921(12) 0.1363(10) 0.041(3) Uani 1 1 d . . .
H23A H 0.5190 0.9940 0.1176 0.049 Uiso 1 1 calc R . .
C24 C 0.8173(12) 1.2635(12) 0.1949(10) 0.031(3) Uani 1 1 d . . .
N11 N 1.4180(13) 0.8075(11) 0.2720(10) 0.039(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N5 Ag1 O2 130.5(3) . 2_776 ?
N5 Ag1 O5 118.2(3) . . ?
O2 Ag1 O5 100.9(3) 2_776 . ?
N5 Ag1 N1 75.5(3) . . ?
O2 Ag1 N1 117.8(3) 2_776 . ?
O5 Ag1 N1 112.5(3) . . ?
N7 Ag2 O2 139.2(3) . . ?
N7 Ag2 N9 101.8(3) . . ?
O2 Ag2 N9 117.1(3) . . ?
N7 Ag2 O4 123.2(3) . 1_455 ?
O2 Ag2 O4 72.4(3) . 1_455 ?
N9 Ag2 O4 88.2(4) . 1_455 ?
N7 Ag2 N2 71.8(3) . . ?
O2 Ag2 N2 108.4(3) . . ?
N9 Ag2 N2 71.1(3) . . ?
O4 Ag2 N2 157.3(3) 1_455 . ?
N10 O2 Ag1 106.1(8) . 2_776 ?
N10 O2 Ag2 118.6(8) . . ?
Ag1 O2 Ag2 135.3(4) 2_776 . ?
N11 O4 Ag2 118.3(9) . 1_655 ?
N11 O5 Ag1 110.6(7) . . ?
C1 N1 C2 112.6(10) . . ?
C1 N1 Ag1 116.7(8) . . ?
C2 N1 Ag1 112.2(7) . . ?
C2 N2 C3 112.1(9) . . ?
C2 N2 Ag2 110.4(7) . . ?
C3 N2 Ag2 113.1(7) . . ?
C1 N3 C3 115.8(9) . . ?
C10 N4 C1 131.7(10) . . ?
C10 N4 C4 107.2(9) . . ?
C1 N4 C4 121.1(10) . . ?
C9 N5 C10 114.0(10) . . ?
C9 N5 Ag1 115.7(8) . . ?
C10 N5 Ag1 128.7(8) . . ?
C11 N6 C2 124.0(10) . . ?
C11 N6 C17 106.6(9) . . ?
C2 N6 C17 129.0(10) . . ?
C17 N7 C16 113.3(10) . . ?
C17 N7 Ag2 125.2(8) . . ?
C16 N7 Ag2 120.1(8) . . ?
C3 N8 C24 131.4(9) . . ?
C3 N8 C18 120.8(9) . . ?
C24 N8 C18 107.3(9) . . ?
C23 N9 C24 114.2(10) . . ?
C23 N9 Ag2 118.6(8) . . ?
C24 N9 Ag2 124.3(8) . . ?
O1 N10 O3 122.4(12) . . ?
O1 N10 O2 117.6(12) . . ?
O3 N10 O2 120.0(12) . . ?
N3 C1 N1 126.9(10) . . ?
N3 C1 N4 115.8(10) . . ?
N1 C1 N4 117.2(11) . . ?
N2 C2 N1 127.6(10) . . ?
N2 C2 N6 116.2(10) . . ?
N1 C2 N6 115.5(10) . . ?
N3 C3 N8 118.0(10) . . ?
N3 C3 N2 124.8(11) . . ?
N8 C3 N2 117.1(10) . . ?
C5 C4 N4 108.9(11) . . ?
C4 C5 C6 109.3(11) . . ?
C7 C6 C10 116.8(12) . . ?
C7 C6 C5 136.1(11) . . ?
C10 C6 C5 107.0(10) . . ?
C6 C7 C8 118.3(11) . . ?
C9 C8 C7 120.4(11) . . ?
N5 C9 C8 124.2(12) . . ?
N5 C10 N4 126.3(10) . . ?
N5 C10 C6 126.2(11) . . ?
N4 C10 C6 107.5(10) . . ?
C12 C11 N6 113.2(11) . . ?
C11 C12 C13 106.5(11) . . ?
C14 C13 C17 117.2(12) . . ?
C14 C13 C12 135.5(13) . . ?
C17 C13 C12 107.3(11) . . ?
C15 C14 C13 116.1(12) . . ?
C16 C15 C14 119.8(11) . . ?
N7 C16 C15 126.1(12) . . ?
N7 C17 N6 126.7(11) . . ?
