#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:31:00 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179688 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/10/7001058.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001058
loop_
_publ_author_name
'Hoshino, Manabu'
'Uekusa, Hidehiro'
'Sonoda, Shintaro'
'Otsuka, Takuhiro'
'Kaizu, Youkoh'
_publ_section_title
;
 Photocrystallographic analysis of [AuCl(PPh3)2] for elucidation of the
 crystal packing effect on the photophysical properties
;
_journal_issue                   16
_journal_name_full               'Dalton Transactions'
_journal_page_first              3085
_journal_page_last               3091
_journal_paper_doi               10.1039/b820066a
_journal_year                    2009
_chemical_formula_sum            'C36 H30 Au Cl P2'
_chemical_formula_weight         756.96
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.9509(10)
_cell_angle_beta                 95.6325(8)
_cell_angle_gamma                109.6808(9)
_cell_formula_units_Z            2
_cell_length_a                   10.8346(2)
_cell_length_b                   11.82020(10)
_cell_length_c                   14.1569(2)
_cell_measurement_temperature    118(2)
_cell_volume                     1515.93(4)
_computing_cell_refinement       'HKL Research, Inc. HKL-2000'
_computing_data_collection       'Rigaku RAPID AUTO'
_computing_data_reduction        'HKL Research, Inc. HKL-2000'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR2002 (Giacovazzo, 2003)'
_diffrn_ambient_temperature      118(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku ratating anode Ultrax18'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.022
_diffrn_reflns_av_sigmaI/netI    0.0162
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            43837
_diffrn_reflns_theta_full        32.35
_diffrn_reflns_theta_max         32.35
_diffrn_reflns_theta_min         2.05
_exptl_absorpt_coefficient_mu    5.070
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.721
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'HKL SCALEPACK (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.658
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             744
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.664
_refine_diff_density_min         -0.549
_refine_diff_density_rms         0.077
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     451
_refine_ls_number_reflns         10750
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.110
_refine_ls_R_factor_all          0.0137
_refine_ls_R_factor_gt           0.0136
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0076P)²+1.4889P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0373
_refine_ls_wR_factor_ref         0.0373
_reflns_number_gt                10713
_reflns_number_total             10750
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b820066a.txt
_cod_data_source_block           118Kon
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7001058
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.210819(5) 0.247068(5) 0.275786(4) 0.01352(2) Uani 1 1 d . . .
P1 P 0.30533(3) 0.09759(3) 0.27596(3) 0.01293(6) Uani 1 1 d . . .
C111 C 0.25421(13) 0.00383(13) 0.35099(10) 0.0137(2) Uani 1 1 d . . .
C112 C 0.34071(15) -0.04244(15) 0.38962(12) 0.0185(2) Uani 1 1 d . . .
H112 H 0.431(2) -0.023(2) 0.3765(18) 0.022 Uiso 1 1 d . . .
C113 C 0.29933(15) -0.11504(16) 0.44646(13) 0.0204(3) Uani 1 1 d . . .
H113 H 0.357(2) -0.145(2) 0.4732(18) 0.024 Uiso 1 1 d . . .
C114 C 0.17209(16) -0.14044(15) 0.46595(12) 0.0198(2) Uani 1 1 d . . .
H114 H 0.143(2) -0.193(2) 0.5028(18) 0.024 Uiso 1 1 d . . .
C115 C 0.08603(15) -0.09415(15) 0.42821(12) 0.0191(2) Uani 1 1 d . . .
H115 H -0.001(2) -0.111(2) 0.4443(18) 0.023 Uiso 1 1 d . . .
C116 C 0.12700(13) -0.02141(14) 0.37152(11) 0.0155(2) Uani 1 1 d . . .
H116 H 0.067(2) 0.011(2) 0.3503(17) 0.019 Uiso 1 1 d . . .
C121 C 0.28780(14) -0.02601(14) 0.14288(11) 0.0160(2) Uani 1 1 d . . .
C122 C 0.2758(2) -0.15552(16) 0.11946(13) 0.0280(3) Uani 1 1 d . . .
H122 H 0.271(3) -0.183(3) 0.173(2) 0.034 Uiso 1 1 d . . .
C123 C 0.2694(2) -0.24324(18) 0.01691(15) 0.0357(4) Uani 1 1 d . . .
H123 H 0.262(3) -0.334(3) 0.002(2) 0.043 Uiso 1 1 d . . .
C124 C 0.2741(2) -0.20298(19) -0.06233(14) 0.0312(4) Uani 1 1 d . . .
