#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:19:21 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179685 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/07/7000788.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7000788
loop_
_publ_author_name
'Liu, Fu-Chen'
'Zeng, Yong-Fei'
'Zhao, Jiong-Peng'
'Hu, Bo-Wen'
'Hu, Xin'
'Ribas, J.'
'Bu, Xian-He'
_publ_section_title
;
 Novel lanthanide--azido complexes: hydrothermal syntheses, structures
 and magnetic properties
;
_journal_issue                   12
_journal_name_full               'Dalton Transactions'
_journal_page_first              2074
_journal_page_last               2076
_journal_paper_doi               10.1039/b819955h
_journal_year                    2009
_chemical_formula_sum            'C18 H18 Eu2 N6 O10'
_chemical_formula_weight         782.30
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.094(2)
_cell_angle_beta                 104.365(2)
_cell_angle_gamma                98.055(2)
_cell_formula_units_Z            2
_cell_length_a                   8.1279(9)
_cell_length_b                   12.5922(13)
_cell_length_c                   12.6120(13)
_cell_measurement_reflns_used    2170
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.1607
_cell_measurement_theta_min      2.8203
_cell_volume                     1155.1(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker Smart APEX CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0649
_diffrn_reflns_av_sigmaI/netI    0.0850
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            6328
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.75
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    5.447
_exptl_absorpt_correction_T_max  0.2746
_exptl_absorpt_correction_T_min  0.2252
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR by T.Higashi 8 March, 1995'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.249
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             748
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.32
_refine_diff_density_max         1.837
_refine_diff_density_min         -1.179
_refine_diff_density_rms         0.192
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     377
_refine_ls_number_reflns         4209
_refine_ls_number_restraints     162
_refine_ls_restrained_S_all      1.003
_refine_ls_R_factor_all          0.0515
_refine_ls_R_factor_gt           0.0376
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0120P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0754
_refine_ls_wR_factor_ref         0.0801
_reflns_number_gt                3271
_reflns_number_total             4209
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b819955h.txt
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7000788
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.03883(4) 0.85786(3) 0.40691(3) 0.01438(12) Uani 1 1 d . . .
Eu2 Eu 0.42219(4) 1.13061(3) 0.58073(3) 0.01618(12) Uani 1 1 d . . .
O1 O 0.2036(7) 0.7849(5) 0.5385(5) 0.0298(14) Uani 1 1 d . B .
O2 O 0.4839(7) 0.8002(5) 0.5538(5) 0.0339(16) Uani 1 1 d . . .
O3 O 0.4998(7) 1.0861(5) 0.7533(5) 0.0268(14) Uani 1 1 d . . .
O4 O 0.4772(8) 1.2292(5) 0.9021(5) 0.0368(16) Uani 1 1 d . . .
O5 O 0.6429(7) 1.2978(5) 0.7043(6) 0.0403(18) Uani 1 1 d . A .
O6 O 0.9221(6) 1.3194(5) 0.7164(5) 0.0266(14) Uani 1 1 d . . .
O1W O -0.0057(6) 0.8804(5) 0.2166(5) 0.0242(14) Uani 1 1 d . . .
O7 O -0.2802(6) 0.7388(4) 0.2866(4) 0.0207(13) Uani 1 1 d . . .
O9 O 0.1599(6) 1.0198(4) 0.5876(4) 0.0162(12) Uani 1 1 d . . .
O10 O 0.3238(6) 0.9532(4) 0.4159(4) 0.0146(12) Uani 1 1 d . . .
N4 N -0.1570(8) 0.8242(6) 0.5282(6) 0.0227(16) Uani 1 1 d U . .
N5 N -0.1399(8) 0.7870(7) 0.6035(7) 0.0344(19) Uani 1 1 d U . .
N6 N -0.1241(12) 0.7492(10) 0.6772(9) 0.073(3) Uani 1 1 d U . .
N2 N 0.8152(6) 1.0092(5) 1.1041(5) 0.0360(18) Uani 1 1 d GU . .
C10 C 0.7514(7) 1.1037(5) 1.1442(4) 0.037(2) Uani 1 1 d GU . .
