#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:19:21 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179685 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/07/7000746.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000746
loop_
_publ_author_name
'Ganesamoorthy, Chelladurai'
'Balakrishna, Maravanji S.'
'Mague, Joel T.'
_publ_section_title
;
 Di-, tetra- and polynuclear RhI complexes containing
 phenylene-1,4-diaminotetra(phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2
 and their catalytic investigation towards transfer hydrogenation
 reactions
;
_journal_issue                   11
_journal_name_full               'Dalton Transactions'
_journal_page_first              1984
_journal_page_last               1990
_journal_paper_doi               10.1039/b815849e
_journal_year                    2009
_chemical_formula_moiety         'C66 H64 Cl2 N4 O16 P4 Rh2'
_chemical_formula_sum            'C66 H64 Cl2 N4 O16 P4 Rh2'
_chemical_formula_weight         1569.81
_chemical_name_systematic
;
catena-Poly{dichloro(μ-1,4-bis(bis(bis(2-
methoxyphenoxy)phospino)amino)benzene-1κ²
P,P':2κ²P",P"')(μ-pyrazine-1\kN:2\kN')
dirhodium(I)}
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.072(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.9519(9)
_cell_length_b                   11.3413(6)
_cell_length_c                   18.325(1)
_cell_measurement_reflns_used    6709
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      24.79
_cell_measurement_theta_min      2.20
_cell_volume                     3309.1(3)
_computing_cell_refinement       'Bruker APEX2 (Bruker-AXS, 2006)'
_computing_data_collection       'Bruker APEX2 (Bruker-AXS, 2006)'
_computing_data_reduction        'Bruker SAINT+ (Bruker-AXS, 2006a)'
_computing_molecular_graphics    'Bruker APEX2 (Bruker-AXS, 2006)'
_computing_publication_material  'Bruker APEX2 (Bruker-AXS, 2006)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker Smart APEX CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0704
_diffrn_reflns_av_sigmaI/netI    0.0642
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            23110
_diffrn_reflns_theta_full        24.83
_diffrn_reflns_theta_max         24.83
_diffrn_reflns_theta_min         2.02
_exptl_absorpt_coefficient_mu    0.748
_exptl_absorpt_correction_T_max  0.9364
_exptl_absorpt_correction_T_min  0.9071
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'sadabs (Sheldrick, 2007)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.576
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1600
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.338
_refine_diff_density_min         -0.404
_refine_diff_density_rms         0.103
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     436
_refine_ls_number_reflns         5711
_refine_ls_number_restraints     27
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_all          0.0777
_refine_ls_R_factor_gt           0.0467
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0619P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1051
_refine_ls_wR_factor_ref         0.1197
_reflns_number_gt                4024
_reflns_number_total             5711
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            b815849e.txt
_cod_data_source_block           msb368_0m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7000746
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.68657(2) 0.66180(3) 0.01752(2) 0.02631(14) Uani 1 1 d . . .
Cl1 Cl 0.60681(7) 0.83857(11) -0.00126(8) 0.0340(3) Uani 1 1 d . . .
P1 P 0.80631(7) 0.72449(10) 0.01298(8) 0.0223(3) Uani 1 1 d . . .
P2 P 0.76656(7) 0.51440(11) 0.02234(8) 0.0261(3) Uani 1 1 d . . .
O1 O 0.81799(19) 0.8020(3) -0.05603(19) 0.0261(8) Uani 1 1 d . . .
O2 O 0.8829(2) 0.7026(3) -0.1515(2) 0.0351(9) Uani 1 1 d . . .
O3 O 0.87895(18) 0.7904(3) 0.08219(18) 0.0231(7) Uani 1 1 d . . .
O4 O 1.0217(2) 0.8972(3) 0.0931(2) 0.0335(8) Uani 1 1 d . . .
O5 O 0.7416(2) 0.4157(3) -0.0447(2) 0.0340(9) Uani 1 1 d . . .
O6 O 0.6394(2) 0.2479(3) -0.0376(2) 0.0439(10) Uani 1 1 d . . .
O7 O 0.8086(2) 0.4231(3) 0.0923(2) 0.0332(9) Uani 1 1 d . . .
O8 O 0.7378(7) 0.3351(10) 0.1847(7) 0.049(3) Uani 0.603(17) 1 d PDU A 1
O8A O 0.7579(12) 0.3092(15) 0.1986(11) 0.049(3) Uani 0.397(17) 1 d PDU A 2
N1 N 0.8488(2) 0.5896(3) 0.0118(2) 0.0217(9) Uani 1 1 d . . .
