#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:31:00 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179688 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/10/7001056.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001056
loop_
_publ_author_name
'Hoshino, Manabu'
'Uekusa, Hidehiro'
'Sonoda, Shintaro'
'Otsuka, Takuhiro'
'Kaizu, Youkoh'
_publ_section_title
;
 Photocrystallographic analysis of [AuCl(PPh3)2] for elucidation of the
 crystal packing effect on the photophysical properties
;
_journal_issue                   16
_journal_name_full               'Dalton Transactions'
_journal_page_first              3085
_journal_page_last               3091
_journal_paper_doi               10.1039/b820066a
_journal_year                    2009
_chemical_formula_sum            'C36 H30 Au Cl P2'
_chemical_formula_weight         756.96
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.0306(11)
_cell_angle_beta                 95.5779(9)
_cell_angle_gamma                109.6278(10)
_cell_formula_units_Z            2
_cell_length_a                   10.8497(2)
_cell_length_b                   11.8235(2)
_cell_length_c                   14.1665(2)
_cell_measurement_temperature    137(2)
_cell_volume                     1519.50(5)
_computing_cell_refinement       'HKL Research, Inc. HKL-2000'
_computing_data_collection       'Rigaku RAPID AUTO'
_computing_data_reduction        'HKL Research, Inc. HKL-2000'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR2002 (Giacovazzo, 2003)'
_diffrn_ambient_temperature      137(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode Ultrax18'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.022
_diffrn_reflns_av_sigmaI/netI    0.0162
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            45386
_diffrn_reflns_theta_full        32.34
_diffrn_reflns_theta_max         32.34
_diffrn_reflns_theta_min         2.05
_exptl_absorpt_coefficient_mu    5.058
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.738
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'HKL SCALEPACK (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.654
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             744
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.853
_refine_diff_density_min         -0.578
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.112
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     451
_refine_ls_number_reflns         10769
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.112
_refine_ls_R_factor_all          0.0140
_refine_ls_R_factor_gt           0.0139
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+1.6342P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0375
_refine_ls_wR_factor_ref         0.0380
_reflns_number_gt                10717
_reflns_number_total             10769
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b820066a.txt
_cod_data_source_block           137Kon
_cod_original_cell_volume        1519.50(4)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7001056
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.211000(5) 0.246275(5) 0.275608(4) 0.01571(2) Uani 1 1 d . . .
P1 P 0.30576(4) 0.09706(4) 0.27608(3) 0.01475(6) Uani 1 1 d . . .
C111 C 0.25492(14) 0.00378(14) 0.35129(11) 0.0158(2) Uani 1 1 d . . .
C112 C 0.34078(15) -0.04268(16) 0.38966(13) 0.0209(3) Uani 1 1 d . . .
H112 H 0.432(2) -0.020(2) 0.3786(18) 0.025 Uiso 1 1 d . . .
C113 C 0.29947(17) -0.11494(17) 0.44648(14) 0.0234(3) Uani 1 1 d . . .
H113 H 0.356(2) -0.147(2) 0.4712(19) 0.028 Uiso 1 1 d . . .
C114 C 0.17258(17) -0.14008(16) 0.46623(13) 0.0225(3) Uani 1 1 d . . .
H114 H 0.143(2) -0.192(2) 0.5027(19) 0.027 Uiso 1 1 d . . .
C115 C 0.08678(16) -0.09399(15) 0.42845(13) 0.0216(3) Uani 1 1 d . . .
H115 H 0.000(2) -0.110(2) 0.4443(18) 0.026 Uiso 1 1 d . . .
C116 C 0.12764(14) -0.02144(14) 0.37170(12) 0.0181(2) Uani 1 1 d . . .
H116 H 0.068(2) 0.013(2) 0.3509(17) 0.022 Uiso 1 1 d . . .
C121 C 0.28868(14) -0.02666(15) 0.14317(11) 0.0182(2) Uani 1 1 d . . .
C122 C 0.2774(2) -0.15563(17) 0.11976(14) 0.0319(4) Uani 1 1 d . . .
H122 H 0.273(3) -0.184(3) 0.175(2) 0.038 Uiso 1 1 d . . .
C123 C 0.2714(3) -0.24378(19) 0.01753(16) 0.0413(5) Uani 1 1 d . . .
H123 H 0.259(3) -0.333(3) 0.004(2) 0.050 Uiso 1 1 d . . .
C124 C 0.2752(2) -0.2041(2) -0.06195(15) 0.0364(4) Uani 1 1 d . . .