N7 C17 C13 126.6(11) . . ?
N6 C17 C13 106.3(10) . . ?
C19 C18 N8 109.1(9) . . ?
C18 C19 C20 108.2(10) . . ?
C21 C20 C24 118.5(11) . . ?
C21 C20 C19 134.5(11) . . ?
C24 C20 C19 107.0(10) . . ?
C22 C21 C20 116.2(11) . . ?
C21 C22 C23 121.1(11) . . ?
N9 C23 C22 123.8(10) . . ?
N9 C24 N8 125.7(11) . . ?
N9 C24 C20 125.8(11) . . ?
N8 C24 C20 108.3(10) . . ?
O6 N11 O4 121.0(13) . . ?
O6 N11 O5 122.3(13) . . ?
O4 N11 O5 116.7(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N5 2.204(9) . ?
Ag1 O2 2.282(9) 2_776 ?
Ag1 O5 2.520(9) . ?
Ag1 N1 2.589(10) . ?
Ag2 N7 2.271(9) . ?
Ag2 O2 2.318(8) . ?
Ag2 N9 2.327(10) . ?
Ag2 O4 2.511(10) 1_455 ?
Ag2 N2 2.617(9) . ?
O1 N10 1.203(12) . ?
O2 N10 1.274(12) . ?
O2 Ag1 2.282(9) 2_776 ?
O3 N10 1.227(12) . ?
O4 N11 1.231(12) . ?
O4 Ag2 2.511(10) 1_655 ?
O5 N11 1.249(12) . ?
O6 N11 1.188(12) . ?
N1 C1 1.318(13) . ?
N1 C2 1.340(12) . ?
N2 C2 1.327(12) . ?
N2 C3 1.367(13) . ?
N3 C1 1.301(13) . ?
N3 C3 1.315(13) . ?
N4 C10 1.377(13) . ?
N4 C1 1.385(13) . ?
N4 C4 1.405(13) . ?
N5 C9 1.340(14) . ?
N5 C10 1.350(13) . ?
N6 C11 1.364(13) . ?
N6 C2 1.370(13) . ?
N6 C17 1.408(13) . ?
N7 C17 1.301(13) . ?
N7 C16 1.320(13) . ?
N8 C3 1.351(13) . ?
N8 C24 1.389(13) . ?
N8 C18 1.405(12) . ?
N9 C23 1.327(13) . ?
N9 C24 1.329(13) . ?
C4 C5 1.314(15) . ?
C5 C6 1.395(15) . ?
C6 C7 1.367(15) . ?
C6 C10 1.391(14) . ?
C7 C8 1.387(16) . ?
C8 C9 1.351(15) . ?
C11 C12 1.315(14) . ?
C12 C13 1.426(15) . ?
C13 C14 1.387(15) . ?
C13 C17 1.417(15) . ?
C14 C15 1.386(16) . ?
C15 C16 1.367(15) . ?
C18 C19 1.352(14) . ?
C19 C20 1.420(14) . ?
C20 C21 1.386(14) . ?
C20 C24 1.393(15) . ?
C21 C22 1.360(14) . ?
C22 C23 1.400(15) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N7 Ag2 O2 N10 78.6(9) . . . . ?
N9 Ag2 O2 N10 -82.2(8) . . . . ?
O4 Ag2 O2 N10 -160.6(8) 1_455 . . . ?
N2 Ag2 O2 N10 -4.5(8) . . . . ?
N7 Ag2 O2 Ag1 -102.2(6) . . . 2_776 ?
N9 Ag2 O2 Ag1 97.0(5) . . . 2_776 ?
O4 Ag2 O2 Ag1 18.5(5) 1_455 . . 2_776 ?
N2 Ag2 O2 Ag1 174.7(4) . . . 2_776 ?
N5 Ag1 O5 N11 7.7(9) . . . . ?
O2 Ag1 O5 N11 -140.8(8) 2_776 . . . ?
N1 Ag1 O5 N11 92.8(8) . . . . ?
N5 Ag1 N1 C1 -49.6(9) . . . . ?
O2 Ag1 N1 C1 78.8(9) 2_776 . . . ?
O5 Ag1 N1 C1 -164.5(8) . . . . ?
N5 Ag1 N1 C2 178.3(8) . . . . ?
O2 Ag1 N1 C2 -53.3(8) 2_776 . . . ?
O5 Ag1 N1 C2 63.4(8) . . . . ?
N7 Ag2 N2 C2 -63.3(7) . . . . ?
O2 Ag2 N2 C2 73.7(7) . . . . ?