H10 H 0.7698 1.1389 1.2241 0.037 Uiso 1 1 calc R . .
C11 C 0.6606(7) 1.1464(5) 1.0667(4) 0.030(2) Uani 1 1 d GU . .
H11 H 0.6172 1.2106 1.0939 0.030 Uiso 1 1 calc R . .
C7 C 0.6336(6) 1.0946(5) 0.9491(4) 0.0229(18) Uani 1 1 d GU . .
C8 C 0.6973(7) 1.0001(5) 0.9091(5) 0.034(2) Uani 1 1 d GU . .
H8 H 0.6790 0.9649 0.8291 0.034 Uiso 1 1 calc R . .
C9 C 0.7882(7) 0.9574(5) 0.9866(5) 0.041(2) Uani 1 1 d GU . .
H9 H 0.8316 0.8932 0.9593 0.041 Uiso 1 1 calc R . .
C12 C 0.5258(10) 1.1405(7) 0.8614(8) 0.025(2) Uani 1 1 d . . .
N3 N 0.8905(15) 1.6758(10) 1.0161(10) 0.032(5) Uani 0.487(17) 1 d PGU A 1
C15 C 0.7892(17) 1.5823(11) 1.0185(11) 0.032(5) Uani 0.487(17) 1 d PGU A 1
H15 H 0.7397 1.5893 1.0786 0.032 Uiso 0.487(17) 1 calc PR A 1
C14 C 0.7598(16) 1.4787(10) 0.9334(11) 0.027(5) Uani 0.487(17) 1 d PGU A 1
H14 H 0.6901 1.4144 0.9350 0.027 Uiso 0.487(17) 1 calc PR A 1
C13 C 0.8316(14) 1.4686(9) 0.8459(9) 0.013(5) Uani 0.487(17) 1 d PGU A 1
C17 C 0.9330(17) 1.5621(10) 0.8436(11) 0.026(5) Uani 0.487(17) 1 d PGU A 1
H17 H 0.9824 1.5551 0.7834 0.026 Uiso 0.487(17) 1 calc PR A 1
C16 C 0.9624(18) 1.6657(10) 0.9287(12) 0.031(5) Uani 0.487(17) 1 d PGU A 1
H16 H 1.0321 1.7300 0.9271 0.031 Uiso 0.487(17) 1 calc PR A 1
N3A N 0.9167(17) 1.6881(11) 1.0086(10) 0.049(6) Uani 0.513(17) 1 d PGU A 2
C15A C 0.7479(15) 1.6224(12) 0.9603(13) 0.047(6) Uani 0.513(17) 1 d PGU A 2
H15A H 0.6589 1.6501 0.9857 0.047 Uiso 0.513(17) 1 calc PR A 2
C14A C 0.7108(11) 1.5155(10) 0.8744(11) 0.043(6) Uani 0.513(17) 1 d PGU A 2
H14A H 0.5966 1.4711 0.8418 0.043 Uiso 0.513(17) 1 calc PR A 2
C13A C 0.8424(8) 1.4745(5) 0.8368(5) 0.025(6) Uani 0.513(17) 1 d PGU A 2
C17A C 1.0112(12) 1.5402(8) 0.8851(10) 0.028(4) Uani 0.513(17) 1 d PGU A 2
H17A H 1.1002 1.5124 0.8597 0.028 Uiso 0.513(17) 1 calc PR A 2
C16A C 1.0483(16) 1.6470(9) 0.9709(12) 0.041(5) Uani 0.513(17) 1 d PGU A 2
H16A H 1.1624 1.6915 1.0036 0.041 Uiso 0.513(17) 1 calc PR A 2
C18 C 0.7992(9) 1.3538(7) 0.7460(6) 0.0203(19) Uani 1 1 d GU . .