H124 H 0.269(3) -0.264(3) -0.131(2) 0.044 Uiso 1 1 d . . .
C125 C 0.2857(3) -0.0762(2) -0.03932(16) 0.0401(5) Uani 1 1 d . . .
H125 H 0.289(3) -0.045(3) -0.093(2) 0.048 Uiso 1 1 d . . .
C126 C 0.2917(2) 0.0121(2) 0.06233(14) 0.0317(4) Uani 1 1 d . . .
H126 H 0.300(3) 0.100(3) 0.077(2) 0.038 Uiso 1 1 d . . .
C131 C 0.48740(14) 0.19068(14) 0.33272(11) 0.0163(2) Uani 1 1 d . . .
C132 C 0.58230(15) 0.15019(17) 0.28560(13) 0.0224(3) Uani 1 1 d . . .
H132 H 0.551(2) 0.070(2) 0.2205(19) 0.027 Uiso 1 1 d . . .
C133 C 0.72057(16) 0.22857(19) 0.33291(14) 0.0263(3) Uani 1 1 d . . .
H133 H 0.788(2) 0.201(2) 0.301(2) 0.032 Uiso 1 1 d . . .
C134 C 0.76430(16) 0.34736(18) 0.42613(13) 0.0253(3) Uani 1 1 d . . .
H134 H 0.860(2) 0.401(2) 0.4588(19) 0.030 Uiso 1 1 d . . .
C135 C 0.67017(17) 0.38779(17) 0.47342(13) 0.0251(3) Uani 1 1 d . . .
H135 H 0.696(2) 0.470(2) 0.5344(19) 0.030 Uiso 1 1 d . . .
C136 C 0.53246(16) 0.30991(16) 0.42735(12) 0.0220(3) Uani 1 1 d . . .
H136 H 0.468(2) 0.338(2) 0.4596(19) 0.026 Uiso 1 1 d . . .
P2 P 0.23062(4) 0.39131(4) 0.20067(3) 0.01611(6) Uani 1 1 d . . .
C211 C 0.39804(14) 0.52983(15) 0.26086(11) 0.0178(2) Uani 1 1 d . . .
C212 C 0.50565(17) 0.50501(19) 0.29669(16) 0.0275(3) Uani 1 1 d . . .
H212 H 0.490(2) 0.418(3) 0.287(2) 0.033 Uiso 1 1 d . . .
C213 C 0.63389(17) 0.6087(2) 0.34836(16) 0.0314(4) Uani 1 1 d . . .
H213 H 0.708(3) 0.593(3) 0.376(2) 0.038 Uiso 1 1 d . . .
C214 C 0.65628(17) 0.73730(19) 0.36331(14) 0.0298(3) Uani 1 1 d . . .
H214 H 0.741(3) 0.806(3) 0.399(2) 0.036 Uiso 1 1 d . . .
C215 C 0.55107(18) 0.76292(17) 0.32684(16) 0.0296(3) Uani 1 1 d . . .
H215 H 0.566(3) 0.850(3) 0.339(2) 0.036 Uiso 1 1 d . . .
C216 C 0.42169(16) 0.65998(16) 0.27628(14) 0.0250(3) Uani 1 1 d . . .
H216 H 0.349(2) 0.680(2) 0.2535(19) 0.030 Uiso 1 1 d . . .
C221 C 0.11052(14) 0.46864(14) 0.20682(12) 0.0176(2) Uani 1 1 d . . .
C222 C 0.09248(17) 0.52514(17) 0.13955(13) 0.0242(3) Uani 1 1 d . . .
H222 H 0.143(2) 0.522(2) 0.0881(19) 0.029 Uiso 1 1 d . . .
C223 C 0.00343(18) 0.58820(18) 0.14972(14) 0.0267(3) Uani 1 1 d . . .
H223 H -0.006(2) 0.627(2) 0.104(2) 0.032 Uiso 1 1 d . . .
C224 C -0.06895(18) 0.59310(17) 0.22573(14) 0.0263(3) Uani 1 1 d . . .
H224 H -0.129(2) 0.635(2) 0.232(2) 0.032 Uiso 1 1 d . . .
C225 C -0.05189(18) 0.53635(18) 0.29236(14) 0.0262(3) Uani 1 1 d . . .
H225 H -0.102(2) 0.543(2) 0.346(2) 0.031 Uiso 1 1 d . . .
C226 C 0.03740(16) 0.47387(16) 0.28286(13) 0.0212(3) Uani 1 1 d . . .