N9 Ag2 N2 C2 -173.2(8) . . . . ?
O4 Ag2 N2 C2 161.9(8) 1_455 . . . ?
N7 Ag2 N2 C3 170.1(8) . . . . ?
O2 Ag2 N2 C3 -52.9(8) . . . . ?
N9 Ag2 N2 C3 60.2(8) . . . . ?
O4 Ag2 N2 C3 35.3(13) 1_455 . . . ?
O2 Ag1 N5 C9 80.7(9) 2_776 . . . ?
O5 Ag1 N5 C9 -56.8(9) . . . . ?
N1 Ag1 N5 C9 -164.9(9) . . . . ?
O2 Ag1 N5 C10 -83.6(11) 2_776 . . . ?
O5 Ag1 N5 C10 138.9(10) . . . . ?
N1 Ag1 N5 C10 30.8(10) . . . . ?
O2 Ag2 N7 C17 -56.3(11) . . . . ?
N9 Ag2 N7 C17 106.2(10) . . . . ?
O4 Ag2 N7 C17 -158.2(9) 1_455 . . . ?
N2 Ag2 N7 C17 40.9(9) . . . . ?
O2 Ag2 N7 C16 109.7(9) . . . . ?
N9 Ag2 N7 C16 -87.7(9) . . . . ?
O4 Ag2 N7 C16 7.8(10) 1_455 . . . ?
N2 Ag2 N7 C16 -153.1(9) . . . . ?
N7 Ag2 N9 C23 90.0(9) . . . . ?
O2 Ag2 N9 C23 -102.6(8) . . . . ?
O4 Ag2 N9 C23 -33.5(8) 1_455 . . . ?
N2 Ag2 N9 C23 155.9(9) . . . . ?
N7 Ag2 N9 C24 -110.4(9) . . . . ?
O2 Ag2 N9 C24 57.0(10) . . . . ?
O4 Ag2 N9 C24 126.1(9) 1_455 . . . ?
N2 Ag2 N9 C24 -44.5(9) . . . . ?
Ag1 O2 N10 O1 2.0(12) 2_776 . . . ?
Ag2 O2 N10 O1 -178.6(8) . . . . ?
Ag1 O2 N10 O3 -178.2(8) 2_776 . . . ?
Ag2 O2 N10 O3 1.2(13) . . . . ?
C3 N3 C1 N1 -0.5(19) . . . . ?
C3 N3 C1 N4 177.9(10) . . . . ?
C2 N1 C1 N3 2.2(19) . . . . ?
Ag1 N1 C1 N3 -129.7(12) . . . . ?
C2 N1 C1 N4 -176.2(10) . . . . ?
Ag1 N1 C1 N4 51.9(13) . . . . ?
C10 N4 C1 N3 160.2(12) . . . . ?
C4 N4 C1 N3 -21.2(17) . . . . ?
C10 N4 C1 N1 -21.2(19) . . . . ?
C4 N4 C1 N1 157.4(11) . . . . ?
C3 N2 C2 N1 -2.9(17) . . . . ?
Ag2 N2 C2 N1 -130.1(11) . . . . ?
C3 N2 C2 N6 -172.8(10) . . . . ?
Ag2 N2 C2 N6 60.0(11) . . . . ?
C1 N1 C2 N2 -0.2(18) . . . . ?
Ag1 N1 C2 N2 133.9(11) . . . . ?
C1 N1 C2 N6 169.7(10) . . . . ?
Ag1 N1 C2 N6 -56.2(12) . . . . ?
C11 N6 C2 N2 157.5(11) . . . . ?
C17 N6 C2 N2 -14.2(18) . . . . ?
C11 N6 C2 N1 -13.6(17) . . . . ?
C17 N6 C2 N1 174.6(10) . . . . ?
C1 N3 C3 N8 -179.4(11) . . . . ?
C1 N3 C3 N2 -3.3(18) . . . . ?
C24 N8 C3 N3 -176.4(11) . . . . ?
C18 N8 C3 N3 13.1(16) . . . . ?
C24 N8 C3 N2 7.2(19) . . . . ?
C18 N8 C3 N2 -163.2(10) . . . . ?
C2 N2 C3 N3 4.8(17) . . . . ?
Ag2 N2 C3 N3 130.5(10) . . . . ?
C2 N2 C3 N8 -179.1(10) . . . . ?
Ag2 N2 C3 N8 -53.4(12) . . . . ?
C10 N4 C4 C5 0.9(14) . . . . ?
C1 N4 C4 C5 -178.1(11) . . . . ?
N4 C4 C5 C6 -0.8(16) . . . . ?