N2 N 0.5737(3) 0.5664(4) 0.0110(3) 0.0365(11) Uani 1 1 d . . .
C1 C 0.7673(3) 0.7951(4) -0.1342(3) 0.0268(11) Uani 1 1 d . . .
C2 C 0.6882(3) 0.8400(5) -0.1611(3) 0.0439(14) Uani 1 1 d . . .
H2 H 0.6634 0.8720 -0.1262 0.053 Uiso 1 1 calc R . .
C3 C 0.6438(4) 0.8381(6) -0.2415(4) 0.0590(18) Uani 1 1 d . . .
H3 H 0.5877 0.8666 -0.2611 0.071 Uiso 1 1 calc R . .
C4 C 0.6809(4) 0.7957(6) -0.2913(4) 0.0602(19) Uani 1 1 d . . .
H4 H 0.6514 0.7981 -0.3457 0.072 Uiso 1 1 calc R . .
C5 C 0.7607(4) 0.7495(5) -0.2636(3) 0.0479(15) Uani 1 1 d . . .
H5 H 0.7858 0.7193 -0.2988 0.057 Uiso 1 1 calc R . .
C6 C 0.8043(3) 0.7468(4) -0.1847(3) 0.0298(12) Uani 1 1 d . . .
C7 C 0.9218(4) 0.6482(6) -0.2009(4) 0.0560(17) Uani 1 1 d . . .
H7A H 0.8857 0.5848 -0.2307 0.084 Uiso 1 1 calc R . .
H7B H 0.9763 0.6153 -0.1691 0.084 Uiso 1 1 calc R . .
H7C H 0.9302 0.7070 -0.2366 0.084 Uiso 1 1 calc R . .
C8 C 0.8819(3) 0.9152(4) 0.0866(3) 0.0263(11) Uani 1 1 d . . .
C9 C 0.8125(3) 0.9799(5) 0.0856(3) 0.0366(13) Uani 1 1 d . . .
H9 H 0.7614 0.9415 0.0817 0.044 Uiso 1 1 calc R . .
C10 C 0.8186(4) 1.1029(5) 0.0905(3) 0.0450(15) Uani 1 1 d . . .
H10 H 0.7712 1.1489 0.0889 0.054 Uiso 1 1 calc R . .
C11 C 0.8928(4) 1.1563(5) 0.0974(3) 0.0431(15) Uani 1 1 d . . .
H11 H 0.8968 1.2398 0.1011 0.052 Uiso 1 1 calc R . .
C12 C 0.9624(4) 1.0911(5) 0.0990(3) 0.0396(14) Uani 1 1 d . . .
H12 H 1.0135 1.1301 0.1038 0.048 Uiso 1 1 calc R . .
C13 C 0.9578(3) 0.9692(4) 0.0937(3) 0.0270(11) Uani 1 1 d . . .
C14 C 1.1010(3) 0.9522(5) 0.1029(3) 0.0429(15) Uani 1 1 d . . .
H14A H 1.0930 1.0146 0.0640 0.064 Uiso 1 1 calc R . .
H14B H 1.1402 0.8932 0.0962 0.064 Uiso 1 1 calc R . .
H14C H 1.1239 0.9864 0.1550 0.064 Uiso 1 1 calc R . .
C15 C 0.9260(3) 0.5445(4) 0.0064(3) 0.0196(10) Uani 1 1 d . . .
C16 C 0.9940(3) 0.6197(4) 0.0160(3) 0.0231(11) Uani 1 1 d . . .
H16 H 0.9902 0.7010 0.0269 0.028 Uiso 1 1 calc R . .
C17 C 0.9331(3) 0.4259(4) -0.0095(3) 0.0251(11) Uani 1 1 d . . .
H17 H 0.8867 0.3749 -0.0160 0.030 Uiso 1 1 calc R . .
C18 C 0.6597(3) 0.4189(5) -0.1001(3) 0.0315(12) Uani 1 1 d . . .
C19 C 0.6336(4) 0.5051(5) -0.1552(3) 0.0431(14) Uani 1 1 d . . .
H19 H 0.6721 0.5642 -0.1582 0.052 Uiso 1 1 calc R . .
C20 C 0.5516(4) 0.5075(6) -0.2070(3) 0.0544(17) Uani 1 1 d . . .
H20 H 0.5330 0.5684 -0.2446 0.065 Uiso 1 1 calc R . .