H226 H 0.050(2) 0.435(2) 0.3272(18) 0.025 Uiso 1 1 d . . .
C231 C 0.22010(15) 0.30829(15) 0.05951(12) 0.0200(2) Uani 1 1 d . . .
C232 C 0.3236(2) 0.3508(2) 0.01523(16) 0.0403(5) Uani 1 1 d . . .
H232 H 0.402(3) 0.425(3) 0.055(2) 0.048 Uiso 1 1 d . . .
C233 C 0.3128(3) 0.2778(3) -0.09175(17) 0.0540(7) Uani 1 1 d . . .
H233 H 0.384(3) 0.302(3) -0.121(3) 0.065 Uiso 1 1 d . . .
C234 C 0.1993(2) 0.1612(2) -0.15517(15) 0.0395(5) Uani 1 1 d . . .
H234 H 0.195(3) 0.110(3) -0.228(2) 0.047 Uiso 1 1 d . . .
C235 C 0.0950(2) 0.1188(2) -0.11174(15) 0.0353(4) Uani 1 1 d . . .
H235 H 0.016(3) 0.037(3) -0.153(2) 0.042 Uiso 1 1 d . . .
C236 C 0.10500(18) 0.1918(2) -0.00480(14) 0.0299(3) Uani 1 1 d . . .
H236 H 0.033(3) 0.161(3) 0.025(2) 0.036 Uiso 1 1 d . . .
Cl1 Cl 0.06793(4) 0.26637(4) 0.40842(3) 0.02492(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Au1 P1 136.790(13) . . ?
P2 Au1 Cl1 114.168(13) . . ?
P1 Au1 Cl1 108.688(12) . . ?
P2 Au1 Au1 80.318(9) . 2 ?
P1 Au1 Au1 89.267(9) . 2 ?
Cl1 Au1 Au1 111.591(10) . 2 ?
C111 P1 C131 104.00(6) . . ?
C111 P1 C121 106.10(7) . . ?
C131 P1 C121 104.18(7) . . ?
C111 P1 Au1 119.50(5) . . ?
C131 P1 Au1 108.47(5) . . ?
C121 P1 Au1 113.19(5) . . ?
C112 C111 C116 119.37(13) . . ?
C112 C111 P1 121.27(11) . . ?
C116 C111 P1 119.36(11) . . ?
C113 C112 C111 120.38(14) . . ?
C113 C112 H112 120.7(14) . . ?
C111 C112 H112 118.9(14) . . ?
C114 C113 C112 119.97(14) . . ?
C114 C113 H113 119.3(15) . . ?
C112 C113 H113 120.7(15) . . ?
C115 C114 C113 119.95(14) . . ?
C115 C114 H114 119.6(14) . . ?
C113 C114 H114 120.4(14) . . ?
C114 C115 C116 120.34(14) . . ?
C114 C115 H115 119.4(14) . . ?
C116 C115 H115 120.2(14) . . ?
C115 C116 C111 119.98(14) . . ?
C115 C116 H116 117.8(13) . . ?
C111 C116 H116 122.1(13) . . ?
C122 C121 C126 118.66(15) . . ?
C122 C121 P1 123.19(12) . . ?
C126 C121 P1 118.12(12) . . ?
C121 C122 C123 120.58(17) . . ?
C121 C122 H122 119.5(16) . . ?
C123 C122 H122 120.0(16) . . ?
C124 C123 C122 120.29(19) . . ?
C124 C123 H123 121.7(18) . . ?
C122 C123 H123 117.9(18) . . ?
C125 C124 C123 119.42(17) . . ?
C125 C124 H124 120.3(18) . . ?
C123 C124 H124 120.3(18) . . ?
C124 C125 C126 120.60(18) . . ?
C124 C125 H125 121.6(17) . . ?
C126 C125 H125 117.8(17) . . ?
C125 C126 C121 120.45(17) . . ?
C125 C126 H126 119.6(16) . . ?
C121 C126 H126 119.9(16) . . ?
C132 C131 C136 119.41(13) . . ?
C132 C131 P1 123.17(11) . . ?
C136 C131 P1 117.42(11) . . ?
C133 C132 C131 119.97(15) . . ?
C133 C132 H132 120.9(14) . . ?
C131 C132 H132 119.1(14) . . ?
C134 C133 C132 120.22(15) . . ?
C134 C133 H133 119.2(15) . . ?
C132 C133 H133 120.6(14) . . ?
C133 C134 C135 119.98(15) . . ?