C4 C5 C6 C7 -178.4(14) . . . . ?
C4 C5 C6 C10 0.4(16) . . . . ?
C10 C6 C7 C8 2.4(18) . . . . ?
C5 C6 C7 C8 -179.0(15) . . . . ?
C6 C7 C8 C9 -5.1(19) . . . . ?
C10 N5 C9 C8 -0.9(18) . . . . ?
Ag1 N5 C9 C8 -167.5(10) . . . . ?
C7 C8 C9 N5 4(2) . . . . ?
C9 N5 C10 N4 -179.6(11) . . . . ?
Ag1 N5 C10 N4 -15.1(18) . . . . ?
C9 N5 C10 C6 -2.0(19) . . . . ?
Ag1 N5 C10 C6 162.5(9) . . . . ?
C1 N4 C10 N5 -4(2) . . . . ?
C4 N4 C10 N5 177.4(11) . . . . ?
C1 N4 C10 C6 178.2(12) . . . . ?
C4 N4 C10 C6 -0.6(14) . . . . ?
C7 C6 C10 N5 1.2(19) . . . . ?
C5 C6 C10 N5 -177.8(12) . . . . ?
C7 C6 C10 N4 179.2(10) . . . . ?
C5 C6 C10 N4 0.2(15) . . . . ?
C2 N6 C11 C12 -169.9(11) . . . . ?
C17 N6 C11 C12 3.5(14) . . . . ?
N6 C11 C12 C13 -1.9(15) . . . . ?
C11 C12 C13 C14 179.2(13) . . . . ?
C11 C12 C13 C17 -0.4(14) . . . . ?
C17 C13 C14 C15 -1.1(16) . . . . ?
C12 C13 C14 C15 179.3(13) . . . . ?
C13 C14 C15 C16 -4.8(18) . . . . ?
C17 N7 C16 C15 3.9(18) . . . . ?
Ag2 N7 C16 C15 -163.7(10) . . . . ?
C14 C15 C16 N7 4(2) . . . . ?
C16 N7 C17 N6 177.6(11) . . . . ?
Ag2 N7 C17 N6 -15.5(17) . . . . ?
C16 N7 C17 C13 -10.8(18) . . . . ?
Ag2 N7 C17 C13 156.0(9) . . . . ?
C11 N6 C17 N7 169.4(12) . . . . ?
C2 N6 C17 N7 -17.7(19) . . . . ?
C11 N6 C17 C13 -3.5(12) . . . . ?
C2 N6 C17 C13 169.4(11) . . . . ?
C14 C13 C17 N7 9.8(18) . . . . ?
C12 C13 C17 N7 -170.5(12) . . . . ?
C14 C13 C17 N6 -177.2(10) . . . . ?
C12 C13 C17 N6 2.4(13) . . . . ?
C3 N8 C18 C19 170.4(11) . . . . ?
C24 N8 C18 C19 -2.1(13) . . . . ?
N8 C18 C19 C20 0.3(14) . . . . ?
C18 C19 C20 C21 -178.2(13) . . . . ?
C18 C19 C20 C24 1.6(14) . . . . ?
C24 C20 C21 C22 3.2(17) . . . . ?
C19 C20 C21 C22 -177.0(13) . . . . ?
C20 C21 C22 C23 -0.5(18) . . . . ?
C24 N9 C23 C22 -4.4(17) . . . . ?
Ag2 N9 C23 C22 157.2(9) . . . . ?
C21 C22 C23 N9 1(2) . . . . ?
C23 N9 C24 N8 -177.4(10) . . . . ?
Ag2 N9 C24 N8 22.2(16) . . . . ?
C23 N9 C24 C20 7.5(18) . . . . ?
Ag2 N9 C24 C20 -152.9(10) . . . . ?
C3 N8 C24 N9 16(2) . . . . ?
C18 N8 C24 N9 -172.8(11) . . . . ?
C3 N8 C24 C20 -168.3(12) . . . . ?
C18 N8 C24 C20 3.1(13) . . . . ?
C21 C20 C24 N9 -7.2(19) . . . . ?
C19 C20 C24 N9 173.0(12) . . . . ?
C21 C20 C24 N8 176.9(10) . . . . ?
C19 C20 C24 N8 -2.9(14) . . . . ?
Ag2 O4 N11 O6 9.5(15) 1_655 . . . ?
Ag2 O4 N11 O5 -169.6(8) 1_655 . . . ?
Ag1 O5 N11 O6 -147.1(10) . . . . ?
Ag1 O5 N11 O4 32.0(12) . . . . ?