H124 H 0.269(3) -0.266(3) -0.131(2) 0.037 Uiso 1 1 d . . .
C125 C 0.2852(2) -0.0748(2) -0.03972(14) 0.0350(4) Uani 1 1 d . . .
H125 H 0.286(3) -0.047(3) -0.094(2) 0.042 Uiso 1 1 d . . .
C126 C 0.2915(2) 0.01372(18) 0.06234(13) 0.0276(3) Uani 1 1 d . . .
H126 H 0.300(3) 0.101(3) 0.077(2) 0.033 Uiso 1 1 d . . .
C131 C 0.48735(13) 0.19105(13) 0.33263(11) 0.0145(2) Uani 1 1 d . . .
C132 C 0.58186(14) 0.15016(15) 0.28530(12) 0.0195(2) Uani 1 1 d . . .
H132 H 0.551(2) 0.068(2) 0.2197(18) 0.023 Uiso 1 1 d . . .
C133 C 0.72037(15) 0.22817(17) 0.33262(13) 0.0224(3) Uani 1 1 d . . .
H133 H 0.786(2) 0.201(2) 0.3028(19) 0.027 Uiso 1 1 d . . .
C134 C 0.76453(15) 0.34696(16) 0.42612(12) 0.0218(3) Uani 1 1 d . . .
H134 H 0.859(2) 0.399(2) 0.4589(18) 0.026 Uiso 1 1 d . . .
C135 C 0.67071(16) 0.38771(15) 0.47366(12) 0.0218(3) Uani 1 1 d . . .
H135 H 0.697(2) 0.472(2) 0.5344(19) 0.026 Uiso 1 1 d . . .
C136 C 0.53264(15) 0.31010(15) 0.42743(11) 0.0188(2) Uani 1 1 d . . .
H136 H 0.470(2) 0.340(2) 0.4597(18) 0.023 Uiso 1 1 d . . .
P2 P 0.23015(3) 0.39242(3) 0.20091(3) 0.01398(6) Uani 1 1 d . . .
C211 C 0.39766(13) 0.53104(14) 0.26108(11) 0.0160(2) Uani 1 1 d . . .
C212 C 0.50553(16) 0.50672(17) 0.29763(14) 0.0236(3) Uani 1 1 d . . .
H212 H 0.491(2) 0.424(2) 0.2898(19) 0.028 Uiso 1 1 d . . .
C213 C 0.63405(16) 0.6104(2) 0.34931(15) 0.0277(3) Uani 1 1 d . . .
H213 H 0.709(3) 0.596(3) 0.377(2) 0.033 Uiso 1 1 d . . .
C214 C 0.65634(16) 0.73911(17) 0.36376(13) 0.0255(3) Uani 1 1 d . . .
H214 H 0.741(2) 0.807(2) 0.3986(19) 0.031 Uiso 1 1 d . . .
C215 C 0.55108(17) 0.76417(16) 0.32657(14) 0.0264(3) Uani 1 1 d . . .
H215 H 0.566(3) 0.853(3) 0.337(2) 0.032 Uiso 1 1 d . . .
C216 C 0.42154(15) 0.66097(15) 0.27615(13) 0.0217(3) Uani 1 1 d . . .
H216 H 0.350(2) 0.682(2) 0.2535(18) 0.026 Uiso 1 1 d . . .
C221 C 0.10984(13) 0.46934(14) 0.20705(11) 0.0155(2) Uani 1 1 d . . .
C222 C 0.09154(16) 0.52626(16) 0.13991(12) 0.0211(3) Uani 1 1 d . . .
H222 H 0.142(2) 0.519(2) 0.0854(18) 0.025 Uiso 1 1 d . . .
C223 C 0.00204(17) 0.58861(17) 0.14976(13) 0.0234(3) Uani 1 1 d . . .
H223 H -0.009(2) 0.628(2) 0.1058(19) 0.028 Uiso 1 1 d . . .
C224 C -0.07059(16) 0.59311(16) 0.22572(13) 0.0228(3) Uani 1 1 d . . .
H224 H -0.131(2) 0.638(2) 0.2324(19) 0.027 Uiso 1 1 d . . .
C225 C -0.05333(17) 0.53604(17) 0.29233(13) 0.0231(3) Uani 1 1 d . . .
H225 H -0.103(2) 0.540(2) 0.3456(19) 0.028 Uiso 1 1 d . . .
C226 C 0.03640(15) 0.47402(15) 0.28310(12) 0.0182(2) Uani 1 1 d . . .