C21 C 0.4979(4) 0.4185(6) -0.2020(4) 0.0528(17) Uani 1 1 d . . .
H21 H 0.4416 0.4188 -0.2370 0.063 Uiso 1 1 calc R . .
C22 C 0.5236(3) 0.3291(5) -0.1478(3) 0.0402(14) Uani 1 1 d . . .
H22 H 0.4854 0.2688 -0.1461 0.048 Uiso 1 1 calc R . .
C23 C 0.6068(3) 0.3277(5) -0.0950(3) 0.0363(13) Uani 1 1 d . . .
C24 C 0.5929(3) 0.1410(5) -0.0425(4) 0.0520(17) Uani 1 1 d . . .
H24A H 0.5389 0.1589 -0.0365 0.078 Uiso 1 1 calc R . .
H24B H 0.6249 0.0871 -0.0012 0.078 Uiso 1 1 calc R . .
H24C H 0.5831 0.1039 -0.0932 0.078 Uiso 1 1 calc R . .
C25 C 0.8426(3) 0.4570(4) 0.1713(3) 0.0341(13) Uani 1 1 d . A .
C26 C 0.9075(3) 0.5363(5) 0.1980(3) 0.0399(14) Uani 1 1 d . . .
H26 H 0.9283 0.5757 0.1626 0.048 Uiso 1 1 calc R . .
C27 C 0.9423(3) 0.5583(6) 0.2769(3) 0.0475(16) Uani 1 1 d . . .
H27 H 0.9872 0.6130 0.2954 0.057 Uiso 1 1 calc R . .
C28 C 0.9130(4) 0.5022(6) 0.3287(4) 0.0536(18) Uani 1 1 d . . .
H28 H 0.9373 0.5179 0.3827 0.064 Uiso 1 1 calc R . .
C29 C 0.8473(4) 0.4221(5) 0.3017(4) 0.0489(16) Uani 1 1 d . A .
H29 H 0.8273 0.3823 0.3375 0.059 Uiso 1 1 calc R . .
C30 C 0.8110(4) 0.4002(5) 0.2230(4) 0.0429(15) Uani 1 1 d D . .
C31 C 0.6994(10) 0.2763(13) 0.2345(9) 0.070(3) Uani 0.603(17) 1 d PDU A 1
H31A H 0.7425 0.2330 0.2753 0.104 Uiso 0.603(17) 1 calc PR A 1
H31B H 0.6564 0.2212 0.2035 0.104 Uiso 0.603(17) 1 calc PR A 1
H31C H 0.6734 0.3352 0.2582 0.104 Uiso 0.603(17) 1 calc PR A 1
C31A C 0.7439(16) 0.2372(18) 0.2584(13) 0.070(3) Uani 0.397(17) 1 d PDU A 2
H31D H 0.7970 0.2010 0.2904 0.104 Uiso 0.397(17) 1 calc PR A 2
H31E H 0.7030 0.1753 0.2340 0.104 Uiso 0.397(17) 1 calc PR A 2
H31F H 0.7223 0.2867 0.2911 0.104 Uiso 0.397(17) 1 calc PR A 2
C32 C 0.5742(3) 0.4693(5) 0.0546(3) 0.0350(13) Uani 1 1 d . . .
H32 H 0.6251 0.4457 0.0935 0.042 Uiso 1 1 calc R . .
C33 C 0.4978(3) 0.5956(5) -0.0435(3) 0.0365(13) Uani 1 1 d . . .
H33 H 0.4947 0.6634 -0.0749 0.044 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Rh1 N2 98.49(11) . . ?
P2 Rh1 P1 70.76(4) . . ?
N2 Rh1 P1 167.94(11) . . ?
P2 Rh1 Cl1 171.22(5) . . ?
N2 Rh1 Cl1 88.01(11) . . ?
P1 Rh1 Cl1 102.14(5) . . ?
O1 P1 O3 95.61(17) . . ?
O1 P1 N1 108.40(18) . . ?
O3 P1 N1 102.41(18) . . ?
O1 P1 Rh1 125.20(13) . . ?
O3 P1 Rh1 126.16(13) . . ?
N1 P1 Rh1 96.43(13) . . ?
O1 P1 P2 133.22(14) . . ?
O3 P1 P2 122.57(13) . . ?
N1 P1 P2 42.76(12) . . ?
Rh1 P1 P2 53.80(4) . . ?
O5 P2 O7 95.11(19) . . ?
O5 P2 N1 105.80(18) . . ?
O7 P2 N1 104.88(18) . . ?