N1 N 0.3318(18) 0.4566(11) 0.6546(12) 0.032(4) Uani 0.501(11) 1 d PGU B 1
C3 C 0.2033(19) 0.5156(14) 0.6634(12) 0.023(4) Uani 0.501(11) 1 d PGU B 1
H3 H 0.1129 0.4904 0.6893 0.023 Uiso 0.501(11) 1 calc PR B 1
C2 C 0.208(2) 0.6119(14) 0.6341(13) 0.023(5) Uani 0.501(11) 1 d PGU B 1
H2 H 0.1208 0.6519 0.6401 0.023 Uiso 0.501(11) 1 calc PR B 1
C1 C 0.3412(19) 0.6491(13) 0.5960(13) 0.014(4) Uani 0.501(11) 1 d PGU B 1
C4 C 0.4697(15) 0.5901(12) 0.5872(12) 0.038(5) Uani 0.501(11) 1 d PGU B 1
H4 H 0.5601 0.6154 0.5613 0.038 Uiso 0.501(11) 1 calc PR B 1
C5 C 0.4650(15) 0.4939(11) 0.6165(13) 0.039(5) Uani 0.501(11) 1 d PGU B 1
H5 H 0.5522 0.4538 0.6105 0.039 Uiso 0.501(11) 1 calc PR B 1
N1A N 0.318(2) 0.4739(13) 0.6895(13) 0.045(5) Uani 0.499(11) 1 d PGU B 2
C3A C 0.173(2) 0.4876(14) 0.6195(13) 0.040(6) Uani 0.499(11) 1 d PGU B 2
H3A H 0.0671 0.4348 0.5964 0.040 Uiso 0.499(11) 1 calc PR B 2
C2A C 0.183(2) 0.5781(15) 0.5833(14) 0.034(6) Uani 0.499(11) 1 d PGU B 2
H2A H 0.0830 0.5876 0.5353 0.034 Uiso 0.499(11) 1 calc PR B 2
C1A C 0.337(2) 0.6550(13) 0.6170(13) 0.031(6) Uani 0.499(11) 1 d PGU B 2
C4A C 0.4820(17) 0.6413(13) 0.6869(13) 0.042(5) Uani 0.499(11) 1 d PGU B 2
H4A H 0.5881 0.6941 0.7101 0.042 Uiso 0.499(11) 1 calc PR B 2
C5A C 0.4725(16) 0.5507(12) 0.7232(13) 0.052(5) Uani 0.499(11) 1 d PGU B 2
H5A H 0.5721 0.5413 0.7712 0.052 Uiso 0.499(11) 1 calc PR B 2
C6 C 0.3435(10) 0.7552(7) 0.5634(7) 0.0204(18) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O9 136.66(18) . 2_576 ?
O1 Eu1 O9 75.61(19) . . ?
O9 Eu1 O9 72.47(18) 2_576 . ?
O1 Eu1 O6 75.3(2) . 2_676 ?
O9 Eu1 O6 141.26(17) 2_576 2_676 ?
O9 Eu1 O6 146.26(17) . 2_676 ?
O1 Eu1 O10 83.12(18) . . ?
O9 Eu1 O10 112.36(17) 2_576 . ?
O9 Eu1 O10 70.86(15) . . ?
O6 Eu1 O10 89.06(16) 2_676 . ?
O1 Eu1 O1W 144.60(18) . . ?
O9 Eu1 O1W 78.27(17) 2_576 . ?
O9 Eu1 O1W 121.54(18) . . ?
O6 Eu1 O1W 76.44(19) 2_676 . ?
O10 Eu1 O1W 75.56(17) . . ?
O1 Eu1 N4 75.8(2) . . ?
O9 Eu1 N4 68.8(2) 2_576 . ?
O9 Eu1 N4 76.49(19) . . ?
O6 Eu1 N4 112.0(2) 2_676 . ?
O10 Eu1 N4 144.62(19) . . ?
O1W Eu1 N4 135.37(19) . . ?
O1 Eu1 O7 116.54(19) . . ?
O9 Eu1 O7 69.39(15) 2_576 . ?
O9 Eu1 O7 132.84(15) . . ?
O6 Eu1 O7 76.37(16) 2_676 . ?
O10 Eu1 O7 150.60(17) . . ?
O1W Eu1 O7 76.25(17) . . ?
N4 Eu1 O7 64.60(18) . . ?
O1 Eu1 Eu2 115.97(13) . 2_576 ?
O9 Eu1 Eu2 37.73(12) 2_576 2_576 ?