H226 H 0.048(2) 0.433(2) 0.3270(17) 0.022 Uiso 1 1 d . . .
C231 C 0.21946(15) 0.30946(15) 0.05985(11) 0.0177(2) Uani 1 1 d . . .
C232 C 0.3233(2) 0.3525(2) 0.01564(14) 0.0345(4) Uani 1 1 d . . .
H232 H 0.401(3) 0.431(3) 0.056(2) 0.041 Uiso 1 1 d . . .
C233 C 0.3124(2) 0.2791(3) -0.09179(16) 0.0459(6) Uani 1 1 d . . .
H233 H 0.387(3) 0.306(3) -0.120(2) 0.055 Uiso 1 1 d . . .
C234 C 0.1986(2) 0.1622(2) -0.15511(14) 0.0341(4) Uani 1 1 d . . .
H234 H 0.194(3) 0.110(3) -0.229(2) 0.041 Uiso 1 1 d . . .
C235 C 0.09446(19) 0.1191(2) -0.11152(14) 0.0304(3) Uani 1 1 d . . .
H235 H 0.018(3) 0.039(3) -0.153(2) 0.036 Uiso 1 1 d . . .
C236 C 0.10432(17) 0.19260(18) -0.00457(13) 0.0257(3) Uani 1 1 d . . .
H236 H 0.032(3) 0.162(2) 0.025(2) 0.031 Uiso 1 1 d . . .
Cl1 Cl 0.06807(4) 0.26679(4) 0.40884(3) 0.02136(6) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Au1 P1 136.881(12) . . ?
P2 Au1 Cl1 114.177(12) . . ?
P1 Au1 Cl1 108.598(12) . . ?
P2 Au1 Au1 80.487(9) . 2 ?
P1 Au1 Au1 88.904(8) . 2 ?
Cl1 Au1 Au1 111.797(9) . 2 ?
C111 P1 C131 104.01(6) . . ?
C111 P1 C121 106.04(6) . . ?
C131 P1 C121 104.22(6) . . ?
C111 P1 Au1 119.51(4) . . ?
C131 P1 Au1 108.46(4) . . ?
C121 P1 Au1 113.20(5) . . ?
C116 C111 C112 119.40(12) . . ?
C116 C111 P1 119.44(10) . . ?
C112 C111 P1 121.16(10) . . ?
C113 C112 C111 120.33(13) . . ?
C113 C112 H112 120.4(13) . . ?
C111 C112 H112 119.3(13) . . ?
C114 C113 C112 119.86(13) . . ?
C114 C113 H113 119.5(14) . . ?
C112 C113 H113 120.6(14) . . ?
C113 C114 C115 120.04(13) . . ?
C113 C114 H114 119.6(14) . . ?
C115 C114 H114 120.3(14) . . ?
C114 C115 C116 120.30(13) . . ?
C114 C115 H115 118.7(14) . . ?
C116 C115 H115 121.0(14) . . ?
C115 C116 C111 120.05(13) . . ?
C115 C116 H116 117.0(13) . . ?
C111 C116 H116 122.9(13) . . ?
C122 C121 C126 119.01(14) . . ?
C122 C121 P1 123.04(11) . . ?
C126 C121 P1 117.90(11) . . ?
C121 C122 C123 120.20(16) . . ?
C121 C122 H122 119.1(16) . . ?
C123 C122 H122 120.7(16) . . ?
C124 C123 C122 120.52(17) . . ?
C124 C123 H123 120.2(17) . . ?
C122 C123 H123 119.2(17) . . ?
C123 C124 C125 119.54(16) . . ?
C123 C124 H124 118.3(16) . . ?
C125 C124 H124 122.2(16) . . ?
C124 C125 C126 120.50(17) . . ?
C124 C125 H125 120.3(17) . . ?
C126 C125 H125 119.2(17) . . ?
C121 C126 C125 120.23(16) . . ?
C121 C126 H126 120.3(16) . . ?
C125 C126 H126 119.5(16) . . ?
C132 C131 C136 119.63(13) . . ?
C132 C131 P1 122.99(11) . . ?
C136 C131 P1 117.38(10) . . ?
C133 C132 C131 119.84(14) . . ?
C133 C132 H132 120.5(13) . . ?
C131 C132 H132 119.7(13) . . ?
C134 C133 C132 120.19(14) . . ?
C134 C133 H133 118.7(14) . . ?
C132 C133 H133 121.1(14) . . ?
C133 C134 C135 120.12(14) . . ?