C133 C134 H134 120.0(14) . . ?
C135 C134 H134 120.0(15) . . ?
C136 C135 C134 120.18(15) . . ?
C136 C135 H135 117.2(15) . . ?
C134 C135 H135 122.5(15) . . ?
C135 C136 C131 120.24(15) . . ?
C135 C136 H136 120.0(14) . . ?
C131 C136 H136 119.7(14) . . ?
C221 P2 C211 105.86(7) . . ?
C221 P2 C231 104.36(7) . . ?
C211 P2 C231 105.51(7) . . ?
C221 P2 Au1 119.52(5) . . ?
C211 P2 Au1 109.50(5) . . ?
C231 P2 Au1 111.09(5) . . ?
C212 C211 C216 118.89(14) . . ?
C212 C211 P2 118.14(12) . . ?
C216 C211 P2 122.92(11) . . ?
C213 C212 C211 120.49(17) . . ?
C213 C212 H212 120.4(15) . . ?
C211 C212 H212 119.1(15) . . ?
C214 C213 C212 120.19(17) . . ?
C214 C213 H213 118.5(16) . . ?
C212 C213 H213 121.3(16) . . ?
C215 C214 C213 119.93(16) . . ?
C215 C214 H214 120.2(17) . . ?
C213 C214 H214 119.9(17) . . ?
C214 C215 C216 120.29(17) . . ?
C214 C215 H215 119.8(16) . . ?
C216 C215 H215 119.8(16) . . ?
C215 C216 C211 120.19(16) . . ?
C215 C216 H216 119.4(14) . . ?
C211 C216 H216 120.4(14) . . ?
C226 C221 C222 119.61(14) . . ?
C226 C221 P2 118.57(11) . . ?
C222 C221 P2 121.80(12) . . ?
C223 C222 C221 119.99(15) . . ?
C223 C222 H222 121.0(15) . . ?
C221 C222 H222 119.0(15) . . ?
C224 C223 C222 120.05(15) . . ?
C224 C223 H223 121.7(15) . . ?
C222 C223 H223 118.3(15) . . ?
C225 C224 C223 120.14(15) . . ?
C225 C224 H224 120.2(16) . . ?
C223 C224 H224 119.6(15) . . ?
C224 C225 C226 120.02(16) . . ?
C224 C225 H225 118.9(15) . . ?
C226 C225 H225 121.1(15) . . ?
C225 C226 C221 120.19(14) . . ?
C225 C226 H226 121.2(14) . . ?
C221 C226 H226 118.6(14) . . ?
C232 C231 C236 118.91(15) . . ?
C232 C231 P2 123.38(13) . . ?
C236 C231 P2 117.58(12) . . ?
C231 C232 C233 120.52(18) . . ?
C231 C232 H232 121.3(18) . . ?
C233 C232 H232 118.1(18) . . ?
C234 C233 C232 120.5(2) . . ?
C234 C233 H233 118(2) . . ?
C232 C233 H233 121(2) . . ?
C233 C234 C235 119.29(18) . . ?
C233 C234 H234 119.6(17) . . ?
C235 C234 H234 121.1(17) . . ?
C234 C235 C236 120.44(18) . . ?
C234 C235 H235 121.4(17) . . ?
C236 C235 H235 118.1(17) . . ?
C231 C236 C235 120.31(17) . . ?
C231 C236 H236 119.5(15) . . ?
C235 C236 H236 120.2(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P2 2.3100(4) . ?
Au1 P1 2.3230(4) . ?
Au1 Cl1 2.5439(4) . ?
Au1 Au1 7.44377(19) 2 ?
P1 C111 1.8112(14) . ?
P1 C131 1.8124(14) . ?
P1 C121 1.8206(15) . ?
C111 C112 1.394(2) . ?
C111 C116 1.3958(19) . ?
C112 C113 1.389(2) . ?
C112 H112 0.98(2) . ?
C113 C114 1.388(2) . ?
C113 H113 0.93(2) . ?
C114 C115 1.386(2) . ?
C114 H114 0.94(2) . ?
C115 C116 1.390(2) . ?
C115 H115 0.97(2) . ?
C116 H116 0.95(2) . ?
C121 C122 1.386(2) . ?
C121 C126 1.389(2) . ?
C122 C123 1.394(3) . ?
C122 H122 0.96(3) . ?
C123 C124 1.378(3) . ?
C123 H123 0.96(3) . ?
C124 C125 1.378(3) . ?
C124 H124 0.93(3) . ?
C125 C126 1.389(3) . ?