O9 Eu1 Eu2 90.67(11) . 2_576 ?
O6 Eu1 Eu2 117.38(12) 2_676 2_576 ?
O10 Eu1 Eu2 149.86(12) . 2_576 ?
O1W Eu1 Eu2 95.80(12) . 2_576 ?
N4 Eu1 Eu2 40.35(15) . 2_576 ?
O7 Eu1 Eu2 42.30(10) . 2_576 ?
O1 Eu1 Eu1 107.13(13) . 2_576 ?
O9 Eu1 Eu1 36.39(11) 2_576 2_576 ?
O9 Eu1 Eu1 36.09(11) . 2_576 ?
O6 Eu1 Eu1 177.54(14) 2_676 2_576 ?
O10 Eu1 Eu1 91.78(11) . 2_576 ?
O1W Eu1 Eu1 101.53(13) . 2_576 ?
N4 Eu1 Eu1 68.37(16) . 2_576 ?
O7 Eu1 Eu1 101.86(11) . 2_576 ?
Eu2 Eu1 Eu1 61.229(11) 2_576 2_576 ?
O1 Eu1 Eu2 82.17(14) . . ?
O9 Eu1 Eu2 88.66(11) 2_576 . ?
O9 Eu1 Eu2 35.95(12) . . ?
O6 Eu1 Eu2 122.55(12) 2_676 . ?
O10 Eu1 Eu2 35.59(11) . . ?
O1W Eu1 Eu2 95.67(12) . . ?
N4 Eu1 Eu2 112.30(15) . . ?
O7 Eu1 Eu2 157.64(12) . . ?
Eu2 Eu1 Eu2 120.023(12) 2_576 . ?
Eu1 Eu1 Eu2 58.793(12) 2_576 . ?
O1 Eu1 Eu2 62.97(13) . 2_676 ?
O9 Eu1 Eu2 139.59(12) 2_576 2_676 ?
O9 Eu1 Eu2 84.61(11) . 2_676 ?
O6 Eu1 Eu2 67.12(12) 2_676 2_676 ?
O10 Eu1 Eu2 27.25(12) . 2_676 ?
O1W Eu1 Eu2 86.59(12) . 2_676 ?
N4 Eu1 Eu2 137.82(15) . 2_676 ?
O7 Eu1 Eu2 142.42(11) . 2_676 ?
Eu2 Eu1 Eu2 175.278(14) 2_576 2_676 ?
Eu1 Eu1 Eu2 114.325(14) 2_576 2_676 ?
Eu2 Eu1 Eu2 55.558(11) . 2_676 ?
O2 Eu2 O5 77.0(2) 2_676 . ?
O2 Eu2 O3 147.81(19) 2_676 . ?
O5 Eu2 O3 80.4(2) . . ?
O2 Eu2 O10 82.39(19) 2_676 . ?
O5 Eu2 O10 149.92(18) . . ?
O3 Eu2 O10 107.80(19) . . ?
O2 Eu2 O9 138.11(18) 2_676 . ?
O5 Eu2 O9 137.96(19) . . ?
O3 Eu2 O9 72.97(18) . . ?
O10 Eu2 O9 70.89(15) . . ?
O2 Eu2 O10 82.66(19) 2_676 2_676 ?
O5 Eu2 O10 81.33(18) . 2_676 ?
O3 Eu2 O10 71.48(17) . 2_676 ?
O10 Eu2 O10 74.47(16) . 2_676 ?
O9 Eu2 O10 118.44(17) . 2_676 ?
O2 Eu2 N4 76.2(2) 2_676 2_576 ?
O5 Eu2 N4 112.4(2) . 2_576 ?
O3 Eu2 N4 134.3(2) . 2_576 ?
O10 Eu2 N4 83.01(19) . 2_576 ?
O9 Eu2 N4 69.2(2) . 2_576 ?
O10 Eu2 N4 150.89(19) 2_676 2_576 ?
O2 Eu2 O7 116.5(2) 2_676 2_576 ?
O5 Eu2 O7 73.42(18) . 2_576 ?
O3 Eu2 O7 77.71(18) . 2_576 ?
O10 Eu2 O7 136.17(15) . 2_576 ?