C133 C134 H134 120.0(14) . . ?
C135 C134 H134 119.9(14) . . ?
C136 C135 C134 120.03(14) . . ?
C136 C135 H135 117.1(14) . . ?
C134 C135 H135 122.6(14) . . ?
C135 C136 C131 120.19(14) . . ?
C135 C136 H136 119.4(14) . . ?
C131 C136 H136 120.4(14) . . ?
C221 P2 C211 105.87(6) . . ?
C221 P2 C231 104.42(7) . . ?
C211 P2 C231 105.55(6) . . ?
C221 P2 Au1 119.54(5) . . ?
C211 P2 Au1 109.52(5) . . ?
C231 P2 Au1 110.97(5) . . ?
C216 C211 C212 118.72(13) . . ?
C216 C211 P2 123.03(11) . . ?
C212 C211 P2 118.19(11) . . ?
C213 C212 C211 120.69(15) . . ?
C213 C212 H212 119.7(15) . . ?
C211 C212 H212 119.6(16) . . ?
C214 C213 C212 119.96(16) . . ?
C214 C213 H213 118.1(15) . . ?
C212 C213 H213 121.9(15) . . ?
C215 C214 C213 119.97(15) . . ?
C215 C214 H214 121.0(16) . . ?
C213 C214 H214 119.0(16) . . ?
C214 C215 C216 120.25(16) . . ?
C214 C215 H215 120.2(15) . . ?
C216 C215 H215 119.6(15) . . ?
C211 C216 C215 120.39(15) . . ?
C211 C216 H216 121.2(14) . . ?
C215 C216 H216 118.4(14) . . ?
C226 C221 C222 119.53(13) . . ?
C226 C221 P2 118.55(10) . . ?
C222 C221 P2 121.90(11) . . ?
C223 C222 C221 120.13(14) . . ?
C223 C222 H222 121.8(14) . . ?
C221 C222 H222 118.0(14) . . ?
C224 C223 C222 120.05(14) . . ?
C224 C223 H223 120.0(15) . . ?
C222 C223 H223 120.0(15) . . ?
C225 C224 C223 120.07(14) . . ?
C225 C224 H224 120.7(14) . . ?
C223 C224 H224 119.2(14) . . ?
C224 C225 C226 120.13(15) . . ?
C224 C225 H225 119.9(15) . . ?
C226 C225 H225 119.9(15) . . ?
C225 C226 C221 120.09(13) . . ?
C225 C226 H226 121.2(13) . . ?
C221 C226 H226 118.7(13) . . ?
C232 C231 C236 118.93(14) . . ?
C232 C231 P2 123.26(12) . . ?
C236 C231 P2 117.69(11) . . ?
C231 C232 C233 120.38(17) . . ?
C231 C232 H232 121.0(17) . . ?
C233 C232 H232 118.7(17) . . ?
C234 C233 C232 120.46(18) . . ?
C234 C233 H233 119.5(19) . . ?
C232 C233 H233 119.8(19) . . ?
C233 C234 C235 119.39(17) . . ?
C233 C234 H234 119.6(16) . . ?
C235 C234 H234 121.0(16) . . ?
C234 C235 C236 120.39(16) . . ?
C234 C235 H235 120.3(16) . . ?
C236 C235 H235 119.2(16) . . ?
C231 C236 C235 120.44(15) . . ?
C231 C236 H236 119.7(15) . . ?
C235 C236 H236 119.9(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P2 2.3110(3) . ?
Au1 P1 2.3221(3) . ?
Au1 Cl1 2.5431(3) . ?
Au1 Au1 7.44406(17) 2 ?
P1 C111 1.8121(13) . ?
P1 C131 1.8122(13) . ?
P1 C121 1.8210(14) . ?
C111 C116 1.3937(18) . ?
C111 C112 1.3979(19) . ?
C112 C113 1.391(2) . ?
C112 H112 0.98(2) . ?
C113 C114 1.388(2) . ?
C113 H113 0.93(2) . ?
C114 C115 1.389(2) . ?
C114 H114 0.95(2) . ?
C115 C116 1.3897(19) . ?
C115 H115 0.96(2) . ?
C116 H116 0.94(2) . ?
C121 C122 1.390(2) . ?
C121 C126 1.391(2) . ?
C122 C123 1.395(2) . ?
C122 H122 0.93(3) . ?
C123 C124 1.378(3) . ?
C123 H123 0.98(3) . ?
C124 C125 1.380(3) . ?
C124 H124 0.95(3) . ?