C125 H125 0.96(3) . ?
C126 H126 0.94(3) . ?
C131 C132 1.396(2) . ?
C131 C136 1.398(2) . ?
C132 C133 1.394(2) . ?
C132 H132 0.95(2) . ?
C133 C134 1.386(2) . ?
C133 H133 0.98(2) . ?
C134 C135 1.390(3) . ?
C134 H134 0.96(2) . ?
C135 C136 1.386(2) . ?
C135 H135 0.94(2) . ?
C136 H136 0.96(2) . ?
P2 C221 1.8170(15) . ?
P2 C211 1.8212(15) . ?
P2 C231 1.8220(15) . ?
C211 C212 1.392(2) . ?
C211 C216 1.394(2) . ?
C212 C213 1.389(2) . ?
C212 H212 0.93(3) . ?
C213 C214 1.380(3) . ?
C213 H213 0.96(3) . ?
C214 C215 1.379(3) . ?
C214 H214 0.92(3) . ?
C215 C216 1.393(2) . ?
C215 H215 0.93(3) . ?
C216 H216 0.96(2) . ?
C221 C226 1.393(2) . ?
C221 C222 1.394(2) . ?
C222 C223 1.392(2) . ?
C222 H222 0.95(2) . ?
C223 C224 1.388(3) . ?
C223 H223 0.94(3) . ?
C224 C225 1.386(2) . ?
C224 H224 0.93(2) . ?
C225 C226 1.390(2) . ?
C225 H225 0.98(2) . ?
C226 H226 0.94(2) . ?
C231 C232 1.382(2) . ?
C231 C236 1.389(2) . ?
C232 C233 1.389(3) . ?
C232 H232 0.91(3) . ?
C233 C234 1.378(3) . ?
C233 H233 0.93(3) . ?
C234 C235 1.381(3) . ?
C234 H234 0.96(3) . ?
C235 C236 1.391(3) . ?
C235 H235 0.96(3) . ?
C236 H236 0.96(3) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C114 H114 Cl1 0.94(2) 2.77(2) 3.5426(16) 140.0(18) 2_556
C116 H116 Cl1 0.95(2) 2.78(2) 3.5259(15) 136.0(16) .
C226 H226 Cl1 0.94(2) 2.71(2) 3.6246(16) 165.6(18) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Au1 P1 C111 179.62(5) . . . . ?
Cl1 Au1 P1 C111 7.18(6) . . . . ?
Au1 Au1 P1 C111 -105.41(5) 2 . . . ?
P2 Au1 P1 C131 60.80(5) . . . . ?
Cl1 Au1 P1 C131 -111.63(5) . . . . ?
Au1 Au1 P1 C131 135.78(5) 2 . . . ?
P2 Au1 P1 C121 -54.28(5) . . . . ?
Cl1 Au1 P1 C121 133.28(5) . . . . ?
Au1 Au1 P1 C121 20.69(5) 2 . . . ?
C131 P1 C111 C112 -32.96(14) . . . . ?
C121 P1 C111 C112 76.60(13) . . . . ?
Au1 P1 C111 C112 -154.03(11) . . . . ?
C131 P1 C111 C116 146.70(12) . . . . ?
C121 P1 C111 C116 -103.75(12) . . . . ?
Au1 P1 C111 C116 25.62(13) . . . . ?
C116 C111 C112 C113 0.8(2) . . . . ?
P1 C111 C112 C113 -179.50(13) . . . . ?
C111 C112 C113 C114 -0.6(3) . . . . ?
C112 C113 C114 C115 0.5(3) . . . . ?
C113 C114 C115 C116 -0.6(2) . . . . ?
C114 C115 C116 C111 0.8(2) . . . . ?
C112 C111 C116 C115 -0.9(2) . . . . ?
P1 C111 C116 C115 179.40(12) . . . . ?
C111 P1 C121 C122 -16.38(17) . . . . ?
C131 P1 C121 C122 93.05(16) . . . . ?
Au1 P1 C121 C122 -149.33(14) . . . . ?
C111 P1 C121 C126 165.81(14) . . . . ?
C131 P1 C121 C126 -84.77(15) . . . . ?
Au1 P1 C121 C126 32.86(15) . . . . ?
C126 C121 C122 C123 1.0(3) . . . . ?
P1 C121 C122 C123 -176.79(17) . . . . ?
C121 C122 C123 C124 -0.7(4) . . . . ?
C122 C123 C124 C125 0.3(4) . . . . ?