O5 P2 Rh1 121.11(14) . . ?
O7 P2 Rh1 129.58(14) . . ?
N1 P2 Rh1 97.87(13) . . ?
O5 P2 P1 128.16(15) . . ?
O7 P2 P1 127.72(14) . . ?
N1 P2 P1 42.56(13) . . ?
Rh1 P2 P1 55.44(4) . . ?
C1 O1 P1 125.2(3) . . ?
C6 O2 C7 118.2(4) . . ?
C8 O3 P1 120.6(3) . . ?
C13 O4 C14 116.9(4) . . ?
C18 O5 P2 117.9(3) . . ?
C23 O6 C24 116.6(4) . . ?
C25 O7 P2 123.6(3) . . ?
C30 O8 C31 115.9(9) . . ?
C30 O8A C31A 116.5(14) . . ?
C15 N1 P1 136.2(3) . . ?
C15 N1 P2 129.1(3) . . ?
P1 N1 P2 94.68(18) . . ?
C32 N2 C33 116.1(4) . . ?
C32 N2 Rh1 123.0(3) . . ?
C33 N2 Rh1 120.7(4) . . ?
C2 C1 O1 122.3(5) . . ?
C2 C1 C6 121.2(5) . . ?
O1 C1 C6 116.3(4) . . ?
C1 C2 C3 118.8(6) . . ?
C1 C2 H2 120.6 . . ?
C3 C2 H2 120.6 . . ?
C4 C3 C2 120.2(6) . . ?
C4 C3 H3 119.9 . . ?
C2 C3 H3 119.9 . . ?
C3 C4 C5 120.7(6) . . ?
C3 C4 H4 119.7 . . ?
C5 C4 H4 119.7 . . ?
C4 C5 C6 120.0(6) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
O2 C6 C5 124.6(5) . . ?
O2 C6 C1 116.4(4) . . ?
C5 C6 C1 119.0(5) . . ?
O2 C7 H7A 109.5 . . ?
O2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
O2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 C13 121.6(5) . . ?
C9 C8 O3 121.2(4) . . ?
C13 C8 O3 117.3(4) . . ?
C8 C9 C10 119.1(5) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 H9 120.5 . . ?
C11 C10 C9 119.6(5) . . ?
C11 C10 H10 120.2 . . ?
C9 C10 H10 120.2 . . ?
C10 C11 C12 121.2(5) . . ?
C10 C11 H11 119.4 . . ?
C12 C11 H11 119.4 . . ?
C11 C12 C13 120.3(5) . . ?
C11 C12 H12 119.9 . . ?
C13 C12 H12 119.9 . . ?
O4 C13 C12 125.0(5) . . ?
O4 C13 C8 116.7(4) . . ?
C12 C13 C8 118.3(5) . . ?
O4 C14 H14A 109.5 . . ?
O4 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
O4 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C17 C15 C16 119.4(4) . . ?
C17 C15 N1 120.3(4) . . ?
C16 C15 N1 120.4(4) . . ?
C17 C16 C15 119.0(4) 3_765 . ?
C17 C16 H16 120.5 3_765 . ?
C15 C16 H16 120.5 . . ?
C16 C17 C15 121.6(4) 3_765 . ?
C16 C17 H17 119.2 3_765 . ?
C15 C17 H17 119.2 . . ?
C19 C18 C23 121.9(5) . . ?
C19 C18 O5 122.6(5) . . ?
C23 C18 O5 115.5(5) . . ?
C18 C19 C20 121.0(6) . . ?
C18 C19 H19 119.5 . . ?
C20 C19 H19 119.5 . . ?
C21 C20 C19 117.8(6) . . ?
C21 C20 H20 121.1 . . ?
C19 C20 H20 121.1 . . ?
C22 C21 C20 122.1(6) . . ?
C22 C21 H21 119.0 . . ?
C20 C21 H21 119.0 . . ?
C21 C22 C23 119.8(5) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 H22 120.1 . . ?
O6 C23 C18 116.6(5) . . ?
O6 C23 C22 125.9(5) . . ?
C18 C23 C22 117.4(5) . . ?
O6 C24 H24A 109.5 . . ?
O6 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
O6 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 C25 C30 120.4(6) . . ?
C26 C25 O7 122.6(5) . . ?
C30 C25 O7 116.9(5) . . ?
C25 C26 C27 119.5(5) . . ?
C25 C26 H26 120.2 . . ?
C27 C26 H26 120.2 . . ?
C28 C27 C26 120.9(6) . . ?