C125 C126 1.393(2) . ?
C125 H125 0.94(3) . ?
C126 H126 0.94(3) . ?
C131 C132 1.3952(19) . ?
C131 C136 1.3981(19) . ?
C132 C133 1.393(2) . ?
C132 H132 0.97(2) . ?
C133 C134 1.388(2) . ?
C133 H133 0.94(2) . ?
C134 C135 1.389(2) . ?
C134 H134 0.95(2) . ?
C135 C136 1.387(2) . ?
C135 H135 0.96(2) . ?
C136 H136 0.95(2) . ?
P2 C221 1.8145(14) . ?
P2 C211 1.8191(14) . ?
P2 C231 1.8204(14) . ?
C211 C216 1.392(2) . ?
C211 C212 1.393(2) . ?
C212 C213 1.388(2) . ?
C212 H212 0.89(2) . ?
C213 C214 1.384(3) . ?
C213 H213 0.96(3) . ?
C214 C215 1.377(3) . ?
C214 H214 0.91(2) . ?
C215 C216 1.392(2) . ?
C215 H215 0.96(3) . ?
C216 H216 0.95(2) . ?
C221 C226 1.3952(19) . ?
C221 C222 1.3954(19) . ?
C222 C223 1.390(2) . ?
C222 H222 0.98(2) . ?
C223 C224 1.389(2) . ?
C223 H223 0.93(2) . ?
C224 C225 1.388(2) . ?
C224 H224 0.96(2) . ?
C225 C226 1.389(2) . ?
C225 H225 0.96(2) . ?
C226 H226 0.95(2) . ?
C231 C232 1.385(2) . ?
C231 C236 1.389(2) . ?
C232 C233 1.395(3) . ?
C232 H232 0.93(3) . ?
C233 C234 1.379(3) . ?
C233 H233 0.95(3) . ?
C234 C235 1.381(3) . ?
C234 H234 0.97(3) . ?
C235 C236 1.392(2) . ?
C235 H235 0.93(3) . ?
C236 H236 0.95(2) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C114 H114 Cl1 0.95(2) 2.76(2) 3.5348(15) 139.0(18) 2_556
C116 H116 Cl1 0.94(2) 2.81(2) 3.5242(14) 134.5(16) .
C226 H226 Cl1 0.95(2) 2.70(2) 3.6240(15) 166.7(18) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Au1 P1 C111 179.81(5) . . . . ?
Cl1 Au1 P1 C111 7.27(5) . . . . ?
Au1 Au1 P1 C111 -105.40(5) 2 . . . ?
P2 Au1 P1 C131 60.98(5) . . . . ?
Cl1 Au1 P1 C131 -111.56(5) . . . . ?
Au1 Au1 P1 C131 135.77(5) 2 . . . ?
P2 Au1 P1 C121 -54.17(5) . . . . ?
Cl1 Au1 P1 C121 133.29(5) . . . . ?
Au1 Au1 P1 C121 20.62(5) 2 . . . ?
C131 P1 C111 C116 146.65(11) . . . . ?
C121 P1 C111 C116 -103.76(11) . . . . ?
Au1 P1 C111 C116 25.57(13) . . . . ?
C131 P1 C111 C112 -32.68(13) . . . . ?
C121 P1 C111 C112 76.91(13) . . . . ?
Au1 P1 C111 C112 -153.76(10) . . . . ?
C116 C111 C112 C113 1.1(2) . . . . ?
P1 C111 C112 C113 -179.57(12) . . . . ?
C111 C112 C113 C114 -0.7(2) . . . . ?
C112 C113 C114 C115 0.4(2) . . . . ?
C113 C114 C115 C116 -0.5(2) . . . . ?
C114 C115 C116 C111 0.9(2) . . . . ?
C112 C111 C116 C115 -1.2(2) . . . . ?
P1 C111 C116 C115 179.47(11) . . . . ?
C111 P1 C121 C122 -16.20(15) . . . . ?
C131 P1 C121 C122 93.24(15) . . . . ?
Au1 P1 C121 C122 -149.11(13) . . . . ?
C111 P1 C121 C126 166.10(13) . . . . ?
C131 P1 C121 C126 -84.46(14) . . . . ?
Au1 P1 C121 C126 33.19(14) . . . . ?
C126 C121 C122 C123 0.9(3) . . . . ?
P1 C121 C122 C123 -176.82(16) . . . . ?
C121 C122 C123 C124 -0.4(3) . . . . ?
C122 C123 C124 C125 0.0(3) . . . . ?