C123 C124 C125 C126 -0.4(4) . . . . ?
C124 C125 C126 C121 0.8(4) . . . . ?
C122 C121 C126 C125 -1.1(3) . . . . ?
P1 C121 C126 C125 176.85(18) . . . . ?
C111 P1 C131 C132 99.94(13) . . . . ?
C121 P1 C131 C132 -11.02(15) . . . . ?
Au1 P1 C131 C132 -131.86(12) . . . . ?
C111 P1 C131 C136 -81.03(13) . . . . ?
C121 P1 C131 C136 168.00(12) . . . . ?
Au1 P1 C131 C136 47.17(12) . . . . ?
C136 C131 C132 C133 -0.1(2) . . . . ?
P1 C131 C132 C133 178.95(13) . . . . ?
C131 C132 C133 C134 -0.6(3) . . . . ?
C132 C133 C134 C135 0.8(3) . . . . ?
C133 C134 C135 C136 -0.3(3) . . . . ?
C134 C135 C136 C131 -0.4(2) . . . . ?
C132 C131 C136 C135 0.6(2) . . . . ?
P1 C131 C136 C135 -178.50(13) . . . . ?
P1 Au1 P2 C221 169.72(5) . . . . ?
Cl1 Au1 P2 C221 -18.14(6) . . . . ?
Au1 Au1 P2 C221 91.29(6) 2 . . . ?
P1 Au1 P2 C211 -68.02(5) . . . . ?
Cl1 Au1 P2 C211 104.12(5) . . . . ?
Au1 Au1 P2 C211 -146.45(5) 2 . . . ?
P1 Au1 P2 C231 48.12(6) . . . . ?
Cl1 Au1 P2 C231 -139.73(5) . . . . ?
Au1 Au1 P2 C231 -30.31(5) 2 . . . ?
C221 P2 C211 C212 160.57(13) . . . . ?
C231 P2 C211 C212 -89.16(14) . . . . ?
Au1 P2 C211 C212 30.47(14) . . . . ?
C221 P2 C211 C216 -16.81(15) . . . . ?
C231 P2 C211 C216 93.46(14) . . . . ?
Au1 P2 C211 C216 -146.91(12) . . . . ?
C216 C211 C212 C213 1.0(3) . . . . ?
P2 C211 C212 C213 -176.51(14) . . . . ?
C211 C212 C213 C214 -0.9(3) . . . . ?
C212 C213 C214 C215 0.0(3) . . . . ?
C213 C214 C215 C216 0.9(3) . . . . ?
C214 C215 C216 C211 -0.9(3) . . . . ?
C212 C211 C216 C215 -0.1(3) . . . . ?
P2 C211 C216 C215 177.29(14) . . . . ?
C211 P2 C221 C226 -104.21(13) . . . . ?
C231 P2 C221 C226 144.71(12) . . . . ?
Au1 P2 C221 C226 19.82(14) . . . . ?
C211 P2 C221 C222 74.24(14) . . . . ?
C231 P2 C221 C222 -36.84(15) . . . . ?
Au1 P2 C221 C222 -161.73(11) . . . . ?
C226 C221 C222 C223 1.0(2) . . . . ?
P2 C221 C222 C223 -177.41(13) . . . . ?
C221 C222 C223 C224 -1.0(3) . . . . ?
C222 C223 C224 C225 0.6(3) . . . . ?
C223 C224 C225 C226 -0.3(3) . . . . ?
C224 C225 C226 C221 0.3(3) . . . . ?
C222 C221 C226 C225 -0.7(2) . . . . ?
P2 C221 C226 C225 177.78(13) . . . . ?
C221 P2 C231 C232 110.83(18) . . . . ?
C211 P2 C231 C232 -0.50(19) . . . . ?
Au1 P2 C231 C232 -119.08(17) . . . . ?
C221 P2 C231 C236 -73.19(15) . . . . ?
C211 P2 C231 C236 175.47(14) . . . . ?
Au1 P2 C231 C236 56.89(15) . . . . ?
C236 C231 C232 C233 -0.2(4) . . . . ?
P2 C231 C232 C233 175.7(2) . . . . ?
C231 C232 C233 C234 -0.6(5) . . . . ?
C232 C233 C234 C235 1.2(5) . . . . ?
C233 C234 C235 C236 -0.9(4) . . . . ?
C232 C231 C236 C235 0.5(3) . . . . ?
P2 C231 C236 C235 -175.64(16) . . . . ?
C234 C235 C236 C231 0.0(3) . . . . ?