O9 Eu2 O7 69.58(16) . 2_576 ?
O10 Eu2 O7 142.85(16) 2_676 2_576 ?
N4 Eu2 O7 65.89(19) 2_576 2_576 ?
O2 Eu2 Eu1 117.27(14) 2_676 2_576 ?
O5 Eu2 Eu1 115.63(14) . 2_576 ?
O3 Eu2 Eu1 93.08(13) . 2_576 ?
O10 Eu2 Eu1 93.20(10) . 2_576 ?
O9 Eu2 Eu1 37.12(12) . 2_576 ?
O10 Eu2 Eu1 155.46(12) 2_676 2_576 ?
N4 Eu2 Eu1 41.37(15) 2_576 2_576 ?
O7 Eu2 Eu1 43.09(11) 2_576 2_576 ?
O2 Eu2 Eu2 80.60(15) 2_676 2_676 ?
O5 Eu2 Eu2 116.27(14) . 2_676 ?
O3 Eu2 Eu2 89.35(13) . 2_676 ?
O10 Eu2 Eu2 37.66(11) . 2_676 ?
O9 Eu2 Eu2 95.65(11) . 2_676 ?
O10 Eu2 Eu2 36.81(10) 2_676 2_676 ?
N4 Eu2 Eu2 118.58(15) 2_576 2_676 ?
O7 Eu2 Eu2 162.57(13) 2_576 2_676 ?
Eu1 Eu2 Eu2 127.704(15) 2_576 2_676 ?
O2 Eu2 Eu1 109.05(14) 2_676 . ?
O5 Eu2 Eu1 173.56(16) . . ?
O3 Eu2 Eu1 94.89(13) . . ?
O10 Eu2 Eu1 35.88(11) . . ?
O9 Eu2 Eu1 35.67(11) . . ?
O10 Eu2 Eu1 101.40(11) 2_676 . ?
N4 Eu2 Eu1 67.83(16) 2_576 . ?
O7 Eu2 Eu1 101.40(11) 2_576 . ?
Eu1 Eu2 Eu1 59.977(12) 2_576 . ?
Eu2 Eu2 Eu1 67.761(13) 2_676 . ?
O2 Eu2 Eu1 63.88(14) 2_676 2_676 ?
O5 Eu2 Eu1 59.81(14) . 2_676 ?
O3 Eu2 Eu1 85.01(13) . 2_676 ?
O10 Eu2 Eu1 91.49(10) . 2_676 ?
O9 Eu2 Eu1 145.19(12) . 2_676 ?
O10 Eu2 Eu1 26.89(11) 2_676 2_676 ?
N4 Eu2 Eu1 140.07(16) 2_576 2_676 ?
O7 Eu2 Eu1 132.19(11) 2_576 2_676 ?
Eu1 Eu2 Eu1 175.278(14) 2_576 2_676 ?
Eu2 Eu2 Eu1 56.681(11) 2_676 2_676 ?
Eu1 Eu2 Eu1 124.442(11) . 2_676 ?
C6 O1 Eu1 142.0(5) . . ?
C6 O2 Eu2 138.1(5) . 2_676 ?
C12 O3 Eu2 134.8(6) . . ?
C18 O5 Eu2 152.0(5) . . ?
C18 O6 Eu1 136.1(5) . 2_676 ?
Eu2 O7 Eu1 94.62(15) 2_576 . ?
Eu1 O9 Eu1 107.53(18) 2_576 . ?
Eu1 O9 Eu2 105.1(2) 2_576 . ?
Eu1 O9 Eu2 108.38(18) . . ?
Eu2 O10 Eu1 108.53(18) . . ?
Eu2 O10 Eu2 105.53(16) . 2_676 ?
Eu1 O10 Eu2 125.9(2) . 2_676 ?
N5 N4 Eu2 129.0(5) . 2_576 ?
N5 N4 Eu1 132.2(6) . . ?
Eu2 N4 Eu1 98.3(2) 2_576 . ?
N6 N5 N4 179.3(11) . . ?
C9 N2 C10 120.0 . . ?
C11 C10 N2 120.0 . . ?
C11 C10 H10 120.0 . . ?