C123 C124 C125 C126 0.0(3) . . . . ?
C122 C121 C126 C125 -0.9(3) . . . . ?
P1 C121 C126 C125 176.89(16) . . . . ?
C124 C125 C126 C121 0.5(3) . . . . ?
C111 P1 C131 C132 99.81(13) . . . . ?
C121 P1 C131 C132 -11.12(14) . . . . ?
Au1 P1 C131 C132 -131.99(11) . . . . ?
C111 P1 C131 C136 -81.02(12) . . . . ?
C121 P1 C131 C136 168.06(11) . . . . ?
Au1 P1 C131 C136 47.19(12) . . . . ?
C136 C131 C132 C133 -0.1(2) . . . . ?
P1 C131 C132 C133 179.05(12) . . . . ?
C131 C132 C133 C134 -0.6(2) . . . . ?
C132 C133 C134 C135 0.8(2) . . . . ?
C133 C134 C135 C136 -0.4(2) . . . . ?
C134 C135 C136 C131 -0.3(2) . . . . ?
C132 C131 C136 C135 0.6(2) . . . . ?
P1 C131 C136 C135 -178.64(12) . . . . ?
P1 Au1 P2 C221 169.49(5) . . . . ?
Cl1 Au1 P2 C221 -18.27(5) . . . . ?
Au1 Au1 P2 C221 91.45(5) 2 . . . ?
P1 Au1 P2 C211 -68.22(5) . . . . ?
Cl1 Au1 P2 C211 104.02(5) . . . . ?
Au1 Au1 P2 C211 -146.26(5) 2 . . . ?
P1 Au1 P2 C231 47.91(5) . . . . ?
Cl1 Au1 P2 C231 -139.85(5) . . . . ?
Au1 Au1 P2 C231 -30.13(5) 2 . . . ?
C221 P2 C211 C216 -17.11(14) . . . . ?
C231 P2 C211 C216 93.24(13) . . . . ?
Au1 P2 C211 C216 -147.23(12) . . . . ?
C221 P2 C211 C212 160.13(12) . . . . ?
C231 P2 C211 C212 -89.52(13) . . . . ?
Au1 P2 C211 C212 30.00(13) . . . . ?
C216 C211 C212 C213 0.8(2) . . . . ?
P2 C211 C212 C213 -176.54(13) . . . . ?
C211 C212 C213 C214 -0.8(3) . . . . ?
C212 C213 C214 C215 -0.2(3) . . . . ?
C213 C214 C215 C216 1.2(3) . . . . ?
C212 C211 C216 C215 0.2(2) . . . . ?
P2 C211 C216 C215 177.41(13) . . . . ?
C214 C215 C216 C211 -1.2(3) . . . . ?
C211 P2 C221 C226 -104.34(12) . . . . ?
C231 P2 C221 C226 144.52(12) . . . . ?
Au1 P2 C221 C226 19.73(13) . . . . ?
C211 P2 C221 C222 74.11(13) . . . . ?
C231 P2 C221 C222 -37.04(14) . . . . ?
Au1 P2 C221 C222 -161.82(11) . . . . ?
C226 C221 C222 C223 0.8(2) . . . . ?
P2 C221 C222 C223 -177.62(12) . . . . ?
C221 C222 C223 C224 -0.7(2) . . . . ?
C222 C223 C224 C225 0.4(3) . . . . ?
C223 C224 C225 C226 -0.1(3) . . . . ?
C224 C225 C226 C221 0.2(2) . . . . ?
C222 C221 C226 C225 -0.6(2) . . . . ?
P2 C221 C226 C225 177.92(12) . . . . ?
C221 P2 C231 C232 110.80(16) . . . . ?
C211 P2 C231 C232 -0.58(18) . . . . ?
Au1 P2 C231 C232 -119.14(16) . . . . ?
C221 P2 C231 C236 -73.27(14) . . . . ?
C211 P2 C231 C236 175.35(13) . . . . ?
Au1 P2 C231 C236 56.80(14) . . . . ?
C236 C231 C232 C233 -0.2(3) . . . . ?
P2 C231 C232 C233 175.7(2) . . . . ?
C231 C232 C233 C234 -0.6(4) . . . . ?
C232 C233 C234 C235 0.8(4) . . . . ?
C233 C234 C235 C236 -0.3(3) . . . . ?
C232 C231 C236 C235 0.8(3) . . . . ?
P2 C231 C236 C235 -175.32(15) . . . . ?
C234 C235 C236 C231 -0.5(3) . . . . ?