C28 C27 H27 119.6 . . ?
C26 C27 H27 119.6 . . ?
C27 C28 C29 119.6(6) . . ?
C27 C28 H28 120.2 . . ?
C29 C28 H28 120.2 . . ?
C30 C29 C28 120.3(6) . . ?
C30 C29 H29 119.8 . . ?
C28 C29 H29 119.8 . . ?
O8A C30 C29 119.6(9) . . ?
O8A C30 C25 119.9(10) . . ?
C29 C30 C25 119.2(6) . . ?
O8A C30 O8 18.9(11) . . ?
C29 C30 O8 128.0(7) . . ?
C25 C30 O8 112.4(7) . . ?
O8A C31A H31D 109.5 . . ?
O8A C31A H31E 109.5 . . ?
H31D C31A H31E 109.5 . . ?
O8A C31A H31F 109.5 . . ?
H31D C31A H31F 109.5 . . ?
H31E C31A H31F 109.5 . . ?
N2 C32 C33 121.3(5) . 3_665 ?
N2 C32 H32 119.4 . . ?
C33 C32 H32 119.4 3_665 . ?
N2 C33 C32 122.7(5) . 3_665 ?
N2 C33 H33 118.7 . . ?
C32 C33 H33 118.7 3_665 . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P2 2.1350(13) . ?
Rh1 N2 2.165(4) . ?
Rh1 P1 2.1790(12) . ?
Rh1 Cl1 2.3763(13) . ?
P1 O1 1.607(3) . ?
P1 O3 1.616(3) . ?
P1 N1 1.695(4) . ?
P1 P2 2.4980(17) . ?
P2 O5 1.608(3) . ?
P2 O7 1.611(4) . ?
P2 N1 1.702(4) . ?
O1 C1 1.397(6) . ?
O2 C6 1.356(6) . ?
O2 C7 1.429(6) . ?
O3 C8 1.418(5) . ?
O4 C13 1.360(6) . ?
O4 C14 1.437(5) . ?
O5 C18 1.412(6) . ?
O6 C23 1.353(6) . ?
O6 C24 1.432(6) . ?
O7 C25 1.415(6) . ?
O8 C30 1.406(10) . ?
O8 C31 1.451(11) . ?
O8A C30 1.341(13) . ?
O8A C31A 1.449(15) . ?
N1 C15 1.439(5) . ?
N2 C32 1.360(7) . ?
N2 C33 1.371(7) . ?
C1 C2 1.358(7) . ?
C1 C6 1.397(7) . ?
C2 C3 1.407(8) . ?
C2 H2 0.9500 . ?
C3 C4 1.362(9) . ?
C3 H3 0.9500 . ?
C4 C5 1.375(8) . ?
C4 H4 0.9500 . ?
C5 C6 1.380(7) . ?
C5 H5 0.9500 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 C9 1.380(7) . ?
C8 C13 1.390(6) . ?
C9 C10 1.399(7) . ?
C9 H9 0.9500 . ?
C10 C11 1.363(8) . ?
C10 H10 0.9500 . ?
C11 C12 1.384(8) . ?
C11 H11 0.9500 . ?
C12 C13 1.386(7) . ?
C12 H12 0.9500 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C17 1.391(6) . ?
C15 C16 1.395(6) . ?
C16 C17 1.382(6) 3_765 ?
C16 H16 0.9500 . ?
C17 C16 1.382(6) 3_765 ?
C17 H17 0.9500 . ?
C18 C19 1.365(7) . ?
C18 C23 1.392(7) . ?
C19 C20 1.388(8) . ?
C19 H19 0.9500 . ?
C20 C21 1.384(9) . ?
C20 H20 0.9500 . ?
C21 C22 1.381(8) . ?
C21 H21 0.9500 . ?
C22 C23 1.410(7) . ?
C22 H22 0.9500 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C26 1.374(7) . ?
C25 C30 1.397(7) . ?
C26 C27 1.384(8) . ?
C26 H26 0.9500 . ?
C27 C28 1.369(8) . ?
C27 H27 0.9500 . ?
C28 C29 1.389(8) . ?
C28 H28 0.9500 . ?
C29 C30 1.382(8) . ?
C29 H29 0.9500 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C31A H31D 0.9800 . ?
C31A H31E 0.9800 . ?
C31A H31F 0.9800 . ?
C32 C33 1.380(7) 3_665 ?
C32 H32 0.9500 . ?
C33 C32 1.380(7) 3_665 ?
C33 H33 0.9500 . ?