N2 C10 H10 120.0 . . ?
C7 C11 C10 120.0 . . ?
C7 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C8 C7 C11 120.0 . . ?
C8 C7 C12 120.0(5) . . ?
C11 C7 C12 119.9(5) . . ?
C7 C8 C9 120.0 . . ?
C7 C8 H8 120.0 . . ?
C9 C8 H8 120.0 . . ?
C8 C9 N2 120.0 . . ?
C8 C9 H9 120.0 . . ?
N2 C9 H9 120.0 . . ?
O4 C12 O3 125.5(8) . . ?
O4 C12 C7 117.6(7) . . ?
O3 C12 C7 116.9(7) . . ?
C15 N3 C16 120.0 . . ?
N3 C15 C14 120.0 . . ?
N3 C15 H15 120.0 . . ?
C14 C15 H15 120.0 . . ?
C13 C14 C15 120.0 . . ?
C13 C14 H14 120.0 . . ?
C15 C14 H14 120.0 . . ?
C17 C13 C14 120.0 . . ?
C17 C13 C18 117.9(8) . . ?
C14 C13 C18 122.1(8) . . ?
C13 C17 C16 120.0 . . ?
C13 C17 H17 120.0 . . ?
C16 C17 H17 120.0 . . ?
C17 C16 N3 120.0 . . ?
C17 C16 H16 120.0 . . ?
N3 C16 H16 120.0 . . ?
C15A N3A C16A 120.0 . . ?
C14A C15A N3A 120.0 . . ?
C14A C15A H15A 120.0 . . ?
N3A C15A H15A 120.0 . . ?
C15A C14A C13A 120.0 . . ?
C15A C14A H14A 120.0 . . ?
C13A C14A H14A 120.0 . . ?
C17A C13A C14A 120.0 . . ?
C17A C13A C18 121.0 . . ?
C14A C13A C18 118.9 . . ?
C13A C17A C16A 120.0 . . ?
C13A C17A H17A 120.0 . . ?
C16A C17A H17A 120.0 . . ?
C17A C16A N3A 120.0 . . ?
C17A C16A H16A 120.0 . . ?
N3A C16A H16A 120.0 . . ?
O6 C18 O5 124.8(7) . . ?
O6 C18 C13A 116.8(5) . . ?
O5 C18 C13A 118.4(5) . . ?
O6 C18 C13 120.8(7) . . ?
O5 C18 C13 114.3(7) . . ?
C13A C18 C13 7.0(5) . . ?
C3 N1 C5 120.0 . . ?
C2 C3 N1 120.0 . . ?
C2 C3 H3 120.0 . . ?
N1 C3 H3 120.0 . . ?
C1 C2 C3 120.0 . . ?
C1 C2 H2 120.0 . . ?
C3 C2 H2 120.0 . . ?
C4 C1 C2 120.0 . . ?
C4 C1 C6 120.8(10) . . ?
C2 C1 C6 119.2(10) . . ?
C5 C4 C1 120.0 . . ?
C5 C4 H4 120.0 . . ?
C1 C4 H4 120.0 . . ?
C4 C5 N1 120.0 . . ?
C4 C5 H5 120.0 . . ?
N1 C5 H5 120.0 . . ?
C3A N1A C5A 120.0 . . ?
N1A C3A C2A 120.0 . . ?
N1A C3A H3A 120.0 . . ?
C2A C3A H3A 120.0 . . ?
C1A C2A C3A 120.0 . . ?
C1A C2A H2A 120.0 . . ?
C3A C2A H2A 120.0 . . ?
C2A C1A C4A 120.0 . . ?
C2A C1A C6 117.7(10) . . ?
C4A C1A C6 122.1(10) . . ?
C5A C4A C1A 120.0 . . ?
C5A C4A H4A 120.0 . . ?
C1A C4A H4A 120.0 . . ?
C4A C5A N1A 120.0 . . ?
C4A C5A H5A 120.0 . . ?
N1A C5A H5A 120.0 . . ?
O1 C6 O2 125.0(8) . . ?
O1 C6 C1 118.0(8) . . ?
O2 C6 C1 116.7(9) . . ?
O1 C6 C1A 114.8(9) . . ?
O2 C6 C1A 120.1(9) . . ?
C1 C6 C1A 9.1(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.362(6) . ?
Eu1 O9 2.382(5) 2_576 ?
Eu1 O9 2.399(4) . ?
Eu1 O6 2.406(5) 2_676 ?
Eu1 O10 2.414(4) . ?
Eu1 O1W 2.448(6) . ?
Eu1 N4 2.544(6) . ?
Eu1 O7 2.611(5) . ?
Eu1 Eu2 3.8098(6) 2_576 ?
Eu1 Eu1 3.8567(8) 2_576 ?
Eu1 Eu2 3.9045(6) . ?
Eu1 Eu2 4.3250(7) 2_676 ?
Eu2 O2 2.365(6) 2_676 ?
Eu2 O5 2.366(5) . ?
Eu2 O3 2.372(6) . ?
Eu2 O10 2.396(4) . ?
Eu2 O9 2.415(5) . ?
Eu2 O10 2.444(5) 2_676 ?
Eu2 N4 2.493(7) 2_576 ?
Eu2 O7 2.572(5) 2_576 ?
Eu2 Eu1 3.8098(6) 2_576 ?
Eu2 Eu2 3.8534(8) 2_676 ?
Eu2 Eu1 4.3250(7) 2_676 ?
O1 C6 1.244(9) . ?
O2 C6 1.253(9) . ?
O2 Eu2 2.365(6) 2_676 ?
O3 C12 1.268(9) . ?
O4 C12 1.239(10) . ?
O5 C18 1.255(8) . ?
O6 C18 1.237(8) . ?
O6 Eu1 2.406(5) 2_676 ?
O7 Eu2 2.572(5) 2_576 ?
O9 Eu1 2.382(5) 2_576 ?
O10 Eu2 2.444(5) 2_676 ?
N4 N5 1.171(10) . ?
N4 Eu2 2.493(7) 2_576 ?
N5 N6 1.158(12) . ?
N2 C9 1.367(3) . ?
N2 C10 1.367(3) . ?
C10 C11 1.367(3) . ?
C10 H10 0.9300 . ?
C11 C7 1.367(3) . ?
C11 H11 0.9300 . ?
C7 C8 1.367(3) . ?
C7 C12 1.544(10) . ?
C8 C9 1.367(3) . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?
N3 C15 1.352(7) . ?
N3 C16 1.352(7) . ?
C15 C14 1.352(7) . ?
C15 H15 0.9300 . ?
C14 C13 1.352(7) . ?
C14 H14 0.9300 . ?
C13 C17 1.352(7) . ?
C13 C18 1.531(13) . ?
C17 C16 1.352(7) . ?
C17 H17 0.9300 . ?
C16 H16 0.9300 . ?
N3A C15A 1.376(5) . ?
N3A C16A 1.376(5) . ?
C15A C14A 1.376(5) . ?
C15A H15A 0.9300 . ?
C14A C13A 1.376(5) . ?
C14A H14A 0.9300 . ?
C13A C17A 1.376(5) . ?
C13A C18 1.521(5) . ?
C17A C16A 1.376(5) . ?
C17A H17A 0.9300 . ?
C16A H16A 0.9300 . ?
N1 C3 1.371(9) . ?
N1 C5 1.371(9) . ?
C3 C2 1.371(9) . ?
C3 H3 0.9300 . ?
C2 C1 1.371(9) . ?
C2 H2 0.9300 . ?
C1 C4 1.371(9) . ?
C1 C6 1.513(17) . ?
C4 C5 1.371(9) . ?
C4 H4 0.9300 . ?
C5 H5 0.9300 . ?
N1A C3A 1.353(10) . ?
N1A C5A 1.353(10) . ?
C3A C2A 1.353(10) . ?
C3A H3A 0.9300 . ?
C2A C1A 1.353(10) . ?
C2A H2A 0.9300 . ?
C1A C4A 1.353(10) . ?
C1A C6 1.607(18) . ?
C4A C5A 1.353(10) . ?
C4A H4A 0.9300 . ?
C5A H5A 0.9300 . ?
